CN1823705B - Makeup composition - Google Patents
Makeup composition Download PDFInfo
- Publication number
- CN1823705B CN1823705B CN2005101320099A CN200510132009A CN1823705B CN 1823705 B CN1823705 B CN 1823705B CN 2005101320099 A CN2005101320099 A CN 2005101320099A CN 200510132009 A CN200510132009 A CN 200510132009A CN 1823705 B CN1823705 B CN 1823705B
- Authority
- CN
- China
- Prior art keywords
- methyl
- ester
- acid
- wax
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 26
- 239000000839 emulsion Substances 0.000 claims abstract description 38
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000011347 resin Substances 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims abstract description 13
- 239000007787 solid Substances 0.000 claims abstract description 9
- 239000002537 cosmetic Substances 0.000 claims description 47
- -1 (methyl) glycidyl Chemical group 0.000 claims description 46
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 28
- 239000000194 fatty acid Substances 0.000 claims description 28
- 229930195729 fatty acid Natural products 0.000 claims description 28
- 229910052799 carbon Inorganic materials 0.000 claims description 26
- 150000001721 carbon Chemical group 0.000 claims description 18
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 17
- 150000004665 fatty acids Chemical class 0.000 claims description 16
- 239000000178 monomer Substances 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 15
- 229920001577 copolymer Polymers 0.000 claims description 13
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 12
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 11
- 239000004164 Wax ester Substances 0.000 claims description 11
- 235000019386 wax ester Nutrition 0.000 claims description 11
- 239000004204 candelilla wax Substances 0.000 claims description 10
- 235000013868 candelilla wax Nutrition 0.000 claims description 10
- 229940073532 candelilla wax Drugs 0.000 claims description 10
- 239000004203 carnauba wax Substances 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 10
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 claims description 10
- 239000001993 wax Substances 0.000 claims description 10
- 229920000800 acrylic rubber Polymers 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- 239000000470 constituent Substances 0.000 claims description 8
- 238000006116 polymerization reaction Methods 0.000 claims description 8
- 239000004170 rice bran wax Substances 0.000 claims description 8
- 235000019384 rice bran wax Nutrition 0.000 claims description 8
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 7
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 7
- 229940119170 jojoba wax Drugs 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- 241000238631 Hexapoda Species 0.000 claims description 6
- 150000001735 carboxylic acids Chemical class 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical class C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
- 239000007766 cera flava Substances 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- QTKPMCIBUROOGY-UHFFFAOYSA-N 2,2,2-trifluoroethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)F QTKPMCIBUROOGY-UHFFFAOYSA-N 0.000 claims description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims description 2
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 claims description 2
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 claims description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical class COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 2
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 239000001530 fumaric acid Substances 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 2
- LDHQCZJRKDOVOX-IHWYPQMZSA-N isocrotonic acid Chemical compound C\C=C/C(O)=O LDHQCZJRKDOVOX-IHWYPQMZSA-N 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 2
- AUCNMQYOQYTGPE-UHFFFAOYSA-N n-(hydroxymethyl)-n-methylprop-2-enamide Chemical compound OCN(C)C(=O)C=C AUCNMQYOQYTGPE-UHFFFAOYSA-N 0.000 claims description 2
- YPHQUSNPXDGUHL-UHFFFAOYSA-N n-methylprop-2-enamide Chemical compound CNC(=O)C=C YPHQUSNPXDGUHL-UHFFFAOYSA-N 0.000 claims description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 229920005573 silicon-containing polymer Polymers 0.000 claims description 2
- 239000012177 spermaceti Substances 0.000 claims description 2
- 229940084106 spermaceti Drugs 0.000 claims description 2
- 150000003440 styrenes Chemical class 0.000 claims description 2
- 125000004417 unsaturated alkyl group Chemical group 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 36
- 210000000720 eyelash Anatomy 0.000 abstract description 30
- 150000003839 salts Chemical group 0.000 abstract description 9
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 230000005923 long-lasting effect Effects 0.000 abstract 1
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 18
- 239000000835 fiber Substances 0.000 description 12
- 239000000843 powder Substances 0.000 description 10
- 238000007670 refining Methods 0.000 description 10
- 229940058015 1,3-butylene glycol Drugs 0.000 description 9
- 235000019437 butane-1,3-diol Nutrition 0.000 description 9
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 9
- 235000002639 sodium chloride Nutrition 0.000 description 9
- 239000000126 substance Substances 0.000 description 8
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- BSLCSFCXSUCFQN-UHFFFAOYSA-N 1-aminobutane-2,3-diol Chemical compound CC(O)C(O)CN BSLCSFCXSUCFQN-UHFFFAOYSA-N 0.000 description 5
- 235000021355 Stearic acid Nutrition 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 5
- 230000002045 lasting effect Effects 0.000 description 5
- 239000010445 mica Substances 0.000 description 5
- 229910052618 mica group Inorganic materials 0.000 description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 239000008117 stearic acid Substances 0.000 description 5
- 239000010936 titanium Substances 0.000 description 5
- 229910052719 titanium Inorganic materials 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 229930006000 Sucrose Natural products 0.000 description 4
- 150000001335 aliphatic alkanes Chemical class 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 230000001877 deodorizing effect Effects 0.000 description 4
- 210000004709 eyebrow Anatomy 0.000 description 4
- 230000002209 hydrophobic effect Effects 0.000 description 4
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 4
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 4
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 4
- 229960002216 methylparaben Drugs 0.000 description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 239000004014 plasticizer Substances 0.000 description 4
- 239000003505 polymerization initiator Substances 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- 239000005720 sucrose Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 description 3
- 101150035093 AMPD gene Proteins 0.000 description 3
- 235000021357 Behenic acid Nutrition 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 3
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical class CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 238000006386 neutralization reaction Methods 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 3
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 description 3
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- KVNYFPKFSJIPBJ-UHFFFAOYSA-N 1,2-diethylbenzene Chemical compound CCC1=CC=CC=C1CC KVNYFPKFSJIPBJ-UHFFFAOYSA-N 0.000 description 2
- KZVBBTZJMSWGTK-UHFFFAOYSA-N 1-[2-(2-butoxyethoxy)ethoxy]butane Chemical compound CCCCOCCOCCOCCCC KZVBBTZJMSWGTK-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 description 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- ODKSFYDXXFIFQN-BYPYZUCNSA-N L-arginine Chemical compound OC(=O)[C@@H](N)CCCN=C(N)N ODKSFYDXXFIFQN-BYPYZUCNSA-N 0.000 description 2
- 229930064664 L-arginine Natural products 0.000 description 2
- 235000014852 L-arginine Nutrition 0.000 description 2
- 239000004166 Lanolin Substances 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 235000001014 amino acid Nutrition 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 235000019388 lanolin Nutrition 0.000 description 2
- 229940039717 lanolin Drugs 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000004200 microcrystalline wax Substances 0.000 description 2
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920001515 polyalkylene glycol Polymers 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000008439 repair process Effects 0.000 description 2
- 210000002374 sebum Anatomy 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 238000004017 vitrification Methods 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- 238000004078 waterproofing Methods 0.000 description 2
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- SPTHWAJJMLCAQF-UHFFFAOYSA-N 1,2-di(propan-2-yl)benzene;hydrogen peroxide Chemical compound OO.CC(C)C1=CC=CC=C1C(C)C SPTHWAJJMLCAQF-UHFFFAOYSA-N 0.000 description 1
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 1
- FRPZMMHWLSIFAZ-UHFFFAOYSA-N 10-undecenoic acid Chemical compound OC(=O)CCCCCCCCC=C FRPZMMHWLSIFAZ-UHFFFAOYSA-N 0.000 description 1
- RSVZYSKAPMBSMY-UHFFFAOYSA-N 2,2,3,3-tetrafluoropropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)C(F)F RSVZYSKAPMBSMY-UHFFFAOYSA-N 0.000 description 1
- VXQBJTKSVGFQOL-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethyl acetate Chemical compound CCCCOCCOCCOC(C)=O VXQBJTKSVGFQOL-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Cosmetics (AREA)
Abstract
An oil-in-water makeup composition containing (A) from 1 to 40% by weight of a component selected from the group consisting of a carboxylic acid having from 23 to 100 carbon atoms, a salt form thereof, and mixtures thereof, (B) from 1 to 30% by weight on a solid basis of a resin emulsion, and (C) from 30 to 98% by weight of water. The makeup composition, when used as a mascara for eyelashes, causes good and long-lasting curling-up effect and volumizing effect on individual eyelashes.
Description
Technical field
The present invention relates to a kind of makeup (makeup) and use cosmetic, particularly be used to repair the shape of eyelashes, eyebrow etc., highlight the makeup composition of features.
Background technology
Cosmetic is generally used for beautifying the outward appearance of human body.Particularly the purpose of cosmetic such as mascara is, repairs a mao shape by applying one by one eyelashes or eyebrow, highlights the existence sense of features.In the case, just require its dressing effect can be lasting.
Usually, this class cosmetic is formed centrally in hard fat, tunicle formation agent, pigment etc. being, but for showing good usability, the performance functional characteristic as cosmetic, all the time, people have the cooperation of the raw material of various character in research.For example, attempted fatty acids such as cooperation Palmic acid, stearic acid,, strengthened dressing effects such as volume sticks up, enrichment to improve tack to eyelashes; And for making dressing effect lasting, also attempted the cooperation tunicle and form agent, with the typing of long-term maintenance eyelashes.
Up to now, for making has excellent dressing effect and the good mascara of usability, the chain length that adopts alkyl chain is 12～22 fatty acid ester and fatty acid soaps more.For example, in the TOHKEMY 2000-119140 communique, just disclosed and with the eyelashes cosmetic of specific sucrose fatty acid ester and fatty acid soaps; And in TOHKEMY 2003-128522 communique, then disclosed the keratin fibre coating compositions that contains polyglyceryl fatty acid ester and fatty acid soaps.According to these inventions, can obtain serviceability, easily the property used is good repeatedly, the decoration uniformity after the coating might as well, and can further improve the goods of dense sense.
In addition, in TOHKEMY 2004-10496 communique, disclosed a kind of eyelashes cosmetic, its oil-in-water type eyelashes by will containing solid-state oil content, higher fatty acid salt and water is used with cosmetic and higher alcohol and cyclopolysiloxane and acrylic acid alkyl amide-acrylate copolymer, can improve serviceability and decorate sense, suppress the reduction of life-time service performance.
Summary of the invention
The present invention relates to a kind of oil-in-water type makeup composition, it is characterized in that, contain:
(A) but carboxylic acid 1～40 weight % of the salifiable total carbon atom number 23～100 of part shape wherein;
(B) converting with solid constituent, is the resin emulsion of 1～30 weight %; And
(C) water 30～98 weight %.
The specific embodiment
Described in the prior art when being used for eyelashes when cooperating with the fatty acid of the alkyl chain length 12～22 of cosmetic, the friction of tear, sebum etc. and moment, pressure etc. will destroy this and film, or be dissolved in water or the sebum, and be difficult to the long-term good dressing effect that keeps.In order to make dressing effect lasting, adopt when having increased tunicle and forming the cooperation of agent, will make the eyelashes can not separation of synechia during coating, can't obtain the eyelashes of beautiful moulding.
The present invention relates to a kind of makeup composition, it can give good curling effect, dense effects such as eyelashes, and eyelashes adhesion when avoiding applying forming beautiful moulding, and makes this dressing effect lasting.
Makeup composition of the present invention contain (A) but the carboxylic acid of wherein the salifiable total carbon atom number 23～100 of part shape.Particularly, be preferably the carboxylic acid with following general formula (I) structure, wherein the part carboxylic acid also can form salt.
R
nCOOH (I)
At this, R
nSaturated or unsaturated alkyl for the carbon number 22～99 that can contain hydroxyl.Work as R
nCarbon number 22 when above, can improve the cosmetic persistency, and carbon number is having superiority aspect fusing point, the viscosity 99 when following.According to above-mentioned viewpoint, R
nCarbon number further preferably more than 23, and higher limit is preferably below 70, particularly preferably in below 60.
And R
nBe preferably the saturated hydrocarbyl of straight or branched, especially consider ornamental and the water proofing property aspect, be preferably the straight chain saturation alkane base, being preferably especially on the poly end group has carboxyl.And (A) component preferably has 80～120 ℃ fusing point.
As mentioned above, (A) part in the carboxylic acid of component can form salt, and for improving usability, the degree of neutralization of this carboxylic acid is preferably 0～90 mole of %, more preferably 0.1～50 mole of %, more preferably 0.1～30 mole of %.
Equilibrium ion when the carboxylic acid of total carbon atom number 23～100 is formed salt does not have special restriction, can enumerate alkali metal such as sodium, potassium, organic amines such as monoethanolamine, diethanolamine, triethanolamine, aminomethyl propanol, aminomethyl propylene glycol, Tris, morpholine also have basic amino acid such as L-arginine etc. in addition.Wherein, preferred organic amine, preferred especially aminomethyl propanol, aminomethyl propylene glycol.They can be used as nertralizer and add in the cosmetic of the present invention, and can select suitable use level according to carboxylic acid content in the makeup cosmetic and degree of neutralization, usually, its cooperation scope in cosmetic is preferably 0.01～10 weight %, more preferably 0.1～5 weight %.In addition, during carboxylic acid outside containing aftermentioned (A) component, they have the effect of this part carboxylic acid of neutralization.
The commercially available product that contains the carboxylic acid of (A) total carbon atom number 23～100 has, contain " Performacid 350ACID " (NEW FAITH TECHNOLOGY company), " SYNCROWAXAW1-C " (CRODA company) of straight-chain carboxylic acid etc., or contain straight-chain carboxylic acid and branched carboxylic acids " YOFCO lanolin fatty acid HH " (Nippon Seika K.K.) etc.
Consider usability and cosmetic persistency, (A) content range of component in the cosmetic total amount is preferably 1～40 weight %, and more preferably scope is 1.5～20 weight %, and special preferable range is 2.5～10 weight %.
And used (B) resin emulsion of the present invention can be the emulsion that polymer dispersed is formed in the dispersant based on water, is preferably especially in the presence of plasticizer or coalescents, the emulsion that is formed by the monomer polymerization with polymerizable double bond.Consider the flexibility of film, the vitrification point of this resin emulsion (Tg) is preferably-30～55 ℃, more preferably-20 ℃～45 ℃.
Monomer with polymerizable double bond both can be a hydrophilic monomer, also can be hydrophobic monomer.Can enumerate vinyl unsaturated carboxylic acids such as acrylic acid, methacrylic acid, itaconic acid, maleic acid, fumaric acid .beta.-methylacrylic acid as hydrophilic monomer; The vinyl monomer of hydroxyls such as (methyl) 2-(Acryloyloxy)ethanol, (methyl) glycidyl acrylate, two (methyl) acrylic acid glycol ester, poly-single (methyl) acrylic acid glycol ester; Vinyl amide such as (methyl) acrylamide, N-methylol (methyl) acrylamide, N-N-[2-(2-methyl-4-oxopentyl); (methyl) acrylic-amino ethyl ester, (methyl) acrylic acid N, N-dimethylamino ethyl ester, (methyl) acrylic acid N, N-diethylamino ethyl ester, (methyl) ethylacrylic acid N, N, vinyl amine such as N-trimethyl amino ester or its salt etc.
In addition, hydrophobic monomer can be enumerated aromatic series mono-vinyl and divinyl compounds such as styrene, α-Jia Jibenyixi, chlorostyrene, ring-alkylated styrenes, divinylbenzene; (methyl) acrylate of (methyl) acrylic acid methyl ester., (methyl) ethyl acrylate, (methyl) propyl acrylate, (methyl) butyl acrylate, (methyl) acrylic acid-2-ethyl caproite, (methyl) tert-butyl acrylate, (methyl) cyclohexyl acrylate etc.; Vinyl cyanide such as acrylonitrile, methacrylonitrile based compound; Vinyl acetate such as vinyl acetate; Ethylene halide such as vinyl chloride, vinylidene chloride based compound; Trifluoroethyl methacrylate, methacrylic acid-2,2,3,3-tetrafluoro propyl ester, methacrylic acid-2,2,3,3,4, fluorine such as 4-hexafluoro butyl ester, methacrylic acid perfluor monooctyl ester are monomer; The macromonomer of silicon etc.In addition, (methyl) propylene in this description means propylene or metering system.
These monomers both can only use a kind, also can be used in combination, the combination of hydrophilic monomer 0～15 weight %, hydrophobic monomer 85～100 weight % is more preferably used in the preferred combination of using hydrophilic monomer 0～30 weight %, hydrophobic monomer 70～100 weight %.
In cosmetic of the present invention, can use (methyl) alkyl acrylate polymer emulsion, (methyl) alkyl acrylate copolymer emulsion, (methyl) acrylic acid (methyl) alkyl acrylate copolymer emulsion, (methyl) alkyl acrylate styrol copolymer emulsion, vinyl acetate polymer emulsion, the copolymer emulsion that contains vinyl acetate, vinyl pyrrolidone styrol copolymer emulsion as one sees fit, contain silicone polymer emulsion etc.Specifically can enumerate YODOSOL GH34 (Japanese Niigata Seimitsu Co., Ltd., solid constituent: 45～47 weight %, Tg:-16 ℃), YODOSOL GH810 (Japanese Niigata Seimitsu Co., Ltd., solid constituent: 45～47 weight %, Tg:20 ℃), (big east changes into industrial society to DAITOSOL 5000AD, solid constituent: 48～52 weight %, Tg:-14 ℃), JURYMERET-416 (polyalkyl acrylate emulsion, Japanese pure medicine society, solid constituent: 56～58 weight %, Tg:0 ℃), JURYMERET-410 (alkyl acrylate copolymer emulsion, Japanese pure medicine company, solid constituent: 28.5～31.5 weight %, Tg:44 ℃) etc.
Be used to modulate the plasticizer of resin emulsion of the present invention or the concrete example of coalescents can be enumerated: cellosolve classes such as cellosolve, methyl cellosolve, butyl cellosolve; Carbitol classes such as carbitol, methyl carbitol, ethyl carbitol, BC, dibutyl carbitol (DBC); Carbonates such as ethylene carbonate, propylene carbonate; Acetate esters such as cellosolve acetate, butyl cellosolve acetate, butyl carbitol acetate, sucrose acetate; Alcohols such as hexanol, benzylalcohol, phenethanol; Glycolss such as hexanediol, ethylene glycol, propylene glycol; Esters such as phthalic acid two esters, di adipate class, succinic diester class, dibutoxyethyl sebacate class, rosin acid esters, caprylate, alkyl caproate, acetas, heptanoate, myristinate, citrate; Benzoates such as sucrose benzoate; Diethylbenzene etc.
According to aspects such as polymerization stability, storage stability and the water proofing property of filming, durability, with respect to the above-mentioned monomer of 100 weight portions, the addition of plasticizer or coalescents is preferably 1～50 weight portion, more preferably 5～30 weight portions.Plasticizer or coalescents both can add before polymerization begins in the system in advance, also can add in polymerization process.
The present invention is not particularly limited used polymerization initiator, for example can use cumene hydroperoxide, di-isopropylbenzene hydroperoxide, hydrogen peroxide to hydroperoxide type such as terpanes, the organic polymer initiator of azo-compound such as peroxide such as benzoyl peroxide, lauroyl peroxide and azodiisobutyronitrile and so on; Reach the inorganic polymerization initiator of persulfates such as potassium peroxydisulfate, sodium peroxydisulfate, Ammonium persulfate. and so on etc.And, also Reducing agents such as sodium sulfite, ascorbic acid and salt thereof and polymerization initiator can be used in combination, that is, also can use the oxidation-reduction system polymerization initiator.
And, when carrying out above-mentioned polymerization,, can add anionic, cationic or nonionic surfactant for making stably dispersing.In addition, also can add the chain transfer reaction agent.
The polymerization that is used to modulate the resin emulsifying agent can adopt known methods such as for example emulsion polymerisation, polymerisation in solution, polymerisation in bulk, precipitation polymerization, emulsifier-free emulsion polymerization to carry out.And the weight average molecular weight of the resin emulsion of polymerization gained is preferably below 200,000, more preferably 10,000～100,000.
These resin emulsions can contain a kind of, also can be mixed with two or more.When being mixed with when two or more the two or more polymer that vitrification point also capable of being combined is different.These resin emulsions form base as tunicle and convert with the solid constituent in the cosmetic integral body, and the content in cosmetic of the present invention is 1～30 weight %.And consider that tunicle forms ability and clean-up performance, its scope is 2～20 weight % more preferably.
Cosmetic of the present invention is the oil-in-water emulsion system makeup composition that contains (C) water 30～98 weight %.(C) component is the residue except that above-mentioned (A) component, (B) component, aftermentioned (D) component and other component, when the content of water during at 30～98 weight %, has the advantage of may command dried coating film speed.According to above-mentioned viewpoint, the upper limit of water content is preferably 70 weight %, more preferably 60 weight %.
Except that (A) component, (B) component with (C) the component, in cosmetic of the present invention, also can contain the wax ester of (D) total carbon atom number 24～100.Wax ester is the ester of the total carbon atom number 24～100 of higher fatty acids and/or hydroxyl carboxylic acid and high alcohol generation.It is meant be solid-state under 25 ℃, particularly fusing point is at the wax ester more than 50 ℃.In the present invention, preferably in 12～50 scope, the carbon number of higher alcohol is preferably in 12～50 scope for the carbon number of higher fatty acids.Owing to contain this wax ester, therefore can give effects such as good curling effect such as eyelashes, dense effect.In addition, consider the hardness of filming, more preferably the total carbon atom number of (B) wax ester is in 30～70 scope.
(D) wax ester of total carbon atom number 24～100 specifically can use Brazil wax, rice bran wax, jojoba wax (jojoba wax) (comprising abundant hydrogenant Jojoba oil), candelilla wax etc. to derive from the wax of plant; Spermaceti, Cera Flava, insect wax etc. derive from the wax of animal.
Consider curling effect and dense effect, (D) component is 1～40 weight % with respect to the content of cosmetic total amount, considers usability, is preferably the scope of 2～30 weight %, more preferably the scope of 2.5～20 weight %.
In cosmetic of the present invention, can also contain the saturated or unsaturated carboxylic acid of (E) total carbon atom number 10～22, the salt that partly or entirely obtains in this carboxylic acid that perhaps neutralizes.Particularly, can contain carboxylic acid and salt thereof such as lauric acid, myristic acid, Palmic acid, stearic acid, mountain Yu acid, oleic acid, 9-undecylenic acid, isostearic acid, linoleic acid, linolenic acid, eicosapentaenoic acid, docosahexenoic acid, fatty acid distribution of coconut oil, palm oil fatty acid, tallow fatty acids.Have level and smooth ornamentally for making to film, preferably contain (E) component of 0.1～20 weight %, more preferably content is 2～15 weight %.
And, when except that (A) component, also contain carbon number below 22 carboxylic acid or during its salt, consider cosmetic persistency and the flexibility of filming, (A) carboxylic acid of component (b) is preferably more than 0.21 with respect to all carboxylic acids in the makeup composition (comprising the salifiable part of shape) weight ratio (b)/(a) (a), more preferably 0.25～1.0, be preferably 0.5～0.9 especially.
In addition, consider the stability of cosmetic, above-mentioned (D) component (c) and all carboxylic acids (comprising the salifiable part of shape) ratio (c)/(a) that contains (a) are preferably 2～20, and more preferably 3～5.
In addition, for regulating hardness of film, also can contain in the cosmetic of the present invention and be solid-state hydrocarbon ils under 25 ℃.Specifically can enumerate microwax, paraffin, Tissuemat E, organosilicon wax, ceresin etc., its content in makeup composition is preferably 0.5～20 weight %, more preferably 0.8～10 weight %.
As required, cosmetic of the present invention also can use emulsifying agents such as surfactant.Be to form the emulsified state of oil-in-water type, can enumerate the nonionic surfactant that is generally used in the cosmetic, anionic surfactant, cationic surface active agent, amphoteric surfactant etc. as surfactant.
Wherein, consider and constitute relation between other composition of cosmetic, in the present invention, be preferably nonionic surfactant.Specifically can enumerate alkylene glycol adduct that for example fatty acid glyceride, polyglyceryl fatty acid ester, methyl glycol fatty acid ester, sorbitan fatty acid ester and alkylene glycol adduct thereof, Sorbitol fatty acid ester and alkylene glycol adduct thereof, polyalkylene glycol fatty acid, sucrose fatty acid ester, polyoxyalkylene alkyl, glycerol alkyl ether, polyoxyethylene solidify Oleum Ricini, lanoline, polyoxyalkylene alkyl modified synergic siloxanes etc.Wherein, be preferably polyalkylene glycol fatty acid, sucrose fatty acid ester, polyoxyalkylene alkyl, polyoxyethylene curing Oleum Ricini.The content range of these surfactants is preferably 0.5～10 weight %, more preferably 1～5 weight %.
In cosmetic of the present invention, except that above-mentioned each component, also can contain the composition that is generally used in the cosmetic, for example the powder body composition.Can enumerate inorganic particles such as Prussian blue, ultramarine, iron oxide red, ferrum oxide, titanium oxide, zinc oxide, silicon dioxide, carbon black, magnesium silicate, Magnesiumaluminumsilicate, Muscovitum, synthetic mica, synthetic sericite, sericite, Talcum, Kaolin, carborundum, barium sulfate, bentonite, Montmorillonitum as the powder body composition; Flash of light such as mica titanium, ferrum oxide mica titanium, aluminium powder powder body; The pigment powder body such as lake of organic tar series pigments, organic pigment; Particulate titanium dioxide coats mica titanium, particulate oxide zinc coats composite granules such as mica titanium, barium sulfate coating mica titanium etc.
Product after the surface treatments such as that above-mentioned various powder body can use is saponified by silicone, higher fatty acids, higher alcohol, fatty acid ester, metal, aminoacid, alkylphosphonate, or in be wrapped in goods in the organic or inorganic microcapsule.In addition, when various powder body are contained in the oil phase,, preferably powder surface are carried out hydrophobization and handle, be preferably silicone-treated and acrylic silicone-treated especially for improving the stability that dispersibility and high temperature are preserved.
Above-mentioned various powder body both can be used alone, and also can be used in combination.
And, in cosmetic of the present invention, can also contain oil preparationes such as higher alcohol, water soluble polymer, alcohols, polyalcohols, medicament, hydrocarbon ils, silicone oil; Thickening agent; UV absorbent; The ultraviolet scattering diluent; Wetting agent; Spice; Antioxidant etc.And when this cosmetic is used as mascara,, also can contain fiber for improving fine long (long lash) effect of eyelashes.
State fiber as this and can use natural fibers such as Cotton Gossypii, silk, fiber crops, or regenerated fiber such as artificial silk, or in the synthetic fibers such as polyamide, polyester, acrylic resin, polyolefin etc. any, from the intensity aspect, be preferably polyamide such as nylon.And, as required, also can use and pass through the surface-treated fiber.For example, for improving the dispersibility in oil phase, can use surface-treated fibers such as having passed through silica-treated, silicone-treated, fluoride processing, the saponified processing of metal, oils and fats processing.In addition, consider the tack to eyelashes, it is that (T: the gram number of every 1000m), length is the fiber of 0.1～5mm to 1.0～25.0T that this fiber is preferably cross-sectional diameter.For obtaining fine long-acting fruit fully, according to the cosmetic total amount, the content of this fiber is preferably 0.1～6 weight %.
In addition, but the total content of other adding ingredients such as above-mentioned powder body, fiber is fit to be selected in the scope of 1～50 weight % with respect to common cosmetic total amount.
Cosmetic of the present invention can and stir and modulate according to conventional methods with above-mentioned each composition uniform mixing.
The goods that it is 100～2000Pa.s that cosmetic of the present invention is preferably 25 ℃ of following viscosity of temperature.In the time of in cosmetic viscosity is in above-mentioned scope,, but also be easy to make not only to the good and good decorative property of tack of eyelashes.More preferably viscosity is 150～1000Pas.
When cosmetic of the present invention is used for eyelashes etc., can make each root eyelashes all be played up very beautifully, give its good curling effect and dense effect, and coating the time can not cause the eyelashes adhesion, form beautiful moulding, and can keep this dressing effect for a long time.
Cosmetic of the present invention is preferred for the makeup of eyelashes, particularly, is the cosmetic that is suitable for use as mascara, also is applicable to the makeup of eyebrow, as the color cream of eyebrow.And, not only can be used as the cosmetic that contains coloring pigment, also can be used as so-called eyelashes end cream or top layer nursing agent (top coat).
Embodiment
Embodiment 1～4, comparative example 1,2
Modulation eyelashes cosmetic as shown in table 1.The content and the evaluation result of this cosmetic (1)～(31) composition are shown in table 1.
When modulation, shown in the table 1 in the raw material, heating oils and carboxylic acid make it dissolving under temperature more than 90 ℃, it is added in the mixed aqueous solution of the nertralizer, emulsifying agent, water soluble polymer, 1,3 butylene glycol, antiseptic (methyl parahydroxybenzoate) and the coloring agent (iron oxide black) that are heated to more than 85 ℃.With homomixer it is carried out dispersion treatment, be cooled to room temperature while stir.After the cooling, add resin emulsion, ethanol etc., modulation obtains the eyelashes cosmetic.
Evaluation methodology: cosmetic is filled in the container, optionally it is coated on the eyelashes by 10 experts.Estimate the ornamental of product by the expert, adopt a little according to following standard.The meansigma methods of adopting a result according to 10 people is estimated.Assessment item has:
(1) eyelashes adhesion difficulty or ease; (2) the dressing effect persistency that volume sticks up, enrichment effect and (3) comparison instant according to eyelashes coating back and the dressing effect after 3 hours draws.
5 points: very good
4 points: good
3 points: general
2 points: poor
1 point: non-constant
Table 1
[notes]
(
*1) Performacid 350ACID:(NEW FAITH TECHNOLOGY company) (carboxylic acid 53% that contains total carbon atom number 23～100)
(
*2) YOFCO lanolin fatty acid HH:(contains the carboxylic acid 91% of total carbon atom number 23～100)
(
*3) SUNCROWAX AW1-C:(contains the carboxylic acid 13.5% of total carbon atom number 23～100)
(
*4) alkyl acrylate copolymer emulsion (46% aqueous solution): " YODOSOLGH34 " Japanese Niigata Seimitsu Co., Ltd.)
(
*5) ethyl acrylate butyl acrylate 1-Octyl acrylate copolymer emulsion (50% aqueous solution): " DAITOSOL " (Daito Kasei Kogyo Co., Ltd)
(
*6) Brazil wax: " deodorizing and refining Brazil wax NO.1 " (the wild field of Cerarica Co., Ltd.)
(
*7) Cera Flava: " BEES WAX-s " (Croda Japan Co., Ltd.)
(
*8) candelilla wax: " refining candelilla wax SR-2 " (Croda Japan Co., Ltd.)
(
*9) hydrogenated jojoba oil: " fully hydrogenated jojoba oil " (the capable Co., Ltd. of fragrant Rong Xing)
(
*10) rice bran wax: " rice bran wax F-1 " (the wild field of Cerarica Co., Ltd.)
(
*11) insect wax: " refining insect wax NO1 " (the wild field of Cerarica Co., Ltd.)
(
*12) paraffin: " HNP-9 " (Japanese fine wax Co., Ltd.)
(
*13) microwax: " Multi-wax W445 " (CKWITCO CORPORATION)
(
*14) two polyethylene tetramethylsilane oxygen alkane: " ESE-10 " (Kao Corp)
(
*15) behenyl alcohol: " KALCOL 220-80 " (Kao Corp)
(
*16) mountain Yu acid: New Japan Chem Co., Ltd
(
*17) stearic acid: " LUNAC S-98 " (Kao Corp)
(
*18) Palmic acid: " LUNAC P-95 " (Kao Corp)
(
*19) aminomethyl propanol: " AMP-100 " (ANGUS Chemical Company)
(
*20) aminomethyl propylene glycol: " AMPD " (ANGUS Chemical Company)
(
*21) L-arginine: Ajincomoto Co., Inc
(
*22) polyoxyethylene (7) cetyl ether: " EMULGEN 210P " (Kao Corp)
(
*23) polyvinyl alcohol: " GOHSENOL EG-5 " (The Nippon Synthetic Chemical Industry Co., Ltd)
(
*24) (the copolymer of vinyl pyrrolidone/VA): " PVP/VA S-630 " (ISPJAPAN)
(
*25) (eicosylene/vinyl pyrrolidone) copolymer: " ANTSRON V-220F " (ISP JAPAN)
(
*26) iron oxide black: " PABLACK BL-100 " (three change into Industrial Co., Ltd well)
(
*27) 1,3 butylene glycol: " 1,3 butylene glycol P " (Kyowa Yuka Co., Ltd)
Embodiment 5
Use following compositions to make mascara.
(weight %)
(1) Performacid 350ACID:(NEW FAITH TECHNOLOGY company) (carboxylic acid 53% that contains 7.0 total carbon atom numbers 23～100)
(2) alkyl acrylate copolymer emulsion (DAITOSOL, big east changes into industrial strain formula and understands 10.0 societies)
(3) Brazil wax (deodorizing and refining Brazil wax NO.1, the wild field of Cerarica Co., Ltd.) 1.5
(4) candelilla wax (refining candelilla wax SR-2, Croda Japan Co., Ltd.) 1.5
(5) insect wax (refining insect wax NO1, the wild field of Cerarica Co., Ltd.) 3.0
(6) paraffin (HNP-9, Japanese fine wax Co., Ltd.) 5.0
(7) two polyethylene tetramethylsilane oxygen alkane (ESE-10, Kao Corp) 5.0
(8) behenic acids (New Japan Chem Co., Ltd) 3.0
(9) aminomethyl propanol (AMP-100, ANGUS Chemical Company) 1.0
(10) aminomethyl propylene glycol (AMPD, ANGUS Chemical Company) 0.5
(11) vinyl pyrrolidone/VA copolymer (PVP/VA S-630, ISP JAPAN) 5.0
(12) 1,3 butylene glycol (1,3 butylene glycol P, Kyowa Yuka Co., Ltd) 2.0
(13) ethanol 3.0
(14) methyl parahydroxybenzoate 0.15
(15) propyl p-hydroxybenzoate 0.05
(16) phenyl phenol 0.4
(17) iron oxide black (PA BLACK BL-100, three change into Industrial Co., Ltd well) 5.0
(18) pure water surplus
According to the result who estimates with the described same method of embodiment 1 be: the persistency of good curling effect, enrichment effect, dressing effect is all very excellent.
Embodiment 6
Use following compositions to make mascara.
(weight %)
(1) Performacid 350ACID:(NEW FAITH TECHNOLOGY company) (carboxylic acid 53% that contains 5.0 total carbon atom numbers 23～100)
(2) alkyl acrylate copolymer emulsion (DAITOSOL, big east changes into industrial strain formula and understands 15.0 societies)
(3) Brazil wax (deodorizing and refining Brazil wax NO.1, the wild field of Cerarica Co., Ltd.) 3.0
(4) candelilla wax (refining candelilla wax SR-2, Croda Japan Co., Ltd.) 1.5
(5) abundant hydrogenated jojoba oil (the capable Co., Ltd. of fragrant Rong Xing) 4.0
(6) rice bran wax (rice bran wax F-1, the wild field of Cerarica Co., Ltd.) 3.0
(7) spermol (spermol NX, higher alcohol Industrial Co., Ltd) 1.2
(8) stearyl alcohol (stearyl alcohol NX, higher alcohol Industrial Co., Ltd) 0.8
(9) behenic acids (New Japan Chem Co., Ltd) 1.0
(10) stearic acid (LUNAC S-98, Kao Corp) 2.0
(11) aminomethyl propanol (AMP-100, ANGUS Chemical Company) 1.0
(12) aminomethyl propylene glycol " AMPD ", (ANGUS Chemical Company) 0.5
(13) vinyl pyrrolidone/VA copolymer (PVP/VA S-630, (ISP JAPAN)) 2.0
(14) 1,3 butylene glycol (1,3 butylene glycol P, Kyowa Yuka Co., Ltd) 3.0
(15) methyl parahydroxybenzoate 0.15
(16) propyl p-hydroxybenzoate 0.05
(17) phenyl phenol 0.4
(18) iron oxide black (PA BLACK BL-100, three change into Industrial Co., Ltd well) 5.0
(19) pure water surplus
According to the result who estimates with the described same method of embodiment 1 be: the persistency with good curling effect, enrichment effect and dressing effect is also very excellent.
Embodiment 7
Use following compositions to make mascara.In addition, the carboxylic acid of the total carbon atom number in the mascara 23～100 (b) is 0.33 with respect to the weight ratio (b)/(a) of all carboxylic acids (a).
(weight %)
(1) Performacid 350ACID:(NEW FAITH TECHNOLOGY company) (carboxylic acid 53% that contains 6.0 total carbon atom numbers 23～100)
(2) alkyl acrylate copolymer emulsion (YODOSOL GH34, Japanese NSC strain formula 15.0 commercial firms, 46% aqueous solution)
(3) Brazil wax (deodorizing and refining Brazil wax NO.1, the wild field of Cerarica Co., Ltd.) 3.5
(4) candelilla wax (refining candelilla wax SR-2, Croda Japan Co., Ltd.) 1.5
(5) rice bran wax (rice bran wax F-1, the wild field of Cerarica Co., Ltd.) 3.5
(6) two polyethylene tetramethylsilane oxygen alkane (ESE-10, Kao Corp) 2.0
(7) spermol (spermol NX, higher alcohol Industrial Co., Ltd) 2.0
(8) behenic acids (New Japan Chem Co., Ltd) 1.5
(9) stearic acid (LUNAC S-98, Kao Corp) 2.0
(10) aminomethyl propanol (AMP-100, ANGUS Chemical Company) 1.0
(11) vinyl pyrrolidone/VA copolymer (PVP/VA S-630, ISP JAPAN) 2.0
(12) 1,3 butylene glycol (1,3 butylene glycol P, Kyowa Yuka Co., Ltd) 3.0
(13) ethanol 1.0
(14) methyl parahydroxybenzoate 0.15
(15) propyl p-hydroxybenzoate 0.05
(16) phenyl phenol 0.5
(17) iron oxide black (PA BLACK BL-100, three change into Industrial Co., Ltd well) 5.0
(18) pure water surplus
According to the result who estimates with the described same method of embodiment 1 be: have good curling effect, enrichment effect, and the persistency of dressing effect is also very excellent.
Utilizability on the industry
Cosmetic of the present invention in particular as the eyelashes mascara, can be given the good curling effect of eyelashes and dense effect, and can make this dressing effect lasting.
Claims (4)
1. an oil-in-water type makeup composition is characterized in that, contains:
(A) but salifiable carboxylic acid 1～40 weight % of part shape wherein with following general formula (I) structure,
R
nCOOH (I)
In described general formula (I), R
nBe the saturated or unsaturated alkyl of the carbon number 22～60 that can contain hydroxyl,
Described carboxylic acid is the carboxylic acid that has the saturated hydrocarbyl of straight or branched and have carboxyl on poly end group;
(B) be scaled the resin emulsion of 1～30 weight % with solid constituent,
Described resin emulsion is formed by the monomer polymerization with polymerizable double bond,
Described monomer with polymerizable double bond is selected from: acrylic acid, methacrylic acid, the itaconic acid, maleic acid, fumaric acid, .beta.-methylacrylic acid, (methyl) 2-(Acryloyloxy)ethanol, (methyl) glycidyl acrylate, two (methyl) acrylic acid glycol ester, poly-single (methyl) acrylic acid glycol ester, (methyl) acrylamide, N-methylol (methyl) acrylamide, the N-N-[2-(2-methyl-4-oxopentyl), (methyl) acrylic-amino ethyl ester, (methyl) acrylic acid N, the N-dimethylamino ethyl ester, (methyl) acrylic acid N, N-diethylamino ethyl ester, styrene, α-Jia Jibenyixi, chlorostyrene, ring-alkylated styrenes, divinylbenzene, (methyl) acrylic acid methyl ester., (methyl) ethyl acrylate, (methyl) propyl acrylate, (methyl) butyl acrylate, (methyl) 2-EHA, (methyl) tert-butyl acrylate, (methyl) cyclohexyl acrylate, acrylonitrile, methacrylonitrile, vinyl acetate, vinyl chloride, vinylidene chloride, trifluoroethyl methacrylate, methacrylic acid 2,2,3,3-tetrafluoro propyl ester, methacrylic acid 2,2,3,3,4,4-hexafluoro butyl ester, methacrylic acid perfluor monooctyl ester, acrylic acid perfluor monooctyl ester, the macromonomer of silicon
Described resin emulsion is selected from (methyl) alkyl acrylate polymer emulsion, (methyl) alkyl acrylate copolymer emulsion, (methyl) acrylic acid (methyl) alkyl acrylate copolymer emulsion, (methyl) alkyl acrylate styrol copolymer emulsion, vinyl acetate polymer emulsion, the copolymer emulsion that contains vinyl acetate, vinyl pyrrolidone styrol copolymer emulsion, contains silicone polymer emulsion; And
(C) water 30～98 weight %.
2. oil-in-water type makeup composition as claimed in claim 1 is characterized in that, also contains wax ester 1～40 weight % of (D) total carbon atom number 24～100,
Described wax ester is the wax ester of the total carbon atom number 24～100 that generates of higher fatty acids and/or hydroxyl carboxylic acid and high alcohol, and this wax ester is solid-state under 25 ℃, and fusing point is more than 50 ℃,
Described wax ester is selected from Brazil wax, rice bran wax, jojoba wax, candelilla wax, spermaceti, Cera Flava, insect wax.
3. oil-in-water type makeup composition as claimed in claim 1, it is characterized in that, (A) carboxylic acid of component (b) is more than 0.21 with respect to the weight ratio (b)/(a) of all carboxylic acids (a) in the makeup composition, and wherein, described carboxylic acid (a) comprises the salifiable part of shape.
4. oil-in-water type makeup composition as claimed in claim 1 is characterized in that, described cosmetic is a mascara.
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004366418A JP2006169195A (en) | 2004-12-17 | 2004-12-17 | Makeup cosmetic |
| JP2004366417 | 2004-12-17 | ||
| JP2004-366417 | 2004-12-17 | ||
| JP2004366418 | 2004-12-17 | ||
| JP2004-366418 | 2004-12-17 | ||
| JP2004366417A JP2006169194A (en) | 2004-12-17 | 2004-12-17 | Makeup cosmetic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1823705A CN1823705A (en) | 2006-08-30 |
| CN1823705B true CN1823705B (en) | 2011-02-02 |
Family
ID=36670322
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2005101320099A Expired - Fee Related CN1823705B (en) | 2004-12-17 | 2005-12-16 | Makeup composition |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP2006169194A (en) |
| CN (1) | CN1823705B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012124179A2 (en) * | 2011-03-15 | 2012-09-20 | L'oreal | Cosmetic composition for eyelashes |
| JP6174325B2 (en) * | 2012-01-20 | 2017-08-02 | 花王株式会社 | Cosmetic composition |
| CN104997656A (en) * | 2014-03-19 | 2015-10-28 | 玫琳凯有限公司 | Mascara formulation |
| JP6669574B2 (en) * | 2016-04-25 | 2020-03-18 | 花王株式会社 | Eyelash and eyebrow cosmetics |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0898953A2 (en) * | 1997-08-29 | 1999-03-03 | Shiseido Company, Ltd. | Eyelash cosmetic composition |
| EP0974338A2 (en) * | 1998-07-22 | 2000-01-26 | Beiersdorf Aktiengesellschaft | Cosmetic and dermatological care compositions containing fatty acids |
| US20040091447A1 (en) * | 2002-09-06 | 2004-05-13 | Societe L'oreal. S.A. | Charging/separating cosmetic makeup compositions for keratin fibers |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0623089B2 (en) * | 1986-05-15 | 1994-03-30 | 株式会社資生堂 | External skin preparation |
| US5356627A (en) * | 1993-02-01 | 1994-10-18 | Estee Lauder, Inc. | Waterproof cosmetic compositions |
| US5330747A (en) * | 1993-02-03 | 1994-07-19 | Dow Corning Corporation | Cosmetics with enhanced durability |
| JPH07300419A (en) * | 1993-12-06 | 1995-11-14 | Lansinoh Lab Inc | Composition of lanolin/lanolin acid ester for treating skin |
| US5614200A (en) * | 1994-11-22 | 1997-03-25 | The Procter & Gamble Company | Mascara compositions |
| JP3554995B2 (en) * | 1995-03-29 | 2004-08-18 | 株式会社コーセー | Eyelash cosmetics |
| JPH09100212A (en) * | 1995-10-04 | 1997-04-15 | Shiseido Co Ltd | Solid aqueous cosmetic |
| ES2187833T5 (en) * | 1996-11-27 | 2007-11-01 | THE PROCTER & GAMBLE COMPANY | MASK COMPOSITIONS WITH IMPROVED BENEFITS OF USE AND BEAUTY. |
| JP3565548B2 (en) * | 1997-08-29 | 2004-09-15 | 株式会社資生堂 | Eyelash cosmetics |
| JPH11315010A (en) * | 1997-08-30 | 1999-11-16 | Nonogawa Shoji Kk | Ultraviolet ray injury-protecting eye cosmetic |
| DE19842730A1 (en) * | 1998-09-18 | 2000-03-23 | Beiersdorf Ag | Emulsifier-free finely dispersed systems of the oil-in-water and water-in-oil type |
| FR2804600B1 (en) * | 2000-02-08 | 2002-03-22 | Oreal | PHOTOPROTECTIVE COMPOSITIONS COMPRISING A MIXTURE OF A POLYETHYLENE HAVING A TERMINAL CARBOXYLIC ACID FUNCTION AND A POLYETHYLENE |
| DE10044313A1 (en) * | 2000-09-07 | 2002-03-21 | Beiersdorf Ag | Low-lipid cosmetic and dermatological preparations in the form of O / W emulsions containing fatty acids |
| US20030026815A1 (en) * | 2001-06-05 | 2003-02-06 | Scott Alic Anthony | Film forming cosmetic compositions |
| JP2005508919A (en) * | 2001-09-29 | 2005-04-07 | バイヤースドルフ・アクチエンゲゼルシヤフト | Cosmetic and dermatological sticks |
| JP3660901B2 (en) * | 2001-10-17 | 2005-06-15 | 株式会社ノエビア | Keratin fiber coating composition |
| DE10162842A1 (en) * | 2001-12-20 | 2003-07-03 | Beiersdorf Ag | Cosmetic and dermatological light protection formulations containing benzotriazoles and benzoxazole derivatives |
| EP1458342A1 (en) * | 2001-12-20 | 2004-09-22 | Beiersdorf AG | Cosmetic and dermatological light-protective formulations comprising hydroxybenzophenones and benzoxazole derivatives |
| DE10162840A1 (en) * | 2001-12-20 | 2003-07-03 | Beiersdorf Ag | Cosmetic and dermatological light protection formulations containing water-soluble UV filter substances and benzoxazole derivatives |
| JP2004010496A (en) * | 2002-06-03 | 2004-01-15 | Nippon Shikizai Inc | Eyelash cosmetic |
| JP2004067517A (en) * | 2002-08-01 | 2004-03-04 | Tokiwa Corp | Cosmetic for eyelash |
-
2004
- 2004-12-17 JP JP2004366417A patent/JP2006169194A/en active Pending
-
2005
- 2005-12-16 CN CN2005101320099A patent/CN1823705B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0898953A2 (en) * | 1997-08-29 | 1999-03-03 | Shiseido Company, Ltd. | Eyelash cosmetic composition |
| EP0974338A2 (en) * | 1998-07-22 | 2000-01-26 | Beiersdorf Aktiengesellschaft | Cosmetic and dermatological care compositions containing fatty acids |
| US20040091447A1 (en) * | 2002-09-06 | 2004-05-13 | Societe L'oreal. S.A. | Charging/separating cosmetic makeup compositions for keratin fibers |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2006169194A (en) | 2006-06-29 |
| CN1823705A (en) | 2006-08-30 |
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