CN1352626A - Decorative stone and production method thereof - Google Patents
Decorative stone and production method thereof Download PDFInfo
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- CN1352626A CN1352626A CN99816707.XA CN99816707A CN1352626A CN 1352626 A CN1352626 A CN 1352626A CN 99816707 A CN99816707 A CN 99816707A CN 1352626 A CN1352626 A CN 1352626A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/48—Macromolecular compounds
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Abstract
A production method of a decorative stone characterized by comprising a step of at least one cycle for permeating an inorganic coloring material water solution into a stone surface layer uniformly and to the same extent by drawint specific patterns and characters on the stone surface using the inorganic coloring material water solution with the stone kept dried up, a step of heating the stone surface up to 180 to 200 deg to develop the color of the inorganic coloring material and finally a step of polishing the surface after colling; and a production method of a decorative stone characterized by comprising the steps of drawing specified patterns and characters on the stone surface using the thermoseting plastic suspension of an inorganic coloring material and heating the stone surface up to 180 to 200 deg to develop the color of the inorganic coloring material and cure the thermosetting plastics, whereby making it possible to produce a decorative stone excellent in weatherability and high in decorative value.
Description
Technical field
The present invention relates at stone surface, stone material and manufacture method thereof with inorganic coloring material painting and calligraphy pattern and literal etc., the purpose of this invention is to provide a kind of can at the buildings wall or the floor be inner or various monuments etc. extensively utilize, particularly can stone material that decorative value is low be given the decorative stone and the manufacture method thereof of added value to weathering resistances such as grouan are good.
Background technology
As the method for representing pattern and literal at stone surface, can enumerate employing coating and dyestuff method at surperficial painting and calligraphy.Yet the shortcoming that this method has is, because peeling off or stone surface weathering and damaged of coating causes the pattern of painting and calligraphy and literal to take place damaged.In addition, stone surface is formed recess by engraving,, also can carry out the expression of pattern and literal by at this protuberance coating composition.But,, worry that still coating peels off or variable color take place as time passes even adopt such method.
In view of above-mentioned practical situation, as solution to the problems described above, it is found that and a kind ofly make pattern and literal method of colouring at stone surface, for example, in Japanese kokai publication sho 63-282180 number, disclose a kind ofly, again it has been burnt till 1 hour～24 hours in addition painted technology 200 ℃～1000 ℃ heating at position, stone material top layer coating coloured material., adopt aforesaid method, need carry out heat for a long time and burn till, make coloured material painted, thereby worry that the intensity that causes stone material reduces.Yet while be coated with coloured material owing to pressurize, coloured material can't be uniformly coated on position, stone material top layer, when stone surface is damaged, presents pattern and the literal different originally with manufacturing, hinders attractive in appearance.
In addition, login in Japanese Utility Model and to disclose in No. 3030349 after coloured material coating, burn till, make the technology of the coloured material of coating at position, top layer color development by carrying out heating long-time normal pressure under in 150 ℃～800 ℃.Yet, although adopt this method that coloured material evenly is coated with at position, stone material top layer, colorful performance difficulties such as shade, iridescence, and, owing to enter coloured material painted more shallow at position, stone material top layer, therefore because wearing and tearing are faded or the situation of variable color is taught many.
The present invention is exactly the invention of carrying out in order to solve the problem that exists in above-mentioned original decorative stone and the manufacture method thereof, by adopting the inorganic coloring material, can prevent the variable color that produces as time passes, and by the inorganic coloring material evenly and is similarly permeated at position, stone material top layer, perhaps be fixed on the stone surface by thermosetting resin suspension liquid the inorganic coloring material, that does not worry wearing and tearing and cause fades and variable color, and low cost of manufacture can be used for multi-purpose decorative stone and manufacture method thereof.
Disclosure of an invention
The invention that claim 1 relates to relates to a kind of decorative stone, it is characterized in that at stone surface, and with needed pattern of coloured material painting and calligraphy and literal, this pattern and literal are evenly and similarly painted in the certain degree of depth in position, stone material top layer; The invention that claim 2 relates to relates to a kind of decorative stone, at stone surface with containing the coloured material of thermosetting resin, needed pattern of painting and calligraphy and literal and constitute; The invention that claim 3 relates to, the manufacture method that relates to a kind of decorative stone, it is characterized in that this method makes stone material reach approximate absolutely dry state, under this state, with inorganic coloring material water solution at needed pattern of stone surface painting and calligraphy and literal, the inorganic coloring material water solution that is coated on stone surface evenly and is similarly permeated in position, stone material top layer, after this operation is carried out 1 time at least, the stone surface temperature is heated to 180 ℃～200 ℃, make inorganic coloring material color development, cool off at last, and the attrition process surface; The invention that claim 4 relates to, relate to decorative stone manufacture method as claimed in claim 3, it is characterized in that with inorganic coloring material water solution at needed pattern of stone surface painting and calligraphy and literal, before this inorganic coloring material water solution is carried out toward position, top layer infiltration operation, to the not coloured part coating resist printing coating of stone material and make its curing; The invention that claim 5 relates to relates to as claim 3 or 4 described decorative stone manufacture method, it is characterized in that, makes stone material reach approximate absolutely dry state by heating; The invention that claim 6 relates to relates to as claim 3 or 4 described decorative stone manufacture method, it is characterized in that, makes stone material reach approximate absolute dry condition by decompression; The invention that claim 7 relates to, relate to any one described decorative stone manufacture method as claim 3～6, it is characterized in that, as above-mentioned inorganic coloring material water solution, be to contain the mineral compound that more than one are selected from Xiao Suangu, iron nitrate, iron(ic) chloride, chromium chloride, potassiumchromate, neutralized verdigris, Tai-Ace S 150, nickelous chloride, cobalt chloride, rose vitriol, Xiao Suangu, Red copper oxide, manganous nitrate etc. at least; The invention that claim 8 relates to relates to any one the described decorative stone manufacture method as claim 4～7, it is characterized in that, as above-mentioned resist printing coating use is the coating that contains unsaturated polyester resin; The invention that claim 9 relates to relates to any one the described decorative stone manufacture method as claim 4～7, it is characterized in that, as above-mentioned resist printing coating employing is to contain the coating that water-soluble paste constitutes; The invention that claim 10 relates to, relate to any one described decorative stone manufacture method as claim 3～9, it is characterized in that, as above-mentioned inorganic coloring material water solution, employing be to contain more than one to be selected from the luminous fluor of twinkler, luminous storage material, little radiation of black lamp irradiation, the noctilucence body material of silica shape reflective particle; The invention that claim 11 relates to, the manufacture method that relates to a kind of decorative stone, it is characterized in that at stone surface, thermosetting resin suspension liquid with the inorganic coloring material, behind needed pattern of painting and calligraphy and the literal, be heated to 180～200 ℃, make inorganic coloring material color development, simultaneously, thermosetting resin is solidified; The invention that claim 12 relates to, the manufacture method that relates to a kind of decorative stone, it is characterized in that, carve into needed pattern and literal at stone surface, the thermosetting resin suspension liquid of inorganic coloring material is poured into a mould in its recess, the stone surface temperature is heated to 180～200 ℃, makes inorganic coloring material color development, thermosetting resin is solidified; The invention that claim 13 relates to, relate to as claim 11 or 12 described decorative stone manufacture method, it is characterized in that, as the thermosetting resin suspension liquid of above-mentioned inorganic coloring material, be to adopt to contain the twinkler that is selected from more than a kind with the black lamp irradiation, luminous storage material, the fluor of little radioluminescence, the noctilucence body material of silica shape reflective particle; The invention that claim 14 relates to, relate to any one described ornamental stone material manufacture method as claim 11～13, it is characterized in that, as above-mentioned inorganic coloring material, be to adopt at least that more than one are selected from the mineral compound of Xiao Suangu, iron nitrate, iron(ic) chloride, chromium chloride, potassiumchromate, neutralized verdigris, Tai-Ace S 150, nickelous chloride, cobalt chloride, rose vitriol, Xiao Suangu, Red copper oxide, manganous nitrate.
The simple declaration of accompanying drawing
Fig. 1 is for being processed into the topped figure of stamp paper mold on the stone surface of square plate;
Fig. 2 removes the stamp paper mold for after being coated with resist printing coating, is coated with and makes the figure of the stone material of its infiltration with the inorganic coloring material;
Fig. 3 decorates the figure finished for infiltration;
The figure that Fig. 4 cuts open along the A-A line for the position, top layer of Fig. 3 decorative stone;
Fig. 5 is a stamp paper mold of copying the maple leaf pattern;
Fig. 6 is the decorative stone that the stamp paper mold of employing Fig. 5 is made;
Fig. 7 is the figure that the position, decorative stone top layer of Fig. 6 is cut open along the B-B line;
Fig. 8 is the figure that adopts the decorative stone that the thermosetting resin of inorganic coloring material makes.
Implement preferred plan of the present invention
The decorative stone that the present invention relates to can adopt following two kinds of methods to make respectively, promptly, first method is at stone surface, the aqueous solution with the inorganic coloring material, the method of infiltration colored pattern and literal under normal pressure, and second method is at stone surface, with the thermosetting resin suspension liquid painting and calligraphy pattern and the literal of inorganic coloring material and make its solidified method.Describe the manufacture method of this decorative stone below in detail according to accompanying drawing.
At first, the manufacture method to first decorative stone that adopts inorganic coloring material water solution is illustrated.
As the kind of used stone material, can enumerate grouan (granite), ryolite, andesite, marble etc.Particularly, because the weathering resistance of grouan is good, can preferentially select for use.This is because the decorative value of grouan is low, be used as the material of decorative stone hardly in the past, yet, if according to the decorative stone manufacture method that the present invention relates to, even also can give decorative value for the grouan that decorative value is low, so, by using grouan, it is good to make weather-resistant property, simultaneously the high decorative stone of decorative value.In addition, roughly grind stone surface before the operation, be preferably in below 80 ℃ in addition dry in dyeing.
After above-mentioned stone material carried out drying, cooling, at first coloured part is not imposed resist printing processing.Concrete is, as shown in Figure 1, places stamp paper mold 2 on the surface of stone material 1, under 25 ℃～35 ℃ normal temperature condition, and at the coloured part not pattern part of flower (among the figure for) coating resist printing coating, then, in 30 ℃～40 ℃ normal temperature dry getting final product in addition.
As resist printing coating, can enumerate synthetic resins such as acrylic resin, poly-urethane resin, unsaturated polyester resin, and pasty state that fillers such as interpolation silica solubility promoter, ground silica, talcum powder, white lime, mica powder, bentonite in powder are made in water-soluble paste or sticking fraction etc.Particularly, unsaturated polyester resin is aqueous, mixed fillers easily, and so thermotolerance and excellent in stability are preferred the use.In addition, the resist printing effect of water-soluble paste is low, can easily remove by using high pressure water, so the resist printing coating that has formed the concavo-convex stone material that carries out anti-skidding processing etc. as stone surface is preferred.In addition, in above-mentioned resist printing coating, can also suitably mix peptizer, promotor, vinylbenzene, エ ア ロ ジ Le etc.
Also have,, can enumerate and use stamp paper mold shown in Figure 1, remove employing bristle and scraper coating process, the spraying method, hand-written method such as available writing brush or pen etc. also as the coating process of resist printing coating.In addition, when using silk screen printing, can on stone surface, slather cloth resist printing material, and, can handle complicated patterns, be better.In addition, the above-mentioned resist printing coating of enumerating owing to contain filler, can not infiltrate into position, stone material top layer.
After imposing resist printing processing with aforesaid method, stone material is reached under the approximate absolutely dry state, as shown in Figure 2,, can show desired pattern and literal by at stone surface coating inorganic coloring material water solution.That is, in illustrated embodiment, owing to impose resist printing processing at the pattern part of spending 3, and when at stone surface coating inorganic coloring material water solution, can pattern part 4 a coating inorganic coloring material water solution in addition at flower.
Also have, according to different patterns, do not impose above-mentioned resist printing processing, with topped not coloured parts such as stamp paper molds, coating inorganic coloring material water solution is good, yet when with resist printing coating, transaction capabilities improves, and also is adapted to more complicated patterns, is ideal.
The inorganic coloring material water solution that uses is the tinting material that is used metals such as pottery art technology, be dissolved in independent or compoundly and make its concentration reach 20%～40% and obtain in the water, as the tinting material of metal system, can enumerate iron nitrate, nickelous chloride, the iron(ic) chloride of reddish brown series; The cobalt chloride of green-series, chromium chloride; The rose vitriol of grey black color system, Xiao Suangu; Iron(ic) chloride, the Tai-Ace S 150 of blue series; Other also have the materials that mineral compound constituted such as potassiumchromate, neutralized verdigris, Red copper oxide.
In addition, in above-mentioned inorganic coloring material water solution, also can add luminiferous material, luminous storage material, the little radiation luminous fluor of mixing with the black lamp irradiation, the noctilucence body material of silica shape reflective particle etc., also can make the noctilucence stone material thus, can be used for the eating house sales counter stone and night billboard etc.In addition, as required, also can add chromogenic reagent, sodium cyanide, tetra-sodium, xitix, lactic acid etc. such as mixing the Tripotassium iron hexacyanide, yellow prussiate of potash.
Coating process to inorganic coloring material water solution is not particularly limited, and is same with the occasion of above-mentioned resist printing coating, can enumerate brush or scraper coating, spraying method, with hand-written method such as writing brush or pen etc.
Also have, the coating of inorganic coloring material water solution must make stone material be under the approximate absolute dry condition, carries out with normal pressure.Stone material during approximate absolute dry condition, moisture about 0.2%～0.4%, during stone material under should approximate absolute dry condition with inorganic coloring material water solution coat, moisture permeates from stone surface, moves to stone material inside.At this moment, as shown in Figure 2, tinting material permeates too and is deep into position, stone material top layer.That is, under this approximate absolutely dry state, by coating inorganic coloring material water solution, because can make inorganic coloring material water solution permeate very deeply, so, can prevent caused abrasion of weathering and decolouring.
In addition, coating inorganic coloring material water solution under normal pressure is owing to be permeable to position, stone material top layer, so as shown in Figures 3 and 4, inorganic coloring material water solution can be evenly and similarly infiltrated into the certain depth at position, top layer.Therefore,, also can often manifest pattern and the literal same originally for a long time with manufacturing even cause the occasion that stone surface peels off in weathering, so, can keep the ornamental of stone material.
Also have,, can enumerate decompression method and heating method as making stone material reach the method for approximate absolute dry condition.Make it reach the occasion of approximate absolute dry condition by heating, its Heating temperature is not particularly limited, but 100 ℃～150 ℃ is ideal.This is because when it was lower than 100 ℃, the moisture of stone material can not fully evaporate, inorganic coloring material water solution can not fully infiltrate into stone material, on the other hand, and when higher than 150 ℃, the inorganic coloring material meeting part color development of infiltration, above-mentioned any situation all is unfavorable.In addition, according to the color of used inorganic coloring material also can the appropriate change stone material Heating temperature, for example, when using the inorganic coloring material of black, surface temperature wishes to reach 125 ℃～145 ℃.
Penetration degree to inorganic coloring material water solution is not particularly limited, as long as make it be penetrated into necessary scope when confirming the infiltration state.But,, fade and variable color because of abrasion probably can cause, so infiltrating into about 20%～30% of stone material thickness usually is ideal if the degree of depth of infiltration is too shallow.
In the present invention, be coated with the operation that this inorganic coloring material water solution makes its infiltration, can carry out to decide the deep or light of color according to its number of times more than 1 time or 2 times.That is, by being coated with repeatedly, permeating, color is thickened, so the concentration of color and penetration range can be regulated arbitrarily.Therefore, can present colorful colors such as impossible color that shows of existing manufacture method and iridescence.Also have, even the number of times of coating, infiltration 1 time is also harmless, but the operation more than 2 times is an ideal.This be because, by operation more than 2 times, inorganic coloring material water solution is fully permeated, can prevent the abrasion that weathering causes more definitely and fade.In addition, carrying out under the situation more than 2 times in coating, infiltration operation, after infiltration, in case stone surface is coated with once more, permeates after being scrubbed or roughly grinding, inorganic coloring material water solution is ideally permeated equably, is ideal.
With aforesaid method make inorganic coloring material water solution coat, the infiltration after, the heating stone material the surface.By this heating, will cause the chemical reactions such as oxidation of the inorganic coloring material that is penetrated into position, stone material top layer, so can make its color development by calcination inorganic coloring material.Also have, Heating temperature will reach 180 ℃～200 ℃.This be because, when being lower than 180 ℃, oxidizing reaction is difficult to carry out, abundant color development, otherwise even be higher than 200 ℃, the degree of oxidizing reaction does not have big variation yet, causes the reason of strength degradation on the contrary, so above-mentioned any situation all is unfavorable.
Behind the inorganic coloring material color development, adopted the resist printing coating of synthetic resins, when the stone surface temperature is in high temperature, with scraper etc., and adopt the resistant of water-soluble paste, after cooling, used high pressure water washing, remove resist printing coating respectively, at last, the surface is imposed attrition process, can obtain decorative stone as shown in Figure 3.Also have,, can enumerate sandblast processing, blowtorch processing, polishing processing etc., but not be particularly limited as attrition process.
Decorative stone with the aforesaid method manufacturing, because inorganic coloring material water solution fully infiltrates into position, stone material top layer, so, because of fading of causing of abrasion, decolouring that Exposure to Sunlight causes are not all worried, and, because inorganic coloring material water solution is penetrated into the certain depth at position, stone material top layer equably, when surfacing cut, also can Chang Jiubao hold originally pattern and literal.In addition, by regulating the number of times of coating, infiltration, deep or light, the iridescence etc. that can present color is colorful, and, can enough low Heating temperatures, under normal pressure, carry out operation, therefore can prevent the reduction of stone material intensity, can cheapness make in large quantities simultaneously.
Secondly, the manufacture method to the 2nd decorative stone of the thermosetting resin suspension liquid that adopts the inorganic coloring material is illustrated.
As the kind of used stone material, can use the stone material same with aforesaid method.Particularly in this method, owing to may be to advance pattern and literal also, therefore owing to have former thereby stone material that utility value is low such as concavo-convex and also can utilize in the surface engraving of stone material.
Therefore thermosetting resin owing to be liquid before the heating, can be easily mixes with inorganic coloring material etc., so preferably used, can enumerate acrylic resin, poly-urethane resin, unsaturated polyester resin etc.
In addition, the inorganic coloring material that in thermosetting resin, suspends, can enumerate with the same metal of aforesaid method be coloured material.In addition, noctilucence body material, solidifying agent, reaction promotors etc. such as luminiferous material and luminous storage material, fluor also can be sneaked into.
Make its curing by the surface that the thermosetting resin suspension liquid of inorganic coloring material is coated on above-mentioned stone material, can present desired pattern and literal.
Coating process to the thermosetting resin suspension liquid of inorganic coloring material is not particularly limited, and can enumerate the method that adopts with the same stamp paper mold of the coating process of above-mentioned inorganic coloring material water solution.In addition, also can carve into desired pattern and literal, pour into a mould above-mentioned suspension liquid at its recess at stone surface.
After with aforesaid method the thermosetting resin suspension liquid of inorganic coloring material being coated stone surface, the heating stone surface.By this heating, thermosetting resin solidifies and anchors at stone material recess and surface, simultaneously, and inorganic coloring material color development.Also have, Heating temperature will reach 180～200 ℃.This be because, when being lower than 180 ℃, thermosetting resin is fully solidified, or the abundant color development of inorganic coloring material, otherwise, even be higher than 200 ℃, the color development degree of the state of cure of thermosetting resin and inorganic coloring material also finds no big variation, the intensity of stone material is reduced, so above-mentioned any situation all is unfavorable.
With the decorative stone that aforesaid method is made, not only can easily make, and, can use various twinklers such as noctilucence body, fluor, silica shape reflective particle, simultaneously not because of the time lapse deterioration and do not lose because of abrasion.
According to embodiment the present invention is described in detail below.But the present invention is not limited by these embodiment.Embodiment 1
Talcum powder 40g, エ ア ロ ジ Le (U.S. サ イ ア ミ De company makes, trade(brand)name) 5g, white lime 15g, vinylbenzene 5g and unsaturated polyester resin RIGOLAC 3045B (Showa Highpolymer Co., Ltd's manufacturing) 35g are mixed, and material is washed in the preparation resist printing.
Iron(ic) chloride 100g and L-xitix 0.1g are dissolved in the water of 191g the inorganic coloring material water solution that preparation is red.
The grouan surface of being processed into square plate is roughly ground, make its drying in 60 ℃, after the cooling, stamp paper mold 2 as shown in Figure 1 is placed on the surface of stone material 1, the resist printing coating above-mentioned preparation is coated with on it with silk screen printing in 30 ℃.Make this stone material drying in 40 ℃, behind the resist printing paint solidification, the stone surface temperature is heated to 80 ℃～100 ℃, the inorganic coloring material water solution of the above-mentioned preparation of coating makes it infiltrate into position, stone material top layer under this state.Repeat this operation 5 times, as shown in Figure 2, make the inorganic coloring material fully infiltrate into stone material after, stone material reheat to 180 ℃～200 ℃, under this state, heating was burnt till 15～20 minutes, sintering inorganic coloring material makes its color development.After the cooling, the surface is imposed attrition process thinly, make decorative stone shown in Figure 3.
The decorative stone of finishing is cut open along the dark A-A line of the surperficial 1.5cm of distance, as shown in Figure 4, presented the pattern same, can confirm that the inorganic coloring material evenly and similarly infiltrates into the position, top layer with the stone surface of Fig. 3.
Iron nitrate 100g and L-xitix 0.1g are dissolved in the water of 185g the inorganic coloring material of preparation reddish-brown.
The andesite surface of being processed into square plate is roughly ground, in 60 ℃ in addition dry, after the cooling,, be fitted on the surface of stone material the stamp paper mold of copying the such maple leaf of Fig. 5, be coated with on it in 30 ℃ of resist printing coating that embodiment 1 is prepared with silk screen printing.Make this stone material in 40 ℃ of dryings, behind the resist printing paint solidification, the surface temperature of stone material is heated to 125 ℃～145 ℃, under this state, be coated with the inorganic coloring material water solution of above-mentioned preparation, make to infiltrate into position, stone material top layer.This operation repeats 5 times, and after the inorganic coloring material fully infiltrated into stone material, stone material reheat to 180 ℃～200 ℃, under this state, heating was burnt till 15～20 minutes, and sintering inorganic coloring material makes its color development.After the cooling, the surface is imposed very thin attrition process, make decorative stone shown in Figure 6.
The decorative stone of finishing is cut open along the dark B-B line of the surperficial 1.5cm of distance, as shown in Figure 7, presented the pattern same, can confirm that the inorganic coloring material evenly and similarly infiltrates into the position, top layer with the stone surface of Fig. 6.
Also have, symbol 5 expressions among Fig. 6 are without the stone surface of any coating, and 6 then represent the stone surface after the coating of inorganic coloring material, the infiltration.
In unsaturated polyester resin 40g, mix and to send red luminescent material 30g and chromium chloride 60g, make the thermosetting resin suspension liquid of inorganic coloring material through uviolizing.
The grouan surface of being processed into square plate is roughly ground,, formed recess at maple leaf shape position, poured into a mould the thermosetting resin suspension liquid of the inorganic coloring material of above-mentioned preparation in this recess by the sandblast etch.This stone material is heated to 180 ℃～200 ℃, and under this state, heating was burnt till 15～20 minutes, made inorganic coloring material color development, simultaneously, thermosetting resin was solidified.The cooling back imposes very thin attrition process to the surface, makes decorative stone shown in Figure 8.
The decorative stone of finishing in bright place, can see green maple leaf, and in the dark, when using the uviolizing of specific wavelength, maple leaf sends then as red autumnal leaves red.
Also have, the stone surface of any coating is not made in symbol 7 expressions among Fig. 8,8 thermosetting resines that contain the inorganic coloring material that solidified of expression then.
Industrial utilizability
As mentioned above, adopt TERRAZZO and the manufacture method thereof that the present invention relates to, can prevent because of the time The variable color that passing causes, and, burn till because needn't carry out high-temperature heating, thereby also can prevent stone material Strength deterioration. In addition, adopt the TERRAZZO of inorganic coloring material water solution, can present the dense of color Light, iridescence is colorful, simultaneously, even cause the occasion that stone surface peels off in weathering etc., also still can Present manufacturing pattern and literal originally, therefore can keep cosmetic value; And employing inorganic coloring material The TERRAZZO of the thermosetting plastics suspension of material is used for having adopted thermosetting plastics, so have durable Property and against weather. Therefore, the TERRAZZO that the present invention relates to can be used for abrasion performance and requirement of strength Higher pavement material and building flooring material, wall material, monument material, coffin stone material, furniture material Deng. In addition, to the weather-resistant properties such as granite are superior but the stone material that decorative value is low can invest decoration The sexual valence value, thus decorative value height, the good TERRAZZO of weather-resistant property can easily be obtained. And And, by cooperating the colour former at night, can make also that luminous stone material is used as by the black light lamp irradiation Drink sales counter stone and the night billboard in shop.
Claims (14)
1. a decorative stone is characterized in that, on the surface of stone material, with the needed pattern of coloured material painting and calligraphy and literal, this pattern and literal by even and similarly painted to the certain degree of depth in position, stone material top layer.
2. a decorative stone is characterized in that, at stone surface, and with containing the coloured material of thermosetting resin, needed pattern of painting and calligraphy and literal and constitute.
3. the manufacture method of a decorative stone, it is characterized in that, make stone material reach approximate absolutely dry state, under this state, use inorganic coloring material water solution at needed pattern of stone surface painting and calligraphy and literal, make the inorganic coloring material water solution of stone surface coating evenly and similarly infiltrate into position, stone material top layer, after this operation is carried out 1 time at least, the stone surface temperature is heated to 180 ℃～200 ℃, makes inorganic coloring material color development, cooling at last, the attrition process surface.
4. decorative stone manufacture method as claimed in claim 3, it is characterized in that, with inorganic coloring material water solution, needed pattern of painting and calligraphy and literal on stone surface, before this inorganic coloring material water solution is carried out toward the infiltration operation of position, top layer, to the not coloured part coating resist printing coating of stone material, and make its curing.
5. as claim 3 or 4 described decorative stone manufacture method, it is characterized in that,, make stone material reach approximate absolute dry condition by heating.
6. as claim 3 or 4 described decorative stone manufacture method, it is characterized in that,, make stone material reach approximate and execute drying regime by decompression.
7. as any one the described decorative stone manufacture method in the claim 3～6, it is characterized in that, as above-mentioned inorganic coloring material water solution, contain the mineral compound more than from Xiao Suangu, iron nitrate, iron(ic) chloride, chromium chloride, potassiumchromate, neutralized verdigris, Tai-Ace S 150, nickelous chloride, aluminum chloride, rose vitriol, Xiao Suangu, Red copper oxide, manganous nitrate, select at least a.
8. as any one the described decorative stone manufacture method in the claim 4～7, it is characterized in that, as above-mentioned resist printing coating, use be to contain the coating that unsaturated polyester resin constitutes.
9. as any one the described decorative stone manufacture method in the claim 4～7, it is characterized in that as above-mentioned resist printing coating use is to contain the coating that water-soluble paste constitutes.
10. as any one the described decorative stone manufacture method in the claim 3～9, it is characterized in that, as above-mentioned inorganic coloring material water solution, employing be to contain from more than one the noctilucence body material of selecting the luminous fluor of twinkler, luminous storage material, little radiation of black lamp irradiation, the silica shape reflective particle.
11. the manufacture method of a decorative stone is characterized in that, at stone surface, with the thermosetting resin suspension liquid of inorganic coloring material, behind needed pattern of painting and calligraphy and the literal, the stone surface temperature is heated to 180～200 ℃, make inorganic coloring material color development, thermosetting resin is solidified.
12. the manufacture method of a decorative stone, it is characterized in that, carve into needed pattern and literal at stone surface, thermosetting resin suspension liquid at the inorganic coloring material is poured into a mould its recess, the stone surface temperature is heated to 180～200 ℃, make inorganic coloring material color development, thermosetting resin is solidified.
13. as claim 11 or 12 described decorative stone manufacture method, it is characterized in that, as the thermosetting resin suspension liquid of above-mentioned inorganic coloring material, be to adopt to contain from the noctilucence body material of selecting the twinkler of black lamp irradiation, luminous storage material, little radiation light-emitting fluophor, the silica shape reflective particle more than a kind.
14. as any one the described decorative stone manufacture method in the claim 11～13, it is characterized in that, as above-mentioned inorganic coloring material, be to use the mineral compound of from Xiao Suangu, iron nitrate, iron(ic) chloride, chromium chloride, potassiumchromate, neutralized verdigris, Tai-Ace S 150, nickelous chloride, cobalt chloride, rose vitriol, Xiao Suangu, Red copper oxide, manganous nitrate, selecting more than one at least.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/JP1999/002958 WO2000075090A1 (en) | 1999-06-02 | 1999-06-02 | Decorative stone and production method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1352626A true CN1352626A (en) | 2002-06-05 |
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ID=14235876
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN99816707.XA Pending CN1352626A (en) | 1999-06-02 | 1999-06-02 | Decorative stone and production method thereof |
Country Status (3)
| Country | Link |
|---|---|
| CN (1) | CN1352626A (en) |
| IT (1) | IT1311801B1 (en) |
| WO (1) | WO2000075090A1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITUB20159787A1 (en) * | 2015-12-30 | 2017-06-30 | Univ Degli Studi Genova | Surface finishing method of porous stone materials and product thus obtained |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5269428A (en) * | 1975-12-09 | 1977-06-09 | Nippon Kagaku Sangyo Kk | Method of coloring surface of concrete articles |
| DE3305549A1 (en) * | 1983-02-18 | 1984-08-23 | Schering AG, 1000 Berlin und 4709 Bergkamen | METHOD FOR COATING ARTIFICIAL OR NATURAL STONE BOARDS |
| JPS62252384A (en) * | 1986-04-17 | 1987-11-04 | 李 錫柱 | Method of coloring granite stone material |
| JPH0330349U (en) * | 1989-08-01 | 1991-03-26 | ||
| JPH067998U (en) * | 1992-01-24 | 1994-02-01 | 飛鳥計画株式会社 | Rock display |
-
1999
- 1999-06-02 CN CN99816707.XA patent/CN1352626A/en active Pending
- 1999-06-02 WO PCT/JP1999/002958 patent/WO2000075090A1/en active Search and Examination
- 1999-10-19 IT IT1999VE000041A patent/IT1311801B1/en active
Also Published As
| Publication number | Publication date |
|---|---|
| ITVE990041A1 (en) | 2001-04-19 |
| WO2000075090A1 (en) | 2000-12-14 |
| IT1311801B1 (en) | 2002-03-19 |
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
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