CN107114372A - Composition pesticide containing fludioxonil and preparation method thereof - Google Patents
Composition pesticide containing fludioxonil and preparation method thereof Download PDFInfo
- Publication number
- CN107114372A CN107114372A CN201710339282.1A CN201710339282A CN107114372A CN 107114372 A CN107114372 A CN 107114372A CN 201710339282 A CN201710339282 A CN 201710339282A CN 107114372 A CN107114372 A CN 107114372A
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- China
- Prior art keywords
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- fludioxonil
- composition pesticide
- flumorph
- fenaminosulf
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
- A01N47/14—Di-thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A kind of composition pesticide containing fludioxonil, including fludioxonil, Fluoxastrobin, flumorph, fenaminosulf, dimethomorph, Mancozeb.The invention has the advantages that：By fludioxonil, Fluoxastrobin, flumorph, fenaminosulf, dimethomorph, Mancozeb compound action, the drug resistance of crop can be reduced, that improves crop disease prevents and treats efficiency, reduce the dosage of fludioxonil, production cost is reduced, practical application effect is good, beneficial to popularization.
Description
Technical field
The present invention relates to bactericide technical field, more particularly to a kind of contain the composition pesticide of fludioxonil and its preparation side
Method.
Background technology
Fludioxonil is a kind of contact bactericide, available for seed treatment, can prevent and treat the true of seed-borne fungi and soil-borne
Fungus diseases.Lasting period is long, and is difficult occur cross resistance with other bactericide.Fludioxonil be mainly used in wheat, barley, corn,
Pea, rape, paddy rice, vegetables, grape, lawn, ornamental crops foliar treatment, the rotten Fusariumsp of preventing and treating snow, wheat net raw meat black rot,
Rhizoctonia solani etc., has special efficacy to gray mold；To cereal and non-valley species subprocessing, preventing and treating kind is passed and soil-borne disease bacterium, such as rod method
Category, Ascochyta, aspergillus, Fusarium, Helminthosporium, Rhizoctonia and Penicillium bacterium.
Fludioxonil is non-interior suction benzene pyroles suspension seed-coating agent, high-efficiency broad spectrum.Sac fungus, basidiomycetes, Fungi Imperfecti etc. are permitted
Plant to pass caused by many pathogens and have extraordinary preventive effect with soil-borne disease.It by suppress the relevant transhipment of glucose phosphorylated come
Suppress mycelial growth, ultimately result in germ dead.Its unique mechanism of action, is not interacted anti-with other known bactericide
Property.In seed germination, fludioxonil can be absorbed on a small quantity, so as to control the germ inside seed and caryopsis；Cough up bacterium simultaneously
Nitrile is hardly moved in soil, therefore, it is possible to be maintained in the region around seed, provides crop root long-term guarantor
Shield.The other excellent formulation of fludioxonil causes seed pelleting film forming fast, does not fall off.Fludioxonil is to crop seed safety, tolerance
Good, capsuled seed can be sowed directly, can also be put under appropriate storage requirement to the sowing of next sowing season.Fludioxonil is the whole world
One of product of acquisition EPA EPA " low-risk " certifications few in number.Fludioxonil is widely used in various crop, such as cotton
Flower, wheat, peanut, soybean, paddy rice etc..
At present, for crop disease, drug resistance has been generated to fludioxonil, therefore, bacterium has been coughed up using conventional
Nitrile can not meet require that for market.
The content of the invention
The invention solves the problems that the problem of above-mentioned prior art is present there is provided a kind of composition pesticide containing fludioxonil and its
Preparation method, the problem of solving the fludioxonil drug resistance that current crop disease is produced, the crop demand of satisfaction.
The present invention solves the technical scheme that its technical problem is used：This composition pesticide containing fludioxonil, it be by
The raw material proportioning of following parts by weight is made：20 parts~40 parts of fludioxonil, 10 parts~15 parts of Fluoxastrobin, 5 parts~7 parts of flumorph, enemy
3 parts~5 parts of sulphur sodium, 2 parts~4 parts of dimethomorph, 3 parts~5 parts of Mancozeb, 1 part~3 parts of adhesive, 3 parts~7 parts of filler.
The above-mentioned composition pesticide containing fludioxonil, it is made up of the raw material proportioning of following parts by weight：Fludioxonil 30
Part, 12 parts of Fluoxastrobin, 6 parts of flumorph, 4 parts of fenaminosulf, 3 parts of dimethomorph, 4 parts of Mancozeb, 2 parts of adhesive, 5 parts of filler.
Further, the preparation method of the above-mentioned composition pesticide containing fludioxonil is：By the fludioxonil of selection, phonetic bacterium
Ester, flumorph, fenaminosulf, dimethomorph, Mancozeb are sufficiently mixed, and are then added adhesive and filler, are stirred
Afterwards, the composition pesticide containing fludioxonil is obtained.
Further, above-mentioned adhesive is the fragrant polyoxyethyl ether of alkyl, fatty alcohol polyoxyethyl ether, alkyl naphthalene sulfonic acid
One kind or its any combination in salt, polyvinyl alcohol.
Further, above-mentioned filler is one kind in clay, clay, kaolin, diatomite, pyrophillite or its any group
Close.
The composition pesticide containing fludioxonil of the present invention, it is by fludioxonil, Fluoxastrobin, flumorph, fenaminosulf, alkene acyl
Morpholine, Mancozeb combination are made, the Chinese of fludioxonil：Fluorine fludioxonil；Fludioxonil；When suitable happy；4- (2,2- bis- fluoro- 1,
3- benzo dioxy -4- bases) pyrroles's -3- nitriles, for preventing and treating the bunt of wheat, snow mold, snow mold, banded sclerotial blight, root rot, complete
Lose disease, glume blight, flag smut；Stripe disease of barley, net blotch, covered smut；Corn Stalk Rot, base rot disease, samping off；Cotton
Flower damping-off, red rot, anthracnose, black root, seed rot；Soybean peanut damping-off, root rot (sickle-like bacteria causes)；Water
The Bakanae disease of rice, flax leaf spot, early stage leaf seasonal febrile diseases, damping-off；Alternaria stem rot of colza, balck shank；Potato rhizoctonosis, shot hole；
Vegetables droop, anthracnose, brown spot, blight dis-ease.Suitable for wheat, barley, corn, cotton, soybean, peanut, paddy rice, oil
The crops such as dish, potato, vegetables.Fluoxastrobin Chinese nickname：(E)-[2- [6- (2- cyano-benzene oxygens) pyrimidine-4-yl oxygen] benzene
Base] -3- methoxy-methyl acrylates；Amici reaches；(E) -2- { 2- [6 (2- cyano-benzene oxygens) pyrimidine-4-yl oxygen] phenyl } -3-
Methoxy-methyl acrylate, the product is methoxy acrylic sterilization pesticide, efficient, wide spectrum, to almost all of fungi
Boundary's disease such as powdery mildew, rust, glume blight, net blotch, downy mildew, rice blast etc. have good activity, available for cauline leaf spray
Mist, seed treatment, can also carry out soil treatment, be mainly used in cereal, paddy rice, peanut, grape, potato, fruit tree, vegetables, coffee
Coffee, lawn etc..Flumorph belongs to morpholine class disinfectant use in agriculture, especially effective to Peronospora, the plain germ of phytophthora.To grape, potato
There is fungicidal effectiveness with the Oomycete on tomato, especially Peronosporaceae and Phytophthora bacterium.Fenaminosulf is mainly used as seed treatment and soil
Earth processing, it is also sprayable.Suitable for crop vegetables, sweet tea Lay, wheat class, pineapple, paddy rice, tobacco, cotton etc..Rice blast, rice is prevented and treated to dislike
Seedling diseases, rust, samping off, powdery mildew, epidemic disease, black spot, anthracnose, downy mildew, damping-off, root rot and stem rot, and
Stinking smut of wheat, the bunt of cereal crops.Dimethomorph is a kind of new interior therapeutic special low toxicity bactericide of suction,
Its mechanism of action is the formation for destroying germ cell envelope, causes the decomposition of spore cyst wall, and makes germ dead.Except zoospore
Outside formation and spore swarm stage, there are effect, the especially shape to sporangiophore and egg spore to each stage of the oomycetes history of life
It is more sensitive into the stage, if the medication before sporangium and egg spore are formed, can completely inhibit the generation of spore.The medicine absorbability
By force, root application, can enter each position of plant by root；Blade sprays, and can enter blade interior.It is with metalaxyl etc.
Benzamides bactericide does not have cross resistance.Mancozeb is a kind of excellent protective fungicide, belongs to low-toxin farm chemicals.Due to it
Bactericidal range is wide, be not likely to produce resistance, and prevention effect is substantially better than other same series bactericidal agents, so consumption is always in the world
Large tonnage product.At present, domestic most composite bactericides are all formulated with Mancozeb processing, and manganese, zinc microelement are to making
Thing has obvious rush to strengthen, production-increasing function, by more than ten years Field information, to preventing and treating pear scab, alternaria leaf spot of apple, melon dish
Class epidemic disease, downy mildew, field crop rust and other effects significantly, effectively can control disease to send out completely without other any bactericide
It is raw, it is steady quality, reliable.Main controlling object：Pear scab, citrus scab, canker, alternaria leaf spot of apple, grape
Downy mildew, downy mildew of lichee, phytophthora root rot, Pepper Phytophthora Blight, cucumber, muskmelon, water melon frost mildew, tomato blight, Cotton Boll Rot is small
Wheat rust, powdery mildew, the big spot of corn, cecospora spot, tobacco black shank, Chinese yam anthracnose, brown rot, root neck rot, spot fallen leaves
Disease etc..
The composition pesticide containing fludioxonil of the present invention, it is by fludioxonil, Fluoxastrobin, flumorph, fenaminosulf, alkene acyl
Morpholine, Mancozeb combination are made, and regard fludioxonil as major antibacterial agent, Fluoxastrobin, flumorph, fenaminosulf, dimethomorph, generation
Gloomy MnZn, each other without cross resistance, passes through fludioxonil, Fluoxastrobin, flumorph, fenaminosulf, alkene as aid antibacteria agent
The compound action of morpholide, Mancozeb, reduces the drug resistance of crop, improves the efficiency of preventing and treating of crop disease, and bacterium is coughed up in reduction
The dosage of nitrile, reduces production cost.
The invention has the advantages that：The present invention the composition pesticide containing fludioxonil, by fludioxonil, Fluoxastrobin,
Flumorph, fenaminosulf, dimethomorph, the compound action of Mancozeb, can reduce the drug resistance of crop, improve crop disease
Prevent and treat efficiency, reduce the dosage of fludioxonil, reduce production cost, practical application effect is good, beneficial to popularization.
Embodiment
The invention will be further described below：
Embodiment one：
This composition pesticide containing fludioxonil, it is made up of the raw material proportioning of following weight kilogram：Fludioxonil 20
Kilogram, 10 kilograms of Fluoxastrobin, 5 kilograms of flumorph, 3 kilograms of fenaminosulf, 2 kilograms of dimethomorph, 3 kilograms of Mancozeb, adhesive 1
Kilogram, 3 kilograms of filler.
Further, the preparation method of the above-mentioned composition pesticide containing fludioxonil is：By the fludioxonil of selection, phonetic bacterium
Ester, flumorph, fenaminosulf, dimethomorph, Mancozeb are sufficiently mixed, and are then added adhesive and filler, are stirred
Afterwards, the composition pesticide containing fludioxonil is obtained.
Further, above-mentioned adhesive is the fragrant polyoxyethyl ether of alkyl
Further, above-mentioned filler is clay
Embodiment two：
This composition pesticide containing fludioxonil, it is made up of the raw material proportioning of following weight kilogram：Fludioxonil 30
Kilogram, 12 kilograms of Fluoxastrobin, 6 kilograms of flumorph, 4 kilograms of fenaminosulf, 3 kilograms of dimethomorph, 4 kilograms of Mancozeb, adhesive 2
Kilogram, 5 kilograms of filler.
Further, the preparation method of the above-mentioned composition pesticide containing fludioxonil is：By the fludioxonil of selection, phonetic bacterium
Ester, flumorph, fenaminosulf, dimethomorph, Mancozeb are sufficiently mixed, and are then added adhesive and filler, are stirred
Afterwards, the composition pesticide containing fludioxonil is obtained.
Further, above-mentioned adhesive is fatty alcohol polyoxyethyl ether
Further, above-mentioned filler is clay.
Embodiment three：
This composition pesticide containing fludioxonil, it is made up of the raw material proportioning of following weight kilogram：Fludioxonil 40
Kilogram, 15 kilograms of Fluoxastrobin, 7 kilograms of flumorph, 5 kilograms of fenaminosulf, 4 kilograms of dimethomorph, 5 kilograms of Mancozeb, adhesive 3
Kilogram, 7 kilograms of filler.
Further, the preparation method of the above-mentioned composition pesticide containing fludioxonil is：By the fludioxonil of selection, phonetic bacterium
Ester, flumorph, fenaminosulf, dimethomorph, Mancozeb are sufficiently mixed, and are then added adhesive and filler, are stirred
Afterwards, the composition pesticide containing fludioxonil is obtained.
Further, above-mentioned adhesive is the combination in alkylnaphthalene sulfonate, polyvinyl alcohol.
Further, above-mentioned filler is the combination in kaolin, diatomite, pyrophillite.
In embodiments of the present invention, 1 part is 1 kilogram.
The composition pesticide containing fludioxonil prepared by the embodiment of the present invention one, embodiment two, embodiment three is chosen, it is and normal
Rule fludioxonil is contrasted, and by taking bakanae disease of rice, gray mold of cucumber, potato rhizoctonosis as an example, comparing result is as follows：
Bakanae disease of rice：
Gray mold of cucumber：
Potato rhizoctonosis：
As can be known from the above table, the composition pesticide of the invention containing fludioxonil, prevention effect is better than conventional fludioxonil.
The characteristics of embodiment of the present invention is：Pass through fludioxonil, Fluoxastrobin, flumorph, fenaminosulf, dimethomorph, maneb
The compound action of zinc, can reduce the drug resistance of crop, improve the efficiency of preventing and treating of crop disease, reduce the medication of fludioxonil
Amount, reduces production cost, and practical application effect is good, beneficial to popularization.
Although the present invention is described by reference to preferred embodiment, those skilled in the art should
Work as understanding, in the range of claims, various change in form and details can be made.
Claims (5)
1. a kind of composition pesticide containing fludioxonil, it is characterised in that it is made up of the raw material proportioning of following parts by weight：Cough up
20 parts~40 parts of bacterium nitrile, 10 parts~15 parts of Fluoxastrobin, 5 parts~7 parts of flumorph, 3 parts~5 parts of fenaminosulf, dimethomorph 2 parts~4
Part, 3 parts~5 parts of Mancozeb, 1 part~3 parts of adhesive, 3 parts~7 parts of filler.
2. the composition pesticide according to claim 1 containing fludioxonil, it is characterised in that it is by following parts by weight
Raw material proportioning is made：30 parts of fludioxonil, 12 parts of Fluoxastrobin, 6 parts of flumorph, 4 parts of fenaminosulf, 3 parts of dimethomorph, Mancozeb 4
Part, 2 parts of adhesive, 5 parts of filler.
3. the preparation method of the composition pesticide according to claim 1 or 2 containing fludioxonil, it is characterised in that：Will choosing
Fludioxonil, Fluoxastrobin, flumorph, fenaminosulf, dimethomorph, the Mancozeb taken is sufficiently mixed, and is then added adhesive and is filled out
Material, after stirring, obtains the composition pesticide containing fludioxonil.
4. the composition pesticide according to claim 1 or 2 containing fludioxonil, it is characterised in that：Described adhesive is alkane
Base virtue polyoxyethyl ether, fatty alcohol polyoxyethyl ether, alkylnaphthalene sulfonate, one kind in polyvinyl alcohol or its any combination.
5. the composition pesticide according to claim 1 or 2 containing fludioxonil, it is characterised in that：The filler be clay,
One kind or its any combination in clay, kaolin, diatomite, pyrophillite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710339282.1A CN107114372A (en) | 2017-05-15 | 2017-05-15 | Composition pesticide containing fludioxonil and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710339282.1A CN107114372A (en) | 2017-05-15 | 2017-05-15 | Composition pesticide containing fludioxonil and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107114372A true CN107114372A (en) | 2017-09-01 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710339282.1A Pending CN107114372A (en) | 2017-05-15 | 2017-05-15 | Composition pesticide containing fludioxonil and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107114372A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1385070A (en) * | 2001-05-10 | 2002-12-18 | 沈阳化工研究院 | Disinfectant composition containing flumorph |
| CN101088336A (en) * | 2001-11-27 | 2007-12-19 | 辛根塔参与股份公司 | Synergistic seed treatment compositions |
-
2017
- 2017-05-15 CN CN201710339282.1A patent/CN107114372A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1385070A (en) * | 2001-05-10 | 2002-12-18 | 沈阳化工研究院 | Disinfectant composition containing flumorph |
| CN101088336A (en) * | 2001-11-27 | 2007-12-19 | 辛根塔参与股份公司 | Synergistic seed treatment compositions |
Non-Patent Citations (1)
| Title |
|---|
| 王江柱主编，: "《农民欢迎的200种农药 第2版》", 30 April 2015, 中国农业出版社 * |
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Application publication date: 20170901 |