CN1640972A - Water-based termite-proof insect-protected enclosed paint - Google Patents

Water-based termite-proof insect-protected enclosed paint Download PDF

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Publication number
CN1640972A
CN1640972A CN 200410052132 CN200410052132A CN1640972A CN 1640972 A CN1640972 A CN 1640972A CN 200410052132 CN200410052132 CN 200410052132 CN 200410052132 A CN200410052132 A CN 200410052132A CN 1640972 A CN1640972 A CN 1640972A
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China
Prior art keywords
proof
insect
water
termide
agent
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Application number
CN 200410052132
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Chinese (zh)
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CN1302080C (en
Inventor
陈寿生
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beijing Zhanchen Intelligent Property Management Co ltd
Beijing Zhanchen New Material Co ltd
China Zhanchen New Materials Group Co.,Ltd.
Shanghai Zhanchen Paint Co ltd
Zhuhai Zhanchen New Material Co ltd
Original Assignee
SHENZHEN ZHANCHENDA CHEMICAL INDUSTRY Co Ltd
Shanghai Fuchen Chemical Co Ltd
Beijing Zhanchen Chemical Co Ltd
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Priority to CNB2004100521325A priority Critical patent/CN1302080C/en
Publication of CN1640972A publication Critical patent/CN1640972A/en
Application granted granted Critical
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Abstract

The termite and pest preventing blocking aqueous base paint has the components including 25-50 % solid content aqueous resin 80-98 wt%, antifreeze agent 1-15 wt%, defoaming agent 0.1-0.8 wt%, base material moistening agent 0.1-0.8 wt%, zinc stearate 0-10 wt% and mothproof agent 0.5-8 wt%. It is used in painting wooden furniture, wooden floor and other wooden products to form termite and pest preventing film to inhibit the worm eating. The present invention has the advantages of high termite and pest preventing effect, good decorating effect, simple construction, etc. and is especially suitable for painting and decorating furniture and finishing house and office.

Description

Water-based termide-proof and insect-proof seal coat
Technical field
The present invention relates to a kind of water-borne wood coating, relate in particular to a kind of water-based termide-proof and insect-proof seal coat.
Background technology
At present, the termide-proof and insect-proof of timber is handled mainly based on infusion method and squeegee process, is about to timber and is immersed in the solution that contains medicine, and the solution brushing that maybe will contain medicine is on wood surface.Its shortcoming is that medicine easily runs off, and duration of efficacy is short, and medicine is harmful, can pollute environment; In addition the wood surface brushing behind the drug solution, influenced the lacquer decorations effect of wood surface.Therefore, at present the termide-proof and insect-proof pesticide application technology of timber or plank can not be applicable to the decorations of the application of woodenware such as modern wooden furniture and family, office.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of medicine to be difficult for the good water-based termide-proof and insect-proof seal coat of loss, lasting medicine, safety and environmental protection and decorative effect.
The technical scheme that the present invention solves the problems of the technologies described above is, adopt a kind of water-based termide-proof and insect-proof seal coat, the main ingredient of this lacquer and weight proportion thereof are: solids content is 25%~50% water-base resin 80%~98%, frostproofer 1%~15%, defoamer 0.1%~0.8%, ground wetting agent 0.1%~0.8%, insect-proof agent 0.5%~8%.
In order to increase the grinability of lacquer, this lacquer comprises that also weight ratio is 0~10% Zinic stearas.
Each component and the optimum weight proportioning thereof of this lacquer are: solids content is 32% water-base resin 85%, frostproofer 5%, defoamer 0.35%, ground wetting agent 0.65%, Zinic stearas 5%, insect-proof agent 4%.
In each component of seal coat of the present invention, described water-base resin is aqueous polyurethane dispersion or polyacrylate resin emulsion or their mixture; Described defoamer is polysiloxane-polyether copolymer emulsion class, polypropylene glycols, polyoxyethylene glycol-hydrophobic solid-polysiloxane mixture class, mineral oil base class or their mixture; Described ground wetting agent is polysiloxane-polyether copolymer class, pure ethers, dioctyl sulfuration sodium succinate salt or their mixture; Described insect-proof agent is water-soluble pyrethroid special efficacy insect-proof agent, stuck gram missible oil, the white clever 4-phenelyl of silicon [3-(4-fluoro-3-phenoxy phenyl) propyl group] dimethylsilane or their mixture; Described frostproofer is propylene glycol or ethylene glycol or their mixture.
Concrete each component that adopts of this lacquer is as follows: described water-base resin adopts aqueous polyurethane dispersion, described frostproofer to adopt ethylene glycol, described defoamer to adopt polyoxyethylene glycol-hydrophobic solid-polysiloxane mixture class, described ground wetting agent to adopt dioctyl sulfuration sodium succinate salt, described insect-proof agent to adopt water-soluble pyrethroid special efficacy insect-proof agent.
Compare with prior art, with water-based termide-proof and insect-proof seal coat of the present invention is to add filmogen and insect-proof agent in coatings additive(s), can be at wooden furniture, wood product surfaces such as timber floor form the termide-proof and insect-proof film, thereby stop the moth erosion of termite and other moth to woodenware, detect through GB/G18260-2000 " wood preservative is to termite toxic effect test method ", its termide-proof and insect-proof efficient is more than 1 grade, because medicine is difficult for running off by the paint film sealing, thereby to termite, moth has efficiently, persistent prevention and control capability, and can not cause damage to human body, also do not pollute the environment, than safety and environmental protection, and decorative effect is good, easy construction.
Embodiment
The present invention is further illustrated below in conjunction with embodiment.
The main ingredient and the weight proportion thereof of water-based termide-proof and insect-proof seal coat of the present invention are: solids content is 25%~50% water-base resin 80%~98%, frostproofer 1%~15%, defoamer 0.1%~0.8%, ground wetting agent 0.1%~0.8%, insect-proof agent 0.5%~8%.
In order to increase the grinability of lacquer, also can in said components, add 0~10% Zinic stearas.
In above-mentioned each component:
Aqueous polyurethane dispersion or polyacrylate resin emulsion or their mixture that described water-base resin can self-producedly also can adopt sky, Jieyang patina worker company limited or New Orient, Shuande chemical industry company limited to produce.
Described defoamer can adopt polysiloxane-polyether copolymer emulsion class, as the TEGO805 of the high chemical industry of German enlightening company limited production; Polypropylene glycols, the Pluriol P 2000 that produces as German BASF chemical industry company limited; Polyoxyethylene glycol-hydrophobic solid-polysiloxane mixture class is as the BYK024 of German Bi Ke chemistry (Asia-Pacific) private limited partnership production; The mineral oil base class, Foamster309A that produces as river, Shenzhen sea chemical industry company limited etc. or their mixture.
Described ground wetting agent can adopt the polysiloxane-polyether copolymer class, as the TEGO270 of the high chemical industry of German enlightening company limited production; The alcohol ethers, the Emulan HE 50 that produces as German BASF chemical industry company limited; Dioctyl sulfuration sodium succinate salt, Lutensit A-B0 that produces as German BASF chemical industry company limited etc. or their mixture.
Described insect-proof agent can adopt the water-soluble pyrethroid special efficacy insect-proof agent of Guangdong Province Insects Research Institute development, the stuck gram missible oil that Britain Shell Co. Ltd produces, the white clever 4-phenelyl of silicon [3-(4-fluoro-3-phenoxy phenyl) propyl group] dimethylsilane, other insect-proof agent or their mixture that Japan Pyrethrum Co., Ltd produces;
Described frostproofer can adopt Dow Chemical Pacific Ocean company limited or Guangzhou must justify propylene glycol or ethylene glycol or their mixture that trade Co., Ltd produces.
Concrete component and the weight proportion thereof that adopts of seal coat of the present invention can be following prescription:
Prescription one, aqueous polyurethane dispersion (solids content: 32%) be 85%, ethylene glycol is 5%, polyoxyethylene glycol-hydrophobic solid-polysiloxane mixture defoamer BYK024 is 0.35%, dioctyl sulfuration sodium succinate salt ground wetting agent Lutensit A-B0 is 0.65%, Zinic stearas is 5%, water-soluble pyrethroid special efficacy insect-proof agent is 4%.
Prescription two, aqueous polyurethane dispersion (solids content: 32%) be 89%, ethylene glycol is 4%, polyoxyethylene glycol-hydrophobic solid-polysiloxane mixture defoamer BYK024 is 0.5%, dioctyl sulfuration sodium succinate salt ground wetting agent LutensitA-B0 is 0.5%, Zinic stearas is 3%, water-soluble pyrethroid special efficacy insect-proof agent is 3%.
Prescription three, aqueous polyurethane dispersion (solids content: 32%) be 82%, ethylene glycol is 7%, polyoxyethylene glycol-hydrophobic solid-polysiloxane mixture defoamer BYK024 is 0.6%, dioctyl sulfuration sodium succinate salt ground wetting agent LutensitA-B0 is 0.4%, Zinic stearas is 5%, water-soluble pyrethroid special efficacy insect-proof agent is 5%.
Wherein fill a prescription one for optimum formula.
During preparation, after water-base resin and frostproofer, defoamer, ground wetting agent, these coatings additive(s)s of Zinic stearas are fully disperseed, add water-based pyrethroid special efficacy insect-proof agent and be uniformly dispersed and get final product.During coating decoration, can add an amount of water as the case may be and regulate viscosity, lacquer is applied to wood product surfaces such as furniture, timber floor with the method for brushing or spray again its closed allround is got final product.
Detect with detection method GB/T 18260-2000 " wood preservative is to termite toxic effect test method ", the quality and technical index and the harmful substance contents of water-based termide-proof and insect-proof seal coat of the present invention are as follows:
Sequence number Interventions Requested Assay The method of inspection
??1 Appearance of film Surfacing, smooth Range estimation
??2 Time of drying (25 ℃) Surface drying ??40min GB/T 1728-89 (second method)
Do solid work ??≤24h GB/T 1728-89 (first method)
??3 Sticking power ≤ 3 grades ??GB/T?9286-1998
??4 Hardness (the pencil method, 72h) ??HB GB/T 6739-1996 (A method)
??5 Pendulum-rocker hardness ??≥0.36 ??GB/T?1730-1993
??6 Water tolerance (25 ℃, 24h) Non-foaming, do not come off, wrinkle resistant, allow slightly to turn white, can recover GB/T 1733-93 (first method)
??7 Thermotolerance (60 ℃, 2h) No change ??GB/T?1735-79
??8 Volatile organic compounds (VOC) ??≤250g/L ??HBC12-2002
??9 Shock-resistance, kgcm ??≥45 ??GB/T?1732-1993
??10 Snappiness, mm ??≤2 ??GB/T?1731-1993
After testing, the termide-proof and insect-proof efficient of water-based termide-proof and insect-proof seal coat of the present invention is more than 1 grade.

Claims (9)

1, a kind of water-based termide-proof and insect-proof seal coat, it is characterized in that: the main ingredient of this lacquer and weight proportion thereof are: solids content is 25%~50% water-base resin 80%~98%, frostproofer 1%~15%, defoamer 0.1%~0.8%, ground wetting agent 0.1%~0.8%, insect-proof agent 0.5%~8%.
2, water-based termide-proof and insect-proof seal coat according to claim 1 is characterized in that: this lacquer comprises that also weight ratio is 0~10% Zinic stearas.
3, water-based termide-proof and insect-proof seal coat according to claim 2 is characterized in that: each component and the weight proportion thereof of this lacquer are: solids content is 32% water-base resin 85%, frostproofer 5%, defoamer 0.35%, ground wetting agent 0.65%, Zinic stearas 5%, insect-proof agent 4%.
4, according to claim 1,2 or 3 described water-based termide-proof and insect-proof seal coats, it is characterized in that: described water-base resin is aqueous polyurethane dispersion or polyacrylate resin emulsion or their mixture.
5, according to claim 1,2 or 3 described water-based termide-proof and insect-proof seal coats, it is characterized in that: described defoamer is polysiloxane-polyether copolymer emulsion class, polypropylene glycols, polyoxyethylene glycol-hydrophobic solid-polysiloxane mixture class, mineral oil base class or their mixture.
6, according to claim 1,2 or 3 described water-based termide-proof and insect-proof seal coats, it is characterized in that: described ground wetting agent is polysiloxane-polyether copolymer class, pure ethers, dioctyl sulfuration sodium succinate salt or their mixture.
7, according to claim 1,2 or 3 described water-based termide-proof and insect-proof seal coats, it is characterized in that: described insect-proof agent is water-soluble pyrethroid special efficacy insect-proof agent, stuck gram missible oil, the white clever 4-phenelyl of silicon [3-(4-fluoro-3-phenoxy phenyl) propyl group] dimethylsilane or their mixture.
8, according to claim 1,2 or 3 described water-based termide-proof and insect-proof seal coats, it is characterized in that: described frostproofer is propylene glycol or ethylene glycol or their mixture.
9, water-based termide-proof and insect-proof seal coat according to claim 3 is characterized in that: described water-base resin adopts aqueous polyurethane dispersion, described frostproofer to adopt ethylene glycol, described defoamer to adopt polyoxyethylene glycol-hydrophobic solid-polysiloxane mixture class, described ground wetting agent to adopt dioctyl sulfuration sodium succinate salt, described insect-proof agent to adopt water-soluble pyrethroid special efficacy insect-proof agent.
CNB2004100521325A 2004-11-04 2004-11-04 Water-based termite-proof insect-protected enclosed paint Active CN1302080C (en)

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CN1640972A true CN1640972A (en) 2005-07-20
CN1302080C CN1302080C (en) 2007-02-28

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101760105A (en) * 2010-03-24 2010-06-30 龙岩市金雷白蚁防治技术有限公司 Environment-friendly insect-preventing and heat-insulating coating for trees
CN101845266A (en) * 2009-03-24 2010-09-29 陈姣英 Anti-blushing transparent woodwork coating and production process thereof
CN101967756A (en) * 2010-10-15 2011-02-09 江苏宝泽高分子材料股份有限公司 Anti-mosquito water-proof airpermeability wear-resisting resin used for synthesizing leather and preparation method thereof
CN102489443A (en) * 2011-11-22 2012-06-13 南京林业大学 Sealing paint making technology for wood composite door
CN102675936A (en) * 2012-05-23 2012-09-19 王林宝 Colored paint for trees
CN103131270A (en) * 2013-02-19 2013-06-05 刘川 Multifunctional waterproof antiseptic aldehyde-eliminating glue and preparation method
CN104017405A (en) * 2014-06-19 2014-09-03 南京麦思德餐饮管理有限公司 Insect-repelling wood lacquer and preparation method thereof
CN105111861A (en) * 2015-09-11 2015-12-02 中山市和勍涂料科技有限公司 Formula of water-based multifunctional sealing agent
CN105482695A (en) * 2015-12-15 2016-04-13 天津一橙泽恒环保科技发展有限公司 Environment-friendly insect-proof coating
CN107033766A (en) * 2017-06-06 2017-08-11 合肥月煌新型装饰材料有限公司 A kind of furniture coating and preparation method
CN107815234A (en) * 2017-11-21 2018-03-20 广西吉宽太阳能设备有限公司 Termite-proof Furniture panel coating and production method
CN112694802A (en) * 2020-12-29 2021-04-23 东周化学工业(昆山)有限公司 Termite-resistant water-based paint and preparation method thereof
CN112724728A (en) * 2020-12-29 2021-04-30 东周化学工业(昆山)有限公司 Termite-resistant water-based paint and preparation method thereof
CN112745757A (en) * 2020-12-29 2021-05-04 东周化学工业(昆山)有限公司 Ultraviolet curing coating and preparation method thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1006397B (en) * 1985-09-23 1990-01-10 上海华东新型建筑材料厂 Processing of insecticide coating
CN1027615C (en) * 1988-07-28 1995-02-15 南京军区后勤部军事医学研究所 Long-acting hygiene spraying insecticide and making method
CN1397618A (en) * 2002-07-04 2003-02-19 许凤和 Environment protection type water polyester paint for wood products and its preparing process

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101845266A (en) * 2009-03-24 2010-09-29 陈姣英 Anti-blushing transparent woodwork coating and production process thereof
CN101760105A (en) * 2010-03-24 2010-06-30 龙岩市金雷白蚁防治技术有限公司 Environment-friendly insect-preventing and heat-insulating coating for trees
CN101967756A (en) * 2010-10-15 2011-02-09 江苏宝泽高分子材料股份有限公司 Anti-mosquito water-proof airpermeability wear-resisting resin used for synthesizing leather and preparation method thereof
CN101967756B (en) * 2010-10-15 2012-01-25 江苏宝泽高分子材料股份有限公司 Anti-mosquito water-proof airpermeability wear-resisting resin used for synthesizing leather and preparation method thereof
CN102489443A (en) * 2011-11-22 2012-06-13 南京林业大学 Sealing paint making technology for wood composite door
CN102675936A (en) * 2012-05-23 2012-09-19 王林宝 Colored paint for trees
CN102675936B (en) * 2012-05-23 2014-01-22 王林宝 Colored paint for trees
CN103131270A (en) * 2013-02-19 2013-06-05 刘川 Multifunctional waterproof antiseptic aldehyde-eliminating glue and preparation method
CN104017405A (en) * 2014-06-19 2014-09-03 南京麦思德餐饮管理有限公司 Insect-repelling wood lacquer and preparation method thereof
CN105111861A (en) * 2015-09-11 2015-12-02 中山市和勍涂料科技有限公司 Formula of water-based multifunctional sealing agent
CN105482695A (en) * 2015-12-15 2016-04-13 天津一橙泽恒环保科技发展有限公司 Environment-friendly insect-proof coating
CN107033766A (en) * 2017-06-06 2017-08-11 合肥月煌新型装饰材料有限公司 A kind of furniture coating and preparation method
CN107815234A (en) * 2017-11-21 2018-03-20 广西吉宽太阳能设备有限公司 Termite-proof Furniture panel coating and production method
CN112694802A (en) * 2020-12-29 2021-04-23 东周化学工业(昆山)有限公司 Termite-resistant water-based paint and preparation method thereof
CN112724728A (en) * 2020-12-29 2021-04-30 东周化学工业(昆山)有限公司 Termite-resistant water-based paint and preparation method thereof
CN112745757A (en) * 2020-12-29 2021-05-04 东周化学工业(昆山)有限公司 Ultraviolet curing coating and preparation method thereof

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Owner name: ZHANCHEN PAINTS GROUP CO., LTD.

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