CN1680258B - 无定形水溶性柠檬酸钙盐及其制备和应用方法 - Google Patents
无定形水溶性柠檬酸钙盐及其制备和应用方法 Download PDFInfo
- Publication number
- CN1680258B CN1680258B CN200510056560XA CN200510056560A CN1680258B CN 1680258 B CN1680258 B CN 1680258B CN 200510056560X A CN200510056560X A CN 200510056560XA CN 200510056560 A CN200510056560 A CN 200510056560A CN 1680258 B CN1680258 B CN 1680258B
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- Prior art keywords
- calcium
- citrate
- amorphous
- water
- liquid composition
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- 238000004519 manufacturing process Methods 0.000 title description 8
- 239000011575 calcium Substances 0.000 claims abstract description 239
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 234
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 233
- 239000000203 mixture Substances 0.000 claims abstract description 143
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims abstract description 118
- 239000007788 liquid Substances 0.000 claims abstract description 92
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- 238000000034 method Methods 0.000 claims abstract description 39
- 150000003839 salts Chemical class 0.000 claims abstract description 27
- 239000001354 calcium citrate Substances 0.000 claims abstract description 12
- 235000013337 tricalcium citrate Nutrition 0.000 claims abstract description 12
- 238000003860 storage Methods 0.000 claims abstract description 8
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 115
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- QXDHJHQRJCJRAU-UHFFFAOYSA-N calcium;2-hydroxypropane-1,2,3-tricarboxylic acid Chemical compound [Ca].OC(=O)CC(O)(C(O)=O)CC(O)=O QXDHJHQRJCJRAU-UHFFFAOYSA-N 0.000 description 4
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- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 208000001132 Osteoporosis Diseases 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
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- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C59/235—Saturated compounds containing more than one carboxyl group
- C07C59/245—Saturated compounds containing more than one carboxyl group containing hydroxy or O-metal groups
- C07C59/265—Citric acid
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- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/385—Concentrates of non-alcoholic beverages
- A23L2/39—Dry compositions
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- C07C51/41—Preparation of salts of carboxylic acids
- C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part
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Abstract
Description
钙∶柠檬酸摩尔比 | 含钙量(%) | 溶液pH值 | 溶液最初的外观 |
1∶2 | 9.5 | 3.4 | 无混浊;无沉降物 |
1.5∶2 | 13.6 | 3.8 | 无混浊;无沉降物 |
2∶2 | 17.4 | 4.1 | 无混浊;无沉降物 |
2.25∶2 | 19.2 | 4.3 | 无混浊;无沉降物 |
2.4∶2 | 20.2 | 4.4 | 无混浊;无沉降物 |
2.5∶2 | 20.9 | 4.5 | 轻微混浊;有些沉降物(细微) |
钙∶柠檬酸摩尔比 | 含钙量(%) | 溶液pH值 | 溶液最初的外观 |
3∶2 | 24.1 | 5.4 | 中等混浊;更多沉降物(细微) |
3∶2* | 21.1 | 5.9 | 乳状混浊;沉降物最多(粗糙) |
Claims (29)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/781106 | 2004-02-18 | ||
US10/781,106 US7267832B2 (en) | 2004-02-18 | 2004-02-18 | Amorphous water-soluble calcium citrate salts and method of making and using same |
Publications (2)
Publication Number | Publication Date |
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CN1680258A CN1680258A (zh) | 2005-10-12 |
CN1680258B true CN1680258B (zh) | 2010-06-16 |
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CN200510056560XA Active CN1680258B (zh) | 2004-02-18 | 2005-02-17 | 无定形水溶性柠檬酸钙盐及其制备和应用方法 |
Country Status (12)
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US (2) | US7267832B2 (zh) |
EP (1) | EP1566373B2 (zh) |
CN (1) | CN1680258B (zh) |
AR (1) | AR047680A1 (zh) |
AT (1) | ATE401295T1 (zh) |
BR (1) | BRPI0500418A (zh) |
DE (1) | DE602005008123D1 (zh) |
MX (1) | MXPA05001942A (zh) |
PT (1) | PT1566373E (zh) |
RU (1) | RU2363269C2 (zh) |
TR (1) | TR200500481A2 (zh) |
ZA (1) | ZA200500930B (zh) |
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CN102633627A (zh) * | 2012-04-01 | 2012-08-15 | 江南大学 | 固相合成柠檬酸钙的方法 |
US11013248B2 (en) | 2012-05-25 | 2021-05-25 | Kraft Foods Group Brands Llc | Shelf stable, concentrated, liquid flavorings and methods of preparing beverages with the concentrated liquid flavorings |
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CN105418407B (zh) * | 2015-12-29 | 2018-01-30 | 日照金禾博源生化有限公司 | 一种可溶性三水柠檬酸钙的生产工艺 |
US10939694B2 (en) | 2016-10-25 | 2021-03-09 | Third Wave Water Llc | Drink water treatment composition, and method of making a drink water treatment composition |
IT201700099690A1 (it) * | 2017-09-06 | 2019-03-06 | Abiogen Pharma Spa | Composizione per l’integrazione di calcio |
US11148990B2 (en) * | 2019-12-20 | 2021-10-19 | Jost Chemical Co. | Magnesium citrate glycinate co-salt |
KR102411350B1 (ko) | 2020-07-13 | 2022-06-20 | 한국화학연구원 | 패각을 이용한 모노 칼슘 시트레이트의 제조방법 및 이의 응용 |
US20220046958A1 (en) * | 2020-08-14 | 2022-02-17 | Abt Health And Wellness Private Limited | Fortified beverage composition and process of preparing thereof |
RU2756322C1 (ru) * | 2020-12-29 | 2021-09-29 | Федеральное государственное бюджетное учреждение науки Институт общей и неорганической химии им. Н.С. Курнакова Российской академии наук (ИОНХ РАН) | Способ получения аморфных водорастворимых солей цитрата магния |
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-
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- 2005-02-16 BR BR0500418-7A patent/BRPI0500418A/pt not_active IP Right Cessation
- 2005-02-17 CN CN200510056560XA patent/CN1680258B/zh active Active
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RU2363269C2 (ru) | 2009-08-10 |
EP1566373B1 (en) | 2008-07-16 |
US7267832B2 (en) | 2007-09-11 |
EP1566373A1 (en) | 2005-08-24 |
RU2005104391A (ru) | 2006-07-27 |
AR047680A1 (es) | 2006-02-01 |
CN1680258A (zh) | 2005-10-12 |
US20080014304A1 (en) | 2008-01-17 |
US7713559B2 (en) | 2010-05-11 |
TR200500481A2 (tr) | 2005-09-21 |
PT1566373E (pt) | 2008-10-27 |
ZA200500930B (en) | 2005-10-26 |
MXPA05001942A (es) | 2005-09-08 |
ATE401295T1 (de) | 2008-08-15 |
EP1566373B2 (en) | 2012-10-03 |
BRPI0500418A (pt) | 2005-11-08 |
US20050181096A1 (en) | 2005-08-18 |
DE602005008123D1 (de) | 2008-08-28 |
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