Summary of the invention
The object of the present invention is to provide a kind of edible deciccant, this drier does not have injury to skin, eyes, and eat by mistake and do not have harm, the hygroscopicity height, water holding capacity is strong, and is biodegradable.
In order to achieve the above object, technical solution of the present invention is: this edible deciccant is made up of water-absorbing material and auxiliary material, and its weight proportion is:
0.1~5 part of water-absorbing material (konjaku flour grafted propylene hydrochlorate or starch grafted acrylate or chitin grafted propylene hydrochlorate or cellulose graft acrylates or polyacrylate)
0.1~50 part of auxiliary material (rice or corn or soybean or cassava or potato or sweet potato or wheat or stalk or sawdust)
(1) water-absorbing material comprises:
A konjaku flour grafted propylene hydrochlorate (Chinese patent 1410463): in advance konjaku flour is added water after 30~60 ℃ of following gelatinizations; the passing ratio pump adds the acrylate monomers that partly neutralizes with alkali; initator (potassium peroxydisulfate or ammonium persulfate or ammonium ceric nitrate) and crosslinking agent (N; N '-methylene-bisacrylamide or epoxychloropropane or 1; the 4-butanediol); stir and feed nitrogen or argon shield; after 30~70 ℃ of initiation grafting copolyreaction; follow the reactant liquor injection to enter helix tube type turbulent flow reactor with nitrogen or argon gas and carry out graft copolymerization; react after 30~300 seconds; spiral is extruded and is sent into drum-type film forming drier, makes reactant be membranaceous drying.Dry back product is the film sheet, through being ground into granular product.
B starch grafted acrylate (product)
C chitin grafted propylene hydrochlorate (product)
D cellulose graft acrylates (product)
E polyacrylate (product)
(2) auxiliary material comprises:
F rice starch (product)
G cornstarch (product)
H soybean (product)
I cassava (product)
J potato (product)
K sweet potato (product)
L wheat (product)
M stalk (product)
N sawdust (product)
The edible deciccant preparation process is: water-absorbing material and auxiliary material mixed in stirring mixer, and expanded in bulking machine then, go in the pulverizer and pulverize, granulation then, screening divides packing by quantitative racking machine, obtains edible deciccant.This product must add before use and pack airtight preservation.
Do not add auxiliary material, a kind of or water-absorbing material that is mixed arbitrarily of above-mentioned raw materials all can be realized the present invention.
The present invention compares with existing drier, has the following advantages:
(1) natural plant raw material, green product;
(2) nonpoisonous and tasteless, eat by mistake and do not have harm;
(3) eyes, skin there is not injury;
(4) hygroscopicity height, water holding capacity are strong;
(5) environmental friendliness, biodegradable.
The specific embodiment
Embodiment 1: it is made by following materials of weight proportions:
Prescription: 1 part of konjaku flour grafted propylene hydrochlorate
1 part of rice starch
Preparation method: (Chinese patent 1410463)
1. 4.5 parts of konjaku flours are added 100 parts of water (solid content 4.5%) after gelatinization under 40 ℃ of temperature, the passing ratio pump adds the acrylic acid (degree of neutralization is 80%) that partly neutralizes with NaOH of cooling, and konjaku flour and acrylic acid weight ratio are 1: 50.
2. add the potassium peroxydisulfate of 0.5Wt% and the N of 0.1Wt%, N '-methylene-bisacrylamide stirs and the protection of logical nitrogen, in the copolyreaction of 60 ℃ of temperature initiation graftings.
3. following reactant liquor to spray to enter temperature with nitrogen is that 90 ℃ helix tube type turbulent flow reactor carries out graft copolymerization, 240 seconds reaction time.
4. spiral is extruded and is sent into drum-type film forming drier, makes reactant be membranaceous drying, 140 ℃ of baking temperatures, 120 seconds drying times.
5. it is on chip that dry back water imbibition material is film, through being ground into 120 purpose particles, promptly gets konjaku flour grafted propylene hydrochlorate.
In the agitating type mixer with 1 part of konjaku graft acrylates and 1 part of rice mixing, expanded then, pulverize granulation, screening divides packing by quantitative racking machine.
At 25 ℃, under the condition of RH=90%, this drier hydroscopicity reaches 48%.
Acute oral toxicity test is the result show, and konjaku flour graft acrylic acid safety non-toxic (MTD>2000mg/kgBW); Acute skin irritation test is the result show, the konjaku flour graft acrylic acid is non-stimulated to skin; The biological degradability result of the test shows, konjaku flour graft acrylic acid biodegradable (aerobic composting test organism degradation rate>30%).
Embodiment 2: it is made by following materials of weight proportions:
Prescription: 0.5 part of starch grafted acrylate
5 parts of corns
The preparation method: with 0.5 part of starch grafted acrylate and 5 parts of rice mixings, expanded then in the agitating type mixer, pulverize granulation, screening divides packing by quantitative racking machine.
Embodiment 3: it is made by following materials of weight proportions:
Prescription: 0.2 part of chitin grafted propylene hydrochlorate
10 parts of stalks
The preparation method: with 0.2 part of chitin grafted propylene hydrochlorate and 10 parts of stalk mixings, expanded then in the agitating type mixer, pulverize granulation, screening divides packing by quantitative racking machine.
Embodiment 4: it is made by following materials of weight proportions:
Prescription: 0.5 part of cellulose graft acrylates
0.2 part in sawdust
The preparation method: with 0.5 part of cellulose graft acrylates and 0.2 part of sawdust mixing, expanded then in the agitating type mixer, pulverize granulation, screening divides packing by quantitative racking machine.
Embodiment 5: it is made by following materials of weight proportions:
Prescription: 1.5 parts of polyacrylates
20 parts of soybean
The preparation method: with 1.5 parts of polyacrylates and 20 parts of soybean mixings, expanded then in the agitating type mixer, pulverize granulation, screening divides packing by quantitative racking machine.
Embodiment 6: it is made by following materials of weight proportions:
Prescription: 1.8 parts of starch grafted acrylates
45 parts cassavas
The preparation method: with 1.8 parts of starch grafted acrylates and 45 parts of cassava mixings, expanded then in the agitating type mixer, pulverize granulation, screening divides packing by quantitative racking machine.
Embodiment 7: it is made by following materials of weight proportions:
Prescription: 2.5 parts of chitin grafted propylene hydrochlorates
0.3 part in rice
The preparation method: with 2.5 parts of chitin grafted propylene hydrochlorates and 0.3 part of rice mixing, expanded then in the agitating type mixer, pulverize granulation, screening divides packing by quantitative racking machine.
Embodiment 8: it is made by following materials of weight proportions:
Prescription: 4 parts of konjaku flour grafted propylene hydrochlorates
1 part of potato
2 parts of stalks
The preparation method is identical with embodiment 1
Embodiment 9: it is made by following materials of weight proportions:
Prescription: 3 parts of starch grafted acrylates
The preparation method: 3 parts of starch grafted acrylates is expanded in bulking machine, pulverize granulation, screening divides packing by fixed quantitative racking machine.
Embodiment 10: it is made by following materials of weight proportions:
Prescription: 3 parts of chitin grafted propylene hydrochlorates
0.5 part of polyacrylate
0.5 part of sweet potato
The preparation method: with 3 parts of chitin grafted propylene hydrochlorates, 0.5 part of polyacrylate and 0.5 part of sweet potato mixing, expanded then in the agitating type mixer, pulverize granulation, screening divides packing by quantitative racking machine.
Embodiment 11: it is made by following materials of weight proportions:
Prescription: 2 parts of cellulose graft acrylates
0.3 part of corn
The preparation method: with 2 parts of cellulose graft acrylates and 0.3 part of corn mixing, expanded then in the agitating type mixer, pulverize granulation, screening divides packing by quantitative racking machine.
Embodiment 12: it is made by following materials of weight proportions:
Prescription: 0.5 part of konjaku flour grafted propylene hydrochlorate
2 parts of cellulose graft acrylates
5 parts of wheats
15 parts in rice
The preparation method is identical with embodiment 1
Embodiment 13: it is made by following materials of weight proportions:
Prescription: 2.5 parts of chitin grafted propylene hydrochlorates
2 parts of starch grafted acrylates
The preparation method: with 2.5 parts of chitin grafted propylene hydrochlorates and 2 parts of starch grafted acrylate mixings, expanded then in the agitating type mixer, pulverize granulation, screening divides packing by quantitative racking machine.
Embodiment 14: it is made by following materials of weight proportions:
Prescription: 4 parts of polyacrylates
12 parts in rice
20 parts of stalks
The preparation method: with 4 parts of polyacrylates, 12 portions of rice and 20 parts of stalk mixings, expanded then in the agitating type mixer, pulverize granulation, screening divides packing by quantitative racking machine.
Embodiment 15: it is made by following materials of weight proportions:
Prescription: 2 parts of starch grafted acrylates
2 parts of polyacrylates
0.3 part of soybean
0.2 part of potato
The preparation method: with 2 parts of starch grafted acrylates, 2 parts of polyacrylates, 0.3 portion of soybean and 0.2 part of potato mixing, expanded then in the agitating type mixer, pulverize granulation, screening divides packing by quantitative racking machine.
In addition to the implementation, the present invention can also have other embodiments.Water-absorbing material is konjaku graft acrylates, starch grafted acrylate, chitin grafted propylene hydrochlorate, cellulose graft acrylates, polyacrylate or its a few person's mixtures, auxiliary material is rice, corn, soybean, cassava, potato, sweet potato, wheat, stalk, sawdust or its a few person's mixtures, the technical scheme that is equal to replacement or equivalent deformation of all employing two class materials can both realize the present invention.