CN101041725A - Reproduction new method for waste elastomer and plastic - Google Patents

Abstract

The invention discloses a new regenerating method of waste elastics and plastic, which comprises the following steps: 1. blending waste elastics or/and plastic with grain size between 5 and 80 order and non-polluted regenerative adjuvant according to proportion; placing into the manufacturing machine; grinding; sieving; heating to desulfurize; bulking; soaping; emulsifying; kneading; pressing; graining; obtaining composite product 1 with mother material or mother particle or mother gel of plastic elastic powder; 2. weighing product 1 and non-polluted mating agent into mixing machine according to proportion; kneading; blending evenly; pressing; graining; obtaining the product 2 of mother material or mother particle or mother gel with 5-95% waste elastic or/and plastic.

Description

The new method for regenerating of a kind of waste elastomer, plastics

Technical field

The present invention relates generally to the collaborative regeneration of environmental protectionization of waste elastomer, plastics and other solid waste etc., belongs to the technology category that castoff regenerative utilizes.

Background technology

The regeneration of solid waste such as waste elastomer, plastics, to this developing power of China is an indispensable industrial class, the regeneration of waste elastomer, plastics, they are normally adhered to separately at waste rubber again in occupation, the waste plastics recycling industry in China, they be two mutually between the industry of contacts not too.

At present at the waste rubber major product of (accounting for more than 80%) in the occupation again in China---the fine glue powder of reclaimed rubber and new development in recent years etc. but exists the defective of its product existence of many obstructions or development always! Chinese patent application 200510106078.2 has proposed good improvement project to this present situation; And providing a kind of waste elastomer to account for 95～5%, other auxilliary ingredients accounts for 5～95%, can be as rubber, mould plasticizing rubber powder that goods industry supplementary material uses or/and the masterbatch of fine glue powder, rubber master batch new product.But its preparation method and the masterbatch that is provided, rubber master batch product find that still have deficiency, the subject matter of existence has at least after concrete enforcement:

200510106078.2 reclaiming aid group, " powdery type auxiliary material " in the Synergist S-421 95 that Chinese patent application proposes equal 200 purpose materials for granularity is narrower than, this wherein also comprises dry mash such as carbon black.And be narrower than dry mash such as equaling 200 purpose carbon blacks is the material that a class is very easily flown upward pollution, so implementing pulverizingly when waiting operation, accomplish to feed intake and not pollute, even facilities and equipments have been taked strict airtight measure, also is difficult to realize;

200510106078.2 Chinese patent application propose in the waste elastomer Coarse Aggregate, the reclaiming aid group that adding is made up of a large amount of powdery type auxiliary materials, carry out mixture pulverizing then, the coarse fodder that sieves out after the pulverizing returns row circulation pulverizing again in the batching mix jar again, through implementing discovery, this can make production line occur sieving, and fine powder content descends in the logistics, the coarse fodder amount of the returning rising of constantly to fluctuate again, so that make pulverizer intermittence ground stop into virgin material, finally influence the current stabilization operation of whole continuously acting production lines;

200510106078.2 still have Yatall MA etc. that smelly material is arranged in the tenderizer that Chinese patent application the proposes set;

200510106078.2 the masterbatch that Chinese patent application provides, rubber master batch product, though in specification sheets, mentioned plastic waste add-on in preparation masterbatch, rubber master batch product can be 0～1900 part of (weight)/100 part (weight) (waste elastomer) scope, specific embodiment is not provided;

200510106078.2 the masterbatch that Chinese patent application provides, the rubber master batch product, only be to say to place conventional elastomerics processor to carry out the processing gained, and also do not have any rigidity material of pulverizing efficiently at present in the conventional various elastomerics processors, so masterbatch that 200510106078.2 Chinese patent application provide, in the rubber master batch product to contain powder more, containing the less kind of waste elastomer can't obtain in its described step (1) at an easy rate, so used reclaiming aid group in the step described in 200510106078.2 Chinese patent application (1), the highest consumption of powdery type auxiliary material wherein only can be: 43 parts/100 parts (in waste elastomer rubber powder weight basis).

And at present in the waste plastics recycling industry, plastic waste is mainly reproduced into particle and is gone on the market again, and this regenerated plastic waste particle is applied to rubber, moulds industry such as goods, except reducing cost, to rubber, mould that the serious dust pollution that exists does not have dependency in the industry such as goods;

The renovation process of another kind of plastic waste is to adopt comminuting method, the plastic waste powder obtains regenerating, this renovation process has two shortcomings that are difficult to overcome at present, the first, the reprocessed plastic(s) powder that the normal temperature method obtains, its particle is thicker, generally at 10～80 orders, the normal temperature fine crusher also is difficult to pure gentle matter plastic film in small, broken bits, and normal temperature method method is pulverized the synthetic resin moulding compound obtain can not be in mill and blend rubber system rubber plastic blend material; It two is, the reprocessed plastic(s) powder that cold method obtains, though its particle is thin, its production cost is too high, and market is difficult to accept;

There is a kind of waste plastics recycling scheme to be again, plastics are considered to be worth doing, bar, grain, powder, broken film material as carrier layer batching with as the inorganic of filler nuclear or/and organic powder, fibre material mixes, and the while adds silicane again, titanate ester, the phosphoric acid ester material is as coupling agent, add low molecular polyethylene, polystyrene, stearic acid and its esters material are as dispersion agent, in quick mixer, stir, heat up, fusion, mix, obtain so-called filling master batch product and (see Chemical Industry Press for details, the Materials Science and Engineering publishing centre publishes and distributes, " plastic formula design " July in 2004 the 2nd edition, Wang Wenguang, chief editors such as Tian Yanchen, the recovery formulating of recipe of chapter 13 plastic matrix formulating of recipe and chapter 14 plastic waste); In this regeneration scheme, crush in advance as the powder material of filler nuclear, the blended temperature to reach plastics decompose, more than the melt temperature, the regenerative process energy consumption is big, dust pollution is difficult to eliminate.

The elastomerics normal temperature technology in small, broken bits that existing fine glue powder uses, also there are many defectives in use therein combined machine, concludes to get up to mainly contain:

1. for obtaining the high elastomerics powder of fine powder content, the pulverizing technology of normal temperature normally adds an amount of short broken auxiliary agent in treating the elastomerics coarse grain material of fine pulverizer into, and, cause the auxiliary agent material to pollute production environment because existing integrated clustered aggregates is not provided with corresponding airtight device for carrying out said;

2. existing integrated clustered aggregates is not provided with the corresponding airtight device that adds short broken auxiliary agent, do not urge broken auxiliary agent and do not add, normal temperature is implemented the pulverizing of elastomerics material down, fine pulverizer in existing integrated clustered aggregates, once crossing the material that can cross 90 mesh sieves in the material of fine pulverizer will never surpass 30%, only be between 3～5% usually; And the thick elastomerics powder of 90 eye mesh screens only owing between meal material and virgin rubber tangible new and old glue interface is arranged, not too can form uniform one mutually with new sizing material, so they mix its poor-performing in virgin material;

3. in the existing complete or integrated clustered aggregates unit of so-called vulcanized rubber fine glue powder, the fine pulverizer of each separate unit is all by after the parallel connection in groups, be connected on again and pulverize in the integrated combination unit, 5～40 order coarse fodder storehouses in the import first line of a couplet combination unit of pulverizing unit, the discharge port of pulverizing unit is behind spiral separator, assign rubber powder classification or sieve apparatus, the fines of telling advance storage bin and coarse fodder again back into the coarse fodder storehouse; Such equipment combination process configuration, owing to can not guarantee the constant of short broken auxiliary agent content in into the machine raw meal particle size and charging thing, cause that coarse fodder increases in the material after in small, broken bits, screening back meal feed back increases, be to make 5～40 order coarse fodders advance minimizing of machine flow or pause at last, cause the production capacity of whole piece unit to fluctuate.

At elastomerics, mould in the goods industries; elastomerics, plastic blend are problems that a lot of people of quilt studied; but with the old rubber of abandoning or/and plastic cement or/and plastics and various auxilliary batching; particularly but how itself and other solid waste is worked in coordination with to environmental protectionization and is made masterbatch, master batch, the rubber master batch product that ammunition feed gonosome, plastics etc. are already done the secondary supplementary material use of environment-friendly type, does not then see report more ingenious.

In addition, how the secondary raw material rubber such as reclaimed rubber of commercially available low rerum natura, to improve the scheme of rerum natura, also not seeing has report through reprocessing.

Summary of the invention

In prior art, waste elastomer (being that rubber is or/and plastic cement) is or/and serious, the shortcoming of can not the high-level efficiency serialization producing of dust pollution in the regenerative process of plastics macromolecule material, and the existing regenerated rubber that obtains, the molding product granularity is thick, physical properties is not good, and old rubber, the molding product not miscible problem in regenerative process of abandoning has proposed solution targetedly; Also propose the secondary raw material rubber such as reclaimed rubber of commercially available low rerum natura, through the scheme of reprocessing with the raising rerum natura.

The objective of the invention is, provide a kind of waste elastomer or/and the new method for regenerating of plastics macromolecule material, specifically comprise by to the reclaiming aid group, the innoxious improvement of Synergist S-421 95, and with the reclaiming aid group after improving, Synergist S-421 95 is to waste elastomer, the bits of plastics, bar, grain, powder, broken film etc., or the secondary raw material rubber such as reclaimed rubber of commercially available low rerum natura, contamination-freely comprise mixed, broken, divide, heat, the combined treatment of one or more of technologies such as kneading, make and a kind ofly have at height, all ordorless and be difficult for airborne dust under the room temperature, or also have high anti-characteristic such as open, can give elastomerics, industries such as plastics are as masterbatch or the master batch or the rubber master batch product of the secondary supplementary material use of environment-friendly type;

In the new method for regenerating provided by the invention, also comprise pulverizing, screening process operation a kind of improve and provide a kind of special combined equipment that has the normal temperature fine pulverizer, have with making the fine pulverizer intermittence and stop into new coarse fodder and can make production plant fill the air the disadvantage of dust to eliminate existing working method;

In the new method for regenerating provided by the invention, comprise that also the pulverizing cutterhead to rubber normal temperature fine pulverizer provides a kind of improvement, to improve the new cutterhead output of first time spent.

Another object of the present invention is, a kind of masterbatch or master batch or rubber master batch new product of new shape is provided, and can be mixed into one fully mutually with virgin material, promptly can not see rubber powder granule on the cutter cut surface of goods.

A further object of the present invention is that the application of described new product in industries such as elastomerics, plastics is provided.

In order to reach above goal of the invention, the following inventive concept of existing proposition:

One, the improvement that renovation process is taked

1. to the improvement of manipulation of regeneration mode:

1. (a) the present invention is with waste elastomer, plastics macromolecule material; or secondary raw material rubber such as commercially available plasticizing rubber powder, low rerum natura reclaimed rubber cooperate with reclaiming aid group, Synergist S-421 95 material after the innoxious improvement; can place processors such as conventional elastomerics regeneration or building stones pulverizing then; the combined treatment of one or more of the courses of processing such as that employing comprises is mixed, broken, branch, heat, kneading, granulation, obtain aforesaid contain old abandon rubber or/and plastic cement or/and the masterbatch of plastics or master batch or rubber master batch product 1 and product 2.Use the building stones pulverizer, be suitable for the grinding and processing elastomerics especially or/and plastic content at 70%～5% material, pulverized together rigidity batching also need not be anticipated and be become to be narrower than 200 purpose powders in the material.

1. (b) the present invention is in old pulverizing, the screening workshop section that abandons macromolecule material; employing (as is coarser than 90 orders with the meal that sifts out; powder auxiliary material is always on the low side in these materials) (as be narrower than 250～350 orders with the fine powder material of crossing that sifts out; powder auxiliary material is always on the high side in these materials) interflow after; return coarse fodder again and treat the particle storehouse; or the process program of placed in-line another fine crusher pulverizing of going further; guarantee the feed size of every fine crusher and the proportioning constant of powder auxiliary material, continuous processing is pulverized the flow rate fluctuation impact of production line to reduce or eliminate the coarse grain feed back.

1. (c) the present invention can be lower than under old decomposition of abandoning macromolecule material, the plasticization temperature; it is ground into to be narrower than with the reclaiming aid group that contains powder auxiliary material, Synergist S-421 95 material equals 90 purpose masterbatch products; or again with Powdered masterbatch through operation such as rolling, obtain sheet, bits, grain, gelationus master batch or rubber master batch product.

1. (d) the present invention not only can implement on processing unit lines such as traditional floating reclaim, oil process reclaimed rubber, forcing machine method reclaimed rubber, Banbury mixer method reclaimed rubber, dynamic pot process reclaimed rubber, rapid agitation reclaimed rubber, mill method reclaimed rubber, normal temperature crushing up fine glue powder; More can graft in various mining industry usefulness, or rubber and plastic is with implementing on the processing unit lines such as the abrasive dust of powder auxiliary material, auxiliary agent, mixing, compressing tablet, granulation.

1. in (e) step 2 of the present invention, secondary raw material rubber is mixed with Synergist S-421 95, under oxygen free condition, smoke in glue room/chamber in digester (-tor), flue, between 100-240 ℃, carry out handling to 3 round the clock insulations in 1 hour, reduce to room temperature subsequently, obtain the secondary raw material rubber product that tensile strength is higher than raw material;

The product 1 that comprises the rubber powder, resinifying agent, scrap rubber breast of commercially available mistake 20 order mesh screens, low rerum natura reclaimed rubber, obtains through step 1 as the secondary raw material rubber of raw material wherein; Wherein used oxygen free condition preferably uses the oxygen free condition of reductibility stack gas, water, water vapour, one or more formation of rare gas element; Wherein Synergist S-421 95 contains anti-aging agent; Wherein used insulation treatment condition, preferably in stack gas under 100-120 ℃, condition of normal pressure, insulation is handled 2-3 round the clock, or in water vapour under 230-240 ℃, 3.5MPa condition, 1-5h is handled in insulation.

2. to the used reclaiming aid group that reaches, the improvement of Synergist S-421 95 system in the new method for regenerating:

2. add the batch ingredients be easy to be pulverized but be difficult for flying upward in (a) reclaiming aid group, the Synergist S-421 95 or/and saponification, emulsifying agent or/and ordorless tenderizer; with reach improve to pulverize or/and saponification, emulsification or/and in the processing efficiencies such as swelling, do not have the environmental protection effect of airborne dust, odor pollution etc. again.(this is the improvement that the prerequisite in reclaiming aid group, the Synergist S-421 95 system is carried out).

2. can add batch ingredients in (b) reclaiming aid group, improve anti-good result of tearing to reach with tear resistance.

2. the component that can add lubricated burnish resistance in (c) reclaiming aid group, the component of described lubricated burnish resistance is meant: have when rubber is ground the friction resistance that reduces between rubber particle, thus the abrasion loss when reducing living heat in the pulverizing process and rubber and being re-used.

2. the desulfurization activator class material that can add odorless in (d) reclaiming aid group.

2. can add antioxygen anti-aging agent class material in (e) reclaiming aid group.

2. (f) is when preparation contains more masterbatch of powder auxiliary material or rubber master batch, by method of the present invention, can add the material production of reclaiming aid group earlier and go out to contain the more product of glue, and then add more powder auxiliary material or/and tenderizer or/and materials such as antioxygen anti-aging agent, for the back add main by powder auxiliary material or/and the system that tenderizer class material is formed, also have functional material, macromolecule material, emulsion form monomer, abbreviate Synergist S-421 95 as.Harmless regeneration auxiliary agent group, Synergist S-421 95 system that the present invention proposes also can independently form elastomerics regeneration used additives product.

3. to the used a kind of improvement that has the special combined equipment of normal temperature fine pulverizer that reaches in the new method for regenerating:

3. (a) is provided with the mechanism that can add auxiliary material in that unit in small, broken bits is forward and backward, so that add the operation of auxiliary agent such as short broken, powder granulation in material, makes elastomerics pulverize the product that reclaiming process implements and make and can really realize environmental protectionization in use;

3. the mechanism of (b) described adding auxiliary material is the device that has the weighing of a unitary energy at least;

3. (c) described weighing device can be the scale that can weigh or bucket, groove, the pipe of measuring volume, or their combination;

3. the mechanism of (d) described adding auxiliary material also is to have a unitary auxiliary material that can make adding and micelle, rubber powder blended mechanism mutually at least;

3. (e) described auxiliary material and micelle, rubber powder blended mechanism mutually can be bucket, groove, the pipe that has band to stir, or shell can be done the bucket, groove, the pipe that rotate or their combination;

3. the mechanism of (f) described adding auxiliary material is good with what have airtight dustproof construction.

3. (g) is divided into three groups of two groups of A, B or A, B, C at least to unit in small, broken bits; Be divided into two groups feed rate ratio, its preferable scope is: A/B=2/1～9/1 is divided into two groups unit in small, broken bits and is easy to pulverization process and obtains being narrower than and equal 90 purpose elastomer powders; Be divided into three groups feed rate ratio, its preferable scope is: A/B/C=1/1/1～5/3/1 is divided into three groups unit in small, broken bits and is easy to pulverization process and obtains being narrower than and equal 200 purpose elastomer powders; A, B, C group, all be in parallel in it is organized separately, connect 5～40 order coarse fodder storehouses (not accepting feed back) on the A group, connect the pulverizing of A group, tailover feed back pipeline (only accepting the pulverizing of A group, tailover feed back) on the B group, connect on the C group that the B group is pulverized, tailover feed back pipeline (only accept the B group is pulverized, tailover feed back), this measure can guarantee the constant of the granularity of machine material into and short broken auxiliary agent content; The outlet of A, B, C group can be parallel connection, and outlet in parallel connects classification, sieving machine down behind spiral separator; The outlet of B, C group can be not in parallel with the outlet of A group yet, because the big multipotency of the powder that B, C organize out is narrower than 90～200 orders, so its outlet can be walked around classification, the through fine powder storage bin of sieving machine; The outlet of B, C group also can both join classification, sieving machine by two valve pipelines, through again fine powder storage bin.

3. (h) is provided with feed rate than setting device on fine crusher grouping feeding pipe, so that make the operation of efficiency optimizationization in small, broken bits.

3. (i) is provided with the meal material of not crossing 90～200 mesh sieves (short broken auxiliary agent content is always on the low side in this part material) that can tell classification, sieve apparatus, also flow with the fine powder material of crossing more than 250～350 orders (short broken auxiliary agent content is always higher in this part material) of crossing, supply with the fine crusher mechanism pulverized of row more then, thereby guarantee also to have in the logistics of fine crusher the short broken auxiliary agent of capacity.

3. (j) does crudeization processing to the abrasive dust face of the new pulverizing cutterhead of rubber normal temperature fine pulverizer, increasing new mill surface to the broken efficient of the file of material handling, and the low yield flaw when changing existing city and newly pulverizing cutterhead and when just using, always have several classes.

Two, the design of the masterbatch of the present invention's proposition, master batch, rubber master batch new product:

1. masterbatch that obtains or master batch or rubber master batch mixture granularity are less than 90 orders.

2. waste elastomer (being that rubber is or/and plastic cement) and plastics account for 95%～5%; other auxilliary ingredients accounts for masterbatch or the master batch or the rubber master batch mixture of 5%～95% weight; wherein account for 95%～70% and 30%～5% with waste elastomer and plastics especially, other auxilliary ingredients accounts for 5%～30% and 70%～95% both intervals for good.

3. useless elastomerics in described masterbatch or master batch or the rubber master batch mixture and the ratio of plastic waste in the weight that feeds intake, especially with (30～5): (70～95) and (70～95): (30～5) both intervals are good.

4. the present invention proposes; elastomerics wherein and plastics; the interval that the weight percentage of reclaiming aid group, Synergist S-421 95 etc. all is two apart from each others distributes; can make masterbatch or master batch or rubber master batch product like this when using, can greatly satisfy the prescription maneuverability requirement of downstream application as supplementary material.

5. the masterbatch or master batch or the rubber master batch new product mixture that propose of the present invention; under the hot extrude of downstream product industry, hot-forming condition; can be mixed into a phase fully; promptly on the cutter cut surface of goods, can not see the elastomer precursor gum powder particles, this just by masterbatch or master batch or rubber master batch mixture granularity less than the resulting good character of 90 orders.

6. the new product mixture that proposes of the present invention, odorless under the hot-work condition of downstream product industry, also odorless under the room temperature.

Three, the present invention is proposed masterbatch or the master batch or the rubber master batch new product of protection domain, its application direction is:

Elastomerics is or/and plastics, modifying asphalt, and waterproof roll, paint, tackiness agent, the look mother is used for rubber, moulds master batch, rubber master batch of fire retardant agent for products etc.

Embodiment

A kind of waste elastomer (being that rubber is or/and plastic cement) or/and the new method for regenerating of plastics macromolecule material it is characterized in that: described method comprises following processing step (1) at least or/and processing step (2), wherein,

Processing step (1) is be about 5 orders with granularity but be coarser than 80 purpose waste elastomers or/and the bits of plastics, grain, bar, broken film and improved reclaiming aid group by waste elastomer or/and 100 parts in plastics (dry weight basis), add 5.3～1900 parts of reclaiming aid group materials, place processor, one or more the combined treatment that comprises the harmless regeneration courses of processing such as mixing, pulverizing, screening, the disconnected sulphur of heating, swelling, emulsification and kneading, obtain that a class contains elastomerics or/and the mixing intermediate product of plastics, or the production method of the finished product; Said mixing intermediate product, its waste elastomer or/and plastic content be 95%～more than 5%; Said the finished product, its waste elastomer is or/and plastic content is 95%～5%; Said mixing intermediate product and the finished product, comprise contain the plastifying elastomerics or/masterbatch or the master batch or the rubber master batch of elastomerics and plastics, or elastomerics is or/and the saponification of plastics, emulsification, or obtains 90% above powder granularity and be narrower than and equal 90 purpose elastomericss or/and the fine powder mixture of plastics; Comprise the method handled of row again in processors such as placed in-line pulverizing again after the thick material of not crossing 90 mesh sieves in the pulverization process can merge with the meticulous material of crossing 250～350 mesh sieves in the step;

The treatment condition of processing step (1) comprising: service temperature is room temperature～240 ℃; Working pressure is normal pressure～3.5MPa; By the pH value of reclaiming aid group material regulation and control material system, make pH value stabilization that material is 5～14, or waste elastomer, plastics saponification, emulsification; Material ratio by weight percentage is: waste elastomer is or/and plastics account for 95%～5%, and the reclaiming aid group accounts for 5%～95%; Under above-mentioned processing condition, after the described manipulation of regeneration processing of completing steps (1), obtain a class waste elastomer or/and plastic content is 95%～5% masterbatch or master batch or rubber master batch intermediate product or the finished product.

Processing step (2) is with the waste elastomer of processing step (1) gained or/and plastic content is 95%～intermediate product more than 5% or commercial similar material (as secondary raw material rubber such as low rerum natura reclaimed rubbers), place hybrid process machinery after the weighing in proportion respectively with Synergist S-421 95 again, by stirring or again after further processing treatment such as kneadings, mixing, obtain containing waste elastomer or/and plastic content 5%～be less than the production method of the finished product of 95% masterbatch or master batch or rubber master batch;

The treatment condition of processing step (2) comprising: service temperature is room temperature～180 ℃; Working pressure is normal pressure～0.1MPa; After Synergist S-421 95 added the sizing material system, the pH of sizing material system can be 5～9; Material ratio by weight: taking technique step (1) gained intermediate product or commercial similar material are an amount of, add Synergist S-421 95 again, make the auxilliary ingredients in the material, promptly Synergist S-421 95 comprise reclaiming aid group material that processing step (1) gained intermediate product is comprised account for 95% altogether～more than 5%; Under above-mentioned processing condition, carry out processing treatment and get, to another kind of waste elastomer or/and plastic content be 5%～be less than 95% the masterbatch or the finished product of master batch or rubber master batch;

In the said new method for regenerating of the present invention, can water, but do not discharge waste water to environment.

Method of the present invention, comprise: get 5～40 purpose waste elastomer buffings, grain, meal and carry out when pulverizing, the reclaiming aid group auxiliary agent that adds contains the granular powder auxiliary material that is easy to be ground into powder, because the granular powder auxiliary material has not only been brought into play the efficient of raising comminuting elastomer but also had the effect that is difficult for airborne dust; When granular or with the powder auxiliary material of packing when being added into as grinding aid, the roller pulverizer system of employing is narrower than when equaling 20～40 purpose rubber powders, with the weight of the powder auxiliary material that adds account for gained rubber powder mix products weight 3～10% for good; When adopting the normal temperature ultrafine crusher to produce to be narrower than when equaling 90 purpose fine glue powders, must add the reclaiming aid group that contains the granular powder auxiliary material, wherein processing step (1) with the weight of the powder auxiliary material that adds account for gained rubber powder mix products weight 5～30% for good, one went on foot machine pulverize the coarse fodder sift out with sift out cross fines and merge after, other walks processors such as pulverizer placed in-line or not on line and handles, and no longer returns former fine crusher processing.

Method of the present invention, also comprise: get 5～40 purpose waste elastomer buffings, grain, when meal carries out saponification, emulsification, the reclaiming aid group auxiliary agent that adds contains alkali or alkali and tensio-active agent, also entry can be added, wherein alkaline saponification, emulsive waste elastomer intermediate product can be obtained being at processing step (1); Again in processing step (2); in saponification, emulsive waste elastomer intermediate product, add and be the non-aqueous Synergist S-421 95 material of tart; make be alkaline saponification, emulsive waste elastomer product goes to pH=5～9 scopes again; obtain containing masterbatch or the master batch or the rubber master batch the finished product of waste elastomer, the water cycle of deviating from is used again.

Method of the present invention, also comprise: when system contains waste elastomer at the plasticizing rubber powder of 95～5% scopes or fine glue powder masterbatch or master batch or rubber master batch, the auxilliary auxiliary agent of joining such as more powder auxiliary material, tenderizer need be arranged in the finished product, can rubber powder plastified earlier saponification, emulsification or levigate after processing step (2) in add intermediate product technology again; Said powder auxiliary material, tenderizer also can be separately or be combined to form independently Synergist S-421 95 product together in the processing step (2); Waste elastomer is after nationality helps the reclaiming aid group to finish manipulation of regeneration in processing step (1), can be according to the requirement of downstream industry to the finished product, in processing step (2), add again " Synergist S-421 95 ", after mixing or further kneading, obtain required plasticizing rubber powder or fine glue powder masterbatch or rubber master batch the finished product again.

Method of the present invention; also comprise: old bits, bar, grain, the broken film of abandoning plastics cooperated with reclaiming aid group, Synergist S-421 95; fusing at high temperature, emulsification, mixing obtain containing the old the finished product of abandoning plastics 95%～5% masterbatch or master batch or rubber master batch after the cooling.

Method of the present invention; also comprise: get old bits, bar, grain, the broken film of abandoning shredded rubber, grain, meal and plastic waste of 5～40 purposes and cooperate with reclaiming aid group, Synergist S-421 95; swelling, fusing, mixing, kneading at high temperature obtains containing the old master batch of rubber and plastics 95%～5% or the finished product of rubber master batch abandoned after the cooling.

Method of the present invention; also comprise: can be lower than oldly abandon rubber, mould, under the decomposition of plastic cement macromolecule material, plasticization temperature; with oldly abandon rubber, mould, the plastic cement macromolecule material is ground into to be narrower than with the reclaiming aid group that contains powder auxiliary material, Synergist S-421 95 material and equals 90 purpose masterbatch products, or again with Powdered masterbatch through rolling master batch or the rubber master batch product that obtains sheet, bits shape.

Method of the present invention also comprises: the secondary raw material rubber products such as low rerum natura reclaimed rubber with commercially available through adding Synergist S-421 95 of the present invention again, again through comprising the processing of processing step (2) at least, obtain than the better secondary raw material rubber of original product rerum natura.

Method of the present invention, also comprise: step 1 is or/and after 2, secondary raw material rubber is mixed with Synergist S-421 95, under oxygen free condition, smoke in glue room/chamber in digester (-tor), flue, between 100-240 ℃, carry out handling to 3 round the clock insulations in 1 hour, reduce to room temperature subsequently, obtain the secondary raw material rubber product that tensile strength is higher than raw material;

Wherein as the secondary raw material rubber of raw material comprise the rubber powder, resinifying agent, scrap rubber breast of commercially available mistake 20 order mesh screens, low rerum natura reclaimed rubber, through step 1 or/and 2 products that obtain; Wherein used oxygen free condition, the oxygen free condition of preferred reductibility stack gas, water, water vapour, one or more formation of rare gas element; Wherein Synergist S-421 95 contains anti-aging agent; Wherein used insulation treatment condition, preferably in stack gas under 100-120 ℃, condition of normal pressure, insulation is handled 2-3 round the clock, or in water vapour under 230-240 ℃, 3.5MPa condition, 1-5h is handled in insulation.

Method of the present invention; also comprise: can be at withstand voltage heating tank; opening normal pressure jar; the fine grinding pulverizer; class machineries such as kneading, forcing machine a kind of be or/and on more than one the unit combination equipment line, implements to produce to contain waste elastomer or/and the masterbatch of plastics 95%～5% or master batch or rubber master batch mixture.

The new method for regenerating that the present invention proposes also relates to reclaiming aid group and the Synergist S-421 95 system that cooperates with manipulation of regeneration in its technical scheme of implementing to conceive; Described method, its scheme feature is: to waste elastomer or/and the bits of plastics materials, bar, grain, powder, broken film etc., or the employing of commercially available secondary raw material rubber such as low rerum natura reclaimed rubber comprises mixed, broken, divide, heat, emulsification, kneading, when the combination regeneration of one or more of the courses of processing such as granulation is handled, must under the cooperation of reclaiming aid group or reclaiming aid group and Synergist S-421 95, carry out harmless processing, described reclaiming aid group material, be by (1) essential component, be easy to be pulverized or liquefy but the auxiliary material that is difficult for flying upward with comprise that at least following (2)～(5) choosing adds in the material kind one or more and forms, choosing adds material component can be selected according to the needs of downstream industry by branch of industry, and concrete reclaiming aid group material comprises:

(1) essential component is easy to be pulverized or liquefies but the auxiliary material that is difficult for flying upward; (2) choosing adds component, has the macromolecule material of grafting functional or the reactive monomer of emulsion form; (3) choosing adds component, friction resistant lubricant class material; (4) choosing adds component, the disconnected sulfide linkage activator class material of odorless; (5) choosing adds component, antioxygen anti-aging agent class material.

With above-mentioned reclaiming aid group material through innoxious formula combination with waste elastomer or/and the bits of plastics, bar, grain, powder, broken film etc. after mix, place conventional rubber, mould regeneration, or in the processors such as stone material pulverizing used of mining industry, one or more the combined treatment that comprises the courses of processing such as mixed, broken, branch, heat, kneading makes and a kind ofly contains waste elastomer or/and the plastics weight percent is 95%～5% intermediate product or the finished product; They can be the plasticizing rubber mass, or are narrower than and equal 90 purpose fine rubber powder compounds, or the saponification of rubber mass, emulsification compound, or contain rubber or/and plastics or/and plastic cement mixture etc.; The intermediate product that obtains further add again make behind the Synergist S-421 95 another kind contain old abandon rubber or/and plastics or/and the finished product of plastic cement; waste elastomer wherein or/and the weight percent of plastics 95% during by intermediate product～become 5%～be less than 95% more than 5%; the finished product are no airborne dust; under room temperature～180 ℃, can not distribute coal tar; Stockholm tar; Yatall MA; aromatic hydrocarbon oil; pisselaeum and rubber are arranged; plastics; plastic cement cracking wet goods nuisance smell; smog; or also can have high anti-; masterbatch or the master batch or the rubber master batch product of characteristic such as wear-resisting, the waste elastomer in the product or/and the plastics weight percent especially with 95%～70%; 20%～10% both be excellent.

In method of the present invention, just finish by processing treatment by a step after adding reclaiming aid group material for the product that has; The product that has stirs or/and just can finish after the processing such as kneading, granulation after also needing further to add the Synergist S-421 95 material more again.

In aforesaid method, said reclaiming aid group material, the essential component in (1) wherein is easy to pulverized auxiliary material, comprises following one or more material at least:

(a) has the material of peculiar smell adsorptivity, (b) industrial slag great soil group material, (c) vegeto-animal bone, leaf, root, stem, straw, bar, shell, skin break flour class material, (d) inorganic mineral class material, (e) elastomerics, plastics reinforcement weighting material class material commonly used, (f) the calcining rear surface is the particulate class material of crude hard shape, (g) polycrystalline state compound composition class material, (h) the not sticking class material of wetting ability; Wherein,

(a) have the material of peculiar smell adsorptivity, include but not limited to: the granulation composition after one or more efflorescence of gac, coke, atlapulgite, attapulgite, diatomite, wilkinite etc. or be easy to the atomizing granular composition;

(b) industrial slag great soil group material includes but not limited to: the granulation composition after one or more fine-powdered of the red mud that printed-wiring board (PWB), brick bits, chimney soot, slag, silicon powder, the aluminium manufacturer on slag ash, useless resol, waste paper scrap, useless fabric fibre, river course mud, assorted cullet, assorted waste ceramic, the waste electric appliance dumps, the aluminium ash that aluminium manufacturer dumps, the alkali mud that soda factory dumps, the salt slurry that chlor-alkali plant dumps etc. are handled or be easy to the atomizing granular composition; Granulation composition after gypsum tailings mud fine-powdered that Citric Acid Plant, lactic acid factory, titanium powder plant, phosphoric acid factory, power plant dump is handled or be easy to the atomizing granular composition; The gypsum ironic hydroxide mixing slag mud that steel mill dumps, the slag mud that contains the ginkgo leaf fibres that bilobanone factory dumps, the fibre-bearing dregs of a decoction that the pharmaceutical factory of traditional Chinese medicine dumps, the fibre-bearing slag mud that artificial liner enterprise dumps, sugar refinery, pectin factory, tea processing factory, the fibre-bearing slag mud that paper mill etc. dump, sugar, oil, medicine, the decolouring inactivation gac that chemical plant such as amino acid dump is or/and atlapulgite slag mud, the mine tailings mud that mining industry dumps, the ironic hydroxide mud that the chemical plant dumps, the burning slag that vitriol works dumps, the assorted pigment slag mud that pigment factory dumps, the black slag mud that the carbon black plant dumps, the boron mud that boron saltworks dumps, the barium slag that barium salt factory dumps, the strontium slag that strontium saltworks dumps, the zinc gray that zinc-plated factory dumps, the granulation composition after one or more fine-powdered of the coal gangue that the colliery dumps etc. are handled or be easy to the atomizing granular composition;

(c) vegeto-animal bone, leaf, root, stem, straw, bar, shell, skin break flour class material, include but not limited to: vegeto-animal bone, shell, leaf, root, stem, straw, bar, nuclear, the grain bits combination material of the dry distillation charring of one or more of skin, rice husk, corn cob, straw, shell, cork, wood, leaf, the leaf of bamboo, withered grass, bark, shell, bone, hair, waste leather, the coconut palm cot, coconut palm palm fibre wood wool, one or more compounded plate bits after roll rolls of bamboo bits etc., rice hull ash, powdered rice hulls, the straw ashes, the straw powder, the shell powder, peanut hull meal, dust cork, wood powder, wood charcoal powder, leaf powder, bamboo leaf powder, the withered grass powder, tree bark powder, oyster shell whiting, bone meal, the waste leather powder, coconut palm cot powder, coconut palm palm fibre wood wool powder, one or more powder granulation compositions of bamboo powder etc. or be easy to the atomizing granular composition;

(d) inorganic mineral class material includes but not limited to: chrysotile-asbestos, krocodylite, Tremoliteor Tremoliteasbestos-asbestos, amosite asbestos, crocidolite, the white tremolite-asbestos, aluminite, feather alum, base aluminite, iron alum stone, natroalunite, pickeringite stone, bauxite, diaspore, the malthacite trolleite, gibbsite, augelite, lazurite, barite, calcined kaolin, acidic white earth, wilkinite, potter's clay, attapulgite, earth, serpentine, kolskite, magnesia cerolite, the magnesia cerolite of nickel, picrolite, cerolite, talcum, attapulgite, clinoenstatite, protobastite, forsterite, enstatite, hydrotalcite, foliated talc, cordierite, mountain cork, diopside, monticellite, manganolite, chloropal, allophane, quartzite, kaolin, lineae ablicantes stone, saponite, spadaite, silico-calcium sodium stone, hyalophane, celsian-felspar, anorthite, carnegieite, deweylite, hedenbergite, achmatite achmite, jurupaite, the zinc wernerite, rumpfite, kaliophylite, the buttress shaft nepheline, sodalite, hauyne, noselite, the pyrope garnet, iron aluminium garnet, the brownmillerite garnet, chrysolite, fayalite, willemite, fiber copper silicon ore deposit, meionite, marialite nai, sarcolite, wernerite, gehetinite, sillimanite, melilith, clinozoisite, lawsonite, sial calcium magnesite, dumortierite, staurotide, kornerupine, okenite, rankinite, gyrolite, the monocline rankinite, riversideite, beryl, apophyllite, mordenite, brusterite, the stripping zeolite, the barium staurotide, phillipsite, oblique euthalite, the oblique zeolite of sodium, the oblique zeolite of calcium, natrolite, thomsonite, the porcelain laubanite, light thin zeolite, erionite, single zeolite, zoisite, thaumasite, wollastonite, okenite, plazolite, hibschite, heulandite, euthalite, scolecite, stilbite, edingtonite, stilbite, lomontite, zeolite, aksaite, szaibelyite, carbon boron-calcium-magnesium stone, calciborite, howlite, pinnoite, Ke's hydrotalcite, the tremolite, hypersthene, the iron sepiolite, lazulite, vermiculite, bronzite, chlorite, nephrite, sepiolite, the iron magnesium amphibole, brown spar, amesite, vesuvianite, Tremoliteor Tremoliteasbestos, fine magnesite, brucite, anhydrous carnallite, Dou chlorite, rhombspar, ferrodolomite, gypsum, calcium phosphate, calcite, cancrinite, brushite, prehnite, aspidelite, zoisite, pistacite, callainite, halloysite, andaluzite, pyrophyllite, the iron halloysite, illite, chamosite, feldspar, Juanyingshi, montmorillonite, albite, potash feldspar, amarantite, the monocline modumite, delvauxite, ilmenite, monheimite, zinc～botryogen, carbon sodium rankinite, zincocopiapite, sauconite, smithsonite, hydrozincite, aurichalcite, copper lazur, brochantite, chrysocolla, oblique side's malachite, dioptase, orthite, rinkolite, nepouite, chlorite rises, the phosphorus-aluminium-strontium alum, perlite, the foam powder, opal, diatomite, white mica, biotite, phlogopite, calcium aluminate, the iron calcium aluminate, coal dust, mud coal, lime mudrock, granulation composition after one or more pulverization process of mud flag etc. or be easy to the atomizing granular composition;

(e) elastomerics, plastics are used reinforcement weighting material class material always, include but not limited to: damaged tire, waste tape, the scrap rubber pipe, the charcoal type curing composition of one or more destructive distillation gained of useless macromolecule material products such as useless shoes, carbon black, light calcium carbonate, white carbon black, lithopone, kaolin powder, gypsum, vermiculite power, Strontium Sulphate, barium sulfate, wollastonite powder, staple fibre, the charcoal fiber, secondary calcium phosphate, calcium phosphate, Calcium Fluoride (Fluorspan), strontium fluoride, barium fluoride, magnesium fluoride, secondary magnesium phosphate, silicic acid, Calucium Silicate powder, strontium silicate, barium silicate, barium carbonate, antimonous oxide, zinc borate, aluminium hydroxide, magnesium hydroxide, lime, granulation composition after one or more efflorescence of calcium hydroxide etc. are handled;

(f) the calcining rear surface is the particulate class material of crude hard shape, include but not limited to: calcined kaolin powder, calcinated argil, calcined diatomite, flyash, calcining attapulgite, calcining wilkinite, the granulation composition after one or more efflorescence of cenosphere powder etc.;

(g) polycrystalline state compound composition class material; Include but not limited to: comprise by one or more efflorescence things of above-mentioned (1) (a) and (b), (c), (d), (e), (f) material and the granulation composition after one or more efflorescence of the atypical material that aqueous phase combines again, described atypical material, its general formula is:

∑ai Di·∑bi Ei·Z H2O，

∑ ai in the general formula, ∑ bi, Z, be a mole indeterminate coefficient, wherein ∑ ai, Z can be zero, and ∑ bi must not be zero;

The expanded formula of general formula is:

[a1D1·a2D2......anDn·b1E1·b2E2......bmEm·ZH2O]

Or [∑ ai (D1, D2......Dn) ∑ bi (E1, E2.......Em) ZH2O],

D1 in the general formula expanded formula, D2......Dn are one or more the powder in aforementioned (1) (a) and (b), (c), (d), (e), (f) material, E1 in the general formula, E2......Em are following listed compound newly-generated in liquid, include but not limited to:

Calcium sulfate, secondary calcium phosphate, calcium phosphate, Calcium Fluoride (Fluorspan), strontium fluoride, barium fluoride, magnesium fluoride, magnesium hydroxide, magnesiumcarbonate, secondary magnesium phosphate, silicic acid, Magnesium Silicate q-agent, Calucium Silicate powder, strontium silicate, barium silicate, pure aluminium silicate, zinc silicate, zinc carbonate, zinc subcarbonate, zinc phosphate, basic zinc sulfate, zinc sulphide, zinc hydroxide, aluminium hydroxide, ironic hydroxide, alkali formula iron(ic) chloride, ferric subsulfate, Strontium Sulphate, barium sulfate, metatitanic acid, (without incinerating) lithopone, boric acid, metaboric acid, sodium tetraborate, zinc borate, barium metaphosphate, aluminum borate, citrate of lime, calcium lactate etc. and barba hispanica, ultramarine, titan yellow, zinc yellow, lithol red, phthalocyanine is red, phthalocyanine blue, phthalocyanine green, the combination of one or more in the pigment such as fluorescent yellow;

Contain waste elastomer with the pulverizing mechanism of rubber normal temperature or/and plastics when being narrower than of 95%～70% scope equals 90 purpose fine rubber powder mixtures, aforementioned (1) allocated in the reclaiming aid group (a)～(g) seven materials with contain about 5 orders～be coarser than 200 purpose grain powders to be advisable, especially with about 5 orders～be coarser than and equal 40 purposes to be easy to pulverized pellet be good, saidly be easy to pulverized pellet, be milled to be narrower than and equal 200 order person degree of being once being crossed machine by the rubber fine pulverizer;

If before building stones mill in small, broken bits, employing have series connection just, in the large-scale pulverizer preparation of mining industry of broken function contain elastomerics or/and plastics when 30%～5% mixture, reclaiming aid group, Synergist S-421 95 are mainly aforementioned (1) (a)～(g) seven, and when handled mixture can not be clamminess conglomeration, the grain size that aforementioned material is gone into machine can be as big as decimeter grade;

(h) the not sticking class material of wetting ability; Include but not limited to: the silicic acid that gel does not dewater as yet, the sesbania gum that gel does not dewater as yet, lotus root starch water is stuck with paste, and carboxymethyl cellulose water is stuck with paste, and is taken at mung bean, pea, broad bean, red bean, sweet potato, corn and other starches and contains one or more combination in the glue etc.;

According to design of the present invention, aforesaid (1) essential component, the auxiliary material that is easy to be liquefied also should comprise: (i) saponification, emulsification class material, (j) odorless tenderizer class material; Wherein,

(i) saponification, emulsification class material comprise: alkali or alkali and tensio-active agent material;

Described alkali includes but not limited to: the combination of one or more in sodium hydroxide, potassium hydroxide, yellow soda ash, salt of wormwood, the calcium hydroxide etc.;

Described tensio-active agent comprises:

The combination of one or more in aniorfic surfactant, nonionic surface active agent, the amphoteric surfactant;

Wherein said aniorfic surfactant, include but not limited to: saponification rosin, saponification shellac, stearic saponified, fatty is saponified, aerosol-OT salt, 1,2-dibutyl naphthalene-6-sodium sulfonate, oleic acid normal-butyl sulfuric ester sodium salt, ricinoleate acid butyl sulfuric ester two (or three) ethanolamine salt, N-oleoyl N-methyltaurine sodium, sodium lauryl sulfate, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, alkyl sodium sulfonate, sodium alkyl benzene sulfonate, the polyoxyethylene alkyl ether sulfate sodium salt, the benzyl naphthalene sodium sulfonate, alizarin assistant, the dinaphthylmethane sodium disulfonate, dispersing agent MF, the condenses of benzyl naphthalene sodium sulfonate and formaldehyde, potassium alkyl phosphate, the lauryl alcohol phosphate kalium salt, soap, the combination of one or more in the soap stock etc.;

Wherein said nonionic surface active agent includes but not limited to: the ethylene oxide condensate of C7～C9 straight chain fat, Oleum Cocois alkyl oxalamide, fatty alcohol-polyoxyethylene ether, the fatty alcohol-polyoxyethylene ether of C12～C18, the dodecyl phenol polyethenoxy ether, octane phenol Soxylat A 25-7--10, the polyethylene Viscotrol C, the sorbitan oleic acid polyoxyethylene, sorbitan stearate, sorbitan monooleate, the sorbitan stearate Soxylat A 25-7, polypropylene glycol and ethylene oxide adduct, polyoxyethylated coconut oil alcohol, the combination of one or more in the Triton X-100 etc.;

Wherein said amphoteric surfactant includes but not limited to: the combination of one or more in N-dodecyl L-Ala, the empgen BB etc.;

Wherein, (j) odorless tenderizer class material; At least comprise following one or more material:

(j～a) oil plant benevolence, fruit material, (and j～b) vegetables oil, resin and derivatives class material, (j～c) contains grease decolouring slag mud class material, and (rubber of j～d), moulds tenderizer commonly used; Wherein,

(j～a) oil plant benevolence, fruit material, include but not limited to: tung oil tree benevolence, Fructus oleae europaeae benevolence, coconut benevolence, cotton seed benevolence, vegetable seeds, Semen arachidis hypogaeae, soybean, Fruit of Fortune Windmillpalm benevolence, Safflower fruit, Semen Helianthi, Cha Ziren, Semen Lini, perillaseed benevolence, rubber seed benevolence, Fructus oleae europaeae meat, Semen Sapii benevolence, Wood of Shinyleaf Yellowhorn benevolence, ansu apricot benevolence, hair Lai, fibert, Chinese pistache, chinaberry, walnut kernel, samara oil tree benevolence, the combination of one or more of immature pine nut etc.;

(the vegetables oil of j～b), resin and derivatives class material include but not limited to: Fructus Maydis oil, Rice pollard oil, oleum gossypii seminis, rape seed oil, peanut oil, soybean oil, plam oil, Oleum Helianthi, sweet oil, tea-seed oil, coconut benevolence oil, tung oil, Toenol 1140, Semen Sapii benevolence oil, perilla oil, the restaurant refiltered oil, rosin, alizarin assistant, staybelite, westvaco rosin, ester gum, pentalyn, the dimethylbenzene Gum Rosin, rosin ester, the pine tree resin, the metasequoia resin, the elm resin, the peach resin, the combination of one or more of useless peanut paste etc.;

(j～c) contain grease decolouring slag mud class material includes but not limited to: the gac of the oil-containing that grease, refinery decolorizing purification workshop section dump, fat, lipid acid etc. or the slag mud of carclazyte, the foam oil slick of deviating from the recycled writing paper production that contains printing ink;

(j～d) rubber and plastic is used tenderizer always, includes but not limited to: lubricating oil, machine oil, white oil, halogenated paraffin oil, paraffin oil, third fractional oil, six line oil, transformer oil, polybutene oil, C4～18 lipid acid, Vaseline, halogenated paraffin, paraffin, beeswax, animal oil, dark substitute, white factice, odorless bitumen, epoxy soybean oil, alkyl phenolic resin, the rare resin of terpene, petroleum resin, special octyl phenol urea formaldehyde, coumarone, styrene resin, low-molecular polyethylene wax, low-molecular polypropylene wax, stearic acid, Palmiticacid, oleic acid, palmitinic acid, polyvinyl alcohol, amylalcohol, hexanol, enanthol, octanol, decyl alcohol, lauryl alcohol, tetradecyl alcohol, hexadecanol, stearyl alcohol, cyclopentanol, hexalin, phenylcarbinol, ethylene glycol, propylene glycol, glycerol, 2-Ethylhexyl Alcohol, sec-n-octyl alcohol, lauryl alcohol, Terpineol 350, (C7～18) mixed fatty alcohol, tetramethylolmethane, Xylitol, dipropylene glycol, dibutyl phthalate, diisobutyl phthalate, dialphanyl phthalate, tributyl phosphate, triethyl phosphate, triphenylphosphate, Tritolyl Phosphate, di(2-ethylhexyl)phosphate phenyl-2-ethylhexyl, the terephthalic acid dibutyl ester, the hexanodioic acid dibutyl ester, hexanodioic acid two-2-(ethyl hexyl) ester, the combination of one or more of sebacic acid two-2-(ethyl hexyl) ester etc.;

Described odorless tenderizer class material does not wherein comprise: coal tar, Stockholm tar, aromatic hydrocarbon oil, Yatall MA, have pisselaeum, rubber cracking wet goods to have smelly and the tenderizer of hypertoxic class is arranged;

Above-mentioned (1) (a) and (b), (c), (d), (e), (f), (g) these materials must be anticipated and be become to be difficult for to fly upward and be easy to about pulverized 200mm～be coarser than 200 purpose pieces, grain, powder again, especially be good to be easy to about pulverized 5 orders～to be coarser than equaling 40 purpose pellets, said being easy to pulverized, and is milled to be narrower than and equals 200 order persons for good once being crossed machine by the rubber fine pulverizer; For contained fiber material in (1) (a) and (b), (c), (d), (e), (f), (g) these materials, be milled to be narrower than and equal 60 order persons for good once being crossed machine by the rubber fine pulverizer; Must implement feed intake operation with the form of packing material for material that should not granulated processed in (1) (a) and (b), (c), (d), (e), (f), (g) these materials; (1) (a), (b), (c), (d), (e), (f), (g) these material combinations must can be controlled at final masterbatch, PH in the rubber master batch product is 5～12, especially be good with PH=5～9, and having PH resiliency person with the material after the combination is the best, its weight consumption can be 0～1900 part of (butt)/100 part (in waste elastomer rubber powder weight basis) range, add fashionable in the first step, preferable amount ranges is: 2～43 parts of (butt)/100 part (in the old rubber and plastic weight basis of abandoning) or be: part (in the old rubber and plastic weight basis of abandoning) these two intervals, 400～900 parts of (butt)/100, and easily efflorescence material consumption in the reclaiming aid group is that 0～100% scope is advisable by weight; Above-mentioned granular material can be moisture, because product of the present invention can be heated and generate heat in the course of processing, an amount of water arranged, the incipient scorch in the time of can preventing some sizing material of dry process; Above-mentioned (1) (i) saponification, emulsifying agent, its weight consumption can be 0～10 part of (butt)/100 part (in the old rubber and plastic weight basis of abandoning) range, consumption is that 0～100% scope is advisable by weight in the reclaiming aid group; Above-mentioned (1) (j) weight content of odorless tenderizer class material in masterbatch, rubber master batch product is: 0～30%, but be good with 3～20%; It is 5.3～1900 parts of (butt)/100 part (in the old rubber and plastic weight basis of abandoning) that above-mentioned ten sums of (1) (a) and (b), (c), (d), (e), (f), (g), (h), (i), (j) add fashionable in the first step, promptly (1) (a)～(j) initial amount of ten sums must not be zero simultaneously.

Said reclaiming aid group material, wherein (2) choosing adds component, has the macromolecule material of grafting functional or the reactive monomer of emulsion form, comprises following one or more material at least:

(a) rubber (b) plastics, (c) reinforced resin, (d) resin emulsion, (e) rubber latex, (f) odorless bitumen;

Wherein said (b) plastics include but not limited to: the bits, bar, grain, powder, the coating materials that are recovered after polyvinyl chloride, chlorinatedpolyethylene, polyethylene, polypropylene, polystyrene, ethylene-ethyl acetate copolymer, urethane etc. and these plastics products are discarded;

Wherein said (c) reinforced resin includes but not limited to: resol, polyvinyl acetal resin, urethane etc.;

Wherein said (d) resin emulsion includes but not limited to: ACRYLIC EMULSION, vinyl acetate emulsion, polyvinyl acetal emulsion etc.;

Wherein said (e) rubber latex includes but not limited to: nature rubber latex, synthetic rubber latex;

Wherein said (f) odorless bitumen includes but not limited to: odorless oxidized bitumen, odorless highway asphalt, odorless emulsion pitch, odorless rubber plastics modified bitumen.

Said reclaiming aid group material, (2) choosing wherein adds component, has the macromolecule material of grafting functional or the reactive monomer of emulsion form, and its (2) (a)～(f) five sum add-ons are: 0～15/100 part (in the old rubber and plastic weight basis of abandoning).

Said reclaiming aid group material, wherein (3) choosing adds component, and friction resistant lubricant class material comprises following one or more material at least:

(a) cationic surfactant, (b) aniorfic surfactant, (c) nonionic surface active agent, (d) amphoteric surfactant, (e) silicone based material, and the tensio-active agent that (f) comes from plant fully; Above-mentioned friction resistant lubricant, its consumption account for 0～5% of the free-water amount in the material handling of being reproduced by weight, are good with 0.2%～5%, or account for to be reproduced and handle 0～3% of solid substance, are good with 0.2%～3%; Wherein said:

(a) cationic surfactant includes but not limited to: stearyl dimethyl benzyl ammonium chloride, dodecyl benzyl dimethyl ammonium chloride, trolamine list olein, alkyl phosphate di-alcohol ammonium salt, octadecyl dimethyl hydroxyethyl season ammonium salt, trihydroxyethyl quaternary ammonium Methylsulfate etc. one or more combination;

(b) aniorfic surfactant, include but not limited to: saponification rosin, saponification shellac, stearic saponified, fatty is saponified, aerosol-OT salt, 1,2-dibutyl naphthalene-6-sodium sulfonate, oleic acid normal-butyl sulfuric ester sodium salt, ricinoleate acid butyl sulfuric ester two (or three) ethanolamine salt, N-oleoyl N-methyltaurine sodium, sodium lauryl sulfate, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, alkyl sodium sulfonate, sodium alkyl benzene sulfonate, the polyoxyethylene alkyl ether sulfate sodium salt, the benzyl naphthalene sodium sulfonate, alizarin assistant, the dinaphthylmethane sodium disulfonate, dispersing agent MF, the condenses of benzyl naphthalene sodium sulfonate and formaldehyde, potassium alkyl phosphate, the lauryl alcohol phosphate kalium salt, soap, the combination of one or more of soap stock etc.;

(c) nonionic surface active agent includes but not limited to: the ethylene oxide condensate of C7～C9 straight chain fat, Oleum Cocois alkyl oxalamide, fatty alcohol-polyoxyethylene ether, the fatty alcohol-polyoxyethylene ether of C12～C18, the dodecyl phenol polyethenoxy ether, octane phenol Soxylat A 25-7--10, the polyethylene Viscotrol C, the sorbitan oleic acid polyoxyethylene, sorbitan stearate, sorbitan monooleate, the sorbitan stearate Soxylat A 25-7, polypropylene glycol and ethylene oxide adduct, polyoxyethylated coconut oil alcohol, the combination of one or more of Triton X-100 etc.;

(d) amphoteric surfactant includes but not limited to: the combination of one or more of N-dodecyl L-Ala, empgen BB etc.;

(e) silicone based material includes but not limited to: the combination of one or more of methyl-silicone oil, ethyl silicon oil, methyl phenyl silicone oil, two-[3-triethoxyl silane propyl group] tetrasulfide, r-sulfydryl propyl trimethoxy silicane, dimethyldimethoxysil,ne, methyltrimethoxy silane, methyl triacetoxysilane, Union carbide A-162, tetramethoxy-silicane, tetraethoxysilane, dimethyldiethoxysilane etc.;

(f) come from the tensio-active agent of plant fully, include but not limited to: the combination of one or more of the water extraction of Leaf of Shrubalthea, the water extraction of Chinese honey locust, the water extraction that will is far away, the water extraction of balloonflower root, the water extraction of sea-tangle etc.;

Said (3) choosing adds component, and friction resistant lubricant class material also can comprise following one or more material:

(g) wax class, (h) organic acid and its esters; Wherein,

Said (g) wax class includes but not limited to: the combination of one or more of halogenated paraffin, paraffin, beeswax, low-molecular polyethylene wax, low-molecular polypropylene wax etc.;

Said (h) organic acid and its esters include but not limited to: the combination of one or more of stearic acid, Zinic stearas, barium stearate, calcium stearate, strontium stearate, Magnesium Stearate, lipid acid barium, fatty acid magnesium, fatty acid calcium, lipid acid strontium, barium laurate, calcium laurate, ricinolic acid barium, ricinolic acid calcium, zinc ricinate, barium naphthenate, calcium naphthenate, zinc resinate etc.;

Said reclaiming aid group material, (3) choosing wherein adds component, friction resistant lubricant class material, its (3) (a)～(h) eight sum add-ons are: 0～10/100 part (in the old rubber and plastic weight basis of abandoning).

Said reclaiming aid group material, wherein said (4) choosing adds component, the disconnected sulphur activator class material of odorless, comprise one or more the material that is selected from the following A group (have and to play chain scission and not generate hydrogen sulfide again in pH5～14 scopes) to the elastomerics sulfide linkage, or A and be selected from the following B group material one or more, or A and B and be selected from the following C group material one or more; Above-mentioned said odorless desulfurization activator class material is mixed by following weight ratio and forms,

A group/B group/C group=100～2%/0～98%/0～98%, its consumption is: 0.1～5 part/100 parts (in tire glue powder or the old vulcanized elastomer rubber powder weight basis of abandoning) is for good;

Wherein said A group material, include but not limited to: potassium ferric oxalate, Ferrox, ironic oxalate, zinc, caoxalate, calcium peroxide, hydrogen peroxide calcium sulfate adducts, hydrogen peroxide sodium sulfate, hydrogen peroxide copper sulfate, zinc oxalate, Ferrox zinc, bodied ferric sulfate, Sulfothiorine, S-WAT, sodium bisulfite, ferrous sulfate zinc, alkali formula iron(ic) chloride, iron protochloride, cerous hydroxide, Cerium monophosphate, ferric subsulfate, ferrous sulfate copper, zinc chloride, zinc silicate, zinc carbonate, zinc subcarbonate, zinc phosphate, basic zinc sulfate, zinc hydroxide, phosphoric acid hydrogen is ferrous, phosphoric acid one hydrogen zinc, the ferrous zinc of phosphoric acid hydrogen, the ferrous copper of phosphoric acid hydrogen, zinc sulfate, copper sulfate, copper hydroxide, cupric phosphate, nickel hydroxide, nickelous carbonate, rose vitriol, the ferrous zinc of sylvic acid, sylvic acid is ferrous, zinc abietate, the sylvic acid cobalt, zinc naphthenate, cobalt naphthenate, the lipid acid cobalt, fatty acid zinc, Zinic stearas, Zinc Gluconate, Ferrous Gluconate zinc, zinc laurate, zinc palmitate, calglucon, glucose, waste molasses, ventilation breather, the peacock stone flour, zinc powder, aluminium powder, the aluminium foil bits, the nano level copper powder, nano grade iron powder, cupric oxide powder, leaded plastic waste, contain the cadmium plastic waste, it is leaded or/and the plastic waste of cadmium is done the slide slag, contain chromium scrap leather bits, contain chromium shark bone glue, the refuse battery crushed material, metatitanic acid, the quadrol tetrem is ferrous, xitix, Magnesium ascorbate, the tetramethyl-ammonium halide, hexadecyl ethyl dimethyl ammonium halide, hexadecyl methyl diethyl ammonium halide, monobutyl dimethyl benzyl ammonium halide, the octadecyl ammonium halide, 3,5-dimethylphenyl benzyl ammonium halide, the dimethyl diphenyl ammonium halide, methylethyl propyl group isobutyl-ammonium halide, the tetradecyl trimethyl-ammonium halide, tetradecyl dimethyl ammonium halide, cetyl dimethyl benzyl ammonium halide, hexadecyl halogenation pyridine, tetradecyl halogenation pyridine, dodecyl halogenation pyridine, tetrabutyl halogenation pyridine, ethyl dixylyl ammonium halide, oil base dimethyl benzyl ammonium halide, hexadecyl ethyl dimethyl ammonium halide, 2-thiol benzothiazole zinc, benzene a pair of horses going side by side thiazolyl disulphide, N-cyclohexyl-2-benzene a pair of horses going side by side thiazole sulfinyl amine, the N-tertiary butyl-2-benzene a pair of horses going side by side thiazole sulfinyl amine, ziram, zinc diethyldithiocarbamate, the dipropyl zinc dithiocarbamate, zinc dibutyl dithiocarbamate, zinc dibenzyldithiocarbamate, blue female disulphide of tetraethyl-autumn, blue female disulphide of tetramethyl-autumn, blue female disulphide of tetrabenzyl autumn, N, N '-diphenylguanidine, di-o-tolyl guanidine, 4,4 '-dithiomorpholine, the combination of one or more of zinc dibutyldithiophosphate etc.;

B organizes material, includes but not limited to: the combination of one or more of rosin, staybelite, dimethylbenzene Gum Rosin, special octyl phenol urea formaldehyde, coumarone, alizarin assistant, oleum gossypii seminis, rape seed oil, peanut oil, soybean oil, plam oil, Oleum Helianthi, sweet oil, tea-seed oil, paraffin, stearic acid, beeswax, rubber, desulfurization plasticizing rubber powder, thermoplastic elastomer etc.;

C organizes material, includes but not limited to: the combination of one or more of semi-hydrated gypsum powder, potter's clay powder, calcium sulfate dioxide composite Si powder etc.;

Said reclaiming aid group material, (5) choosing wherein adds component, antioxygen anti-aging agent class material, at least comprise and be selected from down in the listed material one or more, its consumption is 0～5 part/100 parts (in the old rubber and plastic weight basis of abandoning), but for good, said antioxygen anti-aging agent class material includes but not limited in 0.1～5 part/100 parts (with the old rubber and plastic weight basis of abandoning):

N-phenyl-αNai An (abbreviation antioxidant A), 3 acetaldols-2-naphthylamines (being called for short antioxidant A H), 3 acetaldols-2-naphthylamines (being called for short antioxidant A P), styrenated diphenylamine (being called for short antioxidant D FC-34), 4,4 '-two (α, α-Er Jiajibianji) pentanoic (being called for short anti-aging agent KY-405), octylated diphenylamine (being called for short anti-aging agent ODA), N-phenyl-B-naphthylamines (abbreviation antioxidant D), mix two aromatization pentanoic (being called for short anti-aging agent WH-02), N-cyclohexyl-p-ethoxyaniline (being called for short anti-aging agent CEA), N-cyclohexyl-P-nethoxyaniline (being called for short anti-aging agent CMA), N-cyclohexyl-p-ethoxyaniline (being called for short anti-aging agent CEA), N-phenyl-N '-cyclohexyl Ursol D (being called for short antioxidant 4010 or CPPD), N-phenyl-N '-sec.-propyl-Ursol D (being called for short antioxidant 4010NA or IPPD), N-(1, the 3-dimethylbutyl)-N '-diphenyl-para-phenylene diamine (being called for short anti-aging agent 4020), N, N '-two (1,4-dimethyl amyl group) Ursol D (being called for short anti-aging agent 4030), N-1,4-N '-dimethyl amyl group-N '-phenyl-Ursol D (being called for short anti-aging agent 4050), N, N '-phenylbenzene-Ursol D (being called for short antioxidant H or DPPD or PPD), N, N '-diphenyl-para-phenylene diamine (being called for short antioxidant D TPD or anti-aging agent 3100), N-secondary octyl-N '-diphenyl-para-phenylene diamine (being called for short anti-aging agent 688), the compound of N-secondary octyl-N '-diphenyl-para-phenylene diamine and anti-aging agent RD (being called for short anti-aging agent 8PPD), N, N '-two (betanaphthyl) Ursol D (being called for short antioxidant D NP), N-2-aminomethyl phenyl-N '-2-tolyl Ursol D, N-2-aminomethyl phenyl-N '-2, the 6-dimethyl-p-phenylenediamine, N-2,6-3,5-dimethylphenyl-N '-2,6-3,5-dimethylphenyl blend of p phenylene diamine (being called for short anti-aging agent PPD-B), N-(p-methylphenyl alkylsulfonyl)-N '-diphenyl-para-phenylene diamine (being called for short anti-aging agent TPPD), N-phenyl-N '-(3-methacryloyl oxo-2-hydroxypropyl) Ursol D (being called for short anti-aging agent G-1), acetone and pentanoic low-temp reaction thing (being called for short antioxidant A M), acetone and pentanoic pyroreaction thing (abbreviation antioxidant BLE), 6-oxyethyl group-2,2,4-trimethylammonium-1,2-dihyaroquinoline (being called for short antioxidant A W), 2,2,4-trimethylammonium-1,2-dihyaroquinoline (abbreviation aging inhibitor FR), 2,2,4-trimethylammonium-1,2-dihyaroquinoline polymer (abbreviation anti-aging agent RD), Resorcinol benzyl oxide (being called for short antioxidant MB A), hydroquinone dibenzyl ether's (abbreviation antioxidant DBH), N, N, N ', N '-tetraphenyl diamino methane (being called for short anti-aging agent 350), 1,3,5-trimethylammonium-2,4,6-three (3, the 5-di-tert-butyl-4-hydroxyl benzyl) benzene (being called for short anti-aging agent 330), 2,6-di-tert-butyl-4-methy phenol (abbreviation antioxidant 264), the mixture of one hydrocarbonylation bis-phenol (being called for short anti-aging agent 651), styrenated phenol (abbreviation antioxidant SP), 2,2 '-methylene-bis (4-methyl-6-tert butyl phenol) (abbreviation antioxidant 2246), 4,4 '-butyl-two (3 methy 6 tert butyl phenol) (being called for short anti-aging agent W-300), 1,1,3-three (2-methyl-4-hydroxyl-5-tert.-butyl phenol) butane (being called for short anti-aging agent CA), 2,2,6-di-tert-butyl-4-methy phenol (abbreviation antioxidant 264), 2-thiol group benzimidazolyl (abbreviation antioxidant MB), 2-thiol group benzimidazolyl zinc salt (being called for short antioxidant MB Z), Tyox B (abbreviation anti-oxidant DLTP), three (nonyl phenyl) phosphorous acid ester (being called for short anti-aging agent TNP), three (2, the 4-di-tert-butyl-phenyl) phosphorous acid ester (is called for short anti-aging agent 168, TBP), the dibutyl disulfide group is for carboxylamine nickel (abbreviation antioxidant NBC), phosphorous acid benzene di-isooctyl, phosphorous acid dihydroxyphenyl propane ester, hydrazonium sulfate, titanyl sulfate, ferrous sulfate, iron protochloride, ferrous ammonium sulphate, oxammonium hydrochloride, tri-isopropanolamine, the combination of one or more of oxalic acid etc.;

Reclaiming aid group of the present invention, Synergist S-421 95, comprise interim preparation or/and becomes through preprocess, and they all can become independently auxiliary agent category product; Said reclaiming aid group is used by aforementioned material and is formed preparation recently or production in advance by following weight, and its component comprises:

(1) be easy to be pulverized or liquefy but the auxiliary material that is difficult for flying upward: 5.3～1900 parts/100 parts (in waste elastomer or/and the plastics weight basis),

(2) reactive monomer of macromolecule material or emulsion form: 0～15 part/100 parts (in waste elastomer or/and the plastics weight basis),

(3) friction resistant lubricant class material: 0～10 part/100 parts (in waste elastomer or/and the plastics weight basis),

(4) the disconnected sulphur activator class material of odorless: 0～5 part/100 parts (in cross-linked rubber weight basis in the waste elastomer),

(5) antioxygen anti-aging agent class material: 0～5 part/100 parts (in waste elastomer or/and the plastics weight basis);

All kinds of material sum of the reclaiming aid group amount that processing step (1) adds is: 5.3～1900 parts/100 parts (in waste elastomer or/and the plastics weight basis).

Said Synergist S-421 95 in the processing step (2) wherein, its main component be powder auxiliary material or/and the tenderizer of odorless or/and the antioxygen anti-aging agent or/and macromolecule material class material, four sums account for 50.1～100% of Synergist S-421 95 total amount, and according to downstream industry processing needs, add about 49.9～0% one or more the functional material account for the Synergist S-421 95 total amount, said functional material is with said friction resistant lubricant class material in the reclaiming aid group, the desulfurization activator class material of odorless etc.

Said Synergist S-421 95 in the processing step (2) wherein, it is characterized in that, the powder auxiliary material that relates in the said Synergist S-421 95 in the processing step (2) is that a class has and fills or/and reinforcement, which comprises at least as previously mentioned one or more combination of listed material down or/and the powdery type auxiliary material of colouring function:

Material with peculiar smell adsorptivity, industrial slag great soil group material, vegeto-animal bone, leaf, root, stem, straw, bar, shell, skin break flour class material, inorganic mineral class material, elastomerics is used reinforcement weighting material class material always, the calcining rear surface is the particulate class material of crude hard shape, polycrystalline state compound composition class material, and said powdery type auxiliary material all will be anticipated the form that becomes to be difficult for airborne dust.

Because at the said waste elastomer of the present invention, in the plastics macromolecule material new method for regenerating, involved reclaiming aid group material or Synergist S-421 95 material do not use and contain cacodorous coal tar, Stockholm tar, Yatall MA, aromatic hydrocarbons wet goods contaminative material, powdery type auxiliary material is wherein all anticipated the form that becomes to be difficult for airborne dust, so the present invention is said to can be used as and independently auxilliaryly joins reclaiming aid group that the auxiliary agent material uses or Synergist S-421 95 material and by the product of the regeneration process and the output of its cooperation, naturally just do not have coal tar, Stockholm tar, Yatall MA, the smell of aromatic hydrocarbons wet goods nuisance and content rising problem do not have airborne dust yet.

In aforesaid method, said processor is meant one or more combination of following equipment:

The stirring desulphurization jar that uses in water or the water/oil method regenerated rubber technology etc., or the dynamic and static digester that uses in the oil process regenerated rubber technology etc., or the pulverizer that uses in the normal temperature crushing up glue powder craft, the mining pulverizer of stone material, the wind-force pulverizer, Deng, or rubber, mould the mill used in the processing, Banbury mixer, forcing machine, stirring mixer etc., and various mining industry or rubber, mould with the unit equipment that carries out abrasive dust, mixing, compressing tablet, granulation operation on the powder auxiliary production line etc.

A kind of combined machine in small, broken bits that has meticulous slimer also is provided in the method for the invention, it is characterized in that comprising the combination that contains one or more settings as described below:

A. before the unit in small, broken bits or/and after be provided with the machinery that can add auxiliary material;

B., the fine crusher cohort setting that can be divided into many groups is arranged;

C. many groups feeding pipe of fine crusher cohort is provided with feed rate and compares setting device;

D. have and thick, the fine powder material that classification, sieve apparatus are selected to be collaborated and return for the machinery setting of pulverizing;

E. the abrasive dust working face of the new pulverizing cutterhead of rubber normal temperature fine pulverizer is provided with the surface of crudeization;

F. have behind the combined machine of one of five of aforesaid feature a.～e. or five feature setting and be equipped with the setting that more is tending towards perfect again;

Specifically, wherein, a. before the unit in small, broken bits or/and after be provided with the machinery that can add auxiliary material, the mechanism of described adding auxiliary material, at least be the device that has the weighing of a unitary energy, described weighing device can be the scale that can weigh or bucket, groove, the pipe of measuring volume, quantitatively screw rod conveyor, or their combination;

The mechanism of described adding auxiliary material, also be to have a unitary auxiliary material that can make adding and micelle, rubber powder blended mechanism mutually at least, described auxiliary material and micelle, rubber powder be the blended mechanism mutually, can be bucket, groove, the pipe that has band to stir, or shell can be done bucket, groove, the pipe of rotation, or their combination;

The mechanism of described adding auxiliary material is good with what have airtight dustproof construction;

Wherein, b. has the fine crusher cohort settings that can be divided into many groups, and its feature comprises: having one can be the fine crusher cohort that is divided into three groups of two groups of A, B or A, B, C at least;

Described fine crusher cohort, three groups of two groups of A wherein, B or A, B, C, every group contains a unit fine crusher at least;

Described A, B, C unit in small, broken bits all are in parallel in it is organized separately, connect 5～40 order coarse fodder storehouses on the A group, connect the pulverizing of A group, tailover feed back pipeline on B organizes, and connect the pulverizing of B group, tailover feed back pipeline on the C group; The outlet that two groups of A, B or A, B, C are three groups can be parallel connection, and its outlet in parallel connects classification, sieving machine down behind spiral separator; The outlet of B, C group can be not in parallel with the outlet of A group yet, and it exports separately can walk around classification, the through fine powder storage bin of sieving machine; The outlet of B, C group also can both join classification, sieving machine by valve pipeline, through again fine powder storage bin;

Described fine crusher cohort, the production capacity configuration characteristics between its unit are: be divided into two groups, its preferable production capacity configuration than scope is: A/B=2/1～9/1; Be divided into three groups, its preferable production capacity configuration than scope is: A/B/C=1/1/1～5/3/1;

Wherein, many groups feeding pipe of c. fine crusher cohort is provided with feed rate than setting device, its feature comprises: fine crusher is divided into two groups of A, B, and its feed rate than regulation range is: A/B=2/1～9/1; Fine crusher is divided into three groups of A, B, C, and its feed rate than regulation range is: A/B/C=1/1/1～5/3/1;

Wherein, d. have and thick, the fine powder material that classification, sieve apparatus are selected to be collaborated and return for the machinery setting of pulverizing, its feature comprises: be provided with the meal material of not crossing 90～200 mesh sieves that can tell classification, sieve apparatus, cross the fine powder material interflow more than 250～350 orders with crossing, supply with 5～40 order batch mixes storehouses or B, the C group fine crusher mechanism pulverized of row more then;

Wherein, f. be provided with the setting that more is tending towards perfect again, its feature comprises: have to add after the described combination of features machinery of aforementioned a～e is provided with to make the ultra-fine elastomerics powder row machinery of reuniting again, described machinery includes but not limited to again: the combined machine of one or more of powder tablets press, screw extrusion press, rolling press, mill;

Described a kind of combined machine in small, broken bits that has meticulous slimer also can be used as independently product.

Product of the present invention; wherein: contain and oldly abandon rubber or/and the masterbatch of plastics 95%～5% or master batch or rubber master batch mixture; odorless is dustless or also have characteristics such as high anti-, wear-resisting, and the environment-friendly type secondary supplementary material that can be used as industries such as elastomerics, plastics uses.

Wherein the particle diameter of product is smaller or equal to 90 orders.

The aforesaid product of the present invention is that a kind of odorless is dustless, contains waste elastomer or/and the masterbatch of plastics 95%～5% or master batch or rubber master batch mixture contain waste elastomer and the old mixture of abandoning plastics 95%～5%, and other auxilliary ingredients accounts for 5%～95%; This is wherein especially containing waste elastomer and old plastics 95%～70% and 30%～5% abandoned, and it is good that other auxilliary ingredients accounts for the masterbatch in 5%～30% and 70%～95% both intervals or master batch or rubber master batch mixture; Waste elastomer in the mixture is (30～5) with the old plastics of abandoning with the ratio of the weight that feeds intake: (70～95) and (70～95): (30～5) both intervals;

The new product that the present invention proposes, its feature also comprises: under the hot extrude of downstream product industry, hot-forming condition, it can be mixed into one mutually fully with virgin material, promptly on the cutter cut surface of goods, can not see rubber powder granule, and under the hot-work condition of downstream product industry, odorless (being that smell is not more than new sizing material), also odorless under the room temperature.

The present invention proposes the new product of protection domain, and the direction of its application can comprise following one or more at least:

1. be used in elastomerics, plastic article industry, dust, odor pollution in the time of can eliminating batching and refining glue, heating;

2. be used in elastomerics, plastic article industry, can be used as functional auxiliary material or auxiliary agent and use;

3. be used in elastomerics, plastic reclaimed industry, can be used as the waste elastomer of low moral character, the goods support that the commercialization of plastics macromolecule material utilizes again;

4. be used in solid waste utilization industry, make the multiple waste of a plurality of industries obtain the collaborative utilization again of appreciating;

5. be used in elastomerics, plastics with auxiliary material or auxiliary agent production, can make product become masterbatch, master batch, rubber master batch formulation and reduce or eliminate airborne dust by the powder formulation;

6. prepare modifying asphalt, waterproof roll, paint, tackiness agent with it, and be used for rubber, mould fire retardant master batch, the rubber master batch of goods industries, look mother etc.

Description of drawings

Fig. 1 is a schematic flow sheet of the present invention;

Fig. 2 is the device synoptic diagram of the embodiment of the invention 14;

Fig. 3 is the device synoptic diagram of the embodiment of the invention 15

Embodiment

Further specify the content that meets the present invention's design with selected embodiment below, but should not be regarded as limiting the scope of the invention.

Embodiment 1.

Taking by weighing the waste elastomer granularity by weight is 100 parts in 20～30 purpose radial micelles, takes by weighing by 10 parts of isolated polyethylene (or/and polypropylene) plastics in the plastic-aluminum combined waste paper of Tetrapack (about 30 * 100) film bars, takes by weighing by the powdery type auxiliary material:

60 parts of charcoal type cured articles about 5 orders of damaged tire destructive distillation gained to 20 orders,

10 parts in alkali mud (soda factory dumps, and is to 20 orders, moisture 30% about PH＞9,10 orders, in butt),

5 parts of wilkinites (about 10 orders to about 20 orders),

10 parts of paper staple fibre slag spares (water purification workshop section of regeneration paper plant dumps, and pH=6 is about moisture 40%, 5 order, in butt),

85 parts of the reclaiming aid groups of forming; The PH of this kind reclaiming aid group system is 7～9, and has the PH resiliency;

Above-mentioned material is placed mixing of thick step of mix jar earlier, import in the shear-type disc type rubber normal temperature fine pulverizer by quantitative spiral conveying tube then and carry out grinding and processing, in this process, because the reclaiming aid group that adds is many and moisture, make the rubber in the mixture, particles is in pulverized process, material temperature is not crossed 100 ℃, it is the decomposition that temperature does not arrive plastics in the crushing process, plasticization temperature, the group of connecing so plastics can not be clamminess, in addition, again owing to the coating of a large amount of powders in the reclaiming aid group to rubber elastomer, buffer action, in pulverized process, reuniting can not appear in rubber yet, just is ground into 80% and is narrower than and equals 150 orders so rubber elastomer and polyethylene (or/and polypropylene) plastics are once crossed machine at an easy rate; Material after the machine of once crossing is pulverized through wind revolve or sieve classification after, the coarse fodder of crossing 90 mesh sieves can be collected in together and cross crossing fines and closing of 250 mesh sieves, can walk machineries such as placed in-line shear-type disc type rubber normal temperature ultrafine crusher then in addition, goes processing such as pulverizing again; If the coarse fodder after sifting out equals 90 orders with crossing fines and close and be ground into to be narrower than, then walk series connection in addition and pulverize mach product and can belong in the feed bin with aforementioned product;

In the powder mixture of above-mentioned processing step (1) processing gained, contain old rubber elastomer and the plastic waste 56.41% abandoned, contain reclaiming aid group 43.59% mixture, this powder mixture can be called as product 1 or masterbatch product in the present invention; If will reprocess, then this mixture also can be called intermediate product;

As going processing step (2) processing again, 195 parts of desirable above-mentioned intermediate products (in butt) take by weighing by odorless tenderizer, anti-aging agent etc.:

9 parts in transformer oil,

5 parts of rosin,

6-oxyethyl group-2,2,4-trimethylammonium-1,1 part of 2-dihyaroquinoline,

0.5 part of hexadecyl methyl diethyl ammonium halide

0.01 part of peregal-O,

6 parts in water,

Form, heat 15.51 parts of the aqueous Synergist S-421 95s of synthetic emulsification (in butt) through in advance.

Above-mentioned intermediate product and Synergist S-421 95 are placed mix jar mixing once again, this just obtains containing old rubber elastomer and the plastic waste 53.27% abandoned, the mixture that contains reclaiming aid group, Synergist S-421 95 46.73%, this mixture are also referred to as product 2 or masterbatch product in the present invention; As again this mixture being rolled in flakes, consider to be worth doing material through roll, then this sheet, bits material are called as rubber master batch, master batch product in the present invention;

Masterbatch, rubber master batch, the master batch product of this example gained behind processing step (2), the assorted waste rubber of waste elastomer wherein is 100: 10 with the ratio of the weight of plastic waste, waste elastomer rubber and plastic waste account for 53.27% in the masterbatch product, reclaiming aid group, Synergist S-421 95 46.73%, the product odorless, also do not have dust from flying, product can be used for the material set of the reinforcement/filling in the instead of rubber goods prescription.

It is worthy of note that the powdery type auxiliary material among the present invention all is to use the form that is difficult for causing airborne dust, this example at processing step (1) even the open operation of fill process, do not have dust pollution yet.

The shear-type disc type rubber normal temperature fine pulverizer that uses in this example, it is the pulverizer that a class is easy to pulverize softer material, efficiently handling that it is better contains waste elastomer or/and the compositing range of plastic waste and powder auxiliary material mixture is: contain waste elastomer or/and plastic waste accounts for 90%～70%, contain powder auxiliary material 10%～30%; Described powder auxiliary material required once the machine of crossing just can be ground into to be narrower than again to equal 200 orders, was advisable but can require once the mistake machine just can be ground into to be narrower than to equal 60 orders to the fiber in the powder auxiliary material.

The innovative point of this embodiment is: provided concrete odorless, the specific embodiment of dustless elastomerics, plastics fine glue powder masterbatch, rubber master batch, master batch and method for making thereof, its method for making feature is: the powder auxiliary material of going into machine all is difficult for airborne dust, and no longer requiring the powdery type auxiliary material must be to be narrower than to equal 200 orders.

Embodiment 2.

It is 5 parts in the assorted scrap rubber footwear micelle of 20～30 purposes that parts by weights another name is got the waste elastomer granularity, 100 parts of (about 30 * 100) film bars that just is broken into by agricultural waste polyethylene plastics mulch film; Take by weighing the powdery type auxiliary material:

10 parts of the vermiculite grains of calcining back (about 10 orders to about 20 orders),

100 parts of wilkinites (about 10 orders to about 20 orders),

10 parts of salt mud pellets (about the PH that chlor-alkali plant dumps＞9 10-20 orders, moisture 30%, in butt),

10 parts of sepiolites (about 10 orders to about 20 orders),

10 parts of the strontium slags that strontium saltworks dumps (about 10 orders to about 20 orders),

50 parts of paper staple fibre slag spares (the 5 order left and right sides PH=6 that regeneration paper plant water purification workshop section dumps moisture 40%, in butt),

100 parts of (about 10 orders to about 20 orders) bits grains of plant shell, leaf, root, stem, straw, bar, nuclear, skin dry distillation charring,

Decolouring inactivation gac is 100 parts in (about 10 orders to about 20 orders) grain bits or/and atlapulgite slag mud,

50 parts of cerolites (about 10 orders),

50 parts of wollastonites (about 10 orders to about 80 orders),

800 parts in diaspore (about 10 orders to about 20 orders) grain bits,

200 parts in brucite (about 10 orders to about 20 orders) grain bits,

1500 parts of the reclaiming aid groups of forming; The be mixed pH of back of powdery type auxiliary material in this example is not more than 9;

Above-mentioned material is placed mixing of thick step of mix jar earlier, import normally in the vertical refining mill of all kinds of breezes is ground in mining industry by spiral conveying tube then and pulverize, material imports in the collecting bin after the overground pulverizing of this processing step (1), obtains being narrower than equaling 200 purpose mixed powders; And then from collecting bin, get the product of this processing step (1)---1605 parts of mixed powders, and add 495 parts of the Synergist S-421 95s formed by chlorinated paraffinic oil again, in a mix jar, carry out the married operation of processing step (2); Material behind the mixing masterbatch product of the present invention;

This routine described masterbatch product, the assorted rubber of waste elastomer wherein is 5: 100 with the ratio of the weight of plastic waste, and assorted rubber of waste elastomer and plastic waste account for 5% in the masterbatch product, and reclaiming aid group, Synergist S-421 95 account for 95%; This routine described masterbatch product odorless does not have dust from flying yet, and product can be used for fire-retardant rubber such as grade, moulds the usefulness of making the filler masterbatch in the goods.

The innovative point of this embodiment is: provided concrete odorless, dustless rubber, mould the specific embodiment of fine glue powder masterbatch and method for making thereof, its method for making feature is: the powder auxiliary material of going into machine all is difficult for airborne dust, the vertical refining mill that has proposed all kinds of breezes of available mill also can be produced odorless, dustless elastomerics, plastics fine glue powder masterbatch.

Embodiment 3

It is 50 parts in assorted useless butadiene-acrylonitrile rubber micelle about 5 orders that parts by weights another name is got the waste elastomer granularity, 50 parts of (about about 5 orders) bits grains that is become by agricultural waste polyvinyl chloride plastics tubing coarse crushing; Take by weighing by the powdery type auxiliary material:

12 parts of the variegated material slag mud filter cakes (water content＜50%, filter cake footpath＜60cm is in butt) that printing and dyeing or pigment factory dump,

100 parts of the fibre-bearing slag mud filter cakes (water content＜70%, filter cake footpath＜60cm is in butt) that the paper mill dumps,

18 parts of silicon-dioxide composite gypsum filter cakes (filter cake footpath＜60cm is in butt for water content＜40%, PH＞7),

100 parts of (chlor-alkali plant dumps) salt clods (water content＜50%, PH＜11 footpath＜5cm is in butt),

1 part of cellulose sodium carboxymethyl,

231 parts of the reclaiming aid groups of forming; The be mixed pH of back of powdery type auxiliary material in this example is not more than 9;

Above-mentioned material is placed mixing of thick step of mix jar earlier, then it is poured in the brick press, make the adobe of about 50 * 10 * 20cm shape, again adobe is dried in the air in air seasoning place, treat that it is dried to water content approximately after＜15%, again the adobe material is dropped into alligator and obtain the particle of particle diameter less than 20mm, the airtight broken storage bin just of pouring into of particle, again the particle less than 20mm in the first broken storage bin is imported vertical mill meal machine, grind the coarse dust of particle diameter about less than 20 orders, coarse dust is imported in the coarse dust storage bin again, again the coarse dust in the coarse dust storage bin is imported vertical pulverized powder machine, grind particle diameter smaller or equal to 200 purpose mixed powders, get again at last this through 331 parts of the mixed powders of processing step (1) gained with by 10 parts of dioctyl phthalate (DOP)s, 5 parts of rosin, 100.01 parts of octane phenol Soxylat A 25-7s, the an amount of Synergist S-421 95 of forming of water, 15 parts (in solid substance) carries out the married operation of processing step (2) in another mix jar; Material behind the mixing masterbatch product of the present invention.

This routine described masterbatch product can obtain chromaticly, and its color depends on the color of the printing and dyeing of adding or the variegated material slag mud filter cake that pigment factory dumps and the collocation of colour of assorted useless butadiene-acrylonitrile rubber and waste polyvinyl chloride plastics; This routine described masterbatch product can be used for butadiene-acrylonitrile rubber or/and the batching of igelite based article; This routine described masterbatch product, the ratio of waste rubber wherein and plastic waste is 50: 50, and waste rubber and plastic waste account for 28.90% at product, and reclaiming aid group, Synergist S-421 95 account for 71.10% at product, product does not have dust from flying, mix with new product in its smell and control group no significant difference.

To this embodiment, what the inventor particularly pointed out is, waste elastomer micelle in this example, plastic waste bits grain can be with the brickmaking of powdery type auxiliary material, so more can grasp the maneuvering ability that the ratio between waste elastomer, plastic waste and powdery type auxiliary material changes, make the product of gained can better adapt to the demand in market, and the waste elastomer micelle that separates, plastic waste bits grain and reclaiming aid group material can be at first broken storage bin or/and the coarse dust storage bin be met, and products obtained therefrom is also similar.

In embodiment 2 and embodiment 3, all used common mining pulverizer, this pulverizer is open to coersion but not open to persuasion, it can efficiently be handled and contain waste elastomer or/and the compositing range of plastic waste and powder auxiliary material mixture is: contain waste elastomer or/and plastic waste accounts for 30%～5%, contain powder auxiliary material 70%～95%; And need not to consider the pulverizing difficulty of described powder auxiliary material, so with the essential component of the reclaiming aid group of mentioning in the aforesaid embodiment of the present invention contained (1), be easy to pulverized auxiliary material, can both be substituted into use by correspondence one by one as the classification of embodiment 2 and embodiment 3, described auxiliary material comprises following one or more material at least:

(a) has the material of peculiar smell adsorptivity, (b) industrial slag great soil group material, (c) vegeto-animal bone, leaf, root, straw, bar, shell, skin break flour class material, (d) inorganic mineral class material, (e) elastomerics reinforcement weighting material class material commonly used, (f) the calcining rear surface is the particulate class material of crude hard shape, (g) polycrystalline state compound composition class material.

Embodiment 4

It is 100 parts in useless oblique about 20～30 orders or radial micelle that parts by weights another name is got the waste elastomer granularity, use by system and cut out 5 parts of the waste polyethylene acetal plastics abandoned (about about 10～50 * 500) bars during splinter-proof glass, 5 parts of the agricultural broken films of waste polyethylene plastics (about about 500 * 500); Take by weighing by the auxiliary material that is easy to be liquefied materials such as antioxygen anti-aging agent class:

5 parts in machine oil,

5 parts of paraffin oils,

0.5 part in sodium hydroxide,

1 part in calcium hydroxide,

0.5 part of fatty alcohol-polyoxyethylene ether,

0.2 part of refuse battery crushed material (solid NI-G or/and zinc-manganese etc., be narrower than equal 200 orders),

4,0.5 part of 4 '-dithiomorpholine,

1 part of 2,6 di tert butyl 4 methyl phenol,

13.7 parts of the reclaiming aid groups of forming; (the reclaiming aid group mixture strong basicity in this example)

Above-mentioned material is placed water/oil method or the used withstand voltage stirred pot of dynamic method reclaimed rubber that is added with 8～12 parts of water earlier, carry out the operation of processing step (1), insulation is 2 hours after being heated to 200 ℃ while stirring behind the airtight withstand voltage stirred pot, controlled temperature is between 200～210 ℃ between soak, the blowing of lowering the temperature then; By the material of emitting as can be known, the damaged tire micelle has been reproduced alkali in the auxiliary agent group and the saponification of tensio-active agent institute, emulsification, plastic waste also after the fusion at high temperature by the emulsification of tensio-active agent institute, material pH is 13～14;

With above-mentioned middle mix products through 123.7 parts of alkalescence of processing step (1) operation gained, again with by powder auxiliary material:

Citric Acid Plant is (pH＜2, moisture about 30%, with Yu Jiji) 10 parts or/and the gypsum tailings mud that lactic acid factory dumps,

10 parts of the Synergist S-421 95s of forming, normally in mixing the open stirrer of usefulness of mortar, construction industry stirs evenly one, the operation of implementing process step (2), in stirrer, stir evenly in the blended process, the pH of available pH test paper test material, when the pH of material reduces to pH≤9 by strong basicity, but must not pH＜6 o'clock, show that the throwing amount of Synergist S-421 95 is suitable, if alkali partially still, can add Synergist S-421 95 more in right amount, material after stirring evenly places screw extrusion press or mill kneading again, again through the refiner refining, to eliminate the assorted grit in the sizing material, also roll film as reclaimed rubber then, blanking obtains plasticizing rubber and plastic mixing rubber master batch of the present invention;

In this rubber master batch, waste elastomer is 100: 10 with the ratio of the weight of plastic waste, and the weight of waste elastomer and plastic waste accounts for 82.27%, and the weight of reclaiming aid group, Synergist S-421 95 accounts for 17.73%;

The innovative point of present embodiment is: be tart solid Synergist S-421 95 with interpolation the alkali in the sizing material is neutralized, so can not produce a large amount of waste water as water/oil method preparation, regeneration glue; Used the desulfurization activator of odorless, the antioxygen anti-aging agent has guaranteed to save the carbon～carbon bond of rubber as much as possible from damage when destroying the vulcanized rubber cystine linkage; Used in the prescription to have high anti-, anti-tear, wear-resistant plastic waste, and the blending of plastic waste and waste rubber, high temperature emulsification fusion method adopted.

Embodiment 5

It is 100 parts in 20～30 order left and right sides radial micelles that the parts by weights another name is got the waste elastomer granularity, by cutting out 10 parts of the waste polyethylene acetal plastics abandoned (about about 10～50 * 500) bars during splinter-proof glass with system, 10 parts of the agricultural broken films of waste polyethylene plastics (about about 500 * 500); Take by weighing by powder auxiliary material and the auxiliary material that is easy to be liquefied, the desulfurization activator class material of odorless, antioxygen anti-aging agent class material:

50 parts of carbon blacks (N330, the whole packing of band adds),

5 parts of rosin,

10 parts in transformer oil,

15 parts of cottonseed benevolence,

0.5 part of fatty alcohol-polyoxyethylene ether,

4 parts in the mixture of sylvic acid iron zinc/semi-hydrated gypsum powder=1: 2,

1 part of 2,6 di tert butyl 4 methyl phenol,

85.5 parts of the reclaiming aid groups of forming;

Above-mentioned material is placed the used withstand voltage stirred pot of dynamic method reclaimed rubber that is added with 8～12 parts of water earlier, carry out the operation of processing step (1), add while stirring behind the airtight withstand voltage stirred pot, heat is incubated 2 hours after 200 ℃, controlled temperature is between 200～210 ℃ between soak, the blowing of lowering the temperature then; The material of emitting imports screw extrusion press by big funnel, squeezing sizing material that machine squeezes through screw rod is free in carbon black outside the micelle etc. in can be mixture and promptly kneads and can not stain production environment again, the sizing material that is squeezed by screw extrusion press is again through the refiner refining, roll film, blanking then obtains plasticizing rubber and plastic mixing rubber master batch of the present invention.

In this routine gained rubber master batch, waste elastomer is 100: 20 with the ratio of the weight of plastic waste, and the weight of waste elastomer and plastic waste accounts for 58.39%, and the weight of reclaiming aid group, Synergist S-421 95 accounts for 41.61%; This routine gained rubber master batch can be used for making rubber item.The innovative point of present embodiment is: in the high temperature regeneration operation, whole packing ground adds the carbon black with serious dust pollution, utilize the high temperature when regenerating and water condition is arranged, dissolve and destroy the sooty packing bag, plastics in the packing bag are by high-temperature fusion, paper in the packing bag all can be become the component in the product by water and molten mashed, the charing of high temperature; Water in jar has wet carbon black powder again, and material wherein carbon black when going out jar is not flown upward; Used in the prescription to have high anti-, anti-tear, wear-resistant plastic waste, and the blending of plastic waste and waste rubber, method is referred and synthesized in the high temperature emulsification when adopting regeneration; Used the disconnected sulphur activator of odorless, the antioxygen anti-aging agent has guaranteed to save the carbon～carbon bond of rubber as much as possible from damage when destroying the vulcanized rubber cystine linkage; Material is stored in big funnel once going out jar, imports screw extrusion press with machinery then, and this has been avoided temporarily the carbon black by water-wet may be to producing the pollution that environment causes.

Embodiment 6

Compound broken film (about 20 * 20～50 * 50 scopes that the parts by weights another name is got waste polyethylene or acrylic plastering and aluminium foil, wherein contain plastics about 78%, contain aluminium foil 22%, be packaged into 300 * 300 * 300～600 bale packing with Polywoven Bag, in plastics) 100 parts; Take by weighing by the auxiliary material that is easy to be liquefied:

Transformer oil or/and 4.5 parts in machine oil,

0.8 part of fatty alcohol-polyoxyethylene ether,

5.3 parts of the reclaiming aid groups of forming;

Above-mentioned material is placed as used withstand voltage stirred pots such as water/oil method or dynamic method reclaimed rubbers, carry out the operation of processing step (1), material will be filled withstand voltage stirred pot as much as possible, behind the airtight then withstand voltage stirred pot, in jar, feed water vapor, heat about 2 hours of insulated and stirred after 200 ℃, controlled temperature is between 180～210 ℃ between soak, stirring then, and add under the condition of jacket steam insulation of autoclave, the emulsive thermal material is put into a withstand voltage stirred pot that is added with the more twice water-cooled of 1/5 jar of water in advance slowly stir cooling, when treating that material is chilled to below 80 ℃, again the material that becomes the plastic powder particle suspension liquid being put into big pond further cools off, having under the condition of water then, divide the aluminium foil bits that take out in the suspension liquid (collect and do other application) with water-fast corrosive mesh screen, divide water outlet and synthetic resin moulding compound pellet with solid-liquid separating equipments such as whizzer or band filters again, the water cycle of telling is used; The synthetic resin moulding compound pellet of gained just obtains waste polyethylene of the present invention or acrylic plastering masterbatch through warm air drying, if zonal tide becomes bits through rolling after dehydration, this just obtains waste polyethylene of the present invention or acrylic plastering rubber master batch.

This routine described masterbatch, rubber master batch, by feeding intake, plastic waste weight content wherein is 95%, reclaiming aid group weight content is 5%.

The innovative point of this routine described masterbatch, rubber master batch and preparation method thereof is: the described masterbatch of this embodiment, rubber master batch have been broken through the normal hot-extrudable comminution granulation that adopts of traditional waste plastics recovery, comminuting method, heat drop solution, heat agitated completion method, hot solvent partition method; The efficient height of new recovery method; Poisonous and harmful solvent useless; Products obtained therefrom also can be mutually mixing with General Purpose Rubber in mill because fine size (80～200 order) not only can be used for plastics.

Embodiment 7

Parts by weights another name is got useless Ethylene Propylene Terpolymer sealed strip micelle (5～20 order), or useless butadiene-acrylonitrile rubber sealing micelle (5～20 order), or 100 parts in radial micelle (20～30 order); Take by weighing by being easy to pulverized auxiliary material, friction resistant lubricant class material:

5 parts of the sesbania gums (moisture more than or equal to 85, in butt) that gel does not dewater as yet,

0.25 part of zinc silicate (moisture) more than or equal to 60% filter cake, in butt,

0.05 part of sodium lauryl sulfate,

5.3 parts of the reclaiming aid groups of forming;

Above-mentioned material is placed mixing of thick step of mix jar earlier, import in the shear-type disc type rubber normal temperature fine pulverizer by quantitative spiral conveying tube then and carry out grinding and processing, in this process, because the reclaiming aid group that adds contains more water, and is rich in oilness, make rubber grain in the mixture in pulverized process, friction no longer is easy to give birth to heat, water in the material is owing to taked the anti-measure of doing, can be very not fast by evaporate to dryness, material temperature is not crossed 100 ℃, thus the group of connecing of can not being clamminess, in addition, again since the powder in the reclaiming aid group and the water of more amount to the coating of rubber elastomer, buffer action, in pulverized process, reuniting can not appear in rubber yet, just is ground into 60% and is narrower than and equals 90 orders so rubber elastomer is once crossed machine at an easy rate; Material after the machine of once crossing is pulverized through wind revolve or sieve classification after, the coarse fodder of crossing 90 mesh sieves can be collected in together (with reference to embodiment 1), can walk machineries such as placed in-line shear-type disc type rubber normal temperature fine pulverizer then in addition, goes processing such as pulverizing again; Equal 90 orders if the coarse fodder after sifting out is ground into again to be narrower than, then walking the mach product of series connection pulverizing in addition can belong in the feed bin with aforementioned product; This just obtains fine glue powder masterbatch of the present invention, if this fine glue powder masterbatch again through rolling, just obtains fine glue powder master batch of the present invention or rubber master batch.

The described masterbatch of this embodiment, master batch, rubber master batch wherein contain useless Ethylene Propylene Terpolymer or useless butyronitrile or meridian scrap tire rubber elastomerics 95%, contain reclaiming aid group 5%.

The preparation method's of the described masterbatch of this embodiment, master batch, rubber master batch innovative point is: the reclaiming aid group is made up of the very low material of solid content, wherein with water because the existence of antidesiccant, abrasion-proof heat generating agent is arranged, and do not have too fast by evaporate to dryness, thereby make water play coating, buffer action well, cause the products obtained therefrom can be not only pure but also thin rubber elastomer.

Embodiment 8

The parts by weights another name is got the useless Ethylene Propylene Terpolymer sponge sealed strip micelle (5～20 order) of non-black, 100 parts; Take by weighing by being easy to pulverized auxiliary material:

Albescent mineral aggregate: kaolin or/and rhombspar or/and

Gypsum or/and pyrophyllite or/and Juanyingshi or/and montmorillonite

Deng (moisture being not more than equals 20%, and granularity is below 20mm, in butt) 100 parts,

Albescent slag charge: the alkali mud that soda factory dumps is or/and the salt slurry that chlor-alkali plant dumps

Or/and 300 parts of (moisture being not more than equal 20%, and granularity is below 20mm, in butt) such as white claies that the paper mill dumps,

0.2 part of zinc silicate (moisture being not more than equals 60% filter cake, and granularity is below 20mm, in butt),

400.2 parts of the reclaiming aid groups of forming;

Above-mentioned material is placed mixing of thick step of mix jar earlier, import in the vertical refining mill that mining industry uses by quantitative screw rod transmission pipe then and pulverize, material imports in the collecting bin after the overground pulverizing of this processing step (1), obtains being narrower than equaling 100 purpose mixed powders; And then from collecting bin, get the product of this processing step (1)---500.2 parts of mixed powders, and add 50 parts of the Synergist S-421 95s formed by paraffin oil again, in another mix jar, carry out the married operation of processing step (2); Material behind the mixing fine glue powder masterbatch product of the present invention; Also can be again this Ethylene Propylene Terpolymer fine glue powder masterbatch through roll be rolled into bits, sheet obtains fine glue powder master batch of the present invention, rubber master batch product.

The described masterbatch of this embodiment, master batch, rubber master batch wherein contain useless ethylene-propylene-diene monomer glue elastomer 19.99～18.18%, contain reclaiming aid, Synergist S-421 95 group 80.01～81.82%; The product of this embodiment gained can be used for the extrusion molding rubber, moulds goods because fine size, can not make rubber, to mould product surface crude.

The preparation method's of the described masterbatch of this embodiment, rubber master batch innovative point is: the reclaiming aid group has adopted slightly, hard material, the dust pollution when having avoided pulverizing charging; Adopt the mining industry pulverizer.

Embodiment 9

The parts by weights another name is got useless bias tyre micelle (5～20 order), 100 parts; 200 parts of useless assorted rubber overshoes/waste polyethylene/cinder (ratio of weight is 15/15/70, and is milled to be narrower than with reference to the vertical refining mill of embodiment 8 usefulness mining industry and equals 200 orders, and it is wetting to add the 10 parts of mixing of transformer oil of giving up again) masterbatch; 10 parts of waste polyethylene acetal plastics (about about 10～50 * 500) bars; Take by weighing by being easy to pulverized auxiliary material etc.:

100 parts of carbon blacks (can N660 or N330 etc., whole packing drops into),

The decolouring inactivation gac that treated oil factory dumps is (wherein still oil-containing about 20%) 80 parts or/and atlapulgite slag mud,

2 parts of restaurant refiltered oils,

2 parts of rosin,

1 part of peach resin,

Go mouldy 5 parts of useless peanuts,

0.3 part of zinc silicate (moisture being not more than equals 60% filter cake, and granularity is below 20mm, in butt),

0.3 part of Triton X-100,

190.6 parts of the reclaiming aid groups of forming;

Above-mentioned material is placed the used withstand voltage stirred pot of dynamic method reclaimed rubber that is added with 12 parts of water, carry out the operation of processing step (1), add while stirring behind the airtight withstand voltage stirred pot, heat is incubated 2 hours after 200 ℃, controlled temperature is between 200～210 ℃ between soak, the blowing of lowering the temperature then; The material of emitting can import screw extrusion press by big funnel, squeezing sizing material that machine squeezes through screw rod is free in carbon black outside the micelle etc. in can be mixture and promptly kneads and can not stain production environment again, by screw rod squeeze sizing material that machine squeezes out again through mill or/and refiner kneading, refining, blanking then obtains plasticizing rubber and plastic mixing rubber master batch of the present invention;

In this routine gained rubber master batch, waste elastomer is (100+30) with the ratio of the weight of plastic waste: (30+10) promptly, 100: 30.77, the weight of waste elastomer and plastic waste accounted for 33.96%, and the weight of reclaiming aid group, Synergist S-421 95 accounts for 66.04%; This routine gained rubber master batch can be used for making rubber item.

The innovative point of present embodiment is: the combination of withstand voltage stirred pot that the vertical refining mill of use mining industry is used with using the dynamic method reclaimed rubber and screw extrusion press etc., and contamination-freely produce plastifying and contain waste elastomer and plastic waste rubber master batch.

Embodiment 10

Parts by weights another name is got useless Tetrapack paper/aluminium foil/plastic composite (paper/aluminium/mould the content ratio to be about: 75/5.5/19.5 wherein, shape: 20 * 20～50 * 50) or by wherein separating the aluminium foil/plastic composite obtain (aluminium/mould the content ratio to be about wherein: 22/78, shape: 20 * 20～50 * 50) or by wherein separate the broken film of plastics obtain (wherein polyethylene or/and polypropylene content be about: 100%, shape: 20 * 20～50 * 50) 100 parts; Take by weighing by being easy to pulverized auxiliary material:

Talcum or/and hydrotalcite or/and foliated talc or/and

Opal or/and quartzite or/and wollastonite or/and 300 parts in barite (20～60 order),

300 parts of the reclaiming aid groups of forming;

Above-mentioned material is placed the mix jar earlier, the water that adds 10～20 parts again, the thick step is mixed mixing thoroughly, pass through conveying belt then, pulverize in the vertical refining mill that pipe importing mining industry is used, material is after the overground pulverizing of this processing step (1), can obtain paper/aluminium/plastic compound or aluminium/plastic composite or plastics and normally white talcum, hydrotalcite, foliated talc, opal, quartzite, wollastonite, the powdered mixture of the inorganic mineral of one or more in the barite, by the described method of previous embodiment, this routine powdered mixture can be narrower than by pulverizing and equal 100 orders, the powdered mixture of pulverizing gained put into different categories be collected in the collecting bin of each kind, the powdered mixture of this routine gained is the fine glue powder masterbatch that contains plastic waste, and they can comprise:

Paper/aluminium/mould and the steatitic powdered mixture, the powdered mixture of paper/aluminium/mould and opal, quartzite, the powdered mixture of aluminium/mould and quartzite, the powdered mixture of plastics and wollastonite, combinations such as plastics and bar powdered mixture; Contain in the fine glue powder masterbatch combination of plastic waste at these, in the powdered mixture of paper/aluminium/mould and inorganic mineral class, it is about 4.88% to contain plastic waste, the reclaiming aid group of composition (comprising the non-component of moulding in useless Tetrapack paper/aluminium foil/plastic composite) 95.12%; In the powdered mixture of aluminium/mould and inorganic mineral class, it is about 19.50% to contain plastic waste, the reclaiming aid group of composition (comprising the non-component of moulding in useless Tetrapack paper/aluminium foil/plastic composite) 80.50%; Mould in the powdered mixture with the inorganic mineral class, it is about 25% to contain plastic waste, the reclaiming aid group of composition (comprising the non-component of moulding in useless Tetrapack paper/aluminium foil/plastic composite) 75%;

The powdered mixture that present embodiment is obtained through above-mentioned processing step (1), except according to the previous embodiment Synergist S-421 95 formed such as odorless tenderizer in addition again, or again through rolling tablet forming, bits, obtain outside masterbatch of the present invention, rubber master batch, the master batch, the physical difference that also can utilize each component in the powdered mixture its through selection by winnowing or/and the water flotation be divided into paper/aluminium/mould, aluminium/mould again, mould and the breezes such as talcum of white; This has just realized grafting and coproduction plastic waste fine glue powder on all kinds of nonmetal breeze production lines, and through actual tests, grafting coproduction waste rubber fine glue powder also is feasible on all kinds of nonmetal breeze production lines.

Embodiment 11

Parts by weights another name is got useless bias tyre micelle (5～20 order), or 100 parts in meridian damaged tire micelle (24～30 order); 5 parts of waste polyethylene acetal plastics (about about 10～50 * 100) bars; Take by weighing by auxiliary material that is easy to liquefy etc.:

The restaurant refiltered oil or/and useless transformer oil or/and 10 parts of tung oil,

5 parts of low-molecular polyethylene waxs,

Special octyl group phenolic aldehyde is or/and 2 parts of coumarone indene resins,

3 acetaldols-2-naphthylamines is or/and 3 acetaldols-2-naphthylamines

Or/and 6-oxyethyl group-2,2,4-trimethylammonium-1,2-dihyaroquinoline

Or/and acetone and pentanoic pyroreaction thing or/and

5 parts of N-phenyl-B-naphthylamines,

The tetramethyl-ammonium halide or/and hexadecyl ethyl dimethyl ammonium halide or/and

Hexadecyl methyl diethyl ammonium halide is or/and monobutyl dimethyl benzyl ammonium halide

Or/and the octadecyl ammonium halide is or/and 0.5 part on 2-thiol benzothiazole zinc,

22.5 parts of the reclaiming aid groups of forming;

Above-mentioned material is placed the rubber internal mixer of strap clamp cover heating, heat airtight pugging mullering, implement the processing of described processing step (1), control pugging mullering temperature is no more than 240 ℃, when Banbury mixer reometer indicator value becomes to descending from low to high again, rapid blowing, the airtight pugging mullering process of whole heating was at 7～15 minutes, the sizing material of emitting can cool off with water-sprinkling, or pull into the film cooling with mill rapidly, the sizing material that is cooled to room temperature has been a plasticizing rubber master batch of the present invention just, certainly become big for the plasticity-that can make the plasticizing rubber master batch or the tensile yield of its cross-linked rubber, also can be again it with scouring machine thin-pass number time, and then roll film blanking obtains the bigger plasticizing rubber master batch of plasticity.

The described rubber master batch of this embodiment, wherein tire waste rubber elastomerics is 100: 5 with the ratio of plastic waste, contains tire waste rubber elastomerics and plastic waste 85.71%, contains reclaiming aid group 14.29%; The described two kinds of rubber master batch of this embodiment are pressed reclaimed rubber standard GB/T13460-2003 and are detected, and tensile strength at yield can reach 22.12MPa and 18.25MPa, and tensile yield can reach 500% and 450%.

Embodiment 12

Parts by weights another name is got useless butyl curing bag micelle (about 5 orders), or 100 parts in useless Ethylene Propylene Terpolymer sealed strip micelle (5～20 order); 5 parts of waste polyethylene acetal plastics (about about 10～50 * 100) bars; Take by weighing by auxiliary material that is easy to liquefy etc.:

Paraffin oil or/and halogenated paraffin or/and

Low-molecular polyethylene wax is or/and low-molecular polypropylene wax

Or/and stearyl alcohol is or/and 5 parts of (C7～18) mixed fatty alcohols,

N-phenyl-N '-cyclohexyl Ursol D or/and N-phenyl-N '-sec.-propyl-Ursol D or/and

N, N '-phenylbenzene-Ursol D or/and 2-thiol group benzimidazolyl or/and

Tyox B is or/and phosphorous acid benzene di-isooctyl, 4 parts,

Cupric phosphate or/and nickel hydroxide or/and nickelous carbonate or/and rose vitriol

Or/and the ferrous zinc of sylvic acid or/and sylvic acid is ferrous zinc abietate

Or/and the sylvic acid cobalt or/and zinc naphthenate or/and cobalt naphthenate or/and

The lipid acid cobalt or/and fatty acid zinc or/and Zinic stearas or/and Zinc Gluconate or/and 1 part on Ferrous Gluconate zinc,

10 parts of the reclaiming aid groups of forming;

Above-mentioned material is placed the rubber internal mixer of strap clamp cover heating earlier; heat airtight pugging mullering, mixing; control pugging mullering temperature is no more than 180 ℃; when Banbury mixer reometer indicator value becomes to descending from low to high again; rapid blowing; the airtight pugging mullering process of whole heating was at 5～10 minutes; the sizing material of emitting places Rubber Extruder again; extrude pugging mullering; the control extrusion temperature is no more than 220 ℃, and the sizing material that goes out forcing machine pelletizing or reel after water cooling can become useless butyl of the present invention or useless Ethylene Propylene Terpolymer plasticizing rubber master batch.

The described rubber master batch of this embodiment, wherein butyl or Ethylene Propylene Terpolymer waste rubber elastomerics are 100: 5 with the ratio of plastic waste, contain butyl or Ethylene Propylene Terpolymer waste rubber elastomerics and plastic waste 91.30%, contain reclaiming aid group 8.70%.

The inventor is again through the narration of above-mentioned 12 embodiment, describe equipment such as available pulverizing, groove jar, kneading in detail, in the presence of free of contamination reclaiming aid group, Synergist S-421 95, processing obtains the method for product of the present invention, the feature of described product is: odorless is dustless, contains waste elastomer or/and the masterbatch of plastics 95%～5%, master batch, rubber master batch mixture as what the supplementary material of industries such as elastomerics, plastics used.

Embodiment 13.

Get certain commercially available brand reclaimed rubber A, reclaimed rubber B, 40～80 purpose desulfurization plasticizing rubber powder C, 10～30 purpose desulfurization plasticizing rubber powder, grain D, each 100 parts in A, B, C, D material, correspondence respectively adds 5 parts of Synergist S-421 95 A ' respectively, 4 parts of Synergist S-421 95 B ', 2 parts of Synergist S-421 95 C ', 2 parts of Synergist S-421 95 D ', C, D and respectively be added with Synergist S-421 95 material each get final product blanking after handling 3～5 times in that book on the two roller rubber refining mills is logical, will handle the detection method of the rerum natura of forward and backward secondary raw material rubber with reference to GB/T13460-2003 " regenerated rubber ", contrast as follows:

Sample number into spectrum:	1	2	3	4	5		6	7	8
										Test recipe:
Modified adhesive D ' the accelerator CBS stearic acid zinc oxide sulphur of modified adhesive C ' the plasticizing rubber powder D D of modified adhesive B ' the plasticizing rubber powder C C of modified adhesive A ' the reclaimed rubber B B of reclaimed rubber A A	300 / / / / / / / 1.5 1.5 7.5 4.5	/ 300 / / / / / / 1.5 1.5 7.5 4.5	/ / 300 / / / / / 1.5 1.5 7.5 4.5	/ / / 300 / / / / 1.5 1.5 7.5 4.5	/ / / / 300 / / / 1.5 1.5 7.5 4.5		/ / / / / 300 / / 1.5 1.5 7.5 4.5	/ / / / / / 300 / 1.5 1.5 7.5 4.5	/ / / / / / / 300 1.5 1.5 7.5 4.5
										Cure conditions: 142 ℃ * 20 minutes
Physicals is:
										Mooney viscosity ML (1+4)/100 ℃ tensile strength (MPa) elongation rate of tensile failure (%)	68 9.82 410	64 16.95 450	84 6.32 320	80 9.50 430	84 4.30 225		80 5.50 340	82 14.50 360	78 17.20 420

In the present embodiment:

Synergist S-421 95 A ' consists of: antioxidant A W/ antioxidant 4010 A/ anti-aging agent RD/Zinic stearas=1～2/1～2/1～2/0.8～1.5;

Synergist S-421 95 B ' consists of: antioxidant 4010NA/antioxidant 2246/anti-aging agent MDP/ antioxidant A P/ Zinic stearas/Magnesium Stearate=1～2/1～2/1～3/1～4/1～3/1～1.5;

Synergist S-421 95 C ' consists of: antioxidant 4010/antioxidant 264/antioxidant D/antioxidant A/=1～2/1～2/1～3/1～4;

Synergist S-421 95 D ' consists of: antioxidant A H/ aging inhibitor FR/anti-aging agent W-300/ anti-aging agent 330=1～2/1～2/1～3/1～4.

Next the inventor engages accompanying drawing and provides two embodiment again with regard to a kind of improvement that has the special combined equipment of normal temperature fine pulverizer described in the inventive method.

Embodiment 14

At as the accompanying drawing 1 described course of processing, a kind of is raw material with 5～40 order elastomerics micelles, add reclaiming aid group powder, earlier make the ultra-fine rubber powder masterbatch mixture of 90～200 orders with the pulverizing method of normal temperature, add Synergist S-421 95 again, and then make master batch, or be exactly the directly technical process of pack of the masterbatch mixture that adds the mixture that is mixed, the present invention cooperates processing requirement, an integrated cover elastomerics micelle elder generation normal temperature that is combined into as shown in Figure 2 is pulverizing, make the combined machine of master batch again, it is characterized in that: before the fine crusher cohort and after all be provided with the machinery that can add auxiliary material, the elastomerics micelle can both added auxiliary material before and after the process of processing in small, broken bits under airtight operating mode; The fine crusher cohort is divided into two groups of A, B, guaranteed the constant of fine crusher feed components, granularity, and the current stabilization of being convenient to thick micelle material advances machine; On the feeding pipe of fine crusher cohort, there is feed rate to compare setting device; Be provided with the meal material of not crossing 90～mesh sieve that to tell classification, sieve apparatus, cross the fine powder material interflow more than 250～order with crossing, supply with the row machinery setting of pulverizing again of A or B group fine crusher then; Be equipped with the combined machine of powder granulation, packing again;

The machinery that adds auxiliary material of the present invention, as shown in Figure 2, before fine crusher cohort equipment, be by set bucket type material elevator 7, flow direction of material guide groove pipe 48, reclaiming aid group filler bin 1,2,5～40 order elastomer precursor gum pellet storehouses 3, weighing apparatus 4,5,6 compositions in batch mixes storehouse; After fine crusher cohort equipment, be by set bucket type material elevator 25, flow direction of material guide groove pipe 49, Synergist S-421 95 feed bin 26,27,90 orders～elastomer precursor gum filler bin 28, weighing apparatus 30,33,34 compositions in batch mixes storehouse;

Fine crusher cohort of the present invention, as shown in Figure 2, by:

15,16,17 represented unit fine crushers are formed the A group, form the B group with the unit fine crusher of 18,19,20,21 expressions, add up to 7 of unit fine crushers;

Or by:

15,16,17,18,19,20 represented unit fine crushers are formed the A group, form the B group with the unit fine crusher of 21 expressions, add up to 7 of unit fine crushers;

Deciliter variation of A, B group is to operate by the start or stop of valve 11,12,13,14,43,44,45,46 to realize;

Of the present invention have feed rate than setting device on the feeding pipe of fine crusher cohort, as shown in Figure 2, they can be made up of helical feed equipment 10 and 11,12,13,14 on the valve of establishing thereon;

Of the present invention being provided with can be classification, the meal material of not crossing 90～mesh sieve that sieve apparatus is told, also flow with the fine powder material of crossing more than 250～order of crossing, supply with the machinery setting of row pulverizing again of A or B group fine crusher then, as shown in Figure 2, they can (wherein use two-layer screen cloth up and down by sieve apparatus 31, upper strata 90 mesh sieves, lower floor's 250 mesh sieves), do not cross the meal material of 90～mesh sieve, with the fine powder material collecting fitting 22 excessively more than mistake 250～order, cyclonic separator 8, thickness powder mixing bunker 9, helical feed equipment 10 and the valve of establishing thereon 11,12,13,14 form, also can be the meal material of not crossing 90～mesh sieve, collaborate to walk pipe 22 with the fine powder material of crossing more than 250～order of crossing, again through valve 51,52 control, suck by cyclonic separator 53, drop into batch mixes storehouse 6 down;

The combined machine that is equipped with powder granulation, packing more of the present invention, as shown in Figure 2, they can be by screw pelletizer 35; cyclonic separation water cooler 38, pneumatic conveyer road 39, master batch finished product collecting bin 37; automatic packer 36, bag closer 40, rotary conveyor 41 is formed.

In of the present invention having among the elastic body fine crushing combined machine embodiment as shown in Figure 2, other unit machinery and the effect thereof that also indicate are respectively in addition:

Control valve 43,44,45,46,47 is moved towards in the fine powder material outlet, and they can make the powder that is come out by B group fine crusher select the screen casing road of passing by, or choosing walks directly to advance the pipeline of fine powder finished bin;

Pneumatic conveyer 42, cyclonic separator 24 is pulverized and to be waited to sieve feed bin 29, and they can make the powder that is come out by A or A and B group fine crusher be collected into pulverizing and wait to sieve feed bin 29;

Pneumatic conveyer 32, cyclonic separator 23, they can make the mistake 90～purpose powder collection that is sifted out by sieve advance to pulverize and treat batch bin 28 again.

Embodiment 15

At as accompanying drawing 1 described technical process requirement, the present invention cooperates processing requirement again, integrated again be combined into as shown in Figure 3 another set of elastomerics micelle elder generation normal temperature pulverizing, make the combined machine of powder concentrate mixture again, it is characterized in that: all be provided with the machinery that can add auxiliary material before and after the fine crusher cohort, the elastomerics micelle can both added auxiliary material by before and after the process of processing in small, broken bits under airtight operating mode; The fine crusher cohort can be divided into two groups of A, B, or three groups of A, B, C, or four groups of A, B, C, D, has guaranteed the constant of fine crusher feed components, granularity, and the current stabilization of being convenient to thick micelle material advances machine; On the feeding pipe of fine crusher cohort, there is feed rate to compare setting device; Be provided with and do not cross 90 to what classification, sieve apparatus were told～or 150～or the meal material of 200～mesh sieve, cross the fine powder material interflow more than 250～350 orders with crossing, supply with the row machinery setting of pulverizing again of A or B, C, D group fine crusher then; Be equipped with the combined machine of masterbatch powder packing again;

The machinery that adds auxiliary material of the present invention, as shown in Figure 3, before fine crusher cohort equipment, be by set bucket type material elevator 7, flow direction of material guide groove pipe 60, reclaiming aid group filler bin 15,16,5～40 order elastomer precursor gum pellet storehouses 17, weighing apparatus 18,19,20 compositions in batch mixes storehouse; After fine crusher cohort equipment, be by set bucket type material elevator 8, flow direction of material road barrel 72, Synergist S-421 95 feed bin 34,35,90～or 150～or 200～order elastomer precursor gum filler bin 36, weighing apparatus 37,38,39 compositions in batch mixes storehouse;

Fine crusher cohort of the present invention, as shown in Figure 3, by:

21,22,23,24,25,26,27,28 represented unit fine crushers are formed the A group,

With 29 represented unit fine crusher composition B groups, add up to 9 of unit fine crushers;

Or by:

21,22,23,24 represented unit fine crushers are formed the A group,

With 25,26,27,28 represented unit fine crusher composition B groups,

With 29 represented unit fine crusher composition C groups, add up to 9 of unit fine crushers;

Or by:

21,22,23 represented unit fine crushers are formed the A group,

With 24,25,26 represented unit fine crusher composition B groups,

With 27,28 represented unit fine crusher composition C groups,

With 29 represented unit fine crusher composition D groups, add up to 9 of unit fine crushers;

Deciliter variation of fine crusher cohort is to operate by the start or stop of valve 52,53,54,55,56,57,61,62,63,64,65,66,67,68,69,70,71 to realize;

Of the present invention have feed rate than setting device on the feeding pipe of fine crusher cohort, as shown in Figure 3, they can be made up of helical feed equipment 58 and 52,53,54,55,56,57 on the valve of establishing thereon;

Of the present invention be provided with can classification, sieve apparatus tell do not cross 90～, 150～, the meal material of 200～mesh sieve, collaborate with the fine powder material of crossing more than 250～order of crossing, supply with A or B, the machinery setting of row pulverizing again of C, D group fine crusher then, as shown in Figure 3, supply with the machinery setting of row pulverizing again of A group fine crusher:

They can be (wherein to use two-layer screen cloth up and down by sieve apparatus 30, the upper strata with 90～or 150～or 200～mesh sieve, lower floor with 250～or micro mesh sieve more), do not cross the meal material of upper strata coarse meshed sieve, fine powder material collecting fitting 51 excessively with mistake lower floor micro mesh sieve, selected control valve 73,75, cyclonic separator 76, batch mixes storehouse 20 is formed;

Supply with the machinery setting of row pulverizing again of B group fine crusher:

They can be (wherein to use two-layer screen cloth up and down by sieve apparatus 30, the upper strata with 90～or 150～or 200～mesh sieve, lower floor with 250～or micro mesh sieve more), do not cross the meal material of upper strata coarse meshed sieve, fine powder material collecting fitting 51 excessively with mistake lower floor micro mesh sieve, cyclonic separator 1, thickness powder mixing bunker 9, helical feed equipment 58 and 57,56,55 compositions of valve of establishing thereon;

Supply with the machinery setting of row pulverizing again of C group fine crusher:

They can be (wherein to use two-layer screen cloth up and down by sieve apparatus 31, the upper strata with 90～or 150～or 200～mesh sieve, lower floor with 250～or micro mesh sieve more), do not cross the meal material of upper strata coarse meshed sieve, fine powder material collecting fitting 50 excessively with mistake lower floor micro mesh sieve, cyclonic separator 2, thickness powder mixing bunker 10, helical feed equipment 58 and 54,53,52 compositions of valve of establishing thereon;

Supply with the machinery setting of row pulverizing again of D group fine crusher:

They can be (wherein to use two-layer screen cloth up and down by sieve apparatus 32, the upper strata with 90～or 150～or 200～mesh sieve, lower floor with 250～or micro mesh sieve more), do not cross the meal material of upper strata coarse meshed sieve, fine powder material collecting fitting 49 excessively with mistake lower floor micro mesh sieve, cyclonic separator 3, thickness powder mixing bunker 11, helical feed equipment 58 and the valve of establishing thereon 52 are formed;

Of the present inventionly add wrapped combined machine again, as shown in Figure 3, they can be by masterbatch finished product collecting bin 42, automatic packer 43, and bag closer 40, rotary conveyor 41 is formed.

In of the present invention having among the elastic body fine crushing combined machine embodiment as shown in Figure 3, other unit machinery and the effect thereof that also indicate are respectively in addition:

Control valve 61,62,63,64,65,66,67,68,69,70,71 is moved towards in the fine powder material outlet, pneumatic conveyer 44,45,46,47,48,59, cyclonic separator 4,5,6,33, pulverizing waits to sieve feed bin 12,13,14, their effect is to make the powder that is come out by A, B, C, D group fine crusher select away the pipeline that sieves of regulation, or selects the pipeline of walking directly to advance the fine powder finished bin.

Fine crusher cohort of the present invention, the production capacity configuration characteristics between its unit are: be divided into two groups, its preferable production capacity configuration than scope is: A/B=2/1～9/1; Be divided into three groups, its preferable production capacity configuration than scope is: A/B/C=1/1/1～5/3/1.

Fine crusher cohort of the present invention, unit fine crusher wherein be if use normal temperature rubber fine pulverizer, and the fine crusher cohort that then is combined into is suitable for pulverizing at 95～60% material of elastomerics in the treating mixture material, plastic content; If use normal temperature building stones slimer, the fine crusher cohort that then is combined into is suitable for elastomerics in the treating mixture material, plastic content is pulverizing 30～5% materials.

With the combined machine that has the elastic body fine crushing machine of the present invention, prepare the powdered mixture that contains elastomerics, plastics of required fineness, can just can obtain easily by the screen cloth that two-layer different meshes is set in sieve apparatus.

With the normal temperature rubber fine pulverizer that reaches, the abrasive dust working face of its cutterhead is provided with crude surface among the aforesaid embodiment of the present invention, uses the back to find that the use output at the beginning of pulverizer no longer descends.

Next, the inventor provides concrete Application Example to the new product that proposes protection domain in the product of the present invention again; The protection domain of described new product is: odorless is dustless, the masterbatch, master batch, the rubber master batch mixture that contain waste elastomer and plastics 95%～5% weight that use as the supplementary material of industries such as elastomerics, plastics, this is wherein especially containing waste elastomer and old plastics 95%～70% and 30%～5% abandoned, and it is good that other auxilliary ingredients accounts for the masterbatch in 5%～30% and 70%～95% both intervals or master batch or rubber master batch mixture; Waste elastomer in the mixture is (30～5) with the old plastics of abandoning with the ratio of the weight that feeds intake: (70～95) and (70～95): (30～5) both interval be good.

The new product that the present invention proposes, its feature also comprises: under the hot extrude of downstream product industry, hot-forming condition, it can be mixed into one mutually fully with virgin material, promptly on the cutter cut surface of goods, can not see rubber powder granule, and under the hot-work condition of downstream product industry, odorless (being that smell is not more than new sizing material), also odorless under the room temperature.

Embodiment 16

As former employings of rubber item such as a certain tire flaps is following prescription:

Natural rubber 100 high wear-resistant carbon black N660 50

Reclaimed rubber 250 potter's clay 50

5 No. 30 machine oil 13 of zinc oxide

Stearic acid 3 accelerant CZs 1.2

Antioxidant A 1 TM monex TD 0.02

Antioxidant D 1 sulphur 5

Paraffin 3 adds up to (part): 502.22

High wear-resistant carbon black N330 20

Reclaimed rubber wherein causes sizing material that the stench of coal tar, Stockholm tar etc. is always arranged because of using preparations such as coal tar, Stockholm tar, and also there is serious dust pollution in rubber item factory when joining this sizing material of refining.Now this sizing material is resolved into 3 groups of material set:

Material set 1:

Natural rubber 100, (this is the prescription material set of an odorless, no airborne dust),

Material set 2:

Reclaimed rubber 250,

Zinc oxide 5,

High wear-resistant carbon black N330 20,

High wear-resistant carbon black N660 50,

Potter's clay 50,

Paraffin 3,

Stearic acid 3,

No. 30 machine oil 13, (this is the serious prescription material set of a foul smelling, airborne dust),

Material set 3:

Antioxidant A 1,

Antioxidant D 1,

Accelerant CZ 1.2,

TM monex TD 0.02,

Sulphur 5 (this is that a rare prescription material smelly, that airborne dust is little is gathered),

Add up to (part): 502.22

Material set 2 in the prescription that resolves into further is generalized into again:

Material set 2, its total amount is 394 parts, wherein containing reclaimed rubber 63.45% (generally comprises again in the reclaimed rubber: the old rubber for tire 63.45% * 0.84=53.30% that abandons, smelly tenderizer etc. 10.15% is arranged), powder auxiliary material contains 31.73% (comprising initiate zinc oxide 1.27%, N330 5.08%, N660 12.69%, potter's clay 12.69%), odorless tenderizer 4.06% (comprising: paraffin 0.76%, stearic acid 0.76%, number machine oil 3.30%), material set 2 is the serious prescription material set of a foul smelling, airborne dust in the prescription; As a same reason, to the plastics prescription, also can therefrom summarize the same prescription material set that has severe contamination; As former employings of plastics such as a certain floor file is following prescription:

Polyvinyl chloride 100

Waste polyvinyl chloride 30

Organotin 3

Dioctyl phthalate (DOP) 7

Cullet powder 180

Diaspore powder 90

Useless nylon fiber 10

Barium stearate 1.05

Zinic stearas 0.45

Paraffin 0.4

Chlorinatedpolyethylene 10

There is serious dust pollution in plastics factory when joining this sizing material of refining, now this sizing compound formula is resolved into 3 groups of materials set:

Material set 1:

Polyvinyl chloride 100 (this is the prescription material set of an odorless, no easy airborne dust),

Material set 2:

Waste polyvinyl chloride 30

Dioctyl phthalate (DOP) 7

Cullet powder 180

Diaspore powder 90

Useless nylon fiber 10 (this is the prescription material set of serious dust pollution),

Material set 3:

Organotin 3

Barium stearate 1.05

Zinic stearas 0.45

Paraffin 0.4

Chlorinatedpolyethylene 10 (this is that a rare prescription material smelly, that airborne dust is little is gathered);

The present invention proposes the new product of protection domain, and it is used and is exactly: the material set of the waste rubber (as rubber powder, regenerated rubber etc.) that the secondary in elasticity of substitution body, the plastics prescription utilizes again, plastic waste and (smelly, odorless is arranged) tenderizer, (airborne dust is serious) powder auxiliary material etc.; Become smelly, the elastomerics of easy airborne dust is arranged, plastics prescription material set prescription material dustless into odorless or the few dirt of odorless gathers; As the serious prescription material of foul smelling, airborne dust in rubber systems such as the aforesaid a certain tire flap prescription is gathered:

Reclaimed rubber 250,

Zinc oxide 5,

High wear-resistant carbon black N330 20,

High wear-resistant carbon black N660 50,

Potter's clay 50,

Paraffin 3,

Stearic acid 3,

No. 30 machine oil 13,

Total solid is: 394 parts (wherein containing waste rubber 53.30%);

Just can adopt the old prescription of abandoning the plasticizing rubber master batch of rubber and plastic waste as follows, or the similar equivalence of rerum natura or the set of better formulation material substitute:

Waste rubber and plastic waste (100: 5):

Damaged tire micelle (20～30 order) 210,

Waste polyethylene (50 * 50 broken film) 10.5,

The reclaiming aid group:

Zinc oxide (can pack input) 5,

Carbon black (can put in order packing input) 70,

Potter's clay (can put in order packing input) 59,

Paraffin 3,

Stearic acid 3,

Number machine oil 23,

Rosin 10,

Sylvic acid cobalt 0.5,

Water 40,

Total solid is: 394 parts (wherein containing waste rubber and plastic waste 55.96%);

The processing mode of plasticizing rubber master batch can be with reference to embodiment 1～12;

Have again the prescription material set that pollutions such as airborne dust are arranged in the plastics prescriptions such as aforesaid a certain floor file:

Waste polyvinyl chloride 30

Dioctyl phthalate (DOP) 7

Cullet powder 180

Diaspore powder 90

Useless nylon fiber 10,

Total solid is: 317 (parts), (wherein contain and mould 9.46%);

Just can adopt the old prescription of abandoning rubber and/or plastic waste masterbatch, rubber master batch as follows, or the similar equivalence of rerum natura or better formulation material set substitute:

Waste rubber and/or plastic waste (5: 100, or plastic waste is very) the broken film 30 of waste polyvinyl chloride,

Useless paracril micelle (about 5 orders) 1.5/ or be 0,

The reclaiming aid group:

Cullet (about 5 orders) 180

Diaspore (about 5 orders) 90

Useless nylon fiber 10,

Synergist S-421 95:

Dioctyl phthalate (DOP) 5,

Total solid is: 315～316.5 (parts) (wherein contain and mould 9.52%～9.48%);

The processing mode of masterbatch, rubber master batch can be with reference to embodiment 1～12.

Embodiment 17

Summarizing from the prescription of a certain rubber item followingly has the set of smelly, that dust pollution is arranged material to be:

Reclaimed rubber (smelly) 100 ancient marlon resins, 3.64 lime carbonate (dust) 7.27

Zinc oxide (dust) 0.96 C5 resin 2.73 adds up to (part): 146.46,

Stearic acid 0.55 Stockholm tar (smelly) 4.27 (wherein containing rubber powder about 58.72～60.08%);

Paraffin 0.49 colliery powder (dust) 16.36

Anti-aging agent 1.10 potter's clay powder (dust) 9.09

Now can adopt and as followsly oldly abandon rubber or oldly abandon masterbatch, the rubber master batch that rubber and plastic waste form and substitute, its material set is:

Waste rubber tire rubber powder grain (5～30 order) 88

Or add plastic waste (polyethylene is or/and waste plastic film bags such as polypropylene) 6 again

The reclaiming aid group:

Zinc oxide 0.96

Zinic stearas 0.2

Oxalic acid 0.2

Stearic acid 0.55

Paraffin 0.49

Antioxidant A W 1.10

Ancient marlon resin 3.64

C5 resin 2.73

Cottonseed benevolence (in solid substance) 12

Treated oil decolouring slag mud (still oil-containing 20%) 21.35

The alkali mud that alkali factory dumps (contain and consolidate 60%, the butt meter) 11.37

Add up to (part): 142.59 or 148.59,

In the set of this material, it is about 59.22～61.72% to contain rubber powder, and the pH of system is in 7～9 scopes, and pH resiliency again; Material can be handled with reference to embodiment 1～12;

Also can adopt two groups as follows oldly to abandon rubber or oldly abandon rubber and oldly abandon masterbatch, the rubber master batch that plastics are formed, the recombinant by both substitutes then, and its material set is:

Contain old rubber or old rubber and the old more upper limit admixtion of plastics (A group) of abandoning abandoned abandoned:

Waste rubber tire rubber powder grain (5～30 order) 88

Or add the old plastics (polyethylene is or/and waste plastic film bags such as polypropylene) 6 of abandoning again

The reclaiming aid group:

Zinc oxide 0.96

Zinic stearas 0.2

Oxalic acid 0.2

Stearic acid 0.55

Paraffin 0.49

Antioxidant A W 1.10

Ancient marlon resin 3.64

C5 resin 2.73

Cottonseed benevolence (in solid substance) 12

Add up to (part): 109.87 or 115.89,

In this material set, contain rubber powder about 75.93～80.09%;

Contain old rubber or old rubber and the old less lower limit admixtion of plastics (B group) of abandoning abandoned abandoned:

The old rubber tyre rubber powder grain (5～30 order) 88 of abandoning

Or add the old plastics (polyethylene or/and plastic waste such as polypropylene 10 orders bits grain) 6 of abandoning again

The reclaiming aid group:

Zinc oxide 0.96

Zinic stearas 0.2

Oxalic acid 0.2

Alkali factory alkali mud is in potter's clay mixture (about 5 orders, contain and consolidate 90%, the butt meter) 300

Add up to (part): 395.36 or 389.36,

In the set of this material, it is about 22.26～22.60% to contain rubber powder, and the pH of system is in 7～9 scopes, and pH resiliency again; Material can be handled with reference to embodiment 1～12, can adopt the processing such as dynamic jar, refiner, forcing machine, Banbury mixer of reclaimed rubber to obtain as the A group, and B organizes and can adopt processing such as mining industry pulverizer, two roller mills to obtain; Then by both recombinant:

A organizes (containing rubber powder about 75.93～80.09%)

B organizes (containing rubber powder about 22.26～22.60%)

Or the similar equivalence of rerum natura or the set of better formulation material substitute.

Being worth mentioning is, above-mentioned two examples are to substitute the material set smelly, easy airborne dust that has in the original formulation with gel content, masterbatch that the recipe ingredient kind is close, master batch, rubber master batch; Also can differ greatly with gel content, as one is that gel content can be A (as A=95%), another is two masterbatch, master batch, rubber master batch that gel content can be C (as C=5%), by both different ratios combinations of height, join to such an extent that a series of gel contents fall between that to can be B (be that B is less than 95%, but greater than 5%) odorless, the set of dustless material, gather with its a series of materials smelly, airborne dust that have that substitute in certain original formulation; Also can differ greatly with gel content, a plurality of masterbatch, master batch, rubber master batch that Containing Sulfur promoting agent (as zinc oxide etc.), strengthening agent (as carbon black etc.), filler auxiliary material such as (as potter's clay, fine particle calcium carbonate etc.) functional powder and tenderizer etc. also differ greatly, by separating polynary linear function group, join to such an extent that odorless, the dustless material of a series of all material content between a plurality of masterbatch, master batch, rubber master batch gathered, gather with its material smelly, airborne dust that has that substitutes in a series of certain original formulation; The material smelly, airborne dust that has that substitutes in a series of certain original formulation with masterbatch, master batch, rubber master batch new product of the present invention is gathered, the set of the component materials of its masterbatch, rubber master batch new product can be different with the component materials set in replaced a series of certain original formulation, but it is assigned in total material Fang Zhonghou must to control adjustment, the comprehensive rerum natura of new side is good with what be not less than certain original formulation, described control adjustment is all understood its art-recognized meanings the prescription slip-stick artist of elastomerics, plastic product industry.

New product characteristics in the protection domain of the present invention are: odorless is dustless, the masterbatch, master batch, the rubber master batch mixture that contain waste elastomer and plastics 95%～5% weight that use as the supplementary material of industries such as elastomerics, plastics; Owing to wherein contain plastics,, can make the rubber item of gained have advantages such as wear-resisting, anti-tear, hardening, skin friction coefficient diminish so it is assigned in rubber mass side; Again owing to wherein contain rubber,, can make the plastics of gained have shock resistance, deliquescing, skin friction coefficient and become advantage such as big so it is used in plastic square.

Prompting according to embodiment 16,17, if to modifying asphalt, waterproof roll, paint, tackiness agent, the relevant prescription of look rubber master batch, Masterbatch etc. carries out similar analysis, also can summarize waste elastomer (as rubber powder, regeneration rubber etc.), old material set of abandoning plastics and (smelly, odorless is arranged) tenderizer, (airborne dust is serious) powder auxiliary material etc. that secondary utilizes again in prescription; To substitute with masterbatch of the present invention, master batch, rubber master batch new product also be feasible to the set of these materials so.

Embodiment 18

Parts by weights another name is got 100 parts in waste elastomer (as tire, sealed strip etc. a kind of) micelle (about 20 orders);

Take by weighing by easy pulverized auxiliary material:

The damaged tire cracking is or/and 1520 parts of rice husk, 25 parts of straw destructive distillation carbon black A (15～30 order) or B (200mm～30 orders),

N-phenyl-N '-cyclohexyl Ursol D or/and N-phenyl-N '-sec.-propyl-Ursol D or/and

N, N '-phenylbenzene-Ursol D or/and 2-thiol group benzimidazolyl or/and

Tyox B is or/and phosphorous acid benzene di-isooctyl, 4 parts,

Cupric phosphate or/and nickel hydroxide or/and nickelous carbonate or/and rose vitriol

Or/and the ferrous zinc of sylvic acid or/and sylvic acid is ferrous zinc abietate

Or/and the sylvic acid cobalt or/and zinc naphthenate or/and cobalt naphthenate or/and

The lipid acid cobalt or/and fatty acid zinc or/and Zinic stearas or/and Zinc Gluconate or/and 1 part on Ferrous Gluconate zinc,

" the reclaiming aid group A " 30 parts or " the reclaiming aid group B " 1525 parts that form;

The material of 30 parts of above-mentioned adding " reclaiming aid group A " is placed mixing of thick step of stirring mixer earlier, import in the shear-type disc type rubber normal temperature fine pulverizer by spiral conveying tube then and carry out grinding and processing, in the course of processing of this step 1, material temperature is not crossed 80 ℃, it is the decomposition that temperature does not arrive rubber elastomer in the crushing process, plasticization temperature, the group of connecing so rubber elastomer can not be clamminess, in addition, again owing to the coating of a large amount of frangible powder in the reclaiming aid group to rubber elastomer, buffer action, in pulverized process, mixtures such as rubber are once crossed machine at an easy rate and just are ground into 95% and are narrower than and equal 90 orders; Material after the machine of once crossing is pulverized through wind revolve or sieve classification after, the 5% mixture coarse fodder of not crossing 90 mesh sieves can be collected in together and the crossing fines and close of 3% mistake 350 mesh sieves, the magnetic separator of can going further then, remove by richness and amass steel wire, iron filings in 5% coarse fodder, be back to again in the stirring mixer with virgin material and go crushing operation again;

The material of 1525 parts of above-mentioned adding " reclaiming aid group B " is also placed mixing of thick step of stirring mixer earlier, import in the large-scale shear-type disc type stone material fine pulverizer by spiral conveying tube then and carry out grinding and processing, in the course of processing of this step 1, material temperature is not crossed 80 ℃ yet, in pulverized process, the mixture that is mixed with a small amount of rubber elastomer is once crossed machine at an easy rate and just is ground into 99% and is narrower than and equals 90 orders; Material after the machine of once crossing is pulverized through wind revolve or sieve classification after, 1% coarse fodder of not crossing 90 mesh sieves can be collected in together and the crossing fines and close of 1% mistake 350 mesh sieves, the magnetic separator of also going further then, remove by richness and amass steel wire, iron filings in 1% coarse fodder, be back to again in the stirring mixer with virgin material and go crushing operation again;

Through the course of processing of above-mentioned steps 1, obtain containing the old mixture particle of abandoning rubber elastomer 76.92% or 6.15% and be narrower than and equal the ultra-fine rubber powder masterbatch of 90 purposes, be i.e. the finished product 1A or the finished product 1B;

Also can remake further processing with the finished product 1A or the finished product 1B as intermediate product, as being example with the finished product 1A:

Get " intermediate product A1 " 130 parts,

Take by weighing by auxiliary material:

Natural rubber or/and styrene-butadiene rubber(SBR) or/and along 5～20 parts of benzene rubber,

The petroleum pitch of odorless or/and machine oil or/and 7～10 parts of hogwash oil

12～30 parts of the Synergist S-421 95s of forming,

Above-mentioned material was imported in the pressurization internal mixer mixing 4～6 minutes, draw off glue stuff compounding then, again sizing material is placed the machine slice of beginning to pratise; Or again sizing material is placed the screw rod machine to extrude processing, obtain film, adhesive tape or micelle;

Through the processing of above-mentioned steps 2, this just obtains containing the old the finished product 2A that abandons rubber elastomer 62.50%～70.42% again.

With the last step obtain film, adhesive tape hangs in the stack gas chimney kiln/chamber of oxygen free condition, under 100-120 ℃, condition of normal pressure, insulation is handled 2-3 round the clock, reduces to room temperature naturally, obtain tensile strength and can be promoted to 16-20MPa by former 8-12MPa, rerum natura is greatly enhanced.

The innovative point of the described product preparation method of this embodiment is: broken through the pulverizing convention that will add loose black of elastomerics; Broken through carbon black that cracking damaged tire and destructive distillation rice husk, straw obtain must just can be used further to rubber, plastics earlier after pulverizing separately prior art; Changed when carrying out grinding and processing in rubber normal temperature fine pulverizer, feed back is only got the routine that coarse fodder is pulverized again; The preparation process of comminuting elastomer and rigidity powder mixture is migrated in the crushing operation equipment of traditional pure rigidity powder; Having changed preparation, to contain rubber powder, the mixing rubber master batch of sooty, master batch all be directly to use carbon black powder; Broken through in the conventional art, bubbled for preventing cross-linked rubber, needing that also rubber powder, carbon black etc. is provided with water content must not be greater than 1% stringent condition.

The innovative point of these routine described the finished product is: the product airborne dust is little or do not have airborne dust; Cross-linked rubber with this routine product preparation, its cutter cut surface be cannot see rubber powder, and the smell of sizing material under room temperature～180 ℃ do not have the characteristic odor of coal tar, Stockholm tar, Yatall MA, aromatic hydrocarbons wet goods nuisance less than the new standard natural rubber, get wet even sizing material makes moist, when sulfuration, also can not bubble.And the reclaimed rubber of prior art for preparing does not have the their defoaming function to sizing material; Preparation be coarser than the thick rubber powder of 90 purposes, mixing in sizing material, the visible rubber powder of cutter cut surface of its cross-linked rubber.

The present invention has proposed numerous classification materials and has come the described reclaiming aid group of assembly, Synergist S-421 95 in design and embodiment, as long as those skilled in the art is by design of the present invention and embodiment, with reference to embodiment, these materials are organized into described reclaiming aid group, Synergist S-421 95 one by one, again by novel process for regenerating of the present invention, just can obtain contamination-freely that a class is old abandons rubber or/and plastic content is 95%～5% masterbatch, master batch, rubber master batch intermediate product or the finished product.

The above-mentioned description to embodiment is can understand and apply the invention for ease of those skilled in the art.The person skilled in the art obviously can easily make various modifications to these embodiment, and needn't pass through performing creative labour being applied in the General Principle of this explanation among other embodiment.Therefore, the invention is not restricted to the embodiment here, those skilled in the art should be within protection scope of the present invention for improvement and modification that the present invention makes according to announcement of the present invention.

Claims (14)

1. a waste elastomer is or/and the new method for regenerating of plastics, comprises the steps 1 or/and step 2, wherein,

Step 1 is:

With granularity at 5-80 purpose waste elastomer or/and the bits of 5-40 order plastics, grain, bar, broken film and reclaiming aid group B1 weight part, place the combination processor; In room temperature～240 ℃; Working pressure is under normal pressure～3.5MPa condition, carries out the harmless regeneration course of processing: comprise mixing, pulverizing, screening, the disconnected sulphur of heating, swelling, emulsification, kneading, wherein one or more combined treatment; Obtain a class waste elastomer or/and plastic content is 95%～5% product 1, its pH value is between 5～14;

Step 2 is:

The waste elastomer of step 1 gained or/and plastic content is 95%～5% product 1 or commercial low rerum natura reclaimed rubber secondary raw material rubber, being mixed with Synergist S-421 95 B2 weight part, obtain the mixture of pH between 5～9, is room temperature～180 ℃ in service temperature; Working pressure is under the condition of normal pressure～0.1MPa, mixture is placed mixed assemblage machinery, after stirring or kneading, the further processing treatment of mixing, obtain containing waste elastomer or/and the product 2 of the masterbatch of plastic content 95%～5% or master batch or rubber master batch;

In step 1 and the step 2, grain is 100 weight parts in bits, grain, bar, broken film and the commercial low rerum natura reclaimed rubber secondary raw material rubber three sum of 5-80 purpose waste elastomer and 5-40 order plastics, reclaiming aid group B1 weight part and Synergist S-421 95 B2 weight part sum, B1+B2 is 5.3～1,900 weight parts;

Above-mentioned steps is characterised in that, in the step 1: adopt in the operating process of combination processor, one went on foot that pulverizer screening obtains be coarser than 90 purpose coarse fodders, be narrower than 250 purposes and cross fines, need both are mixed, by the placed in-line pulverizer reprocessing of the next one, perhaps return former pulverizer reprocessing and handle by specific pipeline;

In step 1 and the step 2: contain in reclaiming aid group and the Synergist S-421 95: be easy to be pulverized but the auxiliary material that is difficult for flying upward or/and the auxiliary material that is easy to be liquefied; The said auxiliary material that is easy to be pulverized but is difficult for flying upward is meant granularity between the 5-40 order, and once crosses machine through rubber normal temperature fine pulverizer and be milled to be narrower than and equal 200 purpose pellets; The auxiliary material that is easy to be liquefied is meant saponification, emulsification class material, odorless tenderizer class material.

2. as the said method of claim 1, wherein in the step 1, get 5～40 purpose waste elastomer buffings, grain, meal and carry out containing the auxiliary material that is easy to be pulverized but is difficult for flying upward, i.e. powder auxiliary material in the reclaiming aid group of adding when pulverizing;

When adopting roller pulverizer system 20～40 purpose rubber powders, with the weight of the 5-40 order powder auxiliary material that adds account for gained rubber powder mix products weight 3～10% for good;

When adopting the normal temperature ultrafine crusher to produce to be narrower than when equaling 90 purpose fine glue powders, 5～30% or the 70-95% that account for gained rubber powder mix products weight with the weight of the 5-40 order powder auxiliary material that adds are good.

3. as the said method of claim 1, in the step 1, get 5～40 purpose waste elastomer buffings, grain, when meal carries out saponification, emulsification, contain the auxiliary material that is easy to be liquefied in the reclaiming aid group that adds, comprising saponification, emulsification class material, especially comprise alkali, alkali and tensio-active agent, add entry or do not add water that then step 1 obtains being saponification, the emulsive waste elastomer product 1 of alkalescence;

In the step 2, add acid Synergist S-421 95 in the saponification of above-mentioned alkalescence, emulsive waste elastomer product 1, make the saponification that is alkalescence, the scope that emulsive waste elastomer intermediate product is converted into pH=5～9 again, obtain product 2, the water cycle of deviating from is used again.

4. as the said method of claim 1; in the step 1,2; old bits, bar, grain, the broken film of abandoning plastics cooperated with reclaiming aid group, Synergist S-421 95, obtain containing the old product 1,2 of abandoning plastics 95%～5% masterbatch or master batch or rubber master batch grain after fusing at high temperature, emulsification, mixing, the cooling.

5. as the said method of claim 1, in the step 1,2, bits, grain, meal and old bits, bar, grain, the broken film of abandoning plastics of getting 5～40 purpose waste elastomers cooperate with reclaiming aid group, Synergist S-421 95, between 120-240 ℃, carry out swelling, fusing, mixing, kneading, cooling process, obtain containing the product 1,2 of the rubber master batch of waste elastomer and plastics 95%～5%.

6. as the said method of claim 1, in the step 1,2, be lower than waste elastomer or/and under the old decomposition of abandoning the plastics macromolecule material, plasticization temperature, be ground into to be narrower than with the reclaiming aid group that contains powder auxiliary material, Synergist S-421 95 material and equal 90 purpose masterbatch products, or again with Powdered masterbatch through rolling the rubber master batch product 1,2 that obtains sheet, bits shape.

7. the method for claim 1, step 1 is or/and after 2, secondary raw material rubber is mixed with Synergist S-421 95, under oxygen free condition, smoke in glue room/chamber in digester (-tor), flue, between 100-240 ℃, carry out handling to 3 round the clock insulations in 1 hour, reduce to room temperature subsequently, obtain the secondary raw material rubber product that tensile strength is higher than raw material;

Wherein as the secondary raw material rubber of raw material comprise the rubber powder, resinifying agent, scrap rubber breast of commercially available mistake 20 order mesh screens, low rerum natura reclaimed rubber, through step 1 or/and 2 products that obtain;

Wherein used oxygen free condition preferably uses the oxygen free condition of reductibility stack gas, water, water vapour, one or more formation of rare gas element;

Wherein Synergist S-421 95 contains anti-aging agent;

Wherein used insulation treatment condition, preferably in stack gas under 100-120 ℃, condition of normal pressure, insulation is handled 2-3 round the clock, or in water vapour under 230-240 ℃, 3.5MPa condition, 1-5h is handled in insulation.

8. method according to claim 1, used Synergist S-421 95 in used reclaiming aid group, the step 2 in the step 1, be interim preparation or/and the mixture that becomes through preprocess;

The said reclaiming aid group of step 1, or/and plastics weight is 100 parts of benchmark, reclaiming aid group material specifically comprises in waste elastomer:

(1) essential component is easy to be pulverized but the auxiliary material and/or the auxiliary material that is easy to be liquefied, the i.e. powder auxiliary material that are difficult for flying upward: 5.3～1900 parts;

(2) choosing adds component, the reactive monomer of macromolecule material or emulsion form: 0～15 part;

(3) choosing adds component, friction resistant lubricant class material: 0～10 part;

(4) choosing adds component, the disconnected sulphur activator class material of odorless: 0～5 part;

(5) choosing adds component, antioxygen anti-aging agent class material: 0～5 part;

The said Synergist S-421 95 of step 2, its main component is selected from: powder auxiliary material, the tenderizer of odorless, the reactive monomer class material of macromolecule material, emulsion form, one or more in three kinds, three's sum accounts for 50.1～100% of Synergist S-421 95 gross weight; And according to downstream industry processing needs, add 49.9～0% one or more the functional material account for the Synergist S-421 95 total amount, said functional material is with one or more the combination of the disconnected sulphur activator class material of the friction resistant lubricant class material in the step 1 reclaiming aid group, odorless, antioxygen anti-aging agent class material.

9. method according to claim 1 is characterized in that:

The reclaiming aid group of step 1 wherein in (1) essential component, is easy to be pulverized but the auxiliary material that is difficult for flying upward, i.e. powder auxiliary material comprises following one or more pellet at least; The size of pellet is narrower than 200mm, is coarser than 200 orders, preferred 5-40 purpose pellet:

(a) has the material of peculiar smell adsorptivity, (b) industrial slag great soil group material, (c) vegeto-animal bone, leaf, root, straw, bar, shell, skin break flour class material, (d) inorganic mineral class material, (e) elastomerics reinforcement weighting material class material commonly used, (f) the calcining rear surface is the particulate class material of crude hard shape, (g) polycrystalline state compound composition class material; Wherein,

(a) have the material of peculiar smell adsorptivity, include but not limited to: gac, coke, atlapulgite, attapulgite, diatomite, wilkinite, more than granulation thing after one or more efflorescence;

(b) industrial slag great soil group material includes but not limited to: the granulation composition after one or more fine-powdered of the red mud that printed-wiring board (PWB), brick bits, chimney soot, slag, silicon powder, the aluminium manufacturer on slag ash, useless resol, waste paper scrap, useless fabric fibre, river course mud, assorted cullet, assorted waste ceramic, the waste electric appliance dumps, the aluminium ash that aluminium manufacturer dumps, alkali mud that soda factory dumps, salt slurry that chlor-alkali plant dumps are handled or be easy to the atomizing granular composition; Granulation composition after gypsum tailings mud fine-powdered that Citric Acid Plant, lactic acid factory, titanium powder plant, phosphoric acid factory, power plant dump is handled or be easy to the atomizing granular composition; The gypsum ironic hydroxide mixing slag mud that steel mill dumps, the slag mud that contains the ginkgo leaf fibres that bilobanone factory dumps, the fibre-bearing dregs of a decoction that the pharmaceutical factory of traditional Chinese medicine dumps, the fibre-bearing slag mud that artificial liner enterprise dumps, sugar refinery, pectin factory, tea processing factory, the fibre-bearing slag mud that the paper mill dumps, sugar, oil, medicine, the decolouring inactivation gac that the amino acid chemical plant dumps is or/and atlapulgite slag mud, the mine tailings mud that mining industry dumps, the ironic hydroxide mud that the chemical plant dumps, the burning slag that vitriol works dumps, the assorted pigment slag mud that pigment factory dumps, the black slag mud that the carbon black plant dumps, the boron mud that boron saltworks dumps, the barium slag that barium salt factory dumps, the strontium slag that strontium saltworks dumps, the zinc gray that zinc-plated factory dumps, the coal gangue that the colliery dumps, more than one or more fine-powdered after handling the granulation composition or be easy to the atomizing granular composition;

(c) vegeto-animal bone, leaf, root, straw, bar, shell, skin break flour class material, include but not limited to: vegeto-animal bone, shell, leaf, root, stem, straw, bar, nuclear, the grain bits combination material of the dry distillation charring of one or more of skin, rice husk, corn cob, straw, shell, cork, wood, leaf, the leaf of bamboo, withered grass, bark, shell, bone, hair, waste leather, the coconut palm cot, coconut palm palm fibre wood wool, the compounded plate bits of one or more of bamboo bits after roll rolls, rice hull ash, powdered rice hulls, the straw ashes, the straw powder, the shell powder, peanut hull meal, dust cork, wood powder, wood charcoal powder, leaf powder, bamboo leaf powder, the withered grass powder, tree bark powder, oyster shell whiting, bone meal, the waste leather powder, coconut palm cot powder, coconut palm palm fibre wood wool powder, bamboo powder, more than one or more powder granulation compositions or be easy to the granular combination of atomizing;

(d) inorganic mineral class material, include but not limited to: chrysotile-asbestos, krocodylite, Tremoliteor Tremoliteasbestos-asbestos, amosite asbestos, crocidolite, the white tremolite-asbestos, aluminite, feather alum, base aluminite, iron alum stone, natroalunite, pickeringite stone, bauxite, diaspore, the malthacite trolleite, gibbsite, augelite, lazurite, barite, calcined kaolin, acidic white earth, wilkinite, potter's clay, attapulgite, earth, serpentine, kolskite, magnesia cerolite, the magnesia cerolite of nickel, picrolite, cerolite, talcum, attapulgite, clinoenstatite, protobastite, forsterite, enstatite, hydrotalcite, foliated talc, cordierite, mountain cork, diopside, monticellite, manganolite, chloropal, allophane, quartzite, kaolin, lineae ablicantes stone, saponite, spadaite, silico-calcium sodium stone, hyalophane, celsian-felspar, anorthite, carnegieite, deweylite, hedenbergite, achmatite achmite, jurupaite, the zinc wernerite, rumpfite, kaliophylite, the buttress shaft nepheline, sodalite, hauyne, noselite, the pyrope garnet, iron aluminium garnet, the brownmillerite garnet, chrysolite, fayalite, willemite, fiber copper silicon ore deposit, meionite, marialite nai, sarcolite, wernerite, gehetinite, sillimanite, melilith, clinozoisite, lawsonite, sial calcium magnesite, dumortierite, staurotide, kornerupine, okenite, rankinite, gyrolite, the monocline rankinite, riversideite, beryl, apophyllite, mordenite, brusterite, the stripping zeolite, the barium staurotide, phillipsite, oblique euthalite, the oblique zeolite of sodium, the oblique zeolite of calcium, natrolite, thomsonite, the porcelain laubanite, light thin zeolite, erionite, single zeolite, zoisite, thaumasite, wollastonite, okenite, plazolite, hibschite, heulandite, euthalite, scolecite, stilbite, edingtonite, stilbite, lomontite, zeolite, aksaite, szaibelyite, carbon boron-calcium-magnesium stone, calciborite, howlite, pinnoite, Ke's hydrotalcite, the tremolite, hypersthene, the iron sepiolite, lazulite, vermiculite, bronzite, chlorite, nephrite, sepiolite, the iron magnesium amphibole, brown spar, amesite, vesuvianite, Tremoliteor Tremoliteasbestos, fine magnesite, brucite, anhydrous carnallite, Dou chlorite, rhombspar, ferrodolomite, gypsum, calcium phosphate, calcite, cancrinite, brushite, prehnite, aspidelite, zoisite, pistacite, callainite, halloysite, andaluzite, pyrophyllite, the iron halloysite, illite, chamosite, feldspar, Juanyingshi, montmorillonite, albite, potash feldspar, amarantite, the monocline modumite, delvauxite, ilmenite, monheimite, zinc～botryogen, carbon sodium rankinite, zincocopiapite, sauconite, smithsonite, hydrozincite, aurichalcite, copper lazur, brochantite, chrysocolla, oblique side's malachite, dioptase, orthite, rinkolite, nepouite, chlorite rises, the phosphorus-aluminium-strontium alum, perlite, the foam powder, opal, diatomite, white mica, biotite, phlogopite, calcium aluminate, the iron calcium aluminate, coal dust, graphite, more than after one or more pulverization process the granulation composition or be easy to the atomizing granular composition;

(e) rubber-plastic reinforcement weighting material class material commonly used, include but not limited to: damaged tire, waste tape, the scrap rubber pipe, the charcoal type curing composition of one or more destructive distillation gained of the useless macromolecule material product of useless shoes, carbon black, light calcium carbonate, white carbon black, lithopone, kaolin powder, gypsum, vermiculite power, Strontium Sulphate, barium sulfate, wollastonite powder, staple fibre, the charcoal fiber, secondary calcium phosphate, calcium phosphate, Calcium Fluoride (Fluorspan), strontium fluoride, barium fluoride, magnesium fluoride, secondary magnesium phosphate, silicic acid, Calucium Silicate powder, strontium silicate, barium silicate, barium carbonate, antimonous oxide, zinc borate, aluminium hydroxide, magnesium hydroxide, lime, calcium hydroxide, more than one or more efflorescence granulation composition after handling;

(f) the calcining rear surface is the particulate class material of crude hard shape, include but not limited to: calcined kaolin powder, calcinated argil, calcined diatomite, flyash, calcining attapulgite, calcining wilkinite, cenosphere powder, more than granulation composition after one or more efflorescence;

(g) polycrystalline state compound composition class material; Include but not limited to: comprise by one or more efflorescence things of above-mentioned (1) (a) and (b), (c), (d), (e), (f) material and the granulation composition after one or more efflorescence of the atypical material that aqueous phase combines again, described atypical material, its general formula is:

∑ai Di·∑bi Ei·ZH ₂O，

∑ ai in the general formula, ∑ bi, Z, be a mole indeterminate coefficient, wherein ∑ ai, Z can be zero, and ∑ bi must not be zero;

The expanded formula of general formula is:

[a1D1·a2D2......anDn·b1E1·b2E2......bmEm·ZH ₂O]

Or [∑ ai (D1, D2......Dn) ∑ bi (E1, E2......Em) ZH ₂O],

D1 in the general formula expanded formula, D2......Dn are one or more the powder in aforementioned (1) (a) and (b), (c), (d), (e), (f) material, E1 in the general formula, E2......Em are following listed compound newly-generated in liquid phase, include but not limited to:

Calcium sulfate, secondary calcium phosphate, calcium phosphate, Calcium Fluoride (Fluorspan), strontium fluoride, barium fluoride, magnesium fluoride, magnesium hydroxide, magnesiumcarbonate, secondary magnesium phosphate, silicic acid, Magnesium Silicate q-agent, Calucium Silicate powder, strontium silicate, barium silicate, pure aluminium silicate, zinc silicate, zinc carbonate, zinc subcarbonate, zinc phosphate, basic zinc sulfate, zinc sulphide, zinc hydroxide, aluminium hydroxide, ironic hydroxide, alkali formula iron(ic) chloride, ferric subsulfate, Strontium Sulphate, barium sulfate, metatitanic acid, without the incinerating lithopone, lithopone, boric acid, metaboric acid, sodium tetraborate, zinc borate, barium metaphosphate, aluminum borate, citrate of lime, calcium lactate and barba hispanica, ultramarine, titan yellow, zinc yellow, lithol red, phthalocyanine is red, phthalocyanine blue, phthalocyanine green, fluorescent yellow pigment, above-mentioned one or more combination;

In (1) of reclaiming aid group essential component, the auxiliary material that is easy to be liquefied is meant: (h) saponification, emulsification class material, (i) odorless tenderizer class material in the step 1; Wherein:

(h) saponification, emulsification class material comprise: alkali, alkali and tensio-active agent material;

Described alkali includes but not limited to: the combination of one or more in sodium hydroxide, potassium hydroxide, yellow soda ash, salt of wormwood, the calcium hydroxide;

Described tensio-active agent material comprises again:

The combination of one or more in aniorfic surfactant, nonionic surface active agent, the amphoteric surfactant;

Wherein said aniorfic surfactant, include but not limited to: saponification rosin, saponification shellac, stearic saponified, fatty is saponified, aerosol-OT salt, 1,2-dibutyl naphthalene-6-sodium sulfonate, oleic acid normal-butyl sulfuric ester sodium salt, ricinoleate acid butyl sulfuric ester two (or three) ethanolamine salt, N-oleoyl N-methyltaurine sodium, sodium lauryl sulfate, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, alkyl sodium sulfonate, sodium alkyl benzene sulfonate, the polyoxyethylene alkyl ether sulfate sodium salt, the benzyl naphthalene sodium sulfonate, alizarin assistant, the dinaphthylmethane sodium disulfonate, dispersing agent MF, the condenses of benzyl naphthalene sodium sulfonate and formaldehyde, potassium alkyl phosphate, the lauryl alcohol phosphate kalium salt, soap, soap stock, more than one or more combination;

Wherein said nonionic surface active agent, include but not limited to: the ethylene oxide condensate of C7～C9 straight chain fat, Oleum Cocois alkyl oxalamide, fatty alcohol-polyoxyethylene ether, the fatty alcohol-polyoxyethylene ether of C12～C18, the dodecyl phenol polyethenoxy ether, octane phenol Soxylat A 25-7--10, the polyethylene Viscotrol C, the sorbitan oleic acid polyoxyethylene, sorbitan stearate, sorbitan monooleate, the sorbitan stearate Soxylat A 25-7, polypropylene glycol and ethylene oxide adduct, polyoxyethylated coconut oil alcohol, in the Triton X-100, more than one or more combination;

Wherein said amphoteric surfactant includes but not limited to: the combination of one or more in N-dodecyl L-Ala, the empgen BB;

(i) odorless tenderizer class material; Comprise following one or more material:

(i～a) oil plant benevolence, fruit material, (and i～b) vegetables oil, resin and derivatives class material, (i～c) contains grease decolouring slag mud class material, and (the rubber and plastic tenderizer commonly used of i～d); Wherein,

(i～a) oil plant benevolence, fruit material, include but not limited to: tung oil tree benevolence, Fructus oleae europaeae benevolence, coconut benevolence, cotton seed benevolence, vegetable seeds, Semen arachidis hypogaeae, soybean, Fruit of Fortune Windmillpalm benevolence, Safflower fruit, Semen Helianthi, Cha Ziren, Semen Lini, perillaseed benevolence, rubber seed benevolence, Fructus oleae europaeae meat, Semen Sapii benevolence, Wood of Shinyleaf Yellowhorn benevolence, ansu apricot benevolence, hair Lai, fibert, Chinese pistache, chinaberry, walnut kernel, samara oil tree benevolence, immature pine nut, above-mentioned one or more combination;

(the vegetables oil of i～b), resin and derivatives class material, include but not limited to: Fructus Maydis oil, Rice pollard oil, oleum gossypii seminis, rape seed oil, peanut oil, soybean oil, plam oil, Oleum Helianthi, sweet oil, tea-seed oil, coconut benevolence oil, tung oil, Toenol 1140, Semen Sapii benevolence oil, perilla oil, the restaurant refiltered oil, rosin, alizarin assistant, staybelite, westvaco rosin, ester gum, pentalyn, the dimethylbenzene Gum Rosin, rosin ester, the pine tree resin, the metasequoia resin, the elm resin, the peach resin, useless peanut paste, above-mentioned one or more combination;

(i～c) contain grease decolouring slag mud class material includes but not limited to: the grease-contained gac that grease, refinery decolorizing purification workshop section dump or the slag mud of carclazyte, the foam oil slick of deviating from the recycled writing paper production that contains printing ink;

(i～d) rubber and plastic is used tenderizer always, include but not limited to: lubricating oil, machine oil, white oil, halogenated paraffin oil, paraffin oil, third fractional oil, six line oil, transformer oil, polybutene oil, C4～18 lipid acid, Vaseline, halogenated paraffin, paraffin, beeswax, animal oil, dark substitute, white factice, odorless bitumen, epoxy soybean oil, alkyl phenolic resin, the rare resin of terpene, petroleum resin, special octyl phenol urea formaldehyde, coumarone, styrene resin, low-molecular polyethylene wax, low-molecular polypropylene wax, stearic acid, Palmiticacid, oleic acid, palmitinic acid, polyvinyl alcohol, amylalcohol, hexanol, enanthol, octanol, decyl alcohol, lauryl alcohol, tetradecyl alcohol, hexadecanol, stearyl alcohol, cyclopentanol, hexalin, phenylcarbinol, ethylene glycol, propylene glycol, glycerol, 2-Ethylhexyl Alcohol, sec-n-octyl alcohol, lauryl alcohol, Terpineol 350, (C7～18) mixed fatty alcohol, tetramethylolmethane, Xylitol, dipropylene glycol, dioctyl phthalate (DOP), dibutyl phthalate, diisobutyl phthalate, dialphanyl phthalate, tributyl phosphate, triethyl phosphate, triphenylphosphate, Tritolyl Phosphate, di(2-ethylhexyl)phosphate phenyl-2-ethylhexyl, the terephthalic acid dibutyl ester, the hexanodioic acid dibutyl ester, hexanodioic acid two-2-(ethyl hexyl) ester, sebacic acid two-2-(ethyl hexyl) ester, above-mentioned one or more combination;

Above-mentioned (1) (a) and (b), (c), (d), (e), (f), (g) these materials, must anticipate become to be difficult for to fly upward and be easy to again pulverized,, powder, this piece, grain, powder are coarser than 200 orders, and are narrower than 200mm, preferred 5-40 purpose pellet;

In fiber material contained in (1) (a) and (b), (c), (d), (e), (f), (g) these materials, preferably those can once be crossed machine by rubber normal temperature fine pulverizer and are milled to be narrower than and equal 60 purpose materials;

In (1) (a) and (b), (c), (d), (e), (f), (g),, must implement to feed intake operation with the form of packing material less than the material of the easy airborne dust of 40 orders;

(1) ratio of these materials combinations of (a) and (b), (c), (d), (e), (f), (g), according to its with waste elastomer or/and after plastics mix, make that the pH in masterbatch, master batch, the rubber master batch product is 5～12, preferably pH is 5～9 definite; And the material that has pH resiliency person after the preferably combination;

In the step 1, contain 95%～70% waste elastomer or/and being narrower than when equaling 90 purpose fine rubber powder mixtures of plastics when preparing with rubber normal temperature fine pulverizer, aforementioned (1) contained in the reclaiming aid group is eight materials (a)～(g), be required to be 5～200 purpose grain powders, preferred 5～40 purposes are easy to pulverized pellet;

In the step 1, when adopt before building stones mill in small, broken bits, have series connection just, in the large-scale pulverizer preparation of mining industry of broken function contain 30%～5% elastomerics or/and the mixture of plastics, and when handled mixture can not be clamminess conglomeration, the reclaiming aid group contains aforementioned (1) (a)～(g) eight, and this reclaiming aid group material is gone into the grain size of machine at decimeter grade;

(1) (h) saponification of reclaiming aid group, emulsification class material in the step 1, its consumption, can change in 0～10 part of scope or/and plastics weight is 100 parts of benchmark in waste elastomer;

(1) of reclaiming aid group (i) odorless tenderizer class material in the step 1, the weight content in the product 1 that step 1 obtains is: 0～30%, but be good with 3～20%;

Above-mentioned nine sums of (1) (a) and (b), (c), (d), (e), (f), (g), (h), (i), its consumption or/and plastics weight is 100 parts of benchmark, are 5.3～1900 butt parts in waste elastomer when step 1;

Reclaiming aid group material in the step 1, wherein (2) choosing adds component, and the reactive monomer of macromolecule material or emulsion form comprises following one or more material at least:

(a) natural rubber and synthetic rubber (b) plastics, (c) reinforced resin, (d) resin emulsion, (e) rubber latex, (f) odorless bitumen;

Wherein said (b) plastics include but not limited to: the bits, bar, grain, powder, the coating materials that are recovered after polyvinyl chloride, chlorinatedpolyethylene, polyethylene, polypropylene, polystyrene, ethylene-ethyl acetate copolymer, urethane and these plastics products are discarded;

Wherein said (c) reinforced resin includes but not limited to: resol, polyvinyl acetal resin, urethane;

Wherein said (d) resin emulsion includes but not limited to: ACRYLIC EMULSION, vinyl acetate emulsion, polyvinyl acetal emulsion;

Wherein said (e) rubber latex includes but not limited to: nature rubber latex, synthetic rubber latex;

Wherein said (f) odorless bitumen includes but not limited to: odorless oxidized bitumen, odorless highway asphalt, odorless emulsion pitch, odorless rubber, mould modifying asphalt;

Reclaiming aid group material in the step 1, wherein (2) choosing adds component, the reactive monomer of macromolecule material or emulsion form, its (2) (a)～(e) five sum add-ons are: 0～15/100 part, in waste elastomer or/and the plastics weight basis;

Reclaiming aid group material in the step 1, wherein (3) choosing adds component, and friction resistant lubricant class material comprises following one or more material at least:

(a) cationic surfactant, (b) aniorfic surfactant, (c) nonionic surface active agent, (d) amphoteric surfactant, (e) silicone based material, and the tensio-active agent that (f) comes from plant fully; Above-mentioned friction resistant lubricant, its consumption account for 0～5% of the free-water amount in the material handling of being reproduced by weight, are good with 0.2%～5%, or account for to be reproduced and handle 0～3% of solid substance, are good with 0.2%～3%; Wherein said:

(a) cationic surfactant, include but not limited to: stearyl dimethyl benzyl ammonium chloride, dodecyl benzyl dimethyl ammonium chloride, trolamine list olein, alkyl phosphate di-alcohol ammonium salt, octadecyl dimethyl hydroxyethyl season ammonium salt, trihydroxyethyl quaternary ammonium Methylsulfate, more than one or more combination;

(b) aniorfic surfactant, include but not limited to: saponification rosin, saponification shellac, stearic saponified, fatty is saponified, aerosol-OT salt, 1,2-dibutyl naphthalene-6-sodium sulfonate, oleic acid normal-butyl sulfuric ester sodium salt, ricinoleate acid butyl sulfuric ester two (or three) ethanolamine salt, N-oleoyl N-methyltaurine sodium, sodium lauryl sulfate, to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt, alkyl sodium sulfonate, sodium alkyl benzene sulfonate, the polyoxyethylene alkyl ether sulfate sodium salt, the benzyl naphthalene sodium sulfonate, alizarin assistant, the dinaphthylmethane sodium disulfonate, dispersing agent MF, the condenses of benzyl naphthalene sodium sulfonate and formaldehyde, potassium alkyl phosphate, the lauryl alcohol phosphate kalium salt, soap, more than one or more combination;

(c) nonionic surface active agent, include but not limited to: the ethylene oxide condensate of C7～C9 straight chain fat, Oleum Cocois alkyl oxalamide, fatty alcohol-polyoxyethylene ether, the fatty alcohol-polyoxyethylene ether of C12～C18, the dodecyl phenol polyethenoxy ether, octane phenol Soxylat A 25-7--10, the polyethylene Viscotrol C, the sorbitan oleic acid polyoxyethylene, sorbitan stearate, sorbitan monooleate, the sorbitan stearate Soxylat A 25-7, polypropylene glycol and ethylene oxide adduct, polyoxyethylated coconut oil alcohol, Triton X-100, more than one or more combination;

(d) amphoteric surfactant includes but not limited to: the combination of one or more of N-dodecyl L-Ala, empgen BB;

(e) silicone based material, include but not limited to: methyl-silicone oil, ethyl silicon oil, methyl phenyl silicone oil, two-[3-triethoxyl silane propyl group] tetrasulfide, r-sulfydryl propyl trimethoxy silicane, dimethyldimethoxysil,ne, methyltrimethoxy silane, methyl triacetoxysilane, Union carbide A-162, tetramethoxy-silicane, tetraethoxysilane, dimethyldiethoxysilane, more than one or more combination;

(f) come from the tensio-active agent of plant fully, include but not limited to: the water extraction of Leaf of Shrubalthea, the water extraction of Chinese honey locust, the water extraction that will is far away, the water extraction of balloonflower root, the water extraction of sea-tangle, more than one or more combination;

(g) wax class includes but not limited to: halogenated paraffin, paraffin, beeswax, low-molecular polyethylene wax, low-molecular polypropylene wax, more than one or more combination;

(h) organic acid and its esters, include but not limited to: stearic acid, Zinic stearas, barium stearate, calcium stearate, strontium stearate, Magnesium Stearate, lipid acid barium, fatty acid magnesium, fatty acid calcium, lipid acid strontium, barium laurate, calcium laurate, ricinolic acid barium, ricinolic acid calcium, zinc ricinate, barium naphthenate, calcium naphthenate, zinc resinate, more than one or more combination;

Reclaiming aid group material in the step 1, wherein (3) choosing adds component, friction resistant lubricant class material, its (3) (a)～(h) eight sum add-ons are: 0～10/100 part, in waste elastomer or/and the plastics weight basis;

Reclaiming aid group material in the step 1, wherein said (4) choosing adds component, and the disconnected sulphur activator class material of odorless comprises one or more the material in the A group, or A group and B, C make up one or more the combination in the material; The desulfurization activator class material of odorless is mixed by following weight ratio and forms,

=100～2%/0～98%/0～98%, three groups of combinations of A group/B group/C group consumption is: 0.1～5 part/100 parts, in the old vulcanized elastomer rubber powder weight basis of abandoning;

Wherein said A group material, be to have to play chain scission and not generate the material of hydrogen sulfide again in pH5～14 scopes to the elastomerics sulfide linkage, include but not limited to: potassium ferric oxalate, Ferrox, ironic oxalate, zinc, caoxalate, calcium peroxide, hydrogen peroxide calcium sulfate adducts, hydrogen peroxide sodium sulfate, hydrogen peroxide copper sulfate, zinc oxalate, Ferrox zinc, bodied ferric sulfate, Sulfothiorine, S-WAT, sodium bisulfite, ferrous sulfate zinc, alkali formula iron(ic) chloride, iron protochloride, cerous hydroxide, Cerium monophosphate, ferric subsulfate, ferrous sulfate copper, zinc chloride, zinc silicate, zinc carbonate, zinc subcarbonate, zinc phosphate, basic zinc sulfate, zinc hydroxide, phosphoric acid hydrogen is ferrous, phosphoric acid one hydrogen zinc, the ferrous zinc of phosphoric acid hydrogen, the ferrous copper of phosphoric acid hydrogen, zinc sulfate, copper sulfate, copper hydroxide, cupric phosphate, nickel hydroxide, nickelous carbonate, rose vitriol, the ferrous zinc of sylvic acid, sylvic acid is ferrous, zinc abietate, the sylvic acid cobalt, zinc naphthenate, cobalt naphthenate, the lipid acid cobalt, fatty acid zinc, Zinic stearas, Zinc Gluconate, Ferrous Gluconate zinc, zinc laurate, zinc palmitate, calglucon, glucose, waste molasses, ventilation breather, the peacock stone flour, zinc powder, aluminium powder, the aluminium foil bits, the nano level copper powder, nano grade iron powder, cupric oxide powder, leaded plastic waste, contain the cadmium plastic waste, it is leaded or/and the plastic waste of cadmium is done the slide slag, contain chromium scrap leather bits, contain chromium shark bone glue, the refuse battery crushed material, metatitanic acid, the quadrol tetrem is ferrous, xitix, Magnesium ascorbate, the tetramethyl-ammonium halide, hexadecyl ethyl dimethyl ammonium halide, hexadecyl methyl diethyl ammonium halide, monobutyl dimethyl benzyl ammonium halide, the octadecyl ammonium halide, 3,5-dimethylphenyl benzyl ammonium halide, the dimethyl diphenyl ammonium halide, methylethyl propyl group isobutyl-ammonium halide, the tetradecyl trimethyl-ammonium halide, tetradecyl dimethyl ammonium halide, cetyl dimethyl benzyl ammonium halide, hexadecyl halogenation pyridine, tetradecyl halogenation pyridine, dodecyl halogenation pyridine, tetrabutyl halogenation pyridine, ethyl dixylyl ammonium halide, oil base dimethyl benzyl ammonium halide, hexadecyl ethyl dimethyl ammonium halide, 2-thiol benzothiazole zinc, benzene a pair of horses going side by side thiazolyl disulphide, N-cyclohexyl-2-benzene a pair of horses going side by side thiazole sulfinyl amine, the N-tertiary butyl-2-benzene a pair of horses going side by side thiazole sulfinyl amine, ziram, zinc diethyldithiocarbamate, the dipropyl zinc dithiocarbamate, zinc dibutyl dithiocarbamate, zinc dibenzyldithiocarbamate, blue female disulphide of tetraethyl-autumn, blue female disulphide of tetramethyl-autumn, blue female disulphide of tetrabenzyl autumn, N, N '-diphenylguanidine, di-o-tolyl guanidine, 4,4 '-dithiomorpholine, zinc dibutyldithiophosphate, more than one or more combination;

B organizes material, include but not limited to: rosin, staybelite, dimethylbenzene Gum Rosin, special octyl phenol urea formaldehyde, coumarone, alizarin assistant, oleum gossypii seminis, rape seed oil, peanut oil, soybean oil, plam oil, Oleum Helianthi, sweet oil, tea-seed oil, paraffin, stearic acid, beeswax, rubber, desulfurization plasticizing rubber powder, thermoplastic elastomer, more than one or more combination;

C organizes material, includes but not limited to: semi-hydrated gypsum powder, potter's clay powder, calcium sulfate dioxide composite Si powder, more than one or more combination;

Reclaiming aid group material in the step 1, (5) choosing wherein adds component, antioxygen anti-aging agent class material, at least comprise and be selected from down in the listed material one or more, its consumption or/and plastics weight is 100 parts of benchmark, is 0～5 part in waste elastomer, preferred 0.1～5 part/100 parts;

Said antioxygen anti-aging agent class material includes but not limited to:

N-phenyl-αNai An is an antioxidant A; 3 acetaldols-2-naphthylamines is antioxidant A H; 3 acetaldols-2-naphthylamines is antioxidant A P; styrenated diphenylamine is antioxidant D FC-34; 4; 4 '-two (α; α-Er Jiajibianji) pentanoic is anti-aging agent KY-405; octylated diphenylamine is anti-aging agent ODA; N-phenyl-B-naphthylamines is an antioxidant D; mixing two aromatization pentanoic is anti-aging agent WH-02; N-cyclohexyl-p-ethoxyaniline is anti-aging agent CEA; N-cyclohexyl-P-nethoxyaniline is anti-aging agent CMA; N-cyclohexyl-p-ethoxyaniline is anti-aging agent CEA; N-phenyl-N '-cyclohexyl Ursol D is antioxidant 4010 or CPPD; N-phenyl-N '-sec.-propyl-Ursol D is antioxidant 4010NA or IPPD; N-(1; the 3-dimethylbutyl)-N '-diphenyl-para-phenylene diamine is an anti-aging agent 4020; N; N '-two (1; 4-dimethyl amyl group Ursol D is an anti-aging agent 4030; N-1; 4-N '-dimethyl amyl group-N '-phenyl-Ursol D is an anti-aging agent 4050; N; N '-phenylbenzene-Ursol D is antioxidant H or DPPD or PPD; N; N '-diphenyl-para-phenylene diamine is antioxidant D TPD or anti-aging agent 3100; N-secondary octyl-N '-diphenyl-para-phenylene diamine is an anti-aging agent 688; the compound of N-secondary octyl-N '-diphenyl-para-phenylene diamine and anti-aging agent RD is anti-aging agent 8PPD; N; N '-two (betanaphthyl) Ursol D is antioxidant D NP; N-2-aminomethyl phenyl-N '-2-tolyl Ursol D; N-2-aminomethyl phenyl-N '-2; the 6-dimethyl-p-phenylenediamine; N-2; 6-3,5-dimethylphenyl-N '-2; 6-3,5-dimethylphenyl blend of p phenylene diamine is anti-aging agent PPD-B; N-(p-methylphenyl alkylsulfonyl)-N '-diphenyl-para-phenylene diamine is anti-aging agent TPPD; N-phenyl-N '-(3-methacryloyl oxo-2-hydroxypropyl) Ursol D is anti-aging agent G-1; acetone and pentanoic low-temp reaction thing are antioxidant A M; acetone and pentanoic pyroreaction thing are antioxidant BLE; 6-oxyethyl group-2; 2; 4-trimethylammonium-1; the 2-dihyaroquinoline is antioxidant A W; 2; 2; 4-trimethylammonium-1; the 2-dihyaroquinoline is an aging inhibitor FR; 2; 2; 4-trimethylammonium-1; 2-dihyaroquinoline polymer is an anti-aging agent RD; the Resorcinol benzyl oxide is antioxidant MB A; the hydroquinone dibenzyl ether is an antioxidant DBH; N; N; N '; N '-tetraphenyl diamino methane is anti-aging agent 350; 1; 3; 5-trimethylammonium-2; 4; 6-three (3; the 5-di-tert-butyl-4-hydroxyl benzyl) benzene is anti-aging agent 330; 2; the 6-di-tert-butyl-4-methy phenol is an antioxidant 264; the mixture of one hydrocarbonylation bis-phenol is an anti-aging agent 651; styrenated phenol is an antioxidant SP; 2; 2 '-methylene-bis (4-methyl-6-tert butyl phenol) is an antioxidant 2246; 4; 4 '-butyl-two (3 methy 6 tert butyl phenol) is anti-aging agent W-300; 1; 1; 3-three (2-methyl-4-hydroxyl-5-tert.-butyl phenol) butane is anti-aging agent CA; 2; 2; the 6-di-tert-butyl-4-methy phenol is an antioxidant 264; 2-thiol group benzimidazolyl is an antioxidant MB; 2-thiol group benzimidazolyl zinc salt is antioxidant MB Z; Tyox B is an anti-oxidant DLTP; three (nonyl phenyl) phosphorous acid ester is anti-aging agent TNP; three (2; the 4-di-tert-butyl-phenyl) phosphorous acid ester is an anti-aging agent 168; TBP; the dibutyl disulfide group is an antioxidant NBC for carboxylamine nickel; phosphorous acid benzene di-isooctyl; phosphorous acid dihydroxyphenyl propane ester; hydrazonium sulfate; titanyl sulfate; ferrous sulfate; iron protochloride; ferrous ammonium sulphate; oxammonium hydrochloride; tri-isopropanolamine; oxalic acid, more than one or more combination.

10. the method for claim 1 is characterized in that described combination processor, is meant one or more combination of following equipment:

The stirring desulphurization jar that uses in water or the water/oil method regenerated rubber technology, or the dynamic and static digester that uses in the oil process regenerated rubber technology, or the pulverizer that uses in the normal temperature crushing up glue powder craft, the mining pulverizer of stone material, the wind-force pulverizer, or the mill, refiner, Banbury mixer, forcing machine, the stirring mixer that use in the elastomerics processing, and various rubber and plastics are with the unit equipment that carries out abrasive dust, mixing, compressing tablet, granulation operation on powder auxiliary, the auxiliary material production line, digester (-tor), flue is smoked glue room/chamber.

11. the method for claim 1, wherein said combination processor is characterized in that comprising that one or more combinations as described below are provided with:

A. before the unit in small, broken bits or/and back feeding device;

B., the fine crusher cohort that can be divided into many groups is arranged;

C. on many groups feeding pipe of fine crusher cohort, there is feed rate to compare setting device;

D. have and thick, the fine powder material that classification, sieve apparatus are selected to be collaborated and return for the feeding back device of pulverizing;

E. newly pulverize the rubber normal temperature fine pulverizer of crudeization of abrasive dust working face of cutterhead;

F. have behind one of five of aforesaid claim item 8a～8e or five combination of features machinery and be equipped with the setting that more is tending towards perfect again;

Specifically, wherein, a. before the unit in small, broken bits or/and after the machinery that can add auxiliary material is arranged, the mechanism of described adding auxiliary material, at least be the device that has the weighing of a unitary energy, described weighing device can be the scale that can weigh or bucket, groove, the pipe of measuring volume, quantitatively screw rod conveyor, or their combination;

The mechanism of described adding auxiliary material, also be to have a unitary auxiliary material that can make adding and micelle, rubber powder blended mechanism mutually at least, described auxiliary material and micelle, rubber powder be the blended mechanism mutually, can be bucket, groove, the pipe that has band to stir, or shell can be done bucket, groove, the pipe of rotation, or their combination;

The mechanism of described adding auxiliary material is good with what have airtight dustproof construction;

Wherein, b. has the fine crusher cohorts that can be divided into many groups, and its feature comprises: having one can be the fine crusher cohort that is divided into three groups of two groups of A, B or A, B, C at least;

Described fine crusher cohort, three groups of two groups of A wherein, B or A, B, C, every group contains a unit fine crusher at least;

Described A, B, C unit in small, broken bits all are in parallel in it is organized separately, connect 5～40 order coarse fodder storehouses on the A group, connect the pulverizing of A group, tailover feed back pipeline on B organizes, and connect the pulverizing of B group, tailover feed back pipeline on the C group; The outlet that two groups of A, B or A, B, C are three groups can be parallel connection, and its outlet in parallel connects classification, sieving machine down behind spiral separator; The outlet of B, C group can be not in parallel with the outlet of A group yet, and it exports separately can walk around classification, the through fine powder storage bin of sieving machine; The outlet of B, C group also can both join classification, sieving machine by valve pipeline, through again fine powder storage bin;

Described fine crusher cohort, the production capacity configuration characteristics between its unit are: be divided into two groups, its preferable production capacity configuration than scope is: A/B=2/1～9/1; Be divided into three groups, its preferable production capacity configuration than scope is: A/B/C=1/1/1～5/3/1;

Wherein, c has feed rate than setting device on many groups feeding pipe of fine crusher cohort, its feature comprises: fine crusher is divided into two groups of A, B, and its feed rate than regulation range is: A/B=2/1～9/1; Fine crusher is divided into three groups of A, B, C, and its feed rate than regulation range is: A/B/C=1/1/1～5/3/1;

Wherein, d has thick, the fine powder material that can select classification, sieve apparatus and flows back to for the machinery setting of pulverizing, its feature comprises: be provided with the meal material of not crossing 90 mesh sieves that can tell classification, sieve apparatus, cross fine powder material and stream more than 200 orders with crossing, supply with 5～40 order batch mixes storehouses or B, the C group fine crusher mechanism pulverized of row more then;

Wherein, f is provided with the setting that more is tending towards perfect again; its feature comprises: have to add behind one of five of aforementioned a～e or five s' described combination of features machinery to make the ultra-fine elastomerics powder row machinery of reuniting again, described machinery includes but not limited to again: the combined machine of one or more of powder tablets press, screw extrusion press, rolling press, mill.

12. the preparation-obtained product 1 of the method for claim 1 and 2 are dustless for a kind of odorless, contain masterbatch or the master batch or the rubber master batch mixture of waste elastomer and/or plastics 95%～5%, other reclaiming aid and Synergist S-421 95 account for 5%～95%; Be characterised in that and contain waste elastomer and/or oldly abandon plastics 95%～70% and contain waste elastomer and/or the old plastics 30%～5% of abandoning; And the granularity of product is narrower than and equals 90 orders.

13. product 1 as claimed in claim 12 and 2 is characterized in that: under the hot extrude of elastomerics, plastic product industry, hot-forming condition, can be mixed into one fully mutually, promptly on the cutter cut surface of goods, can not see rubber powder granule with virgin material; And under the hot-work condition of downstream product industry, odorless, promptly smell is not more than new sizing material; Also odorless under the room temperature.

14. as claim 12, the application of 13 described products 1 and 2 on following direction:

A. be used in elastomerics, plastic article industry, use as functional auxiliary material or auxiliary agent;

B. be used in elastomerics, plastics with auxiliary material or auxiliary agent production, make product become masterbatch, master batch, rubber master batch formulation and reduce or eliminate airborne dust by the powder formulation;

C. prepare modifying asphalt, waterproof roll, paint, tackiness agent with it, and be used for rubber, mould fire retardant master batch, rubber master batch, the look mother of goods industries.

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