CN1379621A - 木材处理方法 - Google Patents

木材处理方法 Download PDF

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Publication number
CN1379621A
CN1379621A CN00814325A CN00814325A CN1379621A CN 1379621 A CN1379621 A CN 1379621A CN 00814325 A CN00814325 A CN 00814325A CN 00814325 A CN00814325 A CN 00814325A CN 1379621 A CN1379621 A CN 1379621A
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timber
treatment method
fungi
wood treatment
compound
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CN1183830C (zh
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P·E·拉塞尔
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AFINDY AGRICULTURAL SCIENCES GmbH
Bayer CropScience AG
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AFINDY AGRICULTURAL SCIENCES GmbH
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34—Organic impregnating agents
    • B27K3/343—Heterocyclic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34—Organic impregnating agents
    • B27K3/38—Aromatic compounds
    • B27K3/40—Aromatic compounds halogenated

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

本发明是关于用化合物(I)防治木材致害真菌,其中,R是(a)或(b),各R1相同或不同,是C1－4烷基,C1－4烷氧基,三氟甲基或卤素,n是0－3。

Description

木材处理方法
发明领域
本发明涉及木材的保存方法。
WO96/36615和97/00612描述了各种用作防治植物病害的杀真菌剂的环脲。
我们发现，有一类化合物对于防治木材致害真菌非常有效，由其是防治引起腐烂的担子菌纲和破坏木材外观的边材蓝变真菌。
本发明提供化合物I用于防治木材致害真菌的用途：其中R是：a)
Figure A0081432500032
或b) 其中各R1相同或不同，是C1-4烷基，C1-4烷氧基，三氟甲基或卤素，n是0-3。
可用以上化合物防治的真菌例如：青冈边材腐朽病菌(Coriolus versicolor)，黄杨根腐病菌(Poria placenta)，洁丽香菇菌(Lentinus lepideus)，杂色栓菌病菌(Trametes versicolor)，泪菌病菌(Serpula lacrymans)，湿腐粉孢革菌(Coniophoraputeana)和密粘褶菌(Gloeophyllum trabeum)。
通常，腐木真菌似乎是由2种以上真菌组成的复杂菌群。
我们还发现，化合物I在与其他杀木材致害真菌剂联用时特别有效，所述其他杀真菌剂例如：氟喹唑(fluquinconazole)，戊唑醇(tebuconazole)，二氯萘醌，多菌灵，咪鲜安，硅氟唑(sipconazole)和环唑醇。
可将化合物I配制成常规液体制剂形式，其中一般包含有表面活性剂及其他常规添加剂，并且，通常在用水稀释后施用。其浓度范围较宽，例如0.001-10wt％，较好的是0.1-1wt％。
以下将通过实施例来阐明本发明。
实施例1抗木材致害真菌活性的活体试验
将刚伐下的10cm松木薄边板材切割成20cm长。每6片板材为平行试验组中的一份，交替堆叠成6层高的一捆。每一种处理的平行试验组包括3份。
对同一平行试验组中的各份木材用同一种待测化合物的处理溶液分别进行处理。将每捆6层的木材浸入测试液，同时将一条1cm的纵向条带保持清洁。将板材轻轻分开，使处理液可在板材之间自由流动。处理时间约为10秒，然后将板材从处理液中取出，沥干多余的液体，将板材装入聚乙烯袋中。袋子的背面有一个孔，可放出多余的湿汽，但可保持内部高湿度。
将装在袋中的板材放在18℃的暖房中，接受自然光照。各捆木材分开放置，不要堆叠。定期翻动木材捆以确保捆内水分均匀。
5周后进行测评。对每一捆木材中相邻板材的接触面进行边材蓝变菌感染百分比，担子菌纲聚集区面积百分比和烟霉聚集区面积百分比测定。因为每捆有6片板材，所以每捆有5个读数。以未处理板材为对照计算感染水平的相对百分比。
将10EC的化合物A(WO9636615的实施例59)稀释至所需浓度用于处理。与市售产品Evotek(23％的咪鲜安和多菌灵的悬乳液)进行比较。结果如下：
处理 浓度                  ％对照
 边材蓝变菌    担子菌    烟霉
   化合物A     2％     100     100     98
    1％      93      97     93
    0.50％      93      96     65
   Evotek     2％     100       0     97
    1％      99       0     99
    0.50％      98       0    100
显然，所述化合物对于防治边材蓝变菌和烟霉明显优于Evotek，而且还能防治Evotek所不能防治的担子菌。以上对木材致病真菌的广谱效果是出人意料的。
实施例2抗木材致害真菌活性的体外试验
将化合物A在麦芽琼脂中配制成不同浓度，将琼脂倒入培养皿。在琼脂板中央接种4mm腐木真菌的菌丝团。培养板在20℃暗房内放置7天，然后评价化合物A的抗真菌效果。结果如下：
浓度(ppm)               与对照菌落直径相比的百分比
  粉孢革菌  采绒革盖菌   槽粘褶菌  placenta卧孔菌
    100     100    100.0    100.0      100
     25     100      93     92       93
     10     100      76     56       70
      1     100      42     38       54

Claims (1)

1.化合物I用于防治木材致害真菌的用途，
Figure A0081432500021
其中R是：a) 或b)
Figure A0081432500023
其中各R1相同或不同，是C1-4烷基，C1-4烷氧基，三氟甲基或卤素，n是0-3。
CNB008143250A 1999-10-20 2000-10-17 木材处理方法 Expired - Fee Related CN1183830C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB9924692.8A GB9924692D0 (en) 1999-10-20 1999-10-20 Wood treatment
GB99246928 1999-10-20

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CN1183830C CN1183830C (zh) 2005-01-12

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EP (1) EP1221849A1 (zh)
JP (1) JP2003511470A (zh)
KR (1) KR20020059626A (zh)
CN (1) CN1183830C (zh)
AU (1) AU7924100A (zh)
BG (1) BG106599A (zh)
BR (1) BR0014825A (zh)
CA (1) CA2386609A1 (zh)
CZ (1) CZ293103B6 (zh)
GB (1) GB9924692D0 (zh)
HU (1) HUP0203527A3 (zh)
IL (1) IL148822A0 (zh)
NZ (1) NZ517933A (zh)
PL (1) PL356054A1 (zh)
RU (1) RU2240690C2 (zh)
SK (1) SK5182002A3 (zh)
WO (1) WO2001028331A1 (zh)
ZA (1) ZA200202431B (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1326677C (zh) * 2005-07-25 2007-07-18 吴东良 一种木材处理液和处理方法及设备
CN100430373C (zh) * 2005-04-05 2008-11-05 湖南化工研究院 具生物活性的含双三氟甲基苯基的甲氧丙烯酸酯类化合物及其制备方法

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005022149A1 (de) * 2005-05-13 2006-11-16 Lanxess Deutschland Gmbh Verwendung von Prochloraz für den Holzschutz
GB201010439D0 (en) 2010-06-21 2010-08-04 Arch Timber Protection Ltd A method
GB201119139D0 (en) 2011-11-04 2011-12-21 Arch Timber Protection Ltd Additives for use in wood preservation
CN110587753A (zh) 2014-05-02 2019-12-20 奥麟木材保护有限公司 木材防腐剂组合物
CN104610177B (zh) * 2015-02-02 2017-12-19 浙江树人大学 一种三唑酮类化合物的制备与应用

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HUT53889A (en) 1988-03-04 1990-12-28 Sankyo Co. Ltd.,Jp Fungicides comprising triazole derivatives as active ingredient and process for producing the active ingredient
BR9408167A (pt) 1993-11-19 1997-08-26 Du Pont Composto composição fungicida e método de controle de doenças em plantas
DE4429006A1 (de) 1994-08-16 1996-02-22 Basf Ag Substituierte Triazolinone als Pflanzenschutzmittel
WO1996036615A1 (en) 1995-05-16 1996-11-21 E.I. Du Pont De Nemours And Company Fungicidal cyclic amides
PL323497A1 (en) * 1995-05-17 1998-03-30 Du Pont Cyclic amides acting as fungicides
EP0836384A1 (en) 1995-06-20 1998-04-22 E.I. Du Pont De Nemours And Company Arthropodicidal and fungicidal cyclic amides
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CZ184599A3 (cs) * 1996-11-26 1999-09-15 E. I. Du Pont De Nemours And Company Methylem substituované fungicidy a artropodicidy
DE19724200A1 (de) 1997-06-09 1998-12-10 Basf Ag Bisiminosubstituierte Phenylverbindungen
DE19731153A1 (de) 1997-07-21 1999-01-28 Basf Ag 2-(Pyrazolyl- und Triazolyl-3'-oxymethylen)-phenyl-isoxazolone und -triazolone, Verfahren zu ihrer Herstellung und ihre Verwendung
DE19732846A1 (de) 1997-07-30 1999-02-04 Basf Ag Bisiminosubstituierte Phenylverbindungen
WO1999011129A1 (en) * 1997-09-04 1999-03-11 E.I. Du Pont De Nemours And Company Enantiomerically enriched compositions and their pesticidal use
AU1407899A (en) * 1997-12-01 1999-06-16 E.I. Du Pont De Nemours And Company Fungicidal cyclic amides
JP2002506060A (ja) * 1998-03-09 2002-02-26 ビーエーエスエフ アクチェンゲゼルシャフト ヘテロアリール置換ベンジルフェニルエーテル、その製造方法、並びに有害菌類及び有害動物防除用としての使用法
AU6427800A (en) 1999-06-14 2001-01-02 Novartis Ag Fungicidal combinations

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100430373C (zh) * 2005-04-05 2008-11-05 湖南化工研究院 具生物活性的含双三氟甲基苯基的甲氧丙烯酸酯类化合物及其制备方法
CN1326677C (zh) * 2005-07-25 2007-07-18 吴东良 一种木材处理液和处理方法及设备

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CZ20021359A3 (cs) 2002-07-17
BR0014825A (pt) 2002-08-27
KR20020059626A (ko) 2002-07-13
IL148822A0 (en) 2002-09-12
BG106599A (en) 2002-12-29
WO2001028331A1 (en) 2001-04-26
CA2386609A1 (en) 2001-04-26
ZA200202431B (en) 2003-09-23
GB9924692D0 (en) 1999-12-22
NZ517933A (en) 2003-10-31
AU7924100A (en) 2001-04-30
PL356054A1 (en) 2004-06-14
CZ293103B6 (cs) 2004-02-18
HUP0203527A2 (hu) 2003-03-28
HUP0203527A3 (en) 2003-04-28
RU2240690C2 (ru) 2004-11-27
SK5182002A3 (en) 2002-08-06
EP1221849A1 (en) 2002-07-17
CN1183830C (zh) 2005-01-12
JP2003511470A (ja) 2003-03-25
US6824830B1 (en) 2004-11-30

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