CN106726648A - A kind of nano photo-catalytic tooth whitening gel - Google Patents

A kind of nano photo-catalytic tooth whitening gel Download PDF

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Publication number
CN106726648A
CN106726648A CN201710049629.9A CN201710049629A CN106726648A CN 106726648 A CN106726648 A CN 106726648A CN 201710049629 A CN201710049629 A CN 201710049629A CN 106726648 A CN106726648 A CN 106726648A
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Prior art keywords
mass parts
whitening
gel
gelatin
spices
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CN201710049629.9A
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Chinese (zh)
Inventor
宋光荣
宋嘉豪
宋家伟
宋婉祯
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/29Titanium; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/042Gels
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/22Peroxides; Oxygen; Ozone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25Silicon; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/27Zinc; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/28Zirconium; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q11/00Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses

Abstract

The invention belongs to daily use chemicals manufacture field, it is related to a kind of nano photo-catalytic tooth whitening gel.The gel includes following component:The gel of 1 50 mass parts, the surfactant of 0.05 0.5 mass parts, the NMF of 3.3 10 mass parts, the sweetener of 0.01 0.15 mass parts, the deionized water of 20 80 mass parts, the spices of 0.02 0.5 mass parts, the preservative of 0.02 0.18 mass parts, the desensitizer of 0.1 0.5 mass parts, the conditioning agent of 0.1 0.5 mass parts, the whitening factor of 8.8 20 mass parts;The whitening factor is made up of the photocatalyst of 5 10 mass parts, the peracid water element of 3.3 10 mass parts.The gel has high permeability, in can penetrating into the aperture of dentine, the effect of quick whitening;Organic compound and inorganic matter in the pigment of oxidation Decomposition dental surface and oral cavity, destroy the cell membrane of bacterium and the protein of solidification virus, bacterium and decomposing organic matter can be killed, with extremely strong sterilizing oral, except halitosis, tooth-whitening function.Ordinary toothpaste can be played a part of to be beyond one's reach oral cleaning and tooth-whitening.

Description

A kind of nano photo-catalytic tooth whitening gel
Technical field
The invention belongs to daily use chemicals manufacture field, it is related to a kind of nano photo-catalytic tooth whitening gel.
Background technology
Traditional tooth whitening gel be a kind of Hydrogenperoxide gel its it is main into composition be high-strength hydrogen peroxide, urea Carbomer gel.Oxidisability by hydrogen peroxide carrys out bleaching teeth, and oral cavity is glued because high-strength hydrogen peroxide is corrosive Film is damaged.Influence is healthy.It is photocatalyst and the medical peroxidating of low concentration that the invention of this formula is specifically added the whitening factor Hydrogen.With nanometer grade silica gel carrier or Carbomer carrier, ultraviolet light or the illumination of far red light or visible ray is coordinated to reach To safe and efficient U.S. tooth function.Clearly, typically tooth whiteness will rise one to this formula whitening effect after using seven times Level.
There is tooth blackening, flavescence and mainly divide exogenous and two kinds of endogenous in people.Exogenous master is by bacterial plaque, daily Pigment deposition causes in food in diet, and endogenous is normally due to be deposited on dentine medicine tetracycline, drink in tooth growth course What the fluorine in water excessively caused.And the method for tooth-whitening is exactly two kinds:One is to dispel exogenous stain on the tooth surface, and two is to dispel tooth Pigment in essence, the former and need to use whitening agent oxidation Decomposition stain on the tooth surface, traditional whitening is by the friction in toothpaste Agent brushes teeth to rub off the pigment on surface, and effect is undesirable.Pigment particularly in dentine is difficult to remove.
The content of the invention
Therefore, the technical problems to be solved by the invention are to overcome tooth whitening gel effect in the prior art to pay no attention to Think, the pigment in dentine is difficult to the bottleneck for removing, so as to propose the nano photo-catalytic tooth of a kind of oral cleaning and tooth-whitening Tooth whitening gelatin.
In order to solve the above technical problems, the invention discloses a kind of nano photo-catalytic tooth whitening gel, the gel bag Include following component:The gel of 1-50 mass parts, the surfactant of 0.05-0.5 mass parts, the moisturizing of 3.3-10 mass parts Agent, the sweetener of 0.01-0.15 mass parts, the deionized water of 20-80 mass parts, the spices of 0.02-0.5 mass parts, 0.02- The preservative of 0.18 mass parts, the desensitizer of 0.1-0.5 mass parts, the conditioning agent of 0.1-0.5 mass parts, 8.8-20 mass parts The whitening factor;
The whitening factor is made up of the photocatalyst of 5-10 mass parts, the peracid water element of 3.3-10 mass parts.
Preferably, the photocatalyst is TiO2、ZrO2、ZnO、Fe2O3、SrTiO3、SiO2, platinum, in Lao, Palladium at least one Kind.
Preferably, the peracid water element is H2O2
Preferably, the gel is the one kind in Carbomer or nano silicon.
Preferably, the Carbomer is 1-2 mass parts, is the one kind in polyvinylpyrrolidone, poloxamer.
Preferably, the silica is 30-50 mass parts.
Preferably, the surfactant is N- sodium N-lauroyl sarcosinates, lauryl sodium sulfate, laureth At least one in sulphur, acid esters sodium, AEO.
Preferably, the conditioning agent is in NaOH, potassium hydroxide, triethanolamine, aminomethyl propyl alcohol, polyalcohol It is at least one;The desensitizer is at least one in sodium fluoride, potassium nitrate, strontium fluoride.
Preferably, the NMF is glycerine, polyethylene glycol, propane diols, sorbierite, Aceonon 300 MO, phosphinylidyne At least one in amine;The preservative be Sodium Benzoate, p-hydroxybenzoate, chloreresol, methyl hydroxybenzoate, Nipasol, At least one in thimerosal;The sweetener is at least one in xylitol, saccharin sodium;The spices is lactic acid peppermint At least one at least one, peach class, mango class in ester, orange flavor, strawberry flavor, peach spices, mango spices.
The invention also discloses the preparation method of gel described in any one, methods described is as follows:By the solidifying of respective quality part Jelly, surfactant, sweetener, NMF, water, spices, conditioning agent, desensitizer, the whitening factor, preservative, be dissolved in from Sub- water is simultaneously stirred, and obtains the gel.
Above-mentioned technical proposal of the invention has advantages below compared to existing technology:Gel of the present invention has high oozing Permeability, can be penetrated into the aperture of dentine, and hydrogen peroxide is decomposed and produces Strong oxdiative thing to promote color in dental surface and deep layer Element tissue is disintegrated rapidly, the effect of so as to play quick whitening;It is various in the oxidable pigment for decomposing dental surface and oral cavity to have Machine compound and part inorganic matter, can destroy the cell membrane of bacterium and the protein of solidification virus, and can kill bacterium and decomposition has Organic pollutants, with extremely strong sterilizing oral, except halitosis, tooth-whitening function.Photocatalyst when itself receives illumination except that can produce Raw oxidation also promotes effective decomposition of hydrogen peroxide simultaneously, and the HO2- for producing more oxidabilities superpower, HO2- is continuous Oxidize away pigment, ordinary toothpaste can be played a part of and be beyond one's reach oral cleaning and tooth-whitening;With great city Field prospect and economic worth.
Specific embodiment
Embodiment 1 is present embodiment discloses a kind of Buccodental whitening gelatin, and the gel component is as follows:8 mass parts Photocatalyst TIO2, the peracid water element of 7 mass parts, 40 mass parts go from water, the nano silicon of 37 mass parts, 0.3 matter Measure the laureth sodium sulfovinate, the phosphoamide H of 7 mass parts of part2NCONH2(CO(NH2)2), the poly- second two of 1.5 mass parts Alcohol, the xylitol of 0.13 mass parts, the orange flavor of 0.25 mass parts, the Sodium Benzoate of 0.5 mass parts, the nitre of 0.3 mass parts The strontium fluoride of sour potassium, 0.3 mass parts.The cleannes of this implementation whitening gelatin are 94%, remove stain degree 92%.
Embodiment 2 is present embodiment discloses a kind of Buccodental whitening gelatin, and the gel component is as follows:5 mass parts Photocatalyst TIO2, the peracid water element of 7 mass parts, 48 mass parts go from water, the nano silicon of 50 mass parts, 0.05 matter Measure the laureth sodium sulfovinate, the phosphoamide H of 7 mass parts of part2NCONH2(CO(NH2)2), the polyethylene glycol of 1 mass parts, The xylitol of 0.15 mass parts, the orange flavor of 0.02 mass parts, the Sodium Benzoate of 0.5 mass parts, the nitric acid of 0.1 mass parts The strontium fluoride of potassium, 0.5 mass parts.The cleannes of this implementation whitening gelatin are 93%, remove stain degree 91%.
Embodiment 3 is present embodiment discloses a kind of Buccodental whitening gelatin, and the gel component is as follows:10 mass parts Photocatalyst TIO2, the peracid water element of 3.3 mass parts, 80 mass parts are gone from water, the Carbomer of 1 mass parts, 1.5 mass parts Polyvinylpyrrolidone, the poloxamer of 1 mass parts, the laureth sodium sulfovinate of 0.00.5 mass parts, 3.3 mass parts Phosphoamide H2NCONH2(CO(NH2)2), the polyethylene glycol of 2 mass parts, the xylitol of 0.1 mass parts, 0.5 mass parts strawberry it is fragrant Material, the NaOH of 0.1 mass parts, the potassium nitrate of 0.5 mass parts, the strontium fluoride of 0.1 mass parts.This implementation whitening gelatin Cleannes be 90%, remove stain degree 90%.
Embodiment 4 is present embodiment discloses a kind of Buccodental whitening gelatin, and the gel component is as follows:5 mass parts Photocatalyst TIO2, the peracid water element of 10 mass parts, 20 mass parts are gone from water, the Carbomer of 1.5 mass parts, 1 mass parts Polyvinylpyrrolidone, the poloxamer of 1.5 mass parts, the laureth sodium sulfovinate of 0.05 mass parts, 10 mass parts Phosphoamide H2NCONH2(CO(NH2)2), the polyethylene glycol of 1 mass parts, the xylitol of 0.15 mass parts, the strawberry of 0.02 mass parts Spices, the NaOH of 0.5 mass parts, the potassium nitrate of 0.1 mass parts, the strontium fluoride of 0.5 mass parts.This implementation whitening is coagulated The cleannes of glue are 91%, remove stain degree 91%.
The present embodiment also discloses the preparation technology of the gel, comprises the following steps that:
By the gel of respective quality part, surfactant, sweetener, NMF, water, spices, conditioning agent, desensitizer, The whitening factor, preservative, are dissolved in deionized water and stir, and obtain the gel.
Embodiment effect:Embodiment 1 and 2 is by two kinds of whitening factors photocatalyst (nano titanium oxide) of addition in gel With peracid water element (hydrogen peroxide) of low concentration, synthesize whitening gelatin agent, gel has the slow release whitening factor to act on.It is made It is that low mass parts of dense hydrogen peroxide 3.3 have high permeability with mechanism, in can penetrating into the aperture of dentine, peroxidating Hydrogen decomposes pigment tissue in producing Strong oxdiative thing to promote dental surface and deep layer disintegrates rapidly, so as to play the work(of quick whitening Effect.Other photocatalyst (Nano titanium dioxide) ultramicron receive ultraviolet or far infrared that wavelength is below 388nm, During the irradiation of visible ray, similar photosynthetic light-catalyzed reaction can be produced, excite generation electricity inside it due to absorbing luminous energy Sub- hole pair, i.e. photo-generated carrier, then move to rapidly its surface and activate adsorbed oxygen and moisture, produce oxidation The very competent free hydroxy (OH) of activity and superoxide anion O2, active oxygen (HO2.H2O2), with very strong photooxidation Change restoring function light life group, the energy of these light life groups, the high temperature equivalent to 3600K, with very strong oxidisability. Various organic compounds and part inorganic matter in the oxidable pigment for decomposing dental surface and oral cavity, can destroy the cell membrane of bacterium With solidification virus protein, bacterium and decomposing organic pollutant can be killed, organic pollution resolve into it is free of contamination go from Sub- water (H2) and carbon dioxide (CO O2), thus with extremely strong sterilizing oral, except halitosis, tooth-whitening function.Photocatalyst except Oxidation can be produced also to promote effective decomposition of hydrogen peroxide simultaneously when itself is by illumination, produces more oxidabilities to surpass Strong HO2-,HO2- pigment is constantly oxidized away, both whitening factors combine can be played ordinary toothpaste and be beyond one's reach The effect of oral cleaning and tooth-whitening.
Obviously, above-described embodiment is only intended to clearly illustrate example, and not to the restriction of implementation method.It is right For those of ordinary skill in the art, can also make on the basis of the above description other multi-forms change or Change.There is no need and unable to be exhaustive to all of implementation method.And the obvious change thus extended out or Among changing still in the protection domain of the invention.

Claims (10)

1. a kind of nano photo-catalytic tooth whitening gel, it is characterised in that the gel includes following component:1-50 mass parts Gel, the surfactant of 0.05-0.5 mass parts, the NMF of 3.3-10 mass parts, the sweet taste of 0.01-0.15 mass parts Agent, the deionized water of 20-80 mass parts, the spices of 0.02-0.5 mass parts, the preservative of 0.02-0.18 mass parts, 0.1-0.5 The desensitizer of mass parts, the conditioning agent of 0.1-0.5 mass parts, the whitening factor of 8.8-20 mass parts;
The whitening factor is made up of the photocatalyst of 5-10 mass parts, the peracid water element of 3.3-10 mass parts.
2. whitening gelatin as claimed in claim 1, it is characterised in that the photocatalyst is TiO2、ZrO2、ZnO、Fe2O3、 SrTiO3、SiO2, platinum, at least one in Lao, Palladium.
3. whitening gelatin as claimed in claim 2, it is characterised in that the peracid water element is H2O2
4. whitening gelatin as claimed in claim 3, it is characterised in that during the gel is Carbomer or nano silicon One kind.
5. whitening gelatin as claimed in claim 4, it is characterised in that the Carbomer content is 1-2 mass parts, is polyethylene One kind in pyrrolidones, poloxamer.
6. whitening gelatin as claimed in claim 4, it is characterised in that the silica is 30-50 mass parts.
7. the whitening gelatin as described in claim any one of 1-6, it is characterised in that the surfactant is N- lauroyls At least one in sodium sarcosinate, lauryl sodium sulfate, laureth sulphur, acid esters sodium, AEO.
8. whitening gelatin as claimed in claim 7, it is characterised in that the conditioning agent is NaOH, potassium hydroxide, three second At least one in hydramine, aminomethyl propyl alcohol, polyalcohol;The desensitizer be sodium fluoride, potassium nitrate, strontium fluoride at least It is a kind of.
9. whitening gelatin as claimed in claim 8, it is characterised in that the NMF be glycerine, polyethylene glycol, propane diols, At least one in sorbierite, Aceonon 300 MO, phosphoamide;The preservative is Sodium Benzoate, P-hydroxybenzoic acid At least one in ester, chloreresol, methyl hydroxybenzoate, Nipasol, thimerosal;The sweetener is in xylitol, saccharin sodium It is at least one;The spices be menthyl lactate, orange flavor, strawberry flavor, peach spices, mango spices at least one, At least one in peach class, mango class.
10. a kind of method for preparing the whitening gelatin as described in claim any one of 1-6, it is characterised in that methods described is: By the gel of respective quality part, surfactant, sweetener, NMF, water, spices, conditioning agent, desensitizer, the whitening factor, Preservative, is dissolved in deionized water and stirs, and obtains the gel.
CN201710049629.9A 2017-01-23 2017-01-23 A kind of nano photo-catalytic tooth whitening gel Pending CN106726648A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109481069A (en) * 2018-12-21 2019-03-19 南京奇迪康生物科技有限公司 A kind of method of bleaching tooth based on whitening cleansing gel
CN109998933A (en) * 2019-03-04 2019-07-12 西安蓝极医疗电子科技有限公司 A kind of tooth whitening gel and preparation method thereof, application method
CN111214307A (en) * 2020-01-18 2020-06-02 陈敬 Tooth-protecting and whitening tooth socket and manufacturing method and using method thereof
CN111494230A (en) * 2020-04-30 2020-08-07 江西师范大学 Cold light tooth whitening gel, preparation method and application
CN112274441A (en) * 2020-11-03 2021-01-29 成都大学 Tooth polishing paste with whitening self-repairing function and preparation method and application thereof
CN115721572A (en) * 2022-10-27 2023-03-03 四川大学 Novel piezoelectric-photocatalytic tooth whitening formula

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1358085A (en) * 1999-07-02 2002-07-10 石桥卓郎 Tooth bleaching compositions and method of bleaching discored tooth
CN1739482A (en) * 2005-08-26 2006-03-01 广州市华之特奥因特种材料科技有限公司 Photocatalyst beautifying and whitening toothpaste and its prepn process
CN101703456A (en) * 2009-12-11 2010-05-12 江西诚志日化有限公司 Combined chloranthus glaber whitening gelatin with anti-allergic agent and preparation method thereof
CN102614090A (en) * 2012-04-24 2012-08-01 苏州维蒂卡科技有限公司 Toothpaste composition
CN103131556A (en) * 2013-02-20 2013-06-05 杨新莲 Nano-grade photocatalytic/peroxide composite bleaching agent and preparation method thereof
CN103893021A (en) * 2012-12-26 2014-07-02 大连林桥科技有限公司 A preparing method of photocatalyst whitening toothpaste

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1358085A (en) * 1999-07-02 2002-07-10 石桥卓郎 Tooth bleaching compositions and method of bleaching discored tooth
CN1739482A (en) * 2005-08-26 2006-03-01 广州市华之特奥因特种材料科技有限公司 Photocatalyst beautifying and whitening toothpaste and its prepn process
CN101703456A (en) * 2009-12-11 2010-05-12 江西诚志日化有限公司 Combined chloranthus glaber whitening gelatin with anti-allergic agent and preparation method thereof
CN102614090A (en) * 2012-04-24 2012-08-01 苏州维蒂卡科技有限公司 Toothpaste composition
CN103893021A (en) * 2012-12-26 2014-07-02 大连林桥科技有限公司 A preparing method of photocatalyst whitening toothpaste
CN103131556A (en) * 2013-02-20 2013-06-05 杨新莲 Nano-grade photocatalytic/peroxide composite bleaching agent and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109481069A (en) * 2018-12-21 2019-03-19 南京奇迪康生物科技有限公司 A kind of method of bleaching tooth based on whitening cleansing gel
CN109998933A (en) * 2019-03-04 2019-07-12 西安蓝极医疗电子科技有限公司 A kind of tooth whitening gel and preparation method thereof, application method
CN111214307A (en) * 2020-01-18 2020-06-02 陈敬 Tooth-protecting and whitening tooth socket and manufacturing method and using method thereof
CN111494230A (en) * 2020-04-30 2020-08-07 江西师范大学 Cold light tooth whitening gel, preparation method and application
CN112274441A (en) * 2020-11-03 2021-01-29 成都大学 Tooth polishing paste with whitening self-repairing function and preparation method and application thereof
CN115721572A (en) * 2022-10-27 2023-03-03 四川大学 Novel piezoelectric-photocatalytic tooth whitening formula

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