CN107200885A

CN107200885A - A kind of regeneration matter rubber mixes its rubber or rubber and plastic compound composition product and preparation method

Info

Publication number: CN107200885A
Application number: CN201710094488.2A
Authority: CN
Inventors: 鱼伟令; 胡嘉庆; 沙良宝; 陈汇宁; 陈汇宏
Original assignee: Individual
Current assignee: Individual
Priority date: 2016-02-25
Filing date: 2017-02-21
Publication date: 2017-09-26
Anticipated expiration: 2037-02-21
Also published as: CN107200885B

Abstract

The present invention provides a kind of regeneration matter rubber or mixes its rubber or rubber and plastic compound composition product and preparation method, is related to component A obtained by thermoplastification, or/and normal temperature gained B component in small, broken bits, or A/B compound compositions, or mix A or/and B rubber or rubber and plastic compound composition；The product feature of environmental protection is characterised by：Take 3~5g of A or/and B samples, in sample each one mylar of pad up and down, then it is put on vulcameter OR gate Buddhist nun's viscosity apparatus, it is heated 10 minutes at 180 DEG C, take out sample, park at room temperature no less than 5 minutes, then the mylar above and below sample is taken off and be stacked again, and move to observation under fluorescent lamp, mylar will not be deeper than the 101C or 601C of international standard color (Pan PANTONE leads to) card by yellow colouration, or and will not give out any or more feature stench for planting combination of coal tar, pine tar, aromatic naphtha, pitch, or and the people that chokes peculiar smell；Compound composition containing A/B is characterised by：Any proportion by A/B weight than 95/5 to 5/95 scope is pre-mixed.

Description

A kind of regeneration matter rubber mixes its rubber or rubber and plastic compound composition product and preparation method

Technical field

The present invention proposes a kind of regeneration matter rubber or mixes its rubber or rubber and plastic compound composition product and preparation method, is related to right Scrap rubber resource is implemented " in full, green, high level, energy-conservation " and changed under four full buckle-type combined method frameworks, further lifts heat again Raw rubber (component A) and the intension of the green and high level physical property of normal temperature rubber powder in small, broken bits (B component) etc., belong to scrap rubber resource regeneration Technical field.

Technical background

From saying in the world, to the existing century-old history of regeneration of scrap rubber.The main object of scrap rubber regeneration is automobile With the damaged tire abandoned, damaged tire is accounting for waste rubber product total amount more than 60% now.To the resource regeneration profit of damaged tire With at present in the newest issue of China《Scrap rubber comprehensively utilizes industry " 13 " development plan guiding outlines》(hereinafter referred to as Industry outline) embodied in mainstream technology direction be still improvement arranged side by side of both reclaimed rubber, fine glue powder etc., and industry The industry yield rate of " 13 " development that outline is expected carefully is scheduled on 7%, i.e., still may be used in expected " 13 " Can be profitless！And《Chinese tire recycles industry " 13 " development plan》Institute in (hereinafter referred to as sector planning) It is reclaimed rubber, fine glue powder, improvement arranged side by side of thermal cracking three etc. to embody to the mainstream technology direction of damaged tire.

It is that market is in short supply far more than pin in the most deficient country of a rubber sources, the supply history of rubber raw materials that China, which is, Gesture is low；And the year growing amount of the scrap rubber such as damaged tire then rises year by year, far surpass 12,000,000 tons to the end of the year 2015.At present I The rubber industry market of state is just temporarily in the historical most downturn period, and the market price of import natural rubber much breaks the country by a fall Eldest child --- tyre industry in the cost price of natural gum, Rubber Industry chain, national average profit rate in 2015 is rare to be exceeded 5%！Scrap rubber is comprehensively utilized and tire recycles industry and then blown hard the wind of environmental protection, obstinate use coal tar preparation, regeneration rubber The factory of glue all faces the destiny closed down.

The market of rubber industry it is in short supply with it is low, just as four seasons samsara, this is a normal socioeconomic phenomenon, and is incited somebody to action The waste rubber product recycling utilization such as damaged tire, this is the main trend that modern society's sustainable development must be pursued, at me State is currently called under the big atmosphere that popular innovation, millions of people are started an undertaking, and is emerged in large numbers in damaged tire recycling field《Use green in full Ultra-fine rubber powder masterbatch new technology is made in damaged tire by the full buckle-type combined method of high level energy-saving four》(prize-winning certificate： CFLP2015-02-02-40), then it is by tradition and the thermal reclamation rubber, normal temperature method essence still innovated in respective field in bitter bucket Thin rubber powder, pyrolysis method refine oil this three big branch's technique, have imported the technology development of the brand-new combined method of scale coordinated implementation Direction, but fine main support patent ZL200810083330.6, ZL 201010275839.8 for analyzing this new technology etc. Then still feel there is deficiency：

Exist the high-grade damaged tire in part or and the separation from another part damaged tire in ZL200810083330.6 What is gone out implements the technical measures of thermal cracking containing miscellaneous steel wire, polyamide skeleton accessory substance together, and this just makes the high-grade damaged tire in part There is no high-value-use, this runs counter to the conception for four full buckle-types that combined method is advocated；

There is also deficiency by ZL201010275839.8：Its starting material put into agitating and heating device was 5~40 mesh sieves Scrap rubber coarse powder, this scheme for high-grade damaged tire, in this material must exist is not taken off on a small quantity by magnetic separation Most steel wire, material after heat treatment will removing impurities again, the filter glue of traditional highly energy-consuming or/and the nest mortar of refining are just fallen into again.

The application of the reclaimed rubber product obtained again from scrap rubbers such as damaged tires through hot recycling process is said, is pressed《Rubber Practical formulation is complete works of》(Xie Zhonglin, Yang Minfang are compiled, and Chemical Industry Press, Materials Science and Engineering publishing centre are published and distributed, 2 months 2004 second editions) listed formula is counted, it can be gathered that its application is characterized in：In formula of the downstream to reclaimed rubber At least 95% use above example in, is to use the reclaimed rubber for meeting so-called national standard, then add new rubber, reinforcing agent, fill out The materials such as material, softening agent, it is rare to do product with reclaimed rubber entirely through carrying out eating powder gluing again；Through this statistical analysis, and Go into seriously again, it can be found that：The existing reclaimed rubber defined in national standard, except it is relatively low in medium and high-grade system in tensile strength Outside physical property required by product, be more because its wear away it is higher, pressure-resistant it is relatively low, caused by the physical property such as bigger than normal that is permanently deformed is not enough, Cause to have in new product processed with plus the mode of virgin material corrected.

Same exists again《Rubber practical formulation is complete works of》The application examples found about rubber powder is analyzed, and can also be sent out It is existing：The rubber powder of existing (being definitely that normal temperature is in small, broken bits at home), except this rubber powder product is relatively low in tensile strength and elongation at break Made in newly outside the requirement of product, be more because its folding deviation, particle it is partially thick, itself can not wait the not enough institute of physical property in flakes Cause, cause it also to have in new product processed with adding the mode of virgin material to be corrected.

By above-mentioned right《Rubber practical formulation is complete works of》In, be related to it is existing regeneration matter rubber product --- hot method is again The application examples analysis of raw rubber or/and normal temperature fine glue powder, it has also been found that：It is related to the application formula number of cases for mixing reclaimed rubber Amount is approximately more than 10 times for being related to and mixing rubber powder application examples, and mixes that more than half is there are about in rubber powder application examples is with mixing regeneration rubber The scale of glue shares Formulation Example；And scale share normal temperature method rubber powder and thermal reclamation rubber positive effect at least that：

A. the reclaimed rubber obtained by the rubber powder and hot recycling that normal temperature is produced can be made to realize that physical property is complementary, the rubber production of regeneration matter can be reached The total amount of product --- reclaimed rubber and fine glue powder highest percentage shared in formula；

B. contribute to reduce the thermal reclamation rubber consumption of still implicit production contact scar so far and the implicit less productivity dirt of increase The rubber powder consumption of dye.

But《Rubber practical formulation is complete works of》In described scale share the technical scheme of rubber powder and reclaimed rubber, Imply the sick defect of the insurmountable tyre cavity of such a scale Striping scheme, i.e., the regeneration rubber obtained so far from hot recycling The feature of environmental protection of glue is also only to rest on to pursue odorless at room temperature, do not reach also far will downstream a variety of hot procedures all The high standard of odorless is wanted, even prepared by rubber powder wait the state-of-the-art technology of industrialization, such as ZL200810083330.6, though Start to propose four full buckle-type combined method Land use systems for changing " in full, green, high level, the energy-conservation " of damaged tire resource, But it is still in primary level, because wherein imply having that part high-grade waste rubber product (damaged tire) hot tearing is taken off It is contrary in the conception of four full buckle-type combined methods, the hot method not appeared in more under aforementioned combinatorial method framework is cooperateed with normal temperature method Prepare the technology of regeneration matter rubber product.

As it was previously stated, in the prior art, not arising how also to use relatively existing thermal reclamation rubber and known skill Rubber powder physical property more preferably regenerates matter rubber product in art, goes actively close or even fastens a variety of of each change of downstream completely The physical property set of rubber, with reach used as much as possible in downstream product formula green high level regeneration matter rubber and The purpose of virgin material is used less；In addition, being said from emerging combined method regeneration techniques, it is also desirable to there is more preferably scheme perfect to give again.

Goal of the invention

A kind of regeneration matter rubber product of physical property first color ink shape relatively more preferably just as used in colored drawing is provided, phase can be passed through To just as the combination change for operation of mixing colours, the different rubber in a variety of close or even complete fastening downstream is simply obtained actively Or rubber and plastic is combined a variety of physical property of matter product, to reach that multipurpose environment-friendly as far as possible regenerates in downstream rubber, product of rubber and plastic formula Matter rubber and the purpose for using virgin material less；In addition, also from meeting the " in full, green of emerging this upper guiding principle of combination regeneration method Color, high level, energy-conservation " changes the requirement of four full buckle-type resource circulation utilizations, is providing and preparing first colorant just as used in colored drawing Regeneration matter rubber product when, recombinant enters more Innovative Elements.

The content of the invention

The technology of the present invention design is：

1. using hot recycling rubber (component A) and normal temperature rubber powder in small, broken bits (B component), both regeneration matter rubber products are present Complementary physical difference feature, lifts the innovation intension such as green and high level of two kinds of component product physical property of this A, B respectively first, Allow user or the present invention implementation enterprise by this new product of A, B two by simple and use or alone so that this its it is a variety of mixed The physical property set of material or alone material is closed, and the physical property set required by downstream product can be more close or intersecting compared with prior art Obtain more, regeneration material is used as far as possible in downstream rubber or product of rubber and plastic formula and less with the mesh of virgin material so as to reach 's.

2. particularly improve the threshold rank of its odorless, or and expand the things such as the Mooney viscosity of hot recycling rubber (component A) The span of property；Raising normal temperature is in small, broken bits or freezes the lower limit in small, broken bits for once crossing the particle diameter fineness of rubber powder (B component) obtained by machine and screening Threshold, such as cross 100 mesh sieves or improve to cross 150 mesh sieves, or and it is implemented be modified.

The present inventor passes through a variety of so-called hot recycling rubber for meeting European Union environmental protection standard and plasticizing modified glue powder to existing city Heating comparative analysis is carried out, is found：These products by people's nasil ratio, all can not smell its stink at room temperature, but in high temperature Under, such as 180 DEG C of vulcameters or Mooney viscometer heating-up temperature push 10 minutes, not only all can coloured cigarette overflow, and this people that chokes Brown color smog all can dye test when sample above and below the mylar that is padded；Described " dyeing ", quantitatively, just It is that the mylar padded above and below sample can be made mutually to stacked after taking off to observe under fluorescent light, its color depth can be deeper than state The 101C or 601C of border Standard Colors (Pan PANTONE leads to) card.Study carefully its origin cause of formation, this is because prior art always makes application of Rubber there occurs part thermal cracking high temperature or and addition auxiliary agent be intended merely to ask the low requirement of odorless at room temperature caused by, such as The material temperature of its hot recycling was all once heated to 250 DEG C or so, was then generated again through quick cooling by part thermal cracking rubber Brown color oiliness fraction be just swelled into the sizing material not being cleaved, when sizing material is heated again, these thermal cracking rubber institutes The brown color oiliness fraction of generation will overflow with the softening agent component equipped with higher vapor pressure in smoke-like.Existing city is so-called There is the obvious smoke temperature difference opposite sex, the so-called odorless regeneration in Ji Xian cities with new rubber in this flaw of odorless reclaimed rubber The heated smoke temperature of rubber is far below new rubber, and it still can be to the workshop condition of downstream rubber enterprise hot-working sequence There is pollution.

And the greenization to this scrap rubber regenerates problem, the present inventor has at least explored a kind of feasible through experimental study Scheme, i.e.,：Rubber powder can be such as set to reach the grade of 60 to 150 mesh sieves, and fill the odorless of high dose in increase rubber powder fineness Softening agent, so that it may make heating during plasticizing be down to the difficult temperature range by thermal cracking of rubber of room temperature to 200 DEG C, resulting material Not only the index such as Mooney viscosity can pass, and make the experiment of 180 DEG C × 10 minutes on vulcameter OR gate Buddhist nun's viscosity apparatus, both Colourless cigarette will not be such that mylar is substantially dyed again.

3. used heat thermoplastic elastic, waste plastics using waste rubber product or even with part as raw material and be classified as it is high, Low-grade two class, allows non-thermal cracking path of the high-grade raw material as much as possible by the technique such as hot recycling or/and normal temperature be in small, broken bits Cooperate with and contact into product set, or with the innovation of hot recycling is set up into scale between in small, broken bits with normal temperature etc. series and parallel； Allow low grade material or/and isolated from high, bottom grade raw material containing accessory substances such as miscellaneous skeletons, all pass through thermal cracking process Path enters in product set；Or and contact non-cracking path and hot tearing solution path cooperateing with for scale of implementation.

4. hot recycling processing route is applied in combination, using the thin footpath rubber powder for being easy to plastify vulcanization rubber or with high power amount Odorless softening agent, in order to which the decomposition after relatively low heating-up temperature is implemented to be swelled plasticizing and avoid rubber hydrocarbon heated is exaggerated.

5. hot recycling processing route is applied in combination, try to get rid of the filter glue of highly energy-consuming and refining procedure, but can protect again simultaneously That demonstrate,proves the grain of the metal fillings in product is removed rate.

6. normal temperature processing route in small, broken bits is applied in combination, using be easy to refinement, beneficial extrusion, it is cheap and easy to get, easily a point benefit stay, it is suitable With the broken auxiliary agent of rush appreciated, such as minced using the thermal cracking ground-slag of low-grade scrap rubber and make to promote broken and chew enzymolysis auxiliary agent.

7. thermal cracking process path is applied in combination.

8. by the foregoing component of new A, B two, extension grafting to rubber compound composition or modeling compound composition field.

9. it is real to make combined method from advanced reliable hot recycling technique, normal temperature technique in small, broken bits, thermal cracking process and its equipment The unit basis applied or and the further improvement of implementation on this basis.

10. for convenience of the Technique Popularizing of the present invention, the present inventor provides product described in the technical program as much as possible Application direction；And provide a kind of new quality inspection mode including background sizing material C to detect A or/and the B component feature of environmental protection and thing Rationality.

Realize that the concrete technical scheme of the technology of the present invention design is：

1.1. it is a kind of to regenerate matter rubber or mix its rubber or rubber and plastic compound composition product, the product, it can relate to " pass through Fine crusher is freezed once or after crossing normal temperature elastic body fine crushing machine once, gained at least more than 90% must cross 60 mesh sieves and have many In the thin rubber powder that 100 mesh sieves are crossed equal to 50% parts by weight or and promote broken auxiliary agent " this intermediate state mixed material, then apply classification, Component A, B component obtained by pollution-free thermoplastification process, or/and A/B components compound composition, or/and mix A or/and B component Rubber or rubber and plastic compound composition, it is characterised in that：The feature of component A includes any following 1-1 to 1-3 or with 1-5,1-7 Or more the combination planted, the feature of B component includes following 1-1 to 1-2 and 1-4 or any or more group planted with 1-6,1-7 Close, the feature of A/B component compound compositions includes following 1-8, mixing A or/and the rubber compound composition of B component feature is included such as Lower 1-9, mixing A or/and the rubber and plastic compound composition of B component feature includes following 1-10：

1-1.A or/and B component, its characteristic of environmental protection is including 1. or and 2.：

Even 1. is distributed seldom by organic volatile during hyperpyrexia, described " few ", it can easily be detected Go out to be characterised by：A or/and B component 3~5g of sample is taken, in sample each one mylar of pad up and down, it is then put in sulphur Change on instrument OR gate Buddhist nun's viscosity apparatus, be heated 10 minutes at 180 DEG C, take out sample, park at room temperature no less than 5 minutes, so The mylar above and below sample is taken off afterwards and is stacked again, and moves to observation under fluorescent lamp, mylar will not be deeper than by yellow colouration The 101C or 601C of international standard color (Pan PANTONE leads to) card；

2. being heated 10 minutes at 180 DEG C described in 1., takes out sample, will not now give out conventional regeneration Coal tar that rubber is distributed, pine tar, aromatic naphtha, any or more of pitch plant the feature stench of combination, or and choke people's Peculiar smell；

1-2.A components or/and B component, the upstream source feature of its raw material include：The regeneration matter rubber that is related in A, B or With scrap rubber thermal cracking ground-slag mince it is raw materials used be derived from it is listed below it is any or more plant it is identical or different it is high, The combination of low-grade scrap rubber：

High-grade scrap rubber：The automobile useless cross-ply abandoned, the automobile useless steel radial tyre abandoned, automobile uses what is abandoned Useless half steel radial tyre, the automobile tube abandoned, turning, the buffings under polishing, rubber powder material, ore deposit during automobile tire retreading The mountain conveyer belt abandoned；

Low-grade scrap rubber：The automobile tire tyre cushion abandoned, the automobile-used tire abandoned of motorcycle, bicycle, electric car, power, Scrap rubber pipe, scrap rubber footwear, scrap leather footwear, waste tape, scrap rubber pad, the side crops of rubber, the sports ground plastic pad abandoned, give up electricity Cable skin, given up turning rubber covered rollers material, the workshop incipient scorch material of rubber, and colloid give up gloves, is crushed and is divided from the rubber abandoned Any or more of steel wire or/and chemical fibre frame material, fiber lining crumble, metal fillings grain for considering grain to be worth doing containing rubber powder separated out plants Combination；

1-3.A components physical property interval feature at least includes：

Its vulcanizate：Tensile strength is pulled apart in 4.00MPa to 17.00 scopes or is remained before waste rubber product is reproduced Pull apart the 2/3 of tensile strength, proportion in 1.16 to 1.40 scopes, shore a hardness in 45 to 70 scopes, elongation 300% to 500% scope；Pure component A can be extruded or extruded in flakes, and component A is made an addition in background glue C, can be formed non-island, marine facies it is equal Matter sizing material, and the vulcanizate formed with background glue C, it wears away always to be significantly greater tnan adds same amount in background glue C on year-on-year basis B component abrasion；Component A is to sizing material without the froth breaking sexual function for being easy to venting quality；

The background glue C, its specific formula, at least includes：100 parts of butadiene-styrene rubber, 5 parts of zinc oxide, 1 part of stearic acid, 2 parts of sulphur, 1.5 parts of accelerant CZ, 0.5 part of Vulcanization accelerator TMTD, 1 part of antioxidant MB, 0 to 60 part of carbon black N330, calcium carbonate 0 to 200 part, 0 to 15 part of machine oil；When adding component A, the weight of component A/sulphur/accelerant CZ/Vulcanization accelerator TMTD need to be pressed simultaneously Amount ratio=100/0.8/0.6/0.2 is added, and conditions of vulcanization is 155 DEG C/7 minutes；

1-4.B components physical property interval feature at least includes：

Its particle size range exists：100 mesh are crossed to the particle diameter mixing of only 200 mesh sieve scopes or are classified, the identifying way of particle diameter Using：50 parts of B components of weight are added in 100 parts by weight background glue C with pressing (GB 19208-2008-T)《Vulcanized rubber powder》 " cross 100 mesh to the particle diameter mixing of only 120 mesh sieve scopes or be classified " 45 parts of standard specimen weight that operation is obtained, is made vulcanizate Compare the crude property of knife section afterwards, must both be narrower than standard specimen；

Its vulcanizate：Tensile strength is pulled apart in 4.00MPa to 17.00 scopes or is remained before waste rubber product is reproduced Pull apart the 2/3 of tensile strength, proportion in 1.20 to 1.8 scopes, shore a hardness in 70 to 85 scopes, elongation 180% to 350% scope；Pure B component can not be extruded or extruded in flakes, and B component is made an addition into background glue C, can be formed island, marine facies it is non- Matter sizing material, and the vulcanizate formed with background glue C, it wears away always to be significantly less than adds same amount in background glue C on year-on-year basis Component A abrasion；B component has the froth breaking sexual function for being easy to venting quality to sizing material；

The background glue C, its specific formula, at least includes：100 parts of butadiene-styrene rubber, 5 parts of zinc oxide, 1 part of stearic acid, 2 parts of sulphur, 1.5 parts of accelerant CZ, 0.5 part of Vulcanization accelerator TMTD, 1 part of antioxidant MB, 0 to 60 part of carbon black N330, calcium carbonate 0 to 200 part, 0 to 15 part of machine oil；When adding B component, the weight of B component/sulphur/accelerant CZ/Vulcanization accelerator TMTD need to be pressed simultaneously Amount ratio=100/0.8/0.6/0.2 is added, and conditions of vulcanization is 155 DEG C/7 minutes；

Component A described in 1-5., its feature is also including 3. and 4.：

3. be by " by freezing fine crusher once or after crossing normal temperature elastic body fine crushing machine once, gained must be at least More than 90% cross 60 mesh sieves and have cross the thin rubber powder of 100 mesh sieves or and promote broken auxiliary agent more than being equal to 50% parts by weight " in this Between state mixed material, then apply classification, the mesh of mistake 60 obtained to the only grain size grading of any sieve mesh of 150 mesh sieve scopes or mixed The rubber powder of conjunction, or through magnetic field or/and electric field remove metal impurities again, but through pollution-free, energy-conservation plasticizing and with stirring, After extrusion, pelletizing, any or more anabolic process processing for planting operation of roll-in, butter shape, cake powdery, graininess, glue are obtained Bulk, sheet, the plastifying material of any form of strip；Described " pollution-free plasticizing ", it is characterised in that by material by The temperature control of heat is in room temperature to 200 DEG C of intervals；Described " energy-conservation plasticizing ", it is characterised in that highly energy-consuming is not set to material Worry glue or/and refining treatment；Described " promoting broken auxiliary agent " for it is low-grade described in 1-2 or with high-grade scrap rubber thermal cracking slag The powder to the thick mesh sieve of mistake 200；

4. and 3. described " plastifying material ", its Mooney viscosity (ML100 DEG C of 1+4) value are controlled in 15 to 95 scopes It is any；

B component described in 1-6., be further characterized in that 5. or and 6.：

5. be by " by freezing fine crusher once or after crossing normal temperature elastic body fine crushing machine once, gained must be at least More than 90% cross 60 mesh sieves and have cross the thin rubber powder of 100 mesh sieves or and promote broken auxiliary agent more than being equal to 50% parts by weight " in this Between state mixed material, then apply classification, obtained to being slightly 100 mesh to the carefully only grain of any sieve mesh of 200 mesh sieve scopes Radial sector or the ultra-fine rubber powder of mixing；Described " promoting broken auxiliary agent " for it is low-grade described in 1-2 or with high-grade scrap rubber hot tearing Solve the powder to the thick mesh sieve of mistake 200 of slag；

The blended known rubber for admixing nonstaining property is commonly used again single or the softening agent or/and disconnected sulphur modification of compounding Agent, or and with applying extrusion, any or more anabolic process planted of roll-in, last gained for powdered, piece bits shape, particle The ultra-fine rubber powder mixture being modified of any form of shape；

6. is only then the mixing through homogenization to 5. described " ultra-fine rubber powder ", or and is appointed with extrusion, roll-in is applied One or more the anabolic process planted, last gained for powdered, piece bits shape, the ultra-fine rubber of granular any form Powder material；

1-7. or with " the intermediate state mixed material " described in 1-5,1-6 and the " mesh of mistake 60 obtained to only 150 mesh sieve scope Any sieve mesh grain size grading or the rubber powder of mixing ", and " to being slightly 100 mesh to carefully only 200 mesh sieve scope Any sieve mesh grain size grading or the ultra-fine rubber powder of mixing ", its source includes：Make by oneself or/and purchased in market；

1-8. will as described in preceding 1-1 to 1-5 A, B, any proportion by A/B weight than 95/5 to 5/95 scope mixes in advance Close, described hybrid mode includes stirring, rolling, any or more of extrusion and plants the combination operated, then because A/B weight than It is different and obtain planting combination in powdery, graininess, piece bits shape, cake powdery, micelle shape, glue sheet, any or more of adhesive tape shape The stand-by material of storage of form；

1-9. will as described in preceding 1-1 to 1-5 A, B, by A or/and B component：Weight ratio=5~90 of general purpose rubber: The parts by weight summation of 95~10, i.e. both or three are 100 parts, or again with reinforcing agent, constitution filler, through mixing in advance, de- After ripe, kneading any or more the anabolic process of item of water, heat, obtain mixing A or/and the rubber compound composition of B component；It is described General purpose rubber, refer to natural rubber, butadiene-styrene rubber, butadiene rubber, isoprene rubber, neoprene any or with It is upper to plant any of combination or its emulsion or solution；Described reinforcing agent, refers to that carbon black, any or more of white carbon are planted Combination；Described constitution filler, refers to that calcium carbonate, any or more of clay plant combination；

1-10. A, B as described in preceding 1-1 to 1-5, by A or/and B component：Weight ratio=5~95 of resin: 95~5, i.e., The parts by weight summation of both or three are 100 parts, or with known modified additive, after sneaking out journey through heat in advance, obtain mixing A or/ With the rubber and plastic compound composition of B component；Described resin is also well known materials, and it can include polypropylene, polyethylene, polychlorostyrene second Alkene, propylene-ethylene copolymers, ethylene-octene copolymer, ethylene-vinyl acetate copolymer, allyl resin, epoxy resin, Alkyl phenolic resin, polyurethane, any or more combination planted of amino resins, also including such as waste plastics lawn, waste plastics appearance Any or more combination planted of device, waste plastics packaging film；Described known modified additive, including：Rubber vulcanization system is with helping Agent, as sulphur, 2- benzothiazolyl mercaptans, tetramethylthiuram disulfide, zinc oxide, it is stearic one or more of group Close, and preventing aging system used additives, such as N- rings ethyl-N '-diphenyl-para-phenylene diamine, 2 mercapto benzimidazole, peroxidating hexamethylene Ketone, one or more of combinations；Surface coupling agent, such as ethylene methacrylic base silane, anilinomethyl triethoxysilane, metatitanic acid One or more of combinations of glycol ester, glycidyl acrylate；Compatibilization system used additives, such as molecular weight 2000~ The liquid polyisoprene rubber or liquid polybutadiene rubber of 5000 scopes, maleic anhydride；Plasticiser system used additives, such as One or more of combinations of dibutyl phthalate or dioctyl ester or cyclohexane dicarboxylic acid dinonyl；Described is known Modified additive, the known normal dosage ranges of its consumption category；

As above 1-1 to 1-10 is addressed component A, B component, the compound composition of A/B components mix the rubber of A or/and B component Glue compound composition, independent product can all be turned into by mixing A or/and B component rubber and plastic compound composition.

2. component A described in technical scheme 1, wherein preferably the physical property of product and its starting material and the spy after technical process Parameter combination is levied to be：

The feature of environmental protection that 2-1. obtains component A is at least conformed to described in technical scheme 1-1；

4. described " Mooney viscosity (ML100 DEG C of 1+4) value " is controlled in 15 to 35 scopes any or 60 to 2-2.1-5 It is any to 95 scopes；

2-3. is to make by oneself or the mesh of mistake 100 purchased in market is to the only grain size grading of any sieve mesh of 150 mesh sieve scopes or mixing Rubber powder, or after removing metal impurities through magnetic field or/and electric field again, be used as the starting material for implementing thermoplastification processing；

2-4. or during with plasticizing operation heated temperature of charge in room temperature to 150 DEG C of scopes, and with upper stirring, extrusion, After pelletizing, any or more anabolic process processing for planting operation of roll-in, obtain butter shape, cake powdery, graininess, micelle shape, Plastifying material --- the component A of sheet, any form of strip；

2-5. or and not to plastifying material material set highly energy-consuming worry glue or/and refining treatment.

3. prepared by B component described in technical scheme 1, wherein preferably the physical property of product originates mix and after work with it The characteristic parameter combination of skill process is：

The feature of environmental protection that 3-1. obtains B component is at least conformed to described in technical scheme 1-1；

3-2. is to make by oneself or the mesh of mistake 100 purchased in market or to crossing 150 mesh but only the rubber powder of the mixing of 200 mesh sieve scopes Material is the starting mix of B component processed；

3-3. and to described in 3-2 " the starting mix of B component " implement 1-6 it is 5. described " admixing " " modifying agent "；

3-4. imposes the mixing of homogenization to " the starting mix of B component " described in 3-2,3-3 again, or and with apply extrusion, Any or more anabolic process planted of roll-in, last gained for powdered, piece bits shape, granular any form it is super Thin rubber powder material --- B component.

4. component A, the preparation method of B component described in technical scheme 1, it is characterised in that：All " pass through normal temperature elastic body fine crushing machine Or freezing fine crusher once, and excessively it is in small, broken bits cross machine after, just can obtain no less than 90% parts by weight cross 60 mesh sieves with have more than etc. The thin rubber powder of 100 mesh sieves is crossed in 50% parts by weight or and as promoting broken auxiliary agent " mixed material of this intermediate state, then pass through again Lock out operation and subsequent treatment separately win in butter shape, micelle shape, graininess, in flakes shape, in strip any form modeling Change material A component, and shape, granular B component are considered to be worth doing in powder, piece；" component A ", with following 4-5 to 4-6 or and 4-1 Any or more combination for planting feature into 4-4, " B component ", with following 4-5 and 4-7 or with 4-1 into 4-4 Any or more combination for planting feature：

Its quality of rubber materials of 4-1. belongs to the combination of scrap rubber described in technical scheme 1-2；

4-2. obtained 16 to 30 mesh hole scopes using known scrap rubber coarse crushing, crushing, magnetic separation, screening process The grain size grading of any sieve mesh or the thick micelle of mixing；

" thick micelle " described in 4-3. to 4-2, then admix thereto to being slightly the low-grade of 200 mesh sieves or useless with high-grade The powder material of rubber thermal cracking slag, " the thick micelle " had both promoted the charged material weight of broken auxiliary agent with " powder of cracking slag " Compare W_{Thick micelle}/W_{Promote broken auxiliary agent}=100/8~50；

4-4. or by " thick micelle " described in 4-2, imports freezing fine crusher；

4-5. to " cross freezing fine crusher after gained must at least more than 90% cross 60 mesh sieves and have more than be equal to 50% weight Part the thin rubber powder of 100 mesh sieves is crossed, or cross at least more than 90% must the crossing and 60 mesh sieves and have many of gained after normal temperature elastic body fine crushing machine In thin rubber powder and the mixed material of the broken auxiliary agent of rush that 100 mesh sieves are crossed equal to 50% parts by weight ", implement to be classified, described classification, It is characterized in：

" thin rubber powder or and promote the mixed material of broken auxiliary agent " is divided into two parts by 4-5-a.：Both thick material：Cross 60 mesh sieves extremely But 100 mesh or the mixing to the only rubber powder of any mesh sieve of 150 mesh sieve scopes and the metal fines for being enriched not sieve Thing-i；With thin material：Cross 100 mesh or the mixing to the ultra-fine rubber powder for any mesh sieve for crossing 150 mesh sieve scopes or with the broken auxiliary agent of rush Thing-ii；

4-5-b. or " thin rubber powder or and promote the mixed material of broken auxiliary agent " is divided into three parts：Both thick material was：Cross 60 Mesh sieve to only 100 mesh or to the only rubber powder of any mesh sieve of 150 mesh sieve scopes and had been enriched not the metal fines sieved Mixture-i；With thin material：100 mesh are crossed or to any mesh sieve for crossing 150 mesh sieve scopes, to the ultra-fine glue of only 200 mesh sieves Powder-iii；And thinner material：Cross the broken auxiliary agent of rush and the thin rubber powder-iv less than thick micelle throwing amount 5% of 200 mesh sieves；

4-5-c. or the demand according to market, by " i " part described in 4-5-a, 4-5-b, re-grading be 60 mesh extremely The but grain size grading rubber powder-v of any sieve mesh of 150 mesh sieve scopes, and the metal before classification or/and in rear removing rubber powder is thin Bits；

Or the demand according to market, by " ii " described in 4-5-a, or " iii " described in 4-5-b, re-grading was 100 mesh or to any mesh sieve for crossing 150 mesh sieve scopes, to only any sieve mesh of 200 mesh sieve scopes grain size grading material- vi；

4-6. is to described in " i " described in 4-5-a or 4-5-b and 4-5-c " v ", implementing subsequent treatment, separately winning in butter Shape, micelle shape, graininess, in flakes shape, in strip any form plastifying material component A, be specifically：

4-6-a. implements magnetic separation or/and electric field choosing, further removes gold therein to " i " described in 4-5-a or 4-5-b Belong to fines, obtain 60 mesh sieves to only 100 mesh or to the rubber powder-vii of only any mesh sieve of 150 mesh sieve scopes；

The ratio between 4-6-b. is mixed plus known softening agent to " v " described in " vii " described in 4-6-a or/and 4-5-c, by weight For W_{Vii or/and v}/W_{Known softening agent}=100/20~100 scope formulas feed intake, and obtain the starting mix of component A processed；

4-6-c. is to " the starting mix of component A " described in 4-6-b, and temperature is applied in heating, and described " Shi Wen " is controlled in room temperature extremely Any of 200 DEG C of scopes；

Described 4-6-d.4-6-b " softening agent ",：White oil, machine oil, vegetable oil, stearic acid, vaseline, wax, transformation The combination that device oil, ancient marlon resin, terpene resin, modified rosin scope optional one or more is planted；

4-6-e. or and while with addition of softening agent, also add disconnected sulphur or/and desulfurization used additives, the auxiliary agent is known Or function additive purchased in market：

4-6-f. while as described in 4-5-c " heating " is applied, and with upper stirring, extrusion, pelletizing, roll-in any or More than plant operation anabolic process processing after, obtain butter shape, cake powdery, graininess, micelle shape, sheet, strip it is any Plastifying material --- the component A of form；

4-7. is real to " ii " described in 4-5-a, or/and " iii " described in 4-5-b, or/and " vi " described in 4-5-c Apply subsequent treatment, separately win in powdery, piece bits shape, granular any form B component, it is specific as 4-7-a, 4-7-b or and 4-7-c：

4-7-a. mixes softening agent or/and the disconnected sulphur modification agent of the single or compounding that add the known rubber of nonstaining property conventional, Described softening agent, disconnected sulphur modification agent, it is all known kind, and the ratio fed intake by weight is W_{Ii or/and iii or/and vi}/ W_{Softening agent or/and disconnected sulphur modification agent}=100/0~15, obtain the starting mix of B component processed；

4-7-b. applies heating-up temperature, described temperature is in room temperature to 60 to " the starting mix of B component " described in 4-7-a Any of DEG C scope；

4-7-c. imposes the mixing of homogenization to " the starting mix of B component " described in 4-7-a again, or and with apply extrusion, Any or more anabolic process planted of roll-in, last gained for powdered, piece bits shape, granular any form Ultra-fine rubber powder material --- B component.

5. the preparation method of the compound composition of A/B components described in technical scheme 1, its feature also includes：

By the component A described in technical scheme 1, and the B component described in technical scheme 1, by A/B weight than 95/5 to 5/95 Any proportion of scope is pre-mixed, and described hybrid mode includes stirring, banburying, rolling, any or more plant of extrusion and grasped The combination of work, and note to heat during mixing；Because A/B weight than it is different obtain in powdery, graininess, piece bits shape, cake Powdery, micelle shape, glue sheet, the compound composition of the stand-by A/B components of any or more storage for planting combination form of adhesive tape shape Material.

6. mixing the preparation method of A or/and the rubber compound composition of B component described in technical scheme 1, its feature also includes：By skill A, B described in art scheme 1,2,3,4, by A or/and B component：Both weight ratio=5~90 of general purpose rubber: 95~10, i.e., Or the parts by weight summation of three is 100 parts, or again with reinforcing agent, constitution filler, through mixing in advance, dehydration, hot ripe, kneading Any or more anabolic process of item after, obtain mixing A or/and the rubber compound composition of B component；Described general purpose rubber, Refer to natural rubber, butadiene-styrene rubber, butadiene rubber, isoprene rubber, neoprene it is any or more plant combination or its Emulsion or solution it is any；Described reinforcing agent, refers to that carbon black, any or more of white carbon plant combination；Described constitution Filler, refers to that calcium carbonate, any or more of clay plant combination.

7. A or/and the rubber and plastic compound composition of B component are mixed described in technical scheme 1, it is characterised in that：By technical scheme 1,2, 3rd, " A ", " B " described in 4, by A or/and B component：Weight ratio=5~95 of resin: the weight of 95~5, i.e. both or three It is 100 parts to measure number summation, or with known modified additive, after sneaking out journey through heat in advance, obtain mixing A or/and the rubber and plastic of B component Compound composition, described heat, i.e. any temperature of the heated material temperature of its material in 100 to 200 DEG C of scopes；Described is mixed, wraps Stirring, rolling, any or more combination for planting operation of extrusion are included, because of A or/and B component：Weight resin than difference, and obtain To any or more the storage for planting combination form for considering shape, cake powdery, micelle shape, glue sheet, adhesive tape shape to be worth doing in powdery, graininess, piece Deposit stand-by rubber and plastic compound composition material.

8. product described in technology of preparing scheme 1 it is used and combined equipment, its feature at least that：It is related to component A Combined equipment, including following 8-1 or any or more combination with 8-2 to 8-6,8-10, are related to the combined equipment of B component Described in 8-7 specific as follows, it is related to the combined equipment 8-8 specific as follows of A/B component compound compositions or with described in 8-10, is related to containing A Or/and the rubber and plastic compound composition of B component combined equipment 8-9 specific as follows or with described in 8-10：

8-1. carry normal temperature elastic body fine crushing machine and to cross fine crusher material implement selection by winnowing or/and sieve classification machinery After combined machine I, undertaking carried 60 mesh to the only grain size grading of any sieve mesh of 150 mesh sieve scopes or the rubber of mixing The storage bin combined machine II of glue powder grain material, or again with being provided with the removing impurities operative combination machinery III in magnetic field or/and electric field Mutually be connected, II or with III after linking with dispensing operation mechanism thermoplastification modifying composition machinery IV；

8-2. is connected the combined machine V of metering packing component A after IV described in 8-1；

8-3. is set before I described in 8-1 by carrying thick rubber powder storage bin VI-1, scrap rubber thermal cracking carbon black storage bin VI-2 upper subsidiary engine combined machine VI；

8-4. crushes the combined machine VII thick micelle for being stripped of metal fillings in the import of VI-1 described in 8-3 with scrap rubber Output end is mutually connected, or/and the import in VI-2 described in 8-3 and the scrap rubber thermal cracking combination machine with cracking residue crusher group The tool VIII cracking slag crushed material output end VIII-1 phases for being stripped of metal fillings are connected；

Combined machine II described in 8-5.8-1 is connected with III phases again, it is characterised in that：In combined machine II discharging opening Conveying machinery II → III is provided between II-1 and combined machine III magnetic field or/and electric field removing impurities machinery III-1, it is described Conveying machinery II → III at least includes belt conveyor, screw rod transmission, bucket chain type conveying, any or more of air-flow conveying and planted Combination；

Described in 8-6.8-1 II or with III after linking with dispensing operation mechanism thermoplastification modifying composition machinery IV, It is characterized in that：Dispensing operation mechanism IV-1 in combined machine IV, the discharging opening II-1 with combined machine II, or and group Be provided with conveying machinery II → IV or III → IV between the storage bin IV-1 for closing machinery III, described conveying machinery II → IV or III → IV at least includes belt conveyor, screw rod transmission, bucket chain type conveying, any or more combination planted of air-flow conveying；

After combined machine I described in 8-7.8-1, undertaking carried 100 mesh to only any sieve mesh of 200 mesh sieve scopes The rubber powder grain material of grain size grading or mixing and is mixed with or separated the storage bin combination machine of scrap rubber cracking slag powder material Tool IX, or and join again after IX with implement rubber powder modified metering married operation combined machine X, or and concatenation again to preceding Stated IX or implemented the combined machine XI that rolls with X each material, and IX or with X or/and XI after linking metering packing B The combined machine V ' of component；

8-8. in thermoplastification modifying composition machinery IV described in 8-1, with storage bin combined machine IX described in 8-7 or with X or/and After XI, then metering married operation combined machine X ' or the combined machine XI ' rolled with implementation is set, then collection is set again The combined machine V " of the metering packing of A/B component compound compositions；

8-9. and thermoplastification modifying composition machinery IV described in 8-1 are Section 1, and storage bin combined machine IX described in 8-7 or It is Section 2 with X or/and XI, with first and second side by side, then Section 3 is set：Collection puts resin or the storing with modified additive Storehouse combined machine XII, then after foregoing three arranged side by side, metering married operation combined machine X " is set or implements what is rolled Combined machine XI ", then sets the combined machine for the metering packing for collecting the rubber and plastic compound composition containing A or/and B component again V’”；

Combined machine I to XII described in 8-10.8-1 to 8-9, includes purchased in market or/and homemade combined machine.

9. in product described in technical scheme 1, include the quality detecting method to A or/and B, it is characterised in that：It is related to as described below 9-1 or/and 9-2：

The 9-1. quality inspection feature of environmental protection is, using any of vulcameter OR gate Buddhist nun's viscosity apparatus, to make to A or/and B and from former Material is by the heating measuring equipment of sample, and the coloured volatile matter whether overflowed by the dacron membrane of sample institute pad by being heated Dyed, by sample whether there is the qualitative index of contaminative to have used international standard color (Pan PANTONE leads to) card again 101C or 601C；The temperature and time suffered by sample is defined again, is used as additional quantitative target within such as 180 DEG C × 10 minutes；

9-2. quality inspection mechanics physical property is to use the background glue C as described in technical scheme 1-3,1-4.

10. the application of product described in technical scheme 1, it is characterised in that：By the A or/and B component described in technical scheme 1, Combined with any or more plant of natural rubber, butadiene-styrene rubber, butadiene rubber, isoprene rubber, neoprene, or/and with 5 mesh sieves are crossed to the only grain size grading of 60 mesh sieves or the thick micelle powder of the rubber of mixing, or with carbon black, white carbon, calcium carbonate, Any or more of clay plants combination, the elastomeric compound that blending refining is matched somebody with somebody；

Or use foregoing elastomeric compound, the or/and " compound composition of A/B components, mixed with A or/and B component described in technical scheme 1 Rubber compound composition or rubber and plastic compound composition ", further preparing includes automobile tire, tire tyre cushion, motorcycle, bicycle, Tire used in electric car, power car, sole, sebific duct, adhesive tape, rubber cushion, handle gum cover, bicycle pedal blob of viscose, bicycle pedal Gum cover, automotive wheels rear mudguard, vehicle steering handle, automobile chassis foot pad, brake brake rubber block, tail-light bowl, filter press rubber Filter plate frame, solid tyre, oxygen bottle foot pad, mine car are met and discussed with rubber, shield line gum cover, the electricity of ash bucket for building, electric drill dragging line Bore handle gum cover, marine rubber fender, any rubber or product of rubber and plastic of bipeltate material.

Brief description of the drawings：Fig. 1 be preparation method described in the technical program it is used and combined equipment schematic block diagram.

Embodiment

Next, for present disclosure is further illustrated, then specifically contacts selected embodiment and be described further, but this A little embodiments are only limitted to this merely to further illustrate present invention without that should be regarded as protection scope of the present invention.

A kind of regeneration matter rubber of embodiment 1. or product described in mixing its rubber or rubber and plastic compound composition product, can relate to " by freezing fine crusher once or after crossing normal temperature elastic body fine crushing machine once, gained must at least more than 90% cross 60 mesh sieves and Have and cross the thin rubber powder of 100 mesh sieves or and promote broken auxiliary agent more than being equal to 50% parts by weight " this intermediate state mixed material, then apply The compound composition of classification, component A, B component obtained by pollution-free thermoplastification process, or/and A/B components, or/and mix A or/and B The rubber or rubber and plastic compound composition of component, it is characterised in that：The feature of component A include following 1-1 to 1-3 or with 1-5,1-7 The combination of any or more kind, the feature of B component includes following 1-1 to 1-2 and 1-4 or any or more with 1-6,1-7 plants Combination, the features of A/B component compound compositions includes following 1-8, mixes the feature bag of A or/and the rubber compound composition of B component Following 1-9 is included, mixing A or/and the rubber and plastic compound composition of B component feature includes following 1-10：

Even 1. is distributed seldom by organic volatile during hyperpyrexia, described " few ", it can easily be detected Go out to be characterised by：A or/and B component 3~5g of sample is taken, in sample each one mylar of pad up and down, it is then put in sulphur Change on instrument OR gate Buddhist nun's viscosity apparatus, be heated 10 minutes at 180 DEG C, take out sample, park at room temperature no less than 5 minutes, so The mylar above and below sample is taken off afterwards and is stacked again, and move under fluorescent lamp and can one whiteness more than 95% of backing it is white Make on paper nearly vertical observation (photo that observation result can be made to shoot is recorded, but it is noted that：Because full pattern is after photo Discoloration can be brought to disturb because of the factor such as reflective), mylar will not be deeper than international standard color (Pan PANTONE by yellow colouration It is logical) 101C or 601C " of card；

High-grade scrap rubber：Automobile uses the useless cross-ply abandoned and its decomposes times of part such as tire top, sidewall, tire shoulder, mouth circle One or more the combination planted, the automobile tube of non-butyl colloid abandoned, automobile with the useless steel radial tyre abandoned and its Decompose any or more combination planted of part such as tire top, sidewall, tire shoulder, mouth circle, useless half steel radial tyre that automobile use is abandoned and its Decompose any or more combination planted of part such as tire top, sidewall, tire shoulder, mouth circle, turning during automobile tire retreading, polish under Crown buffings, rubber powder material, the mine conveyer belt abandoned；

1-3.A components physical property interval feature at least includes：

The background glue C, its specific formula, at least includes：100 parts of butadiene-styrene rubber, 5 parts of zinc oxide, 1 part of stearic acid, 2 parts of sulphur, 1.5 parts of accelerant CZ, 0.5 part of Vulcanization accelerator TMTD, 1 part of antioxidant MB, 0 to 60 part of carbon black N330, calcium carbonate 0 To 200 parts, 0 to 15 part of machine oil；When adding component A, the weight of component A/sulphur/accelerant CZ/Vulcanization accelerator TMTD need to be pressed simultaneously Added than=100/0.8/0.6/0.2, conditions of vulcanization is 155 DEG C/7 minutes；

1-4.B components physical property interval feature at least includes：

Its particle size range exists：100 mesh are crossed to the particle diameter mixing of only 200 mesh sieve scopes or are classified, the identifying way of particle diameter Using：50 parts of B components of weight are added in 100 parts by weight background glue C with pressing (GB 19208-2008-T)《Vulcanized rubber powder》 " cross 100 mesh to the particle diameter mixing of only 120 mesh sieve scopes or be classified " 45 parts of standard specimen weight that operation is obtained, is made vulcanizate Compare the crude property of knife section afterwards, must both be narrower than standard specimen；(detect B component there is provided a kind of new quality inspection mode here Particle diameter, this mode)；

Component A described in 1-5., its feature is also including 3. and 4.：

B component described in 1-6., be further characterized in that 5. or and 6.：

As above described in 1-3,1-4, because exist between component A, B component physical property interval can not each be stacked the characteristics of, when in use can The component of A, B two is incorporated rubber or product of rubber and plastic formula by simple any weight ratio and use or alone mix, makes this two component It is a variety of and use or alone material physical property set, can more existing reclaimed rubber or/and fine glue powder physical property set, with A variety of physical property set required by product are swum, it is morely more close or intersecting, match somebody with somebody so as to reach in downstream rubber or product of rubber and plastic Regeneration matter rubber is used in side and the purpose of virgin material is used less；Described is more close, including the feature of environmental protection described in 1-1, and 1-4 institutes State " B component makes an addition to background glue C ", " and its wear away always be significantly less than on year-on-year basis in background glue C add same amount component A Abrasion ", both；B and A are shared, can be small compared with the abrasion of alone component A, that is, the abrasion that share of B and A closer to including Virgin material including background glue C, that is, the present invention are carried the regeneration of scrap rubber, make the positive effect institute of the component of A, B two .

Preceding 1-1 1. as described in " take A or/and B component 3~5g of sample, in sample each one mylar of pad up and down, so It is rearmounted its on vulcameter OR gate Buddhist nun's viscosity apparatus, be heated 10 minutes at 180 DEG C, take out sample, park many at room temperature In 5 minutes, then the mylar above and below sample is taken off and is stacked again, and move under fluorescent lamp and one whiteness 95% of backing Make nearly vertical observation on blank sheet of paper above, mylar will not be deeper than international standard color by yellow colouration (Pan PANTONE leads to) The 101C or 601C " of card；Detect, materials by this method：Numbering 1 is that the A and B component material of this law are respectively 2.5g mixing examination Sample, numbering 2 is the sample that component A material is 5g, and numbering 3 is certain flag enterprise in the industry that scrap rubber regeneration association is recommended The discarding test piece being tested after strength for the odorless reclaimed rubber that the continuity method screw rod desulfuration of industry is obtained is (already because by GB 13460- 2008-T《Reclaimed rubber》Quality inspection test piece, and be heated heat of vulcanization and driven away the material for partly having smelly composition), numbering 4 is useless The environmental friendly regenerated rubber that another landmark enterprise produces in the industry that rubber regeneration is recommended using association, numbering 5 is that Chinese tire is followed Ring utilizes the conventional tyre regeneration rubber that certain enterprise produces in association.The sample of numbering 1,2,3 is heated 10 minutes at 180 DEG C, Testing result is that 1,2 numbered samples for representing the present invention will not be deeper than international standard color (Pan PANTONE lead to) by yellow colouration The 101C or 601C of card, and 3 numbered samples contrasted are far deeper than the 101C or 601C of color (Pan PANTONE leads to) card.In addition also The comparison of reduction heating-up temperature has been done, has been specifically that, by the sample of numbering 3 situation heated 10 minutes at 140 DEG C, result is to compile Though number 3 samples is than in 180 DEG C of shallow many, but still to be deeper than international standard color (Pan PANTONE leads to) card by yellow colouration 101C or 601C；With the situation that numbering 4,5 samples are heated to 10 minutes at 160 DEG C, result is numbering 4,5 samples, two The 101C or 601C that international standard color (Pan leads to PANTONE) card is also all far deeper than by yellow colouration of person.Skill proposed by the present invention Art scheme, product vulcanize 140 DEG C to 180 DEG C scopes of temperature range for using in downstream, because can in 180 DEG C of the interval upper limit Reach that cigarette dyeing is shallower than 101C or 601C, then it is just more shallow in 140 DEG C of interval limit its cigarette dyeing, therefore the hair of product of the present invention Cigarette decrement can have the much progress of obvious matter compared with known technology.The sample of numbering 3,4,5 is December 1 in 2016 as previously described Day, to each exhibit-trader's rope sample in the rubber exhibition of the new International Exhibition Centre in Shanghai.

Preceding 1-1 2. as described in " coal tar, pine tar, aromatic naphtha, any or more of pitch will not be given out and plant combination Feature stench, or and will not give out the feature stench of polycyclic aromatic hydrocarbon, or and the people that chokes peculiar smell "；Experiment through the present inventor It was found that：Also it on vulcameter OR gate Buddhist nun's viscosity apparatus, can be heated 10 minutes at 180 DEG C of applying heat with above-mentioned, take out, compare energy It is no to make this straightforward procedure of mylar dyeing and detect；Certainly also it can make more smart with gas chromatography known to classics Accurate checking is determined.

As preceding 1-9. address by A or/and B component：Weight ratio=5~90 of general purpose rubber: 95~10, or again and Reinforcing agent, constitution filler, through mixing in advance, obtain mixing A or/and the rubber compound composition of B component；It is directed to and rubber Emulsion or solution mutually mix, this can refer to known technology such as CN101792546B etc..

The component A of the present invention of embodiment 2., the preparation method of B component are primarily characterized in that：It is all " thin by normal temperature elastomer Broken machine or freezing fine crusher once, and after machine excessively excessively in small, broken bits, can just obtain and cross 60 mesh sieves no less than 90% parts by weight and have many In the thin rubber powder that 100 mesh sieves are crossed equal to 50% parts by weight or and be used as promote broken auxiliary agent " mixed material of this intermediate state, then Separately won again through lock out operation and subsequent treatment in butter shape, micelle shape, in flakes graininess, shape, any form in strip Plastifying material component A, and shape, granular B component are considered to be worth doing in powder, piece；" component A ", with following 2-5 to 2-6 or and Any or more the combinations of planting feature of the 2-1 into 2-4, " B component ", with following 2-5 and 2-7 or with 2-1 to 2-4 In any or more combination for planting feature：

Its quality of rubber materials of 2-1. belongs to the combination of scrap rubber described in embodiment 1-2；

2-2. obtained 16 to 30 mesh hole scopes using known scrap rubber coarse crushing, crushing, magnetic separation, screening process The grain size grading of any sieve mesh or the thick micelle of mixing；

" thick micelle " described in 2-3. to 2-2, then admix thereto to being slightly the low-grade of 200 mesh sieves or useless with high-grade The powder material of rubber thermal cracking slag, " the thick micelle " had both promoted the charged material weight of broken auxiliary agent with " powder of cracking slag " Compare W_{Thick micelle}/W_{Promote broken auxiliary agent}=100/8~50；

2-4. or by " thick micelle " described in 2-2, imports freezing fine crusher；

2-5. to cross freezing fine crusher after gained " must at least more than 90% cross 60 mesh sieves and have more than be equal to 50% weight Part cross the thin rubber powder of 100 mesh sieves ", or cross " at least more than 90% must crossing and 60 mesh sieves and have for gained after normal temperature elastic body fine crushing machine More than the thin rubber powder and the mixed material of the broken auxiliary agent of rush that 100 mesh sieves are crossed equal to 50% parts by weight ", implement classification, described point Level, be characterized in：

" thin rubber powder or and promote the mixed material of broken auxiliary agent " is divided into two parts by 2-5-a.：Both thick material was：Cross 60 mesh sieves It is mixed to only 100 mesh or to the only rubber powder of any mesh sieve of 150 mesh sieve scopes and the metal fines for being enriched not sieve Compound-i；With thin material：Cross 100 mesh or the ultra-fine rubber powder or mixed with the broken auxiliary agent of rush to any mesh sieve for crossing 150 mesh sieve scopes Compound-ii；

2-5-b. or " thin rubber powder or and promote the mixed material of broken auxiliary agent " is divided into three parts：Both thick material was：Cross 60 Mesh sieve to only 100 mesh or to the only rubber powder of any mesh sieve of 150 mesh sieve scopes and had been enriched not the metal fines sieved Mixture-i；With thin material：100 mesh are crossed or to any mesh sieve for crossing 150 mesh sieve scopes, to the ultra-fine glue of only 200 mesh sieves Powder-iii；And thinner material：Cross the broken auxiliary agent of rush and the thin rubber powder-iv less than thick micelle throwing amount 5% of 200 mesh sieves；

2-5-c. or the demand according to market, by " i " part described in 2-5-a, 2-5-b, re-grading be 60 mesh extremely The but grain size grading rubber powder-v of any sieve mesh of 150 mesh sieve scopes, and the metal before classification or/and in rear removing rubber powder is thin Bits；

Or the demand according to market, by " ii " described in 2-5-a, or " iii " described in 2-5-b, re-grading was 100 mesh or to 150 cross mesh sieve scopes any mesh sieves, to only any sieve mesh of 200 mesh sieve scopes grain size grading material- vi；

2-6. is to described in " i " described in 2-5-a or 2-5-b and 2-5-c " v ", implementing subsequent treatment, separately winning in butter Shape, micelle shape, graininess, in flakes shape, in strip any form plastifying material component A, be specifically：

2-6-a. implements magnetic separation or/and electric field choosing, further removes gold therein to " i " described in 2-5-a or 2-5-b Belong to fines, obtain 60 mesh sieves to only 100 mesh or to the rubber powder-vii of only any mesh sieve of 150 mesh sieve scopes；

The ratio between 2-6-b. is mixed plus known softening agent to " v " described in " vii " described in 2-6-a or/and 2-5-c, by weight For W_{Vii or/and v}/W_{Known softening agent}=100/20~100 scope formulas feed intake, and obtain the starting mix of component A processed；

2-6-c. is to " the starting mix of component A " described in 2-6-b, and temperature is applied in heating, and described " Shi Wen " is controlled in room temperature To any of 200 DEG C of scopes；

" softening agent " described in 2-6-d.2-6-b, at least can be：White oil, machine oil, vegetable oil, stearic acid, vaseline, The combination that wax, transformer oil, ancient marlon resin, terpene resin, modified rosin scope optional one or more is planted；To known softening agent Selection mix match somebody with somebody after whether can reach the feature of environmental protection requirement verification mode, be 1. described in detail referring to the 1-1 in embodiment 1；

2-6-e. or and while with addition of softening agent, also add disconnected sulphur or/and desulfurization used additives, the auxiliary agent is known Or function additive kind purchased in market, addition is also by known routine dose；Described known disconnected sulphur or/and desulfurization used additives, It adds metering and kind, reference can be made to Chinese Patent Application No. 95109174.3 etc.；

2-6-f. while as described in 2-5-c " heating " is applied, and with upper stirring, extrusion, pelletizing, roll-in any or More than plant operation anabolic process processing after, obtain butter shape, cake powdery, graininess, micelle shape, sheet, strip it is any Plastifying material --- the component A of form；

2-7. is real to " ii " described in 2-5-a, or/and " iii " described in 2-5-b, or/and " vi " described in 2-5-c Apply subsequent treatment, separately win in powdery, piece bits shape, granular any form B component, it is specific as 2-7-a, 2-7-b or and 2-7-c：

2-7-a. mixes softening agent or/and the disconnected sulphur modification agent of the single or compounding that add the known rubber of nonstaining property conventional, Described softening agent, disconnected sulphur modification agent, it is all known kind, and the ratio fed intake by weight is W_{Ii or/and iii or/and vi}/ W_{Softening agent or/and disconnected sulphur modification agent}=100/0~15, obtain the starting mix of B component processed；

2-7-b. applies heating-up temperature, described temperature is in room temperature to 60 to " the starting mix of B component " described in 2-7-a Any of DEG C scope；

2-7-c. imposes the mixing of homogenization to " the starting mix of B component " described in 2-7-a again, or and with apply extrusion, Any or more anabolic process planted of roll-in, last gained for powdered, piece bits shape, granular any form Ultra-fine rubber powder material --- B component.

The scope formula of weight part ratio 20~100 of the softening agent known in as described in preceding preparation component A is fed intake, it is specifically used many It is fewImplement people only on the premise of locking is without refining process, need to further pass through lock when control prepares component A material Determine heated temperature of charge during plasticizing operation and, in a certain temperature of room temperature to 200 DEG C of scopes, lock the grain of foregoing " i " or " v " Footpath etc., then passes through the experiment of limited number of time again, it is established that a certain physical property of softening agent addition and final component A, the physical property At least include a certain or more the item " interval " of " component A physical property " described in 1-3 in embodiment 1, such as including but not limited to Mooney is viscous Degree (ML100 DEG C of 1+4) is controlled in 15 to 95 scopes, and its vulcanizate shore a hardness at this two of 45 to 70 scopes, Experiment through limited number of time, so that it may which the physical property of component A needed for setting up is closed with the corresponding figure containing number curve of the specifically used amount of softening agent It is that for this common process technical staff to the industry, creative work need not be spent；Similar makes to such as preceding Known softening agent or/and the scope formula of weight part ratio 0~15 of disconnected sulphur modification agent feed intake described in standby B component, specifically used many It is fewImplementing people also only need to be when control prepares B component material, under conditions of locking is not if heated etc., then again by limited Secondary experiment, it is established that a certain physical property of softening agent or/and disconnected sulphur modification agent addition and final B component, the physical property is at least A certain or more item " interval " including " B component physical property " described in 1-4 in embodiment 1, such as includes but is not limited to pull apart stretching strong Degree is in 4.00MPa to 17.00 scopes, or shore a hardness is in two of 70 to 85 scopes, the also experiment through limited number of time, so that it may build The physical property of B component needed for erecting and softening agent or/and the respective function curve map relation of the disconnected specifically used amount of sulphur modification agent, It is also that need not spend creative work for this common process technical staff to the industry.

Its feature for preparing of the A/B components compound composition of the present invention of embodiment 3. also includes：By the A described in embodiment 1 Component, with the B component described in embodiment 1, any proportion by A/B weight than 95/5 to 5/95 scope is pre-mixed, described Hybrid mode includes stirring, banburying, rolling, any or more of extrusion and plants the combination of operation, and note to heat when mixing； Because A/B weight than it is different obtain appointing in powdery, graininess, piece bits shapes, cake powdery, micelle shape, glue sheet, adhesive tape shape One or more plants the compound composition material for storing stand-by A/B components of combination form.

The preparation embodiment of the present invention containing A or/and B component rubber compound composition of embodiment 4. is：By embodiment 1 With A, B described in embodiment 2, by A or/and B component：Weight ratio=5~90 of general purpose rubber: 95~10, i.e., both or three The parts by weight summation of person be 100 parts, or again with reinforcing agent, constitution filler, through in advance mix, dehydration, heat it is ripe, kneading appoint After the anabolic process of one or more item, obtain mixing A or/and the rubber compound composition of B component；Described general purpose rubber, refers to Natural rubber, butadiene-styrene rubber, butadiene rubber, isoprene rubber, any or more of neoprene plant combination or its emulsion Or solution is any；Described reinforcing agent, refers to that carbon black, any or more of white carbon plant combination；Described constitution is filled out Material, refers to that calcium carbonate, any or more of clay plant combination.

The preparation embodiment of the rubber and plastic compound composition of the present invention containing A or/and B component of embodiment 5. is：It will implement A or/and B component described in example 1 and embodiment 2, by A or/and B component and weight ratio=5~95 of resin: 95~5, i.e., two The parts by weight summation of person or three are 100 parts, or with known modified additive, after sneaking out journey through heat in advance, obtain containing A or/and The rubber and plastic compound composition of B component.

Described resin is well known materials, and it can include polypropylene, polyethylene, polyvinyl chloride, propylene-ethylene copolymerization Thing, ethylene-octene copolymer, ethylene-vinyl acetate copolymer, allyl resin, epoxy resin, alkyl phenolic resin, poly- ammonia Any or more combination planted of ester, amino resins, also including such as waste plastics lawn, waste plastics container, waste plastics packaging film The combination of any or more kind；

Described known modified additive, the known normal dosage ranges of its consumption category, its auxiliary agent kind includes：

Rubber vulcanization system used additives, such as sulphur, 2- benzothiazolyl mercaptans, tetramethylthiuram disulfide, zinc oxide, Stearic one or more of combination, and preventing aging system used additives, such as N- rings ethyl-N '-diphenyl-para-phenylene diamine, 2- mercaptan Base benzimidazole, cyclohexanone peroxide, one or more of combinations；Surface coupling agent, such as ethylene methacrylic base silane, aniline MTES, ethylene titanate, one or more of combinations of glycidyl acrylate；Compatibilization system is used Auxiliary agent, such as molecular weight are in the liquid polyisoprene rubber or liquid polybutadiene rubber of 2000~5000 scopes, maleic acid Acid anhydride；One kind of plasticiser system used additives, such as dibutyl phthalate or dioctyl ester or cyclohexane dicarboxylic acid dinonyl or Combination above.

Described heat is mixed, i.e. its material any temperature of heated material temperature in 100 to 200 DEG C of scopes in mixing.

Its overall craft embodiment for preparing of the preferable component A of embodiment 6. 1 is that normal temperature is in small, broken bits again through not higher than rubber The fuel-displaced temperature of thermal cracking and under being acted on while high dose nonstaining property softening agent, realizes plasticizing to scrap rubber.

Described to prepare, it handles the combination for specifically including following 6-1 to 6-7：

Its quality of rubber materials of 6-1. belongs to the combination of scrap rubber described in embodiment 1-2, more specifically selects in high-grade scrap rubber The automobile oblique abandoned or/and the tire shoulder material of all-steel meridian damaged tire；

6-2. is by crossing 60 mesh to the only grain size grading of any sieve mesh of 150 mesh sieve scopes or the rubber powder grain material of mixing To implement the starting material of thermoplastification processing；

The acquisition pattern of the starting material can be：A. with the tire shoulder material of the existing damaged tire as described in ditch roller machine by 6-1 The thick micelle for being broken into 20 mesh sieves is ground, and the broken frame material for separating the still miscellaneous steel wire or/and nylon for thering is rubber powder to consider grain to be worth doing；B. it is right Afterwards by it is miscellaneous have rubber powder consider to be worth doing grain steel wire or/and nylon frame material or with another part scrap rubber import scrap rubber pyrolysis furnace, return Fuel oil is received, and obtains scrap rubber thermal cracking slag simultaneously, here it is worth noting that：Or with another part scrap rubber, to take implementation Low-grade scrap rubber described in example 1-2, such as automobile tire tyre cushion abandoned, the automobile-used wheel abandoned of motorcycle, bicycle, electric car, power Tire, scrap rubber pipe, scrap rubber footwear, scrap leather footwear, waste tape, scrap rubber pad, the side crops of rubber, the sports ground plastic pad abandoned gives up Cable skin, given up turning rubber covered rollers material, the workshop incipient scorch material of rubber, and colloid is given up any or more combination planted of gloves etc. It is preferred, so more meets the sustainable theory of resource rational utilization；C. the thermal cracking slag described in foregoing b is implemented to crush, obtained To the powder for being slightly 200 mesh sieves, make to promote broken auxiliary agent with this thermal cracking ground-slag end；D. with the thick micelle W of 20 mesh sieves excessively_{Thick micelle}With Thermal cracking ground-slag end promotees broken auxiliary agent W_{Promote broken auxiliary agent}Weight ratio=W_{Thick micelle}/W_{Promote broken auxiliary agent}≤ 100/8 implements mixture, and mixture material is led Enter normal temperature elastic body fine crushing machine, from 60 mesh to any sieve mesh of 150 mesh sieve scopes sieve to going out machine stock grading, thus Obtain the starting material of thermoplastification to be made processing, i.e., 60 mesh to the only grain size grading of any sieve mesh of 150 mesh sieve scopes or The rubber powder grain material of mixing；

6-3. to cross 60 mesh to only any sieve mesh of 150 mesh sieve scopes grain size grading or mixed rubber powder grain material, The removing impurities operating process of magnetic field or/and electric field is passed it through again, and metal impurities therein are removed to the low energy consumption of process energy accordingly, With filter glue or/and the removing impurities process of refining with avoiding follow-up highly energy-consuming again to plastifying material；

6-4. thermoplastifications processing softening agent used is to exclude to have coal tar, pine tar, aromatic hydrocarbons smelly or/and that have contaminative Odorless and the known softening agent of nonstaining property that rubber processing industry outside oil, pitch is commonly used, through the environmental protection as described in implementing 1-1 The confirmation of quality control requirement, softening agent kind is selected：The tackifying resins such as coumarone, rosin, modified rosin it is any or more Kind combination, any or more of machine oil, glycerine, odorless heavy oil, transformer oil, vegetable oil, vaseline, naphthenic oil etc. plant Combination；

6-5. and component A material are without the Mooney viscosity of refining process and the shore a hardness control mode of its vulcanizate：It is logical Heated temperature of charge is crossed during locking plasticizing operation in softening agent addition described in 180 DEG C to 200 DEG C scopes and regulation and control 6-4 Combination change, the rubber powder grain material and softening agent composition of metal impurities will be stripped of described in 6-3 through airtight heating, cold But after, its Mooney viscosity (ML100 DEG C of 1+4) is controlled in 55 to 65 scopes, and its vulcanizate shore a hardness 55 to 60 degree of scopes, the softening agent addition, using the weight ratio of starting material described in 6-2 and known softening agent described in 6-4 as W_{Starting material}/W_{Known softening agent}" removing impurities " described in=100/20~25, i.e. 6-3, the weight of the metal impurities removed, which can be omitted, to be disregarded；

6-6. and while with addition of softening agent, also adds disconnected sulphur or/and desulfurization used additives, and the auxiliary agent is known or city The function additive of purchase, it adds metering and kind, reference can be made to Chinese Patent Application No. 95109174.3 etc..

6-7. apply as described in 6-5 " heating " " temperature is in 180 DEG C to 200 DEG C scopes " while, and with it is upper stir, After extrusion, pelletizing, any or more anabolic process processing for planting operation of roll-in, butter shape, cake powdery, graininess, glue are obtained Bulk, sheet, plastifying material --- the component A of any form of strip；

The tensile strength of pulling apart that the present embodiment obtains the vulcanizate of component A product falls in 16.00MPa to 17.00 scopes, pulls Disconnected elongation is in 400% to 450% scope, and proportion is 1.17, and the feature of environmental protection meets described in embodiment 1-1.The present embodiment it is preferable It is described in 6-2, because having thin rubber powder more in rubber powder grain material, this is conducive to making scrap rubber at a lower temperature Powder grain material is softened agent and is swelled.

Its overall craft embodiment for preparing of another the preferable component A of embodiment 7. is that normal temperature is in small, broken bits again through not higher than rubber The fuel-displaced temperature of glue thermal cracking and under being acted on while high dose nonstaining property softening agent, realizes plasticizing to scrap rubber.

Described to prepare, its processing specifically includes combinations of the following 7-1 into 7-7：

Its quality of rubber materials of 7-1. belongs to the combination of scrap rubber described in embodiment 1-2, more specifically selects in low-grade scrap rubber Scrap rubber footwear；

7-2. is by crossing 60 mesh to the only grain size grading of any sieve mesh of 150 mesh sieve scopes or the rubber powder grain material of mixing To implement the starting material of thermoplastification processing；

The acquisition pattern of the starting material can be：A. ground with the existing scrap rubber footwear as described in ditch roller machine by 7-1 and be broken into 5 The thick micelle of mesh sieve, and broken separate the nonrubber impurity such as fiber lining crumble, metal fillings grain in the still miscellaneous footwear for thering is rubber powder to consider grain to be worth doing Material；B. any or more kind and then by nonrubber impurity material or with another part low-grade scrap rubber as described in embodiment 1-2 Combination import scrap rubber pyrolysis furnace, to reclaim fuel oil, and obtain low-grade scrap rubber thermal cracking slag simultaneously；C. to foregoing b institutes The low-grade scrap rubber thermal cracking slag stated is implemented to crush, and obtains to the powder for being slightly 200 mesh sieves, with this thermal cracking ground-slag end Make to promote broken auxiliary agent；D. with the thick micelle W of 5 mesh sieves excessively_{Thick micelle}Promote broken auxiliary agent W with thermal cracking ground-slag end_{Promote broken auxiliary agent}Weight ratio= W_{Thick micelle}/W_{Promote broken auxiliary agent}≤ 100/8 implements mixture, mixture material is imported into normal temperature elastic body fine crushing machine, from 60 mesh to 150 mesh sieve models The sieve for any sieve mesh enclosed obtains the starting material of thermoplastification to be made processing to going out machine stock grading, thus, i.e., 60 mesh extremely The but grain size grading of any sieve mesh of 150 mesh sieve scopes or the rubber powder grain material of mixing；

7-3. to cross 60 mesh to only any sieve mesh of 150 mesh sieve scopes grain size grading or mixed rubber powder grain material, The removing impurities operating process of magnetic field or/and electric field is passed it through again, and metal impurities therein are removed to the low energy consumption of process energy accordingly, With filter glue or/and the removing impurities process of refining with avoiding follow-up highly energy-consuming again to plastifying material；

7-4. thermoplastifications processing softening agent used is to exclude to have coal tar, pine tar, aromatic hydrocarbons smelly or/and that have contaminative Odorless and the known softening agent of nonstaining property that rubber processing industry outside oil, pitch is commonly used, through the ring as described in embodiment 1-1 The confirmation that control of guaranteeing the quality is required, softening agent kind is selected：RX-80 modified rosin resins, odorless heavy oil, transformer oil, plant Any or more combination planted of oil, vaseline, naphthenic oil etc.；

7-5. and component A material are without the Mooney viscosity of refining process and the shore a hardness control mode of its vulcanizate：It is logical Heated temperature of charge is in softening agent addition described in room temperature to 150 DEG C of scopes and regulation and control 7-4 when crossing locking plasticizing operation Combination change, by the softening agent composition described in the rubber powder-granule material and 7-4 described in 7-3 after airtight heating, cooling, makes it Mooney viscosity (ML100 DEG C of 1+4) is controlled in 40 to 55 scopes, and its vulcanizate shore a hardness≤55 degree, the softening Agent addition, the weight ratio using known softening agent described in starting material described in 7-2 and 7-4 is W_{Starting material}/W_{Known softening agent}=100/ " removing impurities " described in 25~35, i.e. 7-3, the weight of the metal impurities removed, which can be omitted, to be disregarded；

7-6. and while with addition of softening agent, also adds disconnected sulphur or/and desulfurization used additives, and the auxiliary agent is known or city The function additive of purchase, it adds metering and kind, reference can be made to Chinese Patent Application No. 95109174.3 etc..

7-7. apply as described in as described in 7-5 " heating " " room temperature to 150 DEG C of scopes " while, and with it is upper stir, extrude, After pelletizing, any or more anabolic process processing for planting operation of roll-in, obtain butter shape, cake powdery, graininess, micelle shape, Plastifying material --- the component A of sheet, any form of strip.

The tensile strength of pulling apart of the vulcanizate of obtained component A product falls in 4.00MPa to 4.80 scopes, and elongation at break exists 300% to 350% scope, proportion is 1.40, and the feature of environmental protection meets described in embodiment 1-1.The preferable of the present embodiment is 7-2 institutes State, relatively show the thin rubber powder of city's technology more because having in rubber powder grain material, can more preferably make by oneself among these or mistake purchased in market 100 mesh are to the only grain size grading of any sieve mesh of 150 mesh sieve scopes or the rubber powder of mixing, or again through magnetic field or/and electricity After field removing metal impurities, as the starting material for implementing thermoplastification processing, this is conducive to making scrap rubber at a lower temperature Powder grain material be softened agent and be swelled；" Mooney viscosity (the ML100 DEG C of 1+4) value " of product be more preferably controlled in 15 to 35 scopes it is any or 60 to 95 scopes any, be so more beneficial for user formula materials selection.

Its overall craft embodiment for preparing of another the preferably component A of embodiment 8. is that normal temperature is in small, broken bits again through being not higher than The fuel-displaced temperature of rubber thermal cracking and under being acted on while high dose nonstaining property softening agent, realizes plasticizing to scrap rubber.

Described to prepare, its processing specifically includes combinations of the following 8-1 into 8-7：

Its quality of rubber materials of 8-1. belongs to the combination of scrap rubber described in embodiment 1-2, specifically selects in high-grade scrap rubber Automobile with the oblique abandoned or/and all-steel meridian damaged tire or its decompose part for example tire top, sidewall, tire shoulder, mouth circle it is any or more Kind combination 1, with automobile with the useless half steel radial tyre abandoned or its decompose part for example tire top, sidewall, tire shoulder, mouth circle any or More than the combination 2 planted, or/and the lower crown buffings of turning during automobile tire retreading, polishing, rubber powder material combination 3, by combination 1 and The weight ratio of combination 2 or/and combination 3 is W_{Combination 1}∶W_{Combination 2}∶W_{Combination 3}=100: 0~100: 0~100 scopes implement combination, to entangle It is just pure with useless half steel radial tyre component A exist material viscosity it is poor caused by sizing material cross the flaw of the easy part of roller；

8-2. is by crossing 60 mesh to the only grain size grading of any sieve mesh of 150 mesh sieve scopes or the rubber powder grain material of mixing To implement the starting material of thermoplastification processing；

The acquisition pattern of the starting material can be：A. with the existing combination 1 as described in ditch roller machine by 8-1, combination 2, group Close 3 materials and grind the thick micelle for being broken into 20 mesh sieves respectively, and the broken still miscellaneous steel wire for thering is rubber powder to consider grain to be worth doing or/and the nylon of separating Frame material；B. and then by the frame material of the miscellaneous steel wire for having rubber powder to consider grain to be worth doing or/and nylon or with another part scrap rubber useless rubber is imported Glue pyrolysis furnace, reclaims fuel oil, and obtains scrap rubber thermal cracking slag simultaneously, here it is worth noting that：Or with another part give up rubber Glue, with low-grade scrap rubber described in Example 1-2, such as automobile tire tyre cushion abandoned, motorcycle, bicycle, electric car, The automobile-used tire abandoned of power, scrap rubber pipe, scrap rubber footwear, scrap leather footwear, waste tape, scrap rubber pad, the side crops of rubber, sports ground is used The plastic pad abandoned, cable waste line skin, give up turning rubber covered rollers material, the workshop incipient scorch material of rubber, colloid give up any of gloves etc. or The combination planted above is preferred, and so more meets the sustainable theory of resource rational utilization；C. to the thermal cracking slag described in foregoing b Implement to crush, obtain to the powder for being slightly 500 mesh sieves, make to promote broken auxiliary agent with this thermal cracking ground-slag end；D. with 20 mesh sieves excessively Thick micelle, that is, meet the thick micelle W of weight ratio scope of the 8-1 aforementioned combinatorials 1 with combining 2 or/and combination 3_{Thick micelle}, with hot tearing Solve ground-slag end and promote broken auxiliary agent W_{Promote broken auxiliary agent}Weight ratio=W_{Thick micelle}/W_{Promote broken auxiliary agent}≤ 100/8 implements mixture, and mixture material is imported into normal temperature Elastic body fine crushing machine, from 60 mesh to any sieve mesh of 150 mesh sieve scopes sieve to going out machine stock grading, thus treated Make the starting material of thermoplastification processing, i.e., 60 mesh to the only grain size grading of any sieve mesh of 150 mesh sieve scopes or mixing Rubber powder grain material；

8-3. to cross 60 mesh to only any sieve mesh of 150 mesh sieve scopes grain size grading or mixed rubber powder grain material, The removing impurities operating process of magnetic field or/and electric field is passed it through again, and metal impurities therein are removed to the low energy consumption of process energy accordingly, With filter glue or/and the removing impurities process of refining with avoiding follow-up highly energy-consuming again to plastifying material；

8-4. thermoplastifications processing softening agent used is to exclude to have coal tar, pine tar, aromatic hydrocarbons smelly or/and that have contaminative Odorless and the known softening agent of nonstaining property that rubber processing industry outside oil, pitch is commonly used, through the environmental protection as described in implementing 1-1 The confirmation of quality control requirement, softening agent kind is selected：The tackifying resins such as coumarone, rosin, modified rosin it is any or more Kind combination, any or more of machine oil, glycerine, odorless heavy oil, transformer oil, vegetable oil, vaseline, naphthenic oil etc. plant Combination；

8-5. and component A material are without the Mooney viscosity of refining process and the shore a hardness control mode of its vulcanizate：It is logical Heated temperature of charge is crossed during locking plasticizing operation in softening agent addition described in 180 DEG C to 200 DEG C scopes and regulation and control 2-4 Combination change, by rubber powder-granule material and softening agent composition through airtight heating, cooling after, make (ML100 DEG C 1 of its Mooney viscosity + 4) it is controlled in 55 to 65 scopes, and the shore a hardness of its vulcanizate spends scopes 55 to 60, the softening agent addition, Weight ratio using known softening agent described in starting material described in 8-2 and 8-4 is W_{Starting material}/W_{Known softening agent}=100/35~40；I.e. " removing impurities " described in 8-3, the weight of the metal impurities removed, which can be omitted, to be disregarded；

8-6. and while with addition of softening agent, also adds disconnected sulphur or/and desulfurization used additives, and the auxiliary agent is known or city The function additive of purchase, it adds metering and kind, reference can be made to Chinese Patent Application No. 95109174.3 etc.；

8-7. while as described in as described in 8-5 " heating " " 180 DEG C to 200 DEG C scopes " is applied, and with it is upper stir, it is crowded Go out, pelletizing, after any or more anabolic process processing for planting operation of roll-in, obtain butter shape, cake powdery, graininess, micelle Shape, sheet, plastifying material --- the component A of any form of strip.

The tensile strength of pulling apart of the vulcanizate of obtained component A product falls in 10.00MPa to 14.00 scopes, elongation at break In 400% to 450% scope, proportion is 1.17, and the feature of environmental protection meets described in embodiment 1-1.

Component A of the present invention, can turn into independent commodity, or produce correlated product or raw material production as Endogenous Intermediate product during product.The preferable of the present embodiment is described in 6-2 that, because having thin rubber powder more in rubber powder grain material, this has It is swelled beneficial to making the powder grain material of scrap rubber be softened agent at a lower temperature.

A kind of its overall craft embodiment of the preferably B component preparation method of embodiment 9. is the thermal cracking using scrap rubber The crushed material of slag, particularly uses the crushed material of the thermal cracking slag of low-grade scrap rubber as much as possible, makees to promote broken auxiliary agent, often Obtained by warm elastic body fine crushing machine processing is in powdered or is processed further considering shape, the thing of granular any form to be worth doing in flakes Material.

Described to prepare, its specific features includes what any or more to 9-2 or with 9-3 to 9-5 of 9-1 as described below planted Combination：

9-1. takes the automobile useless half steel radial tyre abandoned or its decomposition in the high-grade scrap rubber as described in embodiment 1-2 Part such as tire top, sidewall, tire shoulder, the thick micelle of any or more combination planted of mouth circle are the original into normal temperature elastic body fine crushing machine Material, the particle size range of the thick micelle, with took 20 mesh to any sieve mesh of only 40 mesh sieves grain size grading or mixing it is thick Micelle；

Any or more thermal cracking slag for planting combination of low-grade scrap rubber described in 9-2. Examples 1-2 to thick mistake The crushed material of 200 mesh sieves, makees the broken auxiliary agent of rush when normal temperature elastic body fine crushing machine handles thick micelle；

The weight for promoting broken auxiliary agent described in thick micelle described in 9-1 and 9-2 is compared W by 9-3._{Thick micelle}/W_{Promote broken auxiliary agent}=100/25~40 models Enclose the mixing that feeds intake；

9-4. is to crossing at least more than 90% must the crossing 80 mesh sieves and have more than being equal to of gained after normal temperature elastic body fine crushing machine 70% parts by weight cross the thin rubber powder of 100 mesh sieves and promote the mixed material of broken auxiliary agent, implement classification, described classification is characterized in：

Material was at least divided into or only two parts of 120 mesh sieves by 9-4-a., cross 120 mesh sieves to be narrower than equal to 120 Purpose rubber powder and the mixture for promoting broken auxiliary agent, but 120 mesh sieves to be narrower than 60 mesh to being coarser than the rubber powder of 120 mesh and be enriched The mixture of the metal fines of sieve is not crossed；

9-4-b. or material is divided into 60 mesh sieves to only 120 mesh sieve, and crosses 120 mesh sieves to only 200 mesh sieve, mistake Three parts of 200 mesh sieves, the composition of this three part is respectively：Cross 60 mesh sieves to only 120 mesh sieves be corresponding mesh number scope glue The mixture of powder and the metal fines for being enriched not 120 mesh sieves, crosses 120 mesh sieves to the thin rubber powder of only 200 mesh sieves, mistake The broken auxiliary agent of rush of 200 mesh sieves and the thin rubber powder less than thick micelle throwing amount 5%；

Material was at least divided into or only two parts of 150 mesh sieves by 9-4-c., spent being equal to be narrower than for 150 mesh sieves The rubber powder of 150 mesh and the mixture for promoting broken auxiliary agent, but 150 mesh sieves is to be narrower than 60 mesh to the rubber powder and enrichment for being coarser than 150 mesh The mixture of the metal fines of sieve is not crossed；

9-4-d. or material is divided into 60 mesh sieves to only 150 mesh sieve, and crosses 150 mesh sieves to only 200 mesh sieve, mistake Three parts of 200 mesh sieves, the composition of this three part is respectively：Cross 60 mesh sieves to only 150 mesh sieves be corresponding mesh number scope glue The mixture of powder and the metal fines for being enriched not 150 mesh sieves, crosses 150 mesh sieves to the thin rubber powder of only 200 mesh sieves, mistake The broken auxiliary agent of rush of 200 mesh sieves and the thin rubber powder less than thick micelle throwing amount 5%；

9-4-e. or the demand according to market, by the mesh of mistake 60 described in 9-4-a, 9-4-b to the part of only 120 mesh, Re-grading was grain size grading rubber powder of 60 mesh to only any sieve mesh of 120 mesh sieve scopes, and before classification or/and rear removing Metal fines in rubber powder；Mixture by the rubber powder of the mesh sieve of mistake 120 described in 9-4-a or 9-4-b or with the broken auxiliary agent of rush, Re-grading was grain size grading material of 120 mesh to only any sieve mesh of 200 mesh sieve scopes；Or by institute in 9-4-c, 9-4-d The mesh of mistake 60 stated is to the part of only 150 mesh, and re-grading was particle diameter of 60 mesh to only any sieve mesh of 150 mesh sieve scopes It is classified rubber powder, and the metal fines before classification or/and in rear removing rubber powder；By 9-4-c or, the mistake 150 described in 9-4-d The rubber powder of mesh sieve or the mixture with the broken auxiliary agent of rush, re-grading was any sieve mesh of 150 mesh to only 200 mesh sieve scopes Grain size grading material；

9-5. or to the mesh sieve of mistake 120 described in 9-4 to only 200 mesh sieves or to cross 150 mesh sieves thin to only 200 mesh sieves Rubber powder or and promote the mixture of broken auxiliary agent, implement further processing, specifically refer to any or more group planted as described below Close：

9-5-a. mixes softening agent or/and the disconnected sulphur modification agent of the single or compounding that add the known rubber of nonstaining property conventional, Described softening agent, disconnected sulphur modification agent, it is all known kind and known conventional amount used, to known softening agent, disconnected sulphur modification The selection verification mode of agent is met described in embodiment 1-1；

9-5-b. to described in 9-5-a " mix plus the conventional single of known rubber of nonstaining property or the softening agent of compounding or/and Material after disconnected sulphur modification agent ", then fine mixing at a high speed is applied, obtain powder；Or rolled or/and extrusion process after roller, finally Obtain piece bits shape or graininess.

The present embodiment 9 is that, using useless half steel radial tyre B component, B component is independent because of traditional market accreditation rubber powder product The physical property of product that roller can not be in flakes is crossed, therefore when not 120 mesh sieves excessively or even excessively 150 for not approved B component of falling in lines in this example by market During the B component product of mesh sieve, then can will be in small, broken bits after do not cross 120 mesh to the rubber powder of any sieve mesh for crossing 150 mesh sieve scopes and be also regarded as Thick rubber powder, and make getting the raw materials ready for processing in small, broken bits again；Contain in addition, working as to be elected to be the thermal cracking ground-slag for promoting broken auxiliary agent and mince in B component Amount think excessive by market user, or thermal cracking slag resource market it is well sold and in short supply when, then by its selection by winnowing or/and can screen out, also make again Secondary processing in small, broken bits is got the raw materials ready.

B component obtained by the present embodiment, it pulls apart tensile strength in 10.00MPa to 14.00 scopes, that is, remains useless Half steel radial tyre sizing material pulls apart the 2/3 of tensile strength before being reproduced, proportion is in 1.25 to 1.35 scopes, and shore a hardness is 75 To 85 scopes, elongation is in 180% to 350% scope；Pure B component can not be extruded or extrude in flakes, by 20 parts of additions of B component In background glue C, island, the heterogeneous sizing material of marine facies can be formed, the abrasion of its vulcanizate are always significantly less than on year-on-year basis in background glue Such as 20 parts of the component A of embodiment 6 or/and 8 is added in C or does not add the abrasion of B component, the folding resistance of its vulcanizate is always obvious Ground, which is worse than, to be added such as 20 parts of the component A of embodiment 6 or/and 8 in background glue C on year-on-year basis or does not add the folding resistance of B component；Sizing material has Defoaming；

The background glue C, its specific formula, at least includes：100 parts of butadiene-styrene rubber, 5 parts of zinc oxide, 1 part of stearic acid, 2 parts of sulphur, 1.5 parts of accelerant CZ, 0.5 part of Vulcanization accelerator TMTD, 1 part of antioxidant MB, 60 parts of carbon black N330,5 parts of machine oil； , need to be simultaneously by A or B component/sulphur/accelerant CZ/Vulcanization accelerator TMTD weight ratio=100/ when adding 20 parts of A or B component 0.8/0.6/0.2 add, conditions of vulcanization is 155 DEG C/7 minutes.

The preparation method of the another preferable B component of embodiment 10.

Its overall craft embodiment is same as Example 9.

Described to prepare, it is any or more to 10-2 or with 10-3 to 10-5 that its specific features includes 10-1 as described below The combination planted：

10-1. takes the sports ground in the low-grade scrap rubber as described in embodiment 1-2 with the plastic pad abandoned obtained by through coarse crushing Thick micelle is the raw material into normal temperature elastic body fine crushing machine, the particle size range of the thick micelle, to take 5 mesh to only 40 mesh sieve Any sieve mesh grain size grading or the thick micelle of mixing；

Any or more thermal cracking slag for planting combination of low-grade scrap rubber described in 10-2. Examples 1-2 to thick mistake The crushed material of 200 mesh sieves, makees the broken auxiliary agent of rush when normal temperature elastic body fine crushing machine handles thick micelle；

The weight for promoting broken auxiliary agent described in thick micelle described in 10-1 and 10-2 is compared W by 10-3._{Thick micelle}/W_{Promote broken auxiliary agent}=100/25~30 Scope feeds intake mixing；

10-4. is to crossing at least more than 90% must the crossing 80 mesh sieves and have more than being equal to of gained after normal temperature elastic body fine crushing machine 70% parts by weight cross the thin rubber powder of 100 mesh sieves and promote the mixed material of broken auxiliary agent, implement classification, described classification is characterized in：

Material was at least divided into or only two parts of 120 mesh sieves by 10-4-a., cross 120 mesh sieves to be narrower than equal to 120 Purpose rubber powder and the mixture for promoting broken auxiliary agent, but 120 mesh sieves to be narrower than 60 mesh to being coarser than the rubber powder of 120 mesh and be enriched The mixture of the metal fines of sieve is not crossed；

10-4-b. or material is divided into 60 mesh sieves to only 120 mesh sieve, and crosses 120 mesh sieves to only 200 mesh sieve, mistake Three parts of 200 mesh sieves, the composition of this three part is respectively：Cross 60 mesh sieves to only 120 mesh sieves be corresponding mesh number scope glue The mixture of powder and the metal fines for being enriched not 120 mesh sieves, crosses 120 mesh sieves to the thin rubber powder of only 200 mesh sieves, mistake The broken auxiliary agent of rush of 200 mesh sieves and the thin rubber powder less than thick micelle throwing amount 5%；

Material was at least divided into or only two parts of 150 mesh sieves by 10-4-c., spent being equal to be narrower than for 150 mesh sieves The rubber powder of 150 mesh and the mixture for promoting broken auxiliary agent, but 150 mesh sieves is to be narrower than 60 mesh to the rubber powder and enrichment for being coarser than 150 mesh The mixture of the metal fines of sieve is not crossed；

10-4-d. or material is divided into 60 mesh sieves to only 150 mesh sieve, and crosses 150 mesh sieves to only 200 mesh sieve, mistake Three parts of 200 mesh sieves, the composition of this three part is respectively：Cross 60 mesh sieves to only 150 mesh sieves be corresponding mesh number scope glue The mixture of powder and the metal fines for being enriched not 150 mesh sieves, crosses 150 mesh sieves to the thin rubber powder of only 200 mesh sieves, mistake The broken auxiliary agent of rush of 200 mesh sieves and the thin rubber powder less than thick micelle throwing amount 5%；

10-4-e. or the demand according to market, by the mesh of mistake 60 described in 10-4-a, 10-4-b to the portion of only 120 mesh Point, re-grading was grain size grading rubber powder of 60 mesh to only any sieve mesh of 120 mesh sieve scopes, and before classification or/and after Remove the metal fines in rubber powder；It is mixed by the rubber powder of the mesh sieve of mistake 120 described in 10-4-a or 10-4-b or with the broken auxiliary agent of rush Compound, re-grading was grain size grading material of 120 mesh to only any sieve mesh of 200 mesh sieve scopes；Or by 10-4-c, 10- The mesh of mistake 60 described in 4-d is to the part of only 150 mesh, and re-grading was any sieve mesh of 60 mesh to only 150 mesh sieve scopes Grain size grading rubber powder, and the metal fines before classification or/and in rear removing rubber powder；By 10-4-c or, described in 10-4-d The mesh sieve of mistake 150 rubber powder or and promote the mixture of broken auxiliary agent, re-grading was any of 150 mesh to only 200 mesh sieve scopes The grain size grading material of sieve mesh；

10-5. to the mesh sieve of mistake 120 described in 10-4 to only 200 mesh sieves or crosses 150 mesh sieves to only 200 mesh sieves Thin rubber powder or and promote the mixture of broken auxiliary agent, implement further processing, specifically refer to as described below any or more plant Combination：

10-5-a. mixes softening agent or/and the disconnected sulphur modification agent of the single or compounding that add the known rubber of nonstaining property conventional, Described softening agent, disconnected sulphur modification agent, it is all known kind and known conventional amount used, to known softening agent, disconnected sulphur modification The selection verification mode of agent is：Meet described in embodiment 1-1；

10-5-b. to mixed as described in embodiment 10-5-a plus nonstaining property the conventional single of known rubber or compounding it is soft Material after agent or/and disconnected sulphur modification agent applies fine mixing at a high speed again, obtains powder；Or after roller roll or/and extrusion at Reason, finally obtains piece bits shape or graininess.

The present embodiment 10 is that, using the plastic pad material B component abandoned of sports ground, therefore kind material is more miscellaneous, should be focused on pair The physical property detection of raw material, is equal to scrap rubber footwear material, after regeneration in small, broken bits, it pulls apart tensile strength to general visual its of such a material In 4.00MPa to 6.00 scopes, that is, remain the 2/3 of tensile strength is pulled apart before it is reproduced.

Another the preferable B component of embodiment 11. to prepare its overall craft embodiment identical with embodiment 9 and 10.

Described to prepare, it is any or more to 11-2 or with 11-3 to 11-5 that its specific features includes 11-1 as described below The combination planted：

11-1. takes automobile useless cross-ply or/and all steel abandoned in the high-grade scrap rubber as described in embodiment 1-2 Noon tire, or/and this two kinds or any of which damaged tire decomposition part for example tire top, sidewall, tire shoulder, mouth circle any or with The combination of upper kind；To take the thick micelle of 20 mesh sieve purpose grain size gradings or mixing；

Any or more thermal cracking slag for planting combination of low-grade scrap rubber described in 11-2. Examples 1-2 to thick mistake The crushed material of 500 mesh sieves, makees the broken auxiliary agent of rush when normal temperature elastic body fine crushing machine handles thick micelle；

The weight for promoting broken auxiliary agent described in thick micelle described in 11-1 and 11-2 is compared W by 11-3._{Thick micelle}/W_{Promote broken auxiliary agent}=100/25~40 Scope feeds intake mixing；

11-4. is to crossing at least more than 90% must the crossing 80 mesh sieves and have more than being equal to of gained after normal temperature elastic body fine crushing machine 70% parts by weight cross the thin rubber powder of 100 mesh sieves and promote the mixed material of broken auxiliary agent, implement classification, described classification is characterized in：

Material was at least divided into or only two parts of 120 mesh sieves by 11-4-a., cross 120 mesh sieves to be narrower than equal to 120 Purpose rubber powder and the mixture for promoting broken auxiliary agent, but 120 mesh sieves to be narrower than 60 mesh to being coarser than the rubber powder of 120 mesh and be enriched The mixture of the metal fines of sieve is not crossed；

11-4-b. or material is divided into 60 mesh sieves to only 120 mesh sieve, and crosses 120 mesh sieves to only 200 mesh sieve, mistake Three parts of 200 mesh sieves, the composition of this three part is respectively：Cross 60 mesh sieves to only 120 mesh sieves be corresponding mesh number scope glue The mixture of powder and the metal fines for being enriched not 120 mesh sieves, crosses 120 mesh sieves to the thin rubber powder of only 200 mesh sieves, mistake The broken auxiliary agent of rush of 200 mesh sieves and the thin rubber powder less than thick micelle throwing amount 5%；

Material was at least divided into or only two parts of 150 mesh sieves by 11-4-c., spent being equal to be narrower than for 150 mesh sieves The rubber powder of 150 mesh and the mixture for promoting broken auxiliary agent, but 150 mesh sieves is to be narrower than 60 mesh to the rubber powder and enrichment for being coarser than 150 mesh The mixture of the metal fines of sieve is not crossed；

11-4-d. or material is divided into 60 mesh sieves to only 150 mesh sieve, and crosses 150 mesh sieves to only 200 mesh sieve, mistake Three parts of 200 mesh sieves, the composition of this three part is respectively：Cross 60 mesh sieves to only 150 mesh sieves be corresponding mesh number scope glue The mixture of powder and the metal fines for being enriched not 150 mesh sieves, crosses 150 mesh sieves to the thin rubber powder of only 200 mesh sieves, mistake The broken auxiliary agent of rush of 200 mesh sieves and the thin rubber powder less than thick micelle throwing amount 5%；

11-4-e. or the demand according to market, by the mesh of mistake 60 described in 11-4-a, 11-4-b to the portion of only 120 mesh Point, re-grading was grain size grading rubber powder of 60 mesh to only any sieve mesh of 120 mesh sieve scopes, and before classification or/and after Remove the metal fines in rubber powder；It is mixed by the rubber powder of the mesh sieve of mistake 120 described in 11-4-a or 11-4-b or with the broken auxiliary agent of rush Compound, re-grading was grain size grading material of 120 mesh to only any sieve mesh of 200 mesh sieve scopes；Or by 11-4-c, 11- The mesh of mistake 60 described in 4-d is to the part of only 150 mesh, and re-grading was any sieve mesh of 60 mesh to only 150 mesh sieve scopes Grain size grading rubber powder, and the metal fines before classification or/and in rear removing rubber powder；By 11-4-c or, described in 11-4-d The mesh sieve of mistake 150 rubber powder or and promote the mixture of broken auxiliary agent, re-grading was any of 150 mesh to only 200 mesh sieve scopes The grain size grading material of sieve mesh；

11-5. to the mesh sieve of mistake 120 described in 11-4 to only 200 mesh sieves or crosses 150 mesh sieves to only 200 mesh sieves Thin rubber powder or and promote the mixture of broken auxiliary agent, implement further processing, specifically refer to as described below any or more plant Combination：

11-5-a. mixes softening agent or/and the disconnected sulphur modification agent of the single or compounding that add the known rubber of nonstaining property conventional, Described softening agent, disconnected sulphur modification agent, it is all known kind and known conventional amount used, to known softening agent, disconnected sulphur modification The selection verification mode of agent is：Meet described in embodiment 1-1；

11-5-b. to mixed described in 11-5-a plus the conventional single of known rubber of nonstaining property or the softening agent of compounding or/ Fine mixing at a high speed is applied again with the material after disconnected sulphur modification agent, obtains powder；Or rolled or/and extrusion process after roller, finally Obtain piece bits shape or graininess.

The present embodiment 11 is to use useless cross-ply or/and useless steel radial tyre B component, therefore when non-mistake in this example 120 mesh sieves so cross 150 mesh sieves B component of not falling in lines material, then what the component A that can be made to fall in lines was handled gets the raw materials ready.

B component obtained by the present embodiment, it pulls apart tensile strength in 12.00MPa to 16.00 scopes, that is, remains useless Cross-ply or/and useless steel radial tyre sizing material pull apart the 2/3 of tensile strength before being reproduced, and proportion is in 1.16 to 1.45 models Enclose, shore a hardness is in 75 to 85 scopes, and elongation is in 180% to 350% scope；Pure B component can not be extruded or extrude in flakes, By B components, 20 parts make an addition to background glue C, can form island, the heterogeneous sizing material of marine facies, and the abrasion of its vulcanizate are always significantly Less than on year-on-year basis in background glue C addition as embodiment 6,7,8 20 parts of component A or plus B component abrasion, its vulcanizate Folding resistance, which is always significantly worse than, to be added such as 20 parts of the component A of embodiment 6,7,8 in background glue C on year-on-year basis or does not add the resistance to of B component Folding endurance；Sizing material has defoaming；

The background glue C, its specific formula etc., it is the same as those described above.

B component of the present invention, can turn into independent commodity, or produce correlated product or raw material production as Endogenous Intermediate product during product.

The component A prepared described in Example 6 of the compound composition of embodiment 12.A/B components, and described in embodiment 11 B component, by A/B weight ratio, be made into 12-a to 12-i groups：

12-a：95/5,12-b：90/10,12-c：70/30,12-d：40/60,12-e：50/50,12-f：55/45,12- g：60/40,12-h：20/80,12-i：5/95；

By these groups of citing, it is pre-mixed by the part by weight, described hybrid mode includes stirring, rolling, squeezed Any or more the combination for planting operation gone out all can, what is be worth mentioning is only：Because A/B weight than difference and material when applying mixed The difference of compression and obtain in powdery, graininess, piece bits shape, cake powdery, micelle shape, glue sheet, adhesive tape shape it is any or more Form is planted, and is easy to store stand-by material；Such as 12-a is to 12-e groups, and hybrid mode is rolled including rolling or extruder is squeezed Go out, gained mixed material can in glue sheet, adhesive tape shape, micelle shape, beans shape it is any；And for example 12-f, 12-g group, are mixed Mode includes stirring or any or more combination for planting operation with rolling, extrusion, then gained mixed material can be in powdery, cake Powdery or to graininess, piece bits shape；And for example 12-h, 12-i group, hybrid mode includes stirring or/and rolling or/and extrusion, institute Any of shape can be considered to be worth doing in powdery, graininess, piece by obtaining mixed material.

The compound composition of A/B components of the present invention, can turn into independent commodity, or be used as the related system of Endogenous production Intermediate product when product or raw produce.

A groups described in the preparation method Example 6 of rubber and plastic compound composition of the embodiment 13. containing A or/and B component Part, and the B component described in embodiment 11, with the resin described in embodiment 1-10, i.e. polypropylene, polyethylene, polyvinyl chloride, third Alkene-ethylene copolymer, ethylene-octene copolymer, ethylene-vinyl acetate copolymer, allyl resin, epoxy resin, alkyl phenol Urea formaldehyde, polyurethane, any or more combination planted of amino resins, also including such as waste plastics lawn, waste plastics container, give up Any or more combination planted of plastic packaging film；By A or/and B component：Weight ratio=5~95 of resin: 95~5, i.e., The parts by weight summation of both or three are 100 parts, or with the modified additive of known routine dose together, in advance through 100 to Any temperature of 200 DEG C of scopes is implemented heat and sneaked out after journey, obtains the rubber and plastic compound composition containing A or/and B component；More specifically Say, dispensing can be grouped by following 13-a to 13-m：

13-a groups：By A or/and B component：0 part of 5 parts/B component of component A described in weight ratio=embodiment 6 of resin： 95 parts of polypropylene, the parts by weight summation of rubber and plastic compound composition is 100 parts；

13-b groups：By A or/and B component：5 parts/embodiment of component A 11 described in weight ratio=embodiment 6 of resin 5 parts of described B component：90 parts of polyethylene, the parts by weight summation of rubber and plastic compound composition is 100 parts；

13-c groups：By A or/and B component：15 parts/embodiment of component A 11 described in weight ratio=embodiment 6 of resin 5 parts of described B component：80 parts of polyethylene, the parts by weight summation of rubber and plastic compound composition is 100 parts；

13-d groups：By A or/and B component：25 parts/embodiment of component A 11 described in weight ratio=embodiment 6 of resin 10 parts of described B component：65 parts of polyethylene, the parts by weight summation of rubber and plastic compound composition is 100 parts；

13-e groups：By A or/and B component：35 parts/embodiment of component A 11 described in weight ratio=embodiment 6 of resin 35 parts of described B component：Polyvinyl chloride, propylene-ethylene copolymers, ethylene-octene copolymer, ethylene-vinyl acetate copolymer Any or more 30 parts of combination planted, the parts by weight summation of rubber and plastic compound composition is 100 parts；

13-f groups：By A or/and B component：55 parts/embodiment of component A 11 described in weight ratio=embodiment 6 of resin 25 parts of described B component：Allyl resin, epoxy resin, alkyl phenolic resin, polyurethane, any the 20 of amino resins Part, the parts by weight summation of rubber and plastic compound composition is 100 parts；

13-g groups：By A or/and B component：65 parts/embodiment of component A 11 described in weight ratio=embodiment 6 of resin 15 parts of described B component：20 parts of waste plastics lawn, the parts by weight summation of rubber and plastic compound composition is 100 parts；

13-h groups：By A or/and B component：65 parts/embodiment of component A 11 described in weight ratio=embodiment 6 of resin 30 parts of described B component：5 parts of waste plastics container particulate material, the parts by weight summation of rubber and plastic compound composition is 100 parts；

13-i groups：By A or/and B component：The institute of 85 parts/embodiment of component A 11 described in weight ratio=embodiment 6 of resin 10 parts of the B component stated：5 parts of waste plastics packaging film chip powder, the parts by weight summation of rubber and plastic compound composition is 100 parts；

13-j groups：By A or/and B component：0 part/embodiment of component A 11 described in weight ratio=embodiment 6 of resin 95 parts of described B component：5 parts of 1 to 1 batch mixing of polyethylene and waste plastics packaging film chip powder, the parts by weight of rubber and plastic compound composition Number summation is 100 parts；

13-k groups：By A or/and B component：5 parts/embodiment of component A 11 described in weight ratio=embodiment 6 of resin 5 parts of described B component：90 parts of polyethylene and 1 to 3 compound of waste plastics lawn, the parts by weight summation of rubber and plastic compound composition is 100 parts；

13-l groups：By A or/and B component：The weight ratio of resin is the 90 parts/embodiment of component A 11 described in embodiment 6 5 parts of described B component：Waste plastics lawn 3~5cm × 3~5 parts of 5cm blocks, the parts by weight summation of rubber and plastic compound composition is 100 parts；

13-m groups：By A or/and B component：The weight ratio of resin is the 0 part/embodiment of component A 11 described in embodiment 6 5 parts of described B component：Waste plastics lawn 3~5cm × 3~95 parts of 5cm blocks, the parts by weight summation of rubber and plastic compound composition is 100 parts.

Foregoing 13-a assembles material to 13-m components, or can implement in advance in the mixed material of heat again while matching somebody with somebody in above-mentioned these Known modified additive is added, these auxiliary agents include：

Preventing aging system used additives, such as N- rings ethyl-N '-diphenyl-para-phenylene diamine, 2 mercapto benzimidazole, peroxidating hexamethylene Ketone, one or more of combinations, conventional amount used scope：100 parts by weight rubber and plastic compound compositions are with 1~6 part；

Surface coupling agent, such as ethylene methacrylic base silane, anilinomethyl triethoxysilane, ethylene titanate, acrylic acid Any or more combination of ethylene oxidic ester, conventional amount used scope：100 parts by weight rubber and plastic compound compositions are with 2~10 parts；

The liquid polyisoprene rubber or liquid polybutadiene of compatibilization system auxiliary agent, such as molecular weight in 2000~5000 scopes Alkene rubber, one or more of combinations of maleic anhydride, conventional amount used scope：100 parts by weight rubber and plastic compound compositions are with 5~15 Part；

The one of plasticiser system used additives, such as dibutyl phthalate or dioctyl ester or cyclohexane dicarboxylic acid dinonyl The combination of kind or more, conventional amount used scope：100 parts by weight rubber and plastic compound compositions are with 3~8 parts；

Rubber vulcanization system used additives, conventional amount used scope：It is 100 parts by weight such as to press the component A in rubber and plastic compound composition Meter is：Sulphur (0.2~2.5 part), 2- benzothiazolyl mercaptans (0.4~1.0 part), tetramethylthiuram disulfide (0~0.5 Part), zinc oxide (2.0~5.0 parts), stearic acid (0.5~1.0 part).

Any temperature in advance through 100 to 200 DEG C of scopes implements heat and sneaks out journey, and it is mechanical optional that implementation heat used is mixed With known closed refining glue (modeling) machine, open refining glue (modeling) machine, extruder any or more combination planted.

It is noted that the rubber and plastic compound composition product containing A or/and B component of last gained, its formulation is with grain Shape, any or close formulation of piece bits shape are preferred, because extruder when these kind of formulation is relatively easy to subsequently do product enters Material.

It is of the present invention containing A or/and B rubber and plastic compound compositions, independent commodity can be turned into, or Endogenous is used as Produce intermediate product when correlated product or raw produce.

Preparation method described in the technical program of embodiment 14. it is used and combined equipment as shown in Figure 1, its feature at least exists In：It is related to the combined equipment of component A, including the dotted line 14-1 frames of accompanying drawing 1 or any or more with 14-2 to 14-6 dotted line frames Combination, it is specific as described in dotted line 14-7 frames in accompanying drawing 1 to be related to the combined equipment of B component, is related to the group of A/B component compound compositions Attach together for specific as described in dotted line 14-8 in accompanying drawing 1, be related to the combined equipment tool of the rubber and plastic compound composition containing A or/and B component Body is as described in dotted line 14-9 in accompanying drawing 1：

Shown in dotted line 14-1 frames in fig. 1, carrying normal temperature elastic body fine crushing machine and implementing to crossing fine crusher material After the combined machine I of selection by winnowing or/and sieve classification machinery, undertaking carried 60 mesh to any sieve of only 150 mesh sieve scopes The storage bin combined machine II of purpose grain size grading or the rubber powder grain material of mixing, or again with being provided with magnetic field or/and electric field Removing impurities operative combination machinery III phases be connected, II or with III after linking with dispensing operation mechanism thermoplastification be modified Combined machine IV；

Shown in dotted line 14-2 frames in fig. 1, the combined machine of metering packing component A is connected after IV described in 14-1 V；

Shown in dotted line 14-3 frames in fig. 1, set before I described in 14-1 by carry thick rubber powder storage bin VI-1, Scrap rubber thermal cracking carbon black storage bin VI-2 upper subsidiary engine combined machine VI；

Shown in dotted line 14-4 frames in fig. 1, combined machine VII is crushed in import and the scrap rubber of VI-1 described in 14-3 The thick micelle output end for being stripped of metal fillings be mutually connected, or/and VI-2 described in 14-3 import with cracking residue crusher The scrap rubber thermal cracking combined machine VIII of the group cracking slag crushed material output end VIII-1 phases for being stripped of metal fillings are connected；

Shown in dotted line 14-5 oval frames in fig. 1, combined machine II described in 14-1 or it is connected again with III phases, it is special Levy and be：Set between combined machine II discharging opening II-1 and combined machine III magnetic field or/and electric field removing impurities machinery III-1 Conveying machinery II → III is equipped with, described conveying machinery II → III at least includes belt conveyor, screw rod transmission, bucket chain type Conveying, any or more combination planted of air-flow conveying；

Shown in dotted line 14-6 oval frames in fig. 1, described in 14-1 II or with III after linking carry dispensing operation The thermoplastification modifying composition machinery IV of mechanism, it is characterised in that：Dispensing operation mechanism IV-1 in combined machine IV, with group Machinery II discharging opening II-1 is closed, or is provided between combined machine III storage bin IV-1 conveying machinery II → IV or III → IV, described conveying machinery II → IV or III → IV at least include belt conveyor, screw rod transmission, bucket chain type conveying, gas Any or more combination planted of stream conveying；

Shown in dotted line 14-7 frames in fig. 1, after combined machine I described in 14-1, undertaking carried 120 mesh to only The grain size grading of any sieve mesh of 200 mesh sieve scopes or the rubber powder grain material of mixing and are mixed with or separated scrap rubber cracking slag The storage bin combined machine IX of powder material, or and join again after IX with implement rubber powder modified metering married operation group Close machinery X, or and concatenation again to it is foregoing cross IX or and X each material combined machine XI for rolling of implementation, and IX or with X or/ With the combined machine V ' for being connected metering packing B component after XI；

Shown in dotted line 14-8 frames in fig. 1, in thermoplastification modifying composition machinery IV described in 14-1, with being stored up described in 14-7 Feed bin combined machine IX or with after X or/and XI, then sets metering married operation combined machine X ' or and implements the combination that rolls Mechanical XI ', then sets the combined machine V " for the metering packing for collecting A/B component compound compositions again；

It is Section 1 with thermoplastification modifying composition machinery IV described in 14-1 shown in dotted line 14-9 frames in fig. 1, and Storage bin combined machine IX described in 14-7 is Section 2 with X or/and XI, with first and second side by side, then sets Section 3： Store resin or the storage bin combined machine XII with modified additive, then after foregoing three arranged side by side, metering mixing is set The combined machine XI " that operative combination machinery X " or implementation are rolled, then sets the multiple group of rubber and plastic of the collection containing A or/and B component again The combined machine V ' of the metering packing of compound ".

Combined machine I described in the present embodiment includes purchased in market or/and homemade combined machine to XII.Used in the preparation method And combined equipment, can also turn into independent special-purpose machinery commodity.

Embodiment 15. provides a kind of utilization background sizing material C quality inspection by the new of the mechanical property of sample A or/and B component etc. Mode background sizing material C formula sets three variables, i.e., as described in preceding embodiment 1 in background glue C：Carbon black N330 is from 0 To 60 parts, 0 to 200 part of calcium carbonate, 0 to 15 part of machine oil, this is arranged at this three variables in background glue C, can make background sizing material The physical property curvilinear motion that C is presented in itself is：Because C primary elastomeric kind is to select butadiene-styrene rubber, it can be as carbon black N330 be from 0 To 60 parts of (transverse axis：Carbon black variable) add, its (longitudinal axis：Pull apart tensile strength values) can be edged up from 2MPa it is about not low to peak In 22MPa, i.e., walked out on axial plane in length and breadth one it is dull upwards and bending the rim of a bowl first upwards after curvilinear path under, and its Wear profile then can be in the axle (longitudinal axis in length and breadth：Wearing valve, transverse axis：Carbon black variable) that bending the rim of a bowl is walked out in plane is upwards and dull The curvilinear path of decline；When the carbon black N330 in background glue C to 60 parts of peak amount when, when adding calcium carbonate 0 again variable To 200 parts, the background glue C (longitudinal axis：Tensile strength is pulled apart, with transverse axis：Calcium carbonate variable) will walk out between axial plane in length and breadth from The value that peak is such as not less than 22MPa gradually decreases down 10MPa or the curvilinear path to lower monotonic decreasing, while background glue C Wear profile then can be in the axle (longitudinal axis in length and breadth：Wearing valve, transverse axis：Calcium carbonate variable) to walk out bending the rim of a bowl upwards and single for interplanar Adjust the track risen；When the carbon black in background glue C, calcium carbonate are respectively X, Y definite value, when add again variable machine oil 0 to 15 parts, background glue C, can be in the axle (longitudinal axis in length and breadth under its corresponding X parts of carbon black, the definite value of Y parts of calcium carbonate：Shao Er A hardness with Transverse axis：Machine oil variable) interplanar have one by high step-down parallel hardness curve group.

This three variables in background glue C are arranged at as previously described, and it is intended as the quality inspection to A or/and B：

A. added in background sizing material C it is quantitative by sample A or/and B implement quality inspection, be to eliminate single B component Can not be in flakes and on the basis of can not directly measuring B component important physical property drawback, then be superimposed can be by being arranged at the back of the body as previously described The excessive softening agent or/and carbon black that A or/and B are brought into the preparation are answered in the change of this three variables in scape glue C, amendment Or/and constitution filler；

B. the implementation enterprise of this programme from the change of this three variables in background glue C, can be made to select physical property most To approach its product kind, the C for making it only need to be selected with this_X、Y、ZBackground sizing material, fill into quantitative or variable by sample A or/ Implement quality inspection with B, so that it may know the quality good or not of its online product.

(table 1)

Next make to make the explanation of quality inspection A or/and B mechanical property using background sizing material C in conjunction with such as upper table 1：By sample A₁It is taken from 1 sample in embodiment 6, A₂It is taken from 1 sample in EXAMPLE Example 8, A₃It is taken from embodiment 2 1 sample；B₁It is taken from 1 sample in embodiment 9, B₂It is taken from 1 sample in embodiment 10, B₃It is taken from implementing 1 sample in example 11；Table 11,5,9,13, No. 17, be different 5 of this three variables in background glue C respectively Background sizing material C, will be mixed after background sizing material C, the comparison conclusion measured is by sample：

1st, exported by No. 1 standard specimen：A₁Pull apart tensile strength to be not less than 17MPa, B₃Pull apart tensile strength to be equal to or Slightly less than 17MPa；A₁Abrasion be worse than your abrasion 135mm of the slope of No. 1 standard specimen³/ 40m, B₃Abrasion be better than No. 1 standard specimen slope you Wear away 135mm³/ 40m,；A₁/B₃=50/50 tensile strength of pulling apart is 17MPa, and it wears away the slope that abrasion for being worse than No. 1 standard specimen 135mm ³/ 40m, and abrasion are worse than B₃, but it is better than A₁；

2nd, exported by No. 5 standard specimens：A₂Pull apart tensile strength to be not less than 12MPa, B₁Pull apart tensile strength to be equal to or Slightly less than 12MPa；A₂Abrasion be worse than your abrasion 145mm of the slope of No. 5 standard specimens³/ 40m, B₁Abrasion be better than No. 5 standard specimens slope you Wear away 145mm³/ 40m,；A₂/B₁=5/95 tensile strength of pulling apart is to be equal to or slightly less than 12MPa, and its abrasion is better than No. 5 standard specimens Slope you abrasion 145mm³/ 40m, and abrasion elementary errors is in B₁, but it is much better than A₂；

3rd, exported by No. 9 standard specimens：A₁Pull apart tensile strength be less than 22.2MPa, B₃Pull apart tensile strength be less than in 22.2MPa；A₁Abrasion be worse than your abrasion 130mm of the slope of No. 9 standard specimens³/ 40m, B₃Abrasion be better than your abrasion of the slope of No. 9 standard specimens 130mm³/ 40m,；A₁/B₃=50/50 tensile strength of pulling apart is that, less than 22.2MPa, it wears away the slope that slightly poorer to No. 9 standard specimens Wear away 130mm³/ 40m, and abrasion are worse than B₃, but it is much better than A₁；

4th, exported by No. 13 standard specimens：A₃Pull apart tensile strength to be not less than 4.2MPa, B₂Pull apart tensile strength be equal to In 4.2MPa；A₃Abrasion be worse than your abrasion 170mm of the slope of No. 13 standard specimens³/ 40m, B₂Abrasion be better than your mill of the slope of No. 13 standard specimens Consume 170mm³/ 40m,；A₃/B₂=95/5 tensile strength of pulling apart is that, equal to 4.2MPa, it wears away the slope that mill for being worse than No. 13 standard specimens Consume 170mm³/ 40m, and abrasion are worse than B₂, but it is slightly better than A₃；

5th, exported by No. 17 standard specimens：B₂Pull apart tensile strength be less than 10.0MPa；B₂Abrasion be better than No. 17 standard specimens Slope that abrasion 150mm³/ 40m,；A₂/B₂=95/5 tensile strength of pulling apart is that its abrasion is worse than No. 17 standard specimens less than 10.0MPa Slope you abrasion 150mm³/40m；

6th, it is other：Slickness of the knife section of test piece all with standard specimen is mutually equal.

Final sumbission：

A₁Pull apart tensile strength to be not less than 17MPa, A₂Pull apart tensile strength to be not less than 12MPa, A₃Pull apart drawing Intensity is stretched to be not less than 4.2MPa；

B₁Pull apart tensile strength to be equal to or slightly less than 12MPa, B₂Pull apart tensile strength be equal in 4.2MPa, B₃ Pull apart tensile strength to be equal to or slightly less than 17MPa；

Component A, it adds 20 parts of abrasion in the background sizing material C vulcanizates formed and is always significantly greater tnan on year-on-year basis in the back of the body Do not add component A in scape glue C or add the abrasion of 20 parts of B component；Such as A₁Abrasion be worse than your abrasion 135mm of the slope of No. 1 standard specimen³ / 40m, A₂Abrasion be worse than your abrasion 145mm of the slope of No. 5 standard specimens³/ 40m, A₃Abrasion be worse than your abrasion of the slope of No. 13 standard specimens 170mm ³/40m...；

B component, it adds 20 parts of abrasion in the background sizing material C vulcanizates formed, is always significantly less than and exists on year-on-year basis 20 parts of component A is added in background glue C or does not add the abrasion of B component；Such as B₁Abrasion be better than your abrasion 145mm of the slope of No. 5 standard specimens³ / 40m, B₂Abrasion be better than your abrasion 150mm of the slope of No. 17 standard specimens³/ 40m, B₃Abrasion be better than your abrasion of the slope of No. 1 standard specimen 135mm ³/ 40m ...；

The abrasion for filling the vulcanizate after B component, admixture B component in A incorporations C sizing material again always add C to grind less than previous A Consumption；

Compound composition of the A/B weight than >=50/50 can be rolled out sizing material in flakes, can not connect which overcome traditional pure rubber powder The defect of the prior art of piece, also overcomes the higher defect of traditional pure thermal reclamation rubber abrasion.

But it is noted that it is used in C as exemplified above and be comparatively fresh butadiene-styrene rubber, inventory time is longer in this way Afterwards, butadiene-styrene rubber also can be aging, thus cause itself and the tensile strength curve peak height degradation after carbon black N330 cooperations, But the situation of wear profile sinking is simultaneously also brought along, and the aging of these butadiene-styrene rubber changes, can't be to A, B component Detection forms the big influence of reverse property, shown in table 2 specific as follows：

No. 22 in table 2 contrast with No. 9 in table 1, and tensile strength 22.2MPa has been down to 16.9MPa, wears away from 130mm³/ 40m has been down to 81mm³/ 40m, but this has no effect on detection A₂Tensile strength of pulling apart be better than B₁And A₂Abrasion be higher than B₁Deng Conclusion, i.e., B component incorporation C, its wear away always be significantly less than on year-on-year basis in background glue C add same amount component A abrasion； This is with the listed detection data of table 1 to A₂、B₁Evaluation conclusion it is consistent；But in order to which quality detecting data can have preferably repeatability, this hair A person of good sense still advises, in the case where condition is permitted, as far as possible using not aged butadiene-styrene rubber.The present embodiment butadiene-styrene rubber is used Be 1502, if using being also feasible such as 1500 grade other trades mark because being one objective by the physical property of sample A, B etc. In the presence of its physical property substantially with background glue C is unrelated.

(table 2)

The application direction of the product provided by the present invention of embodiment 16., because of A of the present invention or/and B component, it is former Material principally falls into universal waste rubber product, therefore the A of gained or/and B component must be with universal new rubber with compatible well Conjunction property；, also can be with crossing that 5 mesh sieves are to the only grain size grading of 60 mesh sieves or mix in addition, A of the present invention or/and B component The thick micelle powder of rubber mutually mix elastomer material such as cement, yellow sand, stone concrete, this material formed after vulcanization First-class floor file rubber cushion etc. can be prepared；Material property of the present inventor based on A or/and B component is better than traditional thermal reclamation rubber Glue or/and normal temperature method rubber powder, its application can be along the application paths of traditional thermal reclamation rubber or/and normal temperature method rubber powder, in consumption Traditional regeneration matter rubber is substituted with it with the medium-to-high grade rubber or product of rubber and plastic field of universal new rubber more than 80%, with The feature of environmental protection and property/this ratio of downstream product and its preparation process are improved, so recommending：Can be by A of the present invention or/and B Component, is combined with any or more plant of natural rubber, butadiene-styrene rubber, butadiene rubber, isoprene rubber, neoprene, Or/and with cross 5 mesh sieves to the only grain size grading of 60 mesh sieves or the thick micelle powder of the rubber mixed, or with carbon black, white carbon, Calcium carbonate, any or more of clay plant combination, mix compounding and are smelt elastomeric compound；Or use in foregoing elastomeric compound, or/and embodiment 1 " compound composition of A/B components, mixed with A or/and the rubber compound composition or rubber and plastic compound composition of B component " addressed, enters one Prepared by step include automobile tire, tire tyre cushion, motorcycle, bicycle, electric car, the tire used in power car, sole, sebific duct, glue Band, rubber cushion, handle gum cover, bicycle pedal blob of viscose, bicycle pedal gum cover, automotive wheels rear mudguard, vehicle steering handle Hand, automobile chassis damping mat, foot pad in car, brake brake rubber block, tail-light bowl, filter press rubber filter plate frame, solid tyre, oxygen Steel cylinder foot pad, mine car are met and discussed with rubber, the shield line gum cover of ash bucket for building, electric drill dragging line, electric drill handle gum cover, rubber peculiar to vessel Any rubber or product of rubber and plastic of fender, bipeltate material etc..

The elastomeric compound containing A or/and B component described in the present embodiment, can turn into independent commodity, or be used as enterprise Intermediate product when interior production correlated product or raw produce.

Through being described in further detail for as above 1 to 16 embodiment, it can be appreciated that inventing the technical scheme Innovative point is：

1st, for product, the innovative point relative to prior art product at least includes any described in following 5 Or more item combination：

A. using will not rubber thermal cracking hot recycling, the environment-friendly type regeneration matter plasticized rubber component A obtained is and more reasonable Utilize the normal temperature or in small, broken bits, the ultra-fine efflorescence rubber B component of environment-friendly type and the regeneration matter of more high-quality obtained of freezing of resource；And profit With exist between A, B physical property interval can not whole process be stacked the characteristics of, the component of A, B two can be passed through to simple any weight when in use Amount compare and use or it is alone mix supplying rubber formula, make a variety of of this two component and use or alone material physical property set, energy The physical property set of more existing reclaimed rubber or/and fine glue powder, and a variety of physical property set required by downstream product are more close Or it is morely intersecting, so as to reach the purpose that regeneration matter rubber is used in downstream rubber formula and virgin material is used less；

B. with the environment-friendly type, its feature that can be measured is at least：A or/and B component 3~5g of sample is taken, on sample Under each one mylar of pad, then put it on vulcameter OR gate Buddhist nun's viscosity apparatus, be heated 10 minutes at 180 DEG C, taken out Sample, parks no less than 5 minutes, then takes the mylar above and below sample off and be stacked again, and move to fluorescent lamp at room temperature Lower observation, mylar will not be deeper than the 101C or 601C of international standard color (Pan PANTONE leads to) card by yellow colouration；Simultaneously When taking out by sample, any or more feature for planting combination of coal tar, pine tar, aromatic naphtha, pitch will not be also given out Stench, or the peculiar smell with other people that choke；The contaminative smog of dyeing described herein, is verified through the present inventor, include rubber by The miscellaneous hydro carbons smog gone out after high temperature by Partial digestion, or with coal tar, pine tar, aromatic naphtha, pitch any or more kind group Close sent smog, or and be difficult to determine specific composition by complicated groups such as the accelerator be formerly incorporated in rubber material Part once coagulate by high thermal cracking to be stored in after colloid again by during low-heat i.e. 180 DEG C and spilling is choked people's peculiar smell etc.；Limit product not Dyeability, this is current tasteless feature of environmental protection reclaimed rubber so-called at room temperature also all inaccessiable high temperature resistant index, under this is guarantee The ordinary temperature swum in refining glue, vulcanization is to be less than to be equal to the newly-increased easy detection of products innovation for also having the feature of environmental protection under the conditions of 180 DEG C Guarantee index；

C. it is by normal temperature or the freezing mesh of mistake 60 in small, broken bits or obtained with screening to only 150 mesh sieve scope with the component A Any sieve mesh grain size grading or the rubber powder of mixing, or through magnetic field or/and electric field remove metal impurities again, and without dirt Gained after the combination regeneration processing of thermoplastification process is contaminated, is times of butter shape, cake powdery, graininess, micelle shape, sheet, strip A kind of plastifying material of form；Or and plastified, its feature including Mooney viscosity (ML100 DEG C of 1+4) value be controlled in 15 to 95 scopes it is any；

D. with the B component, be by normal temperature it is in small, broken bits or and screening obtained 100 mesh to any sieve mesh of only 200 mesh sieves Grain size grading or mixing rubber powder, or be powder again obtained by blended, extruding any or more anabolic process planted Last shape, piece bits shape, the material of granular any form, it is by crossing 100 mesh to any sieve of only 200 mesh sieve scopes Purpose grain size grading or the rubber powder grain material of mixing, or it is particularly low-grade scrap rubber hot tearing with the scrap rubber for crossing 200 mesh sieves Solve the powder of slag, or and be mixed with nonstaining property the conventional single or compounding of known rubber softening agent or/and disconnected sulphur modification agent Mixture；

E. both with A, B, its is raw materials used to be derived from any or more identical or different group planted listed below Close：High-grade scrap rubber：A variety of automobile damaged tires and its decompose part, mine and planted with any or more of the conveyer belt abandoned etc. Combination；Low-grade scrap rubber：Tire damaged tire pad, the automobile-used tire abandoned such as motor, scrap rubber pipe, scrap rubber footwear, etc., and from abandoning In rubber it is broken apart go out containing rubber powder consider to be worth doing grain steel wire or/and chemical fibre frame material, fiber lining crumble, metal fillings grain Any or more combination planted.

Relative to prior art, the innovative point of product described in the technical program may also include the group of any or more item as follows Close：

F. to both A, B, all fastened entirely using four that implement green high level energy-saving in full to scrap rubber as previously described Obtained by formula combined method；It is described in full, it is intended that scrap rubber includes material and utilized by processing in full；The green, it is intended that useless rubber Glue and its processed each process of the nonrubber material included are all pollution-free；The high level, it is intended that the component of A, B two individually or Mutually mixed material has compared with known products increases the innovation of matter or/and drop originally；The energy-conservation, it is intended that in the hot method of piggybacking tradition again When raw rubber technique prepares component A, material is not heated to the temperature that rubber rapidly cracks out harmful cut, material not set Put the worry glue or/and refining treatment of highly energy-consuming, to low-grade scrap rubber material or/and from scrap rubber material it is broken apart go out Handled containing the accessory substance such as miscellaneous skeleton using the pyrolysis method of low power consuming, or and use thermal cracking when method in small, broken bits prepares B component Cracking slag crushed material obtained by method is made to promote broken auxiliary agent；The combined method, it is intended that by traditional hot recycling rubber method and rubber normal-temperature or Method in small, broken bits, pyrolysis method are freezed, series connection or/and parallel restructuring are implemented by foregoing four full buckle-type requirements；This is existing skill The blind area of art.

G. any proportion by A/B weight than 95/5 to 5/95 scope is pre-mixed, described hybrid mode include stirring, Any or more combination for planting operation of rolling, extrusion, then because A/B weight than it is different obtain in powdery, graininess, Piece bits shape, cake powdery, micelle shape, glue sheet, the stand-by material of any or more storage for planting combination form of adhesive tape shape；

H. the described component of A, B two, all from after elastomer normal temperature or freezing are in small, broken bits gained be no less than 90% Cross 60 mesh sieves and have more than the thin rubber powder and the mixture of broken this intermediate state of auxiliary agent of rush that 100 mesh sieves are crossed equal to 50% parts by weight Material；

The component of A, B two described herein, all setting from this intermediate state mixed material not only implies component A In follow-up removing impurities, without the worry glue or/and refining process for employing highly energy-consuming, and the magnetic field using low power consuming or/and electricity are only needed Field implements to remove to being sized be enriched with metal fillings therein, also implies component A swollen into the implementation thermosol that is heated When particle because thin, and it is interval (such as room temperature to 200 DEG C of scopes) to be difficult thermal cracking temperature in rubber in subsequent heat treatment, Conveniently realize and be fully swelled with high dose softening agent, this is the blind area of existing hot in-place recycling；And can obtain enough excellent again The particle diameter of matter 120 to 200 mesh scopes or more preferably 150 to 200 scopes classification or mix particle diameter ultra-fine rubber powder or and The B component of disintegration promoting agent powder mixture；Stack up is said, environmental protection hot recycling and preparation are used as using this intermediate state mixed material The bifurcated node process stream of the ultra-fine rubber powder of high level, this is a blind area in existing regeneration matter field of rubber technology.

I. by the component of A, B two, extension grafting to rubber compound composition and rubber and plastic compound composition field.

2. the more detailed description through as above 1 to 16 embodiment, is produced it can be appreciated that technical solution of the present invention is involved The preparation method of product A components, its relative to prior art innovative point at least that：

J. the quality of rubber materials of the component A, originates in the combination of scrap rubber described in embodiment 1-2, by normal temperature or freezing It is in small, broken bits, 60 mesh were obtained to the only grain size grading of any sieve mesh of 150 mesh sieve scopes or the rubber powder grain material of mixing, Thus the starting material that material is handled for implementation thermoplastification；Or with the starting material still by B component processed when by-product it is cheap Gained；

K. low power consuming removing impurities, i.e., to the foregoing starting materials of j, then set it to be operated by the removing impurities of magnetic field or/and electric field Journey, removes metal impurities therein, obtains the starting material of removing impurities, prior art has thus been broken away from because particle is excessively thick, wherein always Containing a large amount of metal fillings, the technique disadvantage for being still to implement filter glue or/and the highly energy-consuming process of refining after heat treatment is caused；

L. again through will not rubber thermal cracking hot recycling process, i.e. the starting material to the foregoing low power consuming removing impurities of k, then fill The known softening agent of the conventional odorless of rubber processing industry and nonstaining property, then applies the mesh of mistake 60 for having filled softening agent to not again The grain size grading of any sieve mesh of 150 mesh sieve scopes or the removing impurities rubber powder grain material of mixing are crossed, in the temperature of room temperature to 200 DEG C Degree scope is easily heat-treated to plastifying material, because rubber powder is far narrower than 24 to 30 mesh rubber powders of prior art, and is had and is far above The softening agent of current technology throwing amount, therefore plastics processing is without now as 250 DEG C or so can make the high temperature of rubber thermal cracking；

M., the environmentally friendly quality inspection Con trolling index implemented far above prior art is set, that is, the A groups of gained after plastics processing of learning from else's experience Part sample about 3~5g, in sample each one mylar of pad up and down, then puts it on vulcameter OR gate Buddhist nun's viscosity apparatus, It is heated 10 minutes at 180 DEG C, when taking out by sample, sample, which will not emerge, can make the contaminative cigarette of mylar Inner dyeing Mist；This is itself processing and the high-environmental requirement in downstream application process all odorlesses that ensure that regeneration matter rubber product.

3. the more detailed description through as above 1 to 16 embodiment, it can be appreciated that technical solution of the present invention is carried To the preparation method of product B component, it is relative to the innovative point of prior art：

N. the rubber powder material in material includes any or more combination planted of scrap rubber described in technical scheme 1-2, and adds In work the involved broken auxiliary agent of rush be include only having drawn from low-grade scrap rubber described in technical scheme 1-2 thermal cracking slag powder Mince；

O. to preparing grain size grading or the rubber powder of mixing of 100 mesh to only any sieve mesh of 200 mesh sieve scopes It is broken again without returning fine crusher to the thick rubber powder material for B component of not falling in lines during grain material, it need to only be conducted into and prepare going through for component A Journey, this had both made fine crusher because of the energy current stabilization without time coarse fodder, and the process for preparing A materials has been obtained the starting material of high-quality again, This creates the fine grain condition of beneficial starting material for innoxious preparation component A.

4. contained in technical solution of the present invention a kind of use vulcameter OR gate Buddhist nun's viscosity apparatus it is any come quality inspection A or/ With the B feature of environmental protection, and include using background sizing material C quality inspections A or/and B mechanics physical property new detection method.

5. the technical program especially contains the technical scheme for more preferably using combined method for half steel meridian damaged tire.

In a word, the more detailed description through as above 1 to 16 embodiment, it can be appreciated that the present invention is more known skill Art has made what more upper " in full, green, high level, the energy-conservation " more met resources such as scrap rubbers described in combined method was changed The technical scheme of four full buckle-type conception.

Technical concept of the present invention, technical scheme, branch of industry need according to itself, refer again to embodiment Embodiment narration, can choose needed for be combined implementations, without creative work, it becomes possible to obtain expected from technique effect.

Claims

1. a kind of regeneration matter rubber mixes its rubber or rubber and plastic compound composition product, the product, it can relate to " thin by freezing Broken machine is once or after crossing normal temperature elastic body fine crushing machine once, and gained at least more than 90% must cross 60 mesh sieves and have more than being equal to 50% parts by weight cross the thin rubber powder of 100 mesh sieves or and promote broken auxiliary agent " this intermediate state mixed material, then apply classification, it is pollution-free Component A, B component obtained by thermoplastification process, or/and A/B components compound composition, or/and mix A or/and B component rubber or Rubber and plastic compound composition, it is characterised in that：The feature of component A includes any or more to 1-3 or with 1-5,1-7 of following 1-1 and planted Combination, the feature of B component includes following 1-1 to 1-2 and 1-4 or any or more combination planted with 1-6,1-7, A/B groups The feature of part compound composition includes following 1-8, mixes A or/and the rubber compound composition of B component feature and includes following 1-9, mixes A Or/and the feature of the rubber and plastic compound composition of B component includes following 1-10：

Even 1. is distributed seldom by organic volatile during hyperpyrexia, described " few ", what it can easily be detected It is characterised by：Take A or/and B component 3~5g of sample, in sample each one mylar of pad up and down, then put its in vulcameter or On Mooney viscosity instrument, it is heated 10 minutes at 180 DEG C, takes out sample, park at room temperature no less than 5 minutes, then will examination Mylar above and below sample is taken off to be stacked again, and moves to observation under fluorescent lamp, and mylar will not be deeper than international mark by yellow colouration The 101C or 601C of quasi- color (Pan PANTONE leads to) card；

2. being heated 10 minutes at 180 DEG C described in 1., takes out sample, will not now give out conventional regeneration rubber The coal tar that is distributed, pine tar, aromatic naphtha, any or more feature stench for planting combination of pitch, or and the people that chokes peculiar smell；

1-2.A components or/and B component, the upstream source feature of its raw material include：The regeneration matter rubber or and useless being related in A, B Rubber thermal cracking ground-slag, which minces, raw materials used is derived from any or more identical or different high and low grade planted listed below The combination of scrap rubber：

High-grade scrap rubber：The automobile useless cross-ply abandoned, the automobile useless steel radial tyre abandoned, automobile uses useless half abandoned Steel radial tyre, the tube abandoned of automobile, turning, the buffings under polishing, rubber powder material during automobile tire retreading, mine is with abandoning Conveyer belt；

Low-grade scrap rubber：The automobile tire tyre cushion abandoned, the automobile-used tire abandoned of motorcycle, bicycle, electric car, power, scrap rubber Pipe, scrap rubber footwear, scrap leather footwear, waste tape, scrap rubber pad, the side crops of rubber, the sports ground plastic pad abandoned, cable waste line Skin, given up turning rubber covered rollers material, the workshop incipient scorch material of rubber, and colloid is given up gloves, from the rubber abandoned it is broken apart go out The steel wire or/and chemical fibre frame material, fiber lining crumble, metal fillings grain of considering grain to be worth doing containing rubber powder any or more combination planted；

1-3.A components physical property interval feature at least includes：

Its vulcanizate：Tensile strength is pulled apart to pull apart in 4.00MPa to 17.00 scopes or remain before waste rubber product is reproduced The 2/3 of tensile strength, proportion is in 1.16 to 1.40 scopes, and shore a hardness is in 45 to 70 scopes, and elongation is 300% to 500% Scope；Pure component A can be extruded or extruded in flakes, and component A is made an addition in background glue C, can form non-island, the homogeneous glue of marine facies Material, and the vulcanizate formed with background glue C, it wears away the B groups for being always significantly greater tnan and adding same amount in background glue C on year-on-year basis The abrasion of part；Component A is to sizing material without the froth breaking sexual function for being easy to venting quality；

The background glue C, its specific formula, at least includes：100 parts of butadiene-styrene rubber, 5 parts of zinc oxide, 1 part of stearic acid, sulphur 2 Part, 1.5 parts of accelerant CZ, 0.5 part of Vulcanization accelerator TMTD, 1 part of antioxidant MB, 0 to 60 part of carbon black N330,0 to 200 part of calcium carbonate, 0 to 15 part of machine oil；When adding component A, weight ratio=100/ of component A/sulphur/accelerant CZ/Vulcanization accelerator TMTD need to be pressed simultaneously 0.8/0.6/0.2 add, conditions of vulcanization is 155 DEG C/7 minutes；

1-4.B components physical property interval feature at least includes：

Its particle size range exists：100 mesh are crossed to the particle diameter mixing of only 200 mesh sieve scopes or are classified, the identifying way of particle diameter is used： 50 parts of B components of weight are added in 100 parts by weight background glue C with pressing (GB19208-2008-T)《Vulcanized rubber powder》Operation is obtained " cross 100 mesh to the particle diameter mixing of only 120 mesh sieve scopes or be classified " 45 parts of standard specimen weight, be made after vulcanizate and compare knife and cut The crude property of section, must both be narrower than standard specimen；

Its vulcanizate：Tensile strength is pulled apart to pull apart in 4.00MPa to 17.00 scopes or remain before waste rubber product is reproduced The 2/3 of tensile strength, proportion is in 1.20 to 1.8 scopes, and shore a hardness is in 70 to 85 scopes, and elongation is 180% to 350% Scope；Pure B component can not be extruded or extruded in flakes, and B component is made an addition into background glue C, can form island, the heterogeneous glue of marine facies Material, and the vulcanizate formed with background glue C, it wears away the A groups for being always significantly less than and adding same amount in background glue C on year-on-year basis The abrasion of part；B component has the froth breaking sexual function for being easy to venting quality to sizing material；

The background glue C, its specific formula, at least includes：100 parts of butadiene-styrene rubber, 5 parts of zinc oxide, 1 part of stearic acid, sulphur 2 Part, 1.5 parts of accelerant CZ, 0.5 part of Vulcanization accelerator TMTD, 1 part of antioxidant MB, 0 to 60 part of carbon black N330,0 to 200 part of calcium carbonate, 0 to 15 part of machine oil；When adding B component, weight ratio=100/ of B component/sulphur/accelerant CZ/Vulcanization accelerator TMTD need to be pressed simultaneously 0.8/0.6/0.2 add, conditions of vulcanization is 155 DEG C/7 minutes；

Component A described in 1-5., its feature is also including 3. and 4.：

3. be by " by freezing fine crusher once or after crossing normal temperature elastic body fine crushing machine once, gained must at least 90% with The upper mesh sieve of mistake 60 and have cross the thin rubber powder of 100 mesh sieves or and promote broken auxiliary agent more than being equal to 50% parts by weight " this intermediate state mixes Compound material, then apply classification, the grain size grading or the rubber of mixing of the mesh of mistake 60 obtained to only any sieve mesh of 150 mesh sieve scopes Powder, or through magnetic field or/and electric field remove metal impurities again, but through pollution-free, energy-conservation plasticizing and with stirring, extrusion, pelletizing, After any or more anabolic process processing for planting operation of roll-in, obtain butter shape, cake powdery, graininess, micelle shape, sheet, The plastifying material of any form of strip；Described " pollution-free plasticizing ", it is characterised in that the temperature control that material is heated System is in room temperature to 200 DEG C of intervals；Described " energy-conservation plasticizing ", it is characterised in that material is not set highly energy-consuming worry glue or/and Refining treatment；Described " promoting broken auxiliary agent " for it is low-grade described in 1-2 or with high-grade scrap rubber thermal cracking slag to the thick mesh of mistake 200 The powder of sieve；

4. and 3. described " plastifying material ", its Mooney viscosity (ML100 DEG C of 1+4) value are controlled in appointing for 15 to 95 scopes It is a kind of；

B component described in 1-6., be further characterized in that 5. or and 6.：

5. be by " by freezing fine crusher once or after crossing normal temperature elastic body fine crushing machine once, gained must at least 90% with The upper mesh sieve of mistake 60 and have cross the thin rubber powder of 100 mesh sieves or and promote broken auxiliary agent more than being equal to 50% parts by weight " this intermediate state mixes Compound material, then apply classification, obtained to being slightly 100 mesh to the carefully only grain size grading of any sieve mesh of 200 mesh sieve scopes Or the ultra-fine rubber powder of mixing；Described " promoting broken auxiliary agent " is low-grade or with high-grade scrap rubber thermal cracking slag described in 1-2 To the powder of the thick mesh sieve of mistake 200；

Softening agent or/and the disconnected sulphur modification agent of the conventional single of the blended known rubber for admixing nonstaining property or compounding again, Or and with applying extrusion, any or more anabolic process planted of roll-in, last gained for powdered, piece bits shape, granular The ultra-fine rubber powder mixture being modified of any form；

6. is only then the mixing through homogenization to 5. described " ultra-fine rubber powder ", or and with apply extrusion, roll-in any or More than the anabolic process planted, last gained for powdered, piece bits shape, the ultra-fine rubber powder thing of granular any form Material；

1-7. or with " the intermediate state mixed material " described in 1-5,1-6 and " mesh of mistake 60 obtained to only 150 mesh sieve scopes appoint The grain size grading of one sieve mesh or the rubber powder of mixing ", and " to being slightly 100 mesh to carefully only 200 mesh sieve scopes are appointed The grain size grading of one sieve mesh or the ultra-fine rubber powder of mixing ", its source includes：Make by oneself or/and purchased in market；

1-8. will as described in preceding 1-1 to 1-5 A, B, any proportion by A/B weight than 95/5 to 5/95 scope is pre-mixed, institute The hybrid mode stated includes stirring, rolling, any or more of extrusion and plants the combination operated, then because A/B weight than difference And obtain planting combination form in powdery, graininess, piece bits shape, cake powdery, micelle shape, glue sheet, any or more of adhesive tape shape The stand-by material of storage；

1-9. will as described in preceding 1-1 to 1-5 A, B, by A or/and B component: weight ratio=5~90 of general purpose rubber: 95~ The parts by weight summation of 10, i.e. both or three are 100 parts, or again with reinforcing agent, constitution filler, through mixing in advance, dehydration, heat After ripe, kneading any or more anabolic process of item, obtain mixing A or/and the rubber compound composition of B component；Described is general Type rubber, refers to that natural rubber, butadiene-styrene rubber, butadiene rubber, isoprene rubber, any or more of neoprene plant combination Or its emulsion or solution is any；Described reinforcing agent, refers to that carbon black, any or more of white carbon plant combination；It is described Constitution filler, refer to that calcium carbonate, any or more of clay plant combination；

Both 1-10. A, B as described in preceding 1-1 to 1-5, by A or/and B component: weight ratio=5~95 of resin: 95~5, i.e., Or the parts by weight summation of three be 100 parts, or with known modified additive, after sneaking out journey through heat in advance, obtain mixing A or/and B groups The rubber and plastic compound composition of part；Described resin is also well known materials, and it can include polypropylene, polyethylene, polyvinyl chloride, third Alkene-ethylene copolymer, ethylene-octene copolymer, ethylene-vinyl acetate copolymer, allyl resin, epoxy resin, alkyl phenol Urea formaldehyde, polyurethane, any or more combination planted of amino resins, also including such as waste plastics lawn, waste plastics container, useless mould Expect any or more combination planted of packaging film；Described known modified additive, including：Rubber vulcanization system used additives, such as sulphur Sulphur, 2- benzothiazolyl mercaptans, tetramethylthiuram disulfide, zinc oxide, stearic one or more of combination, and it is anti-old System used additives, such as N- rings ethyl-N '-diphenyl-para-phenylene diamine, 2 mercapto benzimidazole, cyclohexanone peroxide, one kind or Combination above；Surface coupling agent, such as ethylene methacrylic base silane, anilinomethyl triethoxysilane, ethylene titanate, propylene One or more of combinations of acid glycidyl ester；The liquid of compatibilization system used additives, such as molecular weight in 2000~5000 scopes Polyisoprene rubber or liquid polybutadiene rubber, maleic anhydride；Plasticiser system used additives, such as dibutyl phthalate Or one or more of combinations of dioctyl ester or cyclohexane dicarboxylic acid dinonyl；Described known modified additive, its consumption category Known normal dosage ranges；

As above 1-1 to 1-10 is addressed component A, B component, the compound composition of A/B components, the rubber for mixing A or/and B component are answered Composition, independent product can all be turned into by mixing A or/and B component rubber and plastic compound composition.

2. component A described in claim 1, wherein preferably the physical property of product is joined with its starting material and after the feature of technical process Array, which is closed, to be：

The feature of environmental protection that 2-1. obtains component A is at least conformed to described in claim 1-1；

4. described " Mooney viscosity (ML100 DEG C of 1+4) value " is controlled in 15 to 35 scopes any or 60 to 95 to 2-2.1-5 Scope it is any；

2-3. is to make by oneself or the mesh of mistake 100 purchased in market is to the only grain size grading of any sieve mesh of 150 mesh sieve scopes or the rubber of mixing Rubber powder grain, or it is used as the starting material for implementing thermoplastification processing behind magnetic field or/and electric field removing metal impurities again；

2-4. or during with plasticizing operation heated temperature of charge in room temperature to 150 DEG C of scopes, and with upper stirring, extrusion, pelletizing, After any or more anabolic process processing for planting operation of roll-in, obtain butter shape, cake powdery, graininess, micelle shape, sheet, Plastifying material --- the component A of any form of strip；

3. prepared by B component described in claim 1, wherein preferably the physical property of product originates mix and after technique mistake with it The characteristic parameter combination of journey is：

The feature of environmental protection that 3-1. obtains B component is at least conformed to described in claim 1-1；

3-2. is to make by oneself or the mesh of mistake 100 purchased in market or to crossing 150 mesh but only the rubber powder grain material of the mixing of 200 mesh sieve scopes For the starting mix of B component processed；

3-4. imposes the mixing of homogenization to " the starting mix of B component " described in 3-2,3-3 again, or and with applying extrusion, roll-in Any or more anabolic process planted, last gained for powdered, piece bits shape, the ultra-fine rubber of granular any form Rubber powder material --- B component.

4. component A, the preparation method of B component described in claim 1, it is characterised in that：All " pass through normal temperature elastic body fine crushing machine or freezing Fine crusher once, and excessively it is in small, broken bits cross machine after, just can obtain and cross 60 mesh sieves no less than 90% parts by weight and be more than equal to 50% with having Parts by weight cross the thin rubber powder of 100 mesh sieves or and as promoting broken auxiliary agent " mixed material of this intermediate state, then again through lock out operation And subsequent treatment separately win in butter shape, micelle shape, graininess, in flakes shape, in strip any form the A groups of plastifying material Part, and consider shape, granular B component to be worth doing in powder, piece；" component A ", times with following 4-5 to 4-6 or with 4-1 into 4-4 One or more plants the combination of feature, " B component ", is planted with following 4-5 and 4-7 or with any or more into 4-4 of 4-1 The combination of feature：

Its quality of rubber materials of 4-1. belongs to the combination of scrap rubber described in claim 1-2；

4-2. obtained any of 16 to 30 mesh hole scopes using known scrap rubber coarse crushing, crushing, magnetic separation, screening process The grain size grading of sieve mesh or the thick micelle of mixing；

" thick micelle " described in 4-3. to 4-2, then admix thereto to be slightly the low-grade of 200 mesh sieves or with high-grade scrap rubber The powder material of thermal cracking slag, " the thick micelle " had both promoted the charged material weight ratio of broken auxiliary agent with " powder of cracking slag " W_{Thick micelle}/W_{Promote broken auxiliary agent}=100/8~50；

4-4. or by " thick micelle " described in 4-2, imports freezing fine crusher；

4-5. to " cross freezing fine crusher after gained must at least more than 90% cross 60 mesh sieves and have more than be equal to 50% parts by weight mistake The thin rubber powder of 100 mesh sieves, or cross normal temperature elastic body fine crushing machine after gained must at least more than 90% cross 60 mesh sieves and have more than etc. The thin rubber powder of 100 mesh sieves is crossed in 50% parts by weight and promotees the mixed material of broken auxiliary agent ", implement classification, described classification, feature It is：

" thin rubber powder or and promote the mixed material of broken auxiliary agent " is divided into two parts by 4-5-a.：Both thick material：60 mesh sieves are crossed to only 100 mesh or the mixture-i to the only rubber powder of any mesh sieve of 150 mesh sieve scopes and the metal fines for being enriched not sieve； With thin material：Cross 100 mesh or the mixture-ii to the ultra-fine rubber powder for any mesh sieve for crossing 150 mesh sieve scopes or with the broken auxiliary agent of rush；

4-5-b. or " thin rubber powder or and promote the mixed material of broken auxiliary agent " is divided into three parts：Both thick material was：Cross 60 mesh sieves It is mixed to only 100 mesh or to the only rubber powder of any mesh sieve of 150 mesh sieve scopes and the metal fines for being enriched not sieve Compound-i；With thin material：Cross 100 mesh or to cross 150 mesh sieve scopes any mesh sieve, to only 200 mesh sieves ultra-fine rubber powder- iii；And thinner material：Cross the broken auxiliary agent of rush and the thin rubber powder-iv less than thick micelle throwing amount 5% of 200 mesh sieves；

4-5-c. or the demand according to market, by " i " part described in 4-5-a, 4-5-b, re-grading was 60 mesh to only Grain size grading rubber powder-the v of any sieve mesh of 150 mesh sieve scopes, and the metal fines before classification or/and in rear removing rubber powder；

Or the demand according to market, by " ii " described in 4-5-a, or " iii " described in 4-5-b, re-grading was 100 mesh Or to any mesh sieve for crossing 150 mesh sieve scopes, to the grain size grading material-vi of only any sieve mesh of 200 mesh sieve scopes；

4-6. is to described in " i " described in 4-5-a or 4-5-b and 4-5-c " v ", implementing subsequent treatment, separately winning in butter shape, glue Bulk, graininess, in flakes shape, in strip any form plastifying material component A, be specifically：

4-6-a. implements magnetic separation or/and electric field choosing, further removes metal therein thin to " i " described in 4-5-a or 4-5-b Bits, obtained 60 mesh sieves to only 100 mesh or to the rubber powder-vii of only any mesh sieve of 150 mesh sieve scopes；

4-6-b. is mixed plus known softening agent to " v " described in " vii " described in 4-6-a or/and 4-5-c, is the ratio between by weight W_{Vii or/and v}/W_{Known softening agent}=100/20~100 scope formulas feed intake, and obtain the starting mix of component A processed；

Described 4-6-d.4-6-b " softening agent ",：White oil, machine oil, vegetable oil, stearic acid, vaseline, wax, transformer oil, The combination that ancient marlon resin, terpene resin, modified rosin scope optional one or more is planted；

4-6-e. or and while with addition of softening agent, also add disconnected sulphur or/and desulfurization used additives, the auxiliary agent is known or city The function additive of purchase：

4-6-f. while as described in 4-5-c " heating " is applied, and with upper stirring, extrusion, pelletizing, roll-in it is any or more After the anabolic process processing for planting operation, any form of butter shape, cake powdery, graininess, micelle shape, sheet, strip is obtained Plastifying material --- component A；

4-7. implements follow-up to " ii " described in 4-5-a, or/and " iii " described in 4-5-b, or/and " vi " described in 4-5-c Processing, separately win in powdery, piece bits shape, granular any form B component, it is specific such as 4-7-a, 4-7-b or and 4-7-c：

4-7-b. applies heating-up temperature, described temperature is in room temperature to 60 DEG C of models to " the starting mix of B component " described in 4-7-a Any enclosed；

4-7-c. imposes the mixing of homogenization to " the starting mix of B component " described in 4-7-a again, or and with applying extrusion, roll-in Any or more anabolic process planted, last gained for powdered, piece bits shape, the ultra-fine rubber of granular any form Rubber powder material --- B component.

5. the preparation method of the compound composition of A/B components described in claim 1, its feature also includes：

By the component A described in claim 1, and the B component described in claim 1, by A/B weight than 95/5 to 5/95 scope Any proportion is pre-mixed, and described hybrid mode includes stirring, banburying, rolling, any or more of extrusion and plants the group operated Close, and note to heat during mixing；Because A/B weight than it is different obtain in powdery, graininess, piece bits shape, cake powdery, glue Bulk, glue sheet, the compound composition material of the stand-by A/B components of any or more storage for planting combination form of adhesive tape shape.

6. mixing the preparation method of A or/and the rubber compound composition of B component described in claim 1, its feature also includes：Will by right Seek A, B described in 1,2,3,4, by A or/and B component: weight ratio=5~90 of general purpose rubber: 95~10, i.e., both or three The parts by weight summation of person is 100 parts, or again with reinforcing agent, constitution filler, through mixing in advance, dehydration, ripe, kneading any of heat Or more after the anabolic process of item, obtain mixing A or/and the rubber compound composition of B component；Described general purpose rubber, refers to day Right rubber, butadiene-styrene rubber, butadiene rubber, isoprene rubber, neoprene it is any or more plant combination or its emulsion or Solution it is any；Described reinforcing agent, refers to that carbon black, any or more of white carbon plant combination；Described constitution filler, be Refer to calcium carbonate, any or more of clay and plant combination.

7. A or/and the rubber and plastic compound composition of B component are mixed described in claim 1, it is characterised in that：By the institute of claim 1,2,3,4 " A ", " B " stated, by A or/and B component: weight ratio=5~95 of resin: the parts by weight of 95~5, i.e. both or three Summation be 100 parts, or with known modified additive, after sneaking out journey through heat in advance, obtain mixing A or/and the rubber and plastic of B component combined again Thing, described heat, i.e. any temperature of the heated material temperature of its material in 100 to 200 DEG C of scopes；Described is mixed, including stirring, Any or more combination for planting operation of rolling, extrusion, because of A or/and B component: weight resin than difference, and it is in powder to obtain Shape, graininess, piece bits shape, cake powdery, micelle shape, glue sheet, adhesive tape shape any or more storage for planting combination form it is stand-by Rubber and plastic compound composition material.

8. prepare product described in claim 1 it is used and combined equipment, its feature at least that：It is related to the combination of component A Equipment, including following 8-1 or any or more combination with 8-2 to 8-6,8-10, the combined equipment for being related to B component are specific such as Described in lower 8-7, be related to A/B component compound compositions combined equipment 8-8 specific as follows or with described in 8-10, be related to containing A or/and B The combined equipment 8-9 specific as follows of the rubber and plastic compound composition of component or with described in 8-10：

8-1. is carrying normal temperature elastic body fine crushing machine and is implementing the combination of selection by winnowing or/and sieve classification machinery to crossing fine crusher material After mechanical I, undertaking carried 60 mesh to the only grain size grading of any sieve mesh of 150 mesh sieve scopes or the rubber powder of mixing The storage bin combined machine II of material, or be connected again with being provided with the removing impurities operative combination machinery III phases in magnetic field or/and electric field, II or with III after linking with dispensing operation mechanism thermoplastification modifying composition machinery IV；

8-4. is exported in the thick micelle for being stripped of metal fillings that the import of VI-1 described in 8-3 crushes combined machine VII with scrap rubber End is mutually connected, or/and the import in VI-2 described in 8-3 and the scrap rubber thermal cracking combined machine VIII with cracking residue crusher group The cracking slag crushed material output end VIII-1 phases for being stripped of metal fillings be connected；

Combined machine II described in 8-5.8-1 is connected with III phases again, it is characterised in that：In combined machine II discharging opening II-1 Conveying machinery II → III, described conveyer are provided between combined machine III magnetic field or/and electric field removing impurities machinery III-1 Tool II → III at least includes belt conveyor, screw rod transmission, bucket chain type conveying, any or more combination planted of air-flow conveying；

Described in 8-6.8-1 II or with III after linking with dispensing operation mechanism thermoplastification modifying composition machinery IV, its spy Levy and be：Dispensing operation mechanism IV-1 in combined machine IV, the discharging opening II-1 with combined machine II, or and combined machine Conveying machinery II → IV or III → IV, described conveying machinery II → IV or III → IV are provided between III storage bin IV-1 At least include belt conveyor, screw rod transmission, bucket chain type conveying, any or more combination planted of air-flow conveying；

After combined machine I described in 8-7.8-1, undertaking carried 100 mesh to the particle diameter of only any sieve mesh of 200 mesh sieve scopes The rubber powder grain material of classification or mixing or and be mixed with or separate the storage bin combined machine IX of scrap rubber cracking slag powder material, Or and join again after IX with implement rubber powder modified metering married operation combined machine X, or and concatenation again to it is foregoing cross IX Or implement the combined machine XI that rolls with X each material, and IX or with X or/and XI after be connected the group of metering packing B component Close machinery V '；

8-8. in thermoplastification modifying composition machinery IV described in 8-1, with storage bin combined machine IX described in 8-7 or with X or/and XI it Afterwards, then set metering married operation combined machine X ' or and implement the combined machine XI ' that rolls, then collection A/B groups are set again The combined machine V " of the metering packing of part compound composition；

8-9. and thermoplastification modifying composition machinery IV described in 8-1 are Section 1, and storage bin combined machine IX described in 8-7 or and X Or/and XI is Section 2, with first and second side by side, then Section 3 is set：Collection puts resin or the storage bin group with modified additive Close machinery XII, then after foregoing three arranged side by side, the combination machine for setting metering married operation combined machine X " or implementation to roll Tool XI ", then sets the combined machine V " ' for the metering packing for collecting the rubber and plastic compound composition containing A or/and B component again；

9. in product described in claim 1, include the quality detecting method to A or/and B, it is characterised in that：It is related to 9- as described below 1 or/and 9-2：

The 9-1. quality inspection feature of environmental protection is, using any of vulcameter OR gate Buddhist nun's viscosity apparatus, to make to A or/and B and select raw material Contaminated by the heating measuring equipment of sample, and by the coloured the volatile matter whether dacron membrane of sample institute pad is overflowed by being heated Color, by sample whether have the qualitative index of contaminative used again 101C that international standard color (Pan PANTONE lead to) blocks or 601C；The temperature and time suffered by sample is defined again, is used as additional quantitative target within such as 180 DEG C × 10 minutes；

9-2. quality inspection mechanics physical property is to use the background glue C as described in claim 1-3,1-4.

10. the application of product described in claim 1, it is characterised in that：It is and natural by the A or/and B component described in claim 1 Rubber, butadiene-styrene rubber, butadiene rubber, isoprene rubber, any or more of neoprene plant combination, or/and with crossing 5 mesh sieves To the only grain size grading of 60 mesh sieves or the thick micelle powder of the rubber of mixing, or with carbon black, white carbon, calcium carbonate, clay appoint One or more plants combination, the elastomeric compound that blending refining is matched somebody with somebody；

Or use foregoing elastomeric compound, the or/and " compound composition of A/B components, mixed with A or/and the rubber of B component described in claim 1 Glue compound composition or rubber and plastic compound composition ", further preparing includes automobile tire, tire tyre cushion, motorcycle, bicycle, electronic Tire used in car, power car, sole, sebific duct, adhesive tape, rubber cushion, handle gum cover, bicycle pedal blob of viscose, bicycle pedal gum cover, Automotive wheels rear mudguard, vehicle steering handle, automobile chassis foot pad, brake brake rubber block, tail-light bowl, filter press rubber filter plate Frame, solid tyre, oxygen bottle foot pad, mine car are met and discussed with rubber, shield line gum cover, the electric drill handle of ash bucket for building, electric drill dragging line Hand gum cover, marine rubber fender, any rubber or product of rubber and plastic of bipeltate material.