CN1739482A - Photocatalyst beautifying and whitening toothpaste and its prepn process - Google Patents
Photocatalyst beautifying and whitening toothpaste and its prepn process Download PDFInfo
- Publication number
- CN1739482A CN1739482A CN 200510036742 CN200510036742A CN1739482A CN 1739482 A CN1739482 A CN 1739482A CN 200510036742 CN200510036742 CN 200510036742 CN 200510036742 A CN200510036742 A CN 200510036742A CN 1739482 A CN1739482 A CN 1739482A
- Authority
- CN
- China
- Prior art keywords
- parts
- photocatalyst
- toothpaste
- beautifying
- whitening
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Cosmetics (AREA)
Abstract
The photocatalyst beautifying and whitening toothpaste includes photocatalyst titania solution 18.0-30.0 weight portions, glycerin 10.0-20.0 weight portions, calcium peroxide powder 1.0-8.0 weight portions, calcium carbonate 15.0-30.0 weight portions, sodium lauryl sulfate 4.0-10.0 weight portions, silica 25.0-35.0 weight portions, flavoring matter 0.5-1.5 weight portions and hydrogen peroxide 1.0-8.0 weight portions. The preparation process includes mixing all the components inside one dry container. The photocatalyst beautifying and whitening toothpaste has photocatalytic effect, contains whitening factor, has beneficial negative ion effect, powerful friction and adsorption effect, excellent bacteriostasis and foaming property and obvious functions of cleaning teeth, whitening and preventing halitosis, dental diseases and eliminating tartar.
Description
Technical field
The present invention relates to the toothpaste technical field, specifically be meant a kind of photocatalyst beautifying and whitening toothpaste and preparation method thereof.
Background technology
Toothpaste has effects such as taking care of one's teeth, prevent and treat odontopathy, removing halitosis as cleaning agent for mouth cavity.Increasing people begins to be concerned about the effect of toothpaste, and various functional toothpaste arise at the historic moment, and the toothpaste on the China market is broadly divided into ordinary toothpaste, medicated toothpaste two big classes.The basis of ordinary toothpaste generally comprises abrasive, purificant, wetting agent, adhesive, antiseptic, aromatic, water etc., and its bacteriostasis property often is lower than medicated toothpaste, and the effect of prevention halitosis and odontopathy is also not obvious.No. 200410026456.1 applications for a patent for invention of China disclose the preparation method of a kind of normal temperature drying and stable photocatalyst of titanium dioxide composite solution, this solution has very strong catalysed oxidn under visible light, can also produce the negative ion effect useful to health.But still there is not the report of using mentioned component for the research and development of ordinary toothpaste at present.
Summary of the invention
Purpose of the present invention is exactly in order to solve above-mentioned the deficiencies in the prior art part, and a kind of photocatalyst beautifying and whitening toothpaste and preparation method thereof is provided.This toothpaste is on the basis of ordinary toothpaste, in conjunction with the photocatalytic effect of photocatalyst of titanium dioxide composition, tooth is whitened, and improves the biocidal property of toothpaste and the effect of prevention halitosis and odontopathy simultaneously.
Purpose of the present invention is achieved through the following technical solutions: described a kind of photocatalyst beautifying and whitening toothpaste comprises following composition in parts by weight: 18.0～30.0 parts of titanium dioxide light catalyst solutions, 10.0～20.0 parts of weight percent concentration are that 99% glycerol, 1.0～8.0 parts of purity are 80% calcium peroxide powder, 15.0～30.0 parts of calcium carbonate, 4.0～10.0 parts of sodium lauryl sulfates, 25.0～35.0 parts of silicon dioxide, 0.5～1.5 part of flavouring agent, 1.0～8.0 parts of hydrogen peroxide.
In order to realize the present invention better, described flavouring agent comprises Fructus Ananadis comosi odor type toothpaste essence, Herba Menthae essence, fragrant citrus essence, honey peach essence.
In the mentioned component, glycerol is hygroscopic agent and auxiliary agent, stable in properties, and nontoxic nothing corrosion is widely used in food, cosmetics; Calcium carbonate (white powder, avirulence) and silicon dioxide (white powder, avirulence) are abrasive, and silicon dioxide also has thickening power simultaneously; Titanium dioxide light catalyst solution (adopts No. 200410026456.1 disclosed photocatalyst of titanium dioxide composite solutions of application for a patent for invention of China, milky white liquid, avirulence, antibiotic, titanium dioxide wherein is Detitanium-ore-type) and hydrogen peroxide (transparency liquid, avirulence) be whitening composition, especially titanium dioxide light catalyst solution, have extremely strong oxidation disinfection effect, and can oxidation removal tartar and interdental organic bonding layer, thereby effectively remove tartar; Sodium lauryl sulfate (being sodium lauryl sulphate, white or light yellow crystallization or powder) is a foaming agent; Calper calcium peroxide has stronger bleaching, sterilization and disinfective action, is a kind of highly stable peroxide, and dry product is difficult for decomposing under the room temperature, can slowly release oxygen for a long time in humid air or water, and environment is not had harm, has reached the requirement of food stage.
The preparation method of described a kind of photocatalyst beautifying and whitening toothpaste comprises the steps and process conditions:
The first step adds 10.0～20.0 parts of weight percent concentration in the dry mixed container be 99% glycerol, slowly stirs, and adds 18.0～30.0 parts of titanium dioxide light catalyst solutions, 1.0～8.0 parts of hydrogen peroxide and 0.5～1.5 part of flavouring agent again;
Second step stirred and adds 15.0～30.0 parts of calcium carbonate, 25.0～35.0 parts of silicon dioxide down successively;
The 3rd step evacuation adds 4.0～10.0 parts of sodium lauryl sulfates;
The 4th step continued to stir under vacuum, and 1.0～8.0 parts of purity of slow adding are 80% calcium peroxide powder in 20～30 minutes, and temperature is controlled at 30～50 ℃.
Principle of the present invention is that titanium dioxide light catalyst solution and hydrogen peroxide solution, peroxide are brought into play triple whitening functions jointly.The mechanism of titanium dioxide light catalyst solution is by brushing teeth under the illumination condition, and it is fully contacted with tooth, thereby produces the photocatalysis tooth-whitening; Hydrogen peroxide has discoloration to tooth, and particularly its existence can strengthen greatly that the light of titanium dioxide touches catalytic action in the titanium dioxide light catalyst solution; Peroxide can discharge atomic oxygen, and atomic oxygen has discoloration, can remove the mottle in the enamel top layer, reaches the effect of whitening, and peroxide bleaching tooth character is relatively gentleer, and effect is apparent in view, and is also safer to human mouth simultaneously.In addition, abrasive silicon dioxide also is stronger abrasivus, rubs by the mottle generation physical property with dental surface, can remove the exogenous mottle of facing, makes tooth recover original color.Photocatalyst beautifying and whitening toothpaste of the present invention is placed upside down on the Tooth-whitening tooth-brush,,, can will be deposited on the obviously desalination even the removings of dirts such as cigarette stain, mottle bacterial plaque, black dirt, yellow dirt of dental surface through after the scrubbing of repeated multiple times by the method for brushing teeth usually.
The present invention compared with prior art has following advantage and beneficial effect:
1, the present invention increases the hydrogen peroxide of photocatalyst of titanium dioxide, calper calcium peroxide and low concentration on the basis of ordinary toothpaste, this toothpaste has photocatalysis, contain and brighten the factor, can also produce the negative ion effect useful to health, have very strong friction and adsorption, antibacterial good with foaminess, and the effect that cleans the teeth, brightens, prevents halitosis and odontopathy is arranged significantly.
2, common whitening toothpaste can't be removed tartar.Tartar is that the dental plaque calcification hardening by facing forms, and generally must adopt clean smelting (toothwash) method to remove by specialist.And photocatalyst beautifying and whitening toothpaste of the present invention has certain friction removal effect because contain more abrasive silicon dioxide to tartar, reduces supragingival calculus, can alleviate the painted of tooth.
3, preparation technology of the present invention is simple, and processing cost is low, is highly susceptible to promotion and implementation.
The specific embodiment
Below in conjunction with embodiment, the present invention is described in further detail, but embodiments of the present invention are not limited to this.
Embodiment one
The first step adds 10.0 gram weight percent concentrations in the dry mixed container be 99% glycerol, slowly stirs, and adds 18.0 gram titanium dioxide light catalyst solutions, 1.0 gram hydrogen peroxide and 0.5 gram Fructus Ananadis comosi odor type toothpaste essence again;
Second step stirred and adds 15.0 gram calcium carbonate, 25.0 gram silicon dioxide down successively;
The 3rd step evacuation adds 4.0 gram sodium lauryl sulfates;
The 4th step continued to stir under vacuum, and slow adding 1.0 gram purity are 80% calcium peroxide powder in 20 minutes, and temperature is controlled at 30 ℃.Obtain ointment shape goods at last, be packaged into the toothpaste finished product after the sterilization.
Embodiment two
The first step adds 15.0 gram weight percent concentrations in the dry mixed container be 99% glycerol, slowly stirs, and adds 24.0 gram titanium dioxide light catalyst solutions, 5.5 gram hydrogen peroxide and 1.0 gram Herba Menthae essence again;
Second step stirred and adds 25.0 gram calcium carbonate, 32.0 gram silicon dioxide down successively;
The 3rd step evacuation adds 6.5 gram sodium lauryl sulfates;
The 4th step continued to stir under vacuum, and slow adding 4.0 gram purity are 80% calcium peroxide powder in 25 minutes, and temperature is controlled at 45 ℃.Obtain ointment shape goods at last, be packaged into the toothpaste finished product after the sterilization.
Embodiment three
The first step adds 20.0 gram weight percent concentrations in the dry mixed container be 99% glycerol, slowly stirs, and adds 30.0 gram titanium dioxide light catalyst solutions, 8.0 gram hydrogen peroxide and 1.0 gram fragrant citrus essence, 0.5 gram honey peach essence again;
Second step stirred and adds 30.0 gram calcium carbonate, 35.0 gram silicon dioxide down successively;
The 3rd step evacuation adds 10.0 gram sodium lauryl sulfates;
The 4th step continued to stir under vacuum, and slow adding 8.0 gram purity are 80% calcium peroxide powder in 30 minutes, and temperature is controlled at 50 ℃.Obtain ointment shape goods at last, be packaged into the toothpaste finished product after the sterilization.
Long term toxicity test: select the healthy SD rat for use, feed with photocatalyst beautifying and whitening toothpaste of the present invention 60 days, every day the 5mg/kg body weight.The result: rat does not have any clinical abnormal symptom, and blood, routine urianlysis are normal; Liver, renal function are normal; Pathological anatomy checks that brain, the heart, liver, kidney, testis do not have any anomaly.
Crowd's clinical observation: 20 volunteers use photocatalyst beautifying and whitening toothpaste of the present invention, clinical observation after 30 days, the ratio of mutans streptococcus in total anaerobe drops to 10% from 52% in the dental plaque, shows that photocatalyst beautifying and whitening toothpaste of the present invention can effectively kill and suppress the mutans streptococcus in the dental plaque.
The ceramics contrast experiment:
On the identical ceramics of six forms, (indicate numbering 1,2,3,4,5,6 respectively) and coat similar smoke puff (simulation tooth smoke puff), scrub with common cleaning agent then, find that common cleaning agent works hardly to stain, each ceramics stain face color is also similar.
Dispose five identical toothbrush, and bear serial numbers 1,2,3,4,5 respectively.Buy four whitening toothpastes, be respectively certain white refreshing white toothpaste, the white toothpaste of certain telegraphy, certain draft whitening toothpaste, certain ultrawhite toothpaste; Photocatalyst beautifying and whitening toothpaste of the present invention is adopted in contrast simultaneously.
By the toothpaste dosage of normally brushing teeth and the dynamics of brushing teeth normally, scrub corresponding ceramics.Each brush five to ten minutes carries out altogether ten times.If the pollution index of clean ceramics is 0, the ceramics pollution index of handling with smoke puff is 100, and the pollution index of each ceramics of experiment back sees the following form so:
| The ceramics numbering | Test used toothpaste | Experiment after stain index |
| 1 | Certain white refreshing white toothpaste | 20 |
| 2 | The white toothpaste of certain telegraphy | 30 |
| 3 | Certain draft whitening toothpaste | 25 |
| 4 | Certain ultrawhite toothpaste | 50 |
| 5 | Photocatalyst beautifying and whitening toothpaste | 5 |
| 6 | Do not have | 100 |
The tooth contrast experiment:
Similar tooth (pollution index is 100) with 6 real jaundice blackouts carries out above-mentioned experiment.Experiment after stain index sees the following form:
| The tooth numbering | Test used toothpaste | Experiment after stain index |
| 1 | Photocatalyst beautifying and whitening toothpaste | 5 |
| 2 | Photocatalyst beautifying and whitening toothpaste | 8 |
| 3 | Photocatalyst beautifying and whitening toothpaste | 9 |
| 4 | Photocatalyst beautifying and whitening toothpaste | 7 |
| 5 | Certain white refreshing white toothpaste | 50 |
| 6 | The white toothpaste of certain telegraphy | 55 |
Above-mentioned experiment shows, the decontamination of the photocatalyst beautifying and whitening toothpaste of the present invention ability of whitening is stronger than other whitening toothpaste.
As mentioned above, can realize the present invention preferably.
Claims (4)
1, a kind of photocatalyst beautifying and whitening toothpaste, it is characterized in that, in parts by weight, comprise following composition: 18.0～30.0 parts of titanium dioxide light catalyst solutions, 10.0～20.0 parts of weight percent concentration are that 99% glycerol, 1.0～8.0 parts of purity are 80% calcium peroxide powder, 15.0～30.0 parts of calcium carbonate, 4.0～10.0 parts of sodium lauryl sulfates, 25.0～35.0 parts of silicon dioxide, 0.5～1.5 part of flavouring agent, 1.0～8.0 parts of hydrogen peroxide.
According to the described a kind of photocatalyst beautifying and whitening toothpaste of claim 1, it is characterized in that 2, described flavouring agent comprises Fructus Ananadis comosi odor type toothpaste essence, Herba Menthae essence, fragrant citrus essence, honey peach essence.
3, the preparation method of the described a kind of photocatalyst beautifying and whitening toothpaste of claim 1 is characterized in that, comprises the steps and process conditions:
The first step adds 10.0～20.0 parts of weight percent concentration in the dry mixed container be 99% glycerol, slowly stirs, and adds 18.0～30.0 parts of titanium dioxide light catalyst solutions, 1.0～8.0 parts of hydrogen peroxide and 0.5～1.5 part of flavouring agent again;
Second step stirred and adds 15.0～30.0 parts of calcium carbonate, 25.0～35.0 parts of silicon dioxide down successively;
The 3rd step evacuation adds 4.0～10.0 parts of sodium lauryl sulfates;
The 4th step continued to stir under vacuum, and 1.0～8.0 parts of purity of slow adding are 80% calcium peroxide powder in 20～30 minutes, and temperature is controlled at 30～50 ℃.
According to the preparation method of the described a kind of photocatalyst beautifying and whitening toothpaste of claim 3, it is characterized in that 4, described flavouring agent comprises Fructus Ananadis comosi odor type toothpaste essence, Herba Menthae essence, fragrant citrus essence, honey peach essence.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510036742 CN1739482A (en) | 2005-08-26 | 2005-08-26 | Photocatalyst beautifying and whitening toothpaste and its prepn process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510036742 CN1739482A (en) | 2005-08-26 | 2005-08-26 | Photocatalyst beautifying and whitening toothpaste and its prepn process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1739482A true CN1739482A (en) | 2006-03-01 |
Family
ID=36092109
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200510036742 Pending CN1739482A (en) | 2005-08-26 | 2005-08-26 | Photocatalyst beautifying and whitening toothpaste and its prepn process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1739482A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008017203A1 (en) * | 2006-08-01 | 2008-02-14 | Unilever Plc | Biomaterials, their preparation and use |
| CN102614090A (en) * | 2012-04-24 | 2012-08-01 | 苏州维蒂卡科技有限公司 | Toothpaste composition |
| CN102824277A (en) * | 2012-09-06 | 2012-12-19 | 南京市口腔医院 | Application of nanometer titania photocatalyst in false tooth antibiosis and cleaning |
| CN103131556A (en) * | 2013-02-20 | 2013-06-05 | 杨新莲 | Nano-grade photocatalytic/peroxide composite bleaching agent and preparation method thereof |
| CN104784058A (en) * | 2015-05-08 | 2015-07-22 | 苏润文 | Photocatalytic sunscreen essence and preparation method thereof |
| US9149419B2 (en) | 2006-12-05 | 2015-10-06 | Conopco, Inc. | Oral care product |
| CN106265126A (en) * | 2016-08-17 | 2017-01-04 | 林少英 | A kind of whitening toothpaste |
| CN106491384A (en) * | 2016-12-29 | 2017-03-15 | 宋光荣 | A kind of toothpaste |
| CN106726648A (en) * | 2017-01-23 | 2017-05-31 | 宋光荣 | A kind of nano photo-catalytic tooth whitening gel |
| CN109528531A (en) * | 2019-01-18 | 2019-03-29 | 四川涑爽医疗用品有限公司 | A kind of composition for tooth whitening and the oral care product comprising the composition |
| CN114304179A (en) * | 2021-11-29 | 2022-04-12 | 南方科技大学 | Titanium dioxide loaded calcium peroxide compound, disinfectant and method for inactivating pathogenic factors |
| CN115463041A (en) * | 2022-09-28 | 2022-12-13 | 重庆登康口腔护理用品股份有限公司 | Anti-allergy toothpaste with cold light whitening effect and preparation method thereof |
-
2005
- 2005-08-26 CN CN 200510036742 patent/CN1739482A/en active Pending
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008017203A1 (en) * | 2006-08-01 | 2008-02-14 | Unilever Plc | Biomaterials, their preparation and use |
| US9149419B2 (en) | 2006-12-05 | 2015-10-06 | Conopco, Inc. | Oral care product |
| CN102614090A (en) * | 2012-04-24 | 2012-08-01 | 苏州维蒂卡科技有限公司 | Toothpaste composition |
| CN102824277A (en) * | 2012-09-06 | 2012-12-19 | 南京市口腔医院 | Application of nanometer titania photocatalyst in false tooth antibiosis and cleaning |
| CN103131556A (en) * | 2013-02-20 | 2013-06-05 | 杨新莲 | Nano-grade photocatalytic/peroxide composite bleaching agent and preparation method thereof |
| CN104784058B (en) * | 2015-05-08 | 2018-07-06 | 苏润文 | A kind of sun-proof Essence of photocatalyst and preparation method thereof |
| CN104784058A (en) * | 2015-05-08 | 2015-07-22 | 苏润文 | Photocatalytic sunscreen essence and preparation method thereof |
| CN106265126A (en) * | 2016-08-17 | 2017-01-04 | 林少英 | A kind of whitening toothpaste |
| CN106491384A (en) * | 2016-12-29 | 2017-03-15 | 宋光荣 | A kind of toothpaste |
| CN106726648A (en) * | 2017-01-23 | 2017-05-31 | 宋光荣 | A kind of nano photo-catalytic tooth whitening gel |
| CN109528531A (en) * | 2019-01-18 | 2019-03-29 | 四川涑爽医疗用品有限公司 | A kind of composition for tooth whitening and the oral care product comprising the composition |
| CN114304179A (en) * | 2021-11-29 | 2022-04-12 | 南方科技大学 | Titanium dioxide loaded calcium peroxide compound, disinfectant and method for inactivating pathogenic factors |
| CN114304179B (en) * | 2021-11-29 | 2023-04-07 | 南方科技大学 | Titanium dioxide loaded calcium peroxide compound, disinfectant and method for inactivating pathogenic factors |
| CN115463041A (en) * | 2022-09-28 | 2022-12-13 | 重庆登康口腔护理用品股份有限公司 | Anti-allergy toothpaste with cold light whitening effect and preparation method thereof |
| CN115463041B (en) * | 2022-09-28 | 2023-10-20 | 重庆登康口腔护理用品股份有限公司 | Anti-sensitivity toothpaste with cold light whitening effect and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1739482A (en) | Photocatalyst beautifying and whitening toothpaste and its prepn process | |
| JP6956143B2 (en) | Antimicrobial composition and how to use it | |
| US4837009A (en) | Method and composition for prevention of plaque formation and plaque dependent diseases | |
| US4855135A (en) | Method for debriding | |
| US4886657A (en) | Method for preventing periodontitis | |
| US4925656A (en) | Method for retarding formation of dental plaque | |
| US9603791B2 (en) | Oral care product formulation | |
| CN1169516C (en) | Oral cleaning detergent component and tooth-paste, tooth powder component | |
| US20040171505A1 (en) | Cleansers, cleaning system, bleaching agents and compositions for environmental conservation | |
| CA2644381A1 (en) | Oral hygiene products and method of using the same | |
| CN1861039A (en) | Chewing bubble-producing type solid tooth-paste | |
| CN1665473A (en) | Antibacterial dentifrice exhibiting antiplaque and breath freshening properties | |
| CN108685833A (en) | Containing propolis, Radix Notoginseng, moutan bark, the coptis, Radix Glycyrrhizae toothpaste and preparation method thereof | |
| EP1979458B1 (en) | Cleansing composition for use in the treatment or prophylaxis of halitosis or periodontitis | |
| CN1294895C (en) | Natural and whitening tooth powder and production thereof | |
| CN114760976A (en) | Oral care composition containing inulin | |
| CN1179972A (en) | Multifunctional effervescent for cleaning mouth | |
| CN103893021A (en) | A preparing method of photocatalyst whitening toothpaste | |
| CN104523513A (en) | Tooth cleaning fluid | |
| CN107007538A (en) | A kind of oral care composition and application containing marine element, and the toothpaste containing marine element | |
| EP0613678B1 (en) | Oral care composition | |
| CN101406435B (en) | Use of radish chitin-binding protein in preparing dental health product | |
| KR100859967B1 (en) | Composites and preparation method of toothpaste containing extracts from Geum kang pine tree | |
| WO2000044338A1 (en) | Oral hygiene preparations; associated methods and kit | |
| AU642128B2 (en) | Improved method and composition for prevention of plaque formation and plaque dependent diseases |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |