CN1751840A - Sintering welding agent for repairing tube mould, and its mfg. method - Google Patents

Sintering welding agent for repairing tube mould, and its mfg. method Download PDF

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Publication number
CN1751840A
CN1751840A CN 200510047561 CN200510047561A CN1751840A CN 1751840 A CN1751840 A CN 1751840A CN 200510047561 CN200510047561 CN 200510047561 CN 200510047561 A CN200510047561 A CN 200510047561A CN 1751840 A CN1751840 A CN 1751840A
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CN
China
Prior art keywords
ferro
molybdenum
agent
titanium
tube mould
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CN 200510047561
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Chinese (zh)
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CN100374239C (en
Inventor
陈娟娟
陈昱宏
陈元元
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Individual
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Priority to CNB2005100475618A priority Critical patent/CN100374239C/en
Publication of CN1751840A publication Critical patent/CN1751840A/en
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Publication of CN100374239C publication Critical patent/CN100374239C/en
Expired - Fee Related legal-status Critical Current
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Abstract

A sinter welding flux for repairing pipe mould is proportionally prepared from Al2O3, magnesium oxide, calcium oxide, SiO2, calcium fluoride, MnFe alloy, Cr or CrFe alloy, MoFe alloy, Ni and TiFe alloy through proportional mixing, adding water, stirring, granulating, baking and sieving. Its advantages are high resistance to thermal cracking, wear and oxidizing and low linear expansibility.

Description

Sintered flux that agent for repairing tube mould is used and manufacture method thereof
Technical field
The invention belongs to field of welding material, the sintered flux that particularly a kind of agent for repairing tube mould is used is used for whole built-up welding agent for repairing tube mould.
Background technology
Pipe die is the main tool that centrifugal casting machine is produced large-scale cast tube.Produce in the process of large-scale cast tube at centrifugal casting machine, pipe die is worked under hot conditions repeatedly.The pipe die of working under mal-condition like this wall within it forms a large amount of fire checks (be full of cracks) and damages, and is a kind of rapid wear material therefore, its consumption very big (every new pipe die is worth ten thousand yuan of 40-50).In order to reduce production costs, increase economic efficiency, adopt whole technique for overlaying that it is repaired, for using repeatedly.With overlaying method pipe die being carried out integral body reparation, except having the proper tools, mainly is to make overlay cladding can satisfy the job requirement of pipe die with suitable solder flux, and special-purpose sintered flux just will be arranged.
Summary of the invention
The purpose of this invention is to provide sintered flux and manufacture method thereof that a kind of agent for repairing tube mould is used.
The objective of the invention is to realize by following technical proposals.
According to the sintered flux that agent for repairing tube mould of the present invention is used, it is characterized in that being formed by following components in weight percentage:
Alundum (Al 5-25
Magnesia 15-35
Calcium oxide 3-15
Silica 7-18
Calcirm-fluoride 15-35
Manganeisen 2-16
Chromium or ferrochrome 3-9
Ferro-molybdenum 0.6-1.5
Nickel 0.1-0.6
Ferro-titanium 2-6.
Preferred following components in weight percentage:
Alundum (Al 14-16
Magnesia 24-26
Calcium oxide 7-8
Silica 1 2-13
Calcirm-fluoride 21-24
Manganeisen 3-5
Ferrochrome 5-8
Ferro-molybdenum 0.8-1.2
Nickel 0.2-0.5
Ferro-titanium 3-5.
When adopting ferrochrome, preferred following components in weight percentage:
Alundum (Al 14-16
Magnesia 24-26
Calcium oxide 7-8
Silica 1 2-13
Calcirm-fluoride 21-24
Manganeisen 3-5
Ferrochrome 5-8
Ferro-molybdenum 0.8-1.2
Nickel 0.2-0.5
Ferro-titanium 3-5.
Described manganeisen is the mid-carbon fe-mn alloy that contains manganese 75-85%, described ferrochrome is that chrome content is the ferrochrome of 68-75%, described ferro-molybdenum is to contain the ferro-molybdenum that the molybdenum amount is 55-65%, and described ferro-titanium is the ferro-titanium of 25-35% for the titaniferous amount.
The manufacture method of the sintered flux that agent for repairing tube mould of the present invention is used is characterized in that comprising the following steps:
1) described various component raw material are carried out quality inspection,
2) prepare burden according to described components by weight,
3) carry out batch mixing, do earlier and mix, carry out wet mixing for the water of 20-30% at adding raw material weight ratio,
4) granulation on comminutor produces the circular granular that granularity is 2.0-0.28mm,
5) under 600-750 ℃ of temperature, dry,
6) sieve the back with the 10-60 mesh sieve and obtain lark finished product sintered flux.
With the pipe die that the sintered flux of agent for repairing tube mould of the present invention is repaired, use through repeatedly practising test, the result shows that it has following characteristics:
1, heat crack resistance is good;
2, have good abrasion resistance and antioxygenic property;
3, linear expansion coefficient is little;
4, cracking and distortion tendency are little.
Therefore be the sintered flux that a kind of agent for repairing tube mould that promotional value arranged is used very much.
Assay proves, with the resulting deposited metal composition of sintered flux built-up welding of the present invention be: carbon≤0.12%, manganese are 0.4-0.8%, and silicon is 0.40-0.80%, chromium is 2.0-3.0%, molybdenum is 0.30-0.60%, and nickel is about 0.10%, copper about 0.10%, titanium about 0.10%, sulphur≤0.03, phosphorus≤0.03, surplus is an iron.Sulphur wherein, copper, phosphorus are from the minimal residue in the various ferroalloys.
The specific embodiment
With embodiment the specific embodiment of the present invention is described below.
Embodiment 1
The sintered flux that agent for repairing tube mould is used, formed by following components in weight percentage:
Alundum (Al 15
Magnesia 25
Calcium oxide 8
Silica 12
Calcirm-fluoride 25
The manganeisen 4.5 of manganese content 80%
Chromium 5.0
The ferro-molybdenum 1.2 that contains molybdenum amount 60%
Nickel 0.3
The ferro-titanium 4 of titaniferous amount 30%.
The material of said components is done the water that mixes back adding 20-30% mix the back granulation, under 600-750 ℃ of temperature, dry, sieve, obtain qualified finished product through check with 10-60 mesh sieve.
Embodiment 1
The sintered flux that agent for repairing tube mould is used, formed by following components in weight percentage:
Alundum (Al 18
Magnesia 25
Calcium oxide 7
Silica 13
Calcirm-fluoride 22
The mid-carbon fe-mn 4.0 of manganese content 80%
The ferrochrome 6.0 that contains chromium 72%
The ferro-molybdenum 1.0 that contains molybdenum amount 60%
Nickel 0.2
The ferro-titanium 3.8 of titaniferous amount 30%.
Preparation method is with embodiment 1.

Claims (7)

1, the sintered flux used of a kind of agent for repairing tube mould is characterized in that being made up of following components in weight percentage:
Alundum (Al 5-25
Magnesia 15-35
Calcium oxide 3-15
Silica 7-18
Calcirm-fluoride 15-35
Manganeisen 2-16
Chromium or ferrochrome 3-9
Ferro-molybdenum 0.6-1.5
Nickel 0.1-0.6
Ferro-titanium 2-6.
2, the sintered flux used of agent for repairing tube mould according to claim 1 is characterized in that being made up of following components in weight percentage:
Alundum (Al 10-20
Magnesia 20-30
Calcium oxide 5-10
Silica 1 0-15
Calcirm-fluoride 20-25
Manganeisen 3-5
Chromium 4-6
Ferro-molybdenum 0.8-1.2
Nickel 0.2-0.5
Ferro-titanium 3-5.
3, the sintered flux used of agent for repairing tube mould according to claim 1 is characterized in that being made up of following components in weight percentage:
Alundum (Al 14-16
Magnesia 24-26
Calcium oxide 7-8
Silica 1 2-13
Calcirm-fluoride 21-24
Manganeisen 3-5
Ferrochrome 5-8
Ferro-molybdenum 0.8-1.2
Nickel 0.2-0.5
Ferro-titanium 3-5.
4, the sintered flux used of agent for repairing tube mould according to claim 1, it is characterized in that described manganeisen is the mid-carbon fe-mn alloy that contains manganese 75-85%, described ferrochrome is that chrome content is the ferrochrome of 68-75%, described ferro-molybdenum is to contain the ferro-molybdenum that the molybdenum amount is 55-65%, and described ferro-titanium is the ferro-titanium of 25-35% for the titaniferous amount.
5, the sintered flux used of agent for repairing tube mould according to claim 1 is characterized in that being made up of following components in weight percentage:
Alundum (Al 15
Magnesia 25
Calcium oxide 8
Silica 12
Calcirm-fluoride 25
The manganeisen 4.5 of manganese content 80%
Chromium 5.0
The ferro-molybdenum 1.2 that contains molybdenum amount 60%
Nickel 0.3
The ferro-titanium 4 of titaniferous amount 30%.
6, the sintered flux used of agent for repairing tube mould according to claim 1 is characterized in that being made up of following components in weight percentage:
Alundum (Al 18
Magnesia 25
Calcium oxide 7
Silica 13
Calcirm-fluoride 22
The mid-carbon fe-mn 4.0 of manganese content 80%
The ferrochrome 6.0 that contains chromium 72%
The ferro-molybdenum 1.0 that contains molybdenum amount 60%
Nickel 0.2
The ferro-titanium 3.8 of titaniferous amount 30%.
7, the manufacture method of the sintered flux of using according to claim 1,2,3,4,5 or 6 described agent for repairing tube mould is characterized in that comprising the following steps:
1) described various component raw material are carried out quality inspection,
2) prepare burden according to described components by weight,
3) carry out batch mixing, do earlier and mix, add raw material weight again and carry out wet mixing than the water of 20-30%,
4) granulation on comminutor produces the circular granular that granularity is 2.0-0.28mm,
5) under 600-750 ℃ of temperature, dry,
6) sieve the back with 10-60 mesh sieve and obtain lark finished product sintered flux.
CNB2005100475618A 2005-10-22 2005-10-22 Sintering welding agent for repairing tube mould, and its mfg. method Expired - Fee Related CN100374239C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB2005100475618A CN100374239C (en) 2005-10-22 2005-10-22 Sintering welding agent for repairing tube mould, and its mfg. method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB2005100475618A CN100374239C (en) 2005-10-22 2005-10-22 Sintering welding agent for repairing tube mould, and its mfg. method

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CN1751840A true CN1751840A (en) 2006-03-29
CN100374239C CN100374239C (en) 2008-03-12

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100469510C (en) * 2006-11-21 2009-03-18 宝鸡石油钢管有限责任公司 Sintered flux production process
CN102284808A (en) * 2011-09-02 2011-12-21 天津大桥焊材集团有限公司 Whole-position welded high-strength steel basic electrode with super-low hydrogen and high tenacity
CN102528309A (en) * 2010-12-17 2012-07-04 天津重型装备工程研究有限公司 Welding fluid for overlaying welding of strip-shaped electrode electroslag and preparation method thereof
CN102581518A (en) * 2012-03-23 2012-07-18 北京金威焊材有限公司 Sintered flux for stainless steel surfacing with band electrode
CN103372731A (en) * 2012-04-25 2013-10-30 乔治洛德方法研究和开发液化空气有限公司 Flux containing a nickel-chromium (Ni-Cr) alloy for electroslag over-lay welding (esw)
CN108406167A (en) * 2017-02-09 2018-08-17 奥林康焊接技术有限公司 Sintered flux and the austenitic stainless steel buried arc welding method for using the solder flux

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB472323A (en) * 1935-03-21 1937-09-21 British Thomson Houston Co Ltd Improvements in and relating to welding electrodes
GB713381A (en) * 1951-08-14 1954-08-11 Foote Mineral Co Welding electrode coating and method of making the same and electrodes coated therewith
DE1251133C2 (en) * 1961-03-30 1973-01-18 PROCESS FOR THE PRODUCTION OF WELDING POWDER WITH SMALL SHOE WEIGHT FOR SUB-FLOW WELDING
BE619234A (en) * 1962-06-21 1962-10-15 Soudure Electr Autogene Electric fusion welding process.
JPS5115819B2 (en) * 1972-04-01 1976-05-19
CN1013086B (en) * 1988-08-12 1991-07-10 国家机械工业委员会哈尔滨焊接研究所 A kind of high-basicity sintered flux
CN1034265C (en) * 1994-06-14 1997-03-19 冶金工业部钢铁研究总院 ultra-low-hydrogen and high-basicity sintered flux

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100469510C (en) * 2006-11-21 2009-03-18 宝鸡石油钢管有限责任公司 Sintered flux production process
CN102528309A (en) * 2010-12-17 2012-07-04 天津重型装备工程研究有限公司 Welding fluid for overlaying welding of strip-shaped electrode electroslag and preparation method thereof
CN102528309B (en) * 2010-12-17 2014-05-14 天津重型装备工程研究有限公司 Welding fluid for overlaying welding of strip-shaped electrode electroslag and preparation method thereof
CN102284808A (en) * 2011-09-02 2011-12-21 天津大桥焊材集团有限公司 Whole-position welded high-strength steel basic electrode with super-low hydrogen and high tenacity
CN102581518A (en) * 2012-03-23 2012-07-18 北京金威焊材有限公司 Sintered flux for stainless steel surfacing with band electrode
CN102581518B (en) * 2012-03-23 2014-10-15 北京金威焊材有限公司 Sintered flux for stainless steel surfacing with band electrode
CN103372731A (en) * 2012-04-25 2013-10-30 乔治洛德方法研究和开发液化空气有限公司 Flux containing a nickel-chromium (Ni-Cr) alloy for electroslag over-lay welding (esw)
CN108406167A (en) * 2017-02-09 2018-08-17 奥林康焊接技术有限公司 Sintered flux and the austenitic stainless steel buried arc welding method for using the solder flux

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