CN1831061A - Two-components water type epoxy putty for anti-termide and anti-insect, prepn. method and use thereof - Google Patents
Two-components water type epoxy putty for anti-termide and anti-insect, prepn. method and use thereof Download PDFInfo
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- CN1831061A CN1831061A CN 200510024319 CN200510024319A CN1831061A CN 1831061 A CN1831061 A CN 1831061A CN 200510024319 CN200510024319 CN 200510024319 CN 200510024319 A CN200510024319 A CN 200510024319A CN 1831061 A CN1831061 A CN 1831061A
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Abstract
This invention discloses two-component aquosity epoxy termite-proof and bug-proof putty. The filming matter (liquid epoxy resin), special bug proof agent (such as insect control chrysanthemum ester style or other bug proof agent), coating auxiliary agent, quartz powder, talcum powder, disintagrated chalk, curing agent in the receipt are used in painting dressing process of furniture and plank floor to form termite and bug proof putty film to prevent termite and other bristletail to erode carpentry. Its efficiency is high, decorating effect is good, and execution is convenient, it can be used to carpentry processing of modern wood furniture painting and home decoration.
Description
Technical field
The present invention relates to a kind of water-borne wood coating, relate in particular to a kind of double-component aqueous epoxy type termide-proof and insect-proof putty.
Background technology
At present, the timber termide-proof and insect-proof is handled mainly based on infusion method and squeegee process, is about to timber and is immersed in the solution that contains medicine, and the solution brushing that maybe will contain medicine is on wood surface.As Chinese patent, a kind of epoxide modified putty, 02139822.4; Document (1) MA transparent woodenware priming paint of series and putty (" New Building Materials ", 2002,2) and the development (" medium-sized and small enterprises science and technology " of (2) aqueous transparent woodenware putty, 2001,12) technology of being reported, all do not have the termide-proof and insect-proof ability, its shortcoming is that medicine easily runs off, and duration of efficacy is short; Medicine is harmful, environmental pollution; Behind the solution of wood surface brushing medicine, influenced lacquer decorations effect to wood surface.Therefore, the termide-proof and insect-proof pesticide application technology of present timber or plank can not be applicable to the application and the decoration design for residence of modern wooden furniture.
Summary of the invention
The technical issues that need to address of the present invention are to disclose a kind of double-component aqueous epoxy type termide-proof and insect-proof putty, to overcome above-mentioned the deficiencies in the prior art.
Double-component aqueous epoxy type termide-proof and insect-proof putty of the present invention is made up of host and solidifying agent, and the weight ratio of host and solidifying agent is: 10: 1～5;
Wherein: the component and the parts by weight of host comprise:
12～32 parts in water, 0.2～0.6 part of wetting agent, 0.25～0.65 part of dispersion agent, 0.1～0.5 part of defoamer, 0.1～0.5 part in sterilant, 11～19 parts of silica powders, 5～15 parts of talcum powder, 31～41 parts of water-ground limestones, 6～16 parts of aqueous epoxy curing agents, 0.1～0.3 part of thickening material, 0.1～4 part of insect-proof agent;
Said wetting agent is an alkylphenol polyoxyethylene, and can adopt DOW Chemical (Dow Chemical) Investment Co., Ltd's trade mark is the product of X-405;
Said dispersion agent is an aqueous polyurethane, and can select Dutch EFKA (EFKA) the chemical industry company limited trade mark for use is the product of EFKA 4560;
Said defoamer is mineral oil (for the final residual liquid of petroleum refining), and can select Japanese Sheng Nuopuke (SAN-NOPCO) the chemical industry company limited trade mark for use is the product of NXZ;
Said sterilant is 5-chloro-2-methyl-4 isothiazolines-3-ketone, and can select Japanese Sheng Nuopuke (SAN-NOPCO) the chemical industry company limited trade mark for use is the product of A33;
The fineness of silica powder, order talcum powder and water-ground limestone is 800～1000 orders;
The chemical name of said aqueous epoxy curing agent is an aqueous polyamide, and can select the chemical company limited of U.S.'s gas (AIR PRODUCTS) trade mark for use is the product of MH-1000;
Thickening material is an aerosil, can select the product of U.S.'s Cabot (CABOT) chemical industry company limited for use;
Insect-proof agent is selected from a kind of or its mixture in the white spirit of pyrethroid, stuck gram missible oil or silicon (chemical name is 4-phenelyl [3-(4-fluoro-3-phenoxy phenyl) propyl group] dimethylsilane), can select the product of Guangdong Province Insects Research Institute, Britain Shell Co. Ltd or Japan Pyrethrum Co., Ltd for use;
The component and the parts by weight of solidifying agent comprise:
85～95 parts of liquid epoxiess, 4～14 parts of reactive thinners, Glacial acetic acid 0.5～1.5;
It is the product of R-140 that said liquid epoxies can be selected the trade mark of Mitsui petrochemical iy produced for use;
Reactive thinner is selected the butyl glycidyl ester for use, and can select the trade mark of U.S.'s Mobil (EXXONMOBIL) petrochemical iy produced for use is the product of N-10;
The preparation method of component aqueous epoxy type termide-proof and insect-proof putty of the present invention comprises the steps:
The preparation of host:
With 12～32 parts in water, 0.2～0.6 part of wetting agent, 0.25～0.65 part of dispersion agent, 0.1～0.5 part of defoamer, 0.1～0.5 part of mixing and stirring of sterilant adds 11～19 parts of silica powders then, 5～15 parts of talcum powder, 31～41 parts of water-ground limestones, dispersed with stirring 15～20min adds 6～16 parts of aqueous epoxy curing agents, 0.1～4 part of insect-proof agent, add thickening material 0.1～0.3 then and adjust denseness, redispersion 10min gets final product.
The preparation of solidifying agent:
With 85～95 parts of liquid epoxiess, reactive thinner stirs earlier for 4～14 parts, adds 0.5～1.5 part in Glacial acetic acid then, and dispersed with stirring 5min～10min gets final product.
During use being that 10: 1～5 ratio is mixed by weight with host and solidifying agent stirs and can construct, and is used for the application and the decoration design for residence of wooden furniture, and constructional method is identical with the method for this area routine.
The present invention mainly utilizes filmogen (aqueous epoxy resins) in the prescription, insect-proof agent, silica powder, talcum powder, coatings additive(s), solidifying agent etc., in the coating process of woodworks such as wooden furniture, timber floor, form the termide-proof and insect-proof film, thereby stop termite and of the moth erosion of other moth woodenware.Have advantages such as termide-proof and insect-proof efficient height, decorative effect are good, easy construction, can be used as the application and the decoration design for residence of modern wooden furniture.After testing, termide-proof and insect-proof efficient is 1 grade.
Embodiment
Embodiment 1
Host: (weight part)
27 parts in water, 0.4 part of wetting agent X-405,4,560 0.45 parts of dispersion agent EFKA, 0.3 part of defoamer NXZ, sterilant (A33), 0.15 part of 5-chloro-2-methyl-4 isothiazolines-3-ketone, 14 parts of 800 order silica powders, 10 parts of 1000 order talcum powder, 36 parts of 800 order water-ground limestones, 11 parts of aqueous epoxy curing agents (MH-1000), 0.2 part of thickening material aerosil, 0.4 part of insect-proof agent pyrethroid effective cypermethrin.
Solidifying agent: (weight part)
90 parts of liquid epoxiess (R-140), 9 parts of reactive thinners (N-10, butyl glycidyl ester), 1 part in Glacial acetic acid.
With water, wetting agent, dispersion agent, defoamer, the sterilant mixing and stirring adds silica powder then, talcum powder, water-ground limestone, dispersed with stirring 15min adds aqueous epoxy curing agent, and insect-proof agent adds thickening material then and adjusts denseness, and redispersion 10min gets final product.
The preparation of solidifying agent:
With liquid epoxies, reactive thinner stirs earlier, adds Glacial acetic acid then, and dispersed with stirring 5min gets final product.
During use being that 10: 1 ratio is mixed by weight with host and solidifying agent stirs and can construct, and is coated on wooden furniture, and constructional method is identical with the method for this area routine.After testing, termide-proof and insect-proof efficient is 1 grade.Detection method GB/T18260-2000 " wood preservative is to termite toxic effect test method ".Quality and technical index is as follows:
| Sequence number | Interventions Requested | Assay | The method of inspection | |
| 1 | Outward appearance | There is not mechanical impurity, no skinning | ||
| 2 | Appearance of film | Surfacing, smooth | Range estimation | |
| 3 | The host denseness | 8～14cm | GB/T1749 | |
| 4 | Time of drying (25 ℃) | Surface drying | ≤3h | GB/T1728-89 (second method) |
| Do solid work | ≤8h | GB/T1728-89 (first method) | ||
| 5 | Water tolerance | 168h passes through | GB/T1733-1993 | |
| 6 | Anti-gasoline | 96h passes through | GB/T1734-1993 | |
| 7 | The termide-proof and insect-proof ability, level | ≤ 1 grade | GB/T18260-2000 | |
Annotate: 0 grade of expression performance is best, and 1 grade is taken second place, and 5 grades the poorest.
Embodiment 2
Host: (weight part)
22 parts in water, 0.3 part of wetting agent (X-405), (EFKA 4560 for dispersion agent, aqueous polyurethane) 0.3 part, 0.2 part of defoamer (NXZ, mineral oil), sterilant (A33,5-chloro-2-methyl-4 isothiazolines-3-ketone) 0.2 part, 17 parts of 800 order silica powders, 15 parts of 1000 order talcum powder, 34 parts of 800 order water-ground limestones, aqueous epoxy curing agent (MH-1000, aqueous polyamide) 8 parts, 0.2 part of thickening material (M-5, aerosil), 2.8 parts of insect-proof agent (silicon is spirit in vain) 4-phenelyl [3-(4-fluoro-3-phenoxy phenyl) propyl group] dimethylsilane
Solidifying agent: (weight part)
86 parts of liquid epoxiess (R-140), 12.5 parts of reactive thinners (N-10, butyl glycidyl ester), 1.5 parts in Glacial acetic acid.
The blending ratio of host and solidifying agent is 1: 5, weight ratio.Other are identical with embodiment.
After testing, termide-proof and insect-proof efficient is 1 grade.Detection method GB/T18260-2000 " wood preservative is to termite toxic effect test method ".Quality and technical index is as follows:
| Sequence number | Interventions Requested | Assay | The method of inspection | |
| 1 | Outward appearance | There is not mechanical impurity, no skinning | ||
| 2 | Appearance of film | Surfacing, smooth | Range estimation | |
| 3 | The host denseness | 8～14cm | GB/T1749 | |
| 4 | Time of drying (25 ℃) | Surface drying | ≤2h | GB/T1728-89 (second method) |
| Do solid work | ≤7h | GB/T1728-89 (first method) | ||
| 5 | Water tolerance | 168h passes through | GB/T1733-1993 | |
| 6 | Anti-gasoline | 96h passes through | GB/T1734-1993 | |
| 7 | The termide-proof and insect-proof ability, level | ≤ 1 grade | GB/T18260-2000 | |
Annotate: 0 grade of expression performance is best, and 1 grade is taken second place, and 5 grades the poorest.
Claims (10)
1. a double-component aqueous epoxy type termide-proof and insect-proof putty is characterized in that, is made up of host and solidifying agent;
Wherein: the component and the parts by weight of host comprise:
12～32 parts in water, 0.2～0.6 part of wetting agent, 0.25～0.65 part of dispersion agent, defoamer 0.1～0.5, sterilant 0.1～0.5, silica powder 11～19, talcum powder 5～15, water-ground limestone 31～41, aqueous epoxy curing agent 6～16, thickening material 0.1～0.3, insect-proof agent 0.1～4;
Said sterilant is 5-chloro-2-methyl-4 isothiazolines-3-ketone;
Insect-proof agent is selected from a kind of or its mixture in the white spirit of pyrethroid, stuck gram missible oil or silicon (chemical name is 4-phenelyl [3-(4-fluoro-3-phenoxy phenyl) propyl group] dimethylsilane);
The component and the parts by weight of solidifying agent comprise:
85～95 parts of liquid epoxiess, 4～14 parts of reactive thinners, Glacial acetic acid 0.5～1.5;
Reactive thinner is selected the butyl glycidyl ester for use.
2. double-component aqueous epoxy type termide-proof and insect-proof putty according to claim 1 is characterized in that said wetting agent is an alkylphenol polyoxyethylene.
3. double-component aqueous epoxy type termide-proof and insect-proof putty according to claim 1 is characterized in that said dispersion agent is an aqueous polyurethane.
4. double-component aqueous epoxy type termide-proof and insect-proof putty according to claim 1 is characterized in that, said defoamer is mineral oil (for the final residual liquid of petroleum refining).
5. double-component aqueous epoxy type termide-proof and insect-proof putty according to claim 1 is characterized in that the fineness of silica powder, order talcum powder and water-ground limestone is 800～1000 orders.
6. double-component aqueous epoxy type termide-proof and insect-proof putty according to claim 1 is characterized in that thickening material is an aerosil.
7. double-component aqueous epoxy type termide-proof and insect-proof putty according to claim 1 is characterized in that, pyrethroid is Deltamethrin, effective cypermethrin or tetrabromo Cyano chrysanthemate.
8. according to each described double-component aqueous epoxy type termide-proof and insect-proof putty of claim 1～7, it is characterized in that the weight ratio of host and solidifying agent is: 10: 1～5.
9. according to the preparation method of each described double-component aqueous epoxy type termide-proof and insect-proof putty of claim 1～8, it is characterized in that, comprise the steps:
The preparation of host:
With water, wetting agent, dispersion agent, defoamer, the sterilant mixing and stirring adds silica powder then, talcum powder and water-ground limestone, dispersed with stirring 15～20min adds aqueous epoxy curing agent, and insect-proof agent adds thickening material then, and redispersion 10～15min gets final product;
The preparation of solidifying agent:
With liquid epoxies, reactive thinner stirs earlier, adds Glacial acetic acid then, and dispersed with stirring 5min～10min gets final product.
10. according to the application of each described double-component aqueous epoxy type termide-proof and insect-proof putty of claim 1～8, it is characterized in that, be used for the application and the decoration design for residence of wooden furniture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CNB2005100243199A CN100560668C (en) | 2005-03-10 | 2005-03-10 | A kind of double-component aqueous epoxy type termide-proof and insect-proof putty and its production and application |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100243199A CN100560668C (en) | 2005-03-10 | 2005-03-10 | A kind of double-component aqueous epoxy type termide-proof and insect-proof putty and its production and application |
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| CN1831061A true CN1831061A (en) | 2006-09-13 |
| CN100560668C CN100560668C (en) | 2009-11-18 |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101386691B (en) * | 2007-09-14 | 2011-04-27 | 上海富臣化工有限公司 | Woodware filler |
| CN102329551A (en) * | 2011-05-27 | 2012-01-25 | 安徽美佳新材料股份有限公司 | Multifunctional composite coating |
| CN102329552A (en) * | 2011-05-27 | 2012-01-25 | 安徽美佳新材料股份有限公司 | Preparation method of multifunctional composite coating |
| CN101412862B (en) * | 2008-11-18 | 2012-05-30 | 深圳市广田环保涂料有限公司 | Aqueous epoxy putty, and preparation and use method thereof |
| CN103289514A (en) * | 2013-05-10 | 2013-09-11 | 苏州工业园区方圆金属制品有限公司 | Anti-mosquito water-borne latex wall finish |
| CN104231867A (en) * | 2014-08-12 | 2014-12-24 | 海南红杉科创实业有限公司 | Anti-termite inorganic flake waterborne epoxy resin coating |
| CN106336146A (en) * | 2016-08-23 | 2017-01-18 | 柳州市国正机电物资有限责任公司 | Inner wall paint with insect repellent effect |
| CN106479320A (en) * | 2016-11-18 | 2017-03-08 | 陈劲 | A kind of rough ground mould inhibitor |
| CN106978004A (en) * | 2017-06-06 | 2017-07-25 | 合肥月煌新型装饰材料有限公司 | A kind of building decoration engineering inner wall putty and preparation method thereof |
-
2005
- 2005-03-10 CN CNB2005100243199A patent/CN100560668C/en active Active
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101386691B (en) * | 2007-09-14 | 2011-04-27 | 上海富臣化工有限公司 | Woodware filler |
| CN101412862B (en) * | 2008-11-18 | 2012-05-30 | 深圳市广田环保涂料有限公司 | Aqueous epoxy putty, and preparation and use method thereof |
| CN102329551A (en) * | 2011-05-27 | 2012-01-25 | 安徽美佳新材料股份有限公司 | Multifunctional composite coating |
| CN102329552A (en) * | 2011-05-27 | 2012-01-25 | 安徽美佳新材料股份有限公司 | Preparation method of multifunctional composite coating |
| CN103289514A (en) * | 2013-05-10 | 2013-09-11 | 苏州工业园区方圆金属制品有限公司 | Anti-mosquito water-borne latex wall finish |
| CN104231867A (en) * | 2014-08-12 | 2014-12-24 | 海南红杉科创实业有限公司 | Anti-termite inorganic flake waterborne epoxy resin coating |
| CN104231867B (en) * | 2014-08-12 | 2016-09-21 | 海南红杉科创实业有限公司 | Termite-proof inorganic scale aqueous epoxide resin paint |
| CN106336146A (en) * | 2016-08-23 | 2017-01-18 | 柳州市国正机电物资有限责任公司 | Inner wall paint with insect repellent effect |
| CN106479320A (en) * | 2016-11-18 | 2017-03-08 | 陈劲 | A kind of rough ground mould inhibitor |
| CN106978004A (en) * | 2017-06-06 | 2017-07-25 | 合肥月煌新型装饰材料有限公司 | A kind of building decoration engineering inner wall putty and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100560668C (en) | 2009-11-18 |
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Address after: 201700 No. 579, New District Road, Qingpu Industrial Park, Shanghai Co-patentee after: Zhanchen Coatings Group Co., Ltd. Patentee after: Shanghai Fuchen Chemical Co., Ltd. Co-patentee after: Beijing Zhanchen Chemical Industry Co., Ltd. Address before: 201700 No. 579, New District Road, Qingpu Industrial Park, Shanghai Co-patentee before: Shenzhen Zhanchenda Chemical Industry Co., Ltd. Patentee before: Shanghai Fuchen Chemical Co., Ltd. Co-patentee before: Beijing Zhanchen Chemical Industry Co., Ltd. Address after: 201700 No. 579, New District Road, Qingpu Industrial Park, Shanghai Co-patentee after: Zhanchen Coatings Group Co., Ltd. Patentee after: Shanghai Fuchen Chemical Co., Ltd. Co-patentee after: Beijing Zhanchen Chemical Industry Co., Ltd. Address before: 201700 No. 579, New District Road, Qingpu Industrial Park, Shanghai Co-patentee before: Shenzhen Zhanchenda Chemical Industry Co., Ltd. Patentee before: Shanghai Fuchen Chemical Co., Ltd. Co-patentee before: Beijing Zhanchen Chemical Industry Co., Ltd. |
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Address after: 8555 No. 201700 Shanghai city Qingpu District Songze Avenue Patentee after: Shanghai Zhanchen Paint Co., Ltd. Patentee after: CHINA ZHANCHEN PAINTS GROUP LTD. Patentee after: Beijing Zhan Chen novel material company limited Address before: 201700 No. 579, New District Road, Qingpu Industrial Park, Shanghai Patentee before: Shanghai Fuchen Chemical Co., Ltd. Patentee before: Zhanchen Coatings Group Co., Ltd. Patentee before: Beijing Zhanchen Chemical Industry Co., Ltd. Address after: 8555 No. 201700 Shanghai city Qingpu District Songze Avenue Patentee after: Shanghai Zhanchen Paint Co., Ltd. Patentee after: CHINA ZHANCHEN PAINTS GROUP LTD. Patentee after: Beijing Zhan Chen novel material company limited Address before: 201700 No. 579, New District Road, Qingpu Industrial Park, Shanghai Patentee before: Shanghai Fuchen Chemical Co., Ltd. Patentee before: Zhanchen Coatings Group Co., Ltd. Patentee before: Beijing Zhanchen Chemical Industry Co., Ltd. |
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Effective date of registration: 20200514 Address after: 201799 8555 Songze Avenue, Qingpu District, Shanghai Co-patentee after: Zhuhai zhanchen New Material Co., Ltd Patentee after: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Address before: 8555 No. 201700 Shanghai city Qingpu District Songze Avenue Co-patentee before: ZHANCHEN NEW MATERIAL GROUP Co.,Ltd. Patentee before: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Co-patentee before: BEIJING ZHANCHEN NEW MATERIAL Co.,Ltd. |