CN105925002A - Plastic product care solution - Google Patents

Plastic product care solution Download PDF

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Publication number
CN105925002A
CN105925002A CN201610474854.2A CN201610474854A CN105925002A CN 105925002 A CN105925002 A CN 105925002A CN 201610474854 A CN201610474854 A CN 201610474854A CN 105925002 A CN105925002 A CN 105925002A
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CN
China
Prior art keywords
plastic
conditioning liquid
water
vaseline
fatty alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610474854.2A
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Chinese (zh)
Other versions
CN105925002B (en
Inventor
冯幼林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianjin Xiqing Tianqin Technology Co ltd
Original Assignee
Tianjin Zhiyuan Jiangshan Science And Technology Co Ltd
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Priority to CN201610474854.2A priority Critical patent/CN105925002B/en
Publication of CN105925002A publication Critical patent/CN105925002A/en
Application granted granted Critical
Publication of CN105925002B publication Critical patent/CN105925002B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00Compositions of unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D171/00Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D171/02Polyalkylene oxides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D191/00Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
    • C09D191/06Waxes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008Polymeric surface-active agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2072Aldehydes-ketones
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Emergency Medicine (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Cosmetics (AREA)

Abstract

The invention relates to the field of organic chemistry and discloses plastic product care solution. The plastic product care solution is prepared from the following ingredients by weight percent: 2-5% of anti-aging agent 1098, 2-5% of vaseline, 4-8% of fatty alcohol-polyoxyethylene ether, 2-4% of 2,4-dihydroxy benaophenonel, 3-7% of beeswax and the balance of water. The plastic product care solution is simple in ingredient, convenient in preparing process, low in cost and convenient to use and has an anti-aging effect.

Description

Plastic conditioning liquid
Technical field
The present invention relates to organic chemistry filed, particularly relate to a kind of plastic conditioning liquid.
Background technology
Plastic is to be made by macromolecular material, and it is light and handy because of quality, and low price is easily fabricated to variously-shaped and wide General it is applied in daily life.But it is during storing, displaying and use, at complex environment and use mill Under the influence of the composite factors such as damage, due to crosslinking and the cracking of macromolecular main chain, the change of quality can gradually occur, be mainly reflected in Plastic aging on, aging is a kind of irreversible chemical change process, and means can only be taked to delay the process that it is aging.
The existing measure delaying plastic aging mainly has: weakens the storage of plastic and uses environment, avoiding moulding as far as possible The light of material products, heat, oxygen effect, strengthen the temperature and humidity management of environment, it is to avoid the contact of chemical substance and pollution, it is to avoid The environment exopathogenic factor factors such as the destruction of mechanical force, and now relevant can play the plastics system delaying ageing of plastics The appearance of the conditioning liquid of product.
Summary of the invention
The technical problem to be solved in the present invention is to provide that a kind of component is simple, preparation technology is convenient, low cost, easy to use, tool There is the plastic conditioning liquid of anti-aging effect.
For solving above-mentioned technical problem, the present invention adopts the following technical scheme that
Plastic conditioning liquid of the present invention, including following components (mass percent):
Age resistor 1098 2-5%, vaseline 2-5%, fatty alcohol-polyoxyethylene ether 4-8%, 2,4 dihydroxyl benzophenone 2-4% With Cera Flava 3-7%, surplus is water.
Plastic conditioning liquid of the present invention, further, including following components (mass percent):
Age resistor 1,098 2%, vaseline 2%, fatty alcohol-polyoxyethylene ether 6%, 2,4 dihydroxyl benzophenone 2% and Cera Flava 4%, surplus is water.
Plastic conditioning liquid of the present invention, further, uses following methods to be prepared from: to heat the water to 70-80 DEG C, then Age resistor 1098, vaseline, fatty alcohol-polyoxyethylene ether, 2,4-DihydroxyBenzophenone and Cera Flava are preheated, is gradually added heat In water, homogenizing mixes.
Plastic conditioning liquid of the present invention, further, is uniformly sprayed onto surface of plastic products by plastic conditioning liquid, and wiping is equal Even, every square metre of consumption is 15-30mL.
Plastic conditioning liquid of the present invention compared with prior art, has the advantages that
Plastic conditioning liquid of the present invention, by simple wiping mode, rapid osmotic can enter plastics deep layer, age resistor 1098 with 2,4-DihydroxyBenzophenone synergism, prevents plastic aging, and fatty alcohol-polyoxyethylene ether can effectively remove frosting Dirt, thoroughly, vaseline makes frosting soft and moist to cleaning, is formed protecting film by Cera Flava at frosting simultaneously, makes goods light, Simultaneously working as antioxidative effect, each component cooperates, from the maintenance nourishing surface of material deep layer, in conjunction with chemistry and thing Reason effect, delays the aging of plastic jointly.In senile experiment, use the drawing of sample of plastic conditioning liquid of the present invention Stretch performance, bending property and impact strength and be superior to matched group, illustrate that plastic conditioning liquid of the present invention can effectively delay plastics system Product aging, improves mechanical performance, keeps color and luster and the brightness of outward appearance, extends the service life of plastic.Plastics of the present invention Goods conditioning liquid proportioning is simple, the convenient easy operation of preparation technology, and low cost is easy to use, without potential safety hazard.
Detailed description of the invention
Preparation embodiment
Prepare plastic conditioning liquid of the present invention in accordance with the following methods |:
(1) get the raw materials ready: get the raw materials ready according to component (mass percent) shown in table 1:
(2) heat the water to 70-80 DEG C, then by age resistor 1098, vaseline, fatty alcohol-polyoxyethylene ether, 2,4-dihydroxy Base benzophenone and Cera Flava preheating, be gradually added in hot water, and homogenizing mixes
The concrete amounts of components of embodiment prepared by table 1
Preparation 1 Preparation 2 Preparation 3 Preparation 4 Preparation 5
Age resistor 1098 2 5 4 3 2
Vaseline 3 4 5 2 4
Fatty alcohol-polyoxyethylene ether 8 4 5 6 7
2,4 dihydroxyl benzophenone 4 2 3 2 4
Cera Flava 7 3 5 4 6
The plastic conditioning liquid that above-mentioned preparation embodiment prepares uniformly is sprayed onto surface of plastic products, and wiping is uniform, every square metre with Amount is 15-30mL.
Testing example
Selecting polypropylene black plastic products is test sample, arranges 3 experimental grouies and 1 matched group, often group Setup Experiments 3 Individual parallel, according to GB/T3681-2011 " daylight weathering aging and Fei Nie after plastics natural daylight weathering aging, glass filtration Otoscope accelerates the exposure test method of daylight weathering aging " the middle method C Fresenl mirror accelerated method specified, sample is carried out always Changing experiment, wherein matched group spray-water is tap water, experimental group 1-3 spray-water be respectively above-mentioned preparation embodiment 1,2, The 5 plastic conditioning liquids prepared, the spray cycle operates according to the relevant regulations in cycle 1, and exposing the persistent period is 2 weeks, After 2 weeks according to GB/T15596-2009 " plastics after under glass, daylight natural climate or laboratory light source expose color and performance become Change mensuration " in relevant regulations sample is measured and record, to expose before and after testing result carry out statistical analysis, specifically Result as shown in table 2.
The concrete testing result of table 2 testing example
Matched group Experimental group 1 Experimental group 2 Experimental group 3
Ash card 1-2 level 4-5 level 3-4 level 3-4 level
Color changes Bleach Black shoals Black shoals Black shoals
Elongation at break % 1.2 5.5 4.7 5.1
Cantilever beam impact strength (KJ/m2) 17.9 65.4 63.7 60.5
Bending strength (MPa) 3.7 20.5 15.6 17.8
As shown in Table 2, in aging Acceleration study, compared with matched group, use plastic conditioning liquid of the present invention clear for spray The experimental group of washing liquid, the ash organoleptic indicator such as card grade and color change is substantially better than matched group, and catabiosis is not serious, fracture Percentage elongation is 4-5 times of matched group, and cantilever beam impact strength is 3-4 times of matched group, and bending strength is 4-6 times of matched group, Visible, through overaging accelerate after, use the tensile property of experimental group sample of plastic conditioning liquid of the present invention, bending property and Impact strength is superior to matched group, illustrates to use plastic conditioning liquid of the present invention can effectively delay the aging of plastic, improves Mechanical performance, keeps color and luster and the brightness of outward appearance, extends the service life of plastic.
Embodiment described above is only to be described the preferred embodiment of the present invention, not carries out the scope of the present invention Limiting, on the premise of designing spirit without departing from the present invention, technical scheme is made by those of ordinary skill in the art Various deformation and improvement, all should fall in the protection domain that claims of the present invention determines.

Claims (4)

1. plastic conditioning liquid, it is characterised in that: include following components (mass percent):
Age resistor 1098 2-5%, vaseline 2-5%, fatty alcohol-polyoxyethylene ether 4-8%, 2,4 dihydroxyl benzophenone 2-4% With Cera Flava 3-7%, surplus is water.
Plastic conditioning liquid the most according to claim 1, it is characterised in that: include following components (mass percent):
Age resistor 1,098 2%, vaseline 2%, fatty alcohol-polyoxyethylene ether 6%, 2,4 dihydroxyl benzophenone 2% and Cera Flava 4%, surplus is water.
Plastic conditioning liquid the most according to claim 1, it is characterised in that: use following methods to be prepared from: by water It is heated to 70-80 DEG C, then by age resistor 1098, vaseline, fatty alcohol-polyoxyethylene ether, 2,4-DihydroxyBenzophenone and honeybee Wax preheats, and is gradually added in hot water, and homogenizing mixes.
Plastic conditioning liquid the most according to claim 1, it is characterised in that: plastic conditioning liquid is uniformly sprayed onto and moulds Material products surface, uniformly, every square metre of consumption is 15-30mL in wiping.
CN201610474854.2A 2016-06-21 2016-06-21 Plastic products conditioning liquid Expired - Fee Related CN105925002B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610474854.2A CN105925002B (en) 2016-06-21 2016-06-21 Plastic products conditioning liquid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610474854.2A CN105925002B (en) 2016-06-21 2016-06-21 Plastic products conditioning liquid

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CN105925002A true CN105925002A (en) 2016-09-07
CN105925002B CN105925002B (en) 2018-12-04

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107418742A (en) * 2017-08-07 2017-12-01 安徽凤凰松包装有限公司 A kind of plastic products cleaning agent
CN107418766A (en) * 2017-08-07 2017-12-01 安徽凤凰松包装有限公司 A kind of plastic products detergent

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1067263A (en) * 1991-05-27 1992-12-23 刘冠中 Multipurpose high-efficiency detergent cream without water washing
CN1830646A (en) * 2004-10-09 2006-09-13 陈民铎 Regeneration method of waste elastic body
CN101041725A (en) * 2006-03-24 2007-09-26 陈书怡 Reproduction new method for waste elastomer and plastic
CN103045412A (en) * 2012-12-05 2013-04-17 刘聪 Leather cleaning and polishing agent and preparation method thereof
CN104673549A (en) * 2013-12-02 2015-06-03 青岛惠城石化科技有限公司 Leather cleaning agent
CN105082579A (en) * 2015-08-14 2015-11-25 芜湖蓝博塑胶有限公司 Surface scratch repair working table of air conditioner plastic parts and repair method thereof
CN105250172A (en) * 2015-10-14 2016-01-20 刘艺鹏 Witch hazel massage balsam

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1067263A (en) * 1991-05-27 1992-12-23 刘冠中 Multipurpose high-efficiency detergent cream without water washing
CN1830646A (en) * 2004-10-09 2006-09-13 陈民铎 Regeneration method of waste elastic body
CN101041725A (en) * 2006-03-24 2007-09-26 陈书怡 Reproduction new method for waste elastomer and plastic
CN103045412A (en) * 2012-12-05 2013-04-17 刘聪 Leather cleaning and polishing agent and preparation method thereof
CN104673549A (en) * 2013-12-02 2015-06-03 青岛惠城石化科技有限公司 Leather cleaning agent
CN105082579A (en) * 2015-08-14 2015-11-25 芜湖蓝博塑胶有限公司 Surface scratch repair working table of air conditioner plastic parts and repair method thereof
CN105250172A (en) * 2015-10-14 2016-01-20 刘艺鹏 Witch hazel massage balsam

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107418742A (en) * 2017-08-07 2017-12-01 安徽凤凰松包装有限公司 A kind of plastic products cleaning agent
CN107418766A (en) * 2017-08-07 2017-12-01 安徽凤凰松包装有限公司 A kind of plastic products detergent

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Effective date of registration: 20191008

Address after: Area A2-1, workshop 2, Xinghua 2nd Branch Road, Xiqing Economic and Technological Development Zone, Tianjin 300000

Patentee after: Tianjin Xiqing tianqin Technology Co.,Ltd.

Address before: 300000 Tianjin city of Hangu Binhai New Area of Anyang Street No. 39

Co-patentee before: Feng Youlin

Patentee before: TIANJIN ZHIYUAN JIANGS TECHNOLOGY CO.,LTD.

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Granted publication date: 20181204