CN1802910A - Agricultural chemicals preparation containing pyracetic acid - Google Patents

Agricultural chemicals preparation containing pyracetic acid Download PDF

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Publication number
CN1802910A
CN1802910A CN 200610049233 CN200610049233A CN1802910A CN 1802910 A CN1802910 A CN 1802910A CN 200610049233 CN200610049233 CN 200610049233 CN 200610049233 A CN200610049233 A CN 200610049233A CN 1802910 A CN1802910 A CN 1802910A
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acid
class
vinegar liquid
methyl
plant
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马建义
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Zhejiang A&F University ZAFU
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Zhejiang Forestry College
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Abstract

The invention discloses a pesticide preparation containing plant vinegar liquid, wherein the ingredients include plant vinegar liquid 1-99%, conventional pesticides 0.1-90.0%.

Description

A kind of pesticidal preparations that contains plant vinegar liquid
Technical field
The present invention relates to a kind of pesticidal preparations, be specifically related to a kind of pesticidal preparations that contains plant vinegar liquid.
Background technology
Plant vinegar liquid is the brown liquid product that is condensed at normal temperatures by the gas that collection after vegetable material and the industrial wood waste pyrolysis thereof obtains, and contains nearly more than 300 kinds of compositions such as organic acid, phenols, ketone, aldehydes, alcohols and heterocyclic.Main application is Bamboo vinegar solution, pyroligneous liquor and careless vinegar liquid at present.The definition of " plant vinegar liquid " among the present invention comprises Bamboo vinegar solution (being the accessory substance that bamboo surplus material of processing obtains through high temperature pyrolysis), pyroligneous liquor (being the accessory substance that wood machining residues obtains through high temperature pyrolysis) and careless vinegar liquid (being meant the accessory substance that herbaceous plant and crop stalk obtain through high temperature pyrolysis).External research aspect Bamboo vinegar solution mainly is Japan.Develop Bamboo vinegar solution since Japan in 1991, be found in Japanese bamboo charcoal and the Bamboo vinegar solution association of nineteen ninety-five, carry out useful exploration with regard to the application of bamboo charcoal and Bamboo vinegar solution always, and with its commercialization.Calendar year 2001 has also also been held once international bamboo charcoal and Bamboo vinegar solution seminar in China.Japan is applied in it aspects such as health care, beverage, the deodorizing of animal feeding place at present, and according to the interrelated data introduction, Bamboo vinegar solution also has good application prospects aspect higher effective and lower toxic pesticide.Having many scholars and exploitation mechanism once to do bamboo charcoal and by product-Bamboo vinegar solution thereof in Japan waits the application test in field to study in agriculture and forestry (tomato, tea, cabbage, strawberry cultivation, stock growing, agriculture compost etc.), medical science (to allergic dermatitis, pruritus, diabetes etc.), environmental protection (waste water treatment, eliminate peculiar smell etc.); obtained certain effect, but be not used widely.The possible purposes of Bamboo vinegar solution has: making up a prescription etc. of gastrointestinal drug, dermic, patch medicine made the raw material of medicine, extract methyl alcohol and acetic acid etc. and make industrial chemicals, other also have food additives, dyestuff mordant, animal deodorant, pesticides additive agent, soil conditioner, root of hair promoter, Animal nutrition auxiliary agent etc.Wood is attached to add Bamboo vinegar solution when stepping on fruit tree agricultural chemicals such as spraying mancozeb for a long time, only once just obtains theatrical effect, does not also see the generation of stinkbug insect infringement when results, and the no lethality of Bamboo vinegar solution itself mainly plays repellent action.The positive model of Ah portion has been done the test of Bamboo vinegar solution control mushroom evil bacterium lignin Trichoderma, one deck Bamboo vinegar solution is covered until fruiting in bacterium bed culture medium top layer in 7 days, find that 1% concentration can protect from infection fully, 0.25% concentration can suppress mushroom evil bacterium lignin Trichoderma breeding 2～3 days, and 0.5% concentration can suppress to breed 7 days.Exit or entrance of a clitch loyalties etc. are sneaked into medium with Bamboo vinegar solution and are done plant seed germination and growth regulating test, the result shows when Bamboo vinegar solution concentration is 0.1mg/kg, 1.0mg/kg non-activity substantially, and 10mg/kg especially has strong inhibition activity more than the 20mg/kg, then to 2 of the growth inhibitory activity of plant seed and 100mg/kg, 4-D is identical during Bamboo vinegar solution concentration 100mg/kg.The second-class Bamboo vinegar solution of having studied of mouth of a valley gentry carries out the reproduction test of wood-decaying fungus to the preservation of timber against decay effect with culture dish, finds not long bacterium on the culture dish that adds Bamboo vinegar solution, even the Bamboo vinegar solution volatilization, the breeding of bacterium also latens; With the transplant bed of 2 years living seedlings of Bamboo vinegar solution processing, the amount of growth of nursery stock is higher than the check plot; But carry out the prolongation test of cut-flower (cut flower) life-span, the result who can not get determining with Bamboo vinegar solution, pyroligneous liquor, sawdust vinegar liquid, bamboo charcoal, charcoal, sawdust charcoal.The mechanism of Bamboo vinegar solution and application technology are still waiting further research.From charcoal and pyroligneous liquor, take a hint, find the serviceability of bamboo charcoal and Bamboo vinegar solution and it is carried out commercial development, just causing that Japanese scientist and business circles more and more pay close attention to.In addition, also there is the scholar that Bamboo vinegar solution is studied as India, Costa Rica etc.
China comprehensive utilization bamboo resource exploitation Bamboo vinegar solution just began to phase late 1990s, mainly concentrated on some universities and colleges, the research institute in Zhejiang Province, tentatively grasped the physicochemical property of Bamboo vinegar solution and the relation between the preparation technology.China begins to produce bamboo charcoal and Bamboo vinegar solution from nineteen ninety-five, and through effort in a few years, Bamboo vinegar solution production has now spreaded all over provinces such as Zhejiang, Fujian, Hunan and Jiangxi.The production of Bamboo vinegar solution is of certain scale, and products such as the bamboo charcoal in Zhejiang Province and Bamboo vinegar solution mainly are on sale throughout ground such as Japan, Korea S and China Taiwan, and also progressively open in domestic market.Be widely used in body-care, improve living environment, purify water; Food fresh keeping, medical and health; Aspects such as livestock rearing soil melioration and the crop growth adjusting and the ecological agriculture.Domestic field trial shows that also the economic forest fruit growth regulator of modulating with Bamboo vinegar solution has the excellent characteristics nuisanceless, that cost is low, effective.Other discovers has the effect of inhibition and effect to reduce with Bamboo vinegar solution concentration to dissimilar putrefying bacteria in food and the fruit.
Plant vinegar liquid has the effect of expelling parasite, bactericidal, weeding (under the high concentration) and plant growth regulator (under the low concentration).We studies show that, plant vinegar liquid also has the absorption function of change plant leaf blade to material, improves drug effect by the absorption that increases agricultural chemicals.Plant vinegar liquid itself has the pesticide efficacy function, can increase the drug effect of agricultural chemicals with agriculture chemical compounding, reduces toxicity and residual, thereby helps the production of safety in production, green product and the organic farm products of agricultural products, and, reduce greatly agricultural farming this.Plant vinegar liquid itself has the soil structure of improvement and helps continuous agricultural production, plant vinegar liquid to descending slowly and lightly in soil in spray process, not only can not resemble organic solvent such as agricultural chemicals common solvent (medium) toluene and dimethylbenzene to soil harmful outside, also help and improve soil structure.Because the work of some research plant vinegar liquids and agriculture chemical compounding is that ready-made market-oriented pesticidal preparations of employing and plant vinegar liquid carry out now with the current (also claiming existing existing the using of mixing) entirely, like this, cause the peasant very inconvenient in actual use and be difficult to promote and the marketization, this patent is to use plant vinegar liquid and pesticide original medicine and auxiliary agent thereof to process and is prepared into ready-made pesticidal preparations, very easy to use, be fit to promote and the marketization.
Medium as the various aqueous compositions of agricultural chemicals, replace the material of water with plant vinegar liquid as medium, not only comprise former plant vinegar liquid, also comprise the processing plant vinegar liquid, the latter especially can be according to the physicochemical characteristics of different pesticide original medicines, adjust the physicochemical characteristics of plant vinegar liquid, the different pesticide original medicines that suit for example, can be adjusted pH value and can be fit to the requirement (as stability etc.) of pesticide original medicine to pH value.Also can use former plant vinegar liquid, add the method for film forming agent and obtain handling plant vinegar liquid, like this and behind the agriculture chemical compounding, be sprayed to plant leaf blade through dilution, can form the medicine film of gas permeability, not only play the effect of slowly-releasing, also have effect such as sprawl, further improve drug effect, reduce farming this.
Summary of the invention
The present invention aims to provide low, the good drug efficacy of a kind of production cost, and to little, the safe pesticidal preparations that contains plant vinegar liquid of surrounding environment influence.
Described a kind of pesticidal preparations that contains plant vinegar liquid is characterized in that: contain plant vinegar liquid 1-99%, known agricultural chemicals 0.1-90.0%.
The described pesticidal preparations that contains plant vinegar liquid is characterized in that: contain plant vinegar liquid 10-90%, known agricultural chemicals 1-80%.
Described contain plant vinegar liquid pesticidal preparations, it is characterized in that: contain plant vinegar liquid 50-80%, known agricultural chemicals 10-50%.
The described pesticidal preparations that contains plant vinegar liquid is characterized in that: described known agricultural chemicals comprises insecticide, bactericide, weed killer herbicide and plant growth regulator.
The described pesticidal preparations that contains plant vinegar liquid, it is characterized in that: the insecticide in the described known agricultural chemicals scope comprises and contains arsenic, fluorine, the inorganic insecticide of sulphur and phosphorus etc., vegetable insecticide is (as tobacco, trifoliate jewelvine and Dalmatian chrysanthemum etc.), the mineral oils insecticide is (as the machine oil emulsifiable paste, kerosene emulsion etc.), carbamates (Carbamates), organic phosphates (Organo-phosphates), cyclodiene and poly chlorine cycloalkanes (Chlorinated Cyclodienes and Polychlorocycloalkanes), benzene pyrazoles (Phenylpyrazoles), benzoate (Benzoates), Avermectin (Avermectin), more visit rhzomorph (Milbemectin), pyrethroid (Synthetic Pyrethroids), pyrethrins (Pyrethrins), organochlorine (Organo-chlorine) oxadiazine class, jervine (Veratrumalkaloids), anabasine (Neonicotinoids), nicotine (Nicotine), benzene sulfonate (Benzenesulfothioate), thiocarboxylic (Thiocar bamate), the similar thing of nereistoxin (Nereistoxin analogues), pleocidin (Spinosyns), hydrazone class (hydrazones), Bifenazate (Bifenazate), juvenoid (Juvenile hormone analogues), phenylate class (Benzene ether), benzoyl area kind (Benzoylures), thiadiazine (Thiadiazine), triazine (Triazine), bishydrazide (Diacylhydrazines), nimbin (Azadirachtin), azoles quinoline class (Oxazoline), bacillus subtilis (B.sp.), bacillus thuringiensis,Bt subspecies (B.t.subsp.), organic metal miticide (Organotin Miticide), thiocarbamide (Thiourea), sulfite miticide (Sulfite Ester Miticide), organochlorine (Organo-chlorine), pyroles (Pyrrole), nitrocresol (Nitrocresol), pyridazinone (Pyridazinone), quinoline azoles beautiful jade class (Quinaqzoline), pyrazoles (Pyrazole), miazines (Pyrimidine), lactone (Acetogenin), rotenone (Rotenone), hydrazone (Hydrazone), naphthoquinones (Naphthalenedione), strobilurins (Strobilurin), antibiotic (Antibiotic), phosphide (Phosphine), fluoroacetic acid (Fluoroacetate), ether (ether), phosphate (Tributyl phosphate), tetronic acid (Tetronicacid), plant resource compound (Botanicai chemicals), fumigant (Fumigants), anti-feedant (selective feeding blockers), mite growth inhibitor (mite growth inhibitors), tetrazine (Tetrazine), miazines (Pyrimidine) insecticide; Bactericide comprises benzimidazole (Benzimadazoles), dicarboximide class (Dicarboximides), imidazoles (Imidazoles), piperazine (Piperazine), pyridine (Pyridine), miazines (Pyrimidines), triazole type (Triazoles); oxazolidine ketone (Oxazolidinones), butyrolactone (Butyrolactones), morpholine class (Morpholines), organic phosphates (Organophosphorous), anilide (AnilideOxathiin), phenylamino pyrimidine (Anilinopyrimidine), chlorobenzene class (Chlorophenyls), cinnamic acid (Cinnamic acid), reductase inhibitor (Reductase inhibitors), dehydratase inhibitor (Dehydratase inhibitor), hydroxyanilines (Hydroxyanilide), the benzothiadiazine class (Benzothiadiazole, BTH), amino acid amide (Amino acid amide), carbamate (Carbamate), cyanoacetamide (Cyano-acetamide oxime), organic tin (Organo-tins), inorganic matter (Inorganics), dithiocarbamate (Dithiocarbamates), tpn (Chlorothalonil), sulfuric acid diamide (Sulphamides), guanidine class (Guanidines), anil class (Anilazine) bactericide; Weed killer herbicide comprises fragrant phenoxy propionic acid class (AryloxyphenoxPropionates), cyclohexenone analog (cyclohexene oxime), sulfonylurea (Sulfonylureas), the triazolo pyrimidine sulfanilic acid, pyrimidine salicylic acid (Dimethoxypyrimidinylsalicylic Acids), organic phosphates (organophosphorus), dinitroaniline (Dinitrophenols), dibenzyl ethers (Benzylether), chloroacetyl amine (Chloroacetamides), thiocarbamates (Thiocarbamates), triazine (Triazines), substituted urea class (Ureas), two pyridines (Bipyridyliums), benzene nitrile (Benzonitriles), picolinic acid class (Pyridnecarboxylic), quinoline acids, phenoxy carboxylic acid (Phenoxycarboxylic Acids), diphenyl ether (Diphenylethers) oxadiazole class (Oxadiazole), phosphonic acid based, glycine class (Glycines) weed killer herbicide; Plant growth regulator comprises auxins, gibberellin class, cytokinin, vinyl, the acids that comes off, plant growing inhibiting substances.
The described pesticidal preparations that contains plant vinegar liquid, it is characterized in that: described known agricultural chemicals more is optimized for the concrete kind of following agricultural chemicals, and insecticide is: Bassa (fenobucaeb), Methomyl (methomyl), carbofuran (Carbofuran), carbosulfan (Carbosulfan), Mobucin (Isoprocarb), oxamyl (Oxamyl), Aphox (Pirimicarb), chlopyrifos (Chlorpyrifos), diazinon (Diazinon), Menite (Mevinphos), nuvacron (Monocrotophos), methidathion (Methidathion), omethoate (Omethoate), parathion-methyl (Parathion-methyl), phoxim (Phoxim), Hostathion (Triazophos), dicofol (Dicofol), fluorine worm nitrile (Fipronil), Avermectin (Abamectin), more visit rhzomorph (Milbemectin), cyfloxylate (Cyfluthrin), betacyfluthrin (Beta-cyfluthrin), smart gamma cyhalothrin (Gamma-Cyhalothrin), cypermethrin (Cypermethrin), beta-cypermethrin (Beta-cypermethrin), sumicidin (Esfenvalerate), flucythrinate (Flucythrinate), pyrethrins (Pyrethrins), Imidacloprid (Imidacloprid), nicotine (Nicotine), dimehypo (Thiosultap-sodium), diflubenzuron (Diflubenzuron), nimbin (Azadirachtin), bacillus subtilis (Bacillussphaericus), bacillus thuringiensis,Bt (Israelensis), subspecies (B.t.subsp.Israelensis), azacyclotin (Azocyclotin), alkynes mite spy (Propargite), pyridaben (Pyridaben), rotenone (Rotenone), antimycin (Antimycin), De-Green (Tribufos DEF), Butacide (Piperonylbutoxide), four mite piperazines (Clofentezine), fluorine mite piperazine (Flufenzine), Citrazon (Benzoximate), dicofol (Dicofol); Bactericide is: benomyl (Benomyl), carbendazim (Carbendazim), thiophanate-methyl (Thiophanate-methyl), iprodione (Iprodione), press down mould azoles (Imazalil), prochloraz (Prochloraz), alkene azoles alcohol (Diniconazole), own azoles alcohol (Hexaconazole), paclobutrazol (Paclobutrazol), Tebuconazole (Tebuconazole), triazolone (Triadimefon), Triadimenol (Triadimenol), M 9834 (Menalaxyl), metalaxyl (Metalaxyl) Evil frost spirit (Oxadixyl), iprobenfos (Iprobenfos), Isoprothiolane (isoprothiolane), the mould prestige of second (Diethofencarb), tolelofos-methyl (Tolclofos-methyl), tricyclazole (Tricyclazole), blasticidin-S (Blasticidin), kasugarnycin (Kasugamycin), terramycin (oxytetracycline), streptomycin (Streptomycin), valida (Validamycin), polyoxin (Polyoxin), jinggangmeisu (jiangonmycin), Propamocarb (Propamocarb), frost urea cyanogen (Cymoxanil), fentin (Tri-phenyl tins), ethyl phosphine aluminium (Fosetyl-aluminum), mantoquita (Copper plus salts), sulphur (Sulphur), ferbam (Ferbam), mancozeb (Mancozeb), maneb (Maneb), Propineb (Propineb), tmtd (Thiram), zineb (Zineb), ziram (Ziram), tpn (Chlorothalonil), Euparen (Dichlofluanid), biguanides suffering (Iminoctadine), anilazine (Anilazine); Weed killer herbicide is: diclofop-methyl (Diclofop-P), quizalofop-ethyl (Quizalofop-p), haloxyfop-r-methyl (Haloxyfop-R) oxazole standing grain spirit (Fenoxaprop), fluazifop (Fluazifop-p), receive happy logical (Clethodim), nicosulfuron (Nicosulfuron), metsulfuron-methyl (Metsulfron methyl), gold autumn (Cyclosulfamuron), tribenuron-methyl (Tribenuron), Bensulfuron-methyl (Bensulfuron-methyl), chlorimuron (Chlorimuron-ethyl), pyrazosulfuron (Pyrazonsulfuron-ethyl), Ethanetsulfuron (ethametsulfuron), Flumetsulam (flumetsulam), Nong Meili (Bispyribac-sodium), anilofos (Anilofos), trefanocide (Trifluralin), Pendimethalin (Pendimethalin), cinmethylin (Cinmethylin), the third careless amine (Pretilachlor), butachlor (Butachlor), isopropyl methoxalamine (Metolachlor), Acetochlor (Acetochlor), mefenacet (Mefenacet), molinate (Molinate), atrazine (Atrazine), Sigma's piperazine (Simazine), ametryn (ametryne), Caojinjing (Cyanazine), prometryn (prometryne), isoproturon (Isoproturon), chlortoluron (Chlorotoluron), methabenzthiazuron (Methabenzthiazuron), diuron (Diuron), Gramoxone (paraquat), Brominal (Bromoxynil), make it grand (Fluroxypyr), dichloro quinolinic acid (quinclorac), 2 first, 4 chlorine (MCPA, benazolin (Benazolin-ethyl), Oxyfluorfen (Oxyfluorfen), rice thinks to reach (Oxadiargyl), phosphine oxamate (Glufosinate), glyphosate (Glyphosate), glyphosate salt; Plant growth regulator is: 6-benzylaminopurine (6-Benzylaminopurine), kinetin (Kinetin, KT), gibberellin (Gibberellic acid), 2,4-drips (2,4-Dichlorophenoxyacetic acid, 2,4-D), 2,4-D salt, brassinosteroid (Brassinolide, BR), methyl (1-Naphthylacetic acid, NAA), growth hormone (Indole-3-acetic acid, IAA), drop-proof agent (4-Chlorophenoxy acetic acid, PCPA), triacontanol (riacontanol, TRIA), ethrel (Ethephon), paclobutrazol (Paclobutrazol), compound sodium nitrophenolate (Sodium nitrophenolate, Atonik), maleic Min (Flumetralin), abscisic acid (ABA), uniconazole P (uniconazole), chlormequat (chlormequat), casing coupling peace (mepiquat-chloride), CPPU (forchlorfenuron), Thidiazuron (thidiazuron), indolebutyric acid (4-indol-3-ylbutyric acid) and indolebutyric acid salt, increase sweet phosphine (glyphosine).
The described pesticidal preparations that contains plant vinegar liquid is characterized in that: this pesticidal preparations type comprises: soluble liquid, microemulsion, aqueous emulsion, suspending agent, suspended emulsion, micro-capsule suspension and sustained release agent.
Described plant vinegar liquid comprises former plant vinegar liquid, refers to the plant vinegar liquid that does not pass through any processing that directly is recovered in process of production; Also comprise the processing plant vinegar liquid, refer to the plant vinegar liquid that former plant vinegar liquid is obtained through physicochemical processing, processing method is for example filtered, and adds alkaline matter and adjusts the acidity pH value; With plant vinegar liquid is carried out the concentrated plant vinegar liquid that water evaporates obtains to remove part moisture.
The described Recompounded pesticide that contains plant vinegar liquid can be mixed with different formulations such as soluble liquid, microemulsion, aqueous emulsion, suspending agent, suspended emulsion, micro-capsule suspension and sustained release agent.
Because plant vinegar liquid has the effect of expelling parasite, bactericidal, weeding (under the high concentration) and plant growth regulator (under the low concentration), we studies show that, plant vinegar liquid also has the absorption function of change plant leaf blade to material, improve drug effect by the absorption that increases agricultural chemicals, and plant vinegar liquid itself has the pesticide efficacy function; Thereby, the described Recompounded pesticide that contains plant vinegar liquid, by with existing agriculture chemical compounding, can increase the drug effect of existing agricultural chemicals, reduce toxicity and residual, thereby help the production of safety in production, green product and the organic farm products of agricultural products, and, reduce agriculture production cost greatly.
Percentage composition is the weight percentage of pure material in the present specification.
Specific embodiment
Now, further specify beneficial effect of the present invention in conjunction with the embodiments of the invention and the test of pesticide effectiveness.
Embodiment is as follows in soluble liquid (being fit to be dissolved in the agricultural chemicals of water or sour water or buck) preparation:
Embodiment 1
In the 500L reactor, drop into plant vinegar liquid 250L, constantly slowly drop into 5kg urea (antifreezing agent) after all dissolving under the condition of stirring, slowly drop into 98% Methomyl (methomyl) 16kg and insecticides adjuvant 70%JFC 3L again, be stirred into 5% Methomyl aqua.
Embodiment 2
In the 500L reactor, drop into plant vinegar liquid 300L, constantly slowly drop into NaOH under the condition of stirring, up to pH value is 6.5 o'clock, stop to add, discharging and filtering is got filtered fluid 250L and is dropped in another 500L reactor, slowly drop into 90% 3 second phosphorus phosphonic acids aluminium (fosetyl-aluminium) 85kg again, after being stirred in whole dissolvings, add 2.5L insecticides adjuvant Tween-80, be stirred into 30% phosethyl-Al aqua.
Embodiment 3
In the 1000L reactor, drop into plant vinegar liquid 600L, be heated to 100 ℃ and evaporate moisture, when being concentrated to 260L, stop heating, be cooled to normal temperature, constantly slowly drop into 42% paraquat (paraquat) 200kg (or 160L) under the condition of stirring, after all dissolving, add 8.4L insecticides adjuvant 70%JFC, be stirred into 20% paraquat aqua.
Embodiment 4
In the 500L reactor, drop into plant vinegar liquid 150L, drop into 3kg polyvinyl alcohol-124, constantly be heated to 70 ℃ under the condition of stirring, after polyvinyl alcohol-124 melts fully, be cooled to normal temperature, constantly slowly drop into the former medicine 200L of 70% ethrel (ethephon) under the condition of stirring, after all dissolving, add 7L insecticides adjuvant 70%JFC, be stirred into 40% ethephon agent.
Aqueous emulsion (being fit to be not dissolved in the agricultural chemicals of water or sour water or buck)
Embodiment 5
In the 500L reactor, drop into toluene 400kg, constantly slowly drop into Bassa (fenobucaeb) 400kg under the condition of stirring, promptly get A liquid up to dissolving fully.In another 500L reactor, drop into the 380kg plant vinegar liquid, drop into 25kg glycerine, 20kg OPEO phosphate, 10kg polyacrylic acid and 20kg epoxidized soybean oil again, fully stir and promptly get B liquid.Get B liquid 400kg and become uniform dispersion emulsion, constantly slowly adding 100kgA liquid under the condition of stirring then, and fully stirring through the high-shearing dispersion emulsifying machine dispersion and emulsion, final products 10% Bassa aqueous emulsion.
Embodiment 6
In the 500L reactor, drop into toluene 200kg, constantly slowly drop into Prochloraz (prochloraz) 200kg under the condition of stirring, promptly get A liquid up to dissolving fully.In another 500L reactor, drop into the 200kg plant vinegar liquid, drop into 15kg propane diols, 10kg OPEO phosphate, 6kg polyacrylic acid and 10kg epoxidized soybean oil again, fully stir and promptly get B liquid.Get B liquid 100kg and become uniform dispersion emulsion, constantly slowly adding 50kgA liquid under the condition of stirring then, and fully stirring through the high-shearing dispersion emulsifying machine dispersion and emulsion, final products 20% prochloraz aqueous emulsion.
Embodiment 7
In the 500L reactor, drop into dimethylbenzene 200kg, constantly slowly drop into Oxyfluorfen (oxyfluorfen) 200kg under the condition of stirring, promptly get A liquid up to dissolving fully.In another 500L reactor, drop into the 400kg plant vinegar liquid, be heated to 100 ℃ and evaporate moisture, when being concentrated to 200L, stop heating, be cooled to normal temperature, drop into 15kg propane diols, 10kg OPEO phosphate, 6kg polyacrylic acid and 10kg epoxidized soybean oil again, fully stir and promptly get B liquid.Get B liquid 100kg and become uniform dispersion emulsion, constantly slowly adding 50kgA liquid under the condition of stirring then, and fully stirring through the high-shearing dispersion emulsifying machine dispersion and emulsion, final products 20% Oxyfluorfen aqueous emulsion.
Embodiment 8
In the 500L reactor, drop into benzene 200kg, constantly slowly drop into methyl (naphthylacetic acid) 200kg under the condition of stirring, promptly get A liquid up to dissolving fully.In another 500L reactor, drop into the 200kg plant vinegar liquid, drop into 15kg propane diols, 10kg OPEO phosphate, 6kg polyacrylic acid and 10kg epoxidized soybean oil again, fully stir and promptly get B liquid.Get B liquid 200kg and become uniform dispersion emulsion, constantly slowly adding 50kgA liquid under the condition of stirring then, and fully stirring through the high-shearing dispersion emulsifying machine dispersion and emulsion, final products 10% methyl aqueous emulsion.
Embodiment is as follows in aqueous suspension agent (being fit to be not dissolved in the agricultural chemicals of water or sour water or buck) preparation:
Embodiment 9
1kg cyhalothrin (cyhalothrin), 0.2kg sodium lignin sulfonate, 0.5kg OP-10,1kg silica, the 1kg propane diols adds the 37kg plant vinegar liquid continuously, and being crushed to fineness in wet type colloid mill continuous stirring is 2-5 μ m, existing final products.
Embodiment 10
40kg mancozeb (mancozeb), 4kg calcium lignosulfonate, 10kg OP-10,1kg silica, 3kg ethylene glycol, adding 42kg continuously, (PH=6.5-7.0) to be crushed to fineness in wet type colloid mill continuous stirring through the processing Bamboo vinegar solution (handle pyroligneous liquor or handle careless vinegar liquid) of neutralization be 2-5 μ m, existing final products.
Embodiment 11
80kg atrazine (atriazine), 8kg calcium lignosulfonate, 20kg OP-10,2kg silica, 3kg glycerine, adding 80kg continuously, (PH=6.0-6.5) to be crushed to fineness in wet type colloid mill continuous stirring through the processing Bamboo vinegar solution (handle pyroligneous liquor or handle careless vinegar liquid) of neutralization be 2-5 μ m, existing final products.
Embodiment 12
1kg benzyladenine (6-benzyladenine), 0.2kg sodium lignin sulfonate, 0.5kg agricultural emulsifier NO, 1kg silica, the 1kg propane diols, add the 25kg plant vinegar liquid continuously, being crushed to fineness in wet type colloid mill continuous stirring is 2-5 μ m, existing final products.
Embodiment is as follows in preparation for aqueous suspension emulsion (being fit to be not dissolved in the composite of the former medicine of liquid of water or sour water or buck and the former medicine of solid):
Embodiment 13
Pyridaben (pyridaben) 20kg, agricultural emulsifier NO 2kg, sodium lignin sulfonate 1kg, SOPA sodium salt 1kg, propane diols 1kg, white carbon 1kg, 64kg plant vinegar liquid, after ball mill is pulverized, re-use the sand mill pulverizing and be ground to particle diameter less than 3 μ m, obtain suspension liquid A liquid; Alkynes mite spy (propargite) 20kg, dimethylbenzene 10kg, calcium dodecyl benzene sulfonate 2.5kg, emulsifier op-10 1.5kg up to complete mixing, obtains B liquid 30-40 ℃ of heated and stirred; A and B liquid are joined high-shearing dispersion emulsifying machine process high speed homogenize and obtain final products according to 1: 2 ratio of weight.
Embodiment 14
Thiophanate-methyl (thiophanate-methyl) 20kg, agricultural emulsifier NO 1kg, calcium lignosulfonate 1kg, SOPA sodium salt 1kg, glycerine 1kg, white carbon 1kg, 65kg plant vinegar liquid, after ball mill is pulverized, re-use the sand mill pulverizing and be ground to particle diameter less than 3 μ m, obtain suspension liquid A liquid; S-Ethyl ethylthio sulfonate (ethylicin) 20kg, ethanol 3kg, calcium dodecyl benzene sulfonate 1kg, emulsifier op-10 1kg stirs up to complete mixing, obtains B liquid; A and B liquid are joined high-shearing dispersion emulsifying machine process high speed homogenize and obtain final products according to 1: 1 ratio of weight.
Embodiment 15
Atrazine (atriazine) 20kg, No. 602 1kg of farming breast, sodium lignin sulfonate 1kg, SOPA sodium salt 1.2kg, propane diols 1kg, white carbon 0.3kg, 66.5kg plant vinegar liquid, after ball mill is pulverized, re-use the sand mill pulverizing and be ground to particle diameter less than 3 μ m, obtain suspension liquid A liquid; Third careless amine (pretilachlor) 20kg, dimethyl formamide 4kg, calcium dodecyl benzene sulfonate 1kg, emulsifier op-10 1kg up to complete mixing, obtains B liquid 30-40 ℃ of heated and stirred; A and B liquid are joined high-shearing dispersion emulsifying machine process high speed homogenize and obtain final products according to 2: 1 ratios of weight.
Embodiment 16
Brassin lactones (brassinolide) 0.2kg, agricultural emulsifier NO 1kg, calcium lignosulfonate 1kg, SOPA sodium salt 1kg, glycerine 1kg, white carbon 1kg, 94.8kg plant vinegar liquid, after ball mill is pulverized, re-use the sand mill pulverizing and be ground to particle diameter less than 3 μ m, obtain suspension liquid A liquid; Triacontanol (ethylicin) 0.1kg, carrene 8.9kg, calcium dodecyl benzene sulfonate 0.5kg, emulsifier op-10 0.5kg stirs up to complete mixing, obtains B liquid; A and B liquid are joined high-shearing dispersion emulsifying machine process high speed homogenize and obtain final products according to 9: 1 ratios of weight.
Embodiment is as follows in sustained release agent and microcapsule formulations (being fit to all agricultural chemicals) preparation:
Embodiment 17
In the 500L reactor, drop into plant vinegar liquid 300L, constantly slowly drop into NaOH under the condition of stirring, when pH value is 4-5, stop to add, discharging and filtering is got filtered fluid 180L and is dropped in another 500L reactor, be heated to 70 ℃, in heating, drop into the 15kg polyvinyl alcohol slowly, after dissolving disperses fully in constantly stirring, stop heating, continue to add the 120L filtered fluid, stir, be cooled to normal temperature, slowly drop into jinggangmeisu (jiangonmycin) 9kg again, after being stirred in whole dissolvings, add 2.5L insecticides adjuvant JFC, obtain final products after stirring.
Embodiment 18
In the 500L reactor, drop into plant vinegar liquid 300L, constantly slowly dropping into NaOH under the condition of stirring, when pH value is 4-5, stop to add, discharging and filtering is got filtered fluid 180L and is dropped in another 500L reactor, be heated to 70 ℃, in heating, drop into the 15kg natural gum slowly, after dissolving disperses fully in constantly stirring, stop heating, continue to add the 120L filtered fluid, stir, being cooled to normal temperature, to obtain A liquid deposit stand-by.In the 500L reactor, drop into toluene 200kg, constantly slowly drop into triazolone (triadimefon) 50kg under the condition of stirring after dissolving fully, add calcium dodecyl benzene sulfonate 4kg, emulsifier op-10 6kg, stirring is up to complete mixing, and it is stand-by promptly to get B liquid deposit.A and B liquid are joined high-shearing dispersion emulsifying machine process high speed homogenize and obtain final products according to 2: 1 ratios of weight.
Embodiment 19
In the 500L reactor, drop into plant vinegar liquid 180L, be heated to 50 ℃, in heating, drop into the 30kg polyethylene glycol slowly, after dissolving disperses fully in constantly stirring, stop heating, continue to add the 120L filtered fluid, 3kg ethylene glycol stirs, and being cooled to normal temperature, to obtain A liquid deposit stand-by.Get A liquid 66.5kg, tribenuron-methyl (tribenuron-methyl) 20kg, No. 602 1kg of farming breast, sodium lignin sulfonate 1kg, SOPA sodium salt 1.2kg, propane diols 1kg, white carbon 0.3kg, after ball mill is pulverized, re-use the colloid mill pulverizing and be ground to particle diameter, and obtain final products less than 3 μ m.
Embodiment 20
In the 500L reactor, drop into plant vinegar liquid 180L, be heated to 90 ℃, in heating, drop into 30kg agar, after dissolving disperses fully in constantly stirring, stop heating, continue to add the 120L filtered fluid, the 3kg glycerine, No. 602 5kg of farming breast, sodium lignin sulfonate 4kg, SOPA sodium salt 3kg, stir, being cooled to normal temperature, to obtain A liquid deposit stand-by.In another 500L reactor, drop into benzene 200kg, constantly slowly drop into flumetralim (flumetralin) 100kg under the condition of stirring, promptly get B liquid up to dissolving fully.A and B liquid are joined high-shearing dispersion emulsifying machine process high speed homogenize and obtain final products according to 1: 1 ratio of weight.
Below be the test data and the conclusion thereof of the foregoing description:
The synergism test result of table 1 embodiment 1-20
Embodiment Contrast medicament (commodity medicament) The test controlling object Synergistic effect %
Embodiment 1 20% methomyl milk oil Cotton bollworm 50％
Embodiment 2 40% phosethyl-Al wetting powder Cucumber downy mildew 75％
Embodiment 3 20% paraquat dichloride aqua Green foxtail 25％
Embodiment 4 40% ethephon agent Tomato 50％
Embodiment 5 20% Bassa missible oil Rice fulgorid 50％
Embodiment 6 25% Shi Baoke missible oil Pepper anthracnose 50％
Embodiment 7 20% Oxyfluorfen missible oil The barnyard grass grass 25％
Embodiment 8 40% methyl salt aqua Wheat 75％
Embodiment 9 2.5% time missible oil Cabbage caterpillar 50％
Embodiment 10 70% mancozeb wettable powder Vegetables early blight 50％
Embodiment 11 48% atrazine wetting powder The tea place grassy weed 25％
Embodiment 12 Bao Meiling 3.6% liquor Red Fuji apple tree 25％
Embodiment 13 20% pyridaben wetting powder The oranges and tangerines tetranychid 50％
Embodiment 14 50% thiophanate-methyl wetting powder Sclerotinia rot of colza 100％
Embodiment 15 38% atrazine aqueous suspension The orchard broad leaved weed 25％
Embodiment 16 0.2% brassin lactones wetting powder Wheat 50％
Embodiment 17 10% jinggangmeisu aqua Rice sheath blight disease 75％
Embodiment 18 25% trazodone wettable powder Powdery mildew of cucumber 75％
Embodiment 19 75% tribenuron-methyl wetting powder The wheat paddock broad leaved weed 50％
Embodiment 20 25% flumetralim missible oil Flue-cured tobacco 50％
Above-mentioned test data shows: the synergy rate of the described pesticidal preparations that contains plant vinegar liquid has significantly increased the drug effect of existing known agricultural chemicals up to 100%.

Claims (8)

1. a pesticidal preparations that contains plant vinegar liquid is characterized in that: contain plant vinegar liquid 1-99%, known agricultural chemicals 0.1-90.0%.
2. the pesticidal preparations that contains plant vinegar liquid as claimed in claim 1 is characterized in that: contain plant vinegar liquid 10-90%, known agricultural chemicals 1-80%.
3. as claimed in claim 1 contain plant vinegar liquid pesticidal preparations, it is characterized in that: contain plant vinegar liquid 50-80%, known agricultural chemicals 10-50%.
4. as claim 1, the 2 or 3 described pesticidal preparations that contain plant vinegar liquid, it is characterized in that: described known agricultural chemicals comprises insecticide, bactericide, weed killer herbicide and plant growth regulator.
5. as claim 1,2,3 or the 4 described pesticidal preparations that contain plant vinegar liquid, it is characterized in that: the insecticide in the described known agricultural chemicals scope comprises and contains arsenic, fluorine, the inorganic insecticide of sulphur and phosphorus etc., vegetable insecticide, the mineral oils insecticide, carbamates (Carbamates), organic phosphates (Organo-phosphates), cyclodiene and poly chlorine cycloalkanes (ChlorinatedCyclodienes and Polychlorocycloalkanes), benzene pyrazoles (Phenylpyrazoles), benzoate (Benzoates), Avermectin (Avermectin), more visit rhzomorph (Milbemectin), pyrethroid (Synthetic Pyrethroids), pyrethrins (Pyrethrins), organochlorine (Organo-chlorine) oxadiazine class, jervine (Veratrum alkaloids), anabasine (Neonicotinoids), nicotine (Nicotine), benzene sulfonate (Benzenesulfothioate), thiocarboxylic (Thiocar bamate), the similar thing of nereistoxin (Nereistoxin analogues), pleocidin (Spinosyns), hydrazone class (hydrazones), Bifenazate (Bifenazate), juvenoid (Juvenile hormone analogues), phenylate class (Benzene ether), benzoyl area kind (Benzoylures), thiadiazine (Thiadiazine), triazine (Triazine), bishydrazide (Diacylhydrazines), nimbin (Azadirachtin), azoles quinoline class (Oxazoline), bacillus subtilis (B.sp.), bacillus thuringiensis,Bt subspecies (B.t.subsp.), organic metal miticide (OrganotinMiticide), thiocarbamide (Thiourea), sulfite miticide (Sulfite Ester Miticide), organochlorine (Organo-chlorine), pyroles (Pyrrole), nitrocresol (Nitrocresol), pyridazinone (Pyridazinone), quinoline azoles beautiful jade class (Quinaqzoline), pyrazoles (Pyrazole), miazines (Pyrimidine), lactone (Acetogenin), rotenone (Rotenone), hydrazone (Hydrazone), naphthoquinones (Naphthalenedione), strobilurins (Strobilurin), antibiotic (Antibiotic), phosphide (Phosphine), fluoroacetic acid (Fluoroacetate), ether (ether), phosphate (Tributylphosphate), tetronic acid (Tetronic acid), plant resource compound (Botanical chemicals), fumigant (Fumigants), anti-feedant (selective feeding blockers), mite growth inhibitor (mitegrowth inhibitors), tetrazine (Tetrazine), miazines (Pyrimidine) insecticide; Bactericide comprises benzimidazole (Benzimadazoles), dicarboximide class (Dicarboximides), imidazoles (Imidazoles), piperazine (Piperazine), pyridine (Pyridine), miazines (Pyrimidines), triazole type (Triazoles); oxazolidine ketone (Oxazolidinones), butyrolactone (Butyrolactones), morpholine class (Morpholines), organic phosphates (Organophosphorous), anilide (Anilide Oxathiin), phenylamino pyrimidine (Anilinopyrimidine), chlorobenzene class (Chlorophenyls), cinnamic acid (Cinnamic acid), reductase inhibitor (Reductaseinhibitors), dehydratase inhibitor (Dehydratase inhibitor), hydroxyanilines (Hydroxyanilide), the benzothiadiazine class (Benzothiadiazole, BTH), amino acid amide (Aminoacid amide), carbamate (Carbamate), cyanoacetamide (Cyano-acetamide oxime), organic tin (Organo-tins), inorganic matter (Inorganics), dithiocarbamate (Dithiocarbamates), tpn (Chlorothalonil), sulfuric acid diamide (Sulphamides), guanidine class (Guanidines), anil class (Anilazine) bactericide; Weed killer herbicide comprises fragrant phenoxy propionic acid class (Aryloxyphenox Propionates), cyclohexenone analog (cyclohexene oxime), sulfonylurea (Sulfonylureas), the triazolo pyrimidine sulfanilic acid, pyrimidine salicylic acid (Dimethoxypyrimidinylsalicylic Acids), organic phosphates (organophosphorus), dinitroaniline (Dinitrophenols), dibenzyl ethers (Benzylether), chloroacetyl amine (Chloroacetamides), thiocarbamates (Thiocarbamates), triazine (Triazines), substituted urea class (Ureas), two pyridines (Bipyridyliums), benzene nitrile (Benzonitriles), picolinic acid class (Pyridnecarboxylic), quinoline acids, phenoxy carboxylic acid (Phenoxycarboxylic Acids), diphenyl ether (Diphenylethers) oxadiazole class (Oxadiazole), phosphonic acid based, glycine class (Glycines) weed killer herbicide; Plant growth regulator comprises auxins, gibberellin class, cytokinin, vinyl, the acids that comes off, plant growing inhibiting substances.
6. as claim 1,2,3,4 or the 5 described pesticidal preparations that contain plant vinegar liquid, it is characterized in that: described known agricultural chemicals more is optimized for the concrete kind of following agricultural chemicals, and insecticide is: Bassa (fenobucaeb), Methomyl (methomyl), carbofuran (Carbofuran), carbosulfan (Carbosulfan), Mobucin (Isoprocarb), oxamyl (Oxamyl), Aphox (Pirimicarb), chlopyrifos (Chlorpyrifos), diazinon (Diazinon), Menite (Mevinphos), nuvacron (Monocrotophos), methidathion (Methidathion), omethoate (Omethoate), parathion-methyl (Parathion-methyl), phoxim (Phoxim), Hostathion (Triazophos), dicofol (Dicofol), fluorine worm nitrile (Fipronil), Avermectin (Abamectin), more visit rhzomorph (Milbemectin), cyfloxylate (Cyfluthrin), betacyfluthrin (Beta-cyfluthrin), smart gamma cyhalothrin (Gamma-Cyhalothrin), cypermethrin (Cypermethrin), beta-cypermethrin (Beta-cypermethrin), sumicidin (Esfenvalerate), flucythrinate (Flucythrinate), pyrethrins (Pyrethrins), Imidacloprid (Imidacloprid), nicotine (Nicotine), dimehypo (Thiosultap-sodium), diflubenzuron (Diflubenzuron), nimbin (Azadirachtin), bacillus subtilis (Bacillussphaericus), bacillus thuringiensis,Bt (Israelensis), subspecies (B.t.subsp.Israelensis), azacyclotin (Azocyclotin), alkynes mite spy (Propargite), pyridaben (Pyridaben), rotenone (Rotenone), antimycin (Antimycin), De-Green (Tribufos DEF), Butacide (Piperonylbutoxide), four mite piperazines (Clofentezine), fluorine mite piperazine (Flufenzine), Citrazon (Benzoximate), dicofol (Dicofol); Bactericide is: benomyl (Benomyl), carbendazim (Carbendazim), thiophanate-methyl (Thiophanate-methyl), iprodione (Iprodione), press down mould azoles (Imazalil), prochloraz (Prochloraz), alkene azoles alcohol (Diniconazole), own azoles alcohol (Hexaconazole), paclobutrazol (Paclobutrazol), Tebuconazole (Tebuconazole), triazolone (Triadimefon), Triadimenol (Triadimenol), M 9834 (Menalaxyl), metalaxyl (Metalaxyl) Evil frost spirit (Oxadixyl), iprobenfos (Iprobenfos), Isoprothiolane (isoprothiolane), the mould prestige of second (Diethofencarb), tolelofos-methyl (Tolclofos-methyl), tricyclazole (Tricyclazole), blasticidin-S (Blasticidin), kasugarnycin (Kasugamycin), terramycin (oxytetracycline), streptomycin (Streptomycin), valida (Validamycin), polyoxin (Polyoxin), jinggangmeisu (jiangonmycin), Propamocarb (Propamocarb), frost urea cyanogen (Cymoxanil), fentin (Tri-phenyl tins), ethyl phosphine aluminium (Fosetyl-aluminum), mantoquita (Copper plus salts), sulphur (Sulphur), ferbam (Ferbam), mancozeb (Mancozeb), maneb (Maneb), Propineb (Propineb), tmtd (Thiram), zineb (Zineb), ziram (Ziram), tpn (Chlorothalonil), Euparen (Dichlofluanid), biguanides suffering (Iminoctadine), anilazine (Anilazine); Weed killer herbicide is: diclofop-methyl (Diclofop-P), quizalofop-ethyl (Quizalofop-p), haloxyfop-r-methyl (Haloxyfop-R) oxazole standing grain spirit (Fenoxaprop), fluazifop (Fluazifop-p), receive happy logical (Clethodim), nicosulfuron (Nicosulfuron), metsulfuron-methyl (Metsulfron methyl), gold autumn (Cyclosulfamuron), tribenuron-methyl (Tribenuron), Bensulfuron-methyl (Bensulfuron-methyl), chlorimuron (Chlorimuron-ethyl), pyrazosulfuron (Pyrazonsulfuron-ethyl), Ethanetsulfuron (ethametsulfuron), Flumetsulam (flumetsulam), Nong Meili (Bispyribac-sodium), anilofos (Anilofos), trefanocide (Trifluralin), Pendimethalin (Pendimethalin), cinmethylin (Cinmethylin), the third careless amine (Pretilachlor), butachlor (Butachlor), isopropyl methoxalamine (Metolachlor), Acetochlor (Acetochlor), mefenacet (Mefenacet), molinate (Molinate), atrazine (Atrazine), Sigma's piperazine (Simazine), ametryn (ametryne), Caojinjing (Cyanazine), prometryn (prometryne), isoproturon (Isoproturon), chlortoluron (Chlorotoluron), methabenzthiazuron (Methabenzthiazuron), diuron (Diuron), Gramoxone (paraquat), Brominal (Bromoxynil), make it grand (Fluroxypyr), dichloro quinolinic acid (quinclorac), 2 first, 4 chlorine (MCPA, benazolin (Benazolin-ethyl), Oxyfluorfen (Oxyfluorfen), rice thinks to reach (Oxadiargyl), phosphine oxamate (Glufosinate), glyphosate (Glyphosate), glyphosate salt; Plant growth regulator is: 6-benzylaminopurine (6-Benzylaminopurine), kinetin (Kinetin, KT), gibberellin (Gibberellic acid), 2,4-drips (2,4-Dichlorophenoxyacetic acid, 2,4-D), 2,4-D salt, brassinosteroid (Brassinolide, BR), methyl (1-Naphthylacetic acid, NAA), growth hormone (Indole-3-acetic acid, IAA), drop-proof agent (4-Chlorophenoxy acetic acid, PCPA), triacontanol (riacontanol, TRIA), ethrel (Ethephon), paclobutrazol (Paclobutrazol), compound sodium nitrophenolate (Sodium nitrophenolate, Atonik), maleic Min (Flumetralin), abscisic acid (ABA), uniconazole P (uniconazole), chlormequat (chlormequat), casing coupling peace (mepiquat-chloride), CPPU (forchlorfenuron), Thidiazuron (thidiazuron), indolebutyric acid (4-indol-3-ylbutyric acid) and indolebutyric acid salt, increase sweet phosphine (glyphosine).
7. as claim 1,2,3,4, the 5 or 6 described pesticidal preparations that contain plant vinegar liquid, it is characterized in that: described plant vinegar liquid comprises former plant vinegar liquid, handles plant vinegar liquid or concentrated plant vinegar liquid.
8. as claim 1,2,3,4,5, the 6 or 7 described pesticidal preparations that contain plant vinegar liquid, it is characterized in that: this pesticidal preparations type comprises soluble liquid, microemulsion, aqueous emulsion, suspending agent, suspended emulsion, micro-capsule suspension and sustained release agent.
CN 200610049233 2006-01-24 2006-01-24 Agricultural chemicals preparation containing pyracetic acid Pending CN1802910A (en)

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