CN1314715C - 改进对树脂性能的控制 - Google Patents

改进对树脂性能的控制 Download PDF

Info

Publication number
CN1314715C
CN1314715C CNB038231891A CN03823189A CN1314715C CN 1314715 C CN1314715 C CN 1314715C CN B038231891 A CNB038231891 A CN B038231891A CN 03823189 A CN03823189 A CN 03823189A CN 1314715 C CN1314715 C CN 1314715C
Authority
CN
China
Prior art keywords
reaction temperature
resin flow
polyolefin
target
temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CNB038231891A
Other languages
English (en)
Chinese (zh)
Other versions
CN1684987A (zh
Inventor
J·R·帕里什
I·J·哈特利
L·L·潘松
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Chemicals and Plastics Technology LLC
Univation Technologies LLC
Original Assignee
Union Carbide Chemicals and Plastics Technology LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Chemicals and Plastics Technology LLC filed Critical Union Carbide Chemicals and Plastics Technology LLC
Publication of CN1684987A publication Critical patent/CN1684987A/zh
Application granted granted Critical
Publication of CN1314715C publication Critical patent/CN1314715C/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2400/00Characteristics for processes of polymerization
    • C08F2400/02Control or adjustment of polymerization parameters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901Monomer polymerized in vapor state in presence of transition metal containing catalyst

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CNB038231891A 2002-09-27 2003-07-28 改进对树脂性能的控制 Expired - Lifetime CN1314715C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/259,094 2002-09-27
US10/259,094 US6846884B2 (en) 2002-09-27 2002-09-27 Control of resin properties

Publications (2)

Publication Number Publication Date
CN1684987A CN1684987A (zh) 2005-10-19
CN1314715C true CN1314715C (zh) 2007-05-09

Family

ID=32029427

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB038231891A Expired - Lifetime CN1314715C (zh) 2002-09-27 2003-07-28 改进对树脂性能的控制

Country Status (8)

Country Link
US (1) US6846884B2 (enExample)
EP (1) EP1546220A1 (enExample)
JP (1) JP2006500458A (enExample)
CN (1) CN1314715C (enExample)
BR (1) BR0314484B1 (enExample)
CA (1) CA2499233A1 (enExample)
WO (1) WO2004029108A1 (enExample)
ZA (1) ZA200502327B (enExample)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7125933B2 (en) * 2000-06-22 2006-10-24 Univation Technologies, Llc Very low density polyethylene blends
AR048828A1 (es) * 2004-04-13 2006-05-31 Union Carbide Chem Plastic Uso de un fraccionamiento instantaneo para mejorar el control del reactor
US7683140B2 (en) * 2004-05-20 2010-03-23 Univation Technologies, Llc Method for determining temperature value indicative of resin stickiness from data generated by polymerization reaction monitoring
US7754830B2 (en) * 2004-05-20 2010-07-13 Univation Technologies, Llc Polymerization reaction monitoring with determination of induced condensing agent concentration for preventing discontinuity events
EP1805229A1 (en) 2004-10-28 2007-07-11 Dow Gloval Technologies Inc. Method of controlling a polymerization reactor
US7321015B2 (en) * 2004-12-07 2008-01-22 Nova Chemicals (International) S.A. Adjusting polymer characteristics through process control
US7323523B2 (en) * 2004-12-07 2008-01-29 Nova Chemicals (International) S.A. Adjusting polymer characteristics through process control
US7343225B2 (en) * 2005-06-03 2008-03-11 Univation Technologies, Llc Method for reducing off-grade product production during reaction transitions
EP1840140A1 (en) * 2006-03-30 2007-10-03 Total Petrochemicals Research Feluy Method for making a transition between polymer grades
CN101511877B (zh) * 2006-09-07 2012-09-05 尤尼威蒂恩技术有限责任公司 由聚合反应监测产生的数据确定指示树脂粘附的温度值的方法
CN101511882B (zh) * 2006-09-07 2011-09-21 尤尼威蒂恩技术有限责任公司 使用降低熔融起始温度的模型在线测定树脂粘着性程度的方法
AU2006348445B2 (en) * 2006-09-21 2011-03-10 Union Carbide Chemicals & Plastics Technology Llc Method of controlling properties in multimodal systems
WO2008076386A1 (en) * 2006-12-18 2008-06-26 Univation Technologies, Llc Method for reducing and/or preventing production of excessively low density polymer product during polymerization transitions
IN2012DN02132A (enExample) 2009-12-18 2015-08-21 Univation Tech Llc
MX2015003054A (es) 2012-09-07 2016-04-28 Univation Tech Llc Controlar una reaccion de poliolefina.
WO2014039522A1 (en) 2012-09-07 2014-03-13 Univation Technologies, Llc A method for determining a stickiness temperature of a resin
US8986618B2 (en) * 2013-06-28 2015-03-24 Ineos Usa, Llc System and method for rapid transitioning of polyolefin processes from one product to another
EP2995635A1 (en) * 2014-09-11 2016-03-16 Sulzer Chemtech AG Method to minimize the transition time from one polymer grade to another polymer grade in a polymerization plant
CA3044897A1 (en) * 2016-11-28 2018-05-31 Univation Technologies, Llc Producing a polyethylene polymer
CN107098991B (zh) * 2017-04-11 2019-04-16 浙江大学 一种烯烃聚合方法及装置
WO2020160078A1 (en) * 2019-01-31 2020-08-06 Dow Global Technologies Llc Process control

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5627242A (en) * 1996-03-28 1997-05-06 Union Carbide Chemicals & Plastics Technology Corporation Process for controlling gas phase fluidized bed polymerization reactor
US6300429B1 (en) * 1998-12-31 2001-10-09 Union Carbide Chemicals & Plastics Technology Corporation Method of modifying near-wall temperature in a gas phase polymerization reactor

Family Cites Families (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4076698A (en) * 1956-03-01 1978-02-28 E. I. Du Pont De Nemours And Company Hydrocarbon interpolymer compositions
US5106806A (en) * 1990-10-18 1992-04-21 Shell Oil Company Olefin polymerization catalyst
NL130577C (enExample) * 1964-07-17
CA849081A (en) * 1967-03-02 1970-08-11 Du Pont Of Canada Limited PRODUCTION OF ETHYLENE/.alpha.-OLEFIN COPOLYMERS OF IMPROVED PHYSICAL PROPERTIES
US3485706A (en) * 1968-01-18 1969-12-23 Du Pont Textile-like patterned nonwoven fabrics and their production
US4314912A (en) * 1977-02-03 1982-02-09 The Dow Chemical Company High efficiency, high temperature catalyst for polymerizing olefins
US4302565A (en) * 1978-03-31 1981-11-24 Union Carbide Corporation Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization
US4482687A (en) * 1979-10-26 1984-11-13 Union Carbide Corporation Preparation of low-density ethylene copolymers in fluid bed reactor
US4340563A (en) * 1980-05-05 1982-07-20 Kimberly-Clark Corporation Method for forming nonwoven webs
US4322027A (en) * 1980-10-02 1982-03-30 Crown Zellerbach Corporation Filament draw nozzle
US4413110A (en) * 1981-04-30 1983-11-01 Allied Corporation High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore
US4540755A (en) * 1982-09-30 1985-09-10 National Petro Chemicals Corporation Inclusion of oxygen in the polymerization of olefins
US4937299A (en) * 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
US4547475A (en) * 1984-09-07 1985-10-15 The Dow Chemical Company Magnesium halide catalyst support and transition metal catalyst prepared thereon
US4619980A (en) * 1985-04-01 1986-10-28 Phillips Petroleum Company Polymerization catalyst, method of making and use therefor
US4612300A (en) * 1985-06-06 1986-09-16 The Dow Chemical Company Novel catalyst for producing relatively narrow molecular weight distribution olefin polymers
US4663220A (en) * 1985-07-30 1987-05-05 Kimberly-Clark Corporation Polyolefin-containing extrudable compositions and methods for their formation into elastomeric products including microfibers
US4668566A (en) * 1985-10-07 1987-05-26 Kimberly-Clark Corporation Multilayer nonwoven fabric made with poly-propylene and polyethylene
US4668838A (en) * 1986-03-14 1987-05-26 Union Carbide Corporation Process for trimerization
US4735931A (en) * 1986-06-16 1988-04-05 Phillips Petroleum Company In situ comonomer generation in olefin polymerization
US5473027A (en) * 1986-06-20 1995-12-05 Chevron Chemical Company Production of blow molding polyethylene resin
US4804714A (en) * 1987-11-20 1989-02-14 Union Carbide Corporation Polyolefin blends
FR2646426B2 (fr) * 1988-09-13 1991-08-16 Bp Chemicals Sa Procede et appareillage de polymerisation d'alpha-olefine en phase gazeuse en presence d'un agent ralentisseur d'activite
US5115068A (en) * 1988-09-26 1992-05-19 Phillips Petroleum Company High strength linear, low density ethylene copolymer
US5244987A (en) * 1988-12-22 1993-09-14 Bf Chemicals Limited Process for alpha-olefin gas-phase polymerization controlled by the simultaneous addition of an activator and an activity retarder to the polymerization medium
US5218071A (en) * 1988-12-26 1993-06-08 Mitsui Petrochemical Industries, Ltd. Ethylene random copolymers
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US6188178B1 (en) * 1990-05-24 2001-02-13 U.S. Philips Corporation Flat-panel picture display device with spacer means adjacent the display screen
US5191521A (en) * 1990-06-18 1993-03-02 Controlsoft, Inc. Modular multivariable control apparatus and method
US5272236A (en) * 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
ES2071888T3 (es) * 1990-11-12 1995-07-01 Hoechst Ag Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas.
US5189192A (en) * 1991-01-16 1993-02-23 The Dow Chemical Company Process for preparing addition polymerization catalysts via metal center oxidation
US5231151A (en) * 1991-01-18 1993-07-27 The Dow Chemical Company Silica supported transition metal catalyst
US5137994A (en) * 1991-05-23 1992-08-11 Union Carbide Chemicals & Plastics Technology Corporation Process for the simultaneous trimerization and copolymerization of ethylene
TW300901B (enExample) * 1991-08-26 1997-03-21 Hoechst Ag
US5783638A (en) * 1991-10-15 1998-07-21 The Dow Chemical Company Elastic substantially linear ethylene polymers
US5677383A (en) * 1991-10-15 1997-10-14 The Dow Chemical Company Fabricated articles made from ethylene polymer blends
US5525695A (en) * 1991-10-15 1996-06-11 The Dow Chemical Company Elastic linear interpolymers
US5278272A (en) * 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
ATE141609T1 (de) * 1991-11-30 1996-09-15 Hoechst Ag Metallocene mit benzokondensierten indenylderivaten als liganden, verfahren zu ihrer herstellung und ihre verwendung als katalysatoren
EP0574561B1 (en) * 1992-01-06 1998-01-28 The Dow Chemical Company Improved catalyst composition
US5374696A (en) * 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
KR950701650A (ko) 1992-05-29 1995-04-28 리차드 에이. 크렛취머 알파-올레핀의 중합방법(Polymerization of alpha-olefins)
US5317036A (en) * 1992-10-16 1994-05-31 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization reactions utilizing soluble unsupported catalysts
US5608019A (en) * 1992-12-28 1997-03-04 Mobil Oil Corporation Temperature control of MW in olefin polymerization using supported metallocene catalyst
CZ288678B6 (cs) * 1993-01-29 2001-08-15 The Dow Chemical Company Způsob přípravy ethylen/alfa-olefinových interpolymerních kompozic
US5470993A (en) * 1993-06-24 1995-11-28 The Dow Chemical Company Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom
US6111020A (en) * 1994-09-02 2000-08-29 The Dow Chemical Company Crosslinked foams from blends of ethylene vinyl acetate and ethylene-styrene interpolymers
US5869575A (en) * 1995-08-02 1999-02-09 The Dow Chemical Company Ethylene interpolymerizations
US6135953A (en) 1996-01-25 2000-10-24 3M Innovative Properties Company Multi-functional biomedical electrodes
US5977251A (en) * 1996-04-01 1999-11-02 The Dow Chemical Company Non-adiabatic olefin solution polymerization
US5844054A (en) * 1997-03-21 1998-12-01 Samples; Paul Kevin Process control in the presence of chromium based catalysts
US5990250A (en) * 1997-05-30 1999-11-23 Union Carbide Chemicals & Plastics Technology Corporation Method of fluidized bed temperature control
US6063877A (en) * 1997-07-31 2000-05-16 Union Carbide Chemicals & Plastics Technology Corporation Control of gas phase polymerization reactions
CN1273592A (zh) * 1997-08-27 2000-11-15 陶氏化学公司 α烯烃与乙烯基芳族单体的共聚物的流变改性方法
WO1999046327A1 (en) * 1998-03-11 1999-09-16 The Dow Chemical Company STRUCTURES AND FABRICATED ARTICLES HAVING SHAPE MEMORY MADE FROM α-OLEFIN/VINYL OR VINYLIDENE AROMATIC AND/OR HINDERED ALIPHATIC VINYL OR VINYLIDENE INTERPOLYMERS
KR100551782B1 (ko) * 1998-03-11 2006-02-13 다우 글로벌 테크놀로지스 인크. 알파-올레핀/비닐 또는 비닐리덴 방향족 및/또는 장애 지환족 또는 지방족 비닐 또는 비닐리덴 인터폴리머로부터 제조된 섬유
BR9803848A (pt) 1998-10-08 2000-10-31 Opp Petroquimica S A Sistema para inferência em linha de propriedades fìsicas e quìmicas, sistema para inferência em linha de variáveis de processo, e, sistema de controle em linha
US6384157B1 (en) * 2000-05-16 2002-05-07 Union Carbide Chemicals & Plastics Technology Corporation Method of detecting and correcting local defluidization and channeling in fluidized-bed reactors for polymerization
US6365681B1 (en) * 2001-01-16 2002-04-02 Union Carbide Chemicals & Plastics Technology Corporation Preventing upsets in polymerization reactors

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5627242A (en) * 1996-03-28 1997-05-06 Union Carbide Chemicals & Plastics Technology Corporation Process for controlling gas phase fluidized bed polymerization reactor
US6300429B1 (en) * 1998-12-31 2001-10-09 Union Carbide Chemicals & Plastics Technology Corporation Method of modifying near-wall temperature in a gas phase polymerization reactor

Also Published As

Publication number Publication date
CN1684987A (zh) 2005-10-19
ZA200502327B (en) 2006-05-31
US20040063871A1 (en) 2004-04-01
CA2499233A1 (en) 2004-04-08
US6846884B2 (en) 2005-01-25
WO2004029108A1 (en) 2004-04-08
BR0314484B1 (pt) 2013-07-09
BR0314484A (pt) 2005-07-26
EP1546220A1 (en) 2005-06-29
JP2006500458A (ja) 2006-01-05
AU2003254237A1 (en) 2004-04-19
AU2003254237B2 (en) 2009-01-08

Similar Documents

Publication Publication Date Title
CN1314715C (zh) 改进对树脂性能的控制
CN1185270C (zh) 多成分催化剂溶液供料
CN1145646C (zh) 不相容的聚合催化剂之间的转换方法
CN1117810C (zh) 聚烯烃组合物、由其得到的制品及制备该组合物的方法
CN1183168C (zh) 聚合物组合物及其生产方法和由其制备的薄膜
CN1788048A (zh) 制备高分子量-高密度聚乙烯及其薄膜的聚合物组合物和方法
CN1069034A (zh) 烯烃的气相聚合方法
CN1203606A (zh) 单烯烃/多烯烃共聚合物、其制备方法、含该聚合物的组合物和由其生产的制品
CN1051737A (zh) 生产粘性聚合物的方法
CN101035816A (zh) 烯烃气相聚合的方法
CN1391585A (zh) 多成分催化剂体系的启动方法
CN1271089C (zh) 多成分催化剂聚合体系的启动程序
CN1392190A (zh) 制备乙烯聚合物组合物的方法,乙烯聚合物组合物的颗粒和由该颗粒制成的膜
CN87103866A (zh) 一种制备低或中密度的直链聚乙烯的方法以及适合于该目的催化剂
CN1688608A (zh) 反应器壁涂层及其形成方法
CN1099059C (zh) 控制聚烯烃树脂生产装置的方法和仪器
CN1616535A (zh) 聚乙烯薄膜
CN1514846A (zh) 烯烃聚合方法,新型聚乙烯以及由其制造的薄膜和制品
US8071699B2 (en) Methods of controlling properties in multimodal systems
CN1175008C (zh) 异丁烯聚合方法
CN1130636A (zh) 乙烯聚合物
CN1798777A (zh) 气相聚合及其控制方法
US10399052B2 (en) Methods of controlling polyolefin melt index
AU2003254237B9 (en) Improved control of resin properties
CN1302015C (zh) 用于在不同聚合催化剂之间转变的方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
ASS Succession or assignment of patent right

Owner name: UNIVATION TECH LLC

Free format text: FORMER OWNER: UNION CARBIDE CHEMICAL AND PLASTICS TECHNOLOGY CO., CO.LTD.

Effective date: 20100622

C41 Transfer of patent application or patent right or utility model
C56 Change in the name or address of the patentee

Owner name: UNION CARBIDE CHEMICAL AND PLASTICS TECHNOLOGY CO.

Free format text: FORMER NAME: UNION CARBIDE CHEMICAL + PLASTIC TECHNOLOGY CO.,LTD

COR Change of bibliographic data

Free format text: CORRECT: ADDRESS; FROM: MICHIGAN,USA TO: TEXAS, USA

CP03 Change of name, title or address

Address after: michigan

Patentee after: UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY LLC

Address before: American Connecticut

Patentee before: Union Carbide chemicals & Plastics Technology Corp.

TR01 Transfer of patent right

Effective date of registration: 20100622

Address after: Texas, USA

Patentee after: UNIVATION TECHNOLOGIES, LLC

Address before: michigan

Patentee before: UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY LLC

CX01 Expiry of patent term

Granted publication date: 20070509

CX01 Expiry of patent term