CN1513681A - Imitation of ancient stereo polished brick and its production method - Google Patents
Imitation of ancient stereo polished brick and its production method Download PDFInfo
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- CN1513681A CN1513681A CNA031402224A CN03140222A CN1513681A CN 1513681 A CN1513681 A CN 1513681A CN A031402224 A CNA031402224 A CN A031402224A CN 03140222 A CN03140222 A CN 03140222A CN 1513681 A CN1513681 A CN 1513681A
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Abstract
A pseudo-classical polished stereoscopic brick is made of natural mineral materials, ordinary pigments and raw patterning material through moulding the relief-type decorative pattern, silk screen printing, spraying color slurry, and polishing. Its advantages are high strength and classical art effect.
Description
Technical field
The present invention relates to building decoration ceramic material field, particularly a kind of three-dimensional polished bricks modelled after an antique and manufacture method thereof.
Background technology
Three-dimensional polished bricks modelled after an antique integrates the aesthstic performance that charm is simple and tasteful, gradation is clearly demarcated, texture is natural, third dimension is strong of the physicochemical property and the three-dimensional brick modelled after an antique of polished brick in porcelain character excellence, its surface light and sliding, plain and not gorgeous, decorative effect is just as a beautiful landscape painting, having more artistry and sight than general polished brick in porcelain character, is a kind of very promising novel high-grade building decoration ceramic material.Yet, because the particularity of three-dimensional polished bricks decoration technology modelled after an antique, there are the problem of following several respects in existing three-dimensional brick modelled after an antique and production method thereof: (1) is owing to the base substrate batching is unreasonable, can not make base substrate both have enough green strengths, have good penetration simultaneously so that ooze colored liquid and be easy to infiltrate base substrate inside; (2) in compacting process,, easily cause the slabbing of base substrate and density inhomogeneous or inappropriate, thereby influence the intensity of base substrate because powder quality, moisture and drawing method is improper; (3) in the base substrate coloring process, the coloring blank slurry performance affects to dry body strength, and the sizing mode also influences the blank strength after the sizing.Above factor all can affect to base substrate or the intensity of burning till product to a certain extent, thereby causes that product breakage rate height, yield rate are low, production cost increases, and influences economic benefit of enterprises.
Summary of the invention
At the deficiencies in the prior art, the invention provides a kind of primitive and crude simpleness, lines succinct, ooze floral pattern and be rich in anima and the clearly demarcated modelled after an antique three-dimensional polished bricks of gradation.The present invention also provides the method for producing this kind three-dimensional polished bricks modelled after an antique, and this kind production method can improve blank strength and burn till the intensity of back product, thereby reduces the breakage rate of product, improves yield rate.
In order to reach technique scheme, the recipe ratio of the various batchings of three-dimensional polished bricks modelled after an antique of the present invention is:
Body recipe:
SiO
265-72％????Al
2O
317-21％????Fe
2O
3＜1.0％
TiO
2＜0.5％????CaO＜0.5％????????MgO0.5-1.5％
K
2O
2-4％??????Na
2O
2-4％????????I.L.3-5％
The coloring blank slurry prescription:
Base substrate base furnish 100%, colorant 0.5-3.0%, CMC0.2%, sodium phosphate trimer 0.1-0.3%, water 3-8%.
Ooze colored formula of liquid:
Patent flour 7-12%, glycerine 10-15%, industrial alcohol 3-5%, painted
Soluble-salt 0.5-6%, water 65-80%.
The technological process of production of the present invention is:
1. with feed proportioning and carry out ball milling;
2. stock coloring blank slurry, the base slurry is carried out spray-drying and old;
3. pattern is prepared burden;
4. press shape;
5. green compact drying;
6. ooze flower with the colored liquid that oozes for preparing;
7. apply the coloring blank slurry for preparing;
8. burn till;
9. grinding, polishing;
10. pick, packing;
It is characterized in that: above-mentioned technology is by artistic design and the design of pressure-shaped mould tool, gives product surface primitive and crude, rough scenery with hills and waters pattern contour; Impose on the convex surfaces of dry base substrate by the design requirement with silk screen print method; Coloring blank slurry is imposed on the local or whole surface of base substrate with spray process; Main technologic parameters is:
A. base substrate main technologic parameters:
A. mud balance 1.70-1.75g/m
3
B. moil fineness 1.0-2.0% (250 mesh screen residue)
C. powder moisture content 5.5-7.5%
D. powder unit weight 〉=0.97g/cm
3
E. press shape specific pressure 3500-4500Pa
F. green compact thickness 11.0-12.0mm (to 600mm*600mm)
G. dry body strength 〉=280Pa
H. dry body moisture≤0.2%
I. dry body temperature 45-65 ℃
J. maximum sintering temperature≤1230 ℃
K. firing period 55-65Min
B. ooze colored liquid important technological parameters:
A. viscosity: 25-30S (coating-4 viscosity meter, silk screen are the 60-80 order)
B.PH value: 6-8
C. apply mode: a serigraphy
C. coloring blank slurry important technological parameters:
A. proportion: 1.65-1.72g/m
3
B. fineness: 0.5-0.8% (250 mesh screen residue)
C. viscosity: viscosity: 25-30S (coating-4 viscosity meter)
D. applied amount: 300-600g/pcs (to 600mm*600mm)
E. apply mode: secondary or repeatedly the spray
D. grinding-polishing important technological parameters:
Stock removal: 0.3-0.6mm (representing) with thickness difference before and after goods grinding-polishing.
Owing to adopted technique scheme, the present invention to have following beneficial effect:
(1) body recipe is superior, and good raw material is prepared burden to select plasticity for use, can guarantee that base substrate had both had enough green strengths to reduce the breakage rate of product, can guarantee that again base substrate has good penetration and infiltrates base substrate inside easily so that ooze colored liquid.
(1) by artistic design and the design of pressure-shaped mould tool, give product surface primitive and crude, rough scenery with hills and waters pattern contour, billet surface forms the relief shape of certain concavo-convex discrepancy in elevation.
(2) will ooze colored liquid imposes on dry base substrate by the design requirement with silk screen print method convex surfaces, ooze the absorption and the capillarity of colored liquid dependence base substrate, and ion-exchange and diffusion, penetrate into base substrate inside, through after high temperature burns till, these soluble inorganic salts and base substrate generation chemical reaction and stablize colour generation.
(3) will form with the essentially identical coloring blank slurry of base substrate and impose on the local or whole surface of base substrate with spray process, because coloring blank slurry is close with the base substrate composition, the two burns till adaptability and associativity is good.
(4) goods burn till after a series of grinding and polishing processing, the whole base slurry layers and the part crowning at its rat position are ground off, make pattern, texture, color and the gloss at concave-convex surface position present certain difference, thereby obtain the facing modelled after an antique of rich color and well-bedded strong stereoeffect.
Description of drawings
Fig. 1 is a process chart of the present invention.
The specific embodiment
Provide embodiments of the invention and manufacturing process and effect below.
1. the technological process of three-dimensional polished bricks modelled after an antique of the present invention as shown in Figure 1.
2. raw material
The used raw material of the present invention is natural mineral raw, and colorant adopts general body stain, and oozing colored raw material also is the common colored polished bricks raw material that oozes, and the primary raw material chemical composition sees Table 1.
Table 1 primary raw material chemical composition (%)
| The raw material code name | ?SiO 2 | ?Al 2O 3 | ?Fe 2O 3 | ?TiO 2 | ?CaO | ?MgO | ?K2O | ?Na 2O | ?I.L. | ?∑ |
| ?A21 | ?70.10 | ?19.32 | ?1.31 | ?0.17 | ?0.47 | ?0.60 | ?1.93 | ?0.20 | ?5.89 | ?99.99 |
| ?A22 | ?76.88 | ?15.24 | ?0.47 | ?0.26 | ?0.28 | ?0.28 | ?1.50 | ?0.08 | ?4.95 | ?99.94 |
| ?A24 | ?55.00 | ?30.50 | ?1.01 | ?0.25 | ?0.35 | ?0.06 | ?0.60 | ?0.18 | ?11.93 | ?99.88 |
| ?A25 | ?61.64 | ?23.78 | ?1.13 | ?0.17 | ?0.35 | ?0.29 | ?3.48 | ?0.55 | ?8.30 | ?99.69 |
| ?B21 | ?70.03 | ?17.84 | ?0.32 | ?0.16 | ?0.58 | ?0.20 | ?1.20 | ?8.55 | ?1.07 | ?99.95 |
| ?B23 | ?66.84 | ?18.42 | ?0.36 | ?0.29 | ?0.33 | ?0.36 | ?8.15 | ?3.70 | ?1.14 | ?99.59 |
| ?B29 | ?69.50 | ?16.18 | ?0.36 | ?0.18 | ?0.58 | ?0.32 | ?7.80 | ?2.90 | ?1.03 | ?98.85 |
| ?B33 | ?66.51 | ?19.02 | ?0.38 | ?0.19 | ?0.21 | ?0.45 | ?3.96 | ?6.38 | ?1.53 | ?98.63 |
3. fill a prescription
The 3-1 body recipe
Base substrate basic components chemical composition sees Table 2.
Table 2 base substrate basic components chemical composition (%)
| SiO 2 | ?Al 2O 3 | ?Fe 2O 3 | ?TiO 2 | ?CaO | ?MgO | ?K2O | ?Na 2O | ??I.L. | ?∑ |
| 68.24 | ?19.56 | ?0.68 | ?0.21 | ?0.37 | ?0.83 | ?2.25 | ?2.84 | ??4.70 | ?99.68 |
Base substrate pattern prescription is the relevant colorant that adds 0.1-3.0% in its basic components, promptly makes various mill base toners, is delivered to after two kinds or multiple toner mix by proper proportion and presses the shape operation to be shaped.
3-2 coloring blank slurry prescription
The coloring blank slurry prescription is that requirement adds an amount of colorant and additive forms by matching colors on the basis of base substrate basic components, and the coloring blank slurry prescription sees Table 3.
Table 3 base slurry formula (quality %)
| Material name | Base substrate base furnish (reserve pit slurry) | Colorant | CMC | Sodium phosphate trimer | Water |
| Proportioning | 100 | ??0.5-3.0 | 0.2 | ?0.1-0.3 | 3-8 |
3-3 oozes colored formula of liquid
Ooze colored formula of liquid and see Table 4.
Table 4 oozes colored formula of liquid (quality %)
| Material name | Patent flour | Glycerine | Industrial alcohol | Painted soluble-salt | Water |
| Proportioning | ??7-12 | ??10-15 | ??3-5 | ???0.5-6 | ??65-80 |
4. base substrate main technologic parameters
4-1 mud balance 1.70-1.74g/m
3
4-2 moil fineness 1.0-1.5% (250 mesh screen residue)
4-3 powder moisture content 5.8-6.5%
4-3 powder unit weight 〉=0.97g/cm
3
4-4 presses shape specific pressure 3500-4500Pa
4-5 green compact thickness 11.7-12.0mm (to 600mm*600mm)
4-6 dry body strength 〉=280Pa
4-7 dry body moisture≤0.2%
45-65 ℃ of 4-8 dry body temperature
1200 ℃ of 4-9 maximum sintering temperatures
4-10 firing period 60-65Min
5. ooze colored liquid important technological parameters:
5-1 viscosity: 25-30S (coating-4 viscosity meter, silk screen are the 60-80 order)
5-2PH value: 6-8
5-3 applies mode: a serigraphy
6. coloring blank slurry important technological parameters:
6-1 proportion: 1.68-1.72g/m
3
6-2 fineness: 0.5-0.8% (250 mesh screen residue)
6-3 viscosity: viscosity: 25-30S (coating-4 viscosity meter)
6-4 applied amount: 480-600g/pcs (to 600mm*600mm)
6-5 applies mode: secondary or repeatedly the spray
7. grinding-polishing important technological parameters:
7-1 grinding-polishing abrading block collocation and bistrique operating pressure see Table 5.
Table 5 each collocation of bistrique abrading block and operating pressure
| Operation | Corase grind | Middle mill | |||||||||||||||||||||
| The bistrique sequence number | ??1 | ??2 | ??3 | ??4 | ??5 | ??6 | ??7 | ??8 | ??9 | ??10 | ??11 | ????12 | ????13 | ????14 | ????15 | ||||||||
| Abrading block (order) | ?????8 | ????16 | ??24 | ??36 | ??46 | ??60 | ??80 | ??100 | ??120 | ????????180 | ???????240 | ||||||||||||
| Operating pressure (pa) | ???????????????????????????20-25 | ????????????????????????????????20-25 | |||||||||||||||||||||
| Operation | Correct grinding | Polishing | |||||||||||||||||||||
| The bistrique sequence number | ??16 | ??17 | ??18 | ??19 | ??20 | ??21 | ??22 | ????23 | ??24 | ????25 | ????26 | ||||||||||||
| Abrading block (order) | ??300 | ??400 | ???????600 | ??????800 | ?1000 | ????1200 | ??1500 | ??????????????????pp | |||||||||||||||
| Operating pressure (pa) | ????????????????????????15-20 | ??????????????10-15 | |||||||||||||||||||||
7-1 stock removal: 0.4-0.6mm (representing) with thickness difference before and after goods grinding-polishing.
The modelled after an antique three-dimensional polished bricks of producing with this example prescription and method reaches following performance technologies index:
Water absorption rate: 0.10%
Rupture strength: 61.9pa
Surface Mohs' hardness: 7
Heat endurance: 130 ℃/20 ℃ cold cycling are not split for 20 times
Frost resistance: ± 15 ℃ of freeze thawing circulations are not split for 50 times
Anti-dark mill: 116mm
3
Coefficient of friction (ebonite): 0.63
Glossiness: 61%
Dimensional discrepancy :-0.1% to+0.1%
Presentation quality: do not have obvious flaw
Claims (2)
1, a kind of three-dimensional polished bricks modelled after an antique, it is characterized in that: the recipe ratio of its various batchings is:
Body recipe:
SiO
265-72％????Al
2O
317-21％?????Fe
2O
3＜1.0％
TiO
2＜0.5％????CaO＜0.5％?????????MgO0.5-1.5％
K
2O
2-4％??????Na
2O
2-4％?????????I.L.3-5％
The coloring blank slurry prescription:
Base substrate base furnish 100%, colorant 0.5-3.0%, CMC0.2%, sodium phosphate trimer 0.1-0.3%, water 3-8%.
Ooze colored formula of liquid:
Patent flour 7-12%, glycerine 10-15%, industrial alcohol 3-5%, painted
Soluble-salt 0.5-6%, water 65-80%.
2, the production method of the described three-dimensional polished bricks of claim 1, its technological process is:
1. with feed proportioning and carry out ball milling;
2. stock coloring blank slurry, the base slurry is carried out spray-drying and old;
3. pattern is prepared burden;
4. press shape:
5. green compact drying;
6. ooze flower with the colored liquid that oozes for preparing;
7. apply the coloring blank slurry for preparing;
8. burn till;
9. grinding, polishing;
10. pick, packing;
It is characterized in that: above-mentioned technology is by artistic design and the design of pressure-shaped mould tool, gives product surface with the scenery with hills and waters pattern contour; Impose on the convex surfaces of dry base substrate by the design requirement with silk screen print method; Coloring blank slurry is imposed on the local or whole surface of base substrate with spray process; Its main technologic parameters is:
A. base substrate main technologic parameters:
A. mud balance 1.70-1.75g/m
3
B. moil fineness 1.0-2.0% (250 mesh screen residue)
C. powder moisture content 5.5-7.5%
D. powder unit weight 〉=0.97g/cm
3
E. press shape specific pressure 3500-4500Pa
F. green compact thickness 11.0-12.0mm (to 600mm*600mm)
G. dry body strength 〉=280Pa
H. dry body moisture≤0.2%
I. dry body temperature 45-65 ℃
J. maximum sintering temperature≤1230 ℃
K. firing period 55-65Min
B. ooze colored liquid important technological parameters:
A. viscosity: 25-30S (coating-4 viscosity meter, silk screen are the 60-80 order)
B.PH value: 6-8
C. apply mode: a serigraphy
C. coloring blank slurry important technological parameters:
A. proportion: 1.65-1.72g/m
3
B. fineness: 0.5-0.8% (250 mesh screen residue)
C. viscosity: viscosity: 25-30S (coating-4 viscosity meter)
D. applied amount: 300-600g/pcs (to 600mm*600mm)
E. apply mode: secondary or repeatedly the spray
D. grinding-polishing important technological parameters:
Stock removal: 0.3-0.6mm (representing) with thickness difference before and after goods grinding-polishing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03140222 CN1257129C (en) | 2003-08-19 | 2003-08-19 | Imitation of ancient stereo polished brick and its production method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03140222 CN1257129C (en) | 2003-08-19 | 2003-08-19 | Imitation of ancient stereo polished brick and its production method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1513681A true CN1513681A (en) | 2004-07-21 |
| CN1257129C CN1257129C (en) | 2006-05-24 |
Family
ID=34240248
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 03140222 Expired - Fee Related CN1257129C (en) | 2003-08-19 | 2003-08-19 | Imitation of ancient stereo polished brick and its production method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1257129C (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100345797C (en) * | 2005-09-27 | 2007-10-31 | 广东博华陶瓷有限公司 | Polished bricks and prodn. method thereof |
| CN102249654A (en) * | 2011-04-29 | 2011-11-23 | 广西南山瓷器有限公司 | Ancient blue and white porcelain and production method thereof |
| CN106673711A (en) * | 2015-10-28 | 2017-05-17 | 佛山市东鹏陶瓷有限公司 | Method for producing stain-bleeding porcelain tile |
| CN107266054A (en) * | 2016-04-06 | 2017-10-20 | 福建省德化县成艺陶瓷有限公司 | A kind of ceramic clay composition |
| CN108002819A (en) * | 2017-12-12 | 2018-05-08 | 广东冠星陶瓷企业有限公司 | A kind of preparation process based on the internal wall brick once burnt |
| CN110054475A (en) * | 2019-04-09 | 2019-07-26 | 广东金意陶陶瓷集团有限公司 | A kind of bottom has the Ceramic Tiles and preparation method thereof of porous structure |
-
2003
- 2003-08-19 CN CN 03140222 patent/CN1257129C/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100345797C (en) * | 2005-09-27 | 2007-10-31 | 广东博华陶瓷有限公司 | Polished bricks and prodn. method thereof |
| CN102249654A (en) * | 2011-04-29 | 2011-11-23 | 广西南山瓷器有限公司 | Ancient blue and white porcelain and production method thereof |
| CN102249654B (en) * | 2011-04-29 | 2015-11-25 | 广西南山瓷器有限公司 | A kind of ancient blue or green cultural porcelain and production method thereof |
| CN106673711A (en) * | 2015-10-28 | 2017-05-17 | 佛山市东鹏陶瓷有限公司 | Method for producing stain-bleeding porcelain tile |
| CN107266054A (en) * | 2016-04-06 | 2017-10-20 | 福建省德化县成艺陶瓷有限公司 | A kind of ceramic clay composition |
| CN108002819A (en) * | 2017-12-12 | 2018-05-08 | 广东冠星陶瓷企业有限公司 | A kind of preparation process based on the internal wall brick once burnt |
| CN110054475A (en) * | 2019-04-09 | 2019-07-26 | 广东金意陶陶瓷集团有限公司 | A kind of bottom has the Ceramic Tiles and preparation method thereof of porous structure |
| CN110054475B (en) * | 2019-04-09 | 2022-03-22 | 广东金意陶陶瓷集团有限公司 | Ceramic tile with porous structure at bottom and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1257129C (en) | 2006-05-24 |
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