CN1673197A - Production process of active organic fertilizer - Google Patents
Production process of active organic fertilizer Download PDFInfo
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- CN1673197A CN1673197A CNA2005102001122A CN200510200112A CN1673197A CN 1673197 A CN1673197 A CN 1673197A CN A2005102001122 A CNA2005102001122 A CN A2005102001122A CN 200510200112 A CN200510200112 A CN 200510200112A CN 1673197 A CN1673197 A CN 1673197A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract
The active organic fertilizer is produced with waste edible fungi culturing matter, tobacco leftover and/or distiller's residue in 50-60 wt%, bone meal 5-15 wt%, natural phosphate ore powder 5-15 wt% and potassium shale powder 20-30 wt%, and through mixing, sterilizing, fermenting via adding fermenting bacteria, ventilation while fermentation and other steps. The active organic fertilizer has great amount one active microbes and tropina, can raise soil fertility, increase crop yield and quality.
Description
Technical field: the present invention relates to a kind of production method of active organic fertilizer, belong to and utilize soil microorganisms to produce fertilizer
Technical field.
Technical background: China is large agricultural country, and the nearly plant nutrition science of China has during the last ten years obtained high speed development.But how plant nutrition and fertilizer science in the face of entering Chinese agricultural development and the environmental problem behind the WTO, remain the important topic of confronting.The special export of farm produce of China in recent years suffers red light repeatly, developed country utilizes Agricultural Products Trade Gou Ei Lose restriction China agricultural livestock product outlet of lying, break green barrier, the only way of being ready for the challenge and effective way are greatly developed the Organic farming animal industry exactly, develop Organic farming production, at first to solve Organic farming production specifications system, organic production means.But from the most of area of present China, particularly Organic farming production will be developed in the west area, only returning crop stocks to the field by the homemade barnyard manure of peasant, clear muck and green manuring, part is to realize the production of scale sexual development Organic farming far away, besides the peasant is in making the fertilizer process, because the difference of organic raw material, the manufacturing technology disunity is lack of standardization, and the fertilizer that is made into is difficult to reach Organic farming production specifications system standard.
Summary of the invention: the objective of the invention is to: a kind of production method of active organic fertilizer of lower cost is provided, satisfies the demand of modern agriculture to organic fertilizer.
Method of the present invention is: select for use and produce wherein a kind of of depleted bacterium bag behind the edible mushrooms, tobacco leftovers or spirit distiller grain, or three's mixing takes 50 ~ 60%, raw bone meal 5 ~ 15%, natural phosphate ore powder 5 ~ 15% and potassium shale powder 20 ~ 30% are formed mixed culture medium, after sterilising treatment, add 3 ~ 5% fermenting agent, the mixing and stirring heap fermentation, the turning oxygenation ferment is turned out a large amount of active bios, proliferative tropina is made into active organic fertilizer.
The production method of above-mentioned active organic fertilizer, fermenting agent are selected soil microorganisms, phosphorus bacteria, potassium bacterium, cellulose-decomposing bacterium and yeast for use.In order to guarantee the quality of organophosphorus potassium bioprotein bacterial manure, the natural phosphate ore powder of selecting for use contains full phosphorus more than 32%, and natural potassium shale powder contains full potassium more than 10%.
The production method of above-mentioned active organic fertilizer, it comprises following step, a, get sucrose 50 grams, potassium primary phosphate 2 grams, sal epsom 0.5 gram, lime carbonate 0.1 gram, potassium aluminosilicate 0.2 gram, 1 kilogram of raw bone meal, 1 kilogram of mixing and stirring of water, obtain the potassium bacterium solid culture medium, with 100 ~ 120 ℃ of vapor sterilizations after 30 minutes, cool to 40 ~ 50 ℃, get 0.5 kilogram in soil in the neutral soil, 1.5 kilograms of mixed dilutings of water, filter with the husky cloth of individual layer, take the potassium bacterium solid culture medium mixing and stirring after filtering 0.3 kilogram of back soil diluent and sterilizing, pack in the container, cultivated 3 ~ 5 days under 28 ~ 30 ℃ of conditions, separation and Culture finishes, and is covered with the silicate bacteria bacterium colony on the substratum: Bacillus mucilaginosus; Get 10 kilograms of raw bone meals, 1 kilogram of sucrose, 2 kilograms of potassium primary phosphates, 1 kilogram in sal epsom, 20 kilograms of natural potassium shale powders, 20 kilograms of waste spent grains powders, 40 kilograms of mixing and stirring of water are with 100 ~ 120 ℃ of vapor sterilizations after 30 minutes, cool to 40 ~ 50 ℃, add the silicate bacteria mixing and stirring for preparing, heap fermentation 36 ~ 72 hours, turning oxygenation when leavening temperature reaches 40 ℃, then at 40 ~ 45 ℃, continue fermentation 24 ~ 48 hours, after the fermentation ends, about 25%, be crushed to 80 orders through the air-dry moisture that contains, continued heap fermentation again 12 hours, be made into silicate bacteria preparation, standby;
B, take 0.5 kilogram of potato of peeling, potato is cleaned, smash into mud to pieces through boiling, add glucose 50 grams, sal epsom 3 grams, Repone K 3 grams, ferrous sulfate 5 grams, manganous sulfate 0.01 gram, lime carbonate 5 grams, calcium phosphate 10 grams, raw bone meal 50 grams, Yelkin TTS 3 grams, water 40 grams, form potato, carbon, calcium phosphate solid substratum through mixing to stir, after 30 minutes, cool with 100 ~ 120 ℃ of vapor sterilizations to 50 ℃; Fetch earth 0.5 kilogram and add 1.5 kilograms of mixed dilutings of water, use the individual layer filtered through gauze, got 0.3 kilogram of filterable soil diluent and potato, carbon, calcium phosphate solid substratum mixing and stirring after sterilization, pack in the container, under 28 ~ 30 ℃ of conditions, cultivated 5 ~ 7 days, when separation and Culture finishes, be covered with bacterium colony on the culture medium: pseudomonas Pseudomonas and bacillus megaterium Bacillus megaterium.
C, take 0.5 kilogram of qu-liquor losing grain, zinc oxide 1 gram, sal epsom 3 grams, ferrous sulfate 5 grams, manganous sulfate 0.01 gram, copper sulfate 0.01 gram, water and mix for 1.5 kilograms to stir and form wine and lose poor liquid nutrient medium, pack into and stir in the container, with 100 ~ 120 ℃ vapor sterilizations after 30 minutes, cool to 70 ℃, add 0.1 kilogram of horsehit, under 60 ~ 65 ℃ of conditions, cultivated 72 hours, stirred once in per 12 hours, separation and Culture finishes, and obtains cellulose-decomposing bacterium: molten fine brood cell clostridium Clostridiumcellulosolvens;
D, take soybean sprout 150 gram, water 1500 grams, boiled 30 minutes, use filtered through gauze with cooker, add sucrose 50 grams, continue to boil the back cold, stir in the container of packing into to 40 ℃ of adding yeast, under 28 ~ 30 ℃ condition, cultivated 48 hours, obtain yeast Yesat;
E, take 30 kilograms of waste spent grains powders, 15 kilograms of raw bone meals, 0.5 kilogram in ferrous sulfate, 0.5 kilogram in sal epsom, 0.5 kilogram in zinc oxide, 0.05 kilogram in copper sulfate, 0.05 kilogram of manganous sulfate, add 40 kilograms in water, mix to stir and form mixed culture medium, after 1 hour, cool through 100 ~ 120 ℃ vapor sterilizations to 50 ℃, add the phosphorus bacteria for preparing, cellulose-decomposing bacterium, the yeast mixing and stirring, on concrete floor, pile up, fermented 48 ~ 72 hours, carry out the turning oxygenation first time when leavening temperature reaches 40 ℃ with numb sheet covering and heat insulating, continued heap fermentation 72 hours, leavening temperature reaches 40 ~ 45 ℃ of turning oxygenation, and is after the fermentation ends that fermented product is air-dry to containing moisture 25%, becomes 80 orders through mechanical disintegration, continued heap fermentation 12 ~ 24 hours, and be made into by phosphorus bacteria, cellulose-decomposing bacterium, the biological fermentation microbial inoculum that yeast is formed;
F, the depleted bacterium is wrapped after selecting the production edible mushrooms for use, wherein a kind of of tobacco leftovers or spirit distiller grain, or three's mixing is taken 50 kilograms～60 kilograms, in dry-matter, through being ground into about 80 orders, add 5 ~ 15 kilograms of raw bone meals, 5 ~ 15 kilograms of natural phosphate ore powders, 20 ~ 30 kilograms of natural potassium shale powders, 3 ~ 5 kilograms of the biological fermentation microbial inoculums that has been made into, water mixes stirring for 80 kilograms, is deposited in the indoor numb sheet insulation of adding a cover, fermented 48 ~ 72 hours, carry out the turning oxygenation first time when leavening temperature reaches 40 ℃, continue fermentation after 72 hours, add 3 kilograms of silicate bacteria preparations that prepare, continue fermentation 48 hours at 40 ~ 45 ℃, the product that fermentation ends obtains drying under 70 ℃ condition is crushed to 100 orders to containing moisture 15 ~ 20%, is made into active organic fertilizer.
Concrete method is: A, selects neutral soil for use, removes 10 centimeters of veneer of soil, fetch earth 0.5 kilogram at random 10 centimeters depths then, and standby in the sterile bag of packing into; Get sucrose 50 grams, potassium primary phosphate 2 grams, sal epsom 0.5 gram, lime carbonate 0.1 gram, potassium aluminosilicate 0.2 gram, 1 kilogram of raw bone meal, water is formed the potassium bacterium solid culture medium for 1 kilogram, with 100 ~ 120 ℃ of vapor sterilizations after 30 minutes, cool to 40 ~ 50 ℃, fetch earth 0.5 kilogram, 1.5 kilograms of mixed dilutings of water, filter with the husky cloth of individual layer, take the potassium bacterium solid culture medium mixing and stirring after filtering 0.3 kilogram of back soil diluent and sterilizing, pack in the container, under 28 ~ 30 ℃ of conditions, cultivated 3 ~ 5 days, separation and Culture finishes, and is covered with the silicate bacteria bacterium colony on the substratum: Bacillus mucilaginosus; Get 10 kilograms of raw bone meals, 1 kilogram of sucrose, 2 kilograms of potassium primary phosphates, 1 kilogram in sal epsom, 20 kilograms of natural potassium shale powders, 20 kilograms of waste spent grains powders, 40 kilograms of mixing and stirring of water are with 100 ~ 120 ℃ of vapor sterilizations after 30 minutes, cool to 50 ~ 40 ℃, add the silicate bacteria mixing and stirring for preparing, heap fermentation 36 ~ 72 hours, the oxygenation of turning in time when leavening temperature reaches 40 ℃, continue fermentation 24 ~ 48 hours, leavening temperature is controlled at 40 ~ 45 ℃, the product that fermentation ends obtains through the air-dry moisture that contains about 25%, be crushed to 60 ~ 80 orders, continue heap fermentation again 48 hours, and be made into silicate bacteria preparation, standby;
B, take the acid soil of ploughing, remove 10 centimeters of veneer of soil, standby in 10 centimeters depths are fetched earth 0.5 kilogram of sterile bag of packing at random; Take 0.5 kilogram of peeling potato, potato is cleaned, smash into mud to pieces through boiling, add glucose 50 grams, sal epsom 3 grams, Repone K 3 grams, ferrous sulfate 5 grams, manganous sulfate 0.01 gram, lime carbonate 5 grams, calcium phosphate 10 grams, raw bone meal 50 grams, Yelkin TTS 3 grams, water 40 grams, form potato through mixing to stir, carbon, the calcium phosphate solid substratum, with 100 ~ 120 ℃ of vapor sterilizations after 30 minutes, cool during to 50 ℃, 1.5 kilograms of mixed dilutings of 0.5 kilogram of water fetch earth, use the individual layer filtered through gauze, got 0.3 kilogram of filterable soil diluent and potato after sterilization, carbon, calcium phosphate solid substratum mixing and stirring, pack in the container, under 28 ~ 30 ℃ of conditions, cultivated 5 ~ 7 days, when separation and Culture finishes, be covered with bacterium colony on the culture medium: pseudomonas Pseudomonas, bacillus megaterium Bacillus megaterium; C, select for use 0.1 kilogram of sterile bag of packing into of fresh horsehit standby, take 0.5 kilogram of spirit distiller grain, zinc oxide 1 gram, sal epsom 3 grams, ferrous sulfate 5 grams, manganous sulfate 0.01 gram, copper sulfate 0.01 gram, water mixes stirring composition wine for 1.5 kilograms and loses poor liquid nutrient medium, pack into and stir in the container, with 100 ~ 120 ℃ vapor sterilizations after 30 minutes, cool to 70 ℃, add 0.1 kilogram of horsehit, cultivating about 72 hours under 60 ~ 65 ℃ of conditions, stirred once in per 12 hours, when separation and Culture finishes, occur a large amount of fermentation bubbles in the culture medium, obtain cellulose-decomposing bacterium: molten fine brood cell clostridium Clostridiumcellulosolvens; D, take soybean sprout 150 gram, water 1500 grams, boiled 30 minutes with cooker, use filtered through gauze, add sucrose 50 grams, continue to boil that the back is cool adds yeast to 40 ℃ and pack into and stir in the container, under 28 ~ 30 ℃ condition, cultivated 48 hours, occur a large amount of fermentation bubbles in the nutrient solution and obtain yeast Yesat;
E, take 30 kilograms of waste spent grains powders, 15 kilograms of raw bone meals, 0.5 kilogram in ferrous sulfate, 0.5 kilogram in sal epsom, 0.5 kilogram in zinc oxide, 0.05 kilogram in copper sulfate, 0.05 kilogram of manganous sulfate, add 40 kilograms in water, mix to stir and form mixed culture medium, after 1 hour, cool through 100 ~ 120 ℃ vapor sterilizations to 50 ℃, add the phosphorus bacteria for preparing, cellulose-decomposing bacterium, the yeast mixing and stirring, on concrete floor, pile up, fermented 48 ~ 72 hours, carry out the turning oxygenation first time when leavening temperature reaches 40 ℃ with numb sheet covering and heat insulating, continued heap fermentation 72 hours, turning oxygenation in per 12 hours once, and is after the fermentation ends that fermented product is air-dry to containing moisture about 25%, becomes about 80 orders through mechanical disintegration, continued heap fermentation 12 ~ 24 hours, and be made into by phosphorus bacteria, cellulose-decomposing bacterium, the biological fermentation microbial inoculum that yeast is formed;
F, the depleted bacterium is wrapped after selecting the production edible mushrooms for use, wherein a kind of of tobacco leftovers or spirit distiller grain, or three's mixing is taken 50 kilograms～60 kilograms, in dry-matter, after the pulverizing, add 15 kilograms of raw bone meals, 10 kilograms of natural phosphate ore powders, 30 kilograms of natural potassium shale powders, 3 kilograms of the biological fermentation microbial inoculums that has been made into, water mixes stirring for 80 kilograms, be deposited in the indoor numb sheet insulation of adding a cover, fermented 48 ~ 72 hours, and carried out the turning oxygenation first time when leavening temperature reaches 40 ℃, continue fermentation after 72 hours, add 3 kilograms of silicate bacteria preparations that prepare, leavening temperature is controlled at 40 ~ 45 ℃, continues fermentation after 48 hours, tunning under 70 ℃ condition drying to containing moisture 15 ~ 20%, through mechanical disintegration to 100 order, be made into active organic fertilizer.
Compared with prior art: the present invention utilizes soil microorganisms, phosphorus bacteria, the potassium bacterium, cellulose-decomposing bacterium makes fermenting agent, the yeast proliferative tropina, make organic raw material with the byproduct in the industrial and agricultural production process and each breeding stock bone, add natural phosphate ore powder in proportion through processing treatment, natural potassium shale powder, by fermentation, during the fermentation under the interaction by microorganism, produce a large amount of active bios, proliferative tropina, method with the method instead of chemical of biological fermentation is produced phosphorus potash fertilizer, contain phosphorus bacteria more than 500,000,000 in the every gram product that obtains, contain silicate bacterium (potassium bacterium) more than 200,000,000, it is compared with single phosphorus potassium bacterial manure, has increased phosphorus potassium element more, and can embody the capacity of decomposition of phosphorus potassium bacterial degradation phosphorus potassium element intuitively.Compare with the organic fertilizer of additive method production, hyperplasia a large amount of active biological protein and beneficial microorganisms.Therefore the present invention has the farming of raising soil fertility level effect, increases crop products output and improves advantage such as crop products quality.Not only can be used as the production means of Organic farming production specifications system, the fermenting agent that also can be used as fertilizer uses.
Embodiment:
Embodiments of the invention 1:A, with potassium bacterium solid culture medium separation and Culture potassium bacterium: select neutral soil for use, remove 10 centimeters of veneer of soil, fetch earth 0.5 kilogram at random 10 centimeters depths then, in the sterile bag of packing into, standby.Get sucrose 50 grams, potassium primary phosphate 2 grams, sal epsom 0.5 gram, lime carbonate 0.1 gram, potassium aluminosilicate 0.2 gram, 1 kilogram of raw bone meal, water is formed the potassium bacterium solid culture medium for 1 kilogram, with 100 ℃ of vapor sterilizations after 30 minutes, cool to 40 ℃, get 0.5 kilogram in soil in the neutral soil, 1.5 kilograms of mixed dilutings of water, filter with the husky cloth of individual layer, take the potassium bacterium solid culture medium mixing and stirring after filtering 0.3 kilogram of back soil diluent and sterilizing, pack in the container, under 28～30 ℃ of conditions, cultivated 3 days, separation and Culture finishes, and is covered with the silicate bacteria bacterium colony on the substratum: Bacillus mucilaginosus; B, get 10 kilograms of raw bone meals, 1 kilogram of sucrose, 2 kilograms of potassium primary phosphates, 1 kilogram in sal epsom, 20 kilograms of natural potassium shale powders, 20 kilograms of waste spent grains powders, 40 kilograms of mixing and stirring of water are with 100 ℃ of vapor sterilizations after 30 minutes, cool to 40 ℃, add the silicate bacteria preparation mixing and stirring for preparing, heap fermentation 36 ~ 72 hours, turning oxygenation when leavening temperature reaches 40 ℃, continue fermentation 24 hours, leavening temperature is controlled at 40 ℃, tunning through the air-dry moisture that contains about 25%, be crushed to 60 orders, continuing heap fermentation again, to be made into silicate bacteria preparation in 48 hours standby.B, with potato, carbon, calcium phosphate solid substratum separation and Culture phosphorus bacteria: take the acid soil of ploughing, remove 10 centimeters of veneer of soil, in 10 centimeters depths are fetched earth 0.5 kilogram of sterile bag of packing at random.Standby.Take 0.5 kilogram of peeling potato, potato is cleaned, smash into mud to pieces through boiling, add glucose 50 grams, sal epsom 3 grams, Repone K 3 grams, ferrous sulfate 5 grams, manganous sulfate 0.01 gram, lime carbonate 5 grams, calcium phosphate 10 grams, raw bone meal 50 grams, Yelkin TTS 3 grams, water 40 grams, form potato through mixing to stir, carbon, the calcium phosphate solid substratum, with 100 ℃ of vapor sterilizations after 30 minutes, cool during to 50 ℃, 1.5 kilograms of mixed dilutings of 0.5 kilogram of water fetch earth, filter, got 0.3 kilogram of filterable soil diluent and potato after sterilization, carbon, calcium phosphate solid substratum mixing and stirring, pack in the container, under 28～30 ℃ of conditions, cultivated 5 days, when separation and Culture finishes, be covered with bacterium colony on the culture medium: pseudomonas Pseudomonas, bacillus megaterium Bacillus megaterium.C, separation and Culture cellulose-decomposing bacterium: select 0.1 kilogram of sterile bag of packing into of fresh horsehit for use, standby.Taking 0.5 kilogram of spirit distiller grain, zinc oxide 1 gram, sal epsom 3 grams, ferrous sulfate 5 grams, manganous sulfate 0.01 gram, copper sulfate 0.01 gram, water mixes for 1.5 kilograms to stir and forms wine and lose poor liquid nutrient medium, pack into and stir in the container, with 100 ℃ vapor sterilizations after 30 minutes, cool to 70 ℃, add 0.1 kilogram of horsehit, under 60 ℃ of conditions, cultivated 72 hours, stirred once in per 12 hours, when separation and Culture finishes, occur a large amount of fermentation bubbles in the culture medium, obtain molten fine brood cell clostridium Clostridiumcellulosolvens.D, with soybean sprout, sucrose medium separated yeast bacterium: take soybean sprout 150 grams, water 1500 grams, boiled 30 minutes with cooker, use filtered through gauze, add sucrose 50 grams, continuing to boil the back stirs cool the adding in yeast (producing byproduct, upper strata yeast in the beer process) container of packing into to 40 ℃, under 28～30 ℃ condition, cultivated 48 hours, occur a large amount of fermentation bubbles in the nutrient solution, obtain yeast Yesat.E, take 30 kilograms of waste spent grains powders, 15 kilograms of raw bone meals, 0.5 kilogram in ferrous sulfate, 0.5 kilogram in sal epsom, 0.5 kilogram in zinc oxide, 0.05 kilogram in copper sulfate, 0.05 kilogram of manganous sulfate, add 40 kilograms in water, mix to stir and form mixed culture medium, after 1 hour, cool through 100 ℃ vapor sterilizations to 50 ℃, add the phosphorus bacteria for preparing, cellulose-decomposing bacterium, the yeast mixing and stirring, on concrete floor, pile up, fermented 48 ~ 72 hours, carry out the turning oxygenation first time when leavening temperature reaches 40 ℃ with numb sheet covering and heat insulating, continued heap fermentation 72 hours, turning oxygenation in per 12 hours once, and is after the fermentation ends that fermented product is air-dry to containing moisture about 25%, becomes about 80 orders through mechanical disintegration, continued heap fermentation 12 hours, and be made into by phosphorus bacteria, cellulose-decomposing bacterium, the biological fermentation microbial inoculum that yeast is formed.F, be pickled with grains or in wine 100 kilograms with distilling liquor is bright, 15 kilograms of raw bone meals, 10 kilograms of natural phosphate ore powders, 30 kilograms of natural potassium shale powders, the biological fermentation microbial inoculum that has been made into mixes stirring for 5 kilograms, be deposited in the indoor numb sheet insulation of adding a cover, fermented 48 ~ 72 hours, and carried out the turning oxygenation first time when leavening temperature reaches 40 ℃, continue fermentation after 72 hours, add 3 kilograms of silicate bacteria preparations that prepare, continue fermentation 48 hours, leavening temperature is controlled at 40 ℃, fermentation ends, get 0.5 kilogram of fermented product, add 30% urea, mix in the bag of packing into, shook once in per 5～10 minutes, fermented product is rolled into grain to urea in 30 minutes, proves and ferments successfully.Fermented product drying under 70 ℃ condition is contained moisture 15 ~ 20%,, be made into active organic fertilizer through mechanical disintegration to 100 order.
Embodiment of the invention 2:A, with potassium bacterium solid culture medium separation and Culture potassium bacterium: select neutral soil for use, remove 10 centimeters of veneer of soil, fetch earth 0.5 kilogram at random 10 centimeters degree of depth then, in the sterile bag of packing into, standby.Get sucrose 50 grams, potassium primary phosphate 2 grams, sal epsom 0.5 gram, lime carbonate 0.1 gram, potassium aluminosilicate 0.2 gram, 1 kilogram of raw bone meal, water is formed the potassium bacterium solid culture medium for 1 kilogram, with 120 ℃ of vapor sterilizations after 30 minutes, cool to 50 ℃, get 0.5 kilogram in soil in the neutral soil, 1.5 kilograms of mixed dilutings of water, filter with the husky cloth of individual layer, take the potassium bacterium solid culture medium mixing and stirring after filtering 0.3 kilogram of back soil diluent and sterilizing, pack in the container, under 30 ℃ of conditions, cultivated 5 days, separation and Culture finishes, and is covered with silicate bacteria bacterium colony Bacillus mucilaginosus on the substratum; B, get 10 kilograms of raw bone meals, 1 kilogram of sucrose, 2 kilograms of potassium primary phosphates, 1 kilogram in sal epsom, 20 kilograms of natural potassium shale powders, 20 kilograms of waste spent grains powders, 40 kilograms of mixing and stirring of water are with 120 ℃ of vapor sterilizations after 30 minutes, cool to 50 ℃, add the silicate bacteria preparation mixing and stirring for preparing, heap fermentation 36 ~ 72 hours, turning oxygenation when leavening temperature reaches 40 ℃, continue fermentation 48 hours, leavening temperature is controlled at 45 ℃, tunning through the air-dry moisture that contains about 25%, through being crushed to 80 orders, continue heap fermentation again and be made into silicate bacteria preparation in 48 hours, standby.With potato, carbon, calcium phosphate solid substratum separation and Culture phosphorus bacteria: take the acid soil of ploughing, remove 10 centimeters of veneer of soil, standby in 10 centimeters depths are fetched earth 0.5 kilogram of sterile bag of packing at random.Take 0.5 kilogram of peeling potato, potato is cleaned, smash into mud to pieces through boiling, add glucose 50 grams, sal epsom 3 grams, Repone K 3 grams, ferrous sulfate 5 grams, manganous sulfate 0.01 gram, lime carbonate 5 grams, calcium phosphate 10 grams, raw bone meal 50 grams, Yelkin TTS 3 grams, water 40 grams, form potato through mixing to stir, carbon, the calcium phosphate solid substratum, with 120 ℃ of vapor sterilizations after 30 minutes, cool during to 50 ℃, 1.5 kilograms of mixed dilutings of 0.5 kilogram of water fetch earth, use the individual layer filtered through gauze, got 0.3 kilogram of filterable soil diluent and potato after sterilization, carbon, calcium phosphate solid substratum mixing and stirring, pack in the container, under 30 ℃ of conditions, cultivated 5～7 days, when separation and Culture finishes, be covered with bacterium colony on the culture medium: pseudomonas Pseudomonas, bacillus megaterium Bacillus megaterium.C separation and Culture cellulose-decomposing bacterium: select for use 0.1 kilogram of sterile bag of packing into of fresh horsehit standby.Taking 0.5 kilogram of spirit distiller grain, zinc oxide 1 gram, sal epsom 3 grams, ferrous sulfate 5 grams, manganous sulfate 0.01 gram, copper sulfate 0.01 gram, water mixes for 1.5 kilograms to stir and forms wine and lose poor liquid nutrient medium, pack into and stir in the container, with 120 ℃ vapor sterilizations after 30 minutes, cool to 70 ℃, add 0.1 kilogram of horsehit, under 65 ℃ of conditions, cultivated 72 hours, stirred once in per 12 hours, when separation and Culture finishes, occur a large amount of fermentation bubbles in the culture medium, obtain molten fine brood cell clostridium Clostridiumcellulosolvens.D, with soybean sprout, sucrose medium separated yeast bacterium: take soybean sprout 150 grams, water 1500 grams, boiled 30 minutes with cooker, use filtered through gauze, add sucrose 50 grams, continue to boil that the back is cool adds yeast to 50 ℃ and pack into and stir in the container, under 30 ℃ condition, cultivated 48 hours, occur a large amount of fermentation bubbles in the nutrient solution and obtain yeast Yesat.E, take 30 kilograms of waste spent grains powders, 15 kilograms of raw bone meals, 0.5 kilogram in ferrous sulfate, 0.5 kilogram in sal epsom, 0.5 kilogram in zinc oxide, 0.05 kilogram in copper sulfate, 0.05 kilogram of manganous sulfate, add 40 kilograms in water, mix to stir form mixed culture medium, through 120 ℃ vapor sterilizations after 1 hour, cool to 50 ℃, add the phosphorus bacteria for preparing, cellulose-decomposing bacterium, the yeast mixing and stirring is piled up with numb sheet covering and heat insulating on concrete floor, ferments 48 ~ 72 hours, when reaching 40 ℃, leavening temperature carries out the turning oxygenation first time, continued heap fermentation 72 hours, turning oxygenation when leavening temperature reaches 45 ℃, after the fermentation ends that fermented product is air-dry, contain moisture about 25%, become 80 orders through mechanical disintegration, continued heap fermentation 24 hours, be made into by phosphorus bacteria, cellulose-decomposing bacterium, the biological fermentation microbial inoculum that yeast is formed.F, the depleted bacterium is wrapped 60 kilograms (in dry-matter after taking the production edible mushrooms, through being ground into 80 orders), 15 kilograms of raw bone meals, 10 kilograms of natural phosphate ore powders, 30 kilograms of natural potassium shale powders, 3 kilograms of the biological mix bacterium agents that has been made into, water mixes stirring for 80 kilograms, be deposited in the indoor numb sheet insulation of adding a cover, fermented 48 ~ 72 hours, and carried out the turning oxygenation first time when leavening temperature reaches 40 ℃, continue fermentation after 72 hours, add 3 kilograms of silicate bacteria preparations that prepare, continue fermentation 48 hours, leavening temperature is controlled at 45 ℃, fermentation ends, get 0.5 kilogram of fermented product, add 30% urea, mix in the bag of packing into, shook once in per 5～10 minutes, fermented product is rolled into grain to urea in 30 minutes, proves and ferments successfully.Fermented product drying under 70 ℃ condition is contained moisture 15～20%,, be made into active organic fertilizer through mechanical disintegration to 100 order.
Embodiment of the invention 3:A, with potassium bacterium solid culture medium separation and Culture potassium bacterium: select neutral soil for use, remove 10 centimeters of veneer of soil, fetch earth 0.5 kilogram at random 10 centimeters degree of depth then, in the sterile bag of packing into, standby.Get sucrose 50 grams, potassium primary phosphate 2 grams, sal epsom 0.5 gram, lime carbonate 0.1 gram, potassium aluminosilicate 0.2 gram, 1 kilogram of raw bone meal, water is formed the potassium bacterium solid culture medium for 1 kilogram, with 100 ℃ of vapor sterilizations after 30 minutes, cool to 45 ℃, fetch earth 0.5 kilogram, 1.5 kilograms of mixed dilutings of water, filter with the husky cloth of individual layer, take the potassium bacterium solid culture medium mixing and stirring after filtering 0.3 kilogram of back soil diluent and sterilizing, pack in the container, under 25 ℃ of conditions, cultivated 5 days, separation and Culture finishes, and is covered with the silicate bacteria bacterium colony on the substratum: Bacillus mucilaginosus; Get 10 kilograms of raw bone meals, 1 kilogram of sucrose, 2 kilograms of potassium primary phosphates, 1 kilogram in sal epsom, 20 kilograms of natural potassium shale powders, 20 kilograms of waste spent grains powders, 40 kilograms of mixing and stirring of water are with 100 ℃ of vapor sterilizations after 30 minutes, cool to 45 ℃, add the silicate bacteria mixing and stirring for preparing, heap fermentation 36 ~ 72 hours, turning oxygenation when leavening temperature reaches 40 ℃, continue fermentation 36 hours, leavening temperature is controlled at 45 ℃, tunning through the air-dry moisture that contains 20%, through being crushed to 60 orders, continuing heap fermentation again, to be made into the silicate fermenting agent in 48 hours standby.B, with potato, carbon, calcium phosphate solid substratum separation and Culture phosphorus bacteria: take the acid soil of ploughing, remove 10 centimeters of veneer of soil, in 10 fens branches deeply fetch earth 0.5 kilogram of sterile bag of packing at random, standby.Take 0.5 kilogram of peeling potato, potato is cleaned, smash into mud to pieces through boiling, add glucose 50 grams, sal epsom 3 grams, Repone K 3 grams, ferrous sulfate 5 grams, manganous sulfate 0.01 gram, lime carbonate 5 grams, calcium phosphate 10 grams, raw bone meal 50 grams, Yelkin TTS 3 grams, water 40 grams, form potato through mixing to stir, carbon, the calcium phosphate solid substratum, with 100 ℃ of vapor sterilizations after 30 minutes, cool during to 50 ℃, 1.5 kilograms of mixed dilutings of 0.5 kilogram of water fetch earth, filter, got 0.3 kilogram of filterable soil diluent and potato after sterilization, carbon, calcium phosphate solid substratum mixing and stirring, pack in the container, under 30 ℃ of conditions, cultivated 6 days, when separation and Culture finishes, be covered with the phosphorus bacteria bacterium colony on the culture medium: pseudomonas Pseudomonas, bacillus megaterium Bacillus megaterium.C, separation and Culture Mierocrystalline cellulose isolate: select 0.1 kilogram of sterile bag of packing into of fresh horsehit for use, standby.Taking 0.5 kilogram of spirit distiller grain, zinc oxide 1 gram, sal epsom 3 grams, ferrous sulfate 5 grams, manganous sulfate 0.01 gram, copper sulfate 0.01 gram, water mixes for 1.5 kilograms to stir and forms wine and lose poor liquid nutrient medium, pack into and stir in the container, with 100 ℃ vapor sterilizations after 30 minutes, cool to 70 ℃, add 0.1 kilogram of horsehit, under 60 ℃ of conditions, cultivated 72 hours, stirred once in per 12 hours, when separation and Culture finishes, occur a large amount of fermentation bubbles in the culture medium, obtain molten fine brood cell clostridium Clostridiumcellulosolvens.D, with soybean sprout, sucrose medium separated yeast bacterium: take soybean sprout 150 grams, water 1500 grams, boiled 30 minutes with cooker, use filtered through gauze, add sucrose 50 grams, continue to boil that the back is cool adds yeast to 50 ℃ and pack into and stir in the container, under 34 ℃ condition, cultivated 48 hours, occur a large amount of fermentation bubbles in the nutrient solution and obtain yeast Yesat.E, take 30 kilograms of waste spent grains powders, 18 kilograms of raw bone meals, 0.5 kilogram in ferrous sulfate, 0.5 kilogram in sal epsom, 0.5 kilogram in zinc oxide, 0.05 kilogram in copper sulfate, 0.05 kilogram of manganous sulfate, add 40 kilograms in water, mix to stir and form mixed culture medium, after 1 hour, cool through 100 ℃ vapor sterilizations to 50 ℃, add the phosphorus bacteria for preparing, cellulose-decomposing bacterium, the yeast mixing and stirring, on concrete floor, pile up, fermented 48 ~ 72 hours, carry out the turning oxygenation first time when leavening temperature reaches 40 ℃ with numb sheet covering and heat insulating, continued heap fermentation 72 hours, turning oxygenation in per 12 hours once, and is after the fermentation ends that fermented product is air-dry to containing moisture 25%, becomes 80 orders through mechanical disintegration, continued heap fermentation 18 hours, and be made into by phosphorus bacteria, cellulose-decomposing bacterium, the biological fermentation microbial inoculum that yeast is formed.F, 60 kilograms of tobacco leftovers (in dry-matter, through being ground into 80 orders), 15 kilograms of raw bone meals, 10 kilograms of natural phosphate ore powders, 25 kilograms of natural potassium shale powders, 5 kilograms of biological fermentation microbial inoculums, water mixes stirring for 80 kilograms, be deposited in the indoor numb sheet insulation of adding a cover, fermented 48 ~ 72 hours, and carried out the turning oxygenation first time when leavening temperature reaches 40 ℃, continue fermentation after 72 hours, add 3 kilograms of silicate bacteria preparations that prepare, continue fermentation 48 hours, leavening temperature is controlled at 40 ℃, fermentation ends, get 0.5 kilogram of fermented product, add 30% urea, mix in the bag of packing into, shook once in per 5～10 minutes, fermented product is rolled into grain to urea in 30 minutes, proves and ferments successfully.Fermented product drying under 70 ℃ condition is contained moisture 15～20%,, be made into active organic fertilizer through mechanical disintegration to 100 order.
Claims (5)
1. the production method of an active organic fertilizer, it is characterized in that: select for use and produce wherein a kind of of depleted bacterium bag behind the edible mushrooms, tobacco leftovers or spirit distiller grain, or three's mixing takes 50 ~ 60%, raw bone meal 5 ~ 15%, natural phosphate ore powder 5 ~ 15% and potassium shale powder 20 ~ 30%, form mixed culture medium, after sterilising treatment, add 3 ~ 5% fermenting agent, the mixing and stirring heap fermentation, the turning oxygenation ferment, turn out a large amount of active bios, proliferative tropina is made into active organic fertilizer.
2. the production method of active organic fertilizer according to claim 1, it is characterized in that: fermenting agent is selected soil microorganisms, phosphorus bacteria, potassium bacterium, cellulose-decomposing bacterium and yeast for use.
3. the production method of active organic fertilizer according to claim 1, it is characterized in that: the natural phosphate ore powder of selecting for use contains full phosphorus more than 32%, and natural potassium shale powder contains full potassium more than 10%.
4. as production method according to claim 1 and 2 described active organic fertilizers, it is characterized in that: it comprises following step, a, get sucrose 50 grams, potassium primary phosphate 2 grams, sal epsom 0.5 gram, lime carbonate 0.1 gram, potassium aluminosilicate 0.2 gram, 1 kilogram of raw bone meal, 1 kilogram of mixing and stirring of water, obtain the potassium bacterium solid culture medium, with 100 ~ 120 ℃ of vapor sterilizations after 30 minutes, cool to 40 ~ 50 ℃, get 0.5 kilogram in soil in the neutral soil, 1.5 kilograms of mixed dilutings of water, filter with the husky cloth of individual layer, take the potassium bacterium solid culture medium mixing and stirring after filtering 0.3 kilogram of back soil diluent and sterilizing, pack in the container, under 28 ~ 30 ℃ of conditions, cultivated 3 ~ 5 days, separation and Culture finishes, be covered with the silicate bacteria bacterium colony on the substratum: Bacillus mucilaginosus. gets 10 kilograms of raw bone meals, 1 kilogram of sucrose, 2 kilograms of potassium primary phosphates, 1 kilogram in sal epsom, 20 kilograms of natural potassium shale powders, 20 kilograms of waste spent grains powders, 40 kilograms of mixing and stirring of water are with 100 ~ 120 ℃ of vapor sterilizations after 30 minutes, cool to 40 ~ 50 ℃, add the silicate bacteria mixing and stirring for preparing, heap fermentation 36 ~ 72 hours, turning oxygenation when leavening temperature reaches 40 ℃, then at 40 ~ 45 ℃, continue fermentation 24 ~ 48 hours, after the fermentation ends, through the air-dry moisture that contains about 25%, be crushed to 80 orders, continued heap fermentation again 12 hours, be made into silicate bacteria preparation, standby;
B, take 0.5 kilogram of potato of peeling, potato is cleaned, smash into mud to pieces through boiling, add glucose 50 grams, sal epsom 3 grams, Repone K 3 grams, ferrous sulfate 5 grams, manganous sulfate 0.01 gram, lime carbonate 5 grams, calcium phosphate 10 grams, raw bone meal 50 grams, Yelkin TTS 3 grams, water 40 grams, form potato, carbon, calcium phosphate solid substratum through mixing to stir, after 30 minutes, cool with 100 ~ 120 ℃ of vapor sterilizations to 50 ℃; Fetch earth 0.5 kilogram and add 1.5 kilograms of mixed dilutings of water, use the individual layer filtered through gauze, got 0.3 kilogram of filterable soil diluent and potato, carbon, calcium phosphate solid substratum mixing and stirring after sterilization, pack in the container, under 28 ~ 30 ℃ of conditions, cultivated 5 ~ 7 days, when separation and Culture finishes, be covered with bacterium colony on the culture medium: pseudomonas Pseudomonas and bacillus megaterium Bacillus megaterium.
C, take 0.5 kilogram of qu-liquor losing grain, zinc oxide 1 gram, sal epsom 3 grams, ferrous sulfate 5 grams, manganous sulfate 0.01 gram, copper sulfate 0.01 gram, water and mix for 1.5 kilograms to stir and form wine and lose poor liquid nutrient medium, pack into and stir in the container, with 100 ~ 120 ℃ vapor sterilizations after 30 minutes, cool to 70 ℃, add 0.1 kilogram of horsehit, under 60 ~ 65 ℃ of conditions, cultivated 72 hours, stirred once in per 12 hours, separation and Culture finishes, and obtains cellulose-decomposing bacterium: molten fine brood cell clostridium Clostridiumcellulosolvens;
D, take soybean sprout 150 gram, water 1500 grams, boiled 30 minutes, use filtered through gauze with cooker, add sucrose 50 grams, continue to boil the back cold, stir in the container of packing into to 40 ℃ of adding yeast, under 28 ~ 30 ℃ condition, cultivated 48 hours, obtain yeast Yesat;
E, take 30 kilograms of waste spent grains powders, 15 kilograms of raw bone meals, 0.5 kilogram in ferrous sulfate, 0.5 kilogram in sal epsom, 0.5 kilogram in zinc oxide, 0.05 kilogram in copper sulfate, 0.05 kilogram of manganous sulfate, add 40 kilograms in water, mix to stir and form mixed culture medium, after 1 hour, cool through 100 ~ 120 ℃ vapor sterilizations to 50 ℃, add the phosphorus bacteria for preparing, cellulose-decomposing bacterium, the yeast mixing and stirring, on concrete floor, pile up, fermented 48 ~ 72 hours, carry out the turning oxygenation first time when leavening temperature reaches 40 ℃ with numb sheet covering and heat insulating, continued heap fermentation 72 hours, leavening temperature reaches 40 ~ 45 ℃ of turning oxygenation, and is after the fermentation ends that fermented product is air-dry to containing moisture 25%, becomes 80 orders through mechanical disintegration, continued heap fermentation 12 ~ 24 hours, and be made into by phosphorus bacteria, cellulose-decomposing bacterium, the biological fermentation microbial inoculum that yeast is formed;
F, the depleted bacterium is wrapped after selecting the production edible mushrooms for use, wherein a kind of of tobacco leftovers or spirit distiller grain, or three's mixing is taken 50 kilograms～60 kilograms, in dry-matter, through being ground into about 80 orders, add 5 ~ 15 kilograms of raw bone meals, 5 ~ 15 kilograms of natural phosphate ore powders, 20 ~ 30 kilograms of natural potassium shale powders, 3 ~ 5 kilograms of the biological fermentation microbial inoculums that has been made into, water mixes stirring for 80 kilograms, is deposited in the indoor numb sheet insulation of adding a cover, fermented 48 ~ 72 hours, carry out the turning oxygenation first time when leavening temperature reaches 40 ℃, continue fermentation after 72 hours, add 3 kilograms of silicate bacteria preparations that prepare, continue fermentation 48 hours at 40 ~ 45 ℃, the product that fermentation ends obtains drying under 70 ℃ condition is crushed to 100 orders to containing moisture 15 ~ 20%, is made into active organic fertilizer.
5. the production method of active organic fertilizer according to claim 4 is characterized in that: A, selects neutral soil for use, removes 10 centimeters of veneer of soil, fetch earth 0.5 kilogram at random 10 centimeters depths then, and standby in the sterile bag of packing into; Get sucrose 50 grams, potassium primary phosphate 2 grams, sal epsom 0.5 gram, lime carbonate 0.1 gram, potassium aluminosilicate 0.2 gram, 1 kilogram of raw bone meal, water is formed the potassium bacterium solid culture medium for 1 kilogram, with 100 ~ 120 ℃ of vapor sterilizations after 30 minutes, cool to 40 ~ 50 ℃, fetch earth 0.5 kilogram, 1.5 kilograms of mixed dilutings of water, filter with the husky cloth of individual layer, take the potassium bacterium solid culture medium mixing and stirring after filtering 0.3 kilogram of back soil diluent and sterilizing, pack in the container, under 28 ~ 30 ℃ of conditions, cultivated 3 ~ 5 days, separation and Culture finishes, and is covered with the silicate bacteria bacterium colony on the substratum: Bacillus mucilaginosus; Get 10 kilograms of raw bone meals, 1 kilogram of sucrose, 2 kilograms of potassium primary phosphates, 1 kilogram in sal epsom, 20 kilograms of natural potassium shale powders, 20 kilograms of waste spent grains powders, 40 kilograms of mixing and stirring of water are with 100 ~ 120 ℃ of vapor sterilizations after 30 minutes, cool to 50 ~ 40 ℃, add the silicate bacteria mixing and stirring for preparing, heap fermentation 36 ~ 72 hours, the oxygenation of turning in time when leavening temperature reaches 40 ℃, continue fermentation 24 ~ 48 hours, leavening temperature is controlled at 40 ~ 45 ℃, the product that fermentation ends obtains through the air-dry moisture that contains about 25%, be crushed to 60 ~ 80 orders, continue heap fermentation again 48 hours, and be made into silicate bacteria preparation, standby;
B, take the acid soil of ploughing, remove 10 centimeters of veneer of soil, standby in 10 centimeters depths are fetched earth 0.5 kilogram of sterile bag of packing at random; Take 0.5 kilogram of peeling potato, potato is cleaned, smash into mud to pieces through boiling, add glucose 50 grams, sal epsom 3 grams, Repone K 3 grams, ferrous sulfate 5 grams, manganous sulfate 0.01 gram, lime carbonate 5 grams, calcium phosphate 10 grams, raw bone meal 50 grams, Yelkin TTS 3 grams, water 40 grams, form potato through mixing to stir, carbon, the calcium phosphate solid substratum, with 100 ~ 120 ℃ of vapor sterilizations after 30 minutes, cool during to 50 ℃, 1.5 kilograms of mixed dilutings of 0.5 kilogram of water fetch earth, use the individual layer filtered through gauze, got 0.3 kilogram of filterable soil diluent and potato after sterilization, carbon, calcium phosphate solid substratum mixing and stirring, pack in the container, under 28 ~ 30 ℃ of conditions, cultivated 5 ~ 7 days, when separation and Culture finishes, be covered with bacterium colony on the culture medium: pseudomonas Pseudomonas, bacillus megaterium Bacillus megaterium; C, select for use 0.1 kilogram of sterile bag of packing into of fresh horsehit standby, take 0.5 kilogram of spirit distiller grain, zinc oxide 1 gram, sal epsom 3 grams, ferrous sulfate 5 grams, manganous sulfate 0.01 gram, copper sulfate 0.01 gram, water mixes stirring composition wine for 1.5 kilograms and loses poor liquid nutrient medium, pack into and stir in the container, with 100 ~ 120 ℃ vapor sterilizations after 30 minutes, cool to 70 ℃, add 0.1 kilogram of horsehit, cultivating about 72 hours under 60 ~ 65 ℃ of conditions, stirred once in per 12 hours, when separation and Culture finishes, occur a large amount of fermentation bubbles in the culture medium, obtain cellulose-decomposing bacterium: molten fine brood cell clostridium Clostridiumcellulosolvens; D, take soybean sprout 150 gram, water 1500 grams, boiled 30 minutes with cooker, use filtered through gauze, add sucrose 50 grams, continue to boil that the back is cool adds yeast to 40 ℃ and pack into and stir in the container, under 28 ~ 30 ℃ condition, cultivated 48 hours, occur a large amount of fermentation bubbles in the nutrient solution and obtain yeast Yesat;
E, take 30 kilograms of waste spent grains powders, 15 kilograms of raw bone meals, 0.5 kilogram in ferrous sulfate, 0.5 kilogram in sal epsom, 0.5 kilogram in zinc oxide, 0.05 kilogram in copper sulfate, 0.05 kilogram of manganous sulfate, add 40 kilograms in water, mix to stir and form mixed culture medium, after 1 hour, cool through 100 ~ 120 ℃ vapor sterilizations to 50 ℃, add the phosphorus bacteria for preparing, cellulose-decomposing bacterium, the yeast mixing and stirring, on concrete floor, pile up, fermented 48 ~ 72 hours, carry out the turning oxygenation first time when leavening temperature reaches 40 ℃ with numb sheet covering and heat insulating, continued heap fermentation 72 hours, turning oxygenation in per 12 hours once, and is after the fermentation ends that fermented product is air-dry to containing moisture about 25%, becomes about 80 orders through mechanical disintegration, continued heap fermentation 12 ~ 24 hours, and be made into by phosphorus bacteria, cellulose-decomposing bacterium, the biological fermentation microbial inoculum that yeast is formed;
F, the depleted bacterium is wrapped after selecting the production edible mushrooms for use, wherein a kind of of tobacco leftovers or spirit distiller grain, or three's mixing is taken 50 kilograms～60 kilograms, in dry-matter, after the pulverizing, add 15 kilograms of raw bone meals, 10 kilograms of natural phosphate ore powders, 30 kilograms of natural potassium shale powders, 3 kilograms of the biological fermentation microbial inoculums that has been made into, water mixes stirring for 80 kilograms, be deposited in the indoor numb sheet insulation of adding a cover, fermented 48 ~ 72 hours, and carried out the turning oxygenation first time when leavening temperature reaches 40 ℃, continue fermentation after 72 hours, add 3 kilograms of silicate bacteria preparations that prepare, leavening temperature is controlled at 40 ~ 45 ℃, continues fermentation after 48 hours, tunning under 70 ℃ condition drying to containing moisture 15 ~ 20%, through mechanical disintegration to 100 order, be made into active organic fertilizer.
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| CN102584389A (en) * | 2012-01-16 | 2012-07-18 | 瓮福（集团）有限责任公司 | Method for preparing phosphorus-containing organic compound fertilizer |
| CN102775247A (en) * | 2012-08-23 | 2012-11-14 | 刘奋安 | Pest-proof disease-resistant organic fertilizer and preparation method thereof |
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