CN1792588A - Method for mfg. bamboo plywood with high strength - Google Patents

Method for mfg. bamboo plywood with high strength Download PDF

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Publication number
CN1792588A
CN1792588A CN 200510057488 CN200510057488A CN1792588A CN 1792588 A CN1792588 A CN 1792588A CN 200510057488 CN200510057488 CN 200510057488 CN 200510057488 A CN200510057488 A CN 200510057488A CN 1792588 A CN1792588 A CN 1792588A
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bamboo
minutes
raw material
glue
cooled
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章登文
徐传明
刘兴祥
龚举平
刘刚
王建辉
李德军
李平
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CHONGQING CITY JINZHU WAGON PLATE Co Ltd
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CHONGQING CITY JINZHU WAGON PLATE Co Ltd
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Abstract

A method for manufacturing the high-strength ply-bamboo includes such steps as preparing bamboo strips, bamboo mat and bamboo curtain, baking (preheating, evaporating and cooling), immersing in adhesive, baking (preheating, evaporating and cooling), laminating, hot pressing and shaping. It has high strength and high weatherability.

Description

The manufacture method of bamboo plywood with high strength
Technical field
The invention belongs to the Manufacturing Technology of Plywood technical field, specifically, relate to a kind of manufacture method that is used as the bamboo plywood with high strength of container bottom board, auto carriage board and top-grade building template
Background technology
At present, the container bottom board on the market, auto carriage board and top-grade building template adopt full wood plywood mostly; But timber resources is greatly limited, one: the growth cycle of timber is long, needs at least just can cut down usefulness more than 30 years; Its two: countries in the world are for the needs of environmental protection and maintaining ecological balance, launch respectively limit and cut down even prohibit the policy of cutting down, and the wood supply amount is cut down greatly, cause price to rise violently thereupon.A kind of composite bamboo-timber structure glued board with bamboo wood instead of part timber appearred on the market over past ten years, but because bamboo wood is different with timber its MOR, internal stress and water absorption rate under same environment for use, quality problems in use appear easily, and the ratio that bamboo wood occupies is less, can't fundamentally solve the problem of timber resource shortage, for this reason, the glued board of full bamboo wood structure just arises at the historic moment.
At notification number is CN87100368, and the day for announcing is on August 24th, 1988, and name is called and discloses a kind of process that mao bamboon is made bamboo plywood by operations such as softening flattenings in the Chinese invention patent of " bamboo plywood manufacture method ".This method adopts the pressurization flattening process, is easy to generate the crack, thereby influences bonding strength; And do not carry out the position sorting during former bamboo blanking, because the bamboo wood density difference of different parts, the heterogeneity any combination thereof can cause thickness deviation big.The present invention exists softening flattening process route long, and energy resource consumption is big, shortcomings such as cost height.At notification number is CN2161443, the day for announcing is on April 13rd, 1994, name is called the manufacture method that also discloses a kind of bamboo plywood in the Chinese invention patent of " container bamboo plywood ", it is to dry behind the inner skin of a bamboo stem impregnation with certain width and thickness, form by HTHP curing after mould is adorned in the direction layering in length and breadth, the part process is limit by manual operations in whole process, thereby complex process, small scale, difficult quality is guaranteed, the thickness deviation of product is big, the section structure level is not clear, and the space is big, and density unevenness is even, cause the mechanical property instability, stock utilization is low.
Summary of the invention
The manufacture method that the purpose of this invention is to provide a kind of bamboo plywood with high strength, with the bamboo plywood intensity height that this method makes, good weatherability, every performance indications all are better than like product on the market.
The manufacture method of bamboo plywood with high strength of the present invention comprises the following steps:
(1) preparation of raw material bamboo sheet, bamboo mat and bamboo curtain splint, wherein bamboo chip be with fresh bamboo wood through blanking, broken bamboo, go green grass or young crops, go joint and layering machine burst to form; Bamboo mat is to form by braiding with bamboo chip; Bamboo curtain splint is that back side by side the wearing even with cotton rope of bamboo chip formed;
(2) oven dry before the glue, it is online that required raw material evenly are layered on material, and sending into dry kiln drying to moisture content is 8~16%, and its process is divided three phases: warm-up phase was preheating to 120~150 ℃ with raw material from normal temperature with 5~30 minutes; Evaporation stage is controlled at temperature between 120~150 ℃, is incubated 20~150 minutes, with transpiring moisture; Cooling stage, insulating process was cooled to raw material below 60 ℃ from evaporating temperature with 5~30 minutes after finishing;
(3) impregnation, with oven dry before the glue and be cooled to raw material below 40 ℃ to immerse solid content fully be that the impregnation time is 4~6 minutes in 20~50% the phenolic resins glue, impregnation resin content is 70~150Kg/m 3, taking-up drained 60~80 minutes, till rubber drop-free liquid;
(4) dry behind the glue, it is online that required raw material evenly are layered on material, and sending into dry kiln drying to moisture content is 10~14%, and its process is divided three phases: warm-up phase was preheating to 65~95 ℃ with raw material from normal temperature with 5~30 minutes; Evaporation stage is controlled at temperature between 65~95 ℃, is incubated 10~60 minutes, with transpiring moisture; Cooling stage, insulating process was cooled to raw material below 40 ℃ from evaporating temperature with 5~20 minutes after finishing;
(5) assembly according to the used raw-material difference of glued board surface layer, sandwich layer and backing layer, is selected one or both or three kinds in bamboo chip, bamboo mat, the bamboo curtain splint to make up to feed intake and is mated formation, and forms the gummed slab of sandwich construction;
(6) the glued board slab is sent in hot pressing when heating platen is lower than 65 ℃, its process is divided four-stage: the temperature rise period, pressure is 0.5~2Mpa, 10~25 minutes consuming time, slab is risen to 130~160 ℃; Holding stage, pressure are 1.5~3Mpa, are incubated 10~30 minutes; Cooling stage, pressure are 1.5~3Mpa, 10~25 minutes consuming time, blanket are cooled to below 65 ℃; After release, blanket are cooled to below 65 ℃, pressure progressively is released into zero, carries out release;
(7) the glued board finished product of certain size specification is processed in moulding as requested.
The surface layer of glued board, sandwich layer and backing layer all adopt bamboo wood among the present invention, and select one or both or three kinds in bamboo chip, bamboo mat, three kinds of forms of bamboo curtain splint to make up the assembly of mating formation that feeds intake, and are hot pressed into the glued board of sandwich construction.Bamboo wood can be selected the cizu that spreads all over China southwest, Mianzhu etc. for use; Adopt broken bamboo machine to break bamboo, production efficiency height, steady quality.Go green grass or young crops after the bamboo section breaks, remove joint (reservation inner membrance); In order to improve bonding strength, when going to save, tabasheer is scratched with special pressure roller, smooth, the no recovery stress of gained bamboo chip, the gummed area increases greatly; Improve the efficient of subsequent step, saved a large amount of manpower and materials.The process conditions such as time, temperature and pressure in strict each stage of control in oven dry and the hot pressing process make the every performance indications of the glued board that makes all can satisfy and exceed corresponding industry standard behind oven dry before glue, impregnation, the glue.
The manufacture craft of glued board of the present invention is simple, the stock utilization height, and most of operation can realize mechanized operation, every performance indications all are higher than the market like product; Have that intensity height, good springiness, weatherability are strong, anticorrosive, characteristics such as anti-flaming thermal-insulation, cheap, aboundresources, can be widely used in fields such as container bottom board, auto carriage board and top-grade building template.
Description of drawings
Fig. 1 is a process chart of the present invention;
Fig. 2 is the cross-sectional structure schematic diagram of embodiment 1 gained bamboo plywood;
Fig. 3 is the cross-sectional structure schematic diagram of embodiment 2 gained bamboo plywoods;
Fig. 4 is the structural representation of bamboo curtain splint 6 among Fig. 2, Fig. 3;
Fig. 5 is the structural representation of bamboo mat 5 among Fig. 2, Fig. 3.
The specific embodiment
Below in conjunction with the drawings and specific embodiments the present invention is described in further detail.
Embodiment 1:
Make a kind of bamboo plywood, this bamboo plywood is made up of surface layer 1, sandwich layer 2 and backing layer 3, and wherein surface layer 1 is stacked by five bamboo curtain splints 6 and constitutes, and sandwich layer 2 is formed by 12 bamboo mat 5 lay-ups, and backing layer 3 is stacked by five bamboo curtain splints 6 and constitutes, and its manufacturing step is:
(1) preparation of raw material bamboo sheet 4, bamboo mat 5 and bamboo curtain splint 6
Bamboo wood is selected for use and is spread all over the above cizu of China southwest life in 3 years, bamboo chip 4 be with fresh bamboo wood through blanking, broken bamboo, go green grass or young crops, remove joint and layering machine burst and make, bamboo mat 5 is to weave and form by picking up two signatures two with bamboo chip 4; Bamboo curtain splint 6 is that bamboo chip 4 is formed with cotton rope 7 companies of wearing the back side by side.Two kinds of bamboo chips 4 minutes: a kind of width is 30mm, and thickness is 0.6mm, is used on the surface layer bamboo curtain splint 6; Another kind of width is 45mm, and thickness is 1.2mm, is used for sandwich layer 2, also can be used for backing layer 3; Bamboo chip 4 width of surface layer 1 make the surface quality of surface layer 1 better less than bamboo chip 4 width of sandwich layer or backing layer 3.
(2) oven dry before the glue
It is online that required raw material evenly are layered on material, and sending into dry kiln drying to moisture content is 12%, and its process is:
1. warm-up phase was preheating to 120 ℃ with raw material from normal temperature with 25 minutes.
2. evaporation stage is controlled at 120 ℃ with temperature, is incubated 150 minutes, transpiring moisture.
3. cooling stage after the insulating process end, was cooled to 60 ℃ with 30 minutes from evaporating temperature.
(3) impregnation
With oven dry before the glue and be cooled to raw material below the 40 ℃ impregnation frame of packing into, to immerse solid content fully and be in 35% the phenolic resins glue, the impregnation time is 4 minutes, impregnation resin content is 120Kg/m 3, taking-up drained 75 minutes.This phenolic resin glue is phenol and formaldehyde by 1: 2.28 mol ratio, at pH value is under 12 the alkaline aqueous solution, to form through 85 ℃ of high temperature polymerizations, is added with Tailileum-300 (Chinese Tai Lilemu-300 by name) anticorrisive agent in the phenolic resin glue.
(4) dry behind the glue
It is online that required raw material evenly are layered on material, and sending into dry kiln drying to moisture content is 13%, and its process is:
1. warm-up phase was preheating to 80 ℃ with raw material from normal temperature with 18 minutes;
2. evaporation stage is controlled at 80 ℃ with temperature, is incubated 40 minutes, with transpiring moisture;
3. cooling stage after the insulating process end, was cooled to below 40 ℃ from evaporating temperature with 15 minutes.
(5) assembly
Five bamboo curtain splints 6 are stacked be placed on the blanket bottom, 12 bamboo mats 5 of lay-up in the above then stack five bamboo curtain splints 6 and are placed on topmost, and the glued board that forms three-decker is bad.
(6) hot pressing
Send into the glued board slab when heating platen is 65 ℃, its process is:
1. the temperature rise period, pressure is 1.2Mpa, 20 minutes consuming time, slab is risen to 145 ℃;
2. holding stage, pressure is 2.5Mpa, is incubated 30 minutes;
3. cooling stage, pressure is 2.5Mpa, 25 minutes consuming time, blanket is cooled to 65 ℃;
4. after release, blanket are cooled to 65 ℃, pressure progressively is released into zero, carries out release, divided for three steps carried out: the first step is reduced to 2Mpa from insulation pressure; In second step, be reduced to 1.2Mpa from 2Mpa; The 3rd step was reduced to zero from 1.2Mpa, and the used time in per step is 1~2 minute.
(7) moulding---as requested, be processed into the glued board of certain size specification.
The bamboo plywood of making by above processing step its every performance indications after testing is:
Density p=1.0g/cm 3, moisture content 9.8%, bonding strength 3.58Mpa, rift grain MOR 160Mpa, band MOR 50.1Mpa, modulus of elasticity parellel to grain 21810Mpa, tangential elastic module 4660Mpa, compression ratio 1: 0.7.
Embodiment 2:
Make a kind of bamboo plywood, this bamboo plywood is made up of surface layer 1, sandwich layer 2 and backing layer 3, and surface layer 1, sandwich layer 2 and backing layer 3 form by countless Zhang Zhuxi 5 even lay-ups, make according to the following step:
(1) preparation of raw material bamboo sheet 4, bamboo mat 5
Bamboo wood is selected the above cizu of lifes in 3 years that spreads all over China southwest for use.Wherein bamboo chip 4 be with fresh bamboo wood through blanking, broken bamboo, go green grass or young crops, go joint and layering machine burst to form, the preparation method of bamboo mat 5 is identical with embodiment 1, two kinds of bamboo chips 4 minutes: a kind of width is 30mm, and thickness is 0.6mm, is used for surface layer bamboo mat 5; Another kind of width is 45mm, and thickness is 1.2mm, is used for sandwich layer 2, also can be used for backing layer 3; Bamboo chip 4 width of surface layer 1 make the surface quality of surface layer 1 better less than bamboo chip 4 width of sandwich layer 2 or backing layer 3.
(2) oven dry before the glue
It is online that required raw material bamboo mat 5 evenly is layered on material, and sending into dry kiln drying to the moisture content of net belt type is 11%, and its detailed process is:
1. warm-up phase was preheating to 140 ℃ with raw material from normal temperature with 5 minutes;
2. evaporation stage is controlled at 140 ℃ with temperature, is incubated 20 minutes, transpiring moisture;
3. cooling stage after the insulating process end, was cooled to 60 ℃ with 5 minutes from evaporating temperature.
(3) impregnation
With oven dry before the glue and be cooled to raw material below the 40 ℃ impregnation frame of packing into, to immerse solid content fully and be in 35% the phenolic resins glue, the impregnation time is 4 minutes, impregnation resin content is 120Kg/m 3, taking-up drained 75 minutes.This phenolic resin glue is phenol and formaldehyde by 1: 2.28 mol ratio, is under 12 the alkaline aqueous solution at pH value, is polymerized through 85 ℃, is added with Tailileum-300 (Chinese Tai Lilemu-300 by name) anticorrisive agent in the phenolic resin glue.
(4) dry behind the glue
It is online that required raw material evenly are layered on material, and sending into dry kiln drying to the moisture content of net belt type is 13%, and its process is:
1. warm-up phase was preheating to 80 ℃ with raw material from normal temperature with 5 minutes;
2. evaporation stage is controlled at 80 ℃ with temperature, is incubated 10 minutes, with transpiring moisture;
3. cooling stage after the insulating process end, was cooled to below 40 ℃ from evaporating temperature with 5 minutes.
(5) assembly
The bamboo mat 5 of surface layer 1 is layered on the bottom, stacks the bamboo mat 5 of sandwich layer 2 then in the above successively, the bamboo mat 5 of topmost spreading backing layer 3 forms the gummed slab of three-deckers, and bamboo mat 5 adopts in length and breadth evenly braiding, and glued board is consistent in both direction intensity in length and breadth.
(6) hot pressing
Send into the glued board slab when heating platen is 65 ℃, its process is:
1. the temperature rise period, pressure is 20 minutes consuming time of 1.2Mpa, and slab is risen to 145 ℃;
2. holding stage, pressure are 2.0Mpa insulation 30 minutes;
3. cooling stage, pressure is 25 minutes consuming time of 2.0Mpa; Blanket is cooled to 65 ℃;
4. after release, blanket are cooled to 65 ℃, pressure is released into zero, carries out release, divided for three steps carried out: the first step is reduced to 1.5Mpa from insulation pressure; In second step, be reduced to 1.0Mpa from 1.5Mpa; The 3rd step was reduced to zero from 1.0Mpa, and the used time in per step is 1~2 minute.
(7) moulding---as requested, be processed into the glued board of certain size specification.
The bamboo plywood that produces by above technology its every performance indications after testing is:
Density p=0.94g/cm 3, moisture content 10%, bonding strength 3.1Mpa, MOR 107Mpa, elastic modelling quantity 13570Mpa, compression ratio 1: 0.78.
More than two embodiment listed two kinds of concrete structures, when in step (5), feeding intake assembly according to the inventive method, select one or both or three kinds in bamboo chip 4, bamboo mat 5, the bamboo curtain splint 6 to make up, also can make surface layer 1, sandwich layer 2 and backing layer 3 respectively by the bamboo plywood of 4 kinds of structures of following arrangement, be respectively: 1. bamboo chip-bamboo curtain splint-bamboo chip, 2. bamboo curtain splint-bamboo chip-bamboo curtain splint, 3. bamboo mat-bamboo curtain splint-bamboo mat, 4. bamboo mat-bamboo chip-bamboo mat.
The also available bamboo of bamboo chip 4 is fine to be replaced.

Claims (4)

1, a kind of manufacture method of bamboo plywood with high strength is characterized in that comprising the following steps:
(1) preparation of raw material bamboo sheet, bamboo mat and bamboo curtain splint, wherein bamboo chip be with fresh bamboo wood through blanking, broken bamboo, go green grass or young crops, go joint and layering machine burst to form; Bamboo mat is to form by braiding with bamboo chip; Bamboo curtain splint is that back side by side the wearing even with cotton rope of bamboo chip formed;
(2) oven dry before the glue, it is online that required raw material evenly are layered on material, and sending into dry kiln drying to moisture content is 8~16%, and its process is divided three phases: warm-up phase was preheating to 120~150 ℃ with raw material from normal temperature with 5~30 minutes; Evaporation stage is controlled at temperature between 120~150 ℃, is incubated 20~150 minutes, with transpiring moisture; Cooling stage, insulating process was cooled to raw material below 60 ℃ from evaporating temperature with 5~30 minutes after finishing;
(3) impregnation, with oven dry before the glue and be cooled to raw material below 40 ℃ to immerse solid content fully be that the impregnation time is 4~6 minutes in 20~50% the phenolic resins glue, impregnation resin content is 70~150Kg/m3, taking-up drained 60~80 minutes, till rubber drop-free liquid;
(4) dry behind the glue, it is online that required raw material evenly are layered on material, and sending into dry kiln drying to moisture content is 10~14%, and its process is divided three phases: warm-up phase was preheating to 65~95 ℃ with raw material from normal temperature with 5~30 minutes; Evaporation stage is controlled at temperature between 65~95 ℃, is incubated 10~60 minutes, with transpiring moisture; Cooling stage, insulating process was cooled to raw material below 40 ℃ from evaporating temperature with 5~20 minutes after finishing;
(5) assembly according to the used raw-material difference of glued board surface layer, sandwich layer and backing layer, is selected one or both or three kinds in bamboo chip, bamboo mat, the bamboo curtain splint to make up to feed intake and is mated formation, and forms the gummed slab of sandwich construction;
(6) the glued board slab is sent in hot pressing when heating platen is lower than 65 ℃, its process is divided four-stage: the temperature rise period, pressure is 0.5~2Mpa, 10~25 minutes consuming time, slab is risen to 130~160 ℃; Holding stage, pressure are 1.5~3Mpa, are incubated 10~30 minutes; Cooling stage, pressure are 1.5~3Mpa, 10~25 minutes consuming time, blanket are cooled to below 65 ℃; After release, blanket are cooled to below 65 ℃, pressure progressively is released into zero, carries out release;
(7) the glued board finished product of certain size specification is processed in moulding as requested.
2, the manufacture method of bamboo plywood with high strength according to claim 1 is characterized in that bamboo wood selected in the step (1) is cizu or Mianzhu, and the width of bamboo chip is 30~50mm, and thickness is 0.5~1.3mm.
3, the manufacture method of bamboo plywood with high strength according to claim 1, it is characterized in that release divided for three steps carried out in the step (6): the first step is reduced to 2.0~1.5Mpa from insulation pressure; In second step, be reduced to 1.5~1.0Mpa from 2.0~1.5Mpa; The 3rd step was reduced to zero from 1.5~1.0Mpa, and the used time in per step is 1~2 minute.
4, the manufacture method of bamboo plywood with high strength according to claim 1, it is characterized in that used phenolic resin glue in the step (3) is phenol and formaldehyde by 1: 2.28 mol ratio, be under 12 the alkaline aqueous solution, to form at pH value through 85 ℃ high temperature polymerizations.
CN 200510057488 2005-12-31 2005-12-31 Method for mfg. bamboo plywood with high strength Pending CN1792588A (en)

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Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101830017A (en) * 2010-04-29 2010-09-15 苏悦东 Manufacture method of colored texture bamboo board
CN102166861A (en) * 2010-12-28 2011-08-31 湖南恒盾集团有限公司 Preparation method of bamboo batten-reinforced bamboo plastic composite material
CN102335936A (en) * 2011-09-28 2012-02-01 浙江农林大学 Method for preparing bamboo curtain plywood formwork
CN102581913A (en) * 2012-02-28 2012-07-18 福建农林大学 Method for making fully-closed nonhazardous bamboo chopping board with flattened bamboo
CN101181789B (en) * 2007-12-07 2012-09-05 上海星嘉诺华材料科技有限公司 Wood-plastic profiles and manufacturing method therefor
CN102669939A (en) * 2012-06-03 2012-09-19 罗爱国 Bamboo dining table board and manufacturing method thereof
CN102744760A (en) * 2012-07-12 2012-10-24 福建篁城科技竹业有限公司 Bamboo plate manufacturing process
CN103317583A (en) * 2013-06-24 2013-09-25 贵州新锦竹木制品有限公司 Method for manufacturing bamboo chopping board
CN104308943A (en) * 2014-10-13 2015-01-28 苏州东邦家具有限公司 Green and environment-friendly bamboo fiber furniture
CN104760097A (en) * 2015-04-10 2015-07-08 福建和其昌竹业有限公司 Manufacturing method of full bamboo or wood or bamboo-wood mixing scrimber composite board with trimming materials participating
CN105235048A (en) * 2015-09-25 2016-01-13 华南农业大学 High-performance wood composite material and preparation method and application thereof
CN108145826A (en) * 2018-01-30 2018-06-12 江西鼎宏生物科技有限公司 Utilize the method for bamboo making iron Dan Mu
CN108772923A (en) * 2018-06-06 2018-11-09 浙江亮月板业有限公司 A kind of production technology of high intensity bamboo shaving board
CN109465942A (en) * 2018-10-19 2019-03-15 湖南桃花江竹材科技股份有限公司 The high-strength bamboo matter composite wood in 3 D stereo surface and its manufacturing method
CN113664950A (en) * 2021-08-20 2021-11-19 广东省林业科学研究院 Full-bamboo container bottom plate and manufacturing method thereof

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101181789B (en) * 2007-12-07 2012-09-05 上海星嘉诺华材料科技有限公司 Wood-plastic profiles and manufacturing method therefor
CN101830017A (en) * 2010-04-29 2010-09-15 苏悦东 Manufacture method of colored texture bamboo board
CN102166861A (en) * 2010-12-28 2011-08-31 湖南恒盾集团有限公司 Preparation method of bamboo batten-reinforced bamboo plastic composite material
CN102335936B (en) * 2011-09-28 2014-03-19 浙江农林大学 Method for preparing bamboo curtain plywood formwork
CN102335936A (en) * 2011-09-28 2012-02-01 浙江农林大学 Method for preparing bamboo curtain plywood formwork
CN102581913A (en) * 2012-02-28 2012-07-18 福建农林大学 Method for making fully-closed nonhazardous bamboo chopping board with flattened bamboo
CN102669939A (en) * 2012-06-03 2012-09-19 罗爱国 Bamboo dining table board and manufacturing method thereof
CN102744760A (en) * 2012-07-12 2012-10-24 福建篁城科技竹业有限公司 Bamboo plate manufacturing process
CN103317583A (en) * 2013-06-24 2013-09-25 贵州新锦竹木制品有限公司 Method for manufacturing bamboo chopping board
CN104308943A (en) * 2014-10-13 2015-01-28 苏州东邦家具有限公司 Green and environment-friendly bamboo fiber furniture
CN104760097A (en) * 2015-04-10 2015-07-08 福建和其昌竹业有限公司 Manufacturing method of full bamboo or wood or bamboo-wood mixing scrimber composite board with trimming materials participating
CN105235048A (en) * 2015-09-25 2016-01-13 华南农业大学 High-performance wood composite material and preparation method and application thereof
CN108145826A (en) * 2018-01-30 2018-06-12 江西鼎宏生物科技有限公司 Utilize the method for bamboo making iron Dan Mu
CN108772923A (en) * 2018-06-06 2018-11-09 浙江亮月板业有限公司 A kind of production technology of high intensity bamboo shaving board
CN109465942A (en) * 2018-10-19 2019-03-15 湖南桃花江竹材科技股份有限公司 The high-strength bamboo matter composite wood in 3 D stereo surface and its manufacturing method
CN109465942B (en) * 2018-10-19 2022-06-07 湖南桃花江竹材科技股份有限公司 Three-dimensional stereo surface high-strength bamboo composite material and manufacturing method thereof
CN113664950A (en) * 2021-08-20 2021-11-19 广东省林业科学研究院 Full-bamboo container bottom plate and manufacturing method thereof

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