CN1605603A - 一种阻燃增强尼龙组合物及其用途 - Google Patents
一种阻燃增强尼龙组合物及其用途 Download PDFInfo
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- CN1605603A CN1605603A CN 200410006315 CN200410006315A CN1605603A CN 1605603 A CN1605603 A CN 1605603A CN 200410006315 CN200410006315 CN 200410006315 CN 200410006315 A CN200410006315 A CN 200410006315A CN 1605603 A CN1605603 A CN 1605603A
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- reinforced nylon
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 48
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 229920001778 nylon Polymers 0.000 title claims abstract description 30
- 239000004677 Nylon Substances 0.000 title claims abstract description 29
- 239000000203 mixture Substances 0.000 title abstract description 12
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 10
- 239000000314 lubricant Substances 0.000 claims abstract description 10
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 5
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 5
- 150000001875 compounds Chemical class 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 19
- 239000003112 inhibitor Substances 0.000 claims description 18
- 230000003647 oxidation Effects 0.000 claims description 18
- 238000007254 oxidation reaction Methods 0.000 claims description 18
- 239000004033 plastic Substances 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- -1 fatty acyl amide Chemical class 0.000 claims description 8
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims description 7
- 239000010445 mica Substances 0.000 claims description 7
- 229910052618 mica group Inorganic materials 0.000 claims description 7
- 239000005995 Aluminium silicate Substances 0.000 claims description 6
- 235000012211 aluminium silicate Nutrition 0.000 claims description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 239000004411 aluminium Substances 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 claims description 4
- 229920002943 EPDM rubber Polymers 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 3
- 150000002989 phenols Chemical class 0.000 claims description 3
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 150000007970 thio esters Chemical class 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 150000003016 phosphoric acids Chemical class 0.000 claims description 2
- 150000003918 triazines Chemical class 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical class [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims 1
- 125000003473 lipid group Chemical group 0.000 claims 1
- 230000035939 shock Effects 0.000 abstract description 3
- 238000003754 machining Methods 0.000 abstract 1
- 239000003607 modifier Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 15
- 238000012545 processing Methods 0.000 description 6
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 5
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 4
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 3
- 235000013539 calcium stearate Nutrition 0.000 description 3
- 239000008116 calcium stearate Substances 0.000 description 3
- 150000002632 lipids Chemical group 0.000 description 3
- 238000005453 pelletization Methods 0.000 description 3
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 3
- GXURZKWLMYOCDX-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O.OCC(CO)(CO)CO GXURZKWLMYOCDX-UHFFFAOYSA-N 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 235000019260 propionic acid Nutrition 0.000 description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical class NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- XOUQAVYLRNOXDO-UHFFFAOYSA-N 2-tert-butyl-5-methylphenol Chemical compound CC1=CC=C(C(C)(C)C)C(O)=C1 XOUQAVYLRNOXDO-UHFFFAOYSA-N 0.000 description 1
- VSAWBBYYMBQKIK-UHFFFAOYSA-N 4-[[3,5-bis[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-2,4,6-trimethylphenyl]methyl]-2,6-ditert-butylphenol Chemical compound CC1=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C1CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 VSAWBBYYMBQKIK-UHFFFAOYSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 150000002193 fatty amides Chemical class 0.000 description 1
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- KWUZCAVKPCRJPO-UHFFFAOYSA-N n-ethyl-4-(6-methyl-1,3-benzothiazol-2-yl)aniline Chemical compound C1=CC(NCC)=CC=C1C1=NC2=CC=C(C)C=C2S1 KWUZCAVKPCRJPO-UHFFFAOYSA-N 0.000 description 1
- GLDOVTGHNKAZLK-UHFFFAOYSA-N n-octadecyl alcohol Natural products CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229940059574 pentaerithrityl Drugs 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- NMHMNPHRMNGLLB-UHFFFAOYSA-N phloretic acid Chemical compound OC(=O)CCC1=CC=C(O)C=C1 NMHMNPHRMNGLLB-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
PA | 冲击改性剂 | 无机矿物 | 阻燃剂 | 抗氧剂 | 润滑剂 | |
实施例4 | 黏度为2.6Pa·S,50公斤 | MA-PE,6公斤 | 云母,15公斤 | MA,12公斤 | DSTP 0.2公斤 | 硬脂酸钙0.3公斤 |
实施例5 | 黏度为3.0Pa·S,45公斤 | MA-SEBS,10公斤 | 高岭土,20公斤 | MCA,6公斤 | N-苯基苯胺0.2公斤 | 脂肪酰胺0.1公斤 |
实施例6 | 黏度为2.4Pa·S,40公斤 | 丙烯酸-PE,8公斤 | 滑石粉,35公斤 | 三聚氰胺磷酸盐,5公斤 | 626 0.1公斤和DLTP0.2公斤 | 脂肪酸0.2公斤 |
实 | 黏度为 | 丙烯酸- | 云母,15公 | MA,3公 | 1010 0.2公 | 硬脂酸锌 |
施例7 | 3.2Pa·S,65公斤 | SEBS,5公斤 | 斤 | 斤,MCA,5公斤 | 斤和1680.1公斤 | 0.2公斤 |
实施例8 | 黏度为2.8Pa·S,35公斤 | 丙烯酸-POE,4公斤 | 滑石粉,18公斤 | 胍盐,5公斤 | MD10240.2公斤 | 石蜡0.3公斤 |
实施例9 | 黏度为2.6Pa·S,80公斤 | 丙烯酸-EPDM,10公斤 | 高岭土,30公斤 | MA,8公斤,双氰胺盐7公斤 | TPP 0.3公斤 | 硬脂酸锌0.3公斤 |
实施例10 | 黏度为3.2Pa·S,60公斤 | MA-POE,7公斤 | 云母,32公斤 | MCA,6公斤 | 300 0.2公斤 | 硬脂酸铝0.1公斤 |
拉伸屈服强度 | 弯曲强度 | 阻燃性UL94V2 | 弯曲模量 | Izod冲击强度23℃ | ||
GWI 960℃ | 缺口 | 无缺口 | ||||
单位 | MPa | MPa | mm | MPa | KJ/m2 | KJ/m2 |
实施例4 | 70 | 108 | 1.6 | 5300 | 5 | 32 |
实施例5 | 68 | 106 | 1.7 | 5100 | 4 | 31 |
实施例6 | 72 | 105 | 1.6 | 5200 | 4 | 30 |
实施例7 | 68 | 110 | 1.8 | 5000 | 6 | 31 |
实施例8 | 70 | 106 | 2.0 | 5300 | 8 | 32 |
实施例9 | 72 | 105 | 1.6 | 5500 | 6 | 35 |
实施例10 | 72 | 106 | 2.2 | 5400 | 5 | 30 |
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CNB2004100063153A CN1325563C (zh) | 2004-02-25 | 2004-02-25 | 一种阻燃增强尼龙组合物及其用途 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2004100063153A CN1325563C (zh) | 2004-02-25 | 2004-02-25 | 一种阻燃增强尼龙组合物及其用途 |
Publications (2)
Publication Number | Publication Date |
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CN1605603A true CN1605603A (zh) | 2005-04-13 |
CN1325563C CN1325563C (zh) | 2007-07-11 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CNB2004100063153A Expired - Lifetime CN1325563C (zh) | 2004-02-25 | 2004-02-25 | 一种阻燃增强尼龙组合物及其用途 |
Country Status (1)
Country | Link |
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CN (1) | CN1325563C (zh) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101845220A (zh) * | 2010-05-06 | 2010-09-29 | 浙江新力塑料股份有限公司 | 阻燃增强塑料及其制备方法 |
CN102115596A (zh) * | 2010-12-31 | 2011-07-06 | 马艳荣 | 一种电线电缆护套尼龙复合材料 |
CN101191008B (zh) * | 2006-11-21 | 2012-06-06 | 上海普利特复合材料有限公司 | 一种阻燃增强型pa6组合物 |
CN103627168A (zh) * | 2013-11-13 | 2014-03-12 | 广东聚石化学股份有限公司 | 一种尼龙专用无卤阻燃母粒及其制备方法 |
CN103724995A (zh) * | 2013-12-31 | 2014-04-16 | 上海长伟锦磁工程塑料有限公司 | 一种耐低温填充尼龙6复合材料 |
TWI480330B (zh) * | 2008-07-10 | 2015-04-11 | Dsm Ip Assets Bv | 阻燃性聚醯胺組成物 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1109001A (zh) * | 1994-12-30 | 1995-09-27 | 北京云港特种塑料制品公司 | 工程塑料制品 |
CN1055049C (zh) * | 1997-11-13 | 2000-08-02 | 国家建筑材料工业局玻璃钢研究设计院 | 大型异形铸型尼龙燃油箱制造方法 |
CN1190305C (zh) * | 2000-10-09 | 2005-02-23 | 屠金法 | 柴油机塑料盖体材料 |
CN1116360C (zh) * | 2000-11-04 | 2003-07-30 | 中国石化集团巴陵石油化工有限责任公司 | 一种刚性耐低温超韧尼龙生产方法 |
CN1204198C (zh) * | 2001-11-02 | 2005-06-01 | 上海杰事杰新材料股份有限公司 | 吹塑级玻璃纤维增强尼龙 |
-
2004
- 2004-02-25 CN CNB2004100063153A patent/CN1325563C/zh not_active Expired - Lifetime
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101191008B (zh) * | 2006-11-21 | 2012-06-06 | 上海普利特复合材料有限公司 | 一种阻燃增强型pa6组合物 |
TWI480330B (zh) * | 2008-07-10 | 2015-04-11 | Dsm Ip Assets Bv | 阻燃性聚醯胺組成物 |
CN101845220A (zh) * | 2010-05-06 | 2010-09-29 | 浙江新力塑料股份有限公司 | 阻燃增强塑料及其制备方法 |
CN102115596A (zh) * | 2010-12-31 | 2011-07-06 | 马艳荣 | 一种电线电缆护套尼龙复合材料 |
CN103627168A (zh) * | 2013-11-13 | 2014-03-12 | 广东聚石化学股份有限公司 | 一种尼龙专用无卤阻燃母粒及其制备方法 |
CN103627168B (zh) * | 2013-11-13 | 2015-12-02 | 广东聚石化学股份有限公司 | 一种尼龙专用无卤阻燃母粒及其制备方法 |
CN103724995A (zh) * | 2013-12-31 | 2014-04-16 | 上海长伟锦磁工程塑料有限公司 | 一种耐低温填充尼龙6复合材料 |
CN103724995B (zh) * | 2013-12-31 | 2016-06-01 | 上海长伟锦磁工程塑料有限公司 | 一种耐低温填充尼龙6复合材料 |
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Publication number | Publication date |
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Assignee: Foshan Shunde District Ruineng Technology Co.,Ltd. Assignor: Wu Quande Contract fulfillment period: 2008.3.24 to 2023.3.24 Contract record no.: 2008440000113 Denomination of invention: Flame retardant reinforced nylon composition and its use Granted publication date: 20070711 License type: Exclusive license Record date: 20080610 |
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