CN1385070A - Disinfectant composition containing flumorph - Google Patents
Disinfectant composition containing flumorph Download PDFInfo
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- CN1385070A CN1385070A CN 01113936 CN01113936A CN1385070A CN 1385070 A CN1385070 A CN 1385070A CN 01113936 CN01113936 CN 01113936 CN 01113936 A CN01113936 A CN 01113936A CN 1385070 A CN1385070 A CN 1385070A
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Abstract
The present invention relates to a fungicide compound, containing fungicide fluoromorpholine (SYP-L190) and folloiwng any one of strobin Fungicide/Strobilurin Analogues, kresoxim-methyl, azoxystrobin, trifloxystrobin, picoxystrobin, pyraclostrobin, metominostrobin, SSF-129, NA83 and enestroburin, etc. Said compound possesses synergistic effect, can reduce resistance and raise safety.
Description
The present invention relates to contain the microbicide compositions of the bactericide material of combination, relate in particular to the preparation of compositions and the application that contain flumorph (SYP-L190) and methoxy acrylic bactericide (Strobin Fungicides/Strobilurin Analogues).
People know that methoxy acrylic bactericide is important at present, as to have a broad-spectrum sterilization activity compounds.This compounds can have been bought from the market, also can be from " finding external pesticide species handbook (enlarged edition) or " agricultural chemicals handbook " (the ThePesticide Manual) the 12nd edition (2000) by the Britain crop protection committee (The British Crop Protection Coucil) publication that the Ministry of Chemical Industry's agricultural chemicals central information facility is write.
People also know, can kill many plant species germs effectively by the flumorph that inventors of the present invention invented, the existing narration in CN 1167568A of its preparation example.The chemical name and the structure of flumorph are as follows: 3-(4-fluorophenyl)-3-(3, the 4-Dimethoxyphenyl) acryloyl morpholine
In order to satisfy the needs of agricultural production, improve the bactericidal effect of flumorph, enlarge fungicidal spectrum, reduce use cost and improve safety, inventors of the present invention are devoted to develop the new microbicide compositions that contains flumorph all the time.
Have been found that now their bactericidal effect can have the improvement of surprising degree with the use that is mixed of flumorph and methoxy acrylic bactericide.
The present invention proposes a kind of microbicide compositions, contain flumorph and a kind of methoxy acrylic bactericide in the said composition.
The example of methoxy acrylic bactericide that is applicable to the present composition is as follows:
1, (E)-2-methoxyimino-[2-(o-methyl-benzene oxygen ylmethyl) phenyl] methyl acetate (kresoxim-methyl, kresoxim-methyl or kresoxim-methyl)
2, (E)-2-{2-[6-(2-cyano-benzene oxygen) pyrimidine-4-base oxygen] phenyl }-3-methoxy-methyl acrylate (azoxystrobin, Fluoxastrobin)
3, (E, E)-methoxy imino-[2-[1-(3-trifluoromethyl)-ethyleneimine oxygen methyl]-phenyl]-methyl acetate (trifloxystrobin, oxime bacterium ester)
4, (E)-3-methoxyl group-2-[2-(6-trifluoromethyl-2-pyridine oxygen ylmethyl) phenyl] methyl acrylate (picoxystrobin, ZEN 90160)
5, N-[2-[1-(4-chlorphenyl)-1H-pyrazole-3-yl oxygen ylmethyl] phenyl] (N-methoxyl group) methyl carbamate (pyraclostrobin, pyraclostrobin)
6, (E)-2-methoxyimino-N-methyl-2-(2-phenoxy phenyl) acetamide (metominostrobin, SSF 126)
7, (E)-2-methoxyimino-[2-(o-methyl-benzene oxygen ylmethyl) phenyl] methyl acetate (SSF-129, SSF-129)
8, (E)-3-methoxyl group-2-[[[2-(1-methyl ethoxy)-6-(trifluoromethyl)-close pyridine of 4-] oxygen] methyl] phenyl] methyl acrylate (NA83, this compound is at WO9935914 and Ag Chem New Compound Review, 2000, on the books among the Vol.18:84)
9, (E)-3-methoxyl group-2-[2-[[[1-methyl-3-(4-chlorphenyl)-2-propylene fork] amino] the oxygen methyl] phenyl] methyl acrylate (enestroburin, this compound be at Ag Chem New Compound Review, and 2000, Vol.18:104 is on the books)
10, Agrevo strobilurin analogue (this compound is at WO97 07099 and Ag Chem New CompoundReview, 2000, Vol.18:29 is on the books)
The amount of application of compound when the amount that contains active component in the product of the present composition depends on independent the use, but also depend on the ratio of a kind of compound and another kind of compound and the degree of synergistic effect, the while is also relevant with the target fungi.Flumorph can with above-mentioned methoxy acrylic bactericide in any one be mixed, relative scale is 1: 100 to 100: 1 based on the umber of active component weight, preferred proportion is 1: 50 to 50: 1, optimal proportion is 1: 20 to 20: 1.
Active component is 0.5% to 95% of a gross weight in the composition of the present invention.
Composition of the present invention can also comprise carrier, and carrier can be solid or liquid, comprises being generally gas but compression back is the material of liquid, and any carrier that is generally used for preparing microbicide compositions all can use.Active component and carrier are mixed with the place that is easy to be applied to processing, can be plant, seed or soil for example, are easy to store transportation or loading and unloading.The present composition can be mixed with liquor, missible oil, suspending agent, aqueous suspension, microemulsion, microcapsule formulations, (water) emulsion, pulvis, paste, wetting powder, soluble powder, (aqueous dispersion) granule, dust agent, fumicants, sustained release agent or aerosol.Also can use the solution and the powder that are included in the polymer capsule, as flood the natural or synthetic material or the carrier of active substance.
These preparations can be prepared by method in common.For example, active substance is mixed with liquid flux and/or solid carrier, add surfactant such as emulsifier, dispersant, stabilizing agent, wetting agent simultaneously, can also add adhesive, defoamer, oxidant, smoke agent, fire retardant, cooling agent, fuel, dyestuff or odorant.Therefore, the present invention also comprises the method for preparing above-mentioned microbicide compositions.
If water is as solvent or thinner, organic solvent also can be used as secondary solvent or antifreeze additive, and appropriate organic solvent comprises aromatic hydrocarbons, for example benzene, dimethylbenzene, toluene, alkylbenzene, Fluhyzon and chlorinated aromatic hydrocarbons; Chloro aliphatic hydrocarbon, for example chlorobenzene, vinyl chloride, trichloroethanes, carrene, chloroform, carbon tetrachloride and many chloroethanes; Aliphatic hydrocarbon, for example petroleum distillate, cyclohexane, light mineral oil, paraffin and coal; Yet, particularly suitable be polar solvent, i.e. alcohols, for example isopropyl alcohol, butanols, ethylene glycol, propane diols, glycerine, sorbierite, phenmethylol, furfuryl alcohol and cyclohexanol, and their ether and ester; Ketone, for example acetone, MEK, methyl iso-butyl ketone (MIBK), cyclohexanone, butyrolactone, and dimethyl formamide, dimethyl sulfoxide (DMSO) and N-methyl-pyrrolidones; Also have vegetable oil and the molten fiber of methyl.Mixtures of different liquids often is suitable for.
Suitable solid carrier comprises natural or synthetic clay and silicate, for example natural silica and diatomite; Magnesium silicate is talcum for example; Magnesiumaluminumsilicate is atlapulgite for example; Alumina silicate is kaolinite, kaolin, imvite and mica for example; White carbon black; Calcium carbonate, precipitated calcium carbonate; Calcium sulphate; Lime stone; Sodium sulphate; Ammonium salt such as ammonium sulfate, hexamethylene diamine; Synthetic hydrated silica and synthetic calcium silicates or alumina silicate; Element is carbon and sulphur for example; Natural and synthetic resin is cumarone resin, polyvinyl chloride and styrene polymer and copolymer for example; Solid polystream phenol; Pitch; Paraffin; And solid fertilizer, for example perphosphate.The solid carrier that is specially adapted to pulvis comprises the rock dust of natural formation, chalk, quartz, clay, imvite, silica, diatomite, float stone, gypsum, talcum, bentonite, kaolin, potter's clay, and synthetic for example microdispersed silicic acid of the mineral matter that grinds or aluminium oxide; Suitable particulate vector comprises broken and natural rock classification for example calcite, marble, float stone, sepiolite and dolomite and the synthetic particle made by organic and inorganic powder.In addition, particle can prepare from organic material, for example wood chip, peanut shell, cocoa husk, corncob, corn starch, soluble starch and dry tobacco rods.
Agriculturally useful compositions is mixed with various preparations usually, is diluted by the user before use.Exist a spot of supporting surfactant to help dilution.Therefore, at least a carrier is a surfactant in the composition of the present invention.For example, composition contains at least two kinds of carriers, and wherein at least a is surfactant.
Surfactant can be emulsifier, dispersant or wetting agent; Can be nonionic or ionic.The example of suitable surfactant comprises the sodium salt or the calcium salt of polyacrylic acid and lignin sulfonic acid; Contain the fatty acid of at least 12 carbon atoms or the polycondensation product of fatty amine or acid amides and oxirane and/or expoxy propane in the molecule; The fatty acid ester of glycerine, dodecanol-1, tetradecanol-1, sorbierite, sucrose or pentaerythrite; And the polycondensation product of they and oxirane and/or expoxy propane; The sulphate of their polycondensation product or sulfonate; In molecule, contain the sulfuric acid of 10 carbon atoms or the alkali metal or the alkali salt of sulfonic acid at least, preferable is sodium salt, for example, and the sodium salt of lauryl sodium sulfate, Teepol, sulfonated castor oil, and alkylaryl sodium sulfonate, for example neopelex; And the copolymer of polymers of ethylene oxide and oxirane and expoxy propane.Particularly following material can be used emulsifier: nonionic emulsifier, for example polyoxyethylene fatty acid fat, polyoxyethylene aliphatic alcohol ether, polyoxyethylene fatty amine, instantiation such as ethoxylated castor oil, polyoxyethylene (n
20) phenethyl phenolic group oleic acid ester, alkylaryl polyoxyethylene poly-oxygen propylene aether, alkylaryl formaldehyde resin APEO, the different thionic acid calcium of oleic acid, triphenyl vinyl phenol polyoxyethylene (n
20) ether phosphoric acid triethanolamine salt, hexichol ethyl phenolic group polyoxyethylene (n
18) ether formaldehyde condensation products, diphenyl phenolic group polyoxyethylene (n
18) polyoxypropylene (n
20) ether etc., and anion emulsifier; Or directly use commercially available emulsifier: agricultural newborn 0201B, agricultural newborn 0203B, farming breast 100
#, farming breast 500
#, farming breast 600
#, agricultural newborn 600-2
#, farming breast 1601, farming breast 2201, agricultural newborn NP-10, agricultural newborn NP-15, farming breast 507
#, agricultural newborn OX-635, agricultural newborn OX-622, agricultural newborn OX-653, agricultural newborn OX-667, agricultural newborn CS-7, peaceful breast 36
#Particularly following material can be used dispersant: sodium lignin sulfonate; draw back powder; calcium lignosulfonate; condensation compound of methyl naphthalene sulfonic acid and formaldehyde; naphthalene sulfonic acid-formaldehyde condensation product; the methanonaphthalene sodium sulfonate; oleic acid methylamino ethylsulfonic acid sodium; epoxidized polyether; to tertbutyl ether; the dibutyl naphthalene sulfonic acid-formaldehyde condensation product; phosphate such as calgon; the alkylphenol-polyethenoxy based phosphates; alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate; N-methyl-fatty acyl group-sodium taurocholate alkylphenol polyoxyethylene formaldehyde condensation products; aralkyl phenol polyethenoxy ether phosphate alkylphenol polyoxyethylene; the castor oil ethylene oxide adduct; ethylene oxide-propylene oxide block copolymer alkylphenol polyoxyethylene formaldehyde condensation products; alkylphenol-polyethenoxy polyethenoxy ether and methylcellulose.Particularly following material can be with wetting agent: sldium lauryl sulfate; alkylol polyoxyethylene groups ether sodium sulfate; octylphenol polyethylene oxyethylene group ether sulfate; alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate; sodium alkyl sulfonate; neopelex; Negel; dialkyl succinylsuccinate sulfonate; lauryl alcohol polyethylene glycol oxide base ether sulfonic acid sodium; the alkyl amide taurate; aliphatic alcohol polyethenoxy base ether; alkylphenol-polyethenoxy base ether; the polyoxyethylene poly-oxygen propylene aether block copolymer; sorbitan fatty acid ester polyoxyethylene groups ether etc.
Adhesive can be that for example xanthans, gelatin, gum Arabic, polyvinylpyrrolidone, aluminium-magnesium silicate, polyvinyl alcohol, polyethylene glycol, phenolic resins, shellac, carboxymethyl cellulose and sodium alginate etc. can powder, particle or latex form add in the preparation for for example carbonyl methylol, polyvinyl alcohol or the polyvinyl acetate that synthesize or natural water-soluble polymer.
Defoamer is: bubble enemy, silicone, C
8～10Fatty alcohol, C
10～20Saturated fat acids (as capric acid, stearic acid etc.) and acid amides etc.
Oxidant is: potassium chlorate, sodium chlorate, potassium perchlorate, sodium nitrate, potassium nitrate, potassium permanganate, potassium bichromate etc.
Smoke agent is: ammonium chloride, carbamate, rosin, cyanamide, ammonium hydrogencarbonate etc.
Fire retardant is: kaolin, potter's clay, talcum powder, lime stone, gypsum etc.
Cooling agent is: ammonium chloride, magnesia, bentonite, white carbon black, diatomite, zinc oxide etc.
Fuel is: wood powder, charcoal, white sugar, sucrose, thiocarbamide, ammonium thiocyanate, cellulose, urea, Wu Luotuoping, sulphur, coal dust, nitrocellulose, genseng residue etc.
Can contain toner in the preparation, for example inorganic pigment iron oxide, titanium oxide or Prussia orchid; Organic dyestuff is alizarin, azo dyes, metal phthalocyanine or kiton colors for example; Can also contain odorant, for example natural aromatic oil.
According to preparation type, in solid pharmaceutical preparation, contain 5% to 85% active substance by weight, preferably be 10-80%; In pharmaceutical solutions, contain 1-70% active substance by weight; Contain the active substance of 10-60% by weight at suspension preparation.
Wetting powder contains the active component of 10-85% usually, except solid inert carrier, contains the dispersant of 3-10% usually, if desired, contains stabilizing agent and/or other additive of 0-10%, for example bleeding agent or sticker.Pulvis is mixed with the powder concentrate usually, and it and wetting powder have similar composition, but does not contain dispersant, and this pulvis is contained the composition of 0.5-10%W active substance usually down on the farm with other solid carrier dilution.Granule is made 10-100 international standard sieve mesh (1.676-0.152mm) particle usually, can be by reuniting or soaking into the method preparation, usually granule contains the active component of 0.5-75% and the additive of 0-10%W, for example stabilizing agent, surfactant, slow release regulator and adhesive.So-called dry flowable pulvis is made up of smaller containing than the particle of higher concentration active component.Missible oil except containing solvent, containing the cosolvent when needed, contains the 10-50%W/V active component usually, other additive of 2-20%W/V emulsifier and 0-20W%/V, for example stabilizing agent, bleeding agent and corrosion inhibitor.Suspending concentrate need stir usually, to obtain stable non-deposition flowable product, it contains the active component of 10-75%W usually, the dispersant of 0.5-15%W, the suspending agent of 0.1-10%W for example protects other additive of colloid and thixotropic agent, 0-10%W, for example defoamer, corrosion inhibitor, stabilizing agent, bleeding agent and sticker, with water or organic liquid, wherein active component is undissolved basically; Some organic solid or mineral salt can be dissolved in the preparation, to help to prevent deposition or as the antifreezing agent of water.
Moisture dispersion liquid and emulsion, for example the composition that obtains of dilute with water wetting powder of the present invention or concentrate also within the scope of the invention.Above-mentioned emulsion can be water-in-oil type or oil-in-water type, can have dense thick pulpous state denseness.
The product that the present invention describes can be the finished product preparation form, and promptly each material mixes in the composition.Yet, the composition of composition also separately preparation directly mixing in bucket (jar) before using is provided.Concentrate of the present invention mixes the concentration that obtains required active substance usually with water.
Composition of the present invention also can contain other component, for example other compound with weeding, desinsection or bactericidal property protective fungicide particularly.Also can mix with nematocide, protective agent, growth regulator, nutrient for plants or soil conditioner.
The present invention is interested especially to be the duration of improving the protection activity of The compounds of this invention.Use a kind of carrier that can shift to the also slow release Fungicidal compounds of being protected of plant, the preparation of this slow release can be put near the soil the trailing plant root; Or comprise a kind of adhesion component, so that can be applied directly on the stem of trailing plant.
Composition of the present invention can be used by common method, as cast, injection, spraying, dusting, scatter or be fuming.Amount of application of the present invention is with weather condition or crop state variation.Time of application can be before or after infecting.This point is very important, because in fact the infection of Fa Shenging can not be realized immediately.The duration of protection is relevant with selected individualized compound, also relevant with many extraneous factors usually, and for example weather can slow down climatic influences usually by using suitable formulation.
The invention allows for the application of microbicide compositions of above-mentioned meaning and the method for catching and killing fungi at the scene, comprise with said composition and handle this place that it can be the plant that for example is subjected to fungal attack, the seed of this plant or the medium of this plant growing.
Composition of the present invention has three advantages: the one, have synergistic effect; use with and not only improved bactericidal effect; enlarged fungicidal spectrum: the flumorph list is used has excellent protection and therapeutic action to the disease that is caused by Oomycete; methoxy acrylic bactericide has the broad-spectrum sterilization activity to Ascomycetes; Basidiomycetes; most of diseases that pathomycete such as Fungi Imperfecti and Oomycete causes have protection; treatment; eradicant action; the two is used with; both improved flumorph to control efficiency, enlarged its fungicidal spectrum again by the fungus-caused most of diseases of Oomycete.The 2nd, being mixed between the different medicament of the mechanism of action reduced pesticide resistance and produced probability.The 3rd, improved safety, because the two has reduced consumption after using with, though these medicaments itself belong to the low toxicity product, being mixed will be lower to the influence of environment, safer.The beneficial effect the most intuitively of bringing for dish (really) farming is to have reduced the mu use cost therefrom.
For composition of the present invention, when being used for for example grape of many kinds of crops, tobacco, lupulus, millet, paddy rice, the wheat class, peanut, potato, tomato, cucumber, Chinese cabbage, pumpkin, wild cabbage, capsicum, onion, shallot, lettuce, garlic, beet and other vegetables and isatis root, rubber, apple, pears, citrus, avocado, pineapple, lichee, cocoa, rose, control is by microbial disease of Oomycete cause of disease such as downy mildew on carnation and other ornamental plants, late blight, the frost eqpidemic disease, rotten mildew, damping off, black stem, canker, white blister, (millet) poliosis; And control is during by the microbial early blight of other cause of disease, powdery mildew, scab, rust, glume blight, net blotch, leaf spot, damping off, rice blast, gray mold etc.; Flumorph and above-mentioned methoxy acrylic bactericide are used with all has synergistic effect.
The present invention is elaborated with following instantiation, but the present invention only limits to these examples absolutely not.Percentage all is weight percentage in all proportionings.1, the preparation of missible oil
By the prescription requirement, add solvent, former medicine, emulsifier respectively, mix, use the hot bath heating for dissolving in case of necessity, promptly obtain transparence missible oil.As example 1～15 prescription.Example 1 (10%% missible oil)
Flumorph 5%
Kresoxim-methyl 5%
Farming breast 500
#7.5%
The newborn 600-2 of farming
#4.5%
Methyl alcohol 8%
Dimethylbenzene complements to 100% example 2 (10% missible oil)
Flumorph 1%
Kresoxim-methyl 9%
Farming breast 2,201 8%
The newborn OX-622 3% of farming
Methyl alcohol 8%
Toluene complements to 100% example 3 (20% missible oil)
Flumorph 2%
Kresoxim-methyl 18%
Farming breast 2,201 7%
The newborn CS-7 5% of farming
Ethylene glycol 3%
Dimethyl formamide 8%
Dimethylbenzene complements to 100% example 4 (30% missible oil)
Flumorph 3%
Kresoxim-methyl 27%
Farming breast 500
#10%
The newborn OX-635 5% of farming
Methyl alcohol 10%
Dimethylbenzene complements to 100% example 5 (10% missible oil)
Flumorph 3%
Kresoxim-methyl 7%
Farming breast 500
#5%
Farming breast 600
#3%
Nongru-700
#3%
Methyl alcohol 10%
Dimethylbenzene complements to 100% example 6 (20% missible oil)
Flumorph 4%
Kresoxim-methyl 16%
Farming breast 34
#5%
The newborn OX-635 3% of farming
Methyl alcohol 5%
Dimethylbenzene complements to 100% example 7 (30% missible oil)
Flumorph 5%
Kresoxim-methyl 25%
The newborn MOA-3 5% of farming
The newborn OP-15 3% of farming
Ethyl acetate 6%
Methyl alcohol 5%
Dimethylbenzene complements to 100% example 8 (25% missible oil)
Flumorph 5%
Kresoxim-methyl 20%
Farming breast 507
#10%
The newborn OX-653 3% of farming
Methyl alcohol 10%
Dimethylbenzene complements to 100% example 9 (25% missible oil)
Flumorph 20%
Kresoxim-methyl 5%
Farming breast 2201
#8%
The newborn OX-667 4.5% of farming
Dimethyl formamide 8%
Methyl alcohol 5%
Dimethylbenzene complements to 100% example 10 (1% missible oil)
Flumorph 0.5%
Fluoxastrobin 0.5%
Farming breast 500
#5%
Farming breast 600
#2%
Methyl alcohol 5%
Dimethylbenzene complements to 100% example 11 (10% missible oil)
Flumorph 1%
Fluoxastrobin 9%
Farming breast 2,201 9%
Farming breast 1,601 3.5%
Methyl alcohol 8%
Dimethylbenzene complements to 100% example 12 (10% missible oil)
Flumorph 8%
Oxime bacterium ester 2%
Farming breast 2,201 8%
Farming breast 600 2.5%
The newborn NP-10 1.5% of farming
Methyl alcohol 5%
Dimethyl formamide 6%
Toluene complements to 100% example 13 (20% missible oil)
Flumorph 2%
Oxime bacterium ester 18%
The newborn 0201B 5% of farming
The newborn 0203B 5% of farming
Methyl alcohol 5%
Dimethyl formamide 6%
Dimethylbenzene complements to 100% example 14 (20% missible oil)
Flumorph 2%
Pyraclostrobin 18%
Farming breast 507
#12%
The newborn OX-635 3% of farming
Methyl alcohol 10%
Dimethylbenzene complements to 100% example 15 (20% missible oil)
Flumorph 4%
ZEN 90160 16%
Farming breast 500
#12%
Farming breast 600
#3%
The newborn OP-10 3% of farming
Methyl alcohol 10%
Dimethylbenzene complements to 100%2, the preparation of wetting powder
By the prescription requirement, former medicine, various auxiliary agent and filler etc. are fully mixed, after ultrafine crusher is pulverized, promptly obtain converted products.Fill a prescription as example 16～37: example 16 (10% wetting powder)
Flumorph 5%
Oxime bacterium ester 5%
Lauryl sodium sulfate 1.5%
To tertbutyl ether 2%
Sodium lignin sulfonate 8%
Precipitated calcium carbonate complements to 100% example 17 (10% wetting powder)
Flumorph 1%
Kresoxim-methyl 9%
Lauryl sodium sulfate 1.5%
Cresol sulfonic acid formaldehyde condensation products sodium salt 8%
Precipitated calcium carbonate complements to 100% example 18 (20% wetting powder)
Flumorph 2%
Kresoxim-methyl 18%
Lauryl sodium sulfate 1.5%
Carboxymethyl cellulose 1%
Sodium lignin sulfonate 10%
Precipitated calcium carbonate complements to 100% example 19 (30% wetting powder)
Flumorph 3%
Kresoxim-methyl 27%
Neopelex 1%
White carbon black 10%
Sodium lignin sulfonate 10%
Precipitated calcium carbonate complements to 100% example 20 (40% wetting powder)
Flumorph 4%
Kresoxim-methyl 36%
Neopelex 1%
White carbon black 10%
Sodium lignin sulfonate 10%
Precipitated calcium carbonate complements to 100% example 21 (50% wetting powder)
Flumorph 5%
Kresoxim-methyl 45%
Neopelex 1%
White carbon black 10%
Naphtholsulfonic acid formaldehyde condensation products sodium salt 10%
Precipitated calcium carbonate complements to 100% example 22 (50% wetting powder)
Flumorph 5%
Kresoxim-methyl 45%
Lauryl alcohol polyethylene glycol oxide base ether sodium sulfate 1%
Cocinic acid potassium 3%
Petroleum sodium sulfonate 10%
Precipitated calcium carbonate complements to 100% example 23 (60% wetting powder)
Flumorph 6%
Kresoxim-methyl 54%
Draw back powder 1%
Alkylphenol-polyethenoxy base phosphate 3%
Calgon 10%
Precipitated calcium carbonate complements to 100% example 24 (70% wetting powder)
Flumorph 7%
Kresoxim-methyl 63%
Sldium lauryl sulfate 1%
Fatty alcohol ethylene oxide adduct phosphate 3%
Alkylphenol-polyethenoxy base phosphate 7%
Precipitated calcium carbonate complements to 100% example 25 (10% wetting powder)
Flumorph 3%
Kresoxim-methyl 7%
Negel 2%
Enuatrol 1%
Calcium lignosulfonate 5%
Polyoxyethylene polyoxypropylene base ether block copolymers 5%
Precipitated calcium carbonate complements to 100% example 26 (20% wetting powder)
Flumorph 4%
Kresoxim-methyl 16%
Pine tar soap 2%
Enuatrol 1%
Sodium lignin sulfonate 5%
Fatty alcohol ethylene oxide adduct sulfonate 5%
Precipitated calcium carbonate complements to 100% example 27 (30% wetting powder)
Flumorph 6%
Oxime bacterium ester 24%
Dialkyl succinylsuccinate sulfonate 2%
Calcium lignosulfonate 5%
Alkylphenol-polyethenoxy base ether formaldehyde condensation products sulfonate 5%
Precipitated calcium carbonate complements to 100% example 28 (45% wetting powder)
Flumorph 40%
Fluoxastrobin 5%
Alkyl amide taurate 2%
Fluhyzon formaldehyde condensation products 5%
Alkylphenol-polyethenoxy phosphate 5%
Precipitated calcium carbonate complements to 100% example 29 (70% wetting powder)
Flumorph 14%
SSF 126 56%
Octylphenol polyethylene oxyethylene group ether sulfate 2%
Sodium phosphate trimer 5%
Aryl phenol polyoxyethylene groups ether succinate sulfonate 5%
Precipitated calcium carbonate complements to 100% example 30 (60% wetting powder)
Flumorph 12%
ZEN 90160 48%
Lauryl sodium sulfate 2%
White carbon black 8%
Sodium lignin sulfonate 5%
Methyl naphthalene sulfonate formaldehyde condensate 5%
Precipitated calcium carbonate complements to 100% example 31 (40% wetting powder)
Flumorph 32%
Fluoxastrobin 8%
Lauryl sodium sulfate 1.5%
White carbon black 6%
Calcium lignosulfonate 2%
Methyl naphthalene sulfonate formaldehyde condensate 8%
Precipitated calcium carbonate complements to 100% example 32 (50% wetting powder)
Flumorph 40%
Azoles oxygen bacterium ester 10%
Lauryl sodium sulfate 1.5%
Carboxymethyl cellulose 1%
Sodium lignin sulfonate 2%
Naphthalenesulfonic acid-formaldehyde condensate 8%
Precipitated calcium carbonate complements to 100% example 33 (40% wetting powder)
Flumorph 20%
SSF-129 20%
Lauryl sodium sulfate 2%
White carbon black 5%
Sodium lignin sulfonate 5%
Naphthalenesulfonic acid-formaldehyde condensate 5%
Precipitated calcium carbonate complements to 100% example 34 (45% wetting powder)
Flumorph 9%
Fluoxastrobin 36%
Lauryl sodium sulfate 1.5%
To tertbutyl ether 2%
Methyl naphthalene sulfonate formaldehyde condensate 8%
Precipitated calcium carbonate complements to 100% example 35 (60% wetting powder)
Flumorph 12%
Fluoxastrobin 48%
Lauryl sodium sulfate 1.5%
Sodium lignin sulfonate 2.6%
Methyl naphthalene sulfonate formaldehyde condensate 10%
Precipitated calcium carbonate complements to 100% example 36 (50% wetting powder)
Flumorph 45%
Fluoxastrobin 5%
Lauryl sodium sulfate 2%
White carbon black 5%
Sodium lignin sulfonate 8%
Methyl naphthalene sulfonate formaldehyde condensate 5%
Precipitated calcium carbonate complements to 100% example 37 (50% wetting powder)
Flumorph 45%
Fluoxastrobin 5%
Lauryl sodium sulfate 1.5%
White carbon black 6.5%
Carboxymethyl cellulose 1.5%
Methyl naphthalene sulfonate formaldehyde condensate 8%
Precipitated calcium carbonate complements to 100%3, the preparation of aqueous emulsion
Former medicine, solvent, emulsifier added with co-emulsifier be in the same place, make and be dissolved into even oil phase.Water, antifreeze etc. is mixed, becomes the homogeneous water.Under high-speed stirred, water is joined oil phase or oil phase is joined water, form the aqueous emulsion of favorable dispersibility.As example 38～43 prescriptions.Example 38 (10% aqueous emulsion)
Flumorph 9%
Fluoxastrobin 1%
Polyvinyl alcohol 0.8%
Triphenylethylene phenol+oxirane,
In phosphorylation, the triethanolamine and 8.5%
Alkyl-diethylene glycol ether-sodium sulfonate 2.5%
Farming breast 2,201 13%
Dimethyl formamide 8%
Ethylene glycol 5%
Water complements to 100% example 39 (10% aqueous emulsion)
Flumorph 1%
Kresoxim-methyl 9%
Polyoxyethylene (n
20) phenethyl
Phenolic group oleic acid ester 8%
Calcium dodecyl benzene sulfonate 16%
Piperonyl butoxide 15%
Cyclohexanone 10%
Sorbierite 5%
Water complements to 100% example 40 (15% aqueous emulsion)
Flumorph 7.5%
Kresoxim-methyl 7.5%
Polyvinyl alcohol 0.9%
Alkylaryl polyoxyethylene poly-oxygen propylene aether 8.5%
Farming breast 2,201 15%
Dimethyl formamide 12%
Ethylene glycol 5%
Water complements to 100% example 41 (10% aqueous emulsion)
Flumorph 9%
Fluoxastrobin 1%
Alkylaryl formaldehyde resin APEO 10.5%
Farming breast 507
#8.5%
Tetradecanol 0.6%
Dimethyl formamide 15%
Propane diols 5%
Water complements to 100% example 42 (10% aqueous emulsion)
Flumorph 1%
Oxime bacterium ester 9%
Polyoxyethylene (n
20) phenethyl
Phenolic group oleic acid ester 8%
Calcium dodecyl benzene sulfonate 16%
Dodecanol-1 3%
Cyclohexanone 15%
Sorbierite 5%
Water complements to 100% example 43 (15% aqueous emulsion)
Flumorph 7.5%
Kresoxim-methyl 7.5%
Polyvinyl alcohol 0.9%
Alkylaryl formaldehyde resin APEO 12.5%
Farming breast 507
#10%
Dimethyl formamide 13%
Ethylene glycol 5%
Water complements to 100%4, the preparation of water-dispersible granules
Method 1: former medicine and powder carrier, wetting spreader-sticker and binding agent etc. are mixed pulverizing, after adding water again and mediating, add in the comminutor that the certain specification screen cloth is housed and carry out granulation.And then drying, screening (pressing the screen cloth scope) promptly get granular product.As example 44～50 prescriptions.Example 44 (60% water-dispersible granules)
Flumorph 48%
Fluoxastrobin 12%
Methanonaphthalene sodium sulfonate 5%
Epoxidized polyether 5%
Sodium sulphate 15%
Gypsum complements to 100% example 45 (50% water-dispersible granules)
Flumorph 45%
Fluoxastrobin 5%
Methyl naphthalene sulfonate formaldehyde condensate 12%
Epoxidized polyether 5%
Soluble starch 15%
Gypsum complements to 100% example 46 (50% water-dispersible granules)
Flumorph 5%
Kresoxim-methyl 45%
Sodium lignin sulfonate 16%
Naphthalenesulfonic acid-formaldehyde condensate 2%
Bentonite 15%
Gypsum complements to 100% example 47 (60% water-dispersible granules)
Flumorph 30%
Oxime bacterium ester 30%
Sodium lignin sulfonate 8.5%
Methyl naphthalene sulfonate formaldehyde condensate 4.6%
Soluble starch 15%
Gypsum complements to 100% example 48 (50% water-dispersible granules)
Flumorph 10%
Kresoxim-methyl 40%
Methyl naphthalene sulfonate formaldehyde condensate 12%
N-methyl-oleoyl-sodium taurocholate 8%
Polyvinylpyrrolidone 2%
Corn starch 2%
Kaolin complements to 100% example 49 (50% water-dispersible granules)
Flumorph 5%
Pyraclostrobin 45%
Neopelex 1%
Naphtholsulfonic acid formaldehyde condensation products 16%
Calcium dodecyl benzene sulfonate 5%
Bentonite 15%
Kaolin complements to 100% example 50 (60% water-dispersible granules)
Flumorph 30%
SSF 126 30%
Naphtholsulfonic acid formaldehyde condensation products 9.4%
Neopelex 5.6%
Soluble starch 15%
Kaolin complements to 100%
Method 2: with former medicine, dispersant, disintegrant and wetting agent etc., be medium with water, porphyrize in sand mill is made suspending agent, carries out spray drying granulation then.As example 51～54 prescriptions.Example 51 (50% water-dispersible granules)
Flumorph 45%
Fluoxastrobin 5%
Methyl naphthalene sulfonate formaldehyde condensate 15%
Sodium alginate 5%
Polyethylene glycol 8,000 5%
Sodium sulphate 15%
Bentonite complements to 100% example 52 (50% water-dispersible granules)
Flumorph 5%
Kresoxim-methyl 45%
Sodium lignin sulfonate 2%
Condensation compound of methyl naphthalene sulfonic acid and formaldehyde 25%
Hexamethylene diamine 4.5%
Bentonite complements to 100% example 53 (50% water-dispersible granules)
Flumorph 20%
Oxime bacterium ester 30%
Methyl naphthalene sulfonate formaldehyde condensate 16%
White carbon black 0.2%
Polyethylene glycol 8,000 5%
Sodium sulphate 15%
Bentonite complements to 100% example 54 (50% water-dispersible granules)
Flumorph 5%
Pyraclostrobin 45%
Calcium lignosulfonate 8%
Methyl naphthalene sulfonate formaldehyde condensate 15%
Hexamethylene diamine 5%
Bentonite complements to 100%5, the preparation of suspending agent
By the prescription requirement, be medium with water, former medicine, dispersant, suspending agent and antifreezing agent etc. are added in the sand milling still, carry out porphyrize, make suspending agent.As example 55～69 prescriptions.Example 55 (25% suspending agent)
Flumorph 2.5%
Oxime bacterium ester 22.5%
Calcium lignosulfonate 5%
White carbon black 0.3%
Ethylene glycol 4%
Defoamer a little
Water complements to 100% example 56 (25% suspending agent)
Flumorph 22.5%
Fluoxastrobin 2.5%
Sodium lignin sulfonate 6%
White carbon black 0.3%
Xanthans 0.1%
Ethylene glycol 4%
Defoamer a little
Water complements to 100% example 57 (35% suspending agent)
Flumorph 5%
Kresoxim-methyl 30%
Methyl naphthalene sulfonate formaldehyde condensate 2.5%
Bentonite 1.0%
Farming breast 1,601 3%
Glycerine 4%
Defoamer a little
Water complements to 100% example 58 (35% suspending agent)
Flumorph 28%
Fluoxastrobin 7%
Naphthalenesulfonic acid-formaldehyde condensate 5%
White carbon black 0.3%
Xanthans 0.1%
Ethylene glycol 4%
Defoamer a little
Water complements to 100% example 59 (20% suspending agent)
Flumorph 10%
ZEN 90160 10%
Methyl naphthalene sulfonate formaldehyde condensate 2.5%
Sodium lignin sulfonate 3.5%
White carbon black 0.2%
Ethylene glycol 4%
Defoamer a little
Water complements to 100% example 60 (25% suspending agent)
Flumorph 2.5%
Kresoxim-methyl 22.5%
Naphthalenesulfonic acid-formaldehyde condensate 5%
White carbon black 0.1%
Aluminium-magnesium silicate 0.1%
Ethylene glycol 4%
Defoamer a little
Water complements to 100% example 61 (20% suspending agent)
Flumorph 16%
Kresoxim-methyl 4%
Nekal formaldehyde condensation products 4.5%
White carbon black 0.1%
Xanthans 0.1%
Ethylene glycol 4%
Defoamer a little
Water complements to 100% example 62 (35% suspending agent)
Flumorph 5%
Kresoxim-methyl 30%
Methyl naphthalene sulfonate formaldehyde condensate 5%
Bentonite 0.8%
The newborn 203B 1.5% of farming
Glycerine 4%
Defoamer a little
Water complements to 100% example 63 (35% suspending agent)
Flumorph 28%
Fluoxastrobin 7%
Sodium lignin sulfonate 4.5%
White carbon black 0.25%
Aluminium-magnesium silicate 0.15%
Ethylene glycol 4%
Defoamer a little
Water complements to 100% example 64 (10% suspending agent)
Flumorph 5%
Azoles oxygen amine ester 5%
Methyl naphthalene sulfonate formaldehyde condensate 5.5%
White carbon black 0.2%
Aluminium-magnesium silicate 0.18%
Ethylene glycol 4%
Defoamer a little
Water complements to 100%6, the preparation of liquor
By the prescription requirement, add solvent, former medicine, emulsifier respectively, mix, use the hot bath heating for dissolving in case of necessity, can make liquor.As example 65～70 prescriptions.Example 65 (10% soluble liquid)
Flumorph 1%
Kresoxim-methyl 9%
Farming breast 2,201 10%
The newborn NP-15 12.5% of farming
Methyl alcohol 10%
Dimethyl formamide 12%
The molten fiber 30% of methyl
Water complements to 100% example 66 (20% soluble liquid)
Flumorph 18%
Kresoxim-methyl 2%
Nanjing 507
#15%
Farming breast 1,601 3%
Farming breast 100
#3%
Dimethyl formamide 10%
Methyl alcohol 5%
The molten fiber 30% of methyl
Water complements to 100% example 67 (18% soluble liquid)
Flumorph 9%
ZEN 90160 9%
Farming breast 2,201 8.6%
The newborn NP-15 13.4% of farming
Methyl alcohol 5%
Dimethyl formamide 12%
The molten fiber 30% of methyl
Water complements to 100% example 68 (10% soluble liquid)
Flumorph 1%
Oxime bacterium ester 9%
Farming breast 2,201 12.5%
The newborn NP-10 2.5% of farming
Methyl alcohol 8%
Dimethyl formamide 16%
The molten fiber 35% of methyl
Water complements to 100% example 69 (20% soluble liquid)
Flumorph 2%
SSF 126 18%
Nanjing 507
#15%
The newborn CS-7 5% of farming
Farming breast 100
#2.5%
Dimethyl formamide 10%
Methyl alcohol 5%
The molten fiber 30% of methyl
Water complements to 100% example 70 (18% soluble liquid)
Flumorph 9%
Pyraclostrobin 9%
The different thionic acid calcium 7.5% of oleic acid
The newborn NP-15 14.5% of farming
Methyl alcohol 5%
Dimethyl formamide 15%
The molten fiber 30% of methyl
Water complements to 100%7, the preparation example 71 (40% microcapsule formulations) of microcapsule formulations
In 1000 milliliters of plastics (band baffle plate) bottle, 0.5% polyvinyl alcohol water solution that adds 600 milliliters, use the tetrafluoroethene agitator, under high-speed stirred, add 2 gram flumorphs and 18 gram kresoxim-methyls, 9 gram oxirane propylene oxide block copolymers, 6 gram epoxidised soybean oil, 3 gram diphenyl methane-4 ｀ 4-vulcabond, 1.5 gram ethylene diamin(e)s, 5 gram sodium carbonate and 150 ml waters, behind reinforced the finishing, slow-down continues to stir 1 hour, left standstill 1 hour, filter, vacuum drying promptly gets 40% microcapsule formulations.Example 72 (30% microcapsule formulations)
To be dissolved in the solution of gram flumorph of 2.7 in 20 milliliters of ethyl acetate and 0.3 gram Fluoxastrobin, and join in 500 milliliter of 1% aqueous gelatin solution, and in 45 ℃ of stirrings 2 hours, steam clean ethyl acetate afterwards, and leach microcapsules, drying at room temperature promptly gets 30% microcapsule formulations product.8, the preparation of microemulsion
Former medicine, solvent, emulsifier added with co-emulsifier be in the same place, make and be dissolved into even oil phase.Water, antifreeze etc. is mixed, becomes the homogeneous water.Under high-speed stirred, water is joined oil phase or oil phase is joined water, form the aqueous emulsion of favorable dispersibility.As example 73～80 prescriptions.Example 73 (10% microemulsion)
Flumorph 1%
Kresoxim-methyl 9%
Cyclohexanone 25%
Cyclohexanol 8%
Triphenyl vinyl phenol polyoxyethylene (n
20) ether
Phosphorylation triethanolamine salt 2.6%
Dodecyl sodium sulfonate magnesium 17.4%
Dimethyl formamide 5%
Peaceful breast 36
#5%
Ethylene glycol 5%
Water complements to 100% example 74 (15% microemulsion)
Flumorph 1.5%
Kresoxim-methyl 13.5%
Diphenyl phenolic group polyoxyethylene (n
18) ether
Formaldehyde condensation products 6%
Acetonitrile 10%
Ethyl acetate 8%
Farming breast 2,201 15%
The newborn OP-10 3% of farming
Glycerine 5%
Water complements to 100% example 75 (10% microemulsion)
Flumorph 5%
Oxime bacterium ester 5%
Cyclohexanone 15%
Cyclohexanol 10%
Diphenyl phenolic group polyoxyethylene (n
18)
Polyoxypropylene (n
20) ether 2.6%
Neopelex 17.4%
Dimethyl formamide 5%
Ethylene glycol 5%
Water complements to 100% example 76 (20% microemulsion)
Flumorph 18%
Fluoxastrobin 2%
Cyclohexanone 25%
Cyclohexanol 8%
Polyoxyethylene (n
20) phenethyl
Phenolic group oleic acid ester 2.6%
Calcium dodecyl benzene sulfonate 17.4%
Dimethyl formamide 10%
Ethylene glycol 5%
Water complements to 100% example 77 (15% microemulsion)
Flumorph 1.5%
SSF 126 13.5%
Diphenyl phenolic group polyoxyethylene (n
18) ether
Formaldehyde condensation products 8%
Dimethyl formamide 10%
Ethyl acetate 5%
Farming breast 2,201 12%
Propane diols 5%
Water complements to 100% example 78 (10% microemulsion)
Flumorph 5%
Pyraclostrobin 5%
Cyclohexanone 15%
Dimethyl formamide 10%
Phenethyl phenolic group polyoxyethylene (n
18)
Polyoxypropylene (n
20) ether 3.8%
Dodecyl sodium sulfonate calcium 16.8%
Ethylene glycol 5%
Water complements to 100% example 79 (20% microemulsion)
Flumorph 2%
Two SSF 126 18%
Diphenyl phenolic group polyoxyethylene (n
18) ether
Formaldehyde condensation products 6%
Acetonitrile 10%
Ethyl acetate 8%
Farming breast 2,201 16.8%
Nongru-700
#5.2%
Ethylene glycol 5%
Water complements to 100% example 80 (16% microemulsion)
Flumorph 14.8%
Fluoxastrobin 1.2%
Diphenyl phenolic group polyoxyethylene (n
18) ether
Formaldehyde condensation products 10%
Acetonitrile 6%
Ethyl acetate 8%
Farming breast 2,201 8.5%
Nongru-700
#3.5%
Ethylene glycol 5%
Water complements to the preparation of 100%9 fumicants
Former medicine and various auxiliary agent are crushed to 80～100 orders respectively, mix in proportion, put into plastic sack, again with hot non-conductor external packings such as cardboard cylinder or thick bamboo tube, plain soil jar, crocks, lead-in wire is imbedded in the fumicants, spout is put portion or sidepiece, and seam crossing and venthole secure with paraffin paper, and the venthole paper slip of tearing during use gets final product.As example 81～85 prescriptions.Example 81 (10% fumicants)
Flumorph 1%
Kresoxim-methyl 9%
Ammonium chloride 18%
Potassium chlorate 16%
Carboxymethyl cellulose 3%
Potter's clay 8%
Talcum powder 29%
Wood powder complements to 100% example 82 (20% fumicants)
Flumorph 2%
Kresoxim-methyl 18%
Ammonium chloride 15%
Potassium nitrate 20%
Thiocarbamide 5%
Gypsum 6%
Kaolin 26%
Wood powder complements to 100% example 81 (10% fumicants)
Flumorph 2%
Oxime bacterium ester 8%
Ammonium bicarbonate food grade 18%
Potassium perchlorate 18%
Sucrose 3%
Diatomite 8%
Sodium carbonate 29%
Wood powder complements to 100% example 82 (15% fumicants)
Flumorph 3%
Kresoxim-methyl 12%
Carbamate 10%
Potassium nitrate 10%
Nitrocellulose 10%
Carboxymethyl cellulose 5%
Kaolin 5%
Talcum powder 20%
Wood powder complements to 100% example 83 (10% fumicants)
Flumorph 9%
Fluoxastrobin 1%
Rosin 8%
Potassium bichromate 12%
Starch 10%
Calcium carbonate 6%
Kaolin 5%
Lime stone 20%
Wood powder complements to 100% example 84 (20% fumicants)
Flumorph 2%
SSF-129 18%
Cyanogen ammonia 8%
Potassium permanganate 15%
Thiocyanic acid amine 18%
Gypsum 6%
Talcum powder 15%
Bentonite 5%
Wood powder complements to 100% example 85 (15% fumicants)
Flumorph 3%
Pyraclostrobin 15%
Ammonium chloride 11%
Sodium chlorate 15%
Cellulose 10%
Thiocyanic acid amine 6%
Magnesia 5%
Phenolic resins 1%
Wood powder complements to 100% protection activity test
Example 86: the preparation of flumorph, kresoxim-methyl and example 3 is to the control efficiency of cucumber downy mildew (metalaxyl resistant strain) in the greenhouse.
Cucumber variety: Chang Chun Mi Ci, the close thorn in Shandong infect: cucumber downy mildew
Test method: the cucumber seedling pot-culture method is adopted in test, when cucumber grows to two leaves during one heart stage, handles with crop sprayer foliar spray, and the protectiveness test is to handle back 24 hours inoculation germs.The inoculation back was carried out result's investigation in 7-8 days.
Mixture (flumorph 5ppm adds kresoxim-methyl 45ppm) control efficiency is 100%.Mixture (flumorph 2.5ppm adds kresoxim-methyl 22.5ppm) control efficiency is 85.3%.Mixture (flumorph 1.25ppm adds kresoxim-methyl 11.25ppm) control efficiency is 70.5%.Example 87: the preparation of flumorph, kresoxim-methyl and example 3 is to the control efficiency of capsicum epidemic disease in the greenhouse.
| Active substance | ????50ppm | ????25ppm | ????12.5ppm |
| Flumorph | ????61.1％ | ????42.0％ | ????25.4％ |
| Kresoxim-methyl | ????90.2％ | ????75.3％ | ????61.2％ |
| Mixture (20% missible oil) | ????100％ | ????85.3％ | ????70.5％ |
Capsicum variety: the ears of an ox or cow king infects: capsicum epidemic disease
Method: capsicum seedling pot-culture method is adopted in test, and capsicum grows to tri-leaf period, carries out foliar spray with the crop sprayer and handles, and the protectiveness test is to handle back 24 hours inoculation germs.The inoculation back was carried out result's investigation in 10～12 days.
| Active substance | ????100ppm | ????50ppm | ????25ppm | ????12.5ppm |
| Flumorph | ????89.8％ | ????62.3％ | ????45.0％ | ????26.5％ |
| Kresoxim-methyl | ????96.4 | ????92.1％ | ????76.3％ | ????62.1％ |
| Mixture (20% missible oil) | ????100％ | ????99.8％ | ????87.2％ | ????73.1％ |
Mixture (flumorph 10ppm adds kresoxim-methyl 90ppm) control efficiency is 100%;
Mixture (flumorph 5ppm adds kresoxim-methyl 45ppm) control efficiency is 99.8%;
Mixture (flumorph 2.5ppm adds kresoxim-methyl 22.5ppm) control efficiency is 87.2%;
Mixture (flumorph 1.25ppm adds kresoxim-methyl 11.25ppm) control efficiency is 73.1%.Example 88: the preparation of flumorph, kresoxim-methyl and example 26 is to the control efficiency of cucumber downy mildew (metalaxyl resistant strain) in the greenhouse.
Cucumber variety: Chang Chun Mi Ci, the close thorn in Shandong infect: cucumber downy mildew
Test method is with example 86.
| Active substance | ????50ppm | ????25ppm | ????12.5ppm |
| Flumorph | ????61.1％ | ????42.0％ | ????25.4％ |
| Kresoxim-methyl | ????90.2％ | ????75.3％ | ????61.2％ |
| Mixture (20% wetting powder) | ????90.1％ | ????81.0％ | ????61.3％ |
Mixture (flumorph 10ppm adds kresoxim-methyl 40ppm) control efficiency is 90.1%;
Mixture (flumorph 5ppm adds kresoxim-methyl 20ppm) control efficiency is 81.0%;
Mixture (flumorph 2.5ppm adds kresoxim-methyl 10ppm) control efficiency is 61.3%.Example 89: in the greenhouse, test the control efficiency of the preparation of flumorph, kresoxim-methyl and example 26 to capsicum epidemic disease.
Capsicum variety: the ears of an ox or cow king infects: capsicum epidemic disease
Test method is with example 87.
Mixture (flumorph 20ppm adds kresoxim-methyl 80ppm) control efficiency is 100%; Mixture (flumorph 10ppm adds kresoxim-methyl 40ppm) control efficiency is 91.2%; Mixture (flumorph 5ppm adds kresoxim-methyl 20ppm) control efficiency is 80.5%; Mixture (flumorph 2.5ppm adds kresoxim-methyl 10ppm) control efficiency is 60.2%.Example 90: the preparation of flumorph, kresoxim-methyl and example 40 is to the control efficiency of capsicum epidemic disease in the greenhouse.
| Active substance | 100ppm | ????50ppm | ????25ppm | ????12.5ppm |
| Flumorph | 89.8％ | ????62.3％ | ????45.0％ | ????26.5％ |
| Kresoxim-methyl | 96.4 | ????92.1％ | ????76.3％ | ????62.1％ |
| Mixture (20% wetting powder) | 100％ | ????91.2％ | ????80.5％ | ????60.2％ |
Capsicum variety: the ears of an ox or cow king infects: capsicum epidemic disease
The same example 87 of test method.
| Active substance | ????100ppm | ????50ppm | ????25ppm |
| Flumorph | ????89.8％ | ????62.3％ | ????45.0％ |
| Kresoxim-methyl | ????96.4 | ????92.1％ | ????76.3％ |
| Mixture (15% aqueous emulsion) | ????100％ | ????84.8％ | ????75.5％ |
Mixture (flumorph 50ppm adds kresoxim-methyl 50ppm) control efficiency is 100%;
Mixture (flumorph 20ppm adds kresoxim-methyl 20ppm) control efficiency is 84.8%;
Mixture (flumorph 12.5ppm adds kresoxim-methyl 12.5ppm) control efficiency is 75.5%.Example 91: the preparation of flumorph, kresoxim-methyl and example 61 is to the control efficiency of cucumber downy mildew (metalaxyl resistant strain) in the greenhouse.
Cucumber variety: Chang Chun Mi Ci, the close thorn in Shandong infect: cucumber downy mildew
Test method is with example 86.
Mixture (flumorph 20ppm adds kresoxim-methyl 5ppm) control efficiency is 75.1%; Mixture (flumorph 10ppm adds kresoxim-methyl 2.5ppm) control efficiency is 55.3%.Example 92: the preparation of flumorph, kresoxim-methyl and example 66 is to the control efficiency of cucumber downy mildew (metalaxyl resistant strain) in the greenhouse.
| Active substance | ????25ppm | ????12.5ppm |
| Flumorph | ????42.0％ | ????25.4％ |
| Kresoxim-methyl | ????75.3％ | ????61.2％ |
| Mixture (20% suspending agent) | ????75.1％ | ????55.3％ |
Cucumber variety: Chang Chun Mi Ci, the close thorn in Shandong infect: cucumber downy mildew
Test method is with example 86.
| Active substance | ????25ppm | ????12.5ppm |
| Flumorph | ????42.0％ | ????25.4％ |
| Kresoxim-methyl | ????75.3％ | ????61.2％ |
| Mixture (20% soluble liquid) | ????68.5％ | ????48.9％ |
Mixture (flumorph 22.5ppm adds kresoxim-methyl 2.5ppm) control efficiency is 68.5%;
Mixture (flumorph 11.25ppm adds kresoxim-methyl 1.25ppm) control efficiency is 48.9%.Example 93: the preparation of flumorph, Fluoxastrobin and example 31 is to the control efficiency of capsicum epidemic disease in the greenhouse.
Capsicum variety: the ears of an ox or cow king infects: capsicum epidemic disease
Test method is with example 87.
| Active substance | ????100ppm | ????50ppm | ????25ppm |
| Flumorph | ????89.8％ | ????62.3％ | ????45.0％ |
| Fluoxastrobin | ????100％ | ????97.3％ | ????81.5％ |
| Mixture (40% wetting powder) | ????100％ | ????83.0％ | ????77.4％ |
Mixture (flumorph 80ppm adds Fluoxastrobin 20ppm) control efficiency is 100%;
Mixture (flumorph 40ppm adds Fluoxastrobin 10ppm) control efficiency is 83.0%;
Mixture (flumorph 20ppm adds Fluoxastrobin 5ppm) control efficiency is 77.4%.Example 94: the preparation of flumorph, Fluoxastrobin and example 76 is to the control efficiency of capsicum epidemic disease in the greenhouse.
Capsicum variety: the ears of an ox or cow king infects: capsicum epidemic disease
Test method is with example 87.
| Active substance | ???100ppm | ????50ppm | ????25ppm |
| Flumorph | ????89.8％ | ????62.3％ | ????45.0％ |
| Fluoxastrobin | ????100％ | ????97.3％ | ????81.5％ |
| Mixture (20% microemulsion) | ????100％ | ????77.6％ | ????74.0％ |
Mixture (flumorph 90ppm adds Fluoxastrobin 10ppm) control efficiency is 100%;
Mixture (flumorph 45ppm adds Fluoxastrobin 5ppm) control efficiency is 77.6%;
Mixture (flumorph 22.5ppm adds Fluoxastrobin 2.5ppm) control efficiency is 74.0%.Example 95: the preparation of flumorph, kresoxim-methyl and example 18 is to the control efficiency of cucumber downy mildew (metalaxyl resistant strain) in the greenhouse.
Cucumber variety: Chang Chun Mi Ci, the close thorn in Shandong infect: cucumber downy mildew
Test method: the cucumber seedling pot-culture method is adopted in test, when cucumber grows to two leaves during one heart stage, handles with crop sprayer foliar spray, and the protectiveness test is to handle back 24 hours inoculation germs.The inoculation back was carried out result's investigation in 7-8 days.
| Active substance | ????50ppm | ????25ppm | ????12.5ppm |
| Flumorph | ????61.1％ | ????42.0％ | ????25.4％ |
| Kresoxim-methyl | ????90.2％ | ????75.3％ | ????61.2％ |
| Mixture (20% wetting powder) | ????100％ | ????95.0％ | ????82.8％ |
Mixture (flumorph 2.4ppm adds kresoxim-methyl 47.6ppm) control efficiency is 100%.
Mixture (flumorph 1.2ppm adds kresoxim-methyl 23.8ppm) control efficiency is 95.0%.
Mixture (flumorph 0.6ppm adds kresoxim-methyl 11.9ppm) control efficiency is 82.8%.Example 96: the preparation of flumorph, kresoxim-methyl and example 25 is to the control efficiency of cucumber downy mildew (metalaxyl resistant strain) in the greenhouse.
Cucumber variety: Chang Chun Mi Ci, the close thorn in Shandong infect: cucumber downy mildew
Test method: the cucumber seedling pot-culture method is adopted in test, when cucumber grows to two leaves during one heart stage, handles with crop sprayer foliar spray, and the protectiveness test is to handle back 24 hours inoculation germs.The inoculation back was carried out result's investigation in 7-8 days.
| Active substance | ????50ppm | ????25ppm | ????12.5ppm |
| Flumorph | ????61.1％ | ????42.0％ | ????25.4％ |
| Kresoxim-methyl | ????90.2％ | ????75.3％ | ????61.2％ |
| Mixture (20% wetting powder) | ????100％ | ????92.5％ | ????80.3％ |
Mixture (flumorph 3.125ppm adds kresoxim-methyl 46.875ppm) control efficiency is 100%.
Mixture (flumorph 1.56ppm adds kresoxim-methyl 23.44ppm) control efficiency is 92.5%.
Mixture (flumorph 0.78ppm adds kresoxim-methyl 11.72ppm) control efficiency is 80.3%.
Claims (7)
1, a kind of microbicide compositions is characterized in that: contain bactericide flumorph (SYP-L190) and a kind of methoxy acrylic bactericide (Strobin Fungicides/Strobilurin Analogues); The ratio of flumorph and any one methoxy acrylic bactericide is 1: 100 to 100: 1 based on the parts by weight of active component; Active component weight percentage in the composition is 0.5-95%, and all the other are carrier.
2, microbicide compositions according to claim 1 is characterized in that: the ratio of flumorph and any one methoxy acrylic bactericide is 1: 50 to 50: 1 based on the parts by weight of active component in the composition.
3, microbicide compositions according to claim 2 is characterized in that: the ratio of flumorph and any one methoxy acrylic bactericide is 1: 20 to 20: 1 based on the parts by weight of active component in the composition.
4, microbicide compositions according to claim 1 is characterized in that: described methoxy acrylic bactericide is kresoxim-methyl or kresoxim-methyl (kresoxim-methyl), Fluoxastrobin (azoxystrobin), oxime bacterium ester (trifloxystrobin), ZEN 90160 (picoxystrobin), pyraclostrobin (pyraclostrobin), SSF 126 (metominostrobin), SSF-129 (SSF-129), NA 83, enestroburin or Agrevo strobilurin analogue.
5, microbicide compositions according to claim 1 is characterized in that: contain at least two kinds of carriers in the composition, wherein at least a is surfactant.
6, microbicide compositions of the present invention can be used for preventing and treating by the microbial disease of Oomycete cause of disease: downy mildew, late blight, white eqpidemic disease, rotten mildew, damping off, black stem, canker, white blister, the millet downy mildew; Also can be used for control by the microbial early blight of other cause of disease, powdery mildew, scab, rust, glume blight, net blotch, leaf spot, damping off, rice blast, gray mold.
7, catch and kill the method for fungi at the scene, comprise with microbicide compositions of the present invention and handle this place, the wherein on-the-spot plant of standing fungal attack, the seed of these plants or the medium of plant growing of comprising: grape, tobacco, lupulus, millet, water paddy and wheat class, peanut, potato, tomato, cucumber, Chinese cabbage, pumpkin, wild cabbage, capsicum, onion, shallot, lettuce, garlic, beet and other vegetables and isatis root, rubber, apple, pears, citrus, avocado, pineapple, lichee, cocoa, rose, carnation and other ornamental plants.
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| CN 01113936 CN1385070A (en) | 2001-05-10 | 2001-05-10 | Disinfectant composition containing flumorph |
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| CN 01113936 CN1385070A (en) | 2001-05-10 | 2001-05-10 | Disinfectant composition containing flumorph |
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