CN1013086B - A kind of high-basicity sintered flux - Google Patents

A kind of high-basicity sintered flux

Info

Publication number
CN1013086B
CN1013086B CN 88106039 CN88106039A CN1013086B CN 1013086 B CN1013086 B CN 1013086B CN 88106039 CN88106039 CN 88106039 CN 88106039 A CN88106039 A CN 88106039A CN 1013086 B CN1013086 B CN 1013086B
Authority
CN
China
Prior art keywords
flux
basicity
welding
sintered flux
sio
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CN 88106039
Other languages
Chinese (zh)
Other versions
CN1040160A (en
Inventor
叶栋林
薛松柏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HARBIN WELDING INST STATE MECHANICAL INDUSTRY COMMISSION
Original Assignee
HARBIN WELDING INST STATE MECHANICAL INDUSTRY COMMISSION
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HARBIN WELDING INST STATE MECHANICAL INDUSTRY COMMISSION filed Critical HARBIN WELDING INST STATE MECHANICAL INDUSTRY COMMISSION
Priority to CN 88106039 priority Critical patent/CN1013086B/en
Publication of CN1040160A publication Critical patent/CN1040160A/en
Publication of CN1013086B publication Critical patent/CN1013086B/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/3601Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with inorganic compounds as principal constituents
    • B23K35/3602Carbonates, basic oxides or hydroxides

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Nonmetallic Welding Materials (AREA)

Abstract

A kind of high-basicity sintered flux belongs to the used for submerged arc welding sintered flux.Its chemical composition contains 7.0~17.0%SiO by weight 2, 15.0~25.0%Al 2O 3, 5.0~17.0%CaO, 15.0~40.0%MgO, 10.0~35.0%CaF 2, 0.5~5.0%TiO 2, FeO+MnO<6%, K 2O+Na 2O<6%, ReXOy<3%, this flux basicity are 3.0~3.7.When adopting the welding of this solder flux, arc voltage is stable, and weld fumes is little, takes off slag automatically.Flux particle intensity height, the moisture resistance function admirable.

Description

A kind of high-basicity sintered flux
The present invention relates to a kind of used for submerged arc welding high-basicity sintered flux.
Find a United States Patent (USP) by retrieval, the patent No. is 3078193, and its solder flux chemical composition is: SiO 244.20%, CaO 1.06%, MgO 0.18%, Al 2O 32.00%, MnO 42.90%, TiO 20.08%, FeO 1.5%, Na 2O 0.34%, K 2O 0.36%, CaF 26.9%, BaO 0.11%, and this solder flux is acid fysed flux, can not be used for the welding of important structure.
For the processing performance of improving low-alloy high-strength steel submerged-arc welding and the mechanical performance of weld seam, developed this high-basicity sintered flux.
This solder flux adopts that domestic amount is easy to get greatly, cheap ore powder is a primary raw material.It is characterized in that chemical composition (with reference to the GB5292-85 analytical method) contains 7.0-17.0%SiO by weight 2, 15.0-25.0%Al 2O 3, 5.0-17.0%CaO, 15.0-40.0%MgO, 10.0-35.0%CaF2,0.5-5.0%TiO 2, FeO+MnO<6%, K 2O+Na 2O<6%, RexOy<3%, this flux basicity are 3.0-3.7.
With the United States Patent (USP) ratio that retrieves following difference is arranged:
The first, what United States Patent (USP) was reported is a kind of smelting type welding flux.Because the production of fysed flux is use electric arc furnace smelting, solder flux power consumption per ton is the 1500-2000 degree, and a large amount of pernicious gas of generation when smelting.The production technology of sintered flux then is to add the waterglass granulation by powder--oven dry--sintering in the high temperature furnace, power consumptive province not only, and also pollution-free, be convenient to automated production.
The second, the solder flux of U.S. Patent Publication, the SiO in its main component 2With the content of MnO up to 87%, the basicity computing formula of recommending by International Institute of Welding:
Basicity=(CaO+MgO+BaO+CaF 2+ R 2O+1/2 (MnO+FeO))/(SiO 2+ 1/2 (Al 2O 3+ TiO 2))
Calculate, basicity is about 0.7, and it is to belong to acid flux, and solder flux of the present invention, basicity>3 belong to high basicity solder flux, CaF in its composition 2With the total amount of basic anhydride MgO, CaO up to 60%.Because SiO in the acid flux 2Content height, oxidisability are too strong, and the alloying element scaling loss is serious during welding, and weld seam oxygen content height causes the weld seam cold impact value low.
The 3rd, solder flux of the present invention does not contain the BaO composition, and to have added rare earth oxide composition and percentage composition content that both are identical also inequality more.By improving CaF 2Content, increase the dehydrogenation ability, thereby reduced the diffusible hydrogen content of weld seam.By adding the abundant rare earth oxide of china natural resources, improved the form of field trash in the weld seam, further improved the low-temperature impact toughness of weld seam, make solder flux of the present invention have ultralow hydrogen, high tenacity, the good characteristics of welding technological properties.
When adopting high basicity solder flux of the present invention to weld (cooperating homemade submerged-arc welding wire commonly used), arc voltage is stable, and weld fumes is minimum, and figuration of bead is good, in flat board or the groove during welding or postwelding all can take off slag automatically, be particularly suitable for narrow gap, the welding of narrow groove.60 0Still can take off slag automatically when welding in the double V-groove, toe of weld does not have dry slag.Flux particle intensity height, moisture resistance is good, weld metal diffusible hydrogen<1.0 milliliter/100 grams (glycerine method).This solder flux cooperates homemade H08Mn2MoA welding wire, during by Unite States Standard ANSI/AWS A5.23-80-welding, and σ s 〉=550MPa, σ b 〉=650MPa δ 5 〉=22.0%, ψ 〉=65.0%, ballistic work (60 ℃) 〉=34J.When 2 1/4 CrlMoA steel plates cooperated homemade H08Cr2.25-Mo1A welding wire to weld, every index all satisfied the regulation requirement.
Most preferred embodiment: aluminium oxide 21%, fluorite 24%, magnesia 26%, big physics and chemistry 15%, silica flour 5.5%, feldspar 2.5%, manganese ore 2.5%, titanium dioxide 2%, rare earth III 1.5%.
As bonding agent, addition accounts for 20% with the commercial water glass, flux basicity Bi=3.3

Claims (1)

1, a kind of high-basicity sintered flux is characterized in that chemical composition
Contain 7.0~17.0%SiO by weight 2, 15.0~25.0%Al 2O 3, 5.0~17.0%CaO, 15.0~40.0%MgO, 10.0~35.0%CaF 2, 0.5~5.0%TiO 2, FeO+Mo0<6%, K 2O+Na 2O<6%, ReXOy<3%.
CN 88106039 1988-08-12 1988-08-12 A kind of high-basicity sintered flux Expired CN1013086B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 88106039 CN1013086B (en) 1988-08-12 1988-08-12 A kind of high-basicity sintered flux

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 88106039 CN1013086B (en) 1988-08-12 1988-08-12 A kind of high-basicity sintered flux

Publications (2)

Publication Number Publication Date
CN1040160A CN1040160A (en) 1990-03-07
CN1013086B true CN1013086B (en) 1991-07-10

Family

ID=4834075

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 88106039 Expired CN1013086B (en) 1988-08-12 1988-08-12 A kind of high-basicity sintered flux

Country Status (1)

Country Link
CN (1) CN1013086B (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100374239C (en) * 2005-10-22 2008-03-12 陈娟娟 Sintering welding agent for repairing tube mould, and its mfg. method
CN100396427C (en) * 2005-12-20 2008-06-25 宝鸡石油钢管有限责任公司 High welding rate, high ductility fluorine alkaline type sintered flux
CN102560552A (en) * 2012-01-04 2012-07-11 饶云福 Fusing agent for electrolytic aluminium anodic steel claws repairing
CN109530967A (en) * 2018-12-25 2019-03-29 四川大西洋焊接材料股份有限公司 Mating submerged arc welding flux, welding wire and the preparation method of Q690QE bridge steel

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6939413B2 (en) * 2003-03-24 2005-09-06 Lincoln Global, Inc. Flux binder system
JP5111028B2 (en) * 2007-09-06 2012-12-26 株式会社神戸製鋼所 Flux-cored wire for gas shielded arc welding
CN101985194A (en) * 2010-11-19 2011-03-16 天津市永昌焊丝有限公司 Surfacing flux special for alloy powder transition strip surfacing
CN103358054B (en) * 2012-04-10 2015-06-17 机械科学研究院哈尔滨焊接研究所 Coating for removing slag on laser cutting reverse side of thick steel plate
CN102642100A (en) * 2012-04-12 2012-08-22 西安理工大学 Submerged arc sintered flux for X100 pipeline steel and preparation method of submerged arc sintered flux
CN103386558B (en) * 2013-07-25 2016-08-10 上海建工(江苏)钢结构有限公司 Galvanized steel structure submerged arc welding flux
CN103521950B (en) * 2013-10-23 2015-09-30 天津市永昌焊丝有限公司 Low-temperature high-toughness submerged arc welding flux medicinal powder
CN104175022A (en) * 2014-08-22 2014-12-03 首钢总公司 Sintered flux for high-speed submerged arc welding of pressure steel pipes like pipelines and structural pipes
CN105081615B (en) * 2015-09-11 2017-04-05 武汉铁锚焊接材料股份有限公司 A kind of ocean engineering high tenacity low hydrogen type sintered flux and preparation method thereof
CN105269179B (en) * 2015-10-21 2017-08-18 锦州澳林康天鹅焊材有限公司 A kind of strip surfacing sintered flux used for submerged arc welding
CN106078005B (en) * 2016-07-07 2018-10-09 洛阳双瑞特种合金材料有限公司 A kind of stainless steel band pole submerged arc overlay welding solder flux
CN106363284A (en) * 2016-12-06 2017-02-01 武汉天高熔接股份有限公司 Material suitable for submerged arc welding, anatexis and single-side welding process
CN107553008A (en) * 2017-10-30 2018-01-09 巩义市广大焊业有限责任公司 A kind of X70 pipe line steels vertical masonry joint solder flux used for submerged arc welding and preparation method thereof
CN108195865A (en) * 2018-03-29 2018-06-22 兰州兰石检测技术有限公司 For the submerged arc welding flux standard sample and preparation method of X-ray fluorescence spectra analysis
CN109014657A (en) * 2018-09-13 2018-12-18 郑州凤凰新材料科技有限公司 A kind of High Speed Welding sintered flux and preparation method thereof
CN109664051B (en) * 2018-12-29 2021-08-24 天津市金桥焊材集团股份有限公司 Corrosion-resistant high-strength high-toughness submerged arc welding flux and application thereof
CN113305469B (en) * 2021-05-13 2022-11-08 中国船舶重工集团公司第七二五研究所 Smelting flux for submerged-arc welding of austenitic welding wire and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100374239C (en) * 2005-10-22 2008-03-12 陈娟娟 Sintering welding agent for repairing tube mould, and its mfg. method
CN100396427C (en) * 2005-12-20 2008-06-25 宝鸡石油钢管有限责任公司 High welding rate, high ductility fluorine alkaline type sintered flux
CN102560552A (en) * 2012-01-04 2012-07-11 饶云福 Fusing agent for electrolytic aluminium anodic steel claws repairing
CN109530967A (en) * 2018-12-25 2019-03-29 四川大西洋焊接材料股份有限公司 Mating submerged arc welding flux, welding wire and the preparation method of Q690QE bridge steel

Also Published As

Publication number Publication date
CN1040160A (en) 1990-03-07

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