CN100402566C - Edible deciccant - Google Patents

Edible deciccant Download PDF

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Publication number
CN100402566C
CN100402566C CNB2005100185808A CN200510018580A CN100402566C CN 100402566 C CN100402566 C CN 100402566C CN B2005100185808 A CNB2005100185808 A CN B2005100185808A CN 200510018580 A CN200510018580 A CN 200510018580A CN 100402566 C CN100402566 C CN 100402566C
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parts
edible
deciccant
acrylate
grafted
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CN1706544A (en
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姜发堂
李万芬
袁世炬
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Wuhan Licheng Biological Science & Technology Co Ltd
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Individual
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Abstract

The present invention discloses an edible dessicant. Materials with water absorption and auxiliary materials are evenly and proportionally mixed and puffed in a puffing machine, are pulverized in a pulverizer, and are granulated, sieved and packaged. The edible deciccant has the advantages of strong hydroscopic property capable of reaching 35% to 150% under the conditions of 25 DEG C and 90% of RH, strong water retention property, high security after being mistakenly eaten, no damage to skin and eyes, capable biodegradation, etc. The edible deciccant can be widely used for preventing moist and drying food, medicines, optical electron meters, precision instruments, meters, seeds, processed food, tea leaves, garments, footwear, leather, cultural relics, files, industrial arts, etc.

Description

Edible deciccant
Technical field
The present invention relates to a kind of edibility siccative, it is applicable to food; Medicine; Optical electron, precision instrument, instrument; Seed, processed food, tealeaves; The moistureproof drying of article such as clothes, footwear, leather and heritage archive, workmanship.
Background technology
The siccative that uses at present mainly is made as raw material with silica gel, montmorillonite and unslaked lime.
The wettability power of silica-gel drier is 35% of himself weight approximately, in the bigger environment of humidity, easily breaks behind the big water gaging of absorption, and the regeneration temperature height, its application is restricted.Silica gel color and luster shape as siccative is all more beautiful in addition, is eaten by mistake by child easily or is used as seasonings and eats.
The hygroscopic property of montmorillonite siccative is better, but wherein may contain heavy metallic salt and a large amount of other impurity, even some has radioactivity, and the siccative that abandons after using up can cause environmental pollution.
The unslaked lime siccative has stronger hygroscopic property, absorbs the calcium hydroxide of pulverize powder behind the moisture, and just the white lime known of people as long as become powder, has not just had desiccation.If eat this kind siccative by mistake, because of calcium oxide becomes release of heat in the process of calcium hydroxide, can burn oral cavity or esophagus meeting water.Simultaneously, calcium hydroxide is alkalescence, oropharynx, esophagus is corrosive, as is splashed into the damage that can cause conjunctiva and cornea in the eye.
Summary of the invention
The object of the present invention is to provide a kind of edible deciccant, this siccative does not have injury to skin, eyes, and eat by mistake and do not have harm, the water absorbability height, water retention capacity is strong, and is biodegradable.
In order to achieve the above object, technical solution of the present invention is: this edible deciccant is made up of water-absorbing material and auxiliary material, and its weight proportion is:
0.1~5 part of water-absorbing material (Rhizoma amorphophalli powder grafted propylene hydrochlorate or starch grafted acrylate or chitin grafted propylene hydrochlorate or cellulose graft acrylate or polyacrylate)
0.1~50 part of auxiliary material (rice or corn or soybean or cassava or potato or sweet potato or wheat or stalk or sawdust)
(1) water-absorbing material comprises:
A Rhizoma amorphophalli powder grafted propylene hydrochlorate (Chinese patent 1410463): in advance Rhizoma amorphophalli powder is added water after 30~60 ℃ of following gelatinizations; the passing ratio pump adds with alkali part neutral acrylate monomers; initiator (Potassium Persulphate or ammonium persulphate or ceric ammonium nitrate) and linking agent (N; N '-methylene-bisacrylamide or epoxy chloropropane or 1; the 4-butyleneglycol); stir and feed nitrogen or argon shield; after 30~70 ℃ of initiation grafting copolyreaction; follow the reaction solution injection to enter helix tube type turbulent flow reactor with nitrogen or argon gas and carry out graft copolymerization; react after 30~300 seconds; spiral is extruded and is sent into drum-type film forming moisture eliminator, makes reactant be membranaceous drying.Dry back product is the film sheet, through being ground into granular product.
B starch grafted acrylate (product)
C chitin grafted propylene hydrochlorate (product)
D cellulose graft acrylate (product)
E polyacrylate (product)
(2) auxiliary material comprises:
F Starch rice (product)
G W-Gum (product)
H soybean (product)
I cassava (product)
J potato (product)
K sweet potato (product)
L wheat (product)
M stalk (product)
N sawdust (product)
The edible deciccant preparation process is: water-absorbing material and auxiliary material mixed in stirring mixer, and expanded in bulking machine then, go in the pulverizer and pulverize, granulation then, screening divides packing by quantitative portioning machine, obtains edible deciccant.This product must add before use and pack airtight preservation.
Do not add auxiliary material, a kind of or water-absorbing material that is mixed arbitrarily of above-mentioned raw materials all can be realized the present invention.
The present invention compares with existing siccative, has the following advantages:
(1) natural plant raw material, green product;
(2) nonpoisonous and tasteless, eat by mistake and do not have harm;
(3) eyes, skin there is not injury;
(4) water absorbability height, water retention capacity are strong;
(5) environmental friendliness, biodegradable.
Embodiment
Embodiment 1: it is made by following materials of weight proportions:
Prescription: 1 part of Rhizoma amorphophalli powder grafted propylene hydrochlorate
1 part of Starch rice
Preparation method: (Chinese patent 1410463)
1. 4.5 parts of Rhizoma amorphophalli powders are added 100 parts of water (solid content 4.5%) after gelatinization under 40 ℃ of temperature, the passing ratio pump adds refrigerative with sodium hydroxide part neutral vinylformic acid (degree of neutralization is 80%), and Rhizoma amorphophalli powder and vinylformic acid weight ratio are 1: 50.
2. add the Potassium Persulphate of 0.5Wt% and the N of 0.1Wt%, N '-methylene-bisacrylamide stirs and the protection of logical nitrogen, in the copolyreaction of 60 ℃ of temperature initiation graftings.
3. following reaction solution to spray to enter temperature with nitrogen is that 90 ℃ helix tube type turbulent flow reactor carries out graft copolymerization, 240 seconds reaction times.
4. spiral is extruded and is sent into drum-type film forming moisture eliminator, makes reactant be membranaceous drying, 140 ℃ of drying temperatures, 120 seconds time of drying.
5. it is on chip that dry back water-absorbent material is film, through being ground into 120 purpose particles, promptly gets Rhizoma amorphophalli powder grafted propylene hydrochlorate.
In the stirring-type mixing machine with 1 part of konjaku graft acrylate and 1 part of rice mixing, expanded then, pulverize granulation, screening divides packing by quantitative portioning machine.
At 25 ℃, under the condition of RH=90%, this siccative rate of moisture absorption reaches 48%.
Acute oral toxicity test is the result show, and Rhizoma amorphophalli powder graft acrylic acid safety non-toxic (MTD>2000mg/kgBW); Acute skin irritation test is the result show, the Rhizoma amorphophalli powder graft acrylic acid is non-stimulated to skin; The biological degradability test-results shows, Rhizoma amorphophalli powder graft acrylic acid biodegradable (aerobic composting test organism degradation rate>30%).
Embodiment 2: it is made by following materials of weight proportions:
Prescription: 0.5 part of starch grafted acrylate
5 parts of corns
The preparation method: with 0.5 part of starch grafted acrylate and 5 parts of rice mixings, expanded then in the stirring-type mixing machine, pulverize granulation, screening divides packing by quantitative portioning machine.
Embodiment 3: it is made by following materials of weight proportions:
Prescription: 0.2 part of chitin grafted propylene hydrochlorate
10 parts of stalks
The preparation method: with 0.2 part of chitin grafted propylene hydrochlorate and 10 parts of stalk mixings, expanded then in the stirring-type mixing machine, pulverize granulation, screening divides packing by quantitative portioning machine.
Embodiment 4: it is made by following materials of weight proportions:
Prescription: 0.5 part of cellulose graft acrylate
0.2 part in sawdust
The preparation method: with 0.5 part of cellulose graft acrylate and 0.2 part of sawdust mixing, expanded then in the stirring-type mixing machine, pulverize granulation, screening divides packing by quantitative portioning machine.
Embodiment 5: it is made by following materials of weight proportions:
Prescription: 1.5 parts of polyacrylates
20 parts of soybean
The preparation method: with 1.5 parts of polyacrylates and 20 parts of soybean mixings, expanded then in the stirring-type mixing machine, pulverize granulation, screening divides packing by quantitative portioning machine.
Embodiment 6: it is made by following materials of weight proportions:
Prescription: 1.8 parts of starch grafted acrylates
45 parts cassavas
The preparation method: with 1.8 parts of starch grafted acrylates and 45 parts of cassava mixings, expanded then in the stirring-type mixing machine, pulverize granulation, screening divides packing by quantitative portioning machine.
Embodiment 7: it is made by following materials of weight proportions:
Prescription: 2.5 parts of chitin grafted propylene hydrochlorates
0.3 part in rice
The preparation method: with 2.5 parts of chitin grafted propylene hydrochlorates and 0.3 part of rice mixing, expanded then in the stirring-type mixing machine, pulverize granulation, screening divides packing by quantitative portioning machine.
Embodiment 8: it is made by following materials of weight proportions:
Prescription: 4 parts of Rhizoma amorphophalli powder grafted propylene hydrochlorates
1 part of potato
2 parts of stalks
The preparation method is identical with embodiment 1
Embodiment 9: it is made by following materials of weight proportions:
Prescription: 3 parts of starch grafted acrylates
The preparation method: 3 parts of starch grafted acrylates is expanded in bulking machine, pulverize granulation, screening divides packing by fixed quantitative portioning machine.
Embodiment 10: it is made by following materials of weight proportions:
Prescription: 3 parts of chitin grafted propylene hydrochlorates
0.5 part of polyacrylate
0.5 part of sweet potato
The preparation method: with 3 parts of chitin grafted propylene hydrochlorates, 0.5 part of polyacrylate and 0.5 part of sweet potato mixing, expanded then in the stirring-type mixing machine, pulverize granulation, screening divides packing by quantitative portioning machine.
Embodiment 11: it is made by following materials of weight proportions:
Prescription: 2 parts of cellulose graft acrylate
0.3 part of corn
The preparation method: with 2 parts of cellulose graft acrylate and 0.3 part of corn mixing, expanded then in the stirring-type mixing machine, pulverize granulation, screening divides packing by quantitative portioning machine.
Embodiment 12: it is made by following materials of weight proportions:
Prescription: 0.5 part of Rhizoma amorphophalli powder grafted propylene hydrochlorate
2 parts of cellulose graft acrylate
5 parts of wheats
15 parts in rice
The preparation method is identical with embodiment 1
Embodiment 13: it is made by following materials of weight proportions:
Prescription: 2.5 parts of chitin grafted propylene hydrochlorates
2 parts of starch grafted acrylates
The preparation method: with 2.5 parts of chitin grafted propylene hydrochlorates and 2 parts of starch grafted acrylate mixings, expanded then in the stirring-type mixing machine, pulverize granulation, screening divides packing by quantitative portioning machine.
Embodiment 14: it is made by following materials of weight proportions:
Prescription: 4 parts of polyacrylates
12 parts in rice
20 parts of stalks
The preparation method: with 4 parts of polyacrylates, 12 portions of rice and 20 parts of stalk mixings, expanded then in the stirring-type mixing machine, pulverize granulation, screening divides packing by quantitative portioning machine.
Embodiment 15: it is made by following materials of weight proportions:
Prescription: 2 parts of starch grafted acrylates
2 parts of polyacrylates
0.3 part of soybean
0.2 part of potato
The preparation method: with 2 parts of starch grafted acrylates, 2 parts of polyacrylates, 0.3 portion of soybean and 0.2 part of potato mixing, expanded then in the stirring-type mixing machine, pulverize granulation, screening divides packing by quantitative portioning machine.
In addition to the implementation, the present invention can also have other embodiments.Water-absorbing material is konjaku graft acrylate, starch grafted acrylate, chitin grafted propylene hydrochlorate, cellulose graft acrylate, polyacrylate or its a few person's mixtures, auxiliary material is rice, corn, soybean, cassava, potato, sweet potato, wheat, stalk, sawdust or its a few person's mixtures, the technical scheme that is equal to replacement or equivalent deformation of all employing two class materials can both realize the present invention.

Claims (10)

1. edible deciccant, it is made by following materials of weight proportions:
0.1~50 part in 0.1~5 part of Rhizoma amorphophalli powder grafted propylene hydrochlorate or starch grafted acrylate or chitin grafted propylene hydrochlorate or cellulose graft acrylate or polyacrylate and rice or corn or soybean or cassava or potato or sweet potato or wheat or stalk or sawdust.
2. a kind of edible deciccant according to claim 1 is characterized in that:
1 part of Rhizoma amorphophalli powder grafted propylene hydrochlorate
1 part in rice.
3. a kind of edible deciccant according to claim 1 is characterized in that:
0.5 part of starch grafted acrylate
5 parts of corns.
4. a kind of edible deciccant according to claim 1 is characterized in that:
0.2 part of chitin grafted propylene hydrochlorate
10 parts of stalks.
5. a kind of edible deciccant according to claim 1 is characterized in that:
0.5 part of cellulose graft acrylate
0.2 part in sawdust.
6. a kind of edible deciccant according to claim 1 is characterized in that:
1.5 parts of polyacrylates
20 parts of soybean.
7. a kind of edible deciccant according to claim 1 is characterized in that:
1.8 parts of starch grafted acrylates
45 parts cassavas.
8. a kind of edible deciccant according to claim 1 is characterized in that:
4 parts of Rhizoma amorphophalli powder grafted propylene hydrochlorates
1 part of potato
2 parts of stalks.
9. a kind of edible deciccant according to claim 1 is characterized in that:
3 parts of chitin grafted propylene hydrochlorates
0.5 part of polyacrylate
0.5 part of sweet potato.
10. a kind of edible deciccant according to claim 1 is characterized in that:
0.5 part of Rhizoma amorphophalli powder grafted propylene hydrochlorate
2 parts of cellulose graft acrylate
5 parts of wheats
15 parts in rice.
CNB2005100185808A 2005-04-19 2005-04-19 Edible deciccant Active CN100402566C (en)

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CN100402566C true CN100402566C (en) 2008-07-16

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Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1830543B (en) * 2006-02-17 2012-05-30 武汉力诚生物科技有限公司 Drying agent and preparation method
CN101549243B (en) * 2009-04-14 2011-07-20 张红军 Desiccant composition
CN102600705B (en) * 2012-04-10 2014-06-04 福建省中医药研究院 Edible plant dryer
CN106552481A (en) * 2015-09-30 2017-04-05 明光市龙腾矿物有限公司 A kind of mineral drier
CN105413416B (en) * 2015-10-16 2017-12-19 晋江拓普旺防霉材料有限公司 A kind of edibility non-toxic desiccant
CN105944687B (en) * 2016-06-21 2019-09-20 深圳市春旺环保科技股份有限公司 A kind of desiccant and its preparation process
CN106669632A (en) * 2017-01-16 2017-05-17 苏州苏米欧贸易有限公司 Environment-friendly desiccant
CN106721911A (en) * 2017-01-18 2017-05-31 苏州苏米欧贸易有限公司 A kind of food drier
CN106512674A (en) * 2017-01-19 2017-03-22 苏州苏米欧贸易有限公司 Harmless drying agent
CN109248664A (en) * 2017-07-12 2019-01-22 武汉力诚生物科技有限公司 A kind of powder desiccant
CN108786752A (en) * 2018-07-06 2018-11-13 吴勇 A kind of safe drier based on biodegradated polymer materal
CN110229015A (en) * 2019-07-09 2019-09-13 北部湾大学 A kind of pottery mud hybrid desiccant and preparation method thereof, regeneration method

Citations (3)

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Publication number Priority date Publication date Assignee Title
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CN1055185A (en) * 1990-03-24 1991-10-09 中国科学院广州化学研究所 Water-absorption material produced by graft modification with cellulose initiated by potassium permanganate
CN1410463A (en) * 2002-11-26 2003-04-16 姜发堂 Superstrong water absorber and its preparation method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4155888A (en) * 1978-04-17 1979-05-22 A. E. Staley Manufacturing Company Water-absorbent starches
CN1055185A (en) * 1990-03-24 1991-10-09 中国科学院广州化学研究所 Water-absorption material produced by graft modification with cellulose initiated by potassium permanganate
CN1410463A (en) * 2002-11-26 2003-04-16 姜发堂 Superstrong water absorber and its preparation method

Non-Patent Citations (2)

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Title
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Owner name: WUHAN LICHENG BIOLOGICAL SCIENCE + TECHNOLOGY CO.,

Free format text: FORMER OWNER: JIANG FATANG

Effective date: 20130129

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Effective date of registration: 20130129

Address after: 430068 1 South tech Industrial Park, East Lake Development Zone, Wuhan, Hubei

Patentee after: Wuhan Licheng Biological Science & Technology Co., Ltd.

Address before: 430068 No. 1, Xinyu Bay, Hongshan District, Hubei, Wuhan

Patentee before: Jiang Fatang