CN1830646A - Regeneration method of waste elastic body - Google Patents

Abstract

A process for regenerating the used or rejected elastomer features that the non-odor softening agent prepared from the kernel of plant fruit, oil-containing decolored mud and/or frequently used softener, non-odor activating agent, anti-oxidizing-antiageing agent, adsorbent, industrial refuse, the powder of bone, shell, or straw, and/or reinforcing filler are used to treat said used or rejected elastomer to obtain fine (80 meshes) powder, which can be used as the filler of rubber or plastics.

Description

A kind of regeneration method of waste elastic body

Technical field

The present invention proposes a kind of new renovation process of waste elastomer, it by with the reclaiming aid group, the innoxious cooperation of compounding ingredient, and with its piece to waste elastomer, bits, grain, powder mixes, broken, divide, heat, processing such as kneading, make and a kind ofly have that its smell all is not more than new elastomer under room temperature and high temperature, and advantage with no dust from flying, can be as rubber, mould plasticizing rubber powder or fine glue powder masterbatch or rubber master batch that goods industry raw material uses, the present invention relates generally to the regeneration of waste elastomer and solid waste, belongs to the technology category that castoff regenerative utilizes.

Background technology

The regeneration of waste elastomer class solid waste is an indispensable industrial class to this developing power of China, it pollutes etc. environment and has all played positive effect saving rubber, plastic cement resource and reducing waste elastomer class solid waste, especially in this maximum developing country of China, seem even more important! But the fine glue powder of the present elastomer major product of (accounting for more than 80% in China) in the occupation again---reclaimed rubber and new development in recent years etc. but exists the defective of its product survival and development of many obstructions always! The major defect that these products and production method thereof exist is:

1. though fair by its physical and mechanical property of reclaimed rubber of existing reclaimed rubber production method production, but to use foul smelling in a large number in its softening agent prescription and be rich in the aromatic hydrocarbons material of carcinogenicity such as benzo (a) pyrene, as: coal tar, pine tar, the aromatic hydrocarbons wet goods, desulphurizing activated dose also mainly use foul smelling and use in can produce poisonous a few material that the gases such as hydrogen sulfide of pollution are arranged (this be since these desulphurizing activated dose all will pH less than just had in 7 o'clock desulphurizing activated due to), as: contain 2, the tarry material of 2-curing two (the 6-tert-butyl group is to sylvan) (being called for short 420) causes the products obtained therefrom material that the stench that can't remove is all arranged! Particularly at its stink of production place of producing reclaimed rubber with the high temperature regeneration method and using reclaimed rubber more very!

2. for fear of the serious air pollution of elastomer the time with high temperature regeneration, patent such as CN1087099A, CN1127271.A has proposed the scheme of regeneration at room temperature, but the scheme of regenerating under these room temperatures is found after practical application, the product plasticizing rate of gained is poor, and powder is thick excessively, and its rerum natura and economy are all good unlike reclaimed rubber in downstream application; The softening agent prescription still will use the various smelly tar that have in a large number among the CN1087099A, and the air pollution degree of the product of gained when downstream high temperature is used is identical with reclaimed rubber; Do not mention cheap softening agent in the auxiliary agent that CN1127271.A proposes; CN1087099A, CN1127271.A can not get the good sizing material of plasticizing rate or contain the little sizing material product of powder particle diameter.

3. the fine glue powder product is good with thin person, but prior art may be limited to traditional " pure product " idea, the powder auxiliary material of adding can not surpass 5%, therefore the granularity of the product of gained is bigger, its fineness only can reach about 60 orders, and such product is difficult in acquisition application widely in the downstream industry.

4. existing elastomer is the production method of the employed reclaimed rubber of occupation and fine glue powder again, and the product of gained not only quality is of poor quality, and produce and when using dust pollution all very serious, do not meet requirement on environmental protection.

5. existing elastomer is occupation again, does not have to consider the elastomer setting of low gel content or low moral character is used further to the goods support of rubber and plastic industry, causes this class waste elastomer reuse not have door.

In addition, a large amount of solid waste that dump in the modern industry production are utilized with waste elastomer how innoxiously in a large number again, still blank at present.

Summary of the invention

The objective of the invention is; a kind of regeneration method of waste elastic body is provided; specifically by cooperating with the innoxious of one group of reclaiming aid; and with its piece to waste elastomer; bits; grain; powder mixes; broken; divide; heat; processing such as kneading; make and a kind ofly have at height; under the room temperature all ordorless and be difficult for airborne dust can be as rubber; mould plasticizing rubber powder or fine glue powder masterbatch or rubber master batch product that goods industry supplementary material uses; so that waste elastomer is in regeneration and reconstituted product when use environmental protectionization as much as possible all; cheap realizes finally that perhaps solid refuse is by the high-valued utilization again of the collaborative circulation of waste elastomer.Therefore we can say also that the present invention can take solid waste for a kind of waste elastomer and utilize method again.

Waste elastomer renovation process design of the present invention is as follows:

One. the design of renovation process

1. can add the reclaiming aid group that contains the powder auxiliary material system when pulverizing waste elastomer, to improve the efficient of pulverizing; The powder auxiliary material that adds during meticulous comminuting elastomer can be separated behind crushing operation, but better not to be separated into.

2. contain softening agent class batch ingredients in the reclaiming aid group, but do not use cacodorous material in the softening agent class batch ingredients, as: coal tar, pine tar, aromatic naphtha, pisselaeum, rubber cracking wet goods component are arranged; Under the treatment conditions such as high temperature carbonization when the regenerated elastic body or normal temperature pulverizing, the oil-containing benevolence of the oilseed plant of directly use cheapness, fruit are or/and the components such as grease-contained adsorption bleaching slag mud that produced in the operation of oil prodution industry decolorizing purification; And used softening agent consumption compares then still less with conventional amount used, thereby makes plasticizing rubber powder or fine glue powder masterbatch or the rubber master batch odorless or the basic odorless of gained; In softening agent system component, also add macromolecule material or/and activated monomer (emulsion) with grafting functional, the macromolecular chain of impaired fracture is able to the grafting reparation in the waste elastomer thereby make.

3. add desulphurizing activated dose of system component in the reclaiming aid group, it is little that described desulphurizing activated dose of employing has a smell, toxicity little (or being difficult for residual), do not emit pollution gas such as hydrogen sulfide during desulphurization reaction, and have conveniently reinforced, the batch ingredients of advantage such as cheap, with reduce or eliminate produce with use in the pollution of being distributed.

4. add low toxicity, nontoxic antioxygen age resistor class component in the reclaiming aid group, it is aging to reduce the hydrocarbon chain of elastomer when the regeneration of being heated is handled.

5. add the powder auxiliary material component in the reclaiming aid group, described powder auxiliary material is meant: have absorption peculiar smell characteristic the porous powder or/and industrial dregs or/and vegeto-animal bone, shell, leaf, root, straw, bar break flour or/and mineral or/and elastomer reinforcement filler commonly used etc.; Described these powder auxiliary material can be water-containing materials, the dehydrating operations in the time of can reducing existing powder auxiliary material like this and produce; Described these powder auxiliary material, be included in the crude hard filler particles in a kind of surface that generates in the operating process just as miniature file shape, this powder filler particulate can be filed under shearing action and cut chew off part hydrocarbon chain, make sizing material produce plasticity, in sizing material, add surperficial crude (hollow) microballon powder that is easy to slide, thereby offset and fewly to produce the unfavorable factor that plasticity diminishes, make the plasticizing rubber powder of gained or fine glue powder rubber master batch or masterbatch have advantages such as easy extrusion and cheap odorless with softening agent; In the reclaiming aid group, add powder auxiliary material, particularly use various solid refuses to make powder auxiliary material, this also can reduce the noxious waste pollution of other industry when waste elastomer is handled in regeneration, and when downstream application, reduce for the regenerated elastic body and plasticate, dust pollution when minimizing is eaten the powder operation down to elimination is mixing has improved environment widely.

6. add lubricated friction resistant medicament component in the reclaiming aid group, described lubricated friction resistant medicament is meant: have at rubber and reduce the frictional resistance of invalid pulverizing during by abrasive dust, thereby reduce the living heat in the meticulous crushing process.

7. when preparation contains the more odorless of powder auxiliary material plasticizing rubber powder or fine glue powder masterbatch or rubber master batch, more powder auxiliary material, softening agent part can rubber powder plastified earlier or meticulous pulverizing after add again.

8. the new method that proposes of the present invention, the scope of selecting materials of used harmless regeneration auxiliary agent group system is wide, contain the non-reclaiming aid material set that comes from non-renewable resources such as oil, coal, can in multiple elastomer process equipment, all can implement again, to reach the purpose of easy popularization.

9. the harmless regeneration auxiliary agent group system of the present invention's proposition also can independently form elastomer regeneration used additives product, perhaps uses as elastomeric complex; When preparation contains the more odorless plasticizing rubber powder of powder auxiliary material or fine glue powder masterbatch or rubber master batch, produce earlier by method of the present invention and to contain the more product of glue, and then add more powder auxiliary material or/and materials such as softening agents, for the back add main by powder auxiliary material or/and the system that softening agent class material is formed abbreviates compounding ingredient as.Add the product of compounding ingredient, its gel content is less, thereby is low-grade waste elastomer, has found the outlet of a regeneration.

The present invention with waste elastomer with after reclaiming aid group, compounding ingredient material cooperate, place conventional elastomer processing equipment, mix, broken, branch, heat, kneading, granulation handle, obtain the product of aforesaid odorless plasticizing rubber powder or fine glue powder masterbatch or rubber master batch, this product can adopt vacuum bag packages, with transportation and the raising product storage stability that makes things convenient for product.

Two. to the design of product

1. product of the present invention is meant a kind of waste elastomer or waste elastomer and solid waste of comprising, do not have a large amount of airborne dusts, when product uses, do not distribute nuisance smell, smog under residing room temperature～high temperature and the elastomeric compound of rubber and plastic industry is had the plasticizing rubber powder of multiple beneficial function or the masterbatch or the rubber master batch of fine glue powder; It can be used as waste elastomer and can take solid waste and be reproduced the form of utilizing after the processing.

2. the physical characteristic of the plasticizing rubber powder of the present invention's proposition or fine glue powder masterbatch or rubber master batch is better than the quality of existing reclaimed rubber, fine glue powder under the prerequisite of pursuing the downstream practical application effect.

Three. to the design of product application

Product of the present invention can be used as various waste elastomers and carries solid waste, the regeneration rubber, moulds the goods support of the raw material of goods industries with glue and auxiliary material; Rubber, mould and use product of the present invention in the goods industries, the airborne dust in the time of reducing or eliminating refining glue can reduce or eliminate goods and the pernicious gas in the goods process pollutes, and can reduce and fill a prescription and the technology cost, can improve rubber, mould property/this ratios of goods.The scheme of implementing the present invention's design is as follows:

The renovation process that proposes of the present invention specifically, its technical scheme of implementing design relates to: regeneration method of waste elastic body and waste elastomer are reproduced the product of handling the back gained and the application of product; Also relate in the described method with regeneration and handle the reclaiming aid group that cooperates; Its scheme feature is: when waste elastomer piece, bits, grain, powder being regenerated processing, must under the cooperation of reclaiming aid group, carry out harmless processing, described reclaiming aid group material comprises one or more in the following material kind at least, can be selected according to the needs of downstream industry by branch of industry, concrete reclaiming aid group material comprises:

(1) the softening agent class material of odorless, as use the plant benevolence of odorless, fruit is or/and contain grease decolouring slag mud or/and elastomer softening complex commonly used is made softening agent, and the consumption lower limit of softening agent than the usual amounts of prior art still less, its purpose is to make plasticizing rubber powder or fine glue powder masterbatch or the rubber master batch odorless or the basic odorless of processing gained, in this external softening agent material prescription, also can add the macromolecule material with grafting functional or the activated monomer of emulsion form, its objective is to make that the macromolecular chain of impaired fracture obtains the grafting reparation in the waste elastomer, but these are all looked downstream industry product different needs of the present invention are decided; (2) the desulfurization activator class material of odorless; (3) antioxygen age resistor class material; (4) powdery type auxiliary material, as use adsorbent commonly used, or/and industrial dregs, or/and vegeto-animal bone, shell, leaf, root, skin, straw break flour, or/and mineral, or/and elastomer reinforcement filler commonly used; And (5) add friction resistant lubricant class material.

With above-mentioned reclaiming aid group material and waste elastomer thing break flour after mix, place conventional elastomer processing equipment, mix, broken, divide, heat, processing such as kneading, make that a kind of to contain the waste elastomer percentage by weight be 95～70% plasticizing micelle material or be narrower than and equal 80 purpose fine glue powder mixtures, or further add and make another kind behind the compounding ingredient to contain the waste elastomer percentage by weight be to be less than 70～5% no airborne dust, under room temperature～180 ℃, do not distribute coal tar, pine tar, aromatic naphtha, pisselaeum is arranged, rubber hydrocarbon wet goods nuisance smell, smog and have softening to the elastomeric compound of rubber and plastic industry, chew and separate, reinforcement, fill, the plasticizing rubber powder of sulfurate activity function or the masterbatch or the rubber master batch of fine glue powder, dress up product by vacuum packet at last, supply the market.Point out in passing that in masterbatch of the present invention or rubber master batch product in waste elastomer weight percent content 5～95% scopes, just finish by the processing processing by a step after adding the reclaiming aid material for the product that has; The product needed that has further adds and stirs behind the compounding ingredient material or/and can finish after the kneading, granulation again again, in a word by the different requirements of branch of industry by downstream industry, by thinking of the present invention allotment voluntarily in above-mentioned content range.In addition, need under 180～240 ℃, process,, can give play to the effect and the advantage of product of the present invention equally as long as possess sealing or/and the condition of withstand voltage operation as downstream industry.

In above-mentioned method, said reclaiming aid group material, be that auxiliary agent class material with following one or more combines: the softening agent class material that comprises (1) odorless, (2) the desulfurization activator class material of odorless, (3) antioxygen age resistor class material, (4) powdery type auxiliary material, (5) and friction resistant lubricant class material;

The softening agent class material of (1) said odorless wherein, it is characterized in that: comprise following one or more material at least, also comprise by more than one materials and cooperate the softening agent group of forming, said softening agent class material comprises: (a) oil plant benevolence, fruit material, (b) vegetable oil, resin and derivative class material, (c) contain grease decolouring slag mud class material, and (d) elastomer is used softening agent always; Wherein,

(a) oil plant benevolence, fruit material, comprise: tung oil tree benevolence, olive benevolence, coconut benevolence, cotton seed benevolence, vegetable seeds, shelled peanut, soybean, trachycarpi,fructus benevolence, kardiseed, sunflower seeds kernel, Cha Ziren, linseed, perillaseed benevolence, rubber seed benevolence, olive meat, Chinese tallowtree seed benevolence, shiny-leaved yellowhorn benevolence, ansu apricot benevolence, hair Lai, fibert, Chinese pistache, chinaberry, walnut kernel, the sub-benevolence of elaeagnus mollis, immature pine nut;

(b) vegetable oil, resin and derivative class material comprise: maize germ oil, rice bran oil, cotton seed oil, rape seed oil, peanut oil, soybean oil, palm oil, sunflower oil, olive oil, tea-seed oil, coconut benevolence oil, tung oil, Linseed oil, Chinese tallowtree seed benevolence oil, perilla oil, restaurant recovered oil, rosin, tall oil, turkey red oil, Foral, dehydrogenated rosin, ester gum, pentalyn, dimethylbenzene abietic resin, rosin ester, pine tree resin, metasequoia resin, elm resin, peach resin, useless peanut paste;

(c) contain grease decolouring slag mud class material, comprising: the grease-contained active carbon that decolorizing purification workshop section of grease factory dumps or the slag mud of carclazyte;

(d) elastomer softening agent commonly used comprises: lubricating oil, machine oil, white oil, halogenated paraffin oil, paraffin oil, third fractional oil, six line oil, transformer oil, polybutene oil, C _4～18Aliphatic acid, vaseline, halogenated paraffin, paraffin, beeswax, animal oil, dark substitute, white factice, odorless bitumen, epoxidized soybean oil, alkyl phenolic resin, the rare resin of terpene, the rare phenolic resins of terpene, Petropols, special octyl phenol urea formaldehyde, coumarone, styrene resin, polyvinyl acetal resin, zinc resinate, low-molecular polyethylene wax, low-molecular polypropylene wax, stearic acid, palmitic acid, oleic acid, palmitic acid, polyvinyl alcohol, amylalcohol, hexanol, enanthol, octanol, decyl alcohol, lauryl alcohol, tetradecyl alchohol, hexadecanol, 18 alcohol, cyclopentanol, cyclohexanol, phenmethylol, ethylene glycol, propane diols, glycerine, 2-Ethylhexyl Alcohol, sec-n-octyl alcohol, laruyl alcohol, terpinol, (C _7～18) mixed fatty alcohol, pentaerythrite, xylitol, dipropylene glycol, dioctyl phthalate, dibutyl phthalate, diisobutyl phthalate, dialphanyl phthalate, tributyl phosphate, triethyl phosphate, triphenyl phosphate, tricresyl phosphate, di(2-ethylhexyl)phosphate phenyl-2-Octyl Nitrite, the terephthalic acid (TPA) dibutyl ester, the adipic acid dibutyl ester, adipic acid two-2-ethylhexyl, decanedioic acid two-2-ethylhexyl, barium stearate, calcium stearate, strontium stearate, dolomol, aliphatic acid barium, fatty acid magnesium, fatty acid calcium, the aliphatic acid strontium, barium laurate, calcium laurate, castor oil acid barium, castor oil acid calcium, zinc ricinate, barium naphthanate, calcium naphthenate, thermoplastic elastomer (TPE), reinforced resin, resin emulsion, rubber latex;

The weight content of softening agent in product is: 2～30%, but be good with 3～20%;

(2) said " desulfurization activator class material of odorless " wherein, comprise one or more the material that is selected from the following A group (have and to play chain scission and not generate hydrogen sulfide again in pH5～12 scopes) to the elastomer sulfide linkage, and/or be selected from the following B group material one or more, and/or be selected from the following C group material one or more; Above-mentioned said odorless desulfurization activator class material is mixed by following weight ratio and forms,

A group/B group/C group=100～2%/0～98%/0～98%, its consumption is: 0.1～5 part/100 parts (in tire glue powder or waste elastomer rubber powder weight basis) is for good;

Wherein said A group material, comprise: potassium ferric oxalate, ferrous oxalate, ferric oxalate, zinc stannate, calcium oxalate, calper calcium peroxide, hydrogen peroxide calcium sulfate adduct, hydrogen peroxide sodium sulphate, hydrogen peroxide copper sulphate, zinc oxalate, ferrous oxalate zinc, bodied ferric sulfate, sodium thiosulfate, sodium sulfite, sodium hydrogensulfite, ferrous sulfate zinc, alkali formula iron chloride, frerrous chloride, cerium hydroxide, cerous phosphate, ferric subsulfate, ferrous sulfate copper, zinc chloride, zinc silicate, zinc carbonate, basic zinc carbonate, trbasic zinc phosphate, basic zinc sulfate, zinc hydroxide, phosphoric acid hydrogen is ferrous, phosphoric acid one hydrogen zinc, the ferrous zinc of phosphoric acid hydrogen, the ferrous copper of phosphoric acid hydrogen, zinc sulfate, copper sulphate, Kocide SD, cupric phosphate, nickel hydroxide, nickelous carbonate, cobaltous sulfate, the ferrous zinc of rosin acid, rosin acid is ferrous, zinc abietate, the rosin acid cobalt, zinc naphthenate, cobalt naphthenate, the aliphatic acid cobalt, fatty acid zinc, zinc stearate, zinc gluconate, ferrous gluconate zinc, zinc laurate, zinc palmitate, calcium gluconae, glucose, blackstrap, basic copper carbonate, the peacock stone flour, zinc powder, aluminium powder, the aluminium foil bits, the nanoscale copper powder, nano grade iron powder, cupric oxide powder, leaded waste plastics, contain the cadmium waste plastics, contain chromium scrap leather bits, contain chromium shark bone glue, the refuse battery crushed material, metatitanic acid, the ethylenediamine tetrem is ferrous, ascorbic acid, Magnesium ascorbate, the tetramethyl ammonium halide, cetyl ethyl dimethyl ammonium halide, cetyl methyl diethyl ammonium halide, monobutyl dimethyl benzyl ammonium halide, the octadecyl ammonium halide, 3,5-dimethylphenyl benzyl ammonium halide, the dimethyl diphenyl ammonium halide, Methylethyl propyl group isobutyl group ammonium halide, the myristyl trimethyl-ammonium halide, myristyl dimethyl ammonium halide, cetyl dimethyl benzyl ammonium halide, cetyl halogenation pyridine, myristyl halogenation pyridine, dodecyl halogenation pyridine, tetrabutyl halogenation pyridine, ethyl dixylyl ammonium halide, oil base dimethyl benzyl ammonium halide, cetyl ethyl dimethyl ammonium halide, 2-thiol benzothiazole zinc, benzene a pair of horses going side by side thiazolyl disulphide, N-cyclohexyl-2-benzene a pair of horses going side by side thiazole sulfenamide, the N-tert-butyl group-2-benzene a pair of horses going side by side thiazole sulfenamide, PZ, zinc diethyl dithiocarbamate, the dipropyl zinc dithiocarbamate, zinc dibutyl dithiocarbamate, zinc dibenzyl dithiocarbamate, blue female disulphide of tetraethyl autumn, blue female disulphide of tetramethyl autumn, blue female disulphide of tetrabenzyl autumn, N, N '-diphenylguanidine, di-o-tolyl guanidine, 4,4 '-dithiomorpholine, zinc dibutyl dithiophosphate;

B organizes material, comprising: rosin, Foral, dimethylbenzene abietic resin, special octyl phenol urea formaldehyde, coumarone, turkey red oil, cotton seed oil, rape seed oil, peanut oil, soybean oil, palm oil, sunflower oil, olive oil, tea-seed oil, paraffin, stearic acid, beeswax, rubber, desulfurization plasticizing rubber powder, thermoplastic elastomer (TPE);

C organizes material, comprising: semi-hydrated gypsum powder, potter's clay powder, calcium sulfate dioxide composite Si powder;

(3) said " antioxygen age resistor class material " wherein, it is characterized in that said antioxygen age resistor class material comprises at least is selected from down in the listed material one or more, its consumption is that 0.1～5 part/100 parts (in tire glue powder or waste elastomer rubber powder weight basis) are for good, said antioxygen age resistor class material comprises:

3 hydroxybutyraldehydes-2-naphthylamines (being called for short antioxidant A H), 3 hydroxybutyraldehydes-2-naphthylamines (being called for short antioxidant A P), 6-ethyoxyl-2,2,4-trimethyl-1,2-dihyaroquinoline (being called for short antioxidant A W), acetone and diphenylamines pyroreaction thing (abbreviation antioxidant BLE), N-phenyl-B-naphthylamines (abbreviation antioxidant D), 2,6-di-tert-butyl-4-methy phenol (abbreviation antioxidant 264), the mixture of one hydrocarbonylation bis-phenol (being called for short age resistor 651), N-cyclohexyl-p-ethoxyaniline (being called for short age resistor CEA), N-cyclohexyl-P-nethoxyaniline (being called for short age resistor CMA), hydroquinones benzyl oxide (being called for short antioxidant MB A), 2,2 '-di-2-ethylhexylphosphine oxide (4-methyl-6-tert butyl phenol) (abbreviation antioxidant 2246), 2,2,4-trimethyl-1,2-dihyaroquinoline condensate (abbreviation anti-aging agent RD), N-phenyl-N '-cyclohexyl p-phenylenediamine (PPD) (being called for short antioxidant 4010 or CPPD), N-phenyl-N '-isopropyl-p-phenylenediamine (PPD) (being called for short antioxidant 4010NA or IPPD), N, N '-diphenyl-p-phenylenediamine (PPD) (being called for short antioxidant H or DPPD or PPD), 2-mercapto benzimidazole (abbreviation antioxidant MB), dilauryl thiodipropionate (abbreviation anti-oxidant DLTP), phosphorous acid benzene di-isooctyl, phosphorous acid bisphenol-A ester, hydrazine sulfate, titanyl sulfate, ferrous sulfate, frerrous chloride, iron ammonium sulfate, hydroxylamine hydrochloride, triisopropanolamine, oxalic acid;

(4) described " powdery type auxiliary material " wherein, it is characterized in that said " powdery type auxiliary material " has lightweight and fill function or/and have to chew and separate function, which comprises at least granularity and be narrower than and equal one or more in the listed material under 200 purposes, also comprise the polycrystalline attitude compound composition that forms and form by the thing phase change at aqueous phase by one or more material assembly; Said powdery type auxiliary material comprises: the powder class powder that (a) has the peculiar smell adsorptivity, (b) industrial slag great soil group powder, (c) vegeto-animal bone, leaf, root, straw, bar, shell, skin break flour class powder, (d) inorganic mineral class powder, (e) elastomer reinforcement filler class powder commonly used, (f) the calcining rear surface is the particulate class material of crude hard shape, (g) polycrystalline attitude compound composition class material, and (h) class is not subjected to the particulate material of fineness restriction; Wherein said:

(a) have the powder class powder of peculiar smell adsorptivity, comprising: active carbon, atlapulgite, attapulgite, diatomite, bentonite;

(b) industrial slag great soil group powder, comprise: chimney soot, steel-making slag powder, the red mud that aluminium manufacturer dumps, the aluminium ash that aluminium manufacturer dumps, the alkali mud that Sodium Carbonate Plant dumps, the salt slurry that chlor-alkali plant dumps, Citric Acid Plant, lactic acid factory, titanium powder plant, phosphoric acid factory, the gypsum that power plant dumps, the gypsum iron hydroxide mixing slag mud that steel mill dumps, the slag mud that contains the ginkgo leaf fibre that bilobanone factory dumps, the fibre-bearing dregs of a decoction that the pharmaceutical factory of traditional Chinese medicine dumps, the fibre-bearing slag mud that artificial liner enterprise dumps, pectin factory, tea processing factory, the fibre-bearing slag mud that the paper mill dumps, sugar, oil, medicine, the decolouring inactivation active carbon that chemical plant such as amino acid dump is or/and atlapulgite slag mud, the sugarcane that sugar refinery dumps, STEVIA REBAUDIANA, the mine tailings mud that the fibrous residue of beet, mining industry dump, the iron hydroxide mud that the chemical plant dumps, the burning slag that sulfuric acid plant dumps, the assorted pigment slag mud that pigment factory dumps, the black slag mud that the carbon black plant dumps, assorted cullet, assorted waste ceramic, brick bits powder, the boron mud that boron saltworks dumps, the barium slag that barium salt factory dumps, the strontium slag that strontium saltworks dumps, the zinc gray that zinc-plated factory dumps, the gangue that the colliery dumps, slag ash, useless phenol-formaldehyde resin powder, the waste paper scrap powder, useless fabric fibre powder, river course mud;

(c) vegeto-animal bone, leaf, root, straw, bar, shell, skin break flour class powder, comprise: rice hull ash, powdered rice hulls, straw ashes, straw powder, shell powder, peanut hull meal, cork powder, wood powder, charcoal powder, leaf powder, bamboo leaf powder, withered grass powder, bark powder, oyster shell whiting, bone meal, waste leather powder, coconut palm cot powder, coconut palm palm fibre wood wool powder, bamboo powder;

(d) inorganic mineral class powder comprises: chrysotile-asbestos, crocidolite, actinolite-asbestos, amosite, crocidllite, the white tremolite-asbestos, aluminite, alunogen, base aluminite, iron alum stone, natroalunite, pickeringite stone, bauxite, diaspore, the allophane trolleite, zirlite, augelite, celestine, barite, calcined kaolin, Emathlite, bentonite, potter's clay, attapulgite, earth, serpentine, kolskite, magnesia cerolite, the magnesia cerolite of nickel, hampdenite, cerolite, talcum, attapulgite, clinoenstatite, enstatite, forsterite, enstatite, hydrotalcite, foliated talc, cordierite, palygorskite, diopside, monticellite, manganolite, chloropal, allophane, schroetterite, lineae ablicantes stone, yellow kaolin, saponite, spadaite, silico-calcium sodium stone, baryta feldspar, baryta fledspar, anorthite, carnegieite, hydroserpentine, hedenbergite, achmatite achmite, jurupaite, the zinc scapolite, rumpfite, kaliophilite, the buttress shaft nepheline, sodalite, hauynite, noselite, the pyrope garnet, iron aluminium garnet, the brownmillerite garnet, chrysolite, fayalite, willemite, fiber copper silicon ore deposit, meionite, marialite, sarcolite, scapolite, gehetinite, sillimanite, melilite, clinozoisite, lawsonite, sial calcium magnesite, dumortierite, staurolite, kornerupine, okenite, silicoglaserite, gyrolite, the monocline silicoglaserite, riversideite, beryl, fish-eye stone, modenite, brewsterite, the stripping zeolite, the barium staurolite, phillipsite, oblique analcime, the oblique zeolite of sodium, the oblique zeolite of calcium, sodalite, karphostilibite, the porcelain laubanite, light thin zeolite, erionite, single zeolite, zoisite, thaumasite, wollastonite, okenite, Hydrogrossular, hibschite, heulandite, analcime, scolecite, foresite, antiedrite, desmine, laumontite, zeolite, aksaite, boromagnesite, carbon boron-calcium-magnesium stone, calciborite, datolite, pinnoite, Ke's hydrotalcite, the tremolite, hypersthene, the iron sepiolite, lazulite, vermiculite, bronzite, chlorite, nephrite, sepiolite, the iron magnesium amphibole, breunnerite, pictoamesite, vesuvian, actinolite, fine magnesite, shepardite, anhydrous carnallite, Dou chlorite, dolomite, ankerite, gypsum, calcium phosphate, calcite, cancrinite, brushite, prehnite, aspidelite, zoisite, allochite, callainite, galapectite, andalusite, pyrophyllite, the iron galapectite, illite, chamosite, feldspar, Juanyingshi, montmorillonite, albite, orthoclase, ararantite, the monocline natrojarosite, delvauxite, ilmenite, monheimite, zinc～botryogen, carbon sodium silicoglaserite, zincocopiapite, sauconite, smithsonite, marionite, aurichalcite, chessy copper, warringtonite, chrysocolla, oblique side's malachite, dioptase, cerine, rinkolite, nepouite, chlorite rises, the phosphorus-aluminium-strontium alum, perlite, the foam powder, opal, diatomite, muscovite, biotite, phlogopite, calcium aluminate, the iron calcium aluminate, coal dust;

(e) elastomer reinforcement filler class powder commonly used comprises: carbon black, calcium carbonate, white carbon, lithopone, silica flour, talcum powder, diaspore powder, brucite powder, aluminium hydroxide, alumina silicate, magnesium silicate, basic magnesium carbonate, magnesium carbonate, magnesium hydroxide, magnesia, zinc carbonate, zinc silicate, zinc oxide, zinc hydroxide, the Juanyingshi powder, mica powder, feldspar powder, dolomite dust, agstone, kaolin powder, potter's clay, coal dust, gypsum, vermiculite power, strontium sulfate, barium sulfate, wollastonite in powder, short fiber, the charcoal fiber, calcium monohydrogen phosphate, calcium phosphate, calcirm-fluoride, strontium fluoride, barium fluoride, magnesium fluoride, magnesium monohydrogen phosphate, silicic acid, calcium silicates, strontium silicate, barium silicate, cement, strontium carbonate, brium carbonate, Si-Al molecular sieve;

(f) the calcining rear surface is the particulate class material of crude hard shape, comprising: calcined kaolin powder, calcinated argil, calcined diatomite, flyash, calcining attapulgite, calcining bentonite, cenosphere powder;

(g) polycrystalline attitude compound composition class material comprises a class material that is combined again at aqueous phase by above-mentioned auxiliary material:

Its general formula is: [∑ a _iD _i∑ b _iE _iZH ₂O], the ∑ a in the formula _i, ∑ b _i, Z, be the mole indeterminate coefficient, the expansion of general formula is:

[a ₁D ₁·a ₂D ₂……a _nD _n·b ₁E ₁·b ₂E ₂……b _mE _m·ZH ₂O]

Or [∑ a _i(D ₁, D ₂Dn) ∑ b _i(E ₁, E ₂E _m) ZH ₂O],

D in the general formula ₁, D ₂D _nBe one or more the material in aforementioned powder auxilliary (filling out) material, the E in the general formula ₁, E ₂E _mBe following one or more listed compounds newly-generated in water, comprise:

Calcium sulfate, calcium monohydrogen phosphate, calcium phosphate, calcirm-fluoride, strontium fluoride, barium fluoride, magnesium fluoride, magnesium hydroxide, magnesium carbonate, magnesium monohydrogen phosphate, silicic acid, magnesium silicate, calcium silicates, strontium silicate, barium silicate, alumina silicate, zinc silicate, zinc carbonate, basic zinc carbonate, trbasic zinc phosphate, basic zinc sulfate, zinc sulphide, zinc hydroxide, aluminium hydroxide, iron hydroxide, alkali formula iron chloride, ferric subsulfate, strontium sulfate, barium sulfate, metatitanic acid, (without what calcine) lithopone, boric acid, metaboric acid, sodium tetraborate, Firebrake ZB, barium metaphosphate, aluminium borate, calcium citrate, calcium lactate, barba hispanica;

(h) the particulate species filler that not limited by fineness comprises: the old thermoplastic elastomer (TPE) of abandoning, waste plastics;

These above-mentioned materials need not painstakingly to dehydrate earlier, but the PH that must control the combination material that the various materials formation is arranged is 5～12, and wherein PH=5～9 with composition are good.And have PH resiliency person for good with the material after the combination, its proportion is good smaller or equal to 2.70; Its weight consumption in: be advisable in 2～1800 parts of (butt)/100 part (with a waste elastomer rubber powder weight basis), preferable amount ranges is: 2～30 parts of (butt)/100 part (in waste elastomer rubber powder weight basis), and powder auxiliary material consumption in the reclaiming aid group accounts for 5～100% by weight and is advisable; Why above-mentioned material need not earlier painstakingly dehydration, is because product of the present invention can be heated and generate heat in process, and an amount of water is arranged, and can prevent the sizing material incipient scorch.

Wherein (5) described " friction resistant lubricant class material " is characterized in that said friction resistant lubricant class material comprises one or more of following listed material at least; Said friction resistant lubricant class material comprises: (a) cationic surface active agent, (b) anionic surfactant, (c) nonionic surface active agent, (d) amphoteric surfactant, (e) silicone based material, and the surfactant that (f) comes from plant fully; Above-mentioned friction resistant lubricant, its consumption account for by weight the free water amount in the material handling of being reproduced 0.2～5% for good; Wherein said:

(a) cationic surface active agent comprises: stearyl dimethyl benzyl ammonium chloride, dodecyl benzyl dimethyl ammonium chloride, triethanolamine list olein, alkyl phosphate diethanol ammonium salt, octadecyl dimethyl ethoxy season ammonium salt, trihydroxyethyl quaternary ammonium Methylsulfate;

(b) anionic surfactant, comprise: saponification rosin, saponification shellac, stearic saponified, fatty is saponified, aerosol-OT salt, 1,2-dibutyl naphthalene-6-sodium sulfonate, oleic acid normal-butyl sulfuric ester sodium salt, ricinoleic acid butyl sulfuric ester two (or three) ethanolamine salt, N-oleoyl N-methyltaurine sodium, sodium lauryl sulfate, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, sodium alkyl sulfonate, sodium alkyl benzene sulfonate, the polyoxyethylene alkyl ether sulfate sodium salt, the benzyl naphthalene sodium sulfonate, turkey red oil, the dinaphthyl methane sodium disulfonate, dispersing agent MF, the condensation product of benzyl naphthalene sodium sulfonate and formaldehyde, potassium alkyl phosphate, the lauryl alcohol phosphate kalium salt, soap;

(c) nonionic surface active agent comprises: the AEO of the ethylene oxide condensate of C7～C9 straight chain fat, coconut oil alkyl oxalamide, AEO, C12～C18, dodecyl phenol polyethenoxy ether, octane phenol APEO--10, polyethylene castor oil, sorbitan oleic acid polyoxyethylene, sorbitan stearate, sorbitan monooleate, sorbitan stearate APEO, polypropylene glycol and ethylene oxide adduct, coconut Brij, Triton X-100;

(d) amphoteric surfactant comprises: N-dodecyl alanine, empgen BB;

(e) silicone based material comprises: methyl-silicone oil, ethyl silicon oil, methyl phenyl silicone oil, two-[3-triethoxysilane propyl group] tetrasulfide, r-sulfydryl propyl trimethoxy silicane, dimethyldimethoxysil,ne, MTMS, methyl triacetoxysilane, MTES, tetramethoxy-silicane, tetraethoxysilane, dimethyldiethoxysilane;

(f) come from the surfactant of plant fully, comprising: the water extraction of shrubalthea leaf, the water extraction of Chinese honey locust, the water extraction that will is far away, the water extraction of balloonflower root, the water extraction of sea-tangle.

The said waste elastomer renovation process of the present invention comprises two steps, promptly comprise waste elastomer is crushed to be narrower than in advance and equal 20 orders but be coarser than 80 purpose powders, press 100 parts of waste elastomers (dry weight basis) then, add 5.3～43 parts of reclaiming aid group materials, place the rubber manufacturing machinery device to mix, broken, divide, heat, kneading is handled, obtaining a quasi-plastic property rubber powder or granularity is narrower than and equals 80 purpose elastomer fine glue powder mix products, comprise that waste elastomer content is 95%～70% plasticizing rubber powder masterbatch or rubber master batch, or waste elastomer content is the masterbatch of 95%～70% fine glue powder or the production method of rubber master batch, comprise with waste elastomer content being that 95%～70% plasticity rubber powder or granularity are narrower than and equal 80 purpose fine glue powder masterbatch or rubber master batch and further be processed into waste elastomer content and be less than 70%～5% plasticizing sizing material or the masterbatch of fine glue powder or the production method of rubber master batch, and comprise that waste elastomer further is processed into granularity is narrower than the production method that equals the pure fine glue powder of 80 purposes, it is characterized in that: described regeneration method of waste elastic body comprises following two steps at least, wherein

Step (1) is that granularity is equaled 20 orders but after being coarser than 80 purpose waste elastomer particles and the reclaiming aid group being mixed in proportion for being narrower than, place rubber processing machinery, comprise mixing, pulverize, sieve, add harmless regeneration processing processing such as thermally desulfurizing and kneading, obtain plastifying rubber powder masterbatch, rubber master batch, or obtain 95% above powder granularity and be narrower than and equal 80 purpose fine glue powder mixtures, cross 80 purpose materials and return circular treatment in the above-mentioned rubber processing machinery;

The treatment process condition of step (1) comprising: operating temperature is room temperature～240 ℃; Operating pressure is normal pressure～3.5MPa; By the pH value of reclaiming aid group material regulation and control material system, the pH value stabilization that makes material system is 5～12; Material ratio by weight percentage is: the waste elastomer particle accounts for 95%～70%, and the reclaiming aid group accounts for 5%～30%; Under above-mentioned process conditions, after the described regeneration processing of completing steps (1), obtain a class waste elastomer content and be 95%70% plasticity rubber powder masterbatch, rubber master batch product or product, or the masterbatch of fine glue powder or rubber master batch product or product;

Step (2) is that the product with step (1) gained places mixing machinery after the weighing respectively in proportion with compounding ingredient, by stirring or again after mediating mixing and handling, obtaining containing the plasticizing rubber powder or/and granularity is narrower than the product that equals 80 purpose rubber powders;

The treatment process condition of step (2) comprising: operating temperature is room temperature～80 ℃; Operating pressure is normal pressure～0.1MPa; The pH5 of compounding ingredient system～9; Material ratio by weight: step (1) products therefrom accounts for 98%～5%; Compounding ingredient comprises that the reclaiming aid group material that comprises in step (1) products therefrom accounts for 2%～95% altogether; Under above-mentioned process conditions, process to handle and obtain another kind of waste elastomer content for less than 70%～5% plasticizing rubber powder masterbatch, rubber master batch, or/and the masterbatch of fine glue powder or rubber master batch product;

Wherein said reclaiming aid group comprises in the following functional material one or more at least in the step (1); Said functional material comprises the softening agent class material of odorless, the desulfurization activator class material of odorless, and antioxygen age resistor class material has the powder auxiliary material of filling function or/and chew the powder auxiliary material of separating function, and friction resistant lubricant class material;

Wherein the reclaiming aid group comprises that the reclaiming aid group of interim preparation is or/and the independent auxiliary agent category product through being processed in advance.Said reclaiming aid group is used by aforementioned material and is formed preparation recently or production in advance by following weight, and its component comprises following material:

Odorless softening agent class material: 0～30 part/100 parts (in waste elastomer rubber powder weight basis),

Odorless desulfurizing agent class material: 0～5 part/100 parts (in waste elastomer rubber powder weight basis),

Antioxygen age resistor class material: 0～5 part/100 parts (in waste elastomer rubber powder weight basis),

The powdery type auxiliary material: 0～30 part/100 parts (in waste elastomer rubber powder weight basis),

And lubricated anti-friction liniment class material: 0～0.5 part/100 parts (in waste elastomer rubber powder weight basis); The initial amount of all kinds of materials can not be zero simultaneously, and the adding cooperation of all kinds of material sums is: 5.3～43 parts/100 parts (in waste elastomer rubber powder weight basis).

Said compounding ingredient in the step (2) wherein, its main component is that powder auxiliary material is or/and the softening agent class material of odorless, both sums account for 80～100% of compounding ingredient total amount, and according to downstream industry processing needs, add about 20～0% one or more the functional material account for the compounding ingredient total amount, said functional material is with said functional material in the reclaiming aid group.

Said compounding ingredient in the step (2) wherein is characterized in that the powder auxiliary material that relates in the said compounding ingredient in the step (2) is that a class has the powdery type auxiliary material that lightweight is filled function, which comprises at least down one or more of listed material:

Powder with adsorptivity, industrial slag great soil group powder, vegeto-animal bone, leaf, root, straw, bar, shell, skin break flour class powder, inorganic mineral class powder, elastomer is used reinforcement filler class powder always.

Owing to do not use at the involved reclaiming aid group material of the said waste elastomer renovation process of the present invention or compounding ingredient material and to contain coal tar, pine tar, aromatic hydrocarbons wet goods nuisance material, so said reclaiming aid group material or the compounding ingredient material that can be used as the use of independent regeneration analog assistant material of the present invention reaches the product of being handled out again by its cooperation, naturally just do not have coal tar, pine tar, the strong foul smell of aromatic hydrocarbons wet goods nuisance, the inventor finds through the experiment contrast that under ℃ condition of room temperature～180 the said product of the present invention divides secondary primary with the smell that new rubber sent that does not add existing " reclaimed rubber " is difficult.

Method of the present invention, its feature comprises: when waste elastomer is pulverized in advance, add the auxiliary agent that contains powder auxiliary material, because dusty material has been brought into play isolating function, thereby improved the efficient of comminuting elastomer; When powder auxiliary material is added into as grinding aid, the roller pulverizer system of employing is narrower than when equaling 20～40 purpose rubber powders, with the weight of the powder auxiliary material that adds account for gained rubber powder mix products weight 3～10% for good, when adopting the normal temperature ultrafine crusher to produce to be narrower than when equaling 80 purpose fine glue powders, must add the reclaiming aid group that contains powder auxiliary material, wherein with the weight of the powder auxiliary material that adds account for gained rubber powder mix products weight 5～25% for good; When adopting normal temperature ultra-fine grinding mechanism to be narrower than to equal 80 purpose fine glue powders, according to the custom thinking, can use spiral separation equipment or/and the powder auxiliary material that adds will pulverize with the separation equipment such as flotation of ultrasonic device the time is removed, but the inventor the experiment proved that the powder auxiliary material that adds when pulverizing is not to remove to good.

Method of the present invention, its feature comprises: at plasticizing rubber powder or the fine glue powder masterbatch or the rubber master batch of system " containing waste elastomer in 95～5% scopes " " time, auxiliary agents such as more powder auxiliary material, softening agent can add after rubber powder is plastified earlier or be levigate again in the product.Wherein said powder auxiliary material, softening agent can be separately or are combined to form independently " compounding ingredient " together, after the waste elastomer nationality helps the reclaiming aid group to finish the regeneration processing, can be according to the requirement of downstream industry to product, add " compounding ingredient ", after mixing or further kneading, obtain the required less plasticizing rubber powder of waste elastomer or fine glue powder masterbatch or the rubber master batch of containing again.

Method of the present invention, its feature comprises: at the masterbatch or the rubber master batch of system plasticizing rubber powder or fine glue powder " time, to carrying the into nonmetal skeleton break flour of rubber powder in the raw material (waste elastomer) secretly, need not painstakingly to separate; and good not to be separated into, because can be used as auxiliary material equally, they play a role.

The product that waste elastomer is processed to described in the technical solution of the present invention, it is characterized in that: plasticizing rubber powder or fine glue powder masterbatch or rubber master batch do not distribute coal tar, pine tar, aromatic naphtha, pisselaeum are arranged under room temperature～180 degree centigrade, rubber hydrocarbon wet goods nuisance smell, smog, and this product that has just guaranteed that waste elastomer is processed to can not produce secondary pollution under the temperature of the various processing technologys of downstream application; Described masterbatch or rubber master batch can be by its rubber powder fineness that adopts, whether plastify through high temperature, whether advance roller or extruder kneading, processing such as granulation, its product comprises at least that following five classes: a. adopts to be narrower than and equals 20 orders but be coarser than 80 order rubber powders, in the presence of the reclaiming aid group, through mechanical treatment, and the plasticizing rubber powder rubber master batch that plastifies processing such as the kneadings of advancing roller or extruder again through high temperature, b. adopt to be narrower than and equal 20 orders but be coarser than 80 order rubber powders, in the presence of the reclaiming aid group, through mechanical treatment, and the plasticizing rubber powder masterbatch of handling through high temperature plasticizing but without kneading, c. adopt and be narrower than 80 purpose fine glue powders, in the presence of the reclaiming aid group, through mechanical mixture, and the plasticizing fine glue powder rubber master batch that plastifies processing such as the kneadings of advancing roller or extruder again through high temperature more than 80 ℃, d. adopt and be narrower than 80 purpose fine glue powders, in the presence of the reclaiming aid group, through mechanical mixture, and through the plasticizing fine glue powder masterbatch of high temperature plasticizing more than 80 ℃, e. adopts and is narrower than 80 purpose fine glue powders, in the presence of the reclaiming aid group, through mechanical mixture, but without the fine glue powder masterbatch of high temperature plasticizing; Described in addition masterbatch or rubber master batch also can by its to the effect in the rubber and plastic industry mixing process etc. also can be subdivided into have softening, chew separate, the masterbatch or the rubber master batch of one or more functions of reinforcement, filling, sulfurate activity; Contain percentage by weight in described masterbatch or the rubber master batch and be 5～95% waste elastomer, contain the percentage by weight of in process, introducing and be 95～5% the present invention's said " reclaiming aid group " and " compounding ingredient "; Wherein to contain waste elastomer product (promptly containing the less lower limit formulation product of waste elastomer) in weight ratio 10～35% scopes in the product (promptly containing the more upper limit formulation product of waste elastomer) that contains the waste elastomer in weight ratio 76～92% scopes in masterbatch or the rubber master batch and masterbatch or the rubber master batch for good; Be good with plasticizing fine glue powder masterbatch or rubber master batch in the product of the present invention, especially plasticizing fine glue powder masterbatch that makes with the fine glue powder of using 100 mesh sieves or rubber master batch and fine glue powder masterbatch are the best.If from the granule size branch of product, comprise that at least granularity equals to be narrower than 80 orders, but be coarser than 100 orders plasticizing rubber powder or fine glue powder masterbatch or rubber master batch product; Granularity equals to be narrower than 100 orders, but is coarser than 120 orders plasticizing rubber powder or fine glue powder masterbatch or rubber master batch product; Granularity equals to be narrower than 120 orders, but is coarser than 200 orders plasticizing rubber powder or fine glue powder masterbatch or rubber master batch product; And granularity equals to be narrower than 200 orders, but is coarser than 400 orders plasticizing rubber powder or fine glue powder masterbatch or rubber master batch product; Point out in passing: the said less lower limit formulation product of waste elastomer that contains of the present invention, be in particular low-grade waste elastomer harmless regeneration utilization, pointed out a desirable recycling outlet.

" softening " function that product of the present invention has, its reason is: the reclaiming aid group that is adopted is or/and contain foregoing odorless softening agent class material in the compounding ingredient; " chew and separate " function that described product has, its reason is: adopted in the reclaiming aid group at least and contain that the surface is crude hard polycrystalline attitude compound composition particulate or/and the microballon powder material with crude surface that is easy to slide in elastomer, this material has elastomer under the shearing force effect of rubber mixing machine roll chews the function of separating; " reinforcement " function that described product has, its reason is: used reclaiming aid group is or/and contain reinforcement material (as: carbon black, white carbon black, fiber powder, carbon fiber, calcium carbonate activated, activated earth, active bentonite, active Juanyingshi powder, active gypsum, crystal whisker of gypsum, reinforced resin, plastics etc.) in the compounding ingredient; " filling " function that described product has, its reason is: used reclaiming aid group is or/and contain aforesaid powder auxiliary material component in the compounding ingredient, it still is retained in the function that performance is filled in the sizing material after having brought into play the effect of isolating; " sulfurate activity " function that described product has, its reason is: reclaiming aid group or/and contain in the compounding ingredient promotes the elastomer crosslinked component (as: zinc oxide, magnesia, zinc hydroxide, magnesium hydroxide, zinc carbonate, magnesium carbonate etc.) that cures.

The application of product described in the technical solution of the present invention, its technical advantage is: as waste elastomer be reproduced into rubber, when the raw material of moulding goods industries uses with glue or as the auxiliary material carrier material, rubber, mould the airborne dust in the time of reducing or eliminating refining glue in the goods industries, can reduce or eliminate goods and pernicious gas in the goods process and pollute, can reduce the technology cost of filling a prescription and improve rubber, mould property/this ratios of goods; In addition, masterbatch that is processed into waste elastomer of the present invention or rubber master batch product are through practical proof, and it significantly is better than the similar raw and auxiliary material in the existing rubber industry, so have wide application prospect.

The specific embodiment

Further specify the content that meets the present invention's design with selected embodiment below, but should not be regarded as limiting the scope of the invention.

Embodiment 1.

Taking by weighing the waste elastomer granularity by weight is 100 parts in 20～30 purpose radial micelles, take by weighing by the powdery type auxiliary material: " the white carbon clay (aqueous phase is newly-generated; moisture 80%;; in butt ;) 5 parts; ((Sodium Carbonate Plant dumps alkali mud, PH＞9, moisture 30%, in butt) 10 parts, (Citric Acid Plant dumps gypsum, PH＜4, moisture 30%) in butt) 10 parts " and the lubricated class material of friction resistant: " 0.07 part of dispersing agent MF, methyl-silicone oil or/and two-0.07 part of [3-triethoxysilane propyl group] tetrasulfide " 25.14 parts of the reclaiming aid groups formed; The PH of this kind reclaiming aid group system is 7～9.

Above-mentioned material is placed airtight mix jar mixing earlier, import in the rubber normal temperature ultrafine crusher by spiral conveying tube then and pulverize processing, in this process, because the reclaiming aid group that adds is many and moisture, micelle in the mixed material can not reunited after pulverizing again, and gained rubber powder material is easy to be ground into be narrower than and equals 80 orders; Its reason is, because the powder auxiliary material of several different crystal forms that contain in the reclaiming aid group (refers to clay, alkali mud, gypsum class material) in this process, mixes mutually, coat, be heated, reunite, the scleroma back generates a class and has hard crude surface, particle diameter is narrower than and equals 200 purpose particulates, when the particulate of this moisture powdered form uses as reclaiming aid, good interleaving agent when it is the elastomer pulverizing again, simultaneously, this have the powder auxiliary material particulate of miniature file shape (above-mentioned is hard crude surface) configuration under shearing action, can file and cut chew off part hydrocarbon chain, so not only make sizing material be easy to pulverize, and can make product on follow-up roller, add man-hour, make sizing material produce plasticity, the heat that produces in the crushing process is in time taken away by the latent heat of water again, the powder crushing process can be carried out constantly, material after the pulverizing imports material-accumulating bin with aspiration channel, and the steam of evaporation is got rid of by the spiral separation organ pipe.Experimental results show that: the output of product and fineness depend primarily on used pulverizer effect, and when the theoretical volume of the reclaiming aid group material that adds was identical, the size distribution of its gained rubber powder material did not have too big difference.Experimental results show that: with do not add obtain after the reclaiming aid group is pulverized 90% can mistake 40 mesh sieves radial rubber powder object as a comparison, in its hourly output is that the vulcanized rubber normal temperature ultrafine crusher of 100 parts (weight) is a benchmark, after adding reclaiming aid group of the present invention, in 5～55 (reclaiming aid group theoretical volume) ml/100g (tire micelle) scopes, the fineness of gained fine glue powder product rises to 90% can cross 100 mesh sieves, the rubber powder that wherein can cross 120 mesh sieves reaches 70%, and present thin person and rise regularly, thick person descends regularly; The product hourly output rises to more than 150 parts by 100 parts.All adopt plane mill rubber normal temperature ultrafine crusher to pulverize when comparing, the theoretical proportion of reclaiming aid group material is 2.7 in the present embodiment, being equivalent to reclaiming aid group material addition is 9.3 (theoretical volume) ml/100g (tire micelle), 125 parts of the mixed materials that gained is once pulverized, wherein contain free water less than 2%, the rubber powder fineness: 95% crosses 80 mesh sieves, wherein crosses 100 mesh sieves and accounts for 90%, crosses 120 mesh sieves and accounts for 70%.To a crushed mixture material in the feed bin with 80 orders, 100 orders, 120 orders number sieve (industrial metal silk braiding square-mesh screen GB/T5330-1985, eqv ISO4783-2:1981) screening, but 80 mesh sieve materials are led back row circulation pulverizing again in the batching mix jar, screened material is led into different feed bins by the fineness branch again, at least can obtain the product of three kinds of specifications, promptly obtaining granularity is narrower than and equals 80 orders, but greater than 12.5 parts of 100 purpose products, granularity is narrower than and equals 100 orders, but greater than 18.75 parts of 120 purpose products, granularity is narrower than and equals 87.5 parts of 120 purpose products.The product of screening gained is stored in respectively in separately the feed bin, these odorlesses and have and chew the product of separating function and can directly supply market, downstream and use, also can the said goods further be processed according to the different needs in market, downstream, soon the said goods is re-used as raw material and places mechanical mixer with having multi-functional compounding ingredient, mix again, obtain having of another kind of odorless chew separate function and have a softening function, the granularity of desulphurizing activated function is narrower than the masterbatch or the rubber master batch product of 80 purposes plasticizing rubber powder or fine glue powder, show content according to design of the present invention and embodiment in a word, can produce weight content easily with waste elastomer is the product that a series of markets of 5%～95% are suitable for.

Above-mentioned said compounding ingredient, it is formed based on powdery type filler composition, adds in a spot of odorless softening agent class material, desulphurizing activated dose of class material of odorless and antioxygen age resistor class material, the friction resistant lubricant class material one or more according to the needs of downstream industry then.Said in the present embodiment compounding ingredient by " containing 134 parts in paper fibrous residue mud (paper mill dumps; cross the dry powder of 120 mesh sieves), 29 parts of the compound calcium sulphate dihydrates of hydrated SiO 2 (inorganic compound composition; cross the dry powder of 200 mesh sieves), 112 parts of salt slurries (chlor-alkali plant dumps; cross the dry powder of 200 mesh sieves); and 5 parts in machine oil, 5 parts of rosin; " combine, the formation total amount is 285 parts a compounding ingredient 1, and its pH is 8～9.285 parts compounding ingredients 1 are joined in 125 parts of 100 orders of aforementioned gained or the fine glue powder masterbatch that 120 mesh sieves get, carry out abundant mix by mechanical mixer, promptly obtaining a kind of auxiliary agent (comprising reclaiming aid category material and compounding ingredient class material) content is 73%, waste elastomer content is 27% odorless and has and chew the fine glue powder masterbatch of separating function that total amount is 410 parts.

Effect test: do not equal 100 orders and have to chew the fine glue powder masterbatch product of separating function and separate the agent use as natural rubber the chewing in the processing of plasticating with adding being narrower than of compounding ingredient in this example, and compare with prior art, as seen fine glue powder masterbatch product of the present invention has the good effect of plasticating.Table 1 is separated agent to the plasticate detection data of effect of natural rubber for using different chewing.

Table 1

Detect prescription: detect the material numbering:	1#	2#	3#	4#	5#
						(3# smoked sheet) natural rubber (part)	100	100	100	100	100
Present embodiment gained rubber powder masterbatch (part)	12.5	/	/	/	/
						60 order radial-ply tyre rubber powders (part)	/	10	/	/	/
80 order radial-ply tyre rubber powders (part)	/	/	10	/	/
						Precipitated calcium carbonate (part)	/	2.5	2.5	/	/
Processing aid A (part)	/	/	/	2	/

Stearic acid (part)

0.1

0.1

0.1

0.1

0.1

Refining glue mode: 6 mills, zero 5 times/one section of roll spacing thin-pass, 5 times/two sections of thin-passes, 5 times/three sections of thin-passes more again

Intersegmental blanking time diel
						(one section material) ML100 ℃/1+4	50.0	60.0	59.5	50.0	62.0
(two sections material) ML100 ℃/1+4	40.0	51.2	50.5	41.5	53.0
						(three sections material) ML100 ℃/1+4	35.2	46.5	45.6	37.6	48.0

By table 1 as seen: use fine glue powder masterbatch of the present invention to separate agent as chewing of natural rubber, not only have good chewing and separate effect, its effect of plasticating to natural rubber also is better than commercially available chewing and separates processing aid A and (annotate: the compound thing that consists of fatty acid zinc etc. of commercially available processing aid A, the price comparison costliness), and the cost of plasticating of natural rubber is significantly reduced, this is not only because the cheap effect of bringing of fine glue powder masterbatch of the present invention, and owing to fine glue powder is introduced in the natural rubber with larger proportion ground, make the volume increment of sizing material, but the also not obvious reduction of the powerful rerum natura of sizing material, this has very big positive effect to the development of rubber industry undoubtedly.In addition, the masterbatch of fine glue powder described in the present embodiment also has good pH resiliency as chewing to separate when agent is used, thereby has enlarged the operating flexibility of sizing material processing in pH value 5～9 scopes.

Branch of industry such as desire are produced other and are contained odorless that waste elastomer is 5～95% (weight ratios) and elastomer is had when chewing the fine glue powder masterbatch product of separating function, can make relevant product easily with reference to the content of 1 publicity of embodiment.

Note: ML100 ℃/1+4 represents the Mooney viscosity of the sizing material of being plasticated, the detected temperatures of 100 ℃ of expression Mooney detectors, and 1+4 represents that sizing material advances behind the instrument preheating one minute continuous detecting four minutes then.The insider thinks that Mooney viscosity is more little, and the expression sizing material is soft more, and sizing material is easy to moulding more.

Embodiment 2.

It is 20～30 100 parts in order tire micelles and " the reclaiming aid group 2 " 25.5 parts be made up of following material that parts by weights another name is got the waste elastomer granularity, described " reclaiming aid group 2 " is the 200 purposes powder auxiliary material-kahikatea wood sawdust (pH=5 of this material～6 by granularity, moisture about 70%, in butt) 25 parts, with 0.5 part of friction resistant lubricant class material-polyethylene glycol octyl phenyl " combine; above-mentioned material is placed airtight malaxation device mixing earlier; import in the vulcanized rubber normal temperature ultrafine crusher by spiral conveying tube then; pulverize; obtain after the screening being narrower than and equal 120 parts of 80 purpose masterbatch products; import material-accumulating bin, wherein be narrower than and equal 100 purposes with aspiration channel

Material accounts for more than 85%; Granularity is coarser than 80 purpose materials, and can to return pulverizer relaying continued powder broken.Above-mentioned masterbatch product also can further be processed, being about to above-mentioned masterbatch product imports spiral separation equipment (also claiming rotational flow separation equipment) or has in the water flotation formula separation equipment of ultrasound functions and separate, remove the thin wood powder of band water, (the thin wood powder of band water returns dosage bunker and recycles), the fine glue powder that is separated is drying again, screening just can obtain being narrower than and equal the meticulous pure rubber powder of 80 purposes, yield is 85%, past contact meeting mixes in the fine glue powder product that is separated 0～5% powder auxiliary material fine powder, but it does not influence downstream industry (as coatings industry, the rubber and plastic industry) application in.Point out that in passing said friction resistant lubricant is good with non-foaming person, selected friction resistant lubricant all belongs to the friction resistant lubricant of non-foaming type among this example and the embodiment 1.

By embodiment 2 as seen:

Present embodiment can get two series products at least, and wherein a class is the fine glue powder masterbatch (its granularity equals 80 orders for being narrower than, yield is 95%, and the masterbatch product is 120 parts) of the good filling function of having of odorless; Another kind of for odorless, be narrower than and equal the pure rubber powder product of 80 purposes (yield is about 85%, and pure rubber powder product is 102 parts).

Application prospect: the same with embodiment 1, the fine glue powder masterbatch that makes by present embodiment can substitute existing reclaimed rubber, fine glue powder, filler, is used for coatings industry, rubber and plastic industry, and has the good technical effect.

Embodiment 3.

Have the combination principle of chewing the powdery type auxiliary material in the reclaiming aid group of separating function, by the suitable cooperation of selecting materials, make gained powdery type auxiliary materials and mixing after, its pH is controlled in the scope with pH resiliency, and have the surface rockiness and crude property.

The utilization of being showed as embodiment 1 is to elastomeric regenerative operation process, and can obtain has powdery type auxiliary material in the reclaiming aid group of chewing the effect of separating to the macromolecule hydrocarbon chain, lifts 5 cooperation examples that meet the combinations thereof principle again, lists in table 2.

Find with microexamination by a large amount of experiments: the powdery type auxiliary material cooperates mixed mutually, after thing phase change such as the crystallization that is laminated with, is heated, dewaters, its surface all becomes crude hard, and PH is at 5～9 scopes and tool PH resiliency, and these two characteristics are the said characteristic features with the powdery type auxiliary material of chewing separating property of the present invention.

According to relevant bibliographical information in the industry: with can making the mixing materials deliquescing in this example described red (red) mud, the salt slurry adding plastics, thereby can save organic softening agent or plasticizer.But owing to contain a large amount of Mg (OH) in this class mud ₂, alkaline material (PH＞9) such as MgO, so no PH resiliency, those skilled in the art find it is added the problem that occurs three aspects in the rubber and plastic at least, the one, can influence vulcanizing system greatly, the 2nd, can and then influence sizing material viscosity with resin generation saponification such as rosin in the sizing compound formula, the 3rd, can quicken wearing out of rubber and plastic greatly.So the industrial slag charge of PH such as salt slurry＞9 does not see that also application is arranged in the occupation again at elastomer at present.The present invention rationally is mixed by and (weak) alkaline material acid with (weak), makes the PH of material fade to 5～9 scopes, and tool PH resiliency.In newly-generated not the dewatering between the clay or being mixed of itself and other dry material of aqueous phase, make the material microparticle surfaces all with various

Table 2

Material (butt parts by weight): example number	1#	2#	3#	4#	5#
						Potter's clay (PH5.0～5.5)	20	/	/	/	/
(aluminium manufacturer dumps) red (red) mud (PH＞11)	80	/	/	/	/
						(chlor-alkali plant dumps) salt slurry (PH＞11)	/	80	/	/	/
Colliery powder (PH7)	/	/	50	/	/
						Carbon black (PH7)	/	/	/	70	/
White carbon (PH7, dry powder)	/	/	/	/	30
						The silica composite gypsum (moisture 60%, PH5.5)	/	15	50	30	7
PH after the mixing of materials	＜9	＜9	＜7	＜7	＜7

The chemical composition of 7 kinds of listed materials and microparticle surfaces situation are listed in the table 3 in the table 2:

Table 3

Material	Chemical composition	Crystal formation	Surface condition
				Potter's clay	Al 2O 3·2SiO 2·2H 2O	Sheet	Smooth
(aluminium manufacturer dumps) red (red) mud	aCaO·bMgO·cNa 2O·dK 2O·eSiO 2 ·fAl 2O 3·gFe 2O 3·hTiO 2·nOH·mH 2O	Unordered	Hard crude
				(chlor-alkali plant dumps) salt slurry	aBaSO 4·bCaCO 3·cMg(OH) 2 ·dSiO 2·eAl 2O 3·fFe(OH) 3	Do not have	Hard crude
Colliery powder	C·SiO 2	Irregular	Smooth

Carbon black	C	Irregular	Crude softness
				White carbon (doing)	SiO 2·nH 2O	Irregular	Crude softness
The silica composite gypsum	CaSO 4·2H 2O·2SiO 2·nH 2O	Irregular	Hard crude

Be hard crude shape; The particulate that the surface is hard crude shape has good chewing to rubber-plastic and separates function, therefore can chew and separate the agent use, Chinese patent application: 03116373.4 has provided theoretical explanation model (be little file particulate chew separate model) to this, but Chinese patent application: 03116373.4 the starting point is at processing aid, so the having of its proposition chew separate function inorganic particles content between 50%～100% (not comprising 50%), and the starting point of the present invention is in the waste elastomer regeneration, and after taking all factors into consideration from economy reasonability and operability equal angles, propose in the rubber powder system, to have and chew the fraction of particle of separating function and should in 1%～30% scope, choose.

Embodiment 4.

The assembly principle of odorless softening agent class material: facts have proved the material that does not have absolute odorless in the world, if Chang Yong spices overrich for example, it also is a kind of smelly material, therefore how to guarantee that system has under the prerequisite of good softening function, reduce the consumption of softening agent, can yet be regarded as one subtracts smelly very wise move as far as possible.So, select the combination of an amount of material, it can be obtained reducing the consumption of softening agent under the well softening prerequisite satisfying the waste elastomer powder as far as possible, and do not make products obtained therefrom not only smelly and slightly have " fragrance " according to this principle.According to mentioned above principle, present embodiment provides 5 to cooperate example:

Example 1: 7 parts of cotton seed benevolence (oil-containing 39%), 3 parts of restaurant recovered oils, 2 parts of rosin, 2 parts of dimethylbenzene abietic resins;

Example 2: 7 parts of coconut benevolence (oil-containing 40%), 3 parts in machine oil, 1.5 parts of coumarones;

Example 3: 5.5 parts of rubber seed benevolence (oil-containing 50%), 3 parts in cotton seed oil, 2 parts in transformer oil, 3 parts of special octyl phenol urea formaldehydes;

3.5 parts of example 4: Cha Ziren (oil-containing 39%), 3.5 parts of trachycarpi,fructus benevolence, 3 parts of palm oils, 1 part of Foral, 1 part of the rare resin of terpene;

Example 5: contain grease and active carbon or/and 9 parts in the slag mud of carclazyte, 10 parts of chinaberry, 2 parts of zinc resinates.

Said part all by weight in the above-mentioned example.

Do not contain foul smelling materials such as coal tar, pine tar in the softening agent system assembly that the present invention proposes, thereby eliminated the disadvantage of prior art scheme generation stench; As, at system ash content≤10%, (plasticizing) glue (powder) material of acetone extract≤12%, and use again and have when chewing the filler of separating function, press pure oil in the softening agent system, fat, wax, ester, acid, alcohol, soap sum meter, compare with traditional use amount 8～12 parts/100 parts (in the tire glue powder weight), its consumption of softening agent system of the present invention can reduce four to sixty percent, be that consumption is: 3.2～7.2 parts/100 parts (in tire glue powder weight), the softening agent system that the present invention proposes has used the oil-containing benevolence of cheap oilseed plant, fruit is or/and the grease-contained adsorption bleaching slag mud class " waste material " that is produced in the operation of oil prodution industry decolorizing purification, so integrate comparison, property/this property/this ratio of the softening agent system that the present invention proposes than the softening agent system that will be higher than prior art.

Embodiment 5.

The desulfurization activation system matching principle of odorless: in the said waste elastomer renovation process of the present invention, the desulfurization activator that in the reclaiming aid group of using, contains a class odorless, wherein said desulfurization activator, can select one or more odorless desulfurizing agent material arbitrarily, but we find in practice: pass through preferred compositions, the odorless desulfurizing agent system that obtains, in the waste elastomer regeneration process, not only have splendid desulphurizing activated, and it and rubber powder effect are can not produce hydrogen sulfide or other has odour: odorless under the condition of pH5～12, under pH5～12 conditions, have splendid desulphurizing activated, this has just become the target of inventor's pursuit, promptly matches the principle of odorless desulfurizing agent system.

According to mentioned above principle, present embodiment provides 5 to cooperate example:

Example 1: 10 parts on the ferrous zinc of rosin acid, 20 parts in semi-hydrated gypsum powder;

Example 2: basic copper carbonate is or/and 5 parts of peacock stone flours, 10 parts of glucose, 2 parts in turkey red oil, 2 parts in paraffin, 10 parts in semi-hydrated gypsum powder, 10 parts of calcium sulfate composite silicon dioxides;

Example 3: 7 parts on ferrous sulfate zinc, 5 parts of calcium sulfate composite silicon dioxides;

Example 4: 5 parts of zinc powders, 1 part of coumarone, 3 parts in paraffin, 20 parts in semi-hydrated gypsum powder;

Example 5: 5 parts of zinc oxalates, 5 parts of cetyl methyl diethyl ammonium halides, 5 parts of di-o-tolyl guanidines, 2 parts in paraffin, 2 parts of rubber, 3 parts of desulfurization rubber.

Said part all by weight in the above-mentioned example.In a word, the desulfurization activator system that the present invention proposes all can be under pH5～12 conditions does with rubber powder that the time spent does not produce hydrogen sulfide or other has odour, and has splendid desulphurizing activated.

In addition, point out in passing that we are not limited to the traditional concept of prior art, think as CN1127271.A:

Zinc oxide must match with stearic acid and promoter and form desulfurization activator system; We match together and form in the desulfurization activator system proposing to contain stearic acid and promoter, can not need zinc oxide, and can keep desulphurizing activated dose of characteristic that should have of the said odorless of the present invention.

Embodiment 6.

Make up about antioxygen age resistor system: in reclaiming aid group of the present invention, can be selected from the said antioxygen age resistor class material one or more arbitrarily, if but carry out suitable combination, then not only can improve the characteristic of antioxygen age resistor effectively, but also can reduce the consumption of antioxygen age resistor, reduce the cost that regeneration is handled.

According to above-mentioned thinking, present embodiment provides 5 group examples:

Example 1:6-ethyoxyl-2,2,4-trimethyl-1,1 part of 2-dihyaroquinoline, 1 part of iron ammonium sulfate, 1 part of 2-mercapto benzimidazole;

Example 2: 1 part of iron ammonium sulfate, 1 part of 2-mercapto benzimidazole, 2,2,4-trimethyl-1,1 part of 2-dihyaroquinoline condensate;

Example 3:6-ethyoxyl-2,2,4-trimethyl-1,1 part of 2-dihyaroquinoline, 1 part of hydroquinones benzyl oxide;

Example 4:6-ethyoxyl-2,2,4-trimethyl-1,2 parts of 2-dihyaroquinolines, 1 part of iron ammonium sulfate;

Example 5: 1 part of iron ammonium sulfate, 2,2,4-trimethyl-1,1 part of 2-dihyaroquinoline condensate, 1 part of hydroquinones benzyl oxide.

Said part all by weight in the above-mentioned example.

The appropriate combination by above-mentioned more than one antioxygen age resistor is found in experiment, can obtain the anti-old effect of better antioxygen.

Embodiment 7.

The application example of a reclaiming aid group that is combined into by the desulfurization activator and the powdery type auxiliary material system of odorless

Prescription: (waste elastomer :) get 100 parts in granularity 20 order tire micelles and (independently reclaiming aid group :) by " Embodiment 5.1 part in the desulfurization activator of middle 5# number odorless, Embodiment 3. 40 parts of middle 5# powder auxiliary material (PH=7, proportion: 2.4, in butt) " constitute.(above material part all by weight)

Handle: above-mentioned material is mixed the back with mixing machine import in the vulcanized rubber normal temperature ultrafine crusher and pulverize, sieve, must be narrower than and equal 80 orders and be coarser than having of 100 order odorlesses and chew 25 parts of fine glue powder masterbatch separating function and pH shock-absorbing capacity; Must be narrower than and equal 100 orders, odorless, have the pH pooling feature and chew 115 parts of fine glue powder masterbatch separating function.Above-mentioned masterbatch can directly come into the market as product, also can further process.

Further processing:

Getting being narrower than of this example equals 80 orders and is coarser than 100 purpose fine glue powder masterbatch and places mixer again for 141 parts, and adding contains the compounding ingredient of being made up of " 10 parts in transformer oil; 1.5 parts of special octyl phenol urea formaldehydes " 1 again, start mixer, stir about after 8～10 minutes when temperature rises to 175 ℃ (sizing material plastifies), and then add the compounding ingredient 2 that is constituted by " 3 parts of silica composite gypsums (moisture 60%; PH5.5; the butt meter) ", so that material rapid cooling, continue simultaneously to stir 10～20 seconds (stirring evenly) but just discharging of back, thermal material is imported another mixer, add compounding ingredient 3 (its mixed pH=8～9 that constituted by " containing paper fibrous residue mud powder or/and 95 parts in the slag mud powder of ginkgo leaf fiber; leaf powder is or/and 100 parts of bamboo leaf powders; boron mud powder is or/and 50 parts in alkali mud powder " again, have the PH resiliency, proportion is less than 2.70) 245 parts.Treat that material mixes and be cooled to 40 ℃ of left and right sides dischargings thoroughly and can pack, the gained finished product is odorless, no airborne dust, contains the plasticizing fine glue powder masterbatch of the powder auxiliary material about 70% of lightweight (pH has the pH resiliency in 8～9 scopes).Owing to be added with leaf in this example or/and powder auxiliary material such as the leaf of bamboves, so the masterbatch product can contain the leaves of plants fragrance of a little.

Use: fine glue powder masterbatch that this is routine and plasticizing fine glue powder masterbatch can be used for rubber, mould industry, make different class, the product of rubber and plastic of different characteristics.

Embodiment 8.

One by odorless softening agent, odorless desulfurization activator and have a reclaiming aid group that the powdery type auxiliary material of chewing separating property forms

Application example

Prescription: (waste elastomer :) get 100 parts in granularity 20～30 purpose cross-ply micelles and (independently reclaiming aid group :) by " 10 parts of the 1# among the embodiment 4. number odorless softening agents; among 2 parts in desulfurization activator of the 3# among the embodiment 5. number odorless and the embodiment 3. 2# number chew 4 parts of separating property powder auxiliary material ", the regeneration of being formed helps 16 parts of group materials, and adding up to total amount is 116 parts (all in butt weight).Add an amount of water again, in case incipient scorch appears in material in processing procedure, said suitable quantity of water accounts for 5～10% degree of being with water content in total material.

Concrete processing method: will place dynamic digester to above-mentioned material, airtightly be warming up to 200 ℃, and stir insulation and operated 2.5～3.5 hours, cooling discharge, the cotton seed benevolence that can be observed this moment in the reclaiming aid group is also fuel-displaced by charing, and oil is absorbed by the waste elastomer rubber powder again, what emerge in the material is steam, and the smell of the little rubber of peculiar smell, identical when the viscosity of material and existing reclaimed rubber have just gone out jar, this goes out a jar material and is odorless plasticizing rubber powder material.Go out jar material by existing reclaimed rubber and equally handle and promptly use the mill kneading in blocks going out jar material, lead to into 0.18～0.30 millimeter book material roll film with the conche book and open then and cut off material, obtain plastifying the rubber powder rubber master batch with the odorless of the same formulation of existing reclaimed rubber.The sizing material rerum natura detects by national standard (GB/T13460-2003): density 1.18, Mooney viscosity 70, moisture 1.0%, acetone extract are 12%, ash 8%, breaking strength 8.52MPa, elongation at break 380%; The sizing material rerum natura is better than national standard (GB/T13460-2003) described tyre reclaim A2 level or the low reclaimed rubber level of polluting, and the plasticizing sizing material of this example is not smelly, its acetone extract only is 12%, ash 8% is all far below the low pollution reclaimed rubber grade acetone extract of stipulating among the GB/T13460-2003 no more than 20% and the standard of ash no more than 10%.

The odorless of getting this routine gained plastifies 110 parts of rubber powder masterbatch, places agitator tank, adds independent compounding ingredient again, and said independent compounding ingredient is meant the compounding ingredient product that forms by certain prescription,

In this example said independent compounding ingredient by " activated carbon powder or/and 5 parts in atlapulgite powder, iron hydroxide mud powder or/and 10 parts of land plasters, alkali mud powder or/and 30 parts of red mud powder, barium ground-slag or/and 10 parts of strontium ground-slags, talcum powder or/and 34 parts of brucite powders, dreg fibers powder or/and 145 parts in waste paper fibre powder, 50 parts of (rice hull ash gypsum silicic acid) multiple combination powders " form, independent compounding ingredient addition is 284 parts.Behind the mixing, there is the PH resiliency its pH=8～9, and proportion is less than 2.70.

Handle: carry out finished product packing with regard to discharging below 40 ℃ but the abundant stirring and evenly mixing of above-mentioned material etc. is chilled to, the gained finished product is odorless, no airborne dust, (pH is 8～9 to contain lightweight, and having a pH resiliency) powder auxiliary material is 72% plasticizing rubber powder masterbatch, then this plasticizing rubber powder masterbatch is passed through roller again or extrudes kneading, or handle through granulation again, can obtain containing the rubber master batch granule product of the plasticizing rubber powder of powder auxiliary material about 72%.

Use: the plasticizing rubber powder masterbatch of this routine gained or the alternative reclaimed rubber of plasticizing rubber powder rubber master batch grain, applying filler are in the rubber industry, and the rubber of acquisition odorless.

Embodiment 9.

An application example that contains the independent reclaiming aid group of desulfurization activator system

Prescription: get 25 parts of 3# natural gums by weight, waste elastomer: white salt solution bottle stopper granularity is 100 parts of 28～40 order rubber powders; Independent reclaiming aid group: by " 2 parts in the 5# among the embodiment 5. number odorless desulfurization activator, 0.5 part of stearic acid, 1 part of rosin, 2.5 parts of zinc carbonates, 0.9 part of N-cyclohexyl benzothiazole sulfonamide, the reclaiming aid of 1.5 parts of compositions of sulphur ", total amount is 8.4 parts.

Handle: place the mill kneading in blocks above-mentioned material, operating condition is: under the room temperature, and water cooling, logical 10 times of zero roll spacing book; The 150 degrees centigrade of sulfurations 5 minutes on vulcanizing press of gained film, gained sizing material rerum natura is: pull apart powerful 7.1 (MPa), percentage elongation 480%, shore hardness (A) 52 degree; And do not add the desulfurization activator on year-on-year basis to rerum natura in the same old way only be: pull apart powerful 2.58 (MPa), percentage elongation 180%, shore hardness (A) 58 degree.

Embodiment 10.

One by the odorless softening agent, odorless desulfurization activator, the application example of the reclaiming aid group that antioxygen age resistor system combines

Get the waste elastomer granularity and be 100 parts in 20～30 purpose cross-ply micelles and regeneration and help the group thing: by 3 parts in the desulfurization activator of the 1# odorless among the embodiment 5., 5 parts of 5# odorless softening agents among the embodiment 4., 10 parts of 1# odorless softening agents among the embodiment 4. and antioxidant A W1 part, composition total amount are that 19 parts regeneration helps group.

Handle: above-mentioned material is placed dynamic digester, airtightly be warming up to 200～220 degrees centigrade, stir insulation operation 2.5～3.5 hours, cooling discharge, the cotton seed benevolence that can be observed in the material this moment is fuel-displaced by charing, oil is also absorbed by rubber powder, what emerge in the material is steam, and the smell of the little rubber of peculiar smell, it is identical when the viscosity of material and existing reclaimed rubber have just gone out jar, go out the equally processing of jar material going out jar material by existing reclaimed rubber, in blocks with the mill kneading, lead to into 0.18～0.30 millimeter book material roll film with the conche book and open then and cut off material, obtain the same formulation with existing reclaimed rubber but not smelly plasticizing rubber powder rubber master batch, the sizing material rerum natura is better than the reclaimed rubber standard GB/standard tyre reclaim A1 of T13460-2003 institute grade standard.

Embodiment 11.

One by following odorless softening agent, the reclaiming aid group application example that odorless desulfurization activator and powdery type auxiliary material combine

Getting the waste elastomer granularity by weight is 100 parts in 20～30 purpose radial micelles; " by 7.5 parts of the 1# odorless softening agents among 3 parts in desulfurization activator of the 1# odorless among the embodiment 5. and the embodiment 4.; the silica composite gypsum (tool is chewed the powdery type auxiliary material of separating property, and is moisture 60%, PH5.5) 5 parts ", the reclaiming aid group of forming, total amount is 15.5 parts.

Concrete processing mode: above-mentioned material is placed dynamic digester, airtightly be warming up to 200～220 degrees centigrade, stir insulation operation 3～3.5 hours, the 100 degrees centigrade of dischargings of lowering the temperature, charing is fuel-displaced to can be observed cotton seed benevolence in the reclaiming aid group material of composition this moment, oil is absorbed by rubber powder, what emerge in the material is steam, its peculiar smell also is lower than the smell of new rubber, (will " poor " when the existing reclaimed rubber of the viscosity ratio of apparent material has just gone out jar, but after going out jar material and handling by existing reclaimed rubber is same, the Mooney point of glue is the same with existing reclaimed rubber, be that its " ML100 ℃/1+4 " value is no more than 80), in blocks with the mill kneading, leading to into 0.18～0.30 millimeter book material roll film with the conche book opens then and cuts off material, obtain odorless plasticizing rubber powder rubber master batch with the same formulation of existing reclaimed rubber, the sizing material rerum natura reaches reclaimed rubber (the tyre reclaim A3 grade standard of standard GB/T13460-2003), but quality is better than existing reclaimed rubber series products, detect according to a conventional method, its acetone extract only is 12% (far below the low level value " 20% " of polluting of GB), and ash is 7% (also far below the low level value " 10% " of polluting of GB).

Embodiment 12.

One by following odorless softening agent, the reclaiming aid group application example that odorless desulfurization activator and powdery type auxiliary material combine

Table 4

Detection sample prescription: detect the sample numbering:	1# (the existing prescription of using of certain Shoes Factory)	2#
			Natural rubber (3# smoked sheet)	100 parts	100 parts
Reclaimed rubber	170	/
			The present embodiment sizing material	/	282

Zinc oxide	5	5
			Stearic acid	3	3
Antioxidant D	1	1
			High wear-resistant carbon black	66	/
Potter's clay	38	/
			Coumarone indene resin	5	/
Machine oil	3	/
			Diphenylguanidine	1	1
Captax	1.7	1.7
			Altax	0.9	0.9
Sulphur	3.4	3.4
			Add up to	398	398
Beat glue time/dust from flying:	Long/very big	Short/very little
			The vulcanizate rerum natura:
Hot strength (MPa)	11.2	11.5
			Elongation at break (%)	430	425
Shao Er hardness (A)	64	65
			Setafter break (%)	30	25
Flex crack (ten thousand times)	11.5	11.5
			Akron abrasion (cm)	0.7	0.68

Get the reclaiming aid group of waste elastomer granularity by weight for being narrower than 40 100 parts of purpose radial rubber powders and forming by " 1.85 parts in the desulfurization activator of the 1# odorless among the embodiment 5., 6.8 parts of cotton seed benevolence (oil-containing 39%), 2 parts in machine oil; 3 parts of restaurant recovered oils; 3 parts of rosin, 40.7 parts of high wear-resistant carbon blacks, 11 parts in alkali mud (Sodium Carbonate Plant dumps; moisture 30%; PH＞9, in butt), 12 parts in potter's clay ", total amount is 80.35 parts, and above-mentioned solid content adds up to: 180.35 parts;

Concrete processing method: above-mentioned material is placed dynamic digester, add a spot of water before handling, the moisture content in the product of water yield grasp after making processing remains on below 2%, but can make the material incipient scorch not in the processing.Airtightly be warming up to 170～185 degrees centigrade, stir insulation operation 3～5 hours again, the fast cooling discharging, with screw rod machine or banbury or mill under cooling condition, agglomerating or the sheet of kneading, lead to into 0.30 millimeter book material roll film with the conche book, sever blanking then, obtain a kind of plasticizing fine glue powder rubber master batch that reclaiming aid is formed part that contains; Present embodiment is integrated into the processing technology of the dry workshop section of the oil expression workshop section that eats powder workshop section and grease industry of rubber industry and filler industry in the heating digester of vulcanized rubber and finishes in the lump, the sizing material of this routine gained: the waste elastomer rubber powder that contains plasticizing is not less than 55%, filer content is not less than 34.5%, and it is identical that the smell that sizing material discharges and virgin rubber discharge in process of production; Dust from flying is very little during the operation of this example; The reclaimed rubber that sizing material of this example and prior art are produced, when pressing similar prescription application respectively in the footwear industry, the rerum natura contrast of both vulcanized rubbers detects as table 4.

Embodiment 13.

One by following odorless softening agent, odorless desulfurization activator, the application example of the auxiliary agent of the dirt again group that anti-oxidant age resistor and powder wood auxiliary material are combined into

Get waste elastomer by weight: Embodiment 1. 125 parts of the fine glue powder masterbatch of prepared not sieving separating; And the independence regeneration that mountain " 27.8 parts of trachycarpi,fructus benevolence; active breeze mud (oily factory dumps; close solid content＞40%, in pure solid content) 27.8 parts of decolouring oil-containing, 27.8 parts of restaurant recovered oils; 52.7 parts of Petropols; 0.6 part of basic zinc carbonate, 2,2 '-di-2-ethylhexylphosphine oxide (4-methyl-6-tert butyl phenol) (abbreviation antioxidant 2246) 2.78 parts; 166 parts of high wear-resistant carbon blacks " is formed helps 305.48 parts of punishment groups, solid content total: 430.48 parts.Add a spot of water before handling, the moisture content in the product of water yield grasp after making processing remains on below 2%.

Concrete processing method: above-mentioned material is placed dynamic digester, airtightly be warming up to 170～185 degrees centigrade, stir insulation operation 3～10 minutes again, discharging behind the fast cooling then, use the screw rod machine again under water-cooled, air-cooled condition, kneading becomes non-dusting particulate material, is the dustless plasticizing fine glue powder rubber master batch of odorless; The sizing material of this routine gained: the waste elastomer rubber powder that contains plasticizing is not less than 23%, and filer content is not less than 45%, and what discharge in the smell that the gained sizing material discharges and the virgin rubber dirt product process is identical; Dust from flying is very little during the operation of this example; The reclaimed rubber that sizing material of this example and prior art are produced, when in the footwear industry, pressing similar prescription application respectively, the rerum natura contrast testing result such as the table 5 of both vulcanized rubbers.

Table 5

Detection sample prescription: detect the sample numbering:	1# (the existing prescription of using of certain Shoes Factory)	2#
			Natural rubber (3# smoked sheet)	72 parts	72 parts
Butadiene-styrene rubber	28	28
			Reclaimed rubber	40	/
The present embodiment sizing material	/	149
			Zinc oxide	4	4
Stearic acid	2.5	2.5
			Antioxidant D	1	1
High wear-resistant carbon black	60	/
			Calcium carbonate	18	/
Petropols	17	/
			Machine oil	14	/
Diphenylguanidine	1.7	1.7
			Captax	2	2
Altax	0.8	0.8
			Sulphur	2.2	2.2
Add up to	263.2	263.2
			Glue time/dust from flying is beaten in mill:	Long/very big	Short/very little

The vulcanizate rerum natura:
			Hot strength (MPa)	13.9	15.5
Elongation at break (%)	435	440
			Shao Er hardness (A)	66	66
Setafter break (%)	25	20
			Akron abrasion (cm)	0.46	0.40

Embodiment 14.

Getting the waste elastomer granularity by weight is 100 parts in the oblique rubber tire tire of 20～24 purposes micelle; With get 115 parts of the reclaiming aid groups formed by " 15 parts in white carbon clay (aqueous phase is newly-generated, and is moisture 80%, and PH=5～7 are in butt), 100 parts in zinc oxide (nanoscale) ", the PH of reclaiming aid group system is controlled at 5～7 scopes.Add up to total solid heavily to be 215 parts after the above-mentioned mixing of materials.

Concrete processing method 1: with above-mentioned material in confined conditions, with pulverizing in the mixing machine mixing back importing vulcanized rubber normal temperature ultrafine crusher; (in this process, because the auxiliary agent that adds is more and moisture, micelle can not reunited again after pulverizing, gained rubber powder material is easy to be ground into be narrower than and equals 80 orders; In addition, because the white carbon clay that adds equals 1000 purpose particulates for a kind of particle diameter that has hard crude surface and have a miniature file shape configuration is narrower than in this process, good interleaving agent when it is the vulcanized rubber pulverizing, be again that file cuts part hydrocarbon face and makes sizing material produce chewing of plasticity to separate agent, again owing to contain a large amount of zinc oxide in the auxiliary agent, so it is again a kind of vulcanizing activator of excellence, in addition, water in the auxiliary agent, can remove the heat in the crushing process effectively, crushing process is carried out constantly.) obtain being narrower than equal 80 purposes contain waste elastomer rubber powder 46.5% odorless and to elastomer have chew separate, 215 parts of the fine glue powder masterbatch (with Yu Jiji) of sulfurate activity function.

Get 215 parts of above-mentioned fine glue powder masterbatch; Add 6 parts of the compounding ingredients that constitute by " 5 parts in transformer oil, 1 part in the example 5 described desulfurization activators among the embodiment 5. " again; Add up to 221 parts;

Concrete processing method 2: place homogenizer to carry out the agitating heating plasticizing above-mentioned material, until 170～200 ℃, continue then to stir 3～5 minutes, the discharging cooling, promptly get the odorless that contains waste elastomer rubber powder 45.2% and elastomer had to chew and separate the plasticizing fine glue powder masterbatch of sulfurate activity function; As again this plasticizing fine glue powder masterbatch being placed banbury or mill or conche or extruder kneading, can obtain the waste elastomer rubber powder and have to chew at 45.2% odorless and to elastomer and separate the meticulous glue rubber master batch of the plasticizing of sulfurate activity function.This routine fine glue powder masterbatch, plasticizing fine glue powder masterbatch or rubber master batch, if be used for the vulcanized rubber article industry in downstream, 6.5～11 parts of adapteds in 100 parts of natural gums then, and before the workshop section that plasticates, add, just need not add commercially available zinc oxide and gas supplies again.

Desire to produce a kind of contain zinc oxide in 40～75% scope odorless and elastomer had to chew separate, the fine glue powder masterbatch of sulfurate activity function, plasticizing fine glue powder masterbatch or rubber master batch all can references The processing method that embodiment 14. provides realizes

Use: the odorless of this routine gained and elastomer had to chew separate, the fine glue powder masterbatch of sulfurate activity function, plasticizing fine glue powder masterbatch or rubber master batch, are chewed and are separated agent etc. and be applied to the rubber industry at alternative reclaimed rubber, zinc oxide.

Embodiment 15.

Get by weight waste elastomer comprise butyl curing bag capsule blob of viscose material (5～10cm) 50 parts, 50 parts of radial rubber powders (40～100 order), 5 parts in ethylene propylene diene rubber micelle (18～24 order), 5 parts in polyurethane micelle (10～18 order); With by " 3 parts of ferrous sulfate copper, 5 parts of the compound dihydrate gypsums of silica (moisture 40～60%, in butt), the nylon fiber that reclaims in the tire (1～10mm) 20～100 part " 28～108 parts of the reclaiming aid groups formed.

Processing method 1: pulverize importing in rubber fragmentation or the pulverizer after the above-mentioned mixing of materials, obtain particle mean size 138～218 parts of 24～100 purpose rubber powder mixed materials, this rubber powder material odorless contains waste elastomer 79.7%～46.2%; This material is further processed with compounding ingredient mixing post-processing approach 2 again.

Get 138 parts of the rubber powder materials that contains waste elastomer 79.7% of above-mentioned processing gained; 264 parts of the compounding ingredient things that adding is made up of " 100 parts in machine oil, 10 parts of dimethylbenzene modified rosins, 3 parts of glycerine, 150 parts of odorless bitumens, 1 part of antioxidant A W ".(above material all by weight)

Processing method 2: place airtight heating stirred tank to be heated to 200～220 ℃ of following desulfurization plasticizings above-mentioned material, stirring operation was handled about 2 hours, treat to emit cooling after the material fusion, can obtain a kind of waste elastomer 27.36% that contains, the toughness sizing material of desulfurization plasticizing.

Use: the sizing material of this routine gained has pressure-sensitive self-adhesion, anti-(oxygen) anti-characteristics of waiting for a long time, and can be used as good building water-proof material.

In addition, to broken, can produce conglomeration, in flakes waste elastomer sizing material when pulverizing as halogenated butyl rubber, natural emulsion, thermoplastic elastomer (TPE) etc., if desire to carry out fragmentation, pulverizing, all can according to Embodiment 1., Embodiment 2., embodiment 15. realizes; If when desiring to make the gained sizing material to make the unvulcanised colloidal state to use, then can according to Embodiment 15. shown in method process, and needn't limit the pH value of the powder auxiliary material that relates to.

Embodiment 16.

Prescription: getting the waste elastomer granularity by weight is 100 parts in 20 purpose radial micelles; Independent reclaiming aid group 1 by " Embodiment 5.Shown in 3.5 parts in the desulfurization activator of example 3,25 parts of carbon blacks, 0.1 part of Triton X-100 " 28.6 parts in the mixture formed, add entry by 10% of above-mentioned material total amount.

Handle: in confined conditions above-mentioned material, place airtight spice groove to mix earlier, import in the normal temperature abrasive disk type rubber fine pulverizer with auger conveyor then and pulverize, the gained material can both be crossed 100 mesh sieves more than 90%, again comminuting matter after 100 mesh sieves screenings, thick person leads back and regrinds, and the fines of crossing 100 mesh sieves imports in the airtight spice groove, can be used as product after the packing or does further processing as product.Further add man-hour,, add independent compounding ingredient again, 376 parts in the mixture that said compounding ingredient is made up of " 355 parts of carbon blacks, tall oil is or/and 10 parts of blackstrap, 11 parts in transformer oil " in 115 parts of the fineves of crossing 100 mesh sieves; Place airtight mixer together, mix back discharging packing thoroughly, promptly get the fine glue powder masterbatch of odorless, no airborne dust and tool reinforcement.Rubber powder content is 18.3% in this routine masterbatch, and auxiliary agent class mixture content is 81.7%.

Use: the fine glue powder masterbatch of this routine gained, alternative reclaimed rubber, fine glue powder, carbon black are applied to the rubber industry.

Embodiment 17

The application example of the compounding ingredient of forming with odorless softening agent and reinforcing agent class material

Prescription: get the waste elastomer granularity by weight and be narrower than and equal 90 parts of 120 purpose tire glue powders; With 10 parts of the compounding ingredients of forming by " 5 parts of low-molecular polyethylene waxs, 1 part of metasequoia resin, 1 part of special octyl phenol urea formaldehyde, 2 parts in transformer oil, 1 part of epoxy resin ", add up to 100 parts of total amounts.

Concrete processing method: earlier rubber powder is placed an agitator still, then add after the compounding ingredient material heating melting in the agitator still with the rubber powder stirring and evenly mixing after discharging, can obtain a kind of fine glue powder masterbatch that does not have flying upward property of dust soil.

The speed of need not seeking quickness in this example process stirs and is incubated or/and heating, also need not to require material is carried out essence, kneading, as long as can stir, even in room temperature～50 degree centigrade, the rerum natura of gained fine glue powder masterbatch also splendid (promptly being better than reclaimed rubber).Contain rubber powder 90% in this routine masterbatch, contain compounding ingredient material 10%.

Use: the fine glue powder masterbatch of this routine gained, alternative reclaimed rubber, fine glue powder, carbon black are applied to the rubber industry.

Embodiment 18

Prescription: get the waste elastomer granularity by weight and be narrower than and equal at the bottom of the assorted rubber overshoes of 100 orders 100 parts of sulfuration rim charge fine glue powders; With 55 parts of the compounding ingredients that is fine into by " 15 parts of bentonites; 15 parts in the emulsion clay (solid content 40%; water content 60%; in butt) that the polyvinyl butyral resin of phosphoric acid hydrogen calcium composite silicon dioxide or calcium sulfate composite silicon dioxide and nonionic surface active agent (as: AEO etc.) constitute; 15 parts in the sub-powder of chinaberry; 10 parts of low molecular polyethylenes (wax) ", adding up to the material total amount is 155 parts.

Concrete processing method: above-mentioned material is tentatively mixed in the spice groove earlier, being extruded into particle diameter with the screw rod machine under 120～150 ℃ then is 5 purpose particles, treat that particle cools off back (moisture air dry) naturally, promptly getting a kind of rerum natura can quite (compare in containing the suitable detection test piece of rubber powder amount) with tyre reclaim, but does not have the cheap and good-quality plasticizing fine glue powder rubber master batch of commercially available reclaimed rubber stench.

In the fine glue powder masterbatch of this routine gained, contain waste elastomer rubber powder 64.5%, contain reclaiming aid class material 35.5%.In addition, to gum content be lower than 25% or the lower assorted rubber overshoes of hot strength at the bottom of the recycling of waste elastomer of side crops class, all can conceive and realize with reference to the content shown in this example and the present invention.

Use: the plasticizing fine glue powder rubber master batch of this routine gained, alternative reclaimed rubber, filler etc. are applied to the rubber industry.

Embodiment 19.

Prescription: get the waste elastomer granularity by weight and be narrower than and equal in the 100 purpose automobiles 5 parts of the pure rubber powders of rubber mat; With by 95 parts of the compounding ingredients of " 10 parts in waste paper scrap powder; 10 parts in useless (fabric) fiber powder; 10 parts in useless nylon fiber powder; 10 parts in (power plant dumps) gypsum; (chemical plant such as sugar, oil, medicine, amino acid dump) decolouring inactivation active carbon is or/and 10 parts in atlapulgite slag mud mixture, 10 parts of wollastonite gypsum hydrated SiO 2 compound compositions, 10 parts of (pine) leaf powders; 5 parts in waste leather powder, 20 parts in transformer oil " composition; Add up to the material total amount to be: 100 parts.

Concrete processing method: place above-mentioned material the spice groove to mix, can obtain a kind of waste elastomer 5% (being the lower limit batch) that contains, do not have violent airborne dust again, ordorless and the fine glue powder masterbatch of the little perfume (or spice) of pine needle arranged.

Use: the fine glue powder masterbatch of this routine gained can replace common rubber filling to be applied to the product of rubber and plastic industry, and material feeding does not have advantages such as airborne dust soon when having lightweight, can improve sizing material hardness and tear strength significantly and refining glue.

Embodiment 20.

Get by weight the waste elastomer granularity be narrower than equal 100 purposes contain doughnut rubber fine rubber powder 90% with contain buckwheat shell or/and powdered rice hulls 10% mix 111 parts of comminuting matters; With 14 parts of the compounding ingredient things of being made up of " 10 parts in transformer oil, 3 parts of phenolic aldehyde (reinforcement) resins, 1 part of Te Xinji phenolic aldehyde (tackify) resin ", above-mentioned material adds up to 125 parts.

Concrete processing method: the first heat fused of above-mentioned compounding ingredient thing, and then pour in the spice groove and mix by prescription with waste elastomer, temperature during mixing can be no more than 50 ℃, mixing speed gets final product with 40～60 rev/mins, need not vigorous stirring, the back discharging that stirs, promptly obtain a kind of no airborne dust that contains waste elastomer 80%,, ordorless and buckwheat shell is arranged or/and the fine glue powder masterbatch of the little perfume (or spice) of rice husk.

Use: the fine glue powder masterbatch of this routine gained, can replace rubber and plastics batchings such as common reclaimed rubber, filler, softening agent to be applied to the product of rubber and plastic industry, material feeding does not have advantages such as airborne dust soon when having high-strength, lightweight and refining glue.

Embodiment 21.

Get by weight the waste elastomer granularity be narrower than equal 100 purposes contain doughnut rubber fine rubber powder 95% with contain buckwheat shell or/and powdered rice hulls 2.5% and wollastonite zinc silicate calcium sulfate silica compound composition 2.5% mix 105.3 parts of comminuting matters; With 10.5 parts of the compounding ingredients of forming by " 7 parts in transformer oil, 3.5 parts in phenolic resins "; Above-mentioned material adds up to: 115.8 parts.

Concrete processing method: with the first heat fused of above-mentioned compounding ingredient material, and then pour in the spice groove and mix with waste elastomer, temperature during mixing is no more than 50 ℃, mixing speed gets final product with 40～60 rev/mins, need not vigorous stirring, the back discharging that stirs promptly obtains a kind of waste elastomer 86.4%, no airborne dust, ordorless and buckwheat shell is arranged or/and the fine glue powder masterbatch of the little perfume (or spice) of rice husk of containing.This routine products obtained therefrom can keep former hot strength of abandoning elastomer about 80%, and the reclaimed rubber that prior art is produced only can keep former hot strength of abandoning elastomer about 40%～50%.

Use: the fine glue powder masterbatch of this routine gained, can replace rubber and plastics batchings such as new rubber, common reclaimed rubber, filler, softening agent to be applied to the product of rubber and plastic industry, material feeding does not have advantages such as airborne dust soon when having high-strength, lightweight and refining glue.

Embodiment 22.

Get by weight the waste elastomer granularity be narrower than equal 100 purposes contain vehicle glass rubber weather strip fine glue powder 95% with contain wollastonite zinc silicate calcium sulfate silica compound composition 5% mix 105.3 parts of comminuting matters; With 7.2 parts of the compounding ingredients of being made up of " 0.2 part on ferric oxalate zinc, 7 parts of paraffin oils ", above-mentioned material adds up to 112.5 parts.

Concrete processing method: above-mentioned compounding ingredient is mixed in the spice groove with waste elastomer, temperature during mixing should be controlled at 100～150 ℃, mixing speed is 900～1200 rev/mins, discharging after stirring promptly obtains a kind of plasticizing fine glue powder masterbatch that contains waste elastomer (ethylene-propylene diene copolymer) 88.9%, no airborne dust and stench.

Use: this routine gained (ethylene-propylene diene copolymer) fine glue powder masterbatch, can replace (ethylene-propylene diene copolymer) reclaimed rubber to be applied to the product of rubber and plastic industry, but material feeding does not have advantages such as airborne dust soon when having high-strength, easy extrusion froth breaking and refining glue.

Embodiment 23.

Prescription: get old 111 parts in the radial tyre micelle of abandoning of waste elastomer granularity 20 orders (carrying about 10% polyamide skeleton debris secretly) by weight; With by " Embodiment 5.Described in 3.5 parts in the desulfurization activator of example 3,5 parts in boron mud, 5 parts of (giving up) phenol-formaldehyde resin powders, 12 parts in waste paper scrap powder, 3 parts of wollastonite zinc silicate calcium sulfate silica compound compositions, 0.1 part of Triton X-100 " 28.6 parts of reclaiming aid groups; Add up to: 139.6 parts.

Concrete processing method 1: in confined conditions above-mentioned material, place airtight spice groove earlier and add entry by 8% of above-mentioned material, carry out stirring and evenly mixing, import in the normal temperature abrasive disk type rubber fine pulverizer with auger conveyor then and pulverize, (the gained material can both be crossed 100 mesh sieves 80% or more) again comminuting matter after 100 mesh sieves sieve, thick person leads back and regrinds, the fines of crossing 100 mesh sieves imports in another airtight spice groove, and further processing is in 111.7 parts of the fineves of crossing 100 mesh sieves;

Add: 365 parts of the compounding ingredients of being made up of " 70 parts in salt slurry powder; 170 parts of the fibre-bearing dregs of a decoction; decolouring inactivation active carbon is or/and 70 parts in atlapulgite slag mud; 34 parts of wollastonite calcium sulfate silica compound compositions; tall oil is or/and 10 parts of blackstrap, 11 parts in transformer oil ", above-mentioned material adds up to: 476.7 parts again.

Concrete processing method 2: mix above-mentioned material thoroughly back discharging packing together, promptly get the fine glue powder masterbatch of odorless, no airborne dust and tool filling, reinforcing function.Containing the rubber powder amount in this routine masterbatch product is 23.4%, and all the other are auxiliary agent class mixture.

Use: the fine glue powder masterbatch of this routine gained, alternative reclaimed rubber, fine glue powder, carbon black are applied to the rubber industry.

It is worthy of note, this example is not separated the nonmetal skeleton debris of carrying secretly in the waste elastomer into, also need not to separate, this is because the present invention has the inorganic matter micropowder (a kind of grinding aid with hard crude surface) of rigidity to exist when meticulous the pulverizing, so the skeleton debris can both be ground, flour after grinding can not influence the attractive in appearance of sizing material surface again to the sizing material reinforcement.

Embodiment 24.

Prescription: getting the waste elastomer granularity by weight is old 111 parts in the cross-ply micelles of abandoning of 5 orders (carrying about 10% polyamide skeleton debris secretly); With 28.6 parts of the reclaiming aid groups of forming by " 3.5 parts of the crushed materials of (zinc-manganese) refuse battery/potter's clay=1/5; 5 parts in boron mud, 5 parts of (giving up) phenol-formaldehyde resin powders, 12 parts in waste paper scrap powder; 3 parts of wollastonite zinc silicate calcium sulfate silica compound compositions, 0.1 part of Triton X-100 "; Above-mentioned material total amount adds up to 139.6 parts.Do not adding 10% water of above-mentioned material total amount.

Concrete processing method 1: in confined conditions with above-mentioned material, place airtight spice groove to mix earlier, import in the normal temperature abrasive disk type rubber fine pulverizer with auger conveyor then and carry out pulverization process, (the gained material can both be crossed 100 mesh sieves 80% or more) the material of pulverizing gained after 100 mesh sieves sieve, thick person leads back and regrinds, the fines of crossing 100 mesh sieves imports in the airtight spice groove, as product, and then packing listing, as intermediate product, then further processing again.

Further processing: 139.6 parts of fineves getting above-mentioned mistake 100 mesh sieves by weight, with the compounding ingredient of forming by " 70 parts in salt slurry powder; 170 parts of fibrous paper slags; decolouring inactivation active carbon is or/and 70 parts in atlapulgite slag mud; 34 parts of wollastonite calcium sulfate silica compound compositions, tall oil is or/and 10 parts of blackstrap, 11 parts in transformer oil " 365; Above-mentioned material total amount adds up to 504.6 parts.

Concrete processing method 2: above-mentioned material places airtight tank diameter, and discharging is packed after mixing thoroughly, promptly gets the fine glue powder masterbatch of odorless, no airborne dust and tool filling, reinforcing function.Contain rubber powder 19.8% in the masterbatch of this routine gained, contain reclaiming aid group and compounding ingredient mixture 80.2%.

Use: the fine glue powder masterbatch of this routine gained, alternative reclaimed rubber, fine glue powder, carbon black are applied to the rubber industry.

Point out in passing, this example is not separated the nonmetal skeleton debris of carrying secretly in the waste elastomer into yet, and the skeleton debris can be crossed 100 mesh sieves when being crushed to, flour after grinding can have good reinforcing action to rubber and plastic sizing material product, does not influence the attractive in appearance of sizing material product surface again.

Embodiment 25.

The effect of the reclaimed rubber that makes about the application example of product of the present invention and with prior art compares, and data are listed in the table below in 6.

According to the comparing result in the above-mentioned table 6, do a conclusive description: it seems except odorless and dust are little, to also have the advantage on the rerum natura.

Can understand from the comparison of present embodiment, rubber master batch provided by the invention or masterbatch product, itself all have under chamber～high temperature, do not distribute coal tar, pine tar, aromatic naphtha, pisselaeum arranged, rubber hydrocarbon wet goods nuisance smell, smog, do not have the advantage of airborne dust again; Single with upper limit batch and when adding powder system elastomeric compound again, refining glue and sulfidation China National Instruments Import ﹠ Export Corporation manifest ordorless characteristics, but when the bound batch is combined use (can add or not add powder less), the whole operation process just shows Utopian environmental protection characteristics ordorless and not airborne dust.

The present invention has been described by the above embodiments, but it should be noted that a bit, because " odorless " of the present invention index, though also there not be at present the standard of detection again in the occupation at elastomer, but technical staff in the field of business can both understand its connotation qualitatively, " odorless " detection to sizing material can be adopted people's nose and visual method

Table 6

Prescription: numbering:	Certain goods original formulation	New side 1	New side 2	New side 3	New side 4	New side 5	New side 6
								1# smoked sheet natural gum	100	100	100	100	100	100	100
Oblique tire reclaimed rubber (smelly)	50	/	/	/	/	/	/
								Example 11. (plasticizing rubber powder rubber master batch, odorless)	/	50	/	/	/	/	/
Example 8. (plasticizing rubber powder masterbatch, odorless)	/	/	35	30.11	7.92	10.1	/
								Example 8. (plasticizing sizing material 25/ filler 75, odorless)	/	/	/	/	/	80	76.32
Example 1. (fine glue powder 80/ filler 20, odorless)	/	/	/	/	/	/	13.79
								Example 16 (fine glue powder 20/ carbon black 75, odorless)	/	/	60	60	60	60	60
Example 14 (fine glue powder 45/ zinc oxide 45, odorless)	/	/	/	8.89	8.89	8.89	8.89
								Example 1 (fine glue powder 24.4/ filler 73, odorless)	/	/	/	/	82.19	/	/
High abrasion carbon black N330	45	45	/	/	/	/	/
								Precipitated calcium carbonate	60	60	60	60	/	/	/
Nano-class zinc oxide	4	4	4	/	/	/	/
								Stearic acid	3	3	3	3	3	3	3
Transformer oil	5	5	5	5	5	5	5

Rosin	5	5	5	5	5	5	5
								Age resistor Sp-c	1	1	1	1	1	1	1
Accelerant CZ	1	1	1	1	1	1	1
								Sulphur	3	3	3	3	3	3	3
Add up to (part):	277	277	277	277	277	277	277
								Smell when refining glue and sulfuration:	Greatly	Very little	Very little	Very little	Very little	Very little	Very little
Dust during the mill dnockout:	Greatly	Greatly	Slightly little	Slightly little	Very little	Very little	Very little
								Vulcameter detects: 145 ℃, and 20 fens T90 (m.m)	14.35	14.53	14.24	14.41	13.99	13.77	4.40
Min(dNm)	1.030	1.334	1.359	1.379	1.412	1.422	1.431
								Max(dNm)	7.914	9.601	9.963	9.669	9.718	9.640	10.07
Conditions of vulcanization (145 ℃/X branch):	14	15	14	15	14	14	14
								300% stretches (Mpa) surely	9.74	11.76	10.74	10.69	12.24	12.37	2.42
Hot strength (Mpa)	13.67	12.89	13.50	13.38	13.66	14.55	14.66
								Elongation at break (%)	397	376	388	386	350	352	366
Shao Er hardness (A)	68	68	70	70	72	70	70
								Anti-tear (KN/M)	56.4	56.8	56.9	55.8	55.5	58.5	57.6
Proportion:	1.285	1.285	1.290	1.292	1.253	1.234	1.255

Relatively the smell under room temperature or heating condition and the difference of smog size by sample and standard sample draw semiquantitative analysis conclusion; Also can adopt the gas chromatography method, under heating condition, more accurately detect by the vaporizer kind and the content of sample and standard sample.

Method of the present invention and product obviously can also have many variation examples, for example, powder auxilliary (filling out) material are carried out the process that surface treatment obtains active filler with known organosilicon etc., combine enforcement with crushing process; When waste elastomer is suppressed wetting agent that the filler powder flies upward and utilizes by double as, as long as the filler powder is not flown upward, the waste elastomer content in the material even can be low to moderate below 5%; That sifts out during meticulous pulverize plastifies with high temperature than coarse fodder, and then with sieve the meticulous material that sieves merge, make masterbatch or rubber master batch at last; From combination material scope provided by the invention, can be combined to form the good reclaiming aid group of more rerum naturas, and obtain waste elastomer that rerum natura is higher than reclaimed rubber, fine glue powder now in other words waste elastomer take the regeneration product of solid waste; As long as these variations are to meet design of the present invention and concrete technical scheme, these variations just should not be regarded as and exceed protection scope of the present invention so.Should also be noted that protection scope of the present invention comprises that also the regeneration that matches with the waste elastomer harmless treatment is with independent reclaiming aid group and complex.

In the masterbatch or rubber master batch product of plasticizing rubber powder provided by the invention or fine glue powder, be good with the masterbatch or the rubber master batch of fine glue powder, especially the masterbatch or the rubber master batch of the plasticizing fine glue powder that makes with the fine glue powder of using 100 mesh sieves are the best.

The rubber in downstream, mould the goods industry, use the masterbatch or the rubber master batch of plasticizing rubber powder provided by the invention or fine glue powder, by the combination of simple bound rubber master batch material, just can obtain and identical or close prescription of prescription of its original use.The gained sizing material is odorless not only, and can reduce or eliminate the dust pollution that materials such as zinc oxide, carbon black, calcium carbonate, potter's clay, fiber powder cause, from this point, the present invention keeps and expanded existing reclaimed rubber can be as the softening auxiliary agent advantages of application that promotes to eat powder.Gained sizing material of the present invention is good because of odorless and mechanical property, and this is many with regenerated elastic body materials in the odorless sizing compound formula of downstream product industry, provides possibility with new sizing material less.The wetting agent that the present invention is flown upward as inhibition filler powder with waste elastomer, can make and a kind ofly contain less waste elastomer and more powder filler rubber master batch material is a lower limit rubber master batch material of the present invention, thereby, found an approach that recycles for gel content waste elastomer low or the moral character difference is used further to the product of rubber and plastic industry.

Method provided by the invention has been abandoned the smelly shortcoming that has that has (black) reclaimed rubber now with use adsorbent in reclaiming aid group or the compounding ingredient with without measures such as the cacodorous softening agents of coal tar wet goods; The present invention solved well filler and softening agent property/this compares problem; The present invention has expanded the scope of selecting materials of desulfurization activator, and described desulfurization activator does not produce toxic gases such as cacodorous hydrogen sulfide when using; The present invention has solved the powder auxiliary material that adds when waste elastomer is pulverized well and contained that a large amount of reclaiming aids stays or the problem of removing after pulverizing; The present invention proposes the antioxygen age resistor and can be applicable to useless elastomeric regenerative process; Method provided by the invention is guaranteeing under waste elastomer regenerative process and the free of contamination prerequisite of product odorless, also be product when downstream application dustless refining glue and work simplification, the modification of filler product, and the approach that provides such as recycling such as the innoxious high value of the development and use of woodsization, mining product and rotten, of inferior quality oil-containing, confectionery and other industrial slag mud etc.; Auxiliary agent combination provided by the invention can break away from non-renewable materials such as coming from oil, coal fully.The present invention is specially adapted to the regeneration of thermo-setting elastomer.

Product of the present invention, (fillings) plasticizing rubber powder rubber master batch of cooperating of the upper limit wherein, with the formulation that shows the various reclaimed rubbers in city, activated rubber powder, glue kind, rubber hydrocarbon content the same terms under difference be:

With class reclaimed rubber and activated rubber powder comparisons such as the tire of natural gum, cis-butadiene cement, butadiene-styrene rubber system, assorted rubber overshoes, product of the present invention degree centigrade does not distribute coal tar, pine tar, aromatic naphtha in room temperature～180, pisselaeum is arranged, the smell of rubber hydrocarbon ils, only have a small amount of steam to emit in the process outward, the acetone extract of product is low and ash content is controlled; The dehydrate that can detect polycrystalline attitude compound composition in the product of the present invention is or/and oxide; Compare with halobutyl reclaimed rubber, neoprene reclaimed rubber, product of the present invention is few at 180～200 degrees centigrade of following smog, and the acetone extract is low and ash content is controlled; Compare with EPDM, butyronitrile reclaimed rubber, product of the present invention is few at 180～200 degrees centigrade of following smog, and the acetone extract is low, and ash content is controlled.

Because can detect polycrystalline attitude ash content thing and other powder material in the product of the present invention, though the ash content of product has improved, this helps regeneration handles, and also is of value to the application in downstream.

Invent described plasticizing masterbatch or rubber master batch product, during detection, rubber powder granule in its material swelling or plasticizing is clamminess, can't be after screen cloth to define its granularity order number, but can with can cross the mistake roller sizing material test piece that screen cloth defines the sticking thin rubber powder of its granularity and come its compactness of comparison, surface smoothness, and then know its rerum natura by inference.

Masterbatch provided by the invention or rubber master batch product also have the more social effect of deep layer except that remarkable economical value is arranged, that is exactly its nearly all solid refuse of capacity comprehensive utilization modern industrial society generation greatly! Examine masterbatch provided by the invention or rubber master batch product again closely from this angle, can see the product of its solid refuse cycling and reutilization joint of the many kinds of conglomerate that have been a kind of parallel connection.In this free of contamination product, waste elastomer is a kind of important medium that can make the multiple solid cyclic utilization of waste, and she is a scarce resource! A but not refuse! Masterbatch provided by the invention or rubber master batch product are the carriers that waste elastomer and multiple solid refuse etc. is transformed into innoxiously product of rubber and plastic industry raw material, be open waste elastomer and the solid refuse of conglomerate can resource, the recycling door of environmental protectionization, high value one golden key.

Claims (15)

1. regeneration method of waste elastic body, it is characterized in that: described regeneration method of waste elastic body comprises following two steps:

Step (1): be with granularity for be narrower than equal 20 orders to be coarser than 80 purpose waste elastomer particles and reclaiming aid group with dry weight basis in 100 parts: after 5.3～43 parts ratio is mixed, place rubber processing machinery, the harmless regeneration processing that comprises mixing, pulverizing, screening, heating and kneading, granulation is handled, obtain plastifying rubber powder masterbatch or rubber master batch, or obtain 95% above powder granularity and be narrower than and equal 80 purpose fine glue powder mixtures, cross 80 purpose materials and return circular treatment in the above-mentioned rubber processing machinery;

Step (2): be that product with step (1) gained places mixing machinery after the weighing respectively in proportion with compounding ingredient, by stirring or again after mediating mixing and handling, obtaining containing the plasticizing rubber powder or/and granularity is narrower than the masterbatch or the rubber master batch product of the rubber powder that equals 80 orders.

2. regeneration method of waste elastic body as claimed in claim 1, it is characterized in that: this method comprises that waste elastomer regeneration is processed into plasticity rubber powder or granularity to be narrower than and to equal 80 purpose elastomer fine glue powders, comprise that waste elastomer content is 95%～70% plasticizing rubber powder masterbatch or rubber master batch, or the production method of the masterbatch of fine glue powder or rubber master batch, comprise with waste elastomer content being that 95%～70% plasticity rubber powder or granularity are narrower than and equal 80 purpose fine glue powder masterbatch or rubber master batch and further be processed into waste elastomer content and be less than 70%～5% plasticizing sizing material or the masterbatch of fine glue powder or the production method of rubber master batch, and comprise that waste elastomer further is processed into granularity is narrower than the production method that equals the pure fine glue powder of 80 purposes.

3. regeneration method of waste elastic body as claimed in claim 1 is characterized in that:

The treatment process condition of step (1) comprising: with operating temperature is room temperature～240 ℃; Operating pressure is normal pressure～3.5MPa; By the pH value of reclaiming aid group material regulation and control material system, the pH value stabilization that makes material system is 5～12; Material ratio by weight percentage is: the waste elastomer particle accounts for 95%～70%, and the reclaiming aid group accounts for 5%～30%; Under above-mentioned process conditions, after the described regeneration processing of completing steps (1), obtain a class waste elastomer content and be 95%～70% plasticity rubber powder masterbatch, rubber master batch product or product, or the masterbatch of fine glue powder or rubber master batch product or product:

The treatment process condition of step (2) comprising: operating temperature is room temperature～80 ℃; Operating pressure is normal pressure～0.1MPa; The pH 5～9 of compounding ingredient system; Material ratio by weight: step (1) products therefrom accounts for 98%～5%; Compounding ingredient comprises that the reclaiming aid group material that comprises in step (1) products therefrom accounts for 2%～95% altogether; Under above-mentioned process conditions, process and handle that to obtain another kind of waste elastomer content be to be less than 70%～5% plasticizing rubber powder masterbatch or rubber master batch, or/and the rubber master batch of fine glue powder or masterbatch product.

4. regeneration method of waste elastic body as claimed in claim 1 is characterized in that:

Wherein said reclaiming aid group comprises in the following functional material one or more in the step (1); Said functional material comprises the softening agent class material of odorless, the desulfurization activator class material of odorless, and antioxygen age resistor class material has the powder auxiliary material of filling function or/and chew the powder auxiliary material of separating function, and friction resistant lubricant class material;

Said compounding ingredient in the step (2) wherein, its main component is that powder auxiliary material is or/and the softening agent class material of odorless, both sums account for 80～100% of compounding ingredient total amount, and according to downstream industry processing needs, add about 20～0% one or more the functional material account for the compounding ingredient total amount, said functional material is with said functional material in the reclaiming aid group.

5. as the described method of claim 1., it is characterized in that the reclaiming aid group described in the step (1) comprises following one or more auxiliary agent class material at least and forms, said auxiliary agent class material comprises:

(a.) the softening agent class material of odorless; (b) desulphurizing activated dose of class material of odorless; (c) antioxygen age resistor class material; (d) have lightweight and fill the powdery type auxiliary material of function or/and have and chew the powdery type auxiliary material of separating function; And (e) the lubricated class material of friction resistant;

Wherein the reclaiming aid group comprises that the reclaiming aid group of interim preparation is or/and the independent auxiliary agent category product through being processed in advance.Said reclaiming aid group is used by aforementioned material and is formed preparation recently or production in advance by following weight, and its component comprises following material:

Odorless softening agent class material: 0～30 part/100 parts, in waste elastomer rubber powder weight basis;

Odorless desulfurizing agent class material: 0～5 part/100 parts, in waste elastomer rubber powder weight basis;

Antioxygen age resistor class material: 0～5 part/100 parts, in waste elastomer rubber powder weight basis;

The powdery type auxiliary material: 0～30 part/100 parts, in waste elastomer rubber powder weight basis;

And lubricated anti-friction liniment class material: 0～0.5 part/100 parts, in waste elastomer rubber powder weight basis; The initial amount of all kinds of materials can not be zero simultaneously, and the adding cooperation of all kinds of material sums is: 5.3～43 parts/100 parts, and in waste elastomer rubber powder weight basis.

6. method as claimed in claim 5, it is characterized in that: the softening agent class material of said (a.) odorless comprises following one or more material at least, also comprise by more than one materials and cooperate the softening agent group of forming, the consumption of odorless softening agent accounts for 0～21% of said product of step (1) or product population, said softening agent class material comprises: (1) oil plant benevolence, fruit material, (2) vegetable oil, resin and derivative class material, (3) contain grease decolouring slag mud class material, and (4) elastomer softening agent commonly used; Wherein,

(1) oil plant benevolence, fruit material, comprise: tung oil tree benevolence, olive benevolence, coconut benevolence, cotton seed benevolence, vegetable seeds, shelled peanut, soybean, trachycarpi,fructus benevolence, kardiseed, sunflower seeds kernel, Cha Ziren, linseed, perillaseed benevolence, rubber seed benevolence, olive meat, Chinese tallowtree seed benevolence, shiny-leaved yellowhorn benevolence, ansu apricot benevolence, hair Lai, fibert, Chinese pistache, chinaberry, walnut kernel, the sub-benevolence of elaeagnus mollis, immature pine nut;

(2) vegetable oil, resin and derivative class material comprise: maize germ oil, rice bran oil, cotton seed oil, rape seed oil, peanut oil, soybean oil, palm oil, sunflower oil, olive oil, tea-seed oil, coconut benevolence oil, tung oil, Linseed oil, Chinese tallowtree seed benevolence oil, perilla oil, restaurant recovered oil, rosin, tall oil, turkey red oil, Foral, dehydrogenated rosin, ester gum, pentalyn, dimethylbenzene abietic resin, rosin ester, pine tree resin, metasequoia resin, elm resin, peach resin, useless peanut paste;

(3) contain grease decolouring slag mud class material, comprising: the grease-contained active carbon that decolorizing purification workshop section of grease factory dumps or the slag mud of carclazyte;

(4) elastomer softening agent commonly used comprises: lubricating oil, machine oil, white oil, halogenated paraffin oil, paraffin oil, third fractional oil, six line oil, transformer oil, polybutene oil, C _4～18Aliphatic acid, vaseline, halogenated paraffin, paraffin, beeswax, animal oil, dark substitute, white factice, odorless bitumen, epoxidized soybean oil, alkyl phenolic resin, the rare resin of terpene, the rare phenolic resins of terpene, Petropols, special octyl phenol urea formaldehyde, coumarone, styrene resin, polyvinyl acetal resin, zinc resinate, low molecular polyethylene (wax), low-molecular polypropylene wax, stearic acid, palmitic acid, oleic acid, palmitic acid, polyvinyl alcohol, amylalcohol, hexanol, enanthol, octanol, decyl alcohol, lauryl alcohol, tetradecyl alchohol, hexadecanol, 18 alcohol, cyclopentanol, cyclohexanol, phenmethylol, ethylene glycol, propane diols, glycerine, 2-Ethylhexyl Alcohol, sec-n-octyl alcohol, laruyl alcohol, terpinol, C _7～18Mixed fatty alcohol, pentaerythrite, xylitol, dipropylene glycol, dioctyl phthalate, dibutyl phthalate, diisobutyl phthalate, dialphanyl phthalate, tributyl phosphate, triethyl phosphate, triphenyl phosphate, tricresyl phosphate, di(2-ethylhexyl)phosphate phenyl-2-Octyl Nitrite, the terephthalic acid (TPA) dibutyl ester, the adipic acid dibutyl ester, adipic acid two-2-ethylhexyl, decanedioic acid two-2-ethylhexyl, barium stearate, calcium stearate, strontium stearate, dolomol, aliphatic acid barium, fatty acid magnesium, fatty acid calcium, the aliphatic acid strontium, barium laurate, calcium laurate, castor oil acid barium, castor oil acid calcium, zinc ricinate, barium naphthanate, calcium naphthenate, thermoplastic elastomer (TPE), reinforced resin, resin emulsion, rubber latex.

7. method as claimed in claim 5, it is characterized in that: said (b.) odorless desulfurization activator class material comprises at least and is selected from the following A group material one or more, and/or be selected from the following B group material one or more, and/or be selected from the following C group material one or more; Above-mentioned said odorless desulfurization activator class material is mixed by following weight ratio and forms,

A group/B group/C group=100～2%/0～98%/0～98%, in waste elastomer rubber powder weight basis, its consumption with: 0.1～5 part/100 parts is good;

Wherein said A group material, comprise: potassium ferric oxalate, ferrous oxalate, ferric oxalate, zinc stannate, calcium oxalate, calper calcium peroxide, hydrogen peroxide calcium sulfate adduct, hydrogen peroxide sodium sulphate, hydrogen peroxide copper sulphate, zinc oxalate, ferrous oxalate zinc, bodied ferric sulfate, sodium thiosulfate, sodium sulfite, sodium hydrogensulfite, ferrous sulfate zinc, alkali formula iron chloride, frerrous chloride, cerium hydroxide, cerous phosphate, ferric subsulfate, ferrous sulfate copper, zinc chloride, zinc silicate, zinc carbonate, basic zinc carbonate, trbasic zinc phosphate, basic zinc sulfate, zinc hydroxide, phosphoric acid hydrogen is ferrous, phosphoric acid one hydrogen zinc, the ferrous zinc of phosphoric acid hydrogen, the ferrous copper of phosphoric acid hydrogen, zinc sulfate, copper sulphate, Kocide SD, cupric phosphate, nickel hydroxide, nickelous carbonate, cobaltous sulfate, the ferrous zinc of rosin acid, rosin acid is ferrous, zinc abietate, the rosin acid cobalt, zinc naphthenate, cobalt naphthenate, the aliphatic acid cobalt, fatty acid zinc, zinc stearate, zinc gluconate, ferrous gluconate zinc, zinc laurate, zinc palmitate, calcium gluconae, glucose, blackstrap, basic copper carbonate, the peacock stone flour, zinc powder, aluminium powder, the aluminium foil bits, the nanoscale copper powder, nano grade iron powder, cupric oxide powder, leaded waste plastics, contain the cadmium waste plastics, contain chromium scrap leather bits, contain chromium shark bone glue, the refuse battery crushed material, metatitanic acid, the ethylenediamine tetrem is ferrous, ascorbic acid, Magnesium ascorbate, the tetramethyl ammonium halide, cetyl ethyl dimethyl ammonium halide, cetyl methyl diethyl ammonium halide, monobutyl dimethyl benzyl ammonium halide, the octadecyl ammonium halide, 3,5-dimethylphenyl benzyl ammonium halide, the dimethyl diphenyl ammonium halide, Methylethyl propyl group isobutyl group ammonium halide, the myristyl trimethyl-ammonium halide, myristyl dimethyl ammonium halide, cetyl dimethyl benzyl ammonium halide, cetyl halogenation pyridine, myristyl halogenation pyridine, dodecyl halogenation pyridine, tetrabutyl halogenation pyridine, ethyl dixylyl ammonium halide, oil base dimethyl benzyl ammonium halide, cetyl ethyl dimethyl ammonium halide, 2-thiol benzothiazole zinc, benzene a pair of horses going side by side thiazolyl disulphide, N-cyclohexyl-2-benzene a pair of horses going side by side thiazole sulfenamide, the N-tert-butyl group-2-benzene a pair of horses going side by side thiazole sulfenamide, PZ, zinc diethyl dithiocarbamate, the dipropyl zinc dithiocarbamate, zinc dibutyl dithiocarbamate, zinc dibenzyl dithiocarbamate, blue female disulphide of tetraethyl autumn, blue female disulphide of tetramethyl autumn, blue female disulphide of tetrabenzyl autumn, N, N '-diphenylguanidine, di-o-tolyl guanidine, 4,4 '-dithiomorpholine, zinc dibutyl dithiophosphate;

B organizes material, comprising: rosin, Foral, dimethylbenzene abietic resin, special octyl phenol urea formaldehyde, coumarone, turkey red oil, cotton seed oil, rape seed oil, peanut oil, soybean oil, palm oil, sunflower oil, olive oil, tea-seed oil, paraffin, stearic acid, beeswax, rubber, desulfurization plasticizing rubber powder, thermoplastic elastomer (TPE);

C organizes material, comprising: semi-hydrated gypsum powder, potter's clay powder, calcium sulfate dioxide composite Si powder.

8. method as claimed in claim 5 is characterized in that said (c.) antioxygen age resistor class material comprises at least to be selected from the following material one or more that its consumption is 0～5 part/100 parts (waste elastomer rubber powder weight basis meters); Said antioxygen age resistor class material comprises:

3 hydroxybutyraldehydes-2-naphthylamines (being called for short antioxidant A H), 3 hydroxybutyraldehydes-2-naphthylamines (being called for short antioxidant A P), 6-ethyoxyl-2,2,4-trimethyl-1,2-dihyaroquinoline (being called for short antioxidant A W), acetone and diphenylamines pyroreaction thing (abbreviation antioxidant BLE), N-phenyl-B-naphthylamines (abbreviation antioxidant D), 2,6-di-tert-butyl-4-methy phenol (abbreviation antioxidant 264), the mixture of one hydrocarbonylation bis-phenol (being called for short age resistor 651), N-cyclohexyl-p-ethoxyaniline (being called for short age resistor CEA), N-cyclohexyl-P-nethoxyaniline (being called for short age resistor CMA), hydroquinones benzyl oxide (being called for short antioxidant MB A), 2,2 '-di-2-ethylhexylphosphine oxide (4-methyl-6-tert butyl phenol) (abbreviation antioxidant 2246), 2,2,4-trimethyl-1,2-dihyaroquinoline condensate (abbreviation anti-aging agent RD), N-phenyl-N '-cyclohexyl p-phenylenediamine (PPD) (being called for short antioxidant 4010 or CPPD), N-phenyl-N '-isopropyl-p-phenylenediamine (PPD) (being called for short antioxidant 4010NA or IPPD), N, N '-diphenyl-p-phenylenediamine (PPD) (being called for short antioxidant H or DPPD or PPD), 2-mercapto benzimidazole (abbreviation antioxidant MB), dilauryl thiodipropionate (abbreviation anti-oxidant DLTP), phosphorous acid benzene di-isooctyl, phosphorous acid bisphenol-A ester, hydrazine sulfate, titanyl sulfate, ferrous sulfate, frerrous chloride, iron ammonium sulfate, hydroxylamine hydrochloride, triisopropanolamine, oxalic acid.

9. method as claimed in claim 5, it is characterized in that said (d.) has lightweight and fill the powdery type auxiliary material of function or/and have and chew the powdery type auxiliary material of separating function and comprise at least that granularity is narrower than and equal in the following material of 200 purposes one or more, also comprise the polycrystalline attitude compound composition that forms and form by the thing phase change at aqueous phase by one or more material assembly; Said powdery type auxiliary material comprises: (1) has the powder class powder of peculiar smell adsorptivity, (2) industrial slag great soil group powder, (3) vegeto-animal bone, leaf, root, straw, bar, shell, skin break flour class powder, (4) inorganic mineral class powder, (5) elastomer reinforcement filler class powder commonly used, (6) the calcining rear surface is the particulate class material of crude hard shape, (7) polycrystalline attitude compound composition class material, and (8) one classes are not subjected to the particulate material of fineness restriction; Wherein said:

(1) has the powder class powder of peculiar smell adsorptivity, comprising: active carbon, atlapulgite, attapulgite, diatomite, bentonite;

(2) industrial slag great soil group powder, comprise: chimney soot, steel-making slag powder, the red mud that aluminium manufacturer dumps, the aluminium ash that aluminium manufacturer dumps, the alkali mud that Sodium Carbonate Plant dumps, the salt slurry that chlor-alkali plant dumps, Citric Acid Plant, lactic acid factory, titanium powder plant, phosphoric acid factory, the gypsum that power plant dumps, the gypsum iron hydroxide mixing slag mud that steel mill dumps, the slag mud that contains the ginkgo leaf fibre that bilobanone factory dumps, the fibre-bearing dregs of a decoction that the pharmaceutical factory of traditional Chinese medicine dumps, the fibre-bearing slag mud that artificial liner enterprise dumps, pectin factory, tea processing factory, the fibre-bearing slag mud that the paper mill dumps, sugar, oil, medicine, the decolouring inactivation active carbon that chemical plant such as amino acid dump is or/and atlapulgite slag mud, the sugarcane that sugar refinery dumps, STEVIA REBAUDIANA, the mine tailings mud that the fibrous residue of beet, mining industry dump, the iron hydroxide mud that the chemical plant dumps, the burning slag that sulfuric acid plant dumps, the assorted pigment slag mud that pigment factory dumps, the black slag mud that the carbon black plant dumps, assorted cullet, assorted waste ceramic, brick bits powder, the boron mud that boron saltworks dumps, the barium slag that barium salt factory dumps, the strontium slag that strontium saltworks dumps, the zinc gray that zinc-plated factory dumps, the gangue that the colliery dumps, slag ash, useless phenol-formaldehyde resin powder, the waste paper scrap powder, useless fabric fibre powder, river course mud;

(3) vegeto-animal bone, leaf, root, straw, bar, shell, skin break flour class powder, comprise: rice hull ash, powdered rice hulls, straw ashes, straw powder, shell powder, peanut hull meal, cork powder, wood powder, charcoal powder, leaf powder, bamboo leaf powder, withered grass powder, bark powder, oyster shell whiting, bone meal, waste leather powder, coconut palm cot powder, coconut palm palm fibre wood wool powder, bamboo powder;

(4) inorganic mineral class powder comprises: chrysotile-asbestos, crocidolite, actinolite-asbestos, amosite, crocidllite, the white tremolite-asbestos, aluminite, alunogen, base aluminite, iron alum stone, natroalunite, pickeringite stone, bauxite, diaspore, the allophane trolleite, zirlite, augelite, celestine, barite, calcined kaolin, Emathlite, bentonite, potter's clay, attapulgite, earth, serpentine, kolskite, magnesia cerolite, the magnesia cerolite of nickel, hampdenite, cerolite, talcum, attapulgite, clinoenstatite, enstatite, forsterite, enstatite, hydrotalcite, foliated talc, cordierite, palygorskite, diopside, monticellite, manganolite, chloropal, allophane, schroetterite, lineae ablicantes stone, yellow kaolin, saponite, spadaite, silico-calcium sodium stone, baryta feldspar, baryta fledspar, anorthite, carnegieite, hydroserpentine, hedenbergite, achmatite achmite, jurupaite, the zinc scapolite, rumpfite, kaliophilite, the buttress shaft nepheline, sodalite, hauynite, noselite, the pyrope garnet, iron aluminium garnet, the brownmillerite garnet, chrysolite, fayalite, willemite, fiber copper silicon ore deposit, meionite, marialite, sarcolite, scapolite, gehetinite, sillimanite, melilite, clinozoisite, lawsonite, sial calcium magnesite, dumortierite, staurolite, kornerupine, okenite, silicoglaserite, gyrolite, the monocline silicoglaserite, riversideite, beryl, fish-eye stone, modenite, brewsterite, the stripping zeolite, the barium staurolite, phillipsite, oblique analcime, the oblique zeolite of sodium, the oblique zeolite of calcium, sodalite, karphostilibite, the porcelain laubanite, light thin zeolite, erionite, single zeolite, zoisite, thaumasite, wollastonite, okenite, Hydrogrossular, hibschite, heulandite, analcime, scolecite, foresite, antiedrite, desmine, laumontite, zeolite, aksaite, boromagnesite, carbon boron-calcium-magnesium stone, calciborite, datolite, pinnoite, Ke's hydrotalcite, the tremolite, hypersthene, the iron sepiolite, lazulite, vermiculite, bronzite, chlorite, nephrite, sepiolite, the iron magnesium amphibole, breunnerite, pictoamesite, vesuvian, actinolite, fine magnesite, shepardite, anhydrous carnallite, Dou chlorite, dolomite, ankerite, gypsum, calcium phosphate, calcite, cancrinite, brushite, prehnite, aspidelite, zoisite, allochite, callainite, galapectite, andalusite, pyrophyllite, the iron galapectite, illite, chamosite, feldspar, Juanyingshi, montmorillonite, albite, orthoclase, ararantite, the monocline natrojarosite, delvauxite, ilmenite, monheimite, zinc～botryogen, carbon sodium silicoglaserite, zincocopiapite, sauconite, smithsonite, marionite, aurichalcite, chessy copper, warringtonite, chrysocolla, oblique side's malachite, dioptase, cerine, rinkolite, nepouite, chlorite rises, the phosphorus-aluminium-strontium alum, perlite, the foam powder, opal, diatomite, muscovite, biotite, phlogopite, calcium aluminate, the iron calcium aluminate, coal dust;

(5) elastomer reinforcement filler class powder commonly used comprises: carbon black, calcium carbonate, white carbon, lithopone, silica flour, talcum powder, diaspore powder, brucite powder, aluminium hydroxide, alumina silicate, magnesium silicate, basic magnesium carbonate, magnesium carbonate, magnesium hydroxide, magnesia, zinc carbonate, zinc silicate, zinc oxide, zinc hydroxide, the Juanyingshi powder, mica powder, feldspar powder, dolomite dust, agstone, kaolin powder, potter's clay, coal dust, gypsum, vermiculite power, strontium sulfate, barium sulfate, wollastonite in powder, short fiber, the charcoal fiber, calcium monohydrogen phosphate, calcium phosphate, calcirm-fluoride, strontium fluoride, barium fluoride, magnesium fluoride, magnesium monohydrogen phosphate, silicic acid, calcium silicates, strontium silicate, barium silicate, cement, strontium carbonate, brium carbonate, Si-Al molecular sieve;

(6) the calcining rear surface is the particulate class material of crude hard shape, comprising: calcined kaolin powder, calcinated argil, calcined diatomite, flyash, calcining attapulgite, calcining bentonite, cenosphere powder;

(7) polycrystalline attitude compound composition class material comprises a class material that is combined again at aqueous phase by above-mentioned auxiliary material:

Its general formula is: [∑ a _iD _i∑ b _iE _iZH ₂O], the ∑ a in the formula _i, ∑ b _i, Z, be the mole indeterminate coefficient, the expansion of general formula is:

[a ₁D ₁·a ₂D ₂……a _nD _n·b ₁E ₁·b ₂E ₂……b _mE _m·ZH ₂O]

Or [∑ a _i(D ₁, D ₂D _n) ∑ b _i(E ₁, E ₂E _m) ZH ₂O],

D in the general formula ₁, D ₂D _nBe one or more the material in aforementioned powder auxilliary (filling out) material, the E in the general formula ₁, E ₂E _mBe following one or more listed compounds newly-generated in water, comprise:

Calcium sulfate, calcium monohydrogen phosphate, calcium phosphate, calcirm-fluoride, strontium fluoride, barium fluoride, magnesium fluoride, magnesium hydroxide, magnesium carbonate, magnesium monohydrogen phosphate, silicic acid, magnesium silicate, calcium silicates, strontium silicate, barium silicate, alumina silicate, zinc silicate, zinc carbonate, basic zinc carbonate, trbasic zinc phosphate, basic zinc sulfate, zinc sulphide, zinc hydroxide, aluminium hydroxide, iron hydroxide, alkali formula iron chloride, ferric subsulfate, strontium sulfate, barium sulfate, metatitanic acid, (without what calcine) lithopone, boric acid, metaboric acid, sodium tetraborate, Firebrake ZB, barium metaphosphate, aluminium borate, calcium citrate, calcium lactate, barba hispanica;

(8) the particulate species filler that not limited by fineness comprises: the old thermoplastic elastomer (TPE) of abandoning, waste plastics;

These above-mentioned materials need not painstakingly to dehydrate in advance, but the PH after the material combination must be controlled at can be in 5～12 scopes, the material after the combination should have PH resiliency person, its proportion is smaller or equal to 2.7; Powder auxiliary material consumption in the reclaiming aid group accounts for 5～100% by weight.

10. method as claimed in claim 5 is characterized in that: said (e.) friction resistant lubricant class material comprises one or more of following listed material at least; Said friction resistant lubricant class material comprises: (1) cationic surface active agent, (2) anionic surfactant, (3) nonionic surface active agent, (4) amphoteric surfactant, (5) silicone based material, and (6) come from the surfactant of plant fully; The consumption of above-mentioned friction resistant lubricant in " step (1) " accounts for 0.2～5% of the free water amount in the material handling of being reproduced by weight; Wherein said:

(1) cationic surface active agent comprises: basic dimethyl benzyl ammonium chloride, dodecyl benzyl dimethyl ammonium chloride, triethanolamine list olein, alkyl phosphate diethanol ammonium salt, octadecyl dimethyl ethoxy season ammonium salt, trihydroxyethyl quaternary ammonium Methylsulfate;

(2) anionic surfactant, comprise: change rosin, saponification shellac, stearic saponified, fatty is saponified, aerosol-OT salt, 1,2-dibutyl naphthalene-6-sodium sulfonate, oleic acid normal-butyl sulfuric ester sodium salt, ricinoleic acid butyl sulfuric ester two (or three) ethanolamine salt, N-oleoyl N-methyltaurine sodium, sodium lauryl sulfate, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, sodium alkyl sulfonate, sodium alkyl benzene sulfonate, the polyoxyethylene alkyl ether sulfate sodium salt, the benzyl naphthalene sodium sulfonate, turkey red oil, the dinaphthyl methane sodium disulfonate, dispersing agent MF, the condensation product of benzyl naphthalene sodium sulfonate and formaldehyde, potassium alkyl phosphate, the lauryl alcohol phosphate kalium salt, soap;

(3) nonionic surface active agent comprises: the AEO of the ethylene oxide condensate of 7～C9 straight chain fat, coconut oil alkyl oxalamide, AEO, C12～C18, dodecyl phenol polyethenoxy ether, octane phenol APEO--10, polyethylene castor oil, sorbitan oleic acid polyoxyethylene, sorbitan stearate, sorbitan monooleate, sorbitan stearate APEO, polypropylene glycol and ethylene oxide adduct, coconut Brij, Triton X-100;

(4) amphoteric surfactant,, comprising: N-dodecyl alanine, empgen BB;

(5) silicone based material comprises: methyl-silicone oil, ethyl silicon oil, methyl phenyl silicone oil, two-[3-triethoxysilane propyl group] tetrasulfide, r-sulfydryl propyl trimethoxy silicane, dimethyldimethoxysil,ne, MTMS, methyl triacetoxysilane, MTES, tetramethoxy-silicane, tetraethoxysilane, dimethyldiethoxysilane;

(6) come from the surfactant of plant fully, comprising: the water extraction of shrubalthea leaf, the water extraction of Chinese honey locust, the water extraction that will is far away, the water extraction of balloonflower root, the water extraction of sea-tangle.

11. the method for claim 1,, be characterised in that: the powder auxiliary material that relates in the said compounding ingredient in the step (2) is that a class has the powdery type auxiliary material that lightweight is filled function, comprises one or more of following listed material at least:

Powder with adsorptivity, industrial slag great soil group powder, vegeto-animal bone, leaf, root, straw, bar, shell, skin break flour class powder, inorganic mineral class powder, elastomer is used reinforcement filler class powder always;

Above-mentioned said powder specifically comprises with (1) in the claim 9, (2), (3), (4), (5), (6) listed material.

12. the method for claim 1, it is characterized in that: by the said processing method of step (1), obtaining a class, to contain the rubber powder amount be 70%～95% the plasticizing rubber powder or the masterbatch or the rubber master batch product of fine glue powder, said product comprises that granularity equals to be narrower than 80 orders but is coarser than 100 purpose products, granularity equals to be narrower than 100 orders but is coarser than 120 purpose products, granularity equals to be narrower than 120 orders but is coarser than 140 purpose products, granularity equals to be narrower than 140 orders but is coarser than 160 purpose products, granularity equals to be narrower than 160 orders but is coarser than 180 purpose products, granularity equals to be narrower than 180 orders but is coarser than 200 purpose products, and granularity is narrower than 200 purpose products.

13. the method for claim 1, it is characterized in that: with the product of step (1) gained again after step (2) processing, obtaining the another kind of waste elastomer rubber powder amount that contains is to be less than 70%～5% the plasticizing rubber powder or the masterbatch or the rubber master batch product of fine glue powder, said product comprises that granularity equals to be narrower than 80 orders but is coarser than 100 purpose products, granularity equals to be narrower than 100 orders but is coarser than 120 purpose products, granularity equals to be narrower than 120 orders but is coarser than 140 purpose products, granularity equals to be narrower than 140 orders but is coarser than 160 purpose products, granularity equals to be narrower than 160 orders but is coarser than 180 purpose products, granularity equals to be narrower than 180 orders but is coarser than 200 purpose products, and granularity is narrower than 200 purpose products.

14. the method for claim 1, it is characterized in that: except with the product of step (1) method of (2) further the processing set by step, comprise that also just the product of step (1) passes through spiral separation equipment or cyclone separator, after removing regeneration class material, the water flotation formula separation equipment recovery of ultrasound functions obtains a class purity or/and have at the meticulous pure rubber powder product that is higher than 95%～100%, said pure rubber powder product comprises that granularity equals to be narrower than 80 orders but is coarser than 100 purpose products, granularity equals to be narrower than 100 orders but is coarser than 120 purpose products, granularity equals to be narrower than 120 orders but is coarser than 140 purpose products, granularity equals to be narrower than 140 orders but is coarser than 160 purpose products, granularity equals to be narrower than 160 orders but is coarser than 180 purpose products, granularity equals to be narrower than 180 orders but is coarser than 200 purpose products, and granularity is narrower than 200 purpose products.

15. the product as method as described in one of claim 12～14 obtains is characterized in that: this series products all can be used as the raw material or the dressing of rubber industry.