CN1615079A - 基于肟醚衍生物和胍衍生物的杀真菌混合物 - Google Patents
基于肟醚衍生物和胍衍生物的杀真菌混合物 Download PDFInfo
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- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
- A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
- A01N47/44—Guanidine; Derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
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- General Health & Medical Sciences (AREA)
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Abstract
公开了用于防治有害真菌和昆虫的混合物,该混合物包含协同有效量的如下组分作为活性组分:A)式(I)的肟醚衍生物,其中各取代基如下所定义:X为NH或氧;R1和R3相互独立地为氢、氰基、烷基、环丙基或卤代烷基;R2和R4相互独立地为氢、烷基、链烯基、炔基、卤代烷基、卤代链烯基或卤代炔基;和B)式(II)化合物。还公开了使用化合物I与II的混合物防治有害真菌的方法。
Description
本发明涉及用于防治有害真菌和昆虫的混合物,该混合物包含协同有效量的如下组分作为活性组分:
A)式I的肟醚衍生物:
其中各取代基如下所定义:
X为NH或氧;
R1、R3相互独立地为氢、氰基、C1-C4烷基、环丙基或C1-C4卤代烷基;R2、R4相互独立地为氢、C1-C4烷基、C3-C6链烯基、C3-C6炔基、C1-C4卤代烷基、C3-C6卤代链烯基或C3-C6卤代炔基;
和
B)式II化合物:
本发明的目的是提供尤其对稻中的真菌病害具有良好的杀真菌作用且同时具有良好的杀虫作用,而且活性化合物的总施用量降低的混合物(协同增效混合物)。因为在稻生长的气候区域中,有害昆虫通常也大量存在,因此既需要杀真菌作用也需要杀虫作用。
我们发现该目的根据本发明通过权利要求1所要求保护的混合物实现。我们令人惊奇地发现本身没有杀真菌作用的化合物II提高了式I的肟醚衍生物的杀真菌活性。因此,化合物II用作助剂。
式I化合物及其制备本身是已知的且描述于文献中(WO-A 97/15552)。
式II的杀虫剂同样是已知的(通用名:马尼丁(clothianidin))且描述于文献中(EP-A 376 279)。
由于式I化合物的生物活性,优选其中R1和R3为氢、氰基、环丙基、甲基、乙基、1-甲基乙基或CF3的式I化合物。
特别优选其中R1和R3为C1-C4烷基的化合物I。
此外,还特别优选其中R1为甲基的化合物I。
此外,还优选其中R1为CF3的化合物I。
此外,还优选其中R2和R4为氢、环丙基、甲基、乙基、异丙基的化合物I。
此外,还优选其中R4为甲基的化合物I。
此外,还优选其中R4为乙基或异丙基的化合物I。
特别优选其中X为NH的式I肟醚衍生物。
尤其考虑到它们在本发明中与化合物II混合使用,优选总结在下表1中的化合物I。
表1
式I的肟醚衍生物:
序号 | R1 | R2 | R3 | R4 | X |
I-1 | H | H | H | H | NH |
I-2 | H | CH3 | H | CH3 | NH |
I-3 | CH3 | H | CH3 | H | NH |
I-4 | CH3 | CH3 | CH3 | CH3 | NH |
I-5 | CH3 | 环-C3H5 | CH3 | 环-C3H5 | NH |
I-6 | CH3 | CH2CH3 | CH3 | CH2CH3 | NH |
I-7 | CH3 | CH(CH3)2 | CH3 | CH(CH3)2 | NH |
I-8 | CH3 | CH2CH=CH2 | CH3 | CH2CH=CH2 | NH |
I-9 | CF3 | H | CF3 | H | NH |
I-10 | CF3 | CH3 | CF3 | CH3 | NH |
I-11 | CF3 | CH(CH3)2 | CF3 | CH(CH3)2 | NH |
I-12 | CN | H | CH3 | H | NH |
I-13 | CN | CH3 | CH3 | CH3 | NH |
I-14 | H | H | H | H | O |
I-15 | H | CH3 | H | CH3 | O |
I-16 | CH3 | H | CH3 | H | O |
I-17 | CH3 | CH3 | CH3 | CH3 | O |
I-18 | CH3 | 环-C3H5 | CH3 | 环-C3H5 | O |
I-19 | CH3 | CH2CH3 | CH3 | CH2CH3 | O |
I-20 | CH3 | CH(CH3)2 | CH3 | CH(CH3)2 | O |
I-21 | CH3 | CH2CH=CH2 | CH3 | CH2CH=CH2 | O |
I-22 | CF3 | H | CF3 | H | O |
I-23 | CF3 | CH3 | CF3 | CH3 | O |
I-24 | CN | H | CH3 | H | O |
I-25 | CN | CH3 | CH3 | CH3 | O |
存在于本发明混合物中的化合物I对宽范围的植物病原性真菌具有显著的活性,所述真菌尤其选自子囊菌纲(Ascomycetes)、半知菌纲(Deuteromycetes)、藻菌纲(Phycomycetes)和担子菌纲(Basidiomycetes)真菌。
它们对在各种作物如棉花、蔬菜品种(如黄瓜、豆类、西红柿、土豆和葫芦科植物)、大麦、禾草、燕麦、香蕉、咖啡、玉米、水果品种、稻、黑麦、大豆、葡萄藤、小麦、观赏植物、甘蔗和各种种子中防治大量真菌尤其重要。
它们特别适于防治下列植物病原性真菌:禾谷类上的Blumeriagraminis(白粉病),葫芦科植物上的二孢白粉菌(Erysiphe cichoracearum)和单丝壳(Sphaerotheca fuliginea),苹果上的苹果白粉病菌(Podosphaeraleucotricha),葡萄藤上的葡萄钩丝壳(Uncinula necator),禾谷类上的柄锈菌(Puccinia)属,棉花、稻和草坪上的丝核菌(Rhizoctonia)属,禾谷类和甘蔗上的黑粉菌(Ustilago)属,苹果上的苹果黑星菌(Venturia inaequalis)(黑星病),禾谷类和稻上的长蠕孢(Helminthosporium)属,小麦上的颖枯壳针孢(Septoria nodorum),草莓、蔬菜、观赏植物和葡萄藤上的灰葡萄孢(Botrytiscinerea)(灰霉病),花生上的落花生尾孢(Cercospora arachidicola),小麦和大麦上的眼斑病菌(Pseudocercosporella herpotrichoides),稻和草坪上的稻瘟病菌(Pyricularia oryzae),土豆和西红柿上的致病疫霉(Phytophthorainfestans),葡萄藤上的葡萄生单轴霉(Plasmopara viticola),啤酒花和黄瓜上的假霜霉(Pseudoperonospora)属,蔬菜和水果上的链格孢(Alternaria)属,香蕉上的球腔菌(Mycosphaerella)属以及镰孢霉(Fusarium)和轮枝孢(Verticillium)属。
式II化合物用于防治选自昆虫、蜘蛛和线虫的动物害虫。它可以在作物保护中、在卫生领域和储存产品的保护领域中以及在兽医领域中用于防治动物害虫。所述化合物特别适于防治下列动物害虫:
·鳞翅目昆虫(鳞翅目),例如小地老虎(Agrotis ypsilon)、黄地老虎(Agrotissegetum)、Alabama argillacea、黎豆夜蛾(Anticarsia gemmatalis)、Argyresthia conjugella、Autographa gamma、树尺蠖(Bupalus piniarius)、Cacoecia murinana、Capua reticulana、Cheimatobia brumata、云杉色卷蛾(Choristoneura fumiferana)、Choristoneura occidentalis、Cirphisunipuncta、苹果小卷蛾(Cydia pomonella)、Dendrolimus pini、Diaphanianitidalis、西南玉米杆草螟(Diatraea grandiosella)、埃及钻夜蛾(Eariasinsulana)、南美玉米苗斑螟(Elasmopalpus lignosellus)、女贞细卷蛾(Eupoecilia ambiguella)、Evetria bouliana、Feltia subterranea、蜡螟(Galleria mellonella)、李小食心虫(Grapholitha funebrana)、梨小食心虫(Grapholitha molesta)、棉铃虫(Heliothis armigera)、烟芽夜蛾(Heliothisvirescens)、玉米穗虫(Heliothis zea)、菜螟(Hellula undalis)、Hiberniadefoliaria、美国白蛾(Hyphantria cunea)、Hyponomeuta malinellus、番茄虫蛾(Keiferia lycopersicella)、Lambdina fiscellaria、甜菜夜蛾(Laphygmaexigua)、咖啡潜叶蛾(Leucoptera coffeella)、旋纹潜蛾(Leucoptera scitella)、Lithotis blancardella、葡萄浆果小卷蛾(Lobesia botrana)、甜菜网螟(Loxostege sticticalis)、舞毒蛾(Lymantria dispar)、模毒蛾(Lymantriamonacha)、桃潜蛾(Lyonetia clerkella)、黄褐天幕毛虫(Malacosomaneustria)、甘蓝夜蛾(Mamestra brassicae)、Orgyia pseudotsugata、玉米螟(Ostrinia nubilalis)、小眼夜蛾(Panolis flammea)、棉花红铃虫(Pectinophoragossypiella)、疆夜蛾(Peridroma saucia)、圆掌舟蛾(Phalera bucephala)、马铃薯麦蛾(Phthorimaea operculella)、柑桔潜叶蛾(Phyllocnistis citrella)、欧洲粉蝶(Pieris brassicae)、苜蓿绿夜蛾(Plathypena scabra)、菜蛾(Plutellaxylostella)、大豆夜蛾(Pseudoplusia includens)、Rhyacionia frustrana、Scrobipalpula absoluta、麦蛾(Sitotroga cerealella)、葡萄卷叶蛾(Sparganothis pilleriana)、草地夜蛾(Spodoptera frugiperda)、海灰翅夜蛾(Spodoptera littoralis)、斜纹夜蛾(Spodoptera litura)、Thaumatopoeapityocampa、Tortrix viridana、粉纹夜蛾(Trichoplusia ni)和Zeirapheracanadensis,
·甲虫(鞘翅目),例如梨窄吉丁(Agrilus sinuatus)、直条叩头虫(Agrioteslineatus)、暗色叩头虫(Agriotes obscurus)、Amphimallus solstitialis、Anisandrus dispar、墨西哥棉铃象(Anthonomus grandis)、苹花象(Anthonomus pomorum)、甜菜隐食甲(Atomaria linearis)、纵坑切梢小蠹(Blastophagus piniperda)、Blitophaga undata、蚕豆象(Bruchusruffmanus)、豌豆象(Bruchus pisorum)、欧洲兵豆象(Bruchus lentis)、苹卷象(Byctiscus betulae)、甜菜大龟甲(Cassida nebulosa)、Cerotomatrifurcata、白菜籽龟象(Ceuthorrhynchus assimilis)、芫菁龟象(Ceuthorrhynchus napi)、甜菜胫跳甲(Chaetocnema tibialis)、Conoderusvespertinus、石刁柏负泥虫(Crioceris asparagi)、Diabrotica longicornis、Diabrotica 12-punctata、玉米根叶甲(Diabrotica virgifera)、墨西哥豆瓢虫(Epilachna varivestis)、烟草跳甲(Epitrix hirtipennis)、棉灰蒙象变种(Eutinobothrus brasiliensis)、松树皮象(Hylobius abietis)、埃及苜蓿叶象(Hypera brunneipennis)、紫苜蓿叶象(Hypera postica)、云杉八齿小蠹(Ipstypographus)、烟草负泥虫(Lema bilineata)、黑角负泥虫(Lemamelanopus)、马铃薯叶甲(Leptinotarsa decemlineata)、Limoniuscalifornlcus、稻水象甲(Lissorhoptrus oryzophilus)、Melanotus communis、油菜露尾甲(Meligethes aeneus)、大栗鳃金龟(Melolontha hippocastani)、五月鳃金龟(Melolontha melolontha)、水稻负泥虫(Oulema oryzae)、葡萄黑耳喙象(Ortiorrhynchus sulcatus)、草莓根象甲(Otiorrhynchus ovatus)、辣根猿叶甲(Phaedon cochleariae)、Phyllotreta chrysocephala、食叶鳃金龟(Phyllophaga)属、庭园发丽金龟(Phyllopertha horticola)、大豆淡足跳甲(Phyllotreta nemorum)、黄曲条菜跳甲(Phyllotreta striolata)、日本金龟子(Popillia japonica)、豌豆叶象(Sitona lineatus)和谷象(Sitophilus granaria),
·双翅目昆虫(双翅目),例如埃及伊蚊(Aedes aegypti)、剌扰伊蚊(Aedesvexans)、墨西哥果蝇(Anastrepha ludens)、五斑按蚊(Anophelesmaculipennis)、地中海实蝇(Ceratitis capitata)、蛆症金蝇(Chrysomyabezziana)、Chrysomya hominivorax、Chrysomya macellaria、高粱瘿蚊(Contarinia sorghicola)、Cordylobia anthropophaga、尖音库蚊(Culexpipiens)、瓜蝇、油橄榄实蝇(Dacus oleae)、油菜叶瘿蚊、小毛厕蝇(Fanniacanicularis)、马蝇(Gasterophilus intestinalis)、刺舌蝇(Glossina morsitans)、Haematobia irritans、Haplodiplosis equestris、花生田灰地种蝇(Hylemyiaplatura)、纹皮蝇(Hypoderma lineata)、蔬菜斑潜蝇(Liriomyza sativae)、美国潜叶蝇(Liriomyza trifolii)、Lucilia caprina、铜绿蝇(Lucilia cuprina)、丝光绿蝇(Lucilia sericata)、Lycoria pectoralis、麦瘿蚊(Mayetioladestructor)、家蝇(Musca domestica)、厩腐蝇(Muscina stabulans)、羊狂蝇(Oestrus ovis)、欧洲麦秆蝇(Oscinella frit)、天仙子泉蝇(Pegomyahysocyami)、Phorbia antiqua、萝卜蝇(Phorbia brassicae)、Phorbiacoarctata、樱桃实蝇(Rhagoletis cerasi)、苹果实蝇(Rhagoletis pomonella)、Tabanus bovinus、Tipula oleracea和欧洲大蚊(Tipula paludosa),
·蓟马(缨翅目),例如烟褐蓟马(Frankliniella fusca)、苜蓿花蓟马(Frankliniella occidentalis)、东方花蓟马(Frankliniella tritici)、桔硬蓟马(Scirtothrips citri)、稻蓟马(Thrips oryzae)、棕榈蓟马(Thrips palmi)和烟蓟马(Thrips tabaci),
·膜翅目昆虫(膜翅目),例如新疆菜叶蜂(Athalia rosae)、Atta cephalotes、Atta sexdens、Atta texana、Hoplocampa minuta、Hoplocampa testudinea、小黄家蚁(Monomorium pharaonis)、Solenopsis geminata和红火蚁(Solenopsis invicta),
·异翅亚目昆虫(异翅亚目),例如拟绿蝽(Acrosternum hilare)、玉米长蝽(Blissus leucopterus)、黑斑烟盲蝽(Cyrtopeltis notatus)、棉红蝽(Dysdercus cingulatus)、Dysdercus intermedius、麦扁盾蝽(Eurygasterintegriceps)、Euschistus impictiventris、棉红铃喙缘蝽(Leptoglossusphyllopus)、美洲牧草盲蝽(Lygus lineolaris)、牧草盲蝽(Lygus pratensis)、稻绿蝽(Nezara viridula)、甜菜拟网蝽(Piesma quadrata)、Solubea insularis和Thyanta perditor,
·同翅亚目昆虫(同翅亚目),例如Acyrthosiphon onobrychis、落叶松球蚜(Adelges laricis)、Aphidula nasturtii、甜菜蚜(Aphis fabae)、苹果蚜(Aphispomi)、接骨木蚜(Aphis sambuci)、飞廉短尾蚜(Brachycaudus cardui)、甘蓝蚜(Brevicoryne brassicae)、Cerosipha gossypii、高加索冷杉椎球蚜(Dreyfusia nordmannianae)、云杉椎球蚜(Dreyfusia piceae)、居根西圆尾蚜(Dysaphis radicola)、Dysaulacorthum pseudosolani、蚕豆微叶蝉(Empoascafabae)、麦长管蚜(Macrosiphum avenae)、大戟长管蚜(Macrosiphumeuphorbiae)、蔷薇管蚜(Macrosiphon rosae)、巢莱修尾蚜(Megoura viciae)、麦无网蚜(Metopolophium dirhodum)、Myzodes persicae、李瘤蚜(Myzuscerasi)、稻飞虱(Nilaparvata lugens)、囊柄瘿绵蚜(Pemphigus bursarius)、蔗飞虱(Perkinsiella saccharicida)、忽布疣蚜(Phorodon humuli)、苹木虱(Psylla mali)、梨木虱(Psylla piri)、冬葱瘤蛾蚜(Rhopalomyzus ascalonicus)、玉米蚜(Rhopalosiphum maidis)、Sappaphis mala、Sappaphis mali、麦二叉蚜(Schizaphis graminum)、榆绵蚜(Schizoneura lanuginosa)、白粉虱(Trialeurodes vaporariorum)和葡萄根瘤蚜(Viteus vitifolii),
·白蚁(等翅目),例如Calotermes flavicollis、Leucotermes flavipes、欧洲散白蚁(Reticulitermes lucifugus)和Termes natalensis,
·直翅目昆虫(直翅目),例如居屋艾蟋(Acheta domestica)、东方蜚蠊(Blatta orientalis)、德国小蠊(Blattella germanica)、欧洲球螋(Forficulaauricularia)、蝼蛄(Gryllotalpa gryllotalpa)、飞蝗(Locusta migratoria)、双纹黑蝗(Melanoplus bivittatus)、红足黑蝗(Melanoplus femur-rubrum)、墨西哥黑蝗(Melanoplus mexicanus)、迁飞黑蝗(Melanoplus sanguinipes)、石栖黑蝗(Melanoplus spretus)、条纹红蝗(Nomadacris septemfasciata)、美洲蟑螂(Periplaneta americana)、美洲沙漠蝗(Schistocerca americana)、Schistocerca peregrina、Stauronotus maroccanus和庭疾灶螽(Tachycinesasynamorus),
·蜘蛛纲(Arachnoidea),如蜘蛛(蜱螨目),例如长星形壁虱(Amblyommaamericanum)、热带花蜱(Amblyomma variegatum)、波斯锐缘蜱(Argaspersicus)、牛壁虱(Boophilus annulatus)、Boophilus decoloratus、微小牛蜱(Boophilus microplus)、紫红短须螨(Brevipalpus phoenicis)、苜蓿苔螨(Bryobia praetiosa)、Dermacentor silvarum、鹅耳枥始叶螨(Eotetranychus carpini)、桔芽瘿螨(Eriophyes sheldoni)、Hyalommatruncatum、蓖子硬蜱(Ixodes ricinus)、Ixodes rubicundus、Ornithodorusmoubata、Otobius megnini、Paratetranychus pilosus、鸡皮刺螨(Dermanyssus gallinae)、桔皱叶刺瘿螨(Phyllocoptruta oleivora)、侧多食跗线螨(Polyphagotarsonemus latus)、绵羊疥病(Psoroptes ovis)、Rhipicephalus appendiculatus、Rhipicephalus evertsi、人疥螨(Sarcoptesscabiei)、朱砂叶螨(Tetranychus cinnabarinus)、神泽叶螨(Tetranychuskanzawai、太平洋叶螨(Tetranychus pacificus)、棉叶螨(Tetranychustelarius)和二点叶螨(Tetranychus urticae),
·线虫,如根结线虫,例如北方根结线虫(Meloidogyne hapla)、南方根结线虫(Meloidogyne incognita)、爪哇根结线虫(Meloidogyne javanica);孢囊线虫,例如马铃薯金线虫(Globodera rostochiensis)、燕麦胞囊线虫(Heterodera avenae)、大豆胞囊线虫(Heterodera glycines)、甜菜胞囊线虫(Heterodera schachtii)、三叶草胞囊线虫(Heterodera trifolii);以及茎线虫和叶线虫,例如长尾刺线虫(Belonolaimus longicaudatus)、马铃薯腐烂线虫(Ditylenchus destructor)、起绒草茎线虫(Ditylenchus dipsaci)、多带螺旋线虫(Heliocotylenchus multicinctus)、伸展长针线虫(Longidoruselongatus)、香蕉穿孔线虫(Radopholus similis)、强壮盘旋线虫(Rotylenchusrobustus)、原始毛刺线虫(Trichodorus primitivus)、克来顿矮化线虫(Tylenchorhynchus claytoni)、不定矮化线虫(Tylenchorhynchus dubius)、疏忽短体线虫(Pratylenchus neglectus)、穿刺短体线虫(Pratylenchuspenetrans)、Pratylenchus curvitatus和古迪短体线虫(Pratylenchusgoodeyi)。
化合物I和II通常以20∶1至1∶200,尤其10∶1至1∶180,优选2∶1至1∶160的重量比施用。
在室外条件下,为了防治动物害虫,活性化合物的施用率通常为0.01-2.0kg/ha,优选0.02-1.0kg/ha。
本发明混合物尤其优选可以用于在稻中防治植物病害和有害昆虫。
化合物I和化合物II可以同时施用,即一起或单独使用,或依次施用,在单独施用的情况下,施用顺序通常对防治措施的效果没有任何影响。
取决于所需效果的种类,本发明混合物的施用率尤其在农作物区域为0.01-8kg/ha,优选0.1-5kg/ha,尤其为0.5-3.0kg/ha。
化合物I的施用率为0.01-2.5kg/ha,优选0.05-2.5kg/ha,尤其为0.1-1.0kg/ha。
对于种子处理,混合物的施用率通常为0.001-250g/kg种子,优选为0.01-100g/kg,尤其为0.01-50g/kg。
若需要防治植物病原性有害真菌,通过在播种植物之前或之后或在植物出苗之前或之后对种子、植物或土壤喷雾或撒粉而单独或联合施用化合物I和化合物II或化合物I与化合物II的混合物。
本发明混合物可以配制成例如即喷溶液、粉剂和悬浮液形式或高度浓缩的水性、油性或其他悬浮液、分散体、乳剂、油分散体、糊、粉末、撒播用材料或颗粒的形式并通过喷雾、雾化、撒粉、撒播或浇灌施用。使用形式取决于希望的目的;在任何情况下都应确保本发明混合物尽可能精细和均匀地分布。
配制剂以已知方式制备,例如通过将活性化合物与溶剂和/或载体混合来制备,需要的话使用乳化剂和分散剂,若使用水作为稀释剂,则还可以使用其它有机溶剂作为辅助溶剂。适于该目的的助剂主要是溶剂如芳族溶剂(如二甲苯),氯代芳族溶剂(如氯苯),链烷烃(如矿物油馏分),醇(如甲醇、丁醇),酮(如环己酮),胺(如乙醇胺、二甲基甲酰胺)和水;载体如磨碎的天然矿物(如高岭土、粘土、滑石、白垩)和磨碎的合成矿物(如细碎的硅石、硅酸盐);乳化剂如非离子和阴离子乳化剂(如聚氧乙烯脂肪醇醚、烷基磺酸盐和芳基磺酸盐)以及分散剂如木素亚硫酸盐废液和甲基纤维素。
合适的表面活性剂是芳族磺酸如木质素磺酸、苯酚磺酸、萘磺酸和二丁基萘磺酸以及脂肪酸的碱金属盐、碱土金属盐和铵盐,烷基-和烷基芳基磺酸盐,烷基硫酸盐,月桂基醚硫酸盐和脂肪醇硫酸盐以及硫酸化十六-、十七-和十八烷醇的盐,或脂肪醇乙二醇醚的盐,磺化萘及其衍生物与甲醛的缩合物,萘或萘磺酸与苯酚和甲醛的缩合物,聚氧乙烯辛基酚醚,乙氧基化的异辛基酚、辛基酚或壬基酚,烷基苯基聚乙二醇醚,三丁基苯基聚乙二醇醚,烷基芳基聚醚醇,异十三烷醇,脂肪醇/氧化乙烯缩合物,乙氧基化蓖麻油,聚氧乙烯烷基醚或聚氧丙烯烷基醚,月桂醇聚乙二醇醚乙酸酯,山梨醇酯,木素亚硫酸盐废液和甲基纤维素。
粉末、撒播用材料和粉剂可以通过将化合物I和化合物II或化合物I与化合物II的混合物与固体载体混合或一起研磨而制备。
粒剂(如包膜粒剂、浸渍粒剂或均相粒剂)通常通过将一种或多种活性化合物与固体载体粘附而制备。
填料或固体载体例如是矿土如硅石、硅胶、硅酸盐、滑石、高岭土、石灰石、石灰、白垩、红玄武土、黄土、粘土、白云石、硅藻土、硫酸钙、硫酸镁、氧化镁;磨碎的合成材料;肥料如硫酸铵、磷酸铵、硝酸铵、尿素;植物来源的产品如谷粉、树皮粉、木粉和坚果壳粉;纤维素粉或其它固体载体。
配制剂通常包含0.1-95重量%,优选0.5-90重量%的化合物I和化合物II或化合物I与化合物II的混合物。活性化合物以90-100%,优选95-100%的纯度(根据NMR光谱或HPLC)使用。
化合物I和化合物II、混合物或对应的配制剂通过用杀真菌有效量的混合物或在单独施用情况下,化合物I和化合物II处理有害真菌、其栖息地或需要防治有害真菌的植物、种子、土壤、区域、材料或空间而施用。
施用可以在有害真菌侵染之前或之后进行。
包含活性化合物的这类制剂的实例为:
I.90重量份活性化合物与10重量份N-甲基吡咯烷酮的溶液;该溶液适于以微滴使用;
II.20重量份活性化合物、80重量份二甲苯、10重量份8-10mol氧化乙烯与1mol油酸N-单乙醇酰胺的加合物、5重量份十二烷基苯磺酸钙、5重量份40mol氧化乙烯与1mol蓖麻油的加合物的混合物;通过将该溶液精细地分布在水中得到分散体;
III.20重量份活性化合物、40重量份环己酮、30重量份异丁醇、20重量份40mol氧化乙烯与1mol蓖麻油的加合物的水分散体;
IV.20重量份活性化合物、25重量份环己醇、65重量份沸点为210-280℃的矿物油馏分和10重量份40mol氧化乙烯与1mol蓖麻油的加合物的水分散体;
V.80重量份活性化合物、3重量份二异丁基萘-1-磺酸钠、10重量份来自亚硫酸盐废液的木素磺酸钠和7重量份粉状硅胶在锤磨机中研磨的混合物;通过将该混合物精细地分布在水中得到喷雾混合物;
VI.3重量份活性化合物和97重量份细碎高岭土的均匀混合物;该粉末包含3重量%活性化合物;
VII.30重量份活性化合物、92重量份粉状硅胶和8重量份喷雾于该硅胶表面上的石蜡油的均匀混合物;该配制剂赋予活性化合物以良好的粘附性;
VIII.40重量份活性化合物、10重量份苯酚磺酸/脲/甲醛缩合物的钠盐、2重量份硅胶和48重量份水的稳定水分散体;该分散体可以进一步稀释;
IX.20重量份活性化合物、2重量份十二烷基苯磺酸钙、8重量份脂肪醇聚乙二醇醚、20重量份苯酚磺酸/脲/甲醛缩合物的钠盐和88重量份链烷烃矿物油的稳定油分散体。
应用实施例
本发明混合物的协同增效活性可以由下列试验证实:
将活性化合物单独或一起在63重量%环己酮和27重量%乳化剂的混合物中配制成10%乳液并用水稀释到所需的浓度。
通过测定侵染的叶面积(%)进行评价。将这些百分数转化成效力。使用Abbot公式按如下计算效力(W):
W=(1-α/β)·100
a对应于已处理植物的真菌侵染(%),和
b对应于未处理(对照)植物的真菌侵染(%)。
效力为0是指已处理植物的侵染程度对应于未处理对照植物的侵染程度;效力为100是指已处理植物未受侵染。
活性化合物的混合物的预期效力使用Colby公式确定[R.S.Colby,Weeds(杂草)
15,20-22(1967)]并与观察到的效力比较。
Colby公式:E=x+y-x·y/100
E为以浓度a和b使用活性化合物A和B的混合物时的预期效力,以相对于未处理对照的%表示,
x为以浓度a使用活性化合物A时的效力,以相对于未处理对照的%表示,y为以浓度b使用活性化合物B时的效力,以相对于未处理对照的%表示。应用实施例:对由稻瘟病菌(Pyricularia oryzae)引起的稻瘟病的保护活性
将栽培品种为“Tai-Nong 67”的盆载稻秧苗的叶子用活性化合物的含水制剂喷雾至滴流,所述制剂由包含10%活性化合物、85%环己酮和5%乳化剂的储备溶液制备。第二天将植物用稻瘟病菌的含水孢子悬浮液接种。然后将试验植物在22-24℃和95-99%相对大气湿度下于气候调节室中放置6天。然后肉眼评价在叶子上的侵染发展程度。
将侵染叶面积的百分数测定值转化成相对于未处理对照的%的效力。活性化合物组合的预期效力使用Colby公式确定[R.S.Colby,“计算除草剂组合的协同增效和拮抗反应”,杂草(Weeds,15,第20-22页(1967))并与观测到的效力相比较。
表1:对比试验
活性化合物 | 活性化合物在喷雾液中的浓度[ppm] | 相对于未处理对照的%的效力 |
对照(未处理) | (89%侵染) | 0 |
I-4 | 820.5 | 776610 |
II | 80205 | 000 |
表2:本发明混合物
本发明混合物 | 观测到的效力 | 计算的效力*) |
I-4+II8+5ppm混合比1.6∶1 | 97 | 77 |
I-4+II8+20ppm混合比1∶2.5 | 94 | 77 |
I-4+II8+80ppm混合比1∶10 | 97 | 77 |
I-4+II2+20ppm混合比1∶10 | 83 | 66 |
I-4+II0.5+5ppm混合比1∶10 | 21 | 10 |
I-4+II0.5+20ppm混合比1∶40 | 32 | 10 |
I-4+II0.5+80ppm混合比1∶160 | 21 | 10 |
*)使用Colby公式计算的效力
试验结果表明在所有混合比下观测到的效力高于事先使用Colby公式计算的效力。
Claims (6)
1.一种用于作物保护的混合物,包含协同有效量的如下组分作为活性组分:
A)式I的肟醚衍生物:
其中各取代基如下所定义:
X为NH或氧;
R1、R3相互独立地为氢、氰基、C1-C4烷基、环丙基或C1-C4卤代烷基;
R2、R4相互独立地为氢、C1-C4烷基、C3-C6链烯基、C3-C6炔基、C1-C4卤代烷基、C3-C6卤代链烯基或C3-C6卤代炔基;
和
B)式II化合物:
3.如权利要求1或2所要求的混合物,其中组分A和B以20∶1至1∶200的混合比存在。
4.一种防治植物病原性有害真菌的方法,包括用权利要求1-3中任一项所要求的杀真菌混合物处理真菌、其栖息地或需要防治真菌侵染的材料、植物、种子、土壤、区域或空间,其中化合物I和化合物II的施用可以同时,即联合或单独进行,或依次进行。
5.如权利要求4所要求的方法,其中将有害真菌、其栖息地或需要防治有害真菌的植物、种子、土壤、区域、材料或空间用0.005-1kg/ha的如权利要求1或2所述的化合物I处理。
6.如权利要求4所要求的方法,其中将有害真菌、其栖息地或需要防治有害真菌的植物、种子、土壤、区域、材料或空间用0.01-1kg/ha的如权利要求1所述的化合物II处理。
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