CN102166861A - Preparation method of bamboo batten-reinforced bamboo plastic composite material - Google Patents
Preparation method of bamboo batten-reinforced bamboo plastic composite material Download PDFInfo
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- CN102166861A CN102166861A CN2010106099493A CN201010609949A CN102166861A CN 102166861 A CN102166861 A CN 102166861A CN 2010106099493 A CN2010106099493 A CN 2010106099493A CN 201010609949 A CN201010609949 A CN 201010609949A CN 102166861 A CN102166861 A CN 102166861A
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Abstract
The invention belongs to the technical field of a bamboo plastic composite material, and in particular relates to a preparation method of a bamboo batten-reinforced bamboo plastic composite material. The method comprises the steps of: taking a pretreated bamboo batten as a reinforcing material and a filling material; laminating the bamboo batten by means of one lengthways layer and one traverse layer; clamping a layer of bamboo plastic waste composite sheet material between two layers of bamboo battens; repairing and filling; leading a plurality of layers to form a blank; and leading the two bamboo battens into a novel bamboo plastic composite board and a bamboo plastic composite section by the thermoplastic fusion characteristic of thermoplastic plastics and the thermoplasticity of a lignin in the waste material processed by bamboo under the condition that the adhesive is not used. The preparation method can be widely used for preparing a bamboo plastic composite building template, a bamboo plastic composite pallet product, a bamboo plastic composite building material, an outdoor furniture product and the like, thereby being low in cost, environment-friendly, large in width, high in intensity, attractive in surface, and easy to machine.
Description
Technical field
The invention belongs to bamboo-plastic combined material technical field, be specifically related to the manufacture method that a kind of bamboo chip strengthens bamboo-plastic combined material.
Background technology
Wood plastic composite normally utilizes wood particulate or wood powder to join and makes filler in the plastics, produce various goods or section bar by the mode of mold pressing.The North America is the area that Wood-plastic material is with fastest developing speed in the world, consumption is maximum, is mainly used in the rough outdoor building of style.U.S. Wood-plastic material market growth rate in 1990 to 2000 is all more than 10%, increased in nearly 5 years outstanding fast, U.S. existing about 50 tame Wood-plastic material enterprise, annual production is mostly more than ten thousand tons, wherein Zui Da several companies go on the market in the New York Stock Exchange.The Wood-plastic material research and development institution of the U.S. also surpasses 50 families, has formed an entire industries of producing the marketing from research and development of products, raw material collection, device fabrication, mould development, manufactured goods.Europe Wood-plastic material industry overall development is not so good as north America region, but quickening trend is arranged in recent years, and its Wood-plastic material enterprise is few, and output and technical merit and domestic enterprise are suitable, but it has powerful equipment manufacturing capacity, and development potentiality can't neglect.The European is relatively finer and smoother to the requirement of Wood-plastic material, and the demand of variety design also is higher than the North America, and interior decoration decoration and outdoor building are flush goes forward side by side near 100,000 tons, but application technology and commodity market are also very ripe, and the space of rapid growth is arranged.
Japan is owing to geographical reason and environmental consciousness, and the application of Wood-plastic material is commonplace, and product quality is also better.With EIN WOOD Co., Ltd. is the Wood-plastic material research institution of representative, develops high-quality Wood-plastic material through the effort of more than ten years.Its product has the timber color and luster and the texture of nature, is used widely in building construction and interior decoration field, has represented Wood-plastic material to substitute the quality level and the developing direction of natural timber.
Under the dual promotion of the encouragement of national circular economy policy and enterprise's potential benefit demand, national " Wood-plastic material heat " rises gradually.According to incompletely statistics, by the end of the year in 2005, the whole nation directly or indirectly was engaged in Wood-plastic material research and development, production and supporting enterprises and institutions and has been exceeded 150 families, comprises state-owned, private, individual proprietorship, plying and polytype such as joint, state-owned or state-holding enterprise occupies certain advantage.Existing Wood-plastic material industry practitioner tens of thousands of people, wood plastic product year volume of production and marketing annual value of production above 800,000,000 yuans.The Wood-plastic material concentration of enterprises is distributed in Pearl River Delta and Yangtze River Delta Area, the east considerably beyond in, western part.The indivedual enterprises in east technological level is comparatively leading, and southern enterprise then occupies the absolute predominance in product quantity and market.
Domestic research to the bamboo-plastic composite material aspect has also obtained certain progress, but most work, still need further be worked from practicality and commercial angle just at laboratory stage.Less to the Study on Compatibility of bamboo-plastic combined processing technology, bamboo fibre and plastics both at home and abroad, especially do not see relevant report as yet with the research of bamboo processing discarded object and plastic refuse production complex architectural template or bamboo-plastic combined pallet product.
Summary of the invention
The object of the present invention is to provide the manufacture method of a kind of environmentally friendly, function admirable, bamboo-plastic composite material that production cost is low.Bamboo-plastic composite material of the present invention, its structure are to be combined into composite board and composite material that slab mold pressing make through preliminary treatment by certain product structure by bamboo-plastic combined sheet material of several layers and bamboo chip curtain.
Bamboo chip of the present invention strengthens the manufacture method of bamboo-plastic combined material, comprises the step of following order:
(1) bamboo is moulded the preparation of discarded object mixing sheet material:
(a) adopt common beating crusher with bamboo industrial wood waste processing well-thought-out plan particle, the bamboo particle is long to be 2mm ~ 10mm, and wide is 0.8 ~ 5mm;
(b) the bamboo particle is done to add the surface treatment of coupling agent;
(c) bamboo particle and the hot-melt plastic after adopting rubber mixing machine with surface treatment is mixing, and bamboo is moulded mixed proportion and is: 4:6 ~ 7:3;
(d) adopt common pulverizer with previous step evenly mixing and bamboo mould the compound of discarded object, be broken into graininess;
(e) but the hybrid particles that the bamboo of previous step gained is moulded discarded object sent into the water-cooling type hot press be hot pressed into sheet material, sheet thickness is about 3mm, its hot pressing pressure is controlled at 1.0 ~ 2.8MPa, hot pressing temperature is controlled at 115 ℃ ~ 155 ℃, hot pressing time be controlled at 1 millimeter 1 ~ 1.5 minute, cooling water temperature is controlled at 10 ℃ ~ 25 ℃;
(2) preparation of bamboo chip curtain:
(a) adopt common shear and cut open the bamboo machine bamboo chip is processed into thickness is that 0.5mm ~ 5mm, length are that 1350 ~ 2630 mm, width are the bamboo chip of 5 ~ 20 mm;
(b) open dovetail groove on the bamboo chip surface, remove surf green and tabasheer simultaneously;
(c) adopt mode that manual or machinery knits curtain that the bamboo chip of previous step gained is made into the curtain shape, warp adopts the union twist yarn of diameter 0.05mm ~ 0.5mm, and the spacing between the warp is not more than 200mm;
(d) handle bamboo chip curtain surface with bamboo-plastic combined interface coupling agent;
(e) with previous step gained bamboo chip curtain in drying box to be lower than 100 ℃ temperature drying 5 ~ 15 minutes;
(3) with the horizontal lamination of dried vertical one deck of bamboo chip curtain one deck of step (2) gained, two-layer between folder one deck step (1) gained bamboo mould discarded object mixing sheet material, be combined into slab;
(4) but the slab of previous step gained is adopted the mold pressing of water-cooling type hot press, hot pressing pressure is controlled at 1.0 ~ 2.8MPa, hot pressing temperature is controlled at 115 ℃ ~ 155 ℃, hot pressing time be controlled at 1 millimeter 1 ~ 1.5 minute, cooling water temperature is controlled at 10 ℃ ~ 25 ℃.
Specifically, described hot-melt plastic comprises one or more in polyethylene, polypropylene, polyvinyl chloride, polystyrene, the ABS waste plastics recycling pellet.
Bamboo-plastic composite material of the present invention can be widely used in bamboo-plastic combined building template and bamboo-plastic combined pallet product, bamboo-plastic combined construction timber and outdoor furniture goods, and has following beneficial effect:
(1) this product is the circle bamboo to be cutd open be processed into bamboo chip, then bamboo chip laterally is arranged in parallel, is woven into curtain, moulds mixing with bamboo and sheet material that make is combined into composite board and the composite material that the slab mold pressing makes by certain product structure.The bamboo-plastic combined material intensity of this enhancement mode and mixing pattern is higher than existing wood/bamboo-plastic combined material.
(2) the cost plastics use amount that is significantly higher than bamboo wood can be controlled in the 27-34% scope, and more traditional wood and plastic composite plastics use amount can reduce about 20%, and applying to large-scale production can significantly reduce cost.
(3) primary raw material is the bamboo industrial wood waste, be beneficial to and make full use of the bamboo processing discarded object, can prevent excessive exploitation to the forest reserves, thereby help stabilization of environment, simultaneously can partly eliminate the white pollution that plastic refuse brings, turn waste into wealth, slow down pressure, meet China's strategy of sustainable development environment.
(4) the bamboo-plastic combined interface coupling agent that uses Sino-South African Forestry University of Science and Technology's bamboo wood industrial research to be developed by bamboo processing discarded object and plastic refuse are carried out preliminary treatment, improves the compatibility and the adhesion at both interfaces.
(5) utilize the thermoplasticity of lignin in the thermoplastic fusion characteristic of thermoplastic and the bamboo processing discarded object, do not applying under the adhesive condition, make both be combined into a kind of novel bamboo-plastic composite material by adding coupling agent.Make the formaldehydeless release of product, to human body and environmental friendliness.
(6), better remove the surf green tabasheer on the one hand by opening dovetail groove on reinforcing material bamboo chip surface; Utilize the semi-fluid condition of plastics after being heated to flow in the groove on the other hand, fill up the groove internal pore, make both after the cooling in conjunction with firm.
(7) this product breadth is big, intensity is high, surface aesthetic, but can saw, can dig, can bore mortise, has the good characteristics of processing characteristics.
Description of drawings
Fig. 1 is a process chart of the present invention.
The specific embodiment
The invention will be further described below in conjunction with drawings and Examples.
Shown in Figure 1 is process chart of the present invention.
Embodiment 1:
Be used for the manufacturing of the bamboo-plastic combined material of bamboo-plastic combined building template and bamboo-plastic combined pallet:
One, bamboo is moulded the manufacturing of discarded object mixing sheet material:
(1) selection: bamboo wood adopts the factory process residue of low-quality, and hot-melt plastic adopts polyethylene.(2) preparation of bamboo particle: adopt common beating crusher with bamboo industrial wood waste processing well-thought-out plan particle, the bamboo particle requires tiny slightly, can not be too slightly long, and long is 2mm~10mm, wide is 0.8 ~ 5mm.(3) mixing: as to adopt rubber mixing machine that bamboo particle and plastic milling after the coupling agent treatment are made to add in the surface, require bamboo to mould and mix, charge ratio 4:6.(4) pulverize: adopt common pulverizer that even bamboo is moulded the compound of discarded object, be broken into graininess.(5) bamboo is moulded the preparation of discarded object sheet material: the hybrid particles that bamboo is moulded discarded object is sent into hot press and is hot pressed into sheet material, required thickness is about 3mm, its hot pressing pressure is controlled at 1.0MPa, hot pressing temperature is controlled at 155 ℃, hot pressing time be controlled at one millimeter 1 minute, cooling water temperature is controlled at 10 ℃, but equipment adopts the water-cooling type hot press.
Two, the manufacturing of bamboo chip curtain:
(1) processing of bamboo chip: adopt manual mode or utilization to cut open the bamboo machine and bamboo wood is blocked be processed into thickness, can adopt common shear and cut open the bamboo machine for 0.5mm, length are that 1350 mm, width are the bamboo chip of 5 mm.(2) fluting of bamboo chip: at bamboo chip surface fluting, form dovetail groove, with better removal surf green tabasheer and better be beneficial to and the combining of plastics.(3) knit curtain: bamboo chip craft or machinery are knitted curtain, and warp adopts the union twist yarn of diameter 0.05mm, and the spacing between the warp is not more than 200mm.
Three, composite plate manufacturing:
(1) preliminary treatment of bamboo chip: handle bamboo chip curtain surface with bamboo-plastic combined interface coupling agent.(2) bamboo chip drying: in drying box to be lower than 100 ℃ temperature drying 5 minutes.(3) assembly: with the horizontal one deck lamination of the vertical one deck of bamboo chip curtain after the drying, two-layer bamboo chip curtain therebetween one deck bamboo is moulded discarded object mixing sheet material, is combined into slab by product structure.(4) mold pressing: but adopt the water-cooling type hot press with the slab mold pressing, hot pressing pressure is controlled at 1.0MPa, hot pressing temperature is controlled at 155 ℃, hot pressing time be controlled at one millimeter 1 minute, cooling water temperature is controlled at 10 ℃.(5) check grades: carry out the check of surface quality and inherent quality according to the requirement of quality standard, grade according to assay.(6) packing: pack respectively according to the sheet material after grading, put in storage behind its correlating markings of sticker.
Embodiment 2:
Be used for the manufacturing of the bamboo-plastic combined material of bamboo-plastic combined building template and bamboo-plastic combined pallet:
One, bamboo is moulded the manufacturing of discarded object mixing sheet material:
(1) selection: bamboo wood adopts the factory process residue of low-quality, and hot-melt plastic adopts polyethylene, polypropylene, polyvinyl chloride and polystyrene.(2) preparation of bamboo particle: adopt common beating crusher with bamboo industrial wood waste processing well-thought-out plan particle, the bamboo particle requires tiny slightly, can not be too slightly long, and long is 2mm~10mm, wide is 0.8 ~ 5mm.(3) mixing: as to adopt rubber mixing machine that bamboo particle and plastic milling after the coupling agent treatment are made to add in the surface, require bamboo to mould and mix, charge ratio 5:5.(4) pulverize: adopt common pulverizer that even bamboo is moulded the compound of discarded object, be broken into graininess.(5) bamboo is moulded the preparation of discarded object sheet material: the hybrid particles that bamboo is moulded discarded object is sent into hot press and is hot pressed into sheet material, required thickness is about 3mm, its hot pressing pressure is controlled at 2.8MPa, hot pressing temperature is controlled at 115 ℃, hot pressing time be controlled at one millimeter 1.5 minutes, cooling water temperature is controlled at 25 ℃, but equipment adopts the water-cooling type hot press.
Two, the manufacturing of bamboo chip curtain:
(1) processing of bamboo chip: adopt manual mode or utilization to cut open the bamboo machine and bamboo wood is blocked be processed into thickness, can adopt common shear and cut open the bamboo machine for 5mm, length are that 2630 mm, width are the bamboo chip of 20 mm.(2) fluting of bamboo chip: at bamboo chip surface fluting, form dovetail groove, with better removal surf green tabasheer and better be beneficial to and the combining of plastics.(3) knit curtain: bamboo chip craft or machinery are knitted curtain, and warp adopts diameter
0.5mm union twist yarn, the spacing between the warp is not more than 200mm.
Three, composite plate manufacturing:
(1) preliminary treatment of bamboo chip: handle bamboo chip curtain surface with bamboo-plastic combined interface coupling agent.(2) bamboo chip drying: in drying box to be lower than 100 ℃ temperature drying 15 minutes.(3) assembly: with the horizontal one deck lamination of the vertical one deck of bamboo chip curtain after the drying, two-layer bamboo chip curtain therebetween one deck bamboo is moulded discarded object mixing sheet material, is combined into slab by product structure.(4) mold pressing: but adopt the water-cooling type hot press with the slab mold pressing, hot pressing pressure is controlled at 2.8MPa, hot pressing temperature is controlled at 115 ℃, hot pressing time be controlled at one millimeter 1.5 minutes, cooling water temperature is controlled at 25 ℃.(5) check grades: carry out the check of surface quality and inherent quality according to the requirement of quality standard, grade according to assay.(6) packing: pack respectively according to the sheet material after grading, put in storage behind its correlating markings of sticker.
Embodiment 3:
Be used for the manufacturing of the bamboo-plastic combined material of bamboo-plastic combined building template and bamboo-plastic combined pallet:
One, bamboo is moulded the manufacturing of discarded object mixing sheet material:
(1) selection: bamboo wood adopts the factory process residue of low-quality, and hot-melt plastic adopts polyethylene and ABS waste plastics recycling pellet.(2) preparation of bamboo particle: adopt common beating crusher with bamboo industrial wood waste processing well-thought-out plan particle, the bamboo particle requires tiny slightly, can not be too slightly long, and long is 2mm~10mm, wide is 0.8 ~ 5mm.(3) mixing: as to adopt rubber mixing machine that bamboo particle and plastic milling after the coupling agent treatment are made to add in the surface, require bamboo to mould and mix, charge ratio 7:3.(4) pulverize: adopt common pulverizer that even bamboo is moulded the compound of discarded object, be broken into graininess.(5) bamboo is moulded the preparation of discarded object sheet material: the hybrid particles that bamboo is moulded discarded object is sent into hot press and is hot pressed into sheet material, required thickness is about 3mm, its hot pressing pressure is controlled at 2.0MPa, hot pressing temperature is controlled at 140 ℃, hot pressing time be controlled at one millimeter 1.2 minutes, cooling water temperature is controlled at 18 ℃, but equipment adopts the water-cooling type hot press.
Two, the manufacturing of bamboo chip curtain:
(1) processing of bamboo chip: adopt manual mode or utilization to cut open the bamboo machine and bamboo wood is blocked be processed into thickness, can adopt common shear and cut open the bamboo machine for 2.5mm, length are that 1800 mm, width are the bamboo chip of 15 mm.(2) fluting of bamboo chip: at bamboo chip surface fluting, form dovetail groove, with better removal surf green tabasheer and better be beneficial to and the combining of plastics.(3) knit curtain: bamboo chip craft or machinery are knitted curtain, and warp adopts diameter
0.2mm union twist yarn, the spacing between the warp is not more than 200mm.
Three, composite plate manufacturing:
(1) preliminary treatment of bamboo chip: handle bamboo chip curtain surface with bamboo-plastic combined interface coupling agent.(2) bamboo chip drying: in drying box to be lower than 100 ℃ temperature drying 10 minutes.(3) assembly: with the horizontal one deck lamination of the vertical one deck of bamboo chip curtain after the drying, two-layer bamboo chip curtain therebetween one deck bamboo is moulded discarded object mixing sheet material, is combined into slab by product structure.(4) mold pressing: but adopt the water-cooling type hot press with the slab mold pressing, hot pressing pressure is controlled at 2.0MPa, hot pressing temperature is controlled at 140 ℃, hot pressing time be controlled at one millimeter 1.2 minutes, cooling water temperature is controlled at 18 ℃.(5) check grades: carry out the check of surface quality and inherent quality according to the requirement of quality standard, grade according to assay.(6) packing: pack respectively according to the sheet material after grading, put in storage behind its correlating markings of sticker.
Embodiment 4:
The manufacturing technology steps that is used for the bamboo-plastic combined material of bamboo-plastic combined construction timber and outdoor furniture goods is:
One, bamboo is moulded the manufacturing of discarded object mixing sheet material:
Described identical with embodiment 1.
Two, the manufacturing of bamboo chip curtain:
Described identical with embodiment 1.
Three, composite plate manufacturing:
(1) preliminary treatment of bamboo chip: handle bamboo chip curtain surface with bamboo-plastic combined interface coupling agent.(2) bamboo chip drying: in drying box to be lower than 100 ℃ temperature drying 5 minutes.(3) assembly: with the horizontal one deck lamination of the vertical one deck of bamboo chip curtain after the drying, two-layer bamboo chip curtain therebetween one deck bamboo is moulded discarded object mixing sheet material, is combined into slab by product structure.(4) mold pressing: but adopt the water-cooling type hot press with the slab mold pressing, hot pressing pressure is controlled at 1.0MPa, hot pressing temperature is controlled at 155 ℃, hot pressing time be controlled at one millimeter 1 minute, cooling water temperature is controlled at 10 ℃, but equipment adopts the water-cooling type hot press.(5) mold pressing again: because the specification of construction timber and furniture woods is bigger, utilize the thermoplasticity of plastics, the bamboo-plastic combined plate compound suppressing that several mold pressings just can be obtained becomes the section bar of big specification, hot pressing pressure is controlled at 1.0MPa, hot pressing temperature is controlled at 155 ℃, hot pressing time be controlled at one millimeter 1 minute, cooling water temperature is controlled at 10 ℃, but equipment adopts the water-cooling type hot press.(6) check grades: carry out the check of surface quality and inherent quality according to the requirement of quality standard, grade according to assay.(7) packing: pack respectively according to the sheet material after grading, put in storage behind its correlating markings of sticker.
Claims (2)
1. a bamboo chip strengthens the manufacture method of bamboo-plastic combined material, it is characterized in that comprising the step of following order:
(1) bamboo is moulded the preparation of discarded object mixing sheet material:
(a) adopt common beating crusher with bamboo industrial wood waste processing well-thought-out plan particle, the bamboo particle is long to be 2mm ~ 10mm, and wide is 0.8 ~ 5mm;
(b) the bamboo particle is done to add the surface treatment of coupling agent;
(c) bamboo particle and the hot-melt plastic after adopting rubber mixing machine with surface treatment is mixing, and bamboo is moulded mixed proportion and is: 4:6 ~ 7:3;
(d) adopt common pulverizer with previous step evenly mixing and bamboo mould the compound of discarded object, be broken into graininess;
(e) but the hybrid particles that the bamboo of previous step gained is moulded discarded object sent into the water-cooling type hot press be hot pressed into sheet material, sheet thickness is about 3mm, its hot pressing pressure is controlled at 1.0 ~ 2.8MPa, hot pressing temperature is controlled at 115 ℃ ~ 155 ℃, hot pressing time be controlled at 1 millimeter 1 ~ 1.5 minute, cooling water temperature is controlled at 10 ℃ ~ 25 ℃;
(2) preparation of bamboo chip curtain:
(a) adopt common shear and cut open the bamboo machine bamboo chip is processed into thickness is that 0.5mm ~ 5mm, length are that 1350 ~ 2630 mm, width are the bamboo chip of 5 ~ 20 mm;
(b) open dovetail groove on the bamboo chip surface, remove surf green and tabasheer simultaneously;
(c) adopt mode that manual or machinery knits curtain that the bamboo chip of previous step gained is made into the curtain shape, warp adopts the union twist yarn of diameter 0.05mm ~ 0.5mm, and the spacing between the warp is not more than 200mm;
(d) handle bamboo chip curtain surface with bamboo-plastic combined interface coupling agent;
(e) with previous step gained bamboo chip curtain in drying box to be lower than 100 ℃ temperature drying 5 ~ 15 minutes;
(3) with the horizontal lamination of dried vertical one deck of bamboo chip curtain one deck of step (2) gained, two-layer between folder one deck step (1) gained bamboo mould discarded object mixing sheet material, be combined into slab;
(4) but the slab of previous step gained is adopted the mold pressing of water-cooling type hot press, hot pressing pressure is controlled at 1.0 ~ 2.8MPa, hot pressing temperature is controlled at 115 ℃ ~ 155 ℃, hot pressing time be controlled at 1 millimeter 1 ~ 1.5 minute, cooling water temperature is controlled at 10 ℃ ~ 25 ℃.
2. bamboo chip according to claim 1 strengthens the manufacture method of bamboo-plastic combined material, it is characterized in that: described hot-melt plastic comprises one or more in polyethylene, polypropylene, polyvinyl chloride, polystyrene, the ABS waste plastics recycling pellet.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108724412A (en) * | 2018-05-31 | 2018-11-02 | 浙江亮月板业有限公司 | A method of using giving up, bamboo cane prepares Bamboo plastic plate |
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Application publication date: 20110831 |