CN1342625A - Biological organic water flush fertilizer - Google Patents

Biological organic water flush fertilizer Download PDF

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Publication number
CN1342625A
CN1342625A CN 01133323 CN01133323A CN1342625A CN 1342625 A CN1342625 A CN 1342625A CN 01133323 CN01133323 CN 01133323 CN 01133323 A CN01133323 A CN 01133323A CN 1342625 A CN1342625 A CN 1342625A
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fertilizer
sulfate
bone mud
soil
ammonium humate
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王玉兰
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Abstract

A biological organic fertilizer for irrigation is prepared from ammonium humate (20-27 wt.%), acidified bone mud (22-28), urea (22-28), diamine (7.2-7.8), potassium sulfate (13-19), borax (0.3-0.7), zinc sulfate (7-13), magnesium sulfate (0.3-0.7), manganese sulfate (0.3-0.7), copper sulfate (0.03-0.07), sodium molybdate (0.03-0.07) and bacterial agent (3-7) through proportional mixing, and features high fertility, comprehensive nutrients and sufficient nutrients. The water flush solubility is good, the water flush type fertilizer is particularly suitable for being applied to mulching film-covered farming lands, the nutrient utilization rate is high, and crops can be fully utilized and absorbed. The biological activity is high, the nutrition conversion function and the soil activation efficiency are high, the organic matter content is high, and the soil improvement effect can be achieved.

Description

A kind of bio-organic fertilization fertilizer
Technical field:
The invention belongs to a kind of fertilizer, the organic compound fertilising of dashing of particularly a kind of biology.
Background technology:
Chemical fertilizer is generally used in the agriculture production of China at present aspect fertilising, though it has increased the output of farm crop, but long-term a large amount of the use caused the hardening soil, and soil property constantly worsens, and soil fertility descends, the agricultural prods quality descends, simultaneously, using in a large number of fertilizer and pesticide also pollutes soil and water source, and the harm people are healthy, destroy existent environment of people, become people's common recognition.Some agriculture developed countries have been proposed in as countries such as the U.S., Canada, Japan, Germany and no longer to use chemical fertilizer in a short time, and China Taiwan also proposes to separate after 5 years and will never produce and use chemical fertilizer.The USDA prediction; " chemistry agricultural " present to 21 century will be replaced by " biological husbantry "; Japanese government is in recent years in view of the safety of food and its people's health; determined complete " the tractor-ploughing farming is arranged " method; aspect fertilising; correct the road of single administration chemical fertilizer; so early several years ago, the chemical fertilizer that Japan produces is used seldom home; and export to agriculture underdeveloped country in a large number; it seems and reduce a kind of protection environment of development and pollute, strengthen soil fertility; improve crop yield and quality, promote that the novel source of manure of human health is imperative.And bio-fertilizer is the vital movement by microorganism, makes farm crop obtain specific fertilizer effect, makes its growth healthy and strong, and then output is increased; when improving crop yield, also improve the quality of farm crop, strengthen soil fertility; the protection environment reduces and pollutes, and is ideal a new generation source of manure.Along with the rise and the development of " green agriculture ", the position of bio-fertilizer and effect cause the attention of countries in the world day by day, are acknowledged as once " Green Revolution " that world agriculture is produced.The development of China's bio-feritlizer has long history, China brings into use root nodule fertilizer from nineteen fifty, nineteen fifty-two, vinelandii fertilizer brought into use, brought into use phosphorus bacteria fertilizer in 1954,1979 " Beijing Agricultural University " utilizes endophyte of plant to make novel yield increasing fungus fertilizer, thereby the bio-feritlizer of China is advanced to status advanced in the world.Afterwards, the bio-feritlizer that Peking University, Shandong University, Nanjing University do (integrating solid bacterial manure, magnetic is given birth to fertilizer, biological organic-inorganic polyvalent is counted composite fertilizer) all differ from one another.Production technology occupies the leading level in the world.Along with the reach of science, agriculture production also realizes scientific farming, most of area is the northern area of China especially, temperature is lower, in order to improve ground temperature, employing membrane covering plantation, general common ditch spread, the fertilizing method of spreading manuer in holes exist the problem that a use is restricted, promptly increase labor capacity, time-consuming, most of in recent years area, especially northern area, the cultivation of vegetables nearly all is a covering with plastic film, and the fertilising of fertilizer just is greatly limited (peasant can not go large-area mulch film is smash fertilising) like this.So a kind of novel dashing that can be suitable for mulching film planting of peasant's an urgent demand executed type fertilizer, so occurred many fertilisings of dashing on the market, but these mostly are that chemical fertilizer dashes fertilising towards fertilising, also do not have real bio-organic fertilization fertilizer at present.Though prior biological fertilizer fertilizer efficiency is good, the soil that do not harden, free from environmental pollution; active strong, increase soil fertility fertile thing; be that " green agriculture " produces fertilizer; but owing to bio-organic fertilizer, organic component height, poor solubility can not be done to dash and execute; like this at the cultivated land of overlay film; especially biological organic fertilizer be promoted and be used to vegetable protecting field can not, had a strong impact on the development of green agriculture.Therefore modern agriculture demands urgently providing a kind of novel bio-organic fertilization fertilizer to satisfy the demands.
Summary of the invention:
The purpose of this invention is to provide a kind of is the active bio organic fertilization fertilizer, the fertilizer efficiency height, and comprehensive nutrition can be supplied with the crop sufficient nutrient.Good towards executing solubleness, be particularly suitable for using of overlay film cultivated land, the plant recovery of nutrient height can utilize and absorb crop fully.The biological activity height has higher nutrition transformation function and activating soil usefulness, and the organic content height can reach the effect of improving the soil.
Purpose of the present invention is achieved through the following technical solutions: select for use organic materials such as the brown coal that are rich in humic acid and rich phosphorated bone mud to make the main raw material(s) of this product, these starting material are the best fertilizer of farm crop, the effect of well improving the soil is arranged again simultaneously, but these organism all are to belong to the indissoluble material, can not well be absorbed by crop and utilize,, above-mentioned starting material are handled so adopt chemical process, brown coal are carried out ammonification handle, make it generate solubility humic acid amide; Bone mud through acidification, changes into the unavailable phosphorus of crop and can utilize attitude phosphorus, and the nutrient of material more than 90% of handling by above method can both be absorbed by crop, even 10% residue is also very fast by the biological bacteria Degradation and Transformation, is made for thing and absorbs.
For the optimum regime that guarantees that crop absorption is utilized, this technical recipe is taked organic and inorganic combining, long-acting and the quick-acting principles that combine, again according to crop to the needs of nutrition and the physicochemical character of physiological characteristic and soil, carry out scientific and reasonable proportioning, to satisfy the needs of crop to all nutrition and element.
For activity and the physicochemical character that improves soil, crop can better be absorbed and utilization the nutrition in the soil, promote the better growth of crop, utilize biological engineering method screening high-activity biological bacterium, the present invention adopts isolating colloid bacillus cereus Bacillus mucilaginosus Krassilnikov Accc10012 (the bacterial classification center preservation of Beijing Institute of Micro-biology) from the soil sample that rich soil is gathered, colony morphology characteristic: single bacterium colony is positive circle, neat in edge, smooth surface is moistening, water white transparency, glossy, projection is big, the dense thick high resilience of lawn, tractive haircuts when inoculating needle is provoked.A little less than growth on the nitrogenous substratum, slower, less and muddy being creamy white of lawn followed the string and the haircuts shape.The individual morphology feature: colloid bacillus cereus bacterium elongated rod shape, the blunt circle in two ends, the long 4-7 micron of thalline, wide 1 micron, the folder film that cell outsourcing one deck is very thick has layer 2-3, and is together with folder film duration 7-10 micron, wide to the 5-6 micron.The transformation efficiency of bacterium potassium is more than 31%, more than various soil potassium decomposing 500mg/ kilograms.The production bacterial classification of this product no matter pure culture, the test of soil conversion strength and in different soils the mensuration of ability of dissolving potassium, all showed stronger activity and function, be better than all that other is similar.And this bacterial strain also has the stronger fixed nitrogen and the active function of phosphorus decomposing, so this bacterial classification makes this product more show the high reactivity effect of fertilizer in fertilizer efficiency as the function yeast of this fertilizer.Being different from other fertilizer main characteristics towards fertilising is solubility, but most of organic material solubleness is all poor, even some indissoluble and insoluble.The present invention increases concentration with chemical high concentrated acid solution, ammoniation process and increases the absorption rate of crop, improves organic quick-acting.
The component and the part by weight of prescription are: ammonium humate 20-27, acidifying bone mud 22-28, urea 22-28, diamines 7.2-7.8, vitriolate of tartar 13-19, borax 0.3-0.7, zinc sulfate 7-13, sal epsom 0.3-0.7, manganous sulfate 0.3-0.7, copper sulfate 0.03-0.07, copper acid sodium 0.03-0.07, microbial inoculum 3-7;
Production technique is:
1, utilize colloid bacillus cereus to produce microbial inoculum according to existing production technique;
2, preparation ammonium humate: nitre coal and bicarbonate of ammonia are pressed 3.5-4.5: 1 mixed, add 15-25% water, and the back that is mixed keeps 20-25 ℃ under the condition of sealing, form water-soluble ammonium humate after ammonification 10-12 days;
3, the acidification of bone mud: select the bone mud of phosphorus content more than 20% for use, the dilute sulphuric acid of bone mud and 20-30% concentration is in 2-4: after 1 ratio stirred and is mixed, PH reached 5-6, be incubated after 48 hours, and available phosphorus can reach 80-90%, and oven dry back mistake 60 mesh sieves are stand-by;
4, ammonium humate, acidifying bone mud, urea, diamines, vitriolate of tartar, borax, zinc sulfate, sal epsom, manganous sulfate, copper sulfate, copper acid sodium and microbial inoculum stirred in proportion after, packing.
The present invention has following advantage:
1, the technology of the present invention has solved bio-organic fertilizer and can not dash the use problem of executing, and uses simply, and is time saving and energy saving, when watering to farm crop, directly dashes and executes, and just can reach good effect.It not only has the long-lasting of farm organic fertilizer, also has the active of bio-fertilizer, and fertilizer efficiency is fast, nutrition is complete, for canopy kind vegetables and overlay film the source of manure easily is provided efficiently, make peasant household use bio-organic fertilizer more easily, for bright prospects have been opened up in the application of bio-fertilizer.
2, improve the physicochemical character of Soil structure, soil, the permeability that keeps soil, soil does not harden, help microbial growth in the absorption of plant and the soil, life-time service has increases soil fertility, fertile ground, increases the function of organic content, can improve the comprehensive action of soil Zhong Shui, fertilizer, gas, heat and make Soil structure keep benign cycle, not only increase soil fertility but also can alleviate chemical fertilizer to the acidifying of soil, the harm of alkalizing, hardening.Nuisanceless pollution-free, be the best fertilizer that green agriculture is produced.
3, the fertilizer efficiency aspect is better than or equals other bio-feritlizer, but use and effect on than other bio-feritlizer use face width, convenient and simple, save labor.It has promptly possessed the advantage of biological organic fertilizer, has possessed the advantage of chemical fertilizer again, has overcome their shortcoming simultaneously again, and it relatively sees Table 5.
4, proportioning is scientific and reasonable, comprehensive nutrition, fully satisfies the needs of crop to various nutrition and element.
5, effect of increasing production is obvious, fertilizer efficiency period is long, fertilizer efficiency is fast, this fertilizer in recent years in Liaoning, Shenyang, Dalian, Dandong, Anshan, Haicheng City, Xiuyan, Shandong, Linyi, area, Shouguang, carried out large-area test, effect of increasing production is obvious, and amount of increase in production is increased production about 10-20% (seeing Table 1,2,3,4) than other fertilizer.
6, on crop obviously performance emerge strong, stem is thick, blade thick green, bloom early, the setting percentage height, precocious in advance.
7, improve the crop product quality, can improve sugar degree, particularly the fruits crop.Can increase pol 0.5-1%, and the crop products flavor is dense, mouthfeel is good, the quality product height.
8, improve disease resistance, resistant to lodging and good stress resistance.
Table 1 biological defense fertilization of the present invention and diamines are to the comparison of cucumber growing way and output
Contrast 0.08 ?3.7 ????47 ????3.8 ?397
Table 2 biological defense fertilization of the present invention and bio-fertilizer, diamines are gathered rate ratio to the tomato different treatment each period
The kilogram 19.3M of unit 2
Figure A0113332300081
Table 3 biological defense fertilization of the present invention and bio-fertilizer, diamines are to the influence of eggplant output
Handle 0.5 mu of output kilogram Amount to per mu yield kilogram mu Volume increase kilogram mu Stimulation ratio (%)
The present invention ??2.732 ??5.464 ??940 ??20.78
Bio-fertilizer (real board of Shandong autumn) ??2.647 ??5.294 ??770 ??17.02
The phosphoric acid diamines ??2.262 ??4.524
Table 4 biological defense fertilization and bio-fertilizer, diamines are to the influence of eggplant plant
Handle Plant height Internode The flower amount Color and luster The fruit number
The present invention 1.2 rice Short Many Light Many
Bio-fertilizer (real board of Shandong autumn) 1.2 rice Short Many Light Many
The phosphoric acid diamines 1.2 rice Long Few Light Few relatively
Table 5 biological defense fertilization of the present invention and other class fertilizer are relatively
The fertilizer characteristics The present invention Bio-fertilizer Chemical fertilizer dashes fertilising
Effect of increasing production More than the 20-30% More than the 20-30% About 20%
Organic composition ????50 ????50 Do not have
Nutrient Full nutrition Full nutrition Full nutrition
Quick-acting By force Difference By force
Long-lasting Good Good Difference
Solvability Good Difference Good
Fertilizing method Dash execute, spread manuer in holes, ditch spread Spread manuer in holes, ditch spread Dash execute, spread manuer in holes, ditch spread
Crop growing state Thick, the plant height of thick green, the stem of blade Thick, the plant height of thick green, the stem of blade Blade is thin thin
Bloom 7-8 days ahead of time 7-8 days ahead of time
The result High precocious 7-8 days of percentage of fertile fruit
Farming product quality Good Good
Mouthfeel Good Good Light, puckery
Sugar degree Office High Low
Disease resistance By force By force Difference
Resistance By force By force Difference
Improve the soil Good Good Do not have
Destroy soil Do not have Do not have By force
Contaminate environment Do not have Do not have
Embodiment:
1, produce microbial inoculum:
(1) at first the original strain of silicate colloid genus bacillus is activated, the original strain switching on nitrogen-free agar, after cultivating 48 hours under the 26-30 ℃ of temperature, is treated that lawn is plentiful, no living contaminants is as shake-flask seed.
(2) will activate good bacterial classification inoculation in shake-flask culture liquid, and 26-30 ℃ of vibration (reciprocating type shaking table 110 times/minute) down, cultivate after 24 hours, microscopy does not have assorted bacterium, as fermented bacterium.Loading amount: 300-1000 milliliter triangular flask, the kind amount: a slant strains is inoculated three bottles.
(3) submerged fermentation: carry out the first order seed fermentation, the seed that above-mentioned shake-flask culture is good, inoculum size by 5% inserts in the 50 liter seeding tanks, 26-30 ℃ of bottom fermentation 24 hours, microscopy does not have living contaminants and changes in the secondary 500 liter seeding tanks, ferments after 24 hours, does not have living contaminants through microscopy, growth is vigorous, promptly changes fermentor tank over to and ferments.Fermentation condition: air flow is 1: 0.5, and stir: 230 rev/mins, temperature is 26-30 ℃, fermentation period: 48 hours.After the fermentation ends, look bacterium liquid thickness, faint yellow no stink, blood counting is more than 1,200,000,000.
(4) absorption of bacterium liquid: the above-mentioned bacterium liquid that will ferment is that 1 part of brown coal is 5 parts and mixes, the back packing that stirs, and the shady and cool place's preservation of seasoning is used in order to producing.More than the product of Sheng Chaning is a microbial inoculum, and its bacterial classification content is more than 200,000,000/gram.
Above-mentioned spawn culture based formulas: sucrose: 10.0 gram dipotassium hydrogen phosphates: 0.2 gram sal epsom: 0.2 gram sodium-chlor: 0.2 gram lime carbonate: 5.0 gram calcium sulfate: 0.1 gram agar: 15 gram water: 1000 milliliters of PH:7.4
Above-mentioned I and II seed tank culture based formulas: sucrose: 1% dipotassium hydrogen phosphate: 0.2 sal epsom: 0.02 sodium-chlor: 0.2% lime carbonate: 5.0% calcium sulfate: 0.01%PH 7.4
Above-mentioned fermentative medium formula: starch: 0.5% sulfate of ammoniac: 0.1% dipotassium hydrogen phosphate: 0.2% iron trichloride: 0.02% lime carbonate: 0.01% yeast decoction: 0.02%PH:7.4
2, brown coal ammonium processing: nitre coal and bicarbonate of ammonia are pressed 4: 1 mixed, add 20% water, and the back that is mixed keeps 20-25 ℃ under the condition of sealing, form water-soluble ammonium humate after ammonification 10-12 days.
3, the acidification of bone mud: select phosphorus content 20% above bone mud for use, after being mixed after the dilute sulphuric acid of bone mud and 25% concentration stirs in 3: 1 ratio, PH reaches 5-6, be incubated after 48 hours, and available phosphorus can reach 80-90%, and oven dry back mistake 60 mesh sieves are stand-by.
4, composition is taken by weighing by following part by weight and mixes, after stirring, qualified after testing after, pack warehouse-in.Composition proportion is as follows:
Ammonium humate 24, acidifying bone mud 25, urea 25, diamines 7.5,
Vitriolate of tartar 16, borax 0.50, zinc sulfate 10, sal epsom 0.5,
Manganous sulfate 0.5, copper sulfate 0.05, Sodium orthomolybdate 0.05, microbial inoculum 5.
Its technical requirements and index: this product appearance is the gray powder powder darkly, and is nontoxic.Total nutrient nitrogen phosphorus potassium 〉=25%, organic content 〉=30%, humic acids content 〉=15%, living bacteria count 〉=0.3 hundred million/gram, pH value 6-7

Claims (1)

1, a kind of bio-organic fertilization fertilizer is characterized in that the component and the part by weight of filling a prescription are: ammonium humate 20-27, acidifying bone mud 22-28, urea 22-28, diamines 7.2-7.8, vitriolate of tartar 13-19, borax 0.3-0.7, zinc sulfate 7-13, sal epsom 0.3-0.7, manganous sulfate 0.3-0.7, copper sulfate 0.03-0.07, Sodium orthomolybdate 0.03-0.07, microbial inoculum 3-7;
Production technique is:
(1), utilize colloid bacillus cereus to produce microbial inoculum according to existing production technique;
(2), the preparation ammonium humate: nitre coal and bicarbonate of ammonia press 3.5-4.5: 1 mixed, add 15-25% water, be mixed the back the sealing condition under the maintenance 20-25 ℃, after ammonification 10-12 days formation water-soluble ammonium humate;
(3), the acidification of bone mud: select the bone mud of phosphorus content more than 20% for use, the dilute sulphuric acid of bone mud and 20-30% concentration is in 2-4: after 1 ratio stirred and is mixed, PH reached 5-6, be incubated after 48 hours, and available phosphorus can reach 80-90%, and oven dry back mistake 60 mesh sieves are stand-by;
(4), ammonium humate, acidifying bone mud, urea, diamines, vitriolate of tartar, borax, zinc sulfate, sal epsom, manganous sulfate, copper sulfate, Sodium orthomolybdate and microbial inoculum stirred in proportion after, packing.
CN 01133323 2001-10-22 2001-10-22 Biological organic water flush fertilizer Pending CN1342625A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1301938C (en) * 2005-04-11 2007-02-28 张保善 Mixed biological fertilizer for agricultural crops
CN1325440C (en) * 2006-03-12 2007-07-11 马娟利 Humic acid-ammonium phosphate organic fertilizer
CN100486941C (en) * 2007-02-12 2009-05-13 山东省农业科学院土壤肥料研究所 Whole-nutrition biological flushing and spreading fertilizer and preparation method thereof
CN103319285A (en) * 2013-07-08 2013-09-25 刘怀琚 Water flush fertilizer for greenhouses
CN106905011A (en) * 2015-12-22 2017-06-30 沈阳天丰农业科技有限公司 A kind of biomass organic fertilization fertilizer
CN108976092A (en) * 2018-10-26 2018-12-11 河南天赐鼎立农业科技有限公司 A kind of functional form humic acid water-soluble fertilizer and preparation method thereof containing complex microorganism

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1301938C (en) * 2005-04-11 2007-02-28 张保善 Mixed biological fertilizer for agricultural crops
CN1325440C (en) * 2006-03-12 2007-07-11 马娟利 Humic acid-ammonium phosphate organic fertilizer
CN100486941C (en) * 2007-02-12 2009-05-13 山东省农业科学院土壤肥料研究所 Whole-nutrition biological flushing and spreading fertilizer and preparation method thereof
CN103319285A (en) * 2013-07-08 2013-09-25 刘怀琚 Water flush fertilizer for greenhouses
CN103319285B (en) * 2013-07-08 2015-02-18 刘怀琚 Water flush fertilizer for greenhouses
CN106905011A (en) * 2015-12-22 2017-06-30 沈阳天丰农业科技有限公司 A kind of biomass organic fertilization fertilizer
CN108976092A (en) * 2018-10-26 2018-12-11 河南天赐鼎立农业科技有限公司 A kind of functional form humic acid water-soluble fertilizer and preparation method thereof containing complex microorganism

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