CN1927763A - High-white transparent material formulation and manufacture method of crystal full transparency polishing brick - Google Patents
High-white transparent material formulation and manufacture method of crystal full transparency polishing brick Download PDFInfo
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- CN1927763A CN1927763A CN 200610122254 CN200610122254A CN1927763A CN 1927763 A CN1927763 A CN 1927763A CN 200610122254 CN200610122254 CN 200610122254 CN 200610122254 A CN200610122254 A CN 200610122254A CN 1927763 A CN1927763 A CN 1927763A
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- white
- transparent material
- ice crystal
- saturating
- stone flour
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Abstract
The present invention relates to one kind of decorating transparent vitrified ceramic tile and its material recipe and production process. The material for the decorating transparent vitrified ceramic tile consists of white stone powder 10-25 wt%, Chaozhou sand 15-30 wt%, Guangxi sand 15-30 wt%, white jade powder 5-25 wt%, Hunan stone powder 15-30 wt%, kaolin 10-20 wt%, black mud 1-10 wt% and M-type flux 0-10 wt%. The production process includes the steps of compounding material, ball milling, color mixing, spray drying, forming, drying, sintering and polishing. The produced ceramic tile is transparent, high white and high bright, and has no radioactivity, relatively high heat expanding coefficient and other advantages.
Description
Technical field:
The present invention relates to the high-white transparent material formulation of the beautiful matter full impregnated of a kind of ice crystal decoration technology vitreous ceramic tiles and the production method of this brick.
Background technology:
Along with the polished tile state of the art is constantly progressive, the range of application of transparent material in polished tile also constantly enlarges.The production technology that common glomerocryst micro mist just contains transparent material micro mist is ripe relatively, big and small producer some products that release one after another.Usually, transparent material ratio in the glomerocryst micro mist is about 25-50%, as the transparent material ratio of further raising, as reach defective such as will produce distortion big (especially later stage distortion) more than 95%, the pin hole fusion hole is many, and transparent material whiteness low (having only about 45 degree), color development sensitivity, aberration are big, yield poorly.These difficult problems have limited the application of transparent material in the micro-powdered polishing brick, the application of the transparent material of especially high whiteness in polished tile.
Summary of the invention:
The objective of the invention is to overcome the deficiencies in the prior art, the breakthrough production method of having introduced the beautiful matter full impregnated polished tile high-white transparent material formulation of a kind of ice crystal and having produced the beautiful matter full impregnated of a kind of ice crystal decoration technology vitreous ceramic tiles with this prescription.
For achieving the above object, high-white transparent material formulation provided by the invention is:
White stone powder 10-25 Chaozhou sand 15-30 Guangxi sand 15-30 white jade stone flour 5-25
Hunan stone flour 15-30 kaolin 10-20 black mud 1-10 M type flux 0-10.
Described white jade stone flour be a kind of Gao Bai, high potassium, low temperature through artificial selected being crushed to below 10 orders, the stone flour of circulation deferrization repeatedly, its chemical constitution is as follows:
| Project | SiO 2 | Al 2O 3 | Fe 2O 3 | TiO 2 | CaO | MgO | K 2O | Na 2O | I.O.L |
| Form | 60-80 | 10-20 | 0-1 | 0-1 | 0-1 | 0-1 | 5-15 | 0-5 | 1-5 |
Described M type flux chemical composition range is as follows:
| Project | SiO 2 | Al 2O 3 | Fe 2O 3 | TiO 2 | CaO | MgO | K 2O | Na 2O | I.O.L |
| Form | 40-70 | 10-20 | 0-1 | 0-1 | 1-10 | 1-10 | 1-10 | 1-10 | 1-10 |
The method of producing the beautiful matter full impregnated of ice crystal decoration technology vitreous ceramic tiles with this high-white transparent material is:
(1), batching: white stone powder 10-25, Chaozhou sand 15-30, Guangxi sand 15-30, white jade stone flour 5-25, Hunan stone flour 15-30, kaolin 10-20, black mud 1-10, M type flux 0-10;
(2), ball milling: confected materials is qualified to moisture content, fineness, viscosity through ball milling, and behind the blowing, by centrifugal rotation 100 orders shake sieve and 8 deferrization process of three-dimensional circulation, iron-holder is less than 0.1% with the beautiful saturating slurry of ice crystal, and it is old to be screened to stock tank through deironing;
(3), colour mixture: according to space of a whole page difference that colorant is even by being stirred in the different proportionings adding mud, wherein the colour mixture processing parameter is:
Red thoroughly: transparent material+L1300 0.1-1.0%
Saturating yellow: transparent material+L1000 0.1-1.0% praseodymium yellow 0.1-1.0%
Reveal the green: the transparent material+apple green 0.1-1.0% of L1000 0.1-1.0%
Saturating white: transparent material 10-50%+ super-white marerial 50-100%
(4), spraying drying: beautiful saturating mud of ice crystal and spray-dried moisture content and the qualified powder of grain composition made of mill base;
(5), moulding: transparent material of all kinds is by processing requirement, be crushed to 200 order micro mists through high frequency, pile up blanking by the accurate index drum of frequency-variable electronic again, all kinds of micro mist material enter the free cloth of mobile truck according to a certain ratio, be transferred to the press-molding die cavity by ultra-thin grid, form through the secondary material distributing compacting;
(6) drying: the drying kiln dries the moisture content of moulding adobe to below 1%, guarantees that adobe has certain intensity, adapts to the postorder operation;
(7) burn till: maximum sintering temperature 1210 degree, firing period reaches 2 hours, and the slow firing technique of high temperature has solved the distortion of polished tile later stage, has guaranteed that end properties is stable;
(8) polishing: the agglomerating adobe is wipeed off through edging and is polished to finished product, presses the inner quality standard go-on-go by quality inspection, packing back warehouse entry.
The selected introducing of the present invention know clearly high white type white jade stone flour and Gao Bai M type flux cooling material, the white jade stone flour is that a kind of Gao Bai, high potassium, low temperature are through artificial selected being crushed to below 10 orders, the stone flour that obtains of circulation deferrization repeatedly, M type flux is the high white strong cooling flux of a kind of synthetic, be different from general low temperature feedstock, also have the transparent material physical strength of increasing and fastness to rubbing function.By material combination of the present invention and optimization of C, resulting transparent material has the beautiful matter transparent feel of ice crystal, ultrahigh brightness (reaching 65 degree), high glossiness (reaches 80 degree, super clean bright 95 degree), radiationless "dead" pollution, free of pinholes, no fusion hole, no organism, wear-resisting anti-skidding, have a advantage than high expansion coefficient, adaptation ultrahigh brightness polished tile base substrate.The product surface ice crystal made from method of the present invention is beautiful saturating, is covered with the brick face round and round as beautiful piece as the fat, reappears like amber.The white lines is indistinct to be appeared in one's mind in moistening into jade like the white marble marrow, the colour of indistinct colour generation more seemingly curls upwards among the white marble lines with smoke coiling up from burning incense, the beautiful sense of white and colored lines levels are rich is strong, appears in one's mind like the spray of setting out layer by layer, as the phantom stealth of mirage.
Embodiment:
The invention will be further described below in conjunction with embodiment.
Embodiment 1:
1, the beautiful matter transparent material formulation of ice crystal:
(1) prescription is formed: white stone powder 10, Chaozhou sand 22, Guangxi sand 18, Hunan stone flour 18.5, white jade stone flour 10, kaolin 12, black mud 4, M flux 6.5.
(2) raw material chemical constitution
2, colour mixture processing compound
Saturating red material: transparent material 100%+L-1300 0.16%
Saturating white material: transparent material 20%+ super-white marerial 80%
3, moulding process
Lining is formed:
| The hopper numbering | A | B | C | D |
| The powder title | Saturating white material | High-white transparent material | Saturating red material | High-white transparent material |
| Broken fineness (200 order) % | 10 | 15 | 15 | 15 |
| Lining ratio % | 15 | 35 | 15 | 35 |
Distributing mode: secondary material distributing moulding number of times 3.5-4.0 time/minute
Forming pressure 350-380bar
4, dry firing process
300 ℃ of 120 minutes dry kiln cycles of drying temperature
5, burn till parameter:
Firing period 120 minutes
Firing temperature (℃):
| Firing zone | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 |
| The face temperature | 995 | 1065 | 1073 | 1102 | 1120 | 1137 | 1155 | 1163 | 1164 | 1162 |
| End temperature | 1025 | 1100 | 1115 | 1159 | 1154 | 1181 | 1191 | 1195 | 1195 | 1202 |
| Firing zone | 11 | 12 | 13 | 14 | 15 | 16 | 17 | 18 | 19 | 20 |
| The face temperature | 1164 | 1166 | 1169 | 1168 | 1162 | 1158 | 1158 | 1154 | 1113 | 1042 |
| End temperature | 1205 | 1207 | 1204 | 1213 | 1203 | 1186 | 1190 | 1185 | 1018 | 965 |
Embodiment 2
1, the beautiful matter transparent material formulation of ice crystal: with embodiment 1
2, the colour mixture processing compound material that reveals the green: transparent material 100%+L-1000 0.15% is apple green
0.13% saturating white material: transparent material 20%+ super-white marerial 80%
3, moulding process
Lining is formed:
| The hopper numbering | A | B | C | D |
| The powder title | Saturating white material | High-white transparent material | Material reveals the green | High-white transparent material |
| Broken fineness (200 order) % | 10 | 15 | 15 | 15 |
| Lining ratio % | 15 | 35 | 15 | 35 |
Other molding parameter is identical with embodiment 1
4, dry firing process: with embodiment 1; 5, burn till parameter: with embodiment 1;
Embodiment 3
1, the beautiful matter transparent material formulation of ice crystal: identical with embodiment 1
2, the saturating yellow material of colour mixture processing compound: transparent material+L1000 0.35% praseodymium yellow 0.12%;
Saturating white material: transparent material 20%+ super-white marerial 80%
3, moulding process
Lining is formed:
| The hopper numbering | A | B | C | D |
| The powder title | Saturating white material | High-white transparent material | Saturating yellow material | High-white transparent material |
| Broken fineness (200 order) % | 10 | 15 | 15 | 15 |
| Lining ratio % | 15 | 35 | 15 | 35 |
Other molding parameter is identical with embodiment 1
4, dry firing process: with embodiment 1; 5, burn till parameter: with embodiment 1.
Embodiment 4
1, the beautiful matter transparent material formulation of ice crystal: identical with embodiment 1
2, colour mixture processing compound
Saturating white material: transparent material 20%+ super-white marerial 80%
3, moulding process
Lining is formed:
| The hopper numbering | A | B | C |
| The powder title | Saturating white | High-white transparent material | High-white transparent material |
| Broken fineness (200 order) % | 10 | 15 | 15 |
| Lining ratio % | 20 | 40 | 40 |
Other molding parameter is identical with embodiment 1
4, dry firing process: identical with embodiment 1
5, burn till parameter: identical with embodiment 1
By above four embodiments, we research and develop red, green, yellow, the Bai Gongsi beautiful matter full impregnated of a serial ice crystal polished tile.
Claims (4)
1, the beautiful matter full impregnated of a kind of ice crystal polished tile high-white transparent material formulation, it is characterized in that: the component of this prescription is: white stone powder 10-25 Chaozhou sand 15-30 Guangxi sand 15-30 white jade stone flour 5-25 Hunan stone flour 15-30 kaolin 10-20 black mud 1-10M type flux 0-10.
2, the beautiful matter full impregnated of a kind of ice crystal according to claim 1 polished tile high-white transparent material formulation, it is characterized in that: the white jade stone flour is that a kind of Gao Bai, high potassium, low temperature are through artificial selected being crushed to below 10 orders, the stone flour of circulation deferrization repeatedly, its chemical constitution is as follows:
Project SiO
2 Al
2O
3 Fe
2O
3 TiO
2 CaO MgO K
2O
Na
2O
I.O.L
Form 60-80 10-20 0-1 0-1 0-1 0-1 5-15 0-5 1-5
3, the beautiful matter full impregnated of a kind of ice crystal according to claim 1 polished tile high-white transparent material formulation, it is characterized in that: M type flux chemical composition range is as follows:
Project SiO
2 Al
2O
3 Fe
2O
3 TiO
2 CaO MgO K
2O
Na
2O
I.O.L
Form 40-70 10-20 0-1 0-1 1-10 1-10 1-10 1-10 1-10
4, the method for the beautiful matter full impregnated of ice crystal according to claim 1 polished tile high-white transparent material formulation production ceramic tile, it is characterized in that: the concrete steps of this method are:
(1), batching: white stone powder 10-25, Chaozhou sand 15-30, Guangxi sand 15-30, white jade stone flour 5-25, Hunan stone flour 15-30, kaolin 10-20, black mud 1-10, M type flux 0-10;
(2), ball milling: confected materials is qualified to moisture content, fineness, viscosity through ball milling, and behind the blowing, by centrifugal rotation 100 orders shake sieve and 8 deferrization process of three-dimensional circulation, iron-holder is less than 0.1% with the beautiful saturating slurry of ice crystal, and it is old to be screened to stock tank through deironing;
(3), colour mixture: according to space of a whole page difference that colorant is even by being stirred in the different proportionings adding mud, wherein the colour mixture processing parameter is:
Red thoroughly: transparent material+L1300 0.1-1.0%
Saturating yellow: transparent material+L1000 0.1-1.0% praseodymium yellow 0.1-1.0%
Reveal the green: the transparent material+apple green 0.1-1.0% of L1000 0.1-1.0%
Saturating white: transparent material 10-50%+ super-white marerial 50-100%
(4), spraying drying: beautiful saturating mud of ice crystal and spray-dried moisture content and the qualified powder of grain composition made of mill base;
(5), moulding: transparent material of all kinds is by processing requirement, be crushed to 200 order micro mists through high frequency, pile up blanking by the accurate index drum of frequency-variable electronic again, all kinds of micro mist material enter the free cloth of mobile truck according to a certain ratio, be transferred to the press-molding die cavity by ultra-thin grid, form through the secondary material distributing compacting;
(6) drying: the drying kiln dries the moisture content of moulding adobe to below 1%, guarantees that adobe has certain intensity, adapts to the postorder operation;
(7) burn till: maximum sintering temperature 1210 degree, firing period reaches 2 hours, and the slow firing technique of high temperature has solved the distortion of polished tile later stage, has guaranteed that end properties is stable;
(8) polishing: the agglomerating adobe is wipeed off through edging and is polished to finished product, presses the inner quality standard go-on-go by quality inspection, packing back warehouse entry.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610122254 CN1927763A (en) | 2006-09-19 | 2006-09-19 | High-white transparent material formulation and manufacture method of crystal full transparency polishing brick |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610122254 CN1927763A (en) | 2006-09-19 | 2006-09-19 | High-white transparent material formulation and manufacture method of crystal full transparency polishing brick |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1927763A true CN1927763A (en) | 2007-03-14 |
Family
ID=37857920
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200610122254 Pending CN1927763A (en) | 2006-09-19 | 2006-09-19 | High-white transparent material formulation and manufacture method of crystal full transparency polishing brick |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102173739A (en) * | 2010-12-23 | 2011-09-07 | 鄂尔多斯市陶尔斯陶瓷有限公司 | Method for manufacturing polishing brick by utilizing calcium silicate slag |
| CN104649684A (en) * | 2015-02-13 | 2015-05-27 | 合肥市美橙瓷固橱柜有限公司 | Porcelain panel |
| CN107244908A (en) * | 2017-06-02 | 2017-10-13 | 佛山石湾华鹏陶瓷有限公司 | A kind of high white jade stone polished brick adobe and its ceramic tile preparation method |
| CN109251019A (en) * | 2018-09-30 | 2019-01-22 | 佛山市富域新材料有限公司 | Beautiful matter Ceramic Tiles and its production method |
| CN116396065A (en) * | 2023-03-09 | 2023-07-07 | 佛山市富域新材料有限公司 | Ice jade ceramic tile and preparation method thereof |
-
2006
- 2006-09-19 CN CN 200610122254 patent/CN1927763A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102173739A (en) * | 2010-12-23 | 2011-09-07 | 鄂尔多斯市陶尔斯陶瓷有限公司 | Method for manufacturing polishing brick by utilizing calcium silicate slag |
| CN104649684A (en) * | 2015-02-13 | 2015-05-27 | 合肥市美橙瓷固橱柜有限公司 | Porcelain panel |
| CN107244908A (en) * | 2017-06-02 | 2017-10-13 | 佛山石湾华鹏陶瓷有限公司 | A kind of high white jade stone polished brick adobe and its ceramic tile preparation method |
| CN107244908B (en) * | 2017-06-02 | 2021-01-15 | 佛山鹰牌科技有限公司 | High-whiteness jade-like polished tile adobe and tile preparation method thereof |
| CN109251019A (en) * | 2018-09-30 | 2019-01-22 | 佛山市富域新材料有限公司 | Beautiful matter Ceramic Tiles and its production method |
| CN116396065A (en) * | 2023-03-09 | 2023-07-07 | 佛山市富域新材料有限公司 | Ice jade ceramic tile and preparation method thereof |
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