CN1705148A - 一种锂离子电池负极材料的改性方法 - Google Patents
一种锂离子电池负极材料的改性方法 Download PDFInfo
- Publication number
- CN1705148A CN1705148A CNA2004100206068A CN200410020606A CN1705148A CN 1705148 A CN1705148 A CN 1705148A CN A2004100206068 A CNA2004100206068 A CN A2004100206068A CN 200410020606 A CN200410020606 A CN 200410020606A CN 1705148 A CN1705148 A CN 1705148A
- Authority
- CN
- China
- Prior art keywords
- negative material
- lithium ion
- ion battery
- modifying
- battery negative
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims description 38
- 229910001416 lithium ion Inorganic materials 0.000 title claims description 34
- 239000007773 negative electrode material Substances 0.000 title 1
- 239000000463 material Substances 0.000 claims abstract description 55
- 229910021392 nanocarbon Inorganic materials 0.000 claims abstract description 23
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 11
- 229910052751 metal Inorganic materials 0.000 claims abstract description 10
- 239000002184 metal Substances 0.000 claims abstract description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052802 copper Inorganic materials 0.000 claims abstract description 9
- 239000010949 copper Substances 0.000 claims abstract description 9
- 229910052709 silver Inorganic materials 0.000 claims abstract description 9
- 239000004332 silver Substances 0.000 claims abstract description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003575 carbonaceous material Substances 0.000 claims abstract description 8
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 8
- 239000010703 silicon Substances 0.000 claims abstract description 8
- 229910052755 nonmetal Inorganic materials 0.000 claims abstract description 7
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052718 tin Inorganic materials 0.000 claims abstract description 6
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 5
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052796 boron Inorganic materials 0.000 claims abstract description 5
- 239000011135 tin Substances 0.000 claims abstract description 5
- 150000001875 compounds Chemical class 0.000 claims abstract description 3
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 33
- 238000005229 chemical vapour deposition Methods 0.000 claims description 10
- 206010070834 Sensitisation Diseases 0.000 claims description 6
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 claims description 6
- 230000004913 activation Effects 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 claims description 6
- 230000008313 sensitization Effects 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 claims description 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 239000011651 chromium Substances 0.000 claims description 4
- 238000007747 plating Methods 0.000 claims description 4
- 239000007791 liquid phase Substances 0.000 claims description 3
- -1 silane compound Chemical class 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 2
- 238000005137 deposition process Methods 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 150000002430 hydrocarbons Chemical class 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- 239000012286 potassium permanganate Substances 0.000 claims description 2
- 238000012545 processing Methods 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- 229910000077 silane Inorganic materials 0.000 claims description 2
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 claims description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract description 5
- 229910052744 lithium Inorganic materials 0.000 abstract description 5
- 238000002715 modification method Methods 0.000 abstract description 2
- 238000005253 cladding Methods 0.000 abstract 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 10
- 239000004917 carbon fiber Substances 0.000 description 10
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 9
- 239000002131 composite material Substances 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- 229910052786 argon Inorganic materials 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000011339 hard pitch Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 239000010406 cathode material Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000002931 mesocarbon microbead Substances 0.000 description 1
- 239000002121 nanofiber Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000011295 pitch Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Battery Electrode And Active Subsutance (AREA)
Abstract
一种锂离子电池负极材料的改性方法，负极材料为一维纳米炭材料或一维纳米炭材料与碳质、锡基、硅基材料的复合物，一维纳米炭材料的直径范围在1nm－500nm之间，其特征在于：对负极材料表面进行金属与非金属间隔多层包覆处理，金属采用锡、铜、银、铬，非金属采用碳、硅、硼。本发明方法对锂离子电池负极材料的改性提高了锂离子电池负极的储锂容量、循环特性、动力学性能。
Description
技术领域：
本发明方法涉及锂离子电池负极材料的改性方法，本发明方法特别提供了一种间隔多层包覆的方法改进锂离子电池负极材料的性能。
背景技术：
锂离子电池是一种新型高效的化学电源，被广泛应用于便携式电子产品的配套电源。随着材料技术进步和电池设计即使的改进，锂离子电池的应用范围可望从信息产业进一步拓展到能源交通、航天航空、国防等领域。这也对锂离子电池的使用寿命、放电倍率等性能提出了更高要求。锂离子电池性能的提高在很大程度上决定于负极材料性能和比容量的改善。
纳米炭管和纳米纤维是具有准一维结构的纳米炭材料，具有长径比大、比强度高、导电性能好、化学稳定性好等特点。纳米炭纤维/纳米炭管既可单独用做锂离子电池负极，也可以一定比例加入其他负极材料组成复合负极材料。
本发明方法提出了一种纳米炭管/纳米炭纤维锂离子负极材料或纳米炭管/纳米炭纤维复合锂离子电池负极的表面间隔包覆改性方法，具有显著提高其储锂容量、循环特性、动力学性能等特点。
发明内容：
本发明方法的目的在于通过改性锂离子电池负极材料来提高锂离子电池的储锂容量、循环特性、动力学性能。
本发明方法提供了一种锂离子电池负极材料的改性方法，负极材料为一维纳米炭材料或一维纳米炭材料与碳质、锡基、硅基材料的复合物，一维纳米炭材料的直径范围在1nm-500nm之间，其特征在于：对负极材料表面进行金属与非金属间隔多层包覆处理，金属采用锡、铜、银、铬，非金属采用碳、硅、硼。
锂离子电池负极材料的改性方法，在所述负极材料上第一层包覆金属，有锡、铜、银、铬。
锂离子电池负极材料的改性方法，在所述负极材料上第一层包覆金属的方法是化学镀。
锂离子电池负极材料的改性方法，在所述负极材料上第二层包覆非金属，有碳、硅、硼
锂离子电池负极材料的改性方法，在所述负极材料上第二层包覆非金属的方法有化学气相沉积、先包覆前驱体再高温处理二种。
锂离子电池负极材料的改性方法，所述化学镀方法是对负极材料在重铬酸钾、高锰酸钾或硫代硫酸盐的氧化下，分别经氯化锡和氯化钯敏化和活化后，在硫酸铜或硝酸银溶液中电镀。
锂离子电池负极材料的改性方法，所述化学气相沉积处理是以碳氢化合物为碳源，在600-800乇压力和800-1200℃温度或以硅烷类化合物为硅源在600-800乇压力和500-800℃下进行沉积处理。
锂离子电池负极材料的改性方法，所述先包覆液相前驱体再高温处理是将负极材料与沥青、树脂混合均匀，在惰性气氛和900-1200℃条件下处理3-6小时。
本发明方法对锂离子电池负极材料的改性提高了锂离子电池负极的储锂容量、循环特性、动力学性能。
具体实施方式：
实施例1：
选用平均直径150nm的纳米炭纤维首先在重铬酸钾溶液中氧化1小时，再分别于氯化锡和氯化钯溶液中敏化和活化，之后在硫酸铜溶液中电镀，得到表面包覆铜的纳米炭纤维负极材料；将其与高温沥青均匀混合后在氩气气氛下1100℃处理3小时，得到表面包覆铜和碳层的纳米炭纤维负极材料。按常规锂离子电池负极评价方法检测结果为：500次循环充放电后容量提高10％，首次容量提高30％，首次效率保持不变。
实施例2：
选用平均直径250nm的纳米炭纤维首先在重铬酸钾溶液中氧化1小时，再分别于氯化锡和氯化钯溶液中敏化和活化，之后在硝酸银溶液中电镀，得到表面包覆银的纳米炭纤维负极材料；以丙烷为碳源在1000℃下化学气相沉积2小时，得到表面包覆银和碳层的纳米炭纤维负极材料。按常规锂离子电池负极评价方法检测结果为：500次循环充放电后容量提高15％，首次容量提高35％，首次效率保持不变。
实施例3：
选用平均直径90nm的纳米炭管(10wt％)/中间相炭微球复合负极材料首先在重铬酸钾溶液中氧化1小时，再分别于氯化锡和氯化钯溶液中敏化和活化，之后在硝酸银溶液中电镀，得到表面包覆铜的复合负极材料；以丙烷为碳源在1000℃下化学气相沉积2小时，得到表面包覆铜和碳层的复合负极材料。按常规锂离子电池负极评价方法检测结果为：500次循环充放电后容量提高18％，首次容量提高30％，首次效率保持不变。
实施例4：
选用平均直径200nm的纳米炭纤维(重量比8％)/天然石墨复合负极材料，首先在重铬酸钾溶液中氧化1小时，再分别于氯化锡和氯化钯溶液中敏化和活化，之后在硝酸银溶液中电镀，得到表面包覆银的复合负极材料；将其与高温沥青均匀混合后在氩气气氛下1100℃处理3小时得到表面包覆银和碳层的复合负极。按常规锂离子电池负极评价方法检测结果为：500次循环充放电后容量提高20％，首次容量提高20％，首次效率保持不变。
Claims (8)
1、一种锂离子电池负极材料的改性方法，负极材料为一维纳米炭材料或一维纳米炭材料与炭质、锡基、硅基材料的复合物，一维纳米炭材料的直径范围在1nm-500nm之间，其特征在于：对负极材料表面进行金属与非金属间隔多层包覆处理，金属采用锡、铜、银、铬，非金属采用碳、硅、硼。
2、按照权利要求1所述锂离子电池负极材料的改性方法，其特征在于：在所述负极材料上第一层包覆金属有锡、铜、银、铬。
3、按照权利要求2所述锂离子电池负极材料的改性方法，其特征在于：在所述负极材料上第一层包覆金属的方法是化学镀。
4、按照权利要求2所述锂离子电池负极材料的改性方法，其特征在于：在所述负极材料上第二层包覆非金属，碳、硅、硼
5、按照权利要求4所述锂离子电池负极材料的改性方法，其特征在于：在所述负极材料上第二层包覆非金属的方法有化学气相沉积、先包覆液相前驱体再高温处理二种。
6、按照权利要求3所述锂离子电池负极材料的改性方法，其特征在于：所述化学镀方法是负极材料在重铬酸钾、高锰酸钾或硫代硫酸盐氧化，再经氯化锡敏化和氯化钯活化，最后在硫酸铜或硝酸银溶液中电镀。
7、按照权利要求5所述锂离子电池负极材料的改性方法，其特征在于：所述化学气相沉积处理是以碳氢化合物为碳源，在600-800乇压力和800-1200℃温度或以硅烷类化合物为硅源在600-800乇压力和500-800℃下进行沉积处理。
8、按照权利要求5所述锂离子电池负极材料的改性方法，其特征在于：所述先包覆液相前驱体再高温处理是将负极材料与沥青、树脂混合均匀，在惰性气氛和900-1200℃条件下处理3-6小时。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100206068A CN100338796C (zh) | 2004-05-26 | 2004-05-26 | 一种锂离子电池负极材料的改性方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100206068A CN100338796C (zh) | 2004-05-26 | 2004-05-26 | 一种锂离子电池负极材料的改性方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1705148A true CN1705148A (zh) | 2005-12-07 |
| CN100338796C CN100338796C (zh) | 2007-09-19 |
Family
ID=35577543
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100206068A Expired - Fee Related CN100338796C (zh) | 2004-05-26 | 2004-05-26 | 一种锂离子电池负极材料的改性方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100338796C (zh) |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101986442A (zh) * | 2010-05-25 | 2011-03-16 | 耿世达 | 一种内部含有三维导电结构的锂离子电池负极材料及其制备方法 |
| CN101626075B (zh) * | 2009-08-03 | 2011-03-30 | 北京化工大学 | 锡碳复合纳米纤维薄膜负极材料及其制备方法 |
| CN102122708A (zh) * | 2010-01-08 | 2011-07-13 | 中国科学院物理研究所 | 用于锂离子二次电池的负极材料、含该负极材料的负极及其制备方法以及含该负极的电池 |
| CN102185142A (zh) * | 2011-04-08 | 2011-09-14 | 厦门大学 | 锂离子电池用复合碳负极材料及其制备方法 |
| CN102324508A (zh) * | 2011-09-14 | 2012-01-18 | 耿世达 | 一种内部含有三维导电结构的合金包覆负极材料及其制备方法 |
| CN102479948A (zh) * | 2010-11-30 | 2012-05-30 | 比亚迪股份有限公司 | 一种锂离子电池的负极活性材料及其制备方法以及一种锂离子电池 |
| CN102844917A (zh) * | 2010-03-03 | 2012-12-26 | 安普雷斯股份有限公司 | 用于沉积活性材料的模板电极结构 |
| US9172088B2 (en) | 2010-05-24 | 2015-10-27 | Amprius, Inc. | Multidimensional electrochemically active structures for battery electrodes |
| CN105098163A (zh) * | 2014-05-16 | 2015-11-25 | 微宏动力系统（湖州）有限公司 | 一种包覆型电极材料的制备方法 |
| TWI565654B (zh) * | 2014-08-08 | 2017-01-11 | Kureha Corp | Production method of carbonaceous material for negative electrode of nonaqueous electrolyte secondary battery and carbonaceous material for negative electrode of nonaqueous electrolyte secondary battery |
| WO2017024898A1 (zh) * | 2015-08-07 | 2017-02-16 | 田东 | 一种高容量锡碳负极材料的制备方法 |
| CN107093710A (zh) * | 2017-03-31 | 2017-08-25 | 宁夏博尔特科技有限公司 | 双包覆层锂离子电池负极材料及其制备方法和锂离子电池 |
| US9780365B2 (en) | 2010-03-03 | 2017-10-03 | Amprius, Inc. | High-capacity electrodes with active material coatings on multilayered nanostructured templates |
| US9923201B2 (en) | 2014-05-12 | 2018-03-20 | Amprius, Inc. | Structurally controlled deposition of silicon onto nanowires |
| US10090512B2 (en) | 2009-05-07 | 2018-10-02 | Amprius, Inc. | Electrode including nanostructures for rechargeable cells |
| US10096817B2 (en) | 2009-05-07 | 2018-10-09 | Amprius, Inc. | Template electrode structures with enhanced adhesion characteristics |
| WO2019114373A1 (zh) * | 2017-12-12 | 2019-06-20 | 中国科学院物理研究所 | 一种复合包覆的纳米锡负极材料及其制备方法和应用 |
| US10411261B2 (en) | 2014-08-08 | 2019-09-10 | Kureha Corporation | Carbonaceous material for non-aqueous electrolyte secondary battery anodes |
| US10424790B2 (en) | 2014-08-08 | 2019-09-24 | Kureha Corporation | Carbonaceous material for non-aqueous electrolyte secondary battery anode |
| US11121396B2 (en) | 2009-11-11 | 2021-09-14 | Amprius, Inc. | Intermediate layers for electrode fabrication |
| US11996550B2 (en) | 2009-05-07 | 2024-05-28 | Amprius Technologies, Inc. | Template electrode structures for depositing active materials |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6280697B1 (en) * | 1999-03-01 | 2001-08-28 | The University Of North Carolina-Chapel Hill | Nanotube-based high energy material and method |
| US20030152835A1 (en) * | 2002-02-08 | 2003-08-14 | Sankar Dasgupta | Carbon fibre containing negative electrode for lithium battery |
-
2004
- 2004-05-26 CN CNB2004100206068A patent/CN100338796C/zh not_active Expired - Fee Related
Cited By (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10090512B2 (en) | 2009-05-07 | 2018-10-02 | Amprius, Inc. | Electrode including nanostructures for rechargeable cells |
| US11996550B2 (en) | 2009-05-07 | 2024-05-28 | Amprius Technologies, Inc. | Template electrode structures for depositing active materials |
| US11024841B2 (en) | 2009-05-07 | 2021-06-01 | Amprius, Inc. | Template electrode structures for depositing active materials |
| US10811675B2 (en) | 2009-05-07 | 2020-10-20 | Amprius, Inc. | Electrode including nanostructures for rechargeable cells |
| US10230101B2 (en) | 2009-05-07 | 2019-03-12 | Amprius, Inc. | Template electrode structures for depositing active materials |
| US10096817B2 (en) | 2009-05-07 | 2018-10-09 | Amprius, Inc. | Template electrode structures with enhanced adhesion characteristics |
| US9172094B2 (en) | 2009-05-07 | 2015-10-27 | Amprius, Inc. | Template electrode structures for depositing active materials |
| CN101626075B (zh) * | 2009-08-03 | 2011-03-30 | 北京化工大学 | 锡碳复合纳米纤维薄膜负极材料及其制备方法 |
| US11121396B2 (en) | 2009-11-11 | 2021-09-14 | Amprius, Inc. | Intermediate layers for electrode fabrication |
| CN102122708A (zh) * | 2010-01-08 | 2011-07-13 | 中国科学院物理研究所 | 用于锂离子二次电池的负极材料、含该负极材料的负极及其制备方法以及含该负极的电池 |
| US9780365B2 (en) | 2010-03-03 | 2017-10-03 | Amprius, Inc. | High-capacity electrodes with active material coatings on multilayered nanostructured templates |
| CN102844917A (zh) * | 2010-03-03 | 2012-12-26 | 安普雷斯股份有限公司 | 用于沉积活性材料的模板电极结构 |
| CN105206794A (zh) * | 2010-03-03 | 2015-12-30 | 安普雷斯股份有限公司 | 用于沉积活性材料的模板电极结构 |
| CN102844917B (zh) * | 2010-03-03 | 2015-11-25 | 安普雷斯股份有限公司 | 用于沉积活性材料的模板电极结构 |
| CN105206794B (zh) * | 2010-03-03 | 2018-02-23 | 安普瑞斯股份有限公司 | 用于沉积活性材料的模板电极结构 |
| US9172088B2 (en) | 2010-05-24 | 2015-10-27 | Amprius, Inc. | Multidimensional electrochemically active structures for battery electrodes |
| CN101986442A (zh) * | 2010-05-25 | 2011-03-16 | 耿世达 | 一种内部含有三维导电结构的锂离子电池负极材料及其制备方法 |
| US9029020B2 (en) | 2010-11-30 | 2015-05-12 | Shenzhen Byd Auto R&D Company Limited | Negative active material, method for preparing the same and lithium ion battery comprising the same |
| CN102479948B (zh) * | 2010-11-30 | 2015-12-02 | 比亚迪股份有限公司 | 一种锂离子电池的负极活性材料及其制备方法以及一种锂离子电池 |
| CN102479948A (zh) * | 2010-11-30 | 2012-05-30 | 比亚迪股份有限公司 | 一种锂离子电池的负极活性材料及其制备方法以及一种锂离子电池 |
| CN102185142A (zh) * | 2011-04-08 | 2011-09-14 | 厦门大学 | 锂离子电池用复合碳负极材料及其制备方法 |
| CN102324508A (zh) * | 2011-09-14 | 2012-01-18 | 耿世达 | 一种内部含有三维导电结构的合金包覆负极材料及其制备方法 |
| US9923201B2 (en) | 2014-05-12 | 2018-03-20 | Amprius, Inc. | Structurally controlled deposition of silicon onto nanowires |
| US11855279B2 (en) | 2014-05-12 | 2023-12-26 | Amprius Technologies, Inc. | Structurally controlled deposition of silicon onto nanowires |
| US11289701B2 (en) | 2014-05-12 | 2022-03-29 | Amprius, Inc. | Structurally controlled deposition of silicon onto nanowires |
| CN105098163A (zh) * | 2014-05-16 | 2015-11-25 | 微宏动力系统（湖州）有限公司 | 一种包覆型电极材料的制备方法 |
| CN105098163B (zh) * | 2014-05-16 | 2017-09-29 | 微宏动力系统（湖州）有限公司 | 一种包覆型电极材料的制备方法 |
| US10424790B2 (en) | 2014-08-08 | 2019-09-24 | Kureha Corporation | Carbonaceous material for non-aqueous electrolyte secondary battery anode |
| US10797319B2 (en) | 2014-08-08 | 2020-10-06 | Kureha Corporation | Production method for carbonaceous material for non-aqueous electrolyte secondary battery anode, and carbonaceous material for non-aqueous electrolyte secondary battery anode |
| US10411261B2 (en) | 2014-08-08 | 2019-09-10 | Kureha Corporation | Carbonaceous material for non-aqueous electrolyte secondary battery anodes |
| TWI565654B (zh) * | 2014-08-08 | 2017-01-11 | Kureha Corp | Production method of carbonaceous material for negative electrode of nonaqueous electrolyte secondary battery and carbonaceous material for negative electrode of nonaqueous electrolyte secondary battery |
| WO2017024898A1 (zh) * | 2015-08-07 | 2017-02-16 | 田东 | 一种高容量锡碳负极材料的制备方法 |
| CN107093710B (zh) * | 2017-03-31 | 2019-10-08 | 宁夏博尔特科技有限公司 | 双包覆层锂离子电池负极材料及其制备方法和锂离子电池 |
| CN107093710A (zh) * | 2017-03-31 | 2017-08-25 | 宁夏博尔特科技有限公司 | 双包覆层锂离子电池负极材料及其制备方法和锂离子电池 |
| JP2021506056A (ja) * | 2017-12-12 | 2021-02-18 | 中国科学院物理研究所 | 複合被覆ナノスズ負極材料並びにその製造方法及び使用 |
| WO2019114373A1 (zh) * | 2017-12-12 | 2019-06-20 | 中国科学院物理研究所 | 一种复合包覆的纳米锡负极材料及其制备方法和应用 |
| US11362328B2 (en) | 2017-12-12 | 2022-06-14 | Institute Of Physics, Chinese Academy Of Sciences | Composite-coated nano-tin negative electrode material and preparation method and use thereof |
| JP7299214B2 (ja) | 2017-12-12 | 2023-06-27 | 中国科学院物理研究所 | 複合被覆ナノスズ負極材料並びにその製造方法及び使用 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100338796C (zh) | 2007-09-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100338796C (zh) | 一种锂离子电池负极材料的改性方法 | |
| Jian et al. | Flexible diamond fibers for high‐energy‐density zinc‐ion supercapacitors | |
| Cao et al. | Eliminating Zn dendrites by commercial cyanoacrylate adhesive for zinc ion battery | |
| Wang et al. | Sn alloying to inhibit hydrogen evolution of Zn metal anode in rechargeable aqueous batteries | |
| Zheng et al. | Electrostatic shielding regulation of magnetron sputtered Al-based alloy protective coatings enables highly reversible zinc anodes | |
| Yu et al. | Vertical‐graphene‐reinforced titanium alloy bipolar plates in fuel cells | |
| US9138964B2 (en) | Surface-treated copper foil | |
| CN103022418B (zh) | 一种碳纳米管增强的锡铜镍合金负极及其制备方法 | |
| Deng et al. | A hierarchical copper oxide–germanium hybrid film for high areal capacity lithium ion batteries | |
| US20240097138A1 (en) | Composite material and preparation method thereof, negative electrode material, and lithium ion battery | |
| Uysal et al. | Sn–Ni/MWCNT nanocomposite negative electrodes for Li-ion batteries: the effect of Sn: Ni molar ratio | |
| CN103627923B (zh) | 一种高导热低摩擦系数导电材料及其制备方法 | |
| Liu et al. | Interrelation Between External Pressure, SEI Structure, and Electrodeposit Morphology in an Anode‐Free Lithium Metal Battery | |
| Ren et al. | Long‐cycling Zinc Metal Anodes Enabled by an In Situ Constructed ZnO Coating Layer | |
| Hou et al. | Ni-Al nanocomposite coating electrodeposited from deep eutectic solvent | |
| Arai et al. | A carbon nanotube-reinforced noble tin anode structure for lithium-ion batteries | |
| Zhao et al. | Electrochemical performance of Sn film reinforced by Cu nanowire | |
| Zhang et al. | Enabling the conventional TFSI-based electrolytes for high-performance Mg/Li hybrid batteries by Mg electrode interfacial regulation | |
| Zhao et al. | A new secondary battery technology: Electrode structure and charge–discharge mechanism of all-solid-state zinc-graphite batteries | |
| Lai et al. | Enhancing Zinc Electrode Stability Through Pre‐Desolvation and Accelerated Charge Transfer via a Polyimide Interface for Zinc‐Ion Batteries | |
| Wang et al. | Synergistic Effect of 3D Elastomer/Super‐Ionic Conductor Hybrid Fiber Networks Enables Zinc Anode Protection for Aqueous Zinc‐Ion Batteries | |
| Gao et al. | Electrochemical characteristics of electroplating and impregnation Ni-P/SiC/PTFE composite coating on 316L stainless steel | |
| Guo et al. | Fabrication of high-performance carbon nanotube/copper composite fibers by interface thiol-modification | |
| Zhang et al. | Influence of carbon fibers on interfacial bonding properties of copper-coated carbon fibers | |
| Sutrisnoh et al. | Toward High‐Capacity Carbon Fiber Cathodes for Structural Batteries using Electrophoretic Deposition: Effects of Oxidative Surface Treatment on Carbon Fibers |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20070919 Termination date: 20200526 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |