CN1290951C - Polyurethane termite-proof insect-protected enclosed primping paint - Google Patents

Polyurethane termite-proof insect-protected enclosed primping paint Download PDF

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Publication number
CN1290951C
CN1290951C CN 200410015514 CN200410015514A CN1290951C CN 1290951 C CN1290951 C CN 1290951C CN 200410015514 CN200410015514 CN 200410015514 CN 200410015514 A CN200410015514 A CN 200410015514A CN 1290951 C CN1290951 C CN 1290951C
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Prior art keywords
proof
agent
component
insect
mixture
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Expired - Lifetime
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CN 200410015514
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CN1640970A (en
Inventor
陈寿生
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Beijing Zhanchen Intelligent Property Management Co ltd
Beijing Zhanchen New Material Co ltd
China Zhanchen New Materials Group Co ltd
Shanghai Zhanchen Paint Co ltd
Zhuhai Zhanchen New Material Co ltd
Original Assignee
SHENZHEN ZHANCHENDA CHEMICAL INDUSTRY Co Ltd
Shanghai Fuchen Chemical Co Ltd
Beijing Zhanchen Chemical Co Ltd
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Application filed by SHENZHEN ZHANCHENDA CHEMICAL INDUSTRY Co Ltd, Shanghai Fuchen Chemical Co Ltd, Beijing Zhanchen Chemical Co Ltd filed Critical SHENZHEN ZHANCHENDA CHEMICAL INDUSTRY Co Ltd
Priority to CN 200410015514 priority Critical patent/CN1290951C/en
Publication of CN1640970A publication Critical patent/CN1640970A/en
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Publication of CN1290951C publication Critical patent/CN1290951C/en
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  • Chemical And Physical Treatments For Wood And The Like (AREA)
  • Paints Or Removers (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates to termite and moth proof polyurethane sealing paint which mainly makes use of film forming substances (alkyd resin, modified alkyd resin or nitric acid cellulose esters), pyrethroid class specific moth proof agents, zinc stearate, butyl acetate, flatting agents and defoaming agents in the formulation of the paint to form a termite and moth proof thin film during the process of coating wooden furniture, wood floors and other wooden articles, thereby preventing termites and other moths from eating woodenware. The present invention has the advantages of high termite and moth proof efficiency, good decorative effect, convenient construction, etc., and can be widely applied to the coating of modern wooden furniture and the decoration of families.

Description

Urethane termide-proof and insect-proof seal coat
Technical field the present invention relates to contain the solvent-borne type woodwork coating of element or mineral compound insects repellant, relates in particular to a kind of urethane (PU ammonia ester) termide-proof and insect-proof seal coat.
Background technology is present, and the timber termide-proof and insect-proof is handled mainly based on infusion method and squeegee process, is about to timber and is immersed in the solution that contains medicine, and the solution brushing that maybe will contain medicine is on wood surface.Its shortcoming is that medicine easily runs off, and duration of efficacy is short; Medicine is harmful, environmental pollution; Behind the solution of wood surface brushing medicine, influenced lacquer decorations effect to wood surface.Therefore, the termide-proof and insect-proof pesticide application technology of present timber or plank can not be applicable to the application and the decoration design for residence of modern wooden furniture.
Application number for example: 01108674 Chinese invention patent application discloses the technical scheme that name is called " termite preventing and controlling agent and uses thereof ".This scheme provides a kind of termite preventing and controlling agent.It is good fixing effect in soil, and the lasting period is long, the ground that is mainly used in termite prevention handle or be used for that brick mixes, the termite-proof harm of steel and concrete structure buildings over-ground part and ancient building.When the bamboo and wood vessel are carried out the processing of favorable moth-proof, still adopt squeegee process.Medicine easily runs off, and duration of efficacy is short, and medicine is harmful, the not fine yet solution of the shortcoming of environmental pollution.As can be seen, this control agent not too is fit to furniture woodenware termide-proof and insect-proof.
Summary of the invention the objective of the invention is to overcome above-mentioned the deficiencies in the prior art, and a kind of application of wooden furniture and termide-proof and insect-proof seal coat of decoration design for residence of can be used for is provided.
The present invention is achieved by the following scheme:
A kind of urethane termide-proof and insect-proof seal coat is divided into first component and component B, and the weight proportion of prescription is:
The first component comprises
A. the tripolymer of the tripolymer of the affixture of tolylene diisocyanate or hexamethylene diisocyanate and TriMethylolPropane(TMP) or tolylene diisocyanate or hexamethylene diisocyanate or their mixture 25~75%,
B. N-BUTYL ACETATE or vinyl acetic monomer or toluene or their mixture 25~75%,
Component B comprises
A. Synolac or Malin's acid resin or their mixture 63~75%,
B. vinyl acetic monomer or isopropylcarbinol or dimethylbenzene or their mixture 14.6~24.6%,
C. defoamer 0.06~0.40%,
D. flow agent 0.20~0.60%,
E. dispersion agent 0.10~0.30%,
F. Zinic stearas 5.10~8.10%,
G. insect-proof agent pyrethroid or other insect-proof agent 0.50~4.00%,
H. anti-settling agent 2.50~4.50%,
I. siccative T-12 organotin is a compound 0.04~1.00%.
Defoamer described in the component B is meant CFC-151 or BYK 066 or moral modest 5100 or their mixture; Described flow agent is meant KEPER-150 or BYK306 or HX-3130 or their mixture; Described dispersion agent is meant KEPER-602 or BYK-P104S or their mixture; Described anti-settling agent is meant 6901-21X or efka-4500 or organobentonite or their mixture;
First component and component B are in 0.3~1 during use: 1 ratio is mixed.
Mixed lacquer can add thinner and regulate viscosity.
Priming paint of the present invention can adopt following prescription and weight ratio thereof:
Embodiment one,
The first component:
1. the affixture of tolylene diisocyanate and TriMethylolPropane(TMP) and toluene diisocynate
The tripolymer of ester, proportioning are 8: 2 45%
2. N-BUTYL ACETATE 55%
Component B:
1. Synolac 68.34%
2. N-BUTYL ACETATE 20.20%
3. defoamer BYK 066 0.34%
4. flow agent BYK 306 0.38%
5. dispersion agent KEPER-602 0.20%
6. Zinic stearas 6.12%
7. the pyrethroid insect-proof agent 1.00%
8. anti-settling agent 6901-21X 3.20%
9. siccative T-12 0.22%.
Embodiment two,
The first component:
1. the affixture of tolylene diisocyanate and TriMethylolPropane(TMP) and toluene diisocynate
The tripolymer of ester, proportioning are 8: 2 25%
2. N-BUTYL ACETATE 75%
Component B:
1. Synolac 63%
2. N-BUTYL ACETATE 24.60%
3. defoamer BYK 066 0.06%
4. flow agent BYK 306 0.20%
5. dispersion agent KEPER-602 0.10%
6. Zinic stearas 7.10%
7. the pyrethroid insect-proof agent 1.30%
8. anti-settling agent 6901-21X 3.50%
9. siccative T-12 0.14%.
Embodiment three,
The first component:
1. the affixture of tolylene diisocyanate and TriMethylolPropane(TMP) and toluene diisocynate
The tripolymer of ester, proportioning are 8: 2 73%
2. N-BUTYL ACETATE 27%
Component B:
1. Synolac 73%
2. N-BUTYL ACETATE 14.60%
3. defoamer BYK 066 0.4%
4. flow agent BYK 306 0.6%
5. dispersion agent KEPER-602 0.20%
6. Zinic stearas 5.12%
7. the pyrethroid insect-proof agent 3.00%
8. anti-settling agent 6901-21X 2.80%
9. siccative T-12 0.28%.
The present invention mainly utilizes filmogen (Synolac, modified alkyd resin or cellulose nitrate ester), pyrethroid special efficacy insect-proof agent, Zinic stearas, N-BUTYL ACETATE, flow agent, the defoamer in the prescription, in the coating process of woodworks such as wooden furniture, timber floor, form the termide-proof and insect-proof film, thereby stop termite and of the moth erosion of other moth woodenware.Have advantages such as termide-proof and insect-proof efficient height, decorative effect are good, easy construction, can be used as the application and the decoration design for residence of modern wooden furniture.
The weight proportion of one of embodiment embodiment of the invention prescription is:
The first component:
1. the affixture of tolylene diisocyanate (TDI) and TriMethylolPropane(TMP), TDI
Tripolymer (8: 2) 45%
2. N-BUTYL ACETATE 55%
Component B:
1. Synolac 68.34%
2. N-BUTYL ACETATE 20.20%
3. defoamer BYK 066 0.34%
4. flow agent BYK 306 0.38%
5. dispersion agent KEPER-602 0.20%
6. Zinic stearas 6.12%
7. pyrethroid special efficacy insect-proof agent 1.00%
8. anti-settling agent 6901-21X 3.20%
9. siccative T-12 0.22%
Add up to: 100%
The weight proportion of two prescriptions of the embodiment of the invention is:
The first component:
2. the affixture of vulcabond (TDI) and TriMethylolPropane(TMP), TDI
Tripolymer (8: 2) 25%
2. N-BUTYL ACETATE 75%
Component B:
1. Synolac 63%
2. N-BUTYL ACETATE 24.60%
3. defoamer BYK 066 0.06%
4. flow agent BYK 306 0.20%
5. dispersion agent KEPER-602 0.10%
6. Zinic stearas 7.10%
7. pyrethroid special efficacy insect-proof agent 1.30%
8. anti-settling agent 6901-21X 3.50%
9. siccative T-12 0.14%
Add up to: 100%
The weight proportion of three prescriptions of the embodiment of the invention is:
The first component:
1. the affixture of tolylene diisocyanate (TDI) and TriMethylolPropane(TMP), TDI
Tripolymer (8: 2) 73%
2. N-BUTYL ACETATE 27%
Component B:
1. Synolac 73%
2. N-BUTYL ACETATE 14.60%
3. defoamer BYK 066 0.4%
4. flow agent BYK 306 0.6%
5. dispersion agent KEPER-602 0.20%
6. Zinic stearas 5.12%
7. pyrethroid special efficacy insect-proof agent 3.00%
8. anti-settling agent 6901-21X 2.80%
9. siccative T-12 0.28%
Add up to: 100%
Production technique of the present invention is after resin, solvent and coatings additive(s) are fully disperseed, to add pyrethroid special efficacy insect-proof agent and be uniformly dispersed.
Coating process of the present invention requires, and proportioning mixes up the termide-proof and insect-proof seal coat in accordance with regulations, uses the method for brushing and spraying with woodwork closed allround such as wooden furniture, timber floors.
Each chemical composition production firm is exemplified below among the present invention:
The affixture of polyisocyanates (as TDI, HDI) and TriMethylolPropane(TMP) (TMP) or the tripolymer of polyisocyanates or their mixture Bayer A.G.
N-BUTYL ACETATE (vinyl acetic monomer, toluene organic solvent or their mixture) the sincere solvent in Guangdong Jiangmen sky Products Co., Ltd.
Modified alkyd resin (or Synolac, Malin's acid resin or their mixture) Changxing, Guangzhou chemical industry company limited.
Vinyl acetic monomer (or isopropylcarbinol, dimethylbenzene organic solvent or their mixture) the sincere solvent in Guangdong Jiangmen sky Products Co., Ltd, Dongguan City are with boat chemical industry company limited.
Safe source trade Co., Ltd, the dark blue trade Co., Ltd in Guangzhou are engraved in defoamer (CFC-151, BYK 066, moral modest 5100 or their mixture) Dongguan.
Safe source trade Co., Ltd, Guangzhou Xanadu Pentium chemical industry company limited are engraved in flow agent (KEPER-150, BYK 306, HX-3130 or their mixture) Dongguan.
Safe source trade Co., Ltd is engraved in dispersion agent (KEPER-602, BYK-P104S or their mixture) Dongguan.
The fast safe Industrial Co., Ltd. in Zinic stearas Shenzhen.
Special efficacy insect-proof agent pyrethroid or other insect-proof agent Guangdong Province Insects Research Institute.
Anti-settling agent (6901-21X, efka-4500, organobentonite or their mixture) Jiangmen city pull up a horse magnificent trade Co., Ltd, Zhejiang Ward Industrial Co., Ltd..
Sea, siccative (organotin is compound such as T-12) Shenzhen Dehua worker company limited.
After testing, termide-proof and insect-proof efficient is 1 grade.Detection method GB/T 18260-2000 " wood preservative is to termite toxic effect test method ".
After testing, quality and technical index and harmful substance contents are as follows:
Sequence number Interventions Requested Assay The method of inspection
1 Appearance of film Surfacing, smooth Range estimation
2 Time of drying (25 ℃) Surface drying 15min GB/T 1728-89 (second method)
Do solid work ≤24h GB/T 1728-89 (first method)
3 Sticking power ≤ 3 grades GB/T 9286-1998
4 Hardness (the pencil method, 72h) ≥H GB/T 6739-1996 (A method)
5 Water tolerance (25 ℃, 18h) No change GB/T 1733-93 (first method)
6 Thermotolerance (60 ℃, 2h) No change GB/T 1735-79
7 Volatile organic compounds (VOC) 625g/L GB 18581-2001
8 Benzene Do not detect GB 18581-2001 appendix A
9 Toluene and dimethylbenzene summation 27.5% GB 18581-2001 appendix A
10 Free toluene diisocyanate 0.5% GB/T 18446-2001
Facts have proved, the present invention mainly utilizes filmogen (Synolac, modified alkyd resin or cellulose nitrate ester), pyrethroid special efficacy insect-proof agent, Zinic stearas, N-BUTYL ACETATE, flow agent, the defoamer in the prescription, in the coating process of woodworks such as wooden furniture, timber floor, form the termide-proof and insect-proof film, thereby stop termite and of the moth erosion of other moth woodenware.Have termide-proof and insect-proof efficient height, pollute for a short time, guard time is long, advantages such as decorative effect is good, easy construction.

Claims (5)

1. urethane termide-proof and insect-proof seal coat is characterized in that: lacquer is divided into first component and component B, and the weight proportion of prescription is:
The first component comprises
A. the tripolymer of the tripolymer of the affixture of tolylene diisocyanate or hexamethylene diisocyanate and TriMethylolPropane(TMP) or tolylene diisocyanate or hexamethylene diisocyanate or their mixture 25~75%,
B. N-BUTYL ACETATE or vinyl acetic monomer or toluene or their mixture 25~75%,
Component B comprises
A. Synolac or Malin's acid resin or their mixture 63~75%,
B. vinyl acetic monomer or isopropylcarbinol or dimethylbenzene or their mixture 14.6~24.6%,
C. defoamer 0.06~0.40%,
D. flow agent 0.20~0.60%,
E. dispersion agent 0.10~0.30%,
F. Zinic stearas 5.10~8.10%,
G. insect-proof agent pyrethroid or other insect-proof agent 0.50~4.00%,
H. anti-settling agent 2.50~4.50%,
I. siccative T-12 organotin is a compound 0.04~1.00%;
Defoamer is meant CFC-151 or BYK066 or moral modest 5100 or their mixture in the described component B; Described flow agent is meant KEPER-150 or BYK306 or HX-3130 or their mixture; Described dispersion agent is meant KEPER-602 or BYK-P104S or their mixture; Described anti-settling agent is meant 6901-21X or efka-4500 or organobentonite or their mixture;
First component and component B are in 0.3~1 during use: 1 ratio is mixed.
2. urethane termide-proof and insect-proof seal coat according to claim 1, it is characterized in that: the prescription of this lacquer and weight proportion thereof are:
The first component:
1. the tripolymer of the affixture of tolylene diisocyanate and TriMethylolPropane(TMP) and tolylene diisocyanate, proportioning is 8: 2 45%
2. N-BUTYL ACETATE 55%
Component B:
1. Synolac 68.34%
2. N-BUTYL ACETATE 20.20%
3. defoamer BYK066 0.34%
4. flow agent BYK306 0.38%
5. dispersion agent KEPER-602 0.20%
6. Zinic stearas 6.12%
7. the pyrethroid insect-proof agent 1.00%
8. anti-settling agent 6901-21X 3.20%
9. siccative T-12 0.22%.
3. urethane termide-proof and insect-proof seal coat according to claim 1, it is characterized in that: the prescription of this lacquer and weight proportion thereof are:
The first component:
1. the tripolymer of the affixture of tolylene diisocyanate and TriMethylolPropane(TMP) and tolylene diisocyanate, proportioning is 8: 2 25%
2. N-BUTYL ACETATE 75%
Component B:
1. Synolac 63%
2. N-BUTYL ACETATE 24.60%
3. defoamer BYK066 0.06%
4. flow agent BYK306 0.20%
5. dispersion agent KEPER-602 0.10%
6. Zinic stearas 7.10%
7. the pyrethroid insect-proof agent 1.30%
8. anti-settling agent 6901-21X 3.50%
9. siccative T-12 0.14%.
4. urethane termide-proof and insect-proof seal coat according to claim 1, it is characterized in that: the prescription of this lacquer and weight proportion thereof are:
The first component:
1. the tripolymer of the affixture of tolylene diisocyanate and TriMethylolPropane(TMP) and tolylene diisocyanate, proportioning is 8: 2 73%
2. N-BUTYL ACETATE 27%
Component B:
1. Synolac 73%
2. N-BUTYL ACETATE 14.60%
3. defoamer BYK066 0.4%
4. flow agent BYK306 0.6%
5. dispersion agent KEPER-602 0.20%
6. Zinic stearas 5.12%
7. the pyrethroid insect-proof agent 3.00%
8. anti-settling agent 6901-21X 2.80%
9. siccative T-12 0.28%.
5. urethane termide-proof and insect-proof seal coat according to claim 1 is characterized in that: the lacquer that is mixed in proportion adds thinner and regulates viscosity.
CN 200410015514 2004-02-26 2004-02-26 Polyurethane termite-proof insect-protected enclosed primping paint Expired - Lifetime CN1290951C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200410015514 CN1290951C (en) 2004-02-26 2004-02-26 Polyurethane termite-proof insect-protected enclosed primping paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 200410015514 CN1290951C (en) 2004-02-26 2004-02-26 Polyurethane termite-proof insect-protected enclosed primping paint

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Publication Number Publication Date
CN1640970A CN1640970A (en) 2005-07-20
CN1290951C true CN1290951C (en) 2006-12-20

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102504689A (en) * 2011-11-03 2012-06-20 佛山市万正涂料有限公司 Wood enclosing primer and application thereof
CN102533084A (en) * 2010-12-22 2012-07-04 展辰涂料集团股份有限公司 Poly urethane (PU) polyurethane paint
CN102533087A (en) * 2011-12-16 2012-07-04 展辰涂料集团股份有限公司 Polyurethane primer and preparation method thereof
CN103059707A (en) * 2011-10-20 2013-04-24 展辰涂料集团股份有限公司 Polyurethane paint used for melamine substrate

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CN101845266A (en) * 2009-03-24 2010-09-29 陈姣英 Anti-blushing transparent woodwork coating and production process thereof
CN101967756B (en) * 2010-10-15 2012-01-25 江苏宝泽高分子材料股份有限公司 Anti-mosquito water-proof airpermeability wear-resisting resin used for synthesizing leather and preparation method thereof
CN102220082B (en) * 2011-06-10 2013-01-23 东莞大宝化工制品有限公司 Bicomponent oily polyurethane primer with low VOC (volatile organic compounds)
CN102504682B (en) * 2011-11-03 2013-02-13 佛山市万正涂料有限公司 Polyurethane paint applied to woodworking and application thereof
CN103409056B (en) * 2012-12-31 2016-04-27 东莞市泰发化工有限公司 The transparent PU paint of a kind of ultrahard
CN103897580B (en) * 2014-03-11 2016-11-23 上海长润发涂料有限公司 A kind of electrostatic spraying polyurethane lacquer
CN104031539B (en) * 2014-06-17 2016-08-31 展辰新材料集团股份有限公司 A kind of electrostatic spraying priming paint
CN104497839B (en) * 2014-12-11 2017-11-21 三棵树涂料股份有限公司 It is capable of PU seal coats of high wetting Thief zone ground and preparation method thereof
CN106010199A (en) * 2016-07-28 2016-10-12 陈红旗 Termite-proof paint for solid wood furniture

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102533084A (en) * 2010-12-22 2012-07-04 展辰涂料集团股份有限公司 Poly urethane (PU) polyurethane paint
CN103059707A (en) * 2011-10-20 2013-04-24 展辰涂料集团股份有限公司 Polyurethane paint used for melamine substrate
CN103059707B (en) * 2011-10-20 2015-12-02 展辰涂料集团股份有限公司 A kind of polyurethane paint for melamine substrate
CN102504689A (en) * 2011-11-03 2012-06-20 佛山市万正涂料有限公司 Wood enclosing primer and application thereof
CN102533087A (en) * 2011-12-16 2012-07-04 展辰涂料集团股份有限公司 Polyurethane primer and preparation method thereof
CN102533087B (en) * 2011-12-16 2014-07-23 展辰涂料集团股份有限公司 Polyurethane primer and preparation method thereof

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Owner name: ZHANCHEN PAINTS GROUP CO., LTD.

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Address before: 518107 Guangming Niu Shan Industrial Zone, Shenzhen, Guangdong, Baoan District

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Address after: 518107, Shenzhen, Guangdong province Baoan District Guangming Street white industrial park on the south side of the sightseeing highway

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Patentee after: China Zhanchen New Materials Group Co.,Ltd.

Co-patentee after: Beijing zhanchen Intelligent Property Management Co.,Ltd.

Address before: 518107, Shenzhen, Guangdong province Baoan District Guangming Street white industrial park on the south side of the sightseeing highway

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Address after: 518107, Shenzhen, Guangdong province Baoan District Guangming Street white industrial park on the south side of the sightseeing highway

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Patentee after: China Zhanchen New Materials Group Co.,Ltd.

Co-patentee after: BEIJING ZHANCHEN NEW MATERIAL Co.,Ltd.

Address before: 518107, Shenzhen, Guangdong province Baoan District Guangming Street white industrial park on the south side of the sightseeing highway

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Effective date of registration: 20191225

Address after: 519000 No. 28 Nanhua Third Road, Fine Chemical Industry Zone, Gaolangang Economic Zone, Zhuhai City, Guangdong Province

Patentee after: Zhuhai zhanchen New Material Co.,Ltd.

Address before: 518107, Shenzhen, Guangdong province Baoan District Guangming Street white industrial park on the south side of the sightseeing highway

Co-patentee before: SHANGHAI ZHANCHEN PAINT Co.,Ltd.

Patentee before: China Zhanchen New Materials Group Co.,Ltd.

Co-patentee before: Beijing zhanchen Intelligent Property Management Co.,Ltd.

CX01 Expiry of patent term
CX01 Expiry of patent term

Granted publication date: 20061220