CN1302762C - Cleaning agent composition for wiping - Google Patents

Cleaning agent composition for wiping Download PDF

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Publication number
CN1302762C
CN1302762C CNB038114216A CN03811421A CN1302762C CN 1302762 C CN1302762 C CN 1302762C CN B038114216 A CNB038114216 A CN B038114216A CN 03811421 A CN03811421 A CN 03811421A CN 1302762 C CN1302762 C CN 1302762C
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CN
China
Prior art keywords
weight
extract
clearly
fatty acid
acid
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Expired - Fee Related
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CNB038114216A
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Chinese (zh)
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CN1655759A (en
Inventor
宫泽清
久中隆行
谷尾俊幸
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Unicharm Corp
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Unicharm Corp
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C11D3/3742—Nitrogen containing silicones
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/049—Cleaning or scouring pads; Wipes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2065—Polyhydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Abstract

A cleaning agent composition for wiping which comprises (a) 0.01 to 1 wt.% specific aminated silicone, (b) 0.05 to 2 wt.% specific fatty acid soap, (c) 0.05 to 2 wt.% polyoxyethylene sorbitan ester type nonionic surfactant, and (d) 1 to 20 wt.% water-soluble polyhydric alcohol. This composition is advantageously usable as a dilution-type cleaning agent for skin wiping.

Description

Wipe away the agent compositions clearly
Technical field
The skin that the present invention relates to a kind of water or warm water dilution use is with wiping away the agent compositions clearly.In more detail, especially relate to a kind of with the dirt of wiping away positions such as buttocks or pudendum clearly be purpose wipe away the agent compositions clearly, it has sufficient detergency, use the sense of not being clamminess of back skin, when keeping skin sufficient elasticity and wettability, prevent chapped skin, and be difficult to recontaminate that ageing stability is also excellent.
Background technology
People need remove the dirt that comes from the outside termly or stem from " dirt " of the health of secretions such as sebum, antiperspirant in life.Usually when balneation, use the so-called agent cleaning self of wiping away clearly such as solid or liquid soap to remove these dirts.But,, get dirt with the cleaning health so the care-giver must wipe away with wet towel because the inflexible people of baby or health is difficult to clean self.Therefore, the medicament that at this moment will use for health is more cleaned is called " wiping away agent clearly ".Detersive roughly is divided into usually and does not dilute direct use type or with dilution such as warm water use type.
Wherein, the agent of wiping away clearly of dilution use type is diluted to back use about 10 times～1000 times with warm water usually, so the active ingredient amount in the prescription reduces, at detergency or aspect the moisture retention after using, compares with not diluting the use type, and disadvantageous situation is more.But, this dilution type wipe away agent clearly, actual working concentration reduces, and is particularly advantageous aspect safety not only, and can use the water of preference temperature during dilution, so to being comfortable by the care-giver.Moreover, because medicament use amount once is less,, become normally used types such as wiping away clearly of old man's nursing or baby so concerning consumer, seem to feel the cost value height.
Particularly in recent years, along with the arrival of aging society, the needs of wiping away agent clearly also increase rapidly, and the functional more excellent agent of wiping away is clearly developed in people's expectation.Especially, buttocks or pudendum are the parts that mucosa exposes, thus very responsive, and because be attached with specific dirt, so be the part of wiping away clearly often.Therefore, safer, the functional higher agent of wiping away is clearly developed in people expectation.At present, the spy open clear 64-38018 communique and special open put down in writing in the clear 64-79108 communique develop with dimethyl polysiloxane or polyether modified silicone be main composition wipe away agent clearly, but detergency is all insufficient, and, can not give skin sufficient elasticity and wettability after the use.And, do not have following such effect, that is, give skin sufficient shielding after the use, prevent chapped skin, when particularly wiping away other position clearly (when wiping away again), prevent the recontaminate that spot such as dirt shifts from towel etc.
Like this, wiping away clearly among the agent of dilution use type, though people crave for a kind of when being used for buttocks or pudendum, also have skin after sufficient detergency, the use be not clamminess prevent chapped skin in sense, maintenance skin sufficient elasticity and the wettability and also be difficult to when wiping away again recontaminate, ageing stability excellence safety wipe away the agent compositions clearly.
Summary of the invention
Inventors etc. about the result of the wholwe-hearted research of above-mentioned problem are: by with specific ratio specific silicone compounds, specific fatty acid soaps, specific non-ionic surface active agent and water-soluble polyol being made up, obtain the desired agent compositions of wiping away clearly.
Cleaning agent composition of the present invention contains:
(a) amino modified silicone 0.01～1 weight % that represents with formula (I),
Figure C0381142100041
(in the formula, R 1Independent respectively expression methyl or phenyl, and a plurality of R 1At least one be methyl; R 2Independent respectively expression methyl, hydroxyl or R 3Z; R 3The alkylidene of independent respectively expression carbon number 3～6; Z represents usefulness-N (R 4) 2Or-NR 4(CH 2) aN (R 4) 2The amino of expression, herein, R 4The alkyl of independent respectively expression hydrogen atom or carbon number 1～4, and a is 2～6 integer; And m and n independently are respectively 0～20000 integer and m+n=30～20000)
(b) fatty acid soaps 0.05～2 weight % that represents with formula (II),
R 5COOM (II)
(in the formula, R 5COO represents that carbon number is the fatty acid residue of 8～24 straight or branched; And M represents alkali metal atom)
(c) sorbitan polyoxyethylene ester type non-ionic surface active agent 0.05～2 weight %, and
(d) water-soluble polyol 1～20 weight %.
About preferred embodiment, of the present inventionly wipe away clearly that the agent compositions also contains the extract that is selected from the plant (Houttuynia Thunb) that (e) belong to from the extract of the leaf of the tea (C.sinensis L.) of Theaceae Camellia, from Herba Houttuyniae section Herba Houttuyniae, at least a extract in the extract of the plant (Phellodendron Rupr.) that belongs to from the extract of the plant (ArtemisiaL.) of Compositae artemisia and from the Rutaceae Cortex Phellodendri, its content is counted 0.00005～1 weight % with dried residue.
The specific embodiment
The agent compositions of wiping away clearly of the present invention contains following (a) and (b), (c) and composition (d), also contains the composition, (f) additive, (g) solvent of (e) etc. according to necessity.The content of wiping away each composition of agent compositions clearly of the present invention is the content with respect to the compositions full dose that contains solvent (being generally water) etc.
(a) amino modified silicone
Amino modified silicone is the chemical compound with formula (I) expression
In the formula (I), R 1Independent respectively expression methyl or phenyl, and a plurality of R 1At least one be methyl.
R 2Independent respectively expression methyl, hydroxyl or expression R 3Z.
R 3The alkylidene of independent respectively expression carbon number 3～6 is preferably (CH 2) 3-.
Z represents usefulness-N (R 4) 2Or-NR 4(CH 2) aN (R 4) 2The amino of expression, R 4The alkyl of independent respectively expression hydrogen atom or carbon number 1～4, and a is 2～6 integer.Such amino is preferably-NH 2,-NHCH 3,-N (CH 3) 2,-NH (CH 2) 2NH 2,-NH (CH 2) 2NHCH 3Or-NH (CH 2) 2N (CH 3) 2
M and n independently are respectively 0～20000 integer, and m+n=30～20000.M+n is preferably 100～20000, more preferably 1000～20000.
Amino modified silicone of the present inventionly wipe away in the agent compositions full dose clearly, be preferably 0.03～0.7 weight % with 0.01～1 weight %, more preferably the ratio of 0.05～1 weight % contains.During less than 0.01 weight %, use the back to produce the sense of being clamminess, prevent that the effect of recontaminate is insufficient; During greater than 1 weight %, be difficult to make it to contain equably in containing the compositions of solvent, and also unfavorable aspect cost.
(b) fatty acid soaps
Fatty acid soaps is the alkali metal salt with the fatty acid of formula (II) expression
R 5COOM (II)
(in the formula, R 5COO represents that carbon number is the fatty acid residue of 8～24 straight or branched; And M represents alkali metal atom).
As fatty acid, can enumerate for example straight chain fatty acids such as lauric acid, myristic acid, Palmic acid, stearic acid, palmitic olefinic acid, oleic acid, linoleic acid, linolenic acid; A chain saturated fatty acid such as isostearic acid; Reach fatty acid mixeds such as coco-nut oil fatty acid, palm-kernel oil fatty acid, palm oil fatty acid, olive oil fatty acid, Oleum helianthi fatty acid, tallow fatty acids, curing tallow fatty acids.Wherein, from stability, when wiping away clearly sense of touch and prevent that the viewpoint of the effect of chapped skin from considering, contain cis-Δ 9-octadecenic acid (being commonly referred to as oleic acid) and contain this oleic cis-Δ 9-unsaturated fatty acid with the ratio more than the 75 weight % and be preferably the fatty acid that contains with the ratio more than the 85 all weight %, contain cis-Δ 9-octadecenic acid (oleic acid) and contain the fatty acid that this oleic cis-Δ 9-unsaturated fatty acid more preferably contains with the ratio more than the 85 all weight % with the ratio more than the 80 weight %.
As the alkali metal atom of M, can enumerate for example sodium, potassium etc., consider from stability and deliquescent viewpoint, be preferably potassium.
Fatty acid soaps of the present inventionly wipe away in the agent compositions full dose clearly, be preferably 0.07～1.5 weight % with 0.05～2 weight %, more preferably the ratio of 0.1～1 weight % contains.During less than 0.05 weight %, detergency variation but also prevent that the effect of chapped skin is also insufficient not only; During greater than 2 weight %, residual after using have tight sense, moist feeling also deficiency, sense of touch variation, and the stability of compositions also has the probability of reduction.
(c) sorbitan polyoxyethylene ester type non-ionic surface active agent
Sorbitan polyoxyethylene ester type non-ionic surface active agent normally adds to oxirane to be made in the ester (Sorbitol fatty acid ester) that sorbitan and fatty acid response is obtained with 1: 1～1: 4 mol ratio.As above-mentioned fatty acid, can enumerate straight chain fatty acids such as lauric acid, myristic acid, Palmic acid, stearic acid, palmitic olefinic acid, oleic acid, linoleic acid, linolenic acid; A chain saturated fatty acid such as isostearic acid; Fatty acid mixeds such as coco-nut oil fatty acid, palm-kernel oil fatty acid, palm oil fatty acid, olive oil fatty acid, Oleum helianthi fatty acid, tallow fatty acids, curing tallow fatty acids.Be preferably lauric acid or oleic acid.In addition, the average addition molal quantity of oxirane is 5～100, is preferably 10～60.
Sorbitan polyoxyethylene ester type non-ionic surface active agent of the present inventionly wipe away in the agent compositions full dose clearly, be preferably 0.07～1.5 weight % with 0.05～2 weight %, more preferably the ratio of 0.1～1 weight % contains.During less than 0.05 weight %, also variation of detergency variation but also stability not only; During greater than 2 weight %, the sense of touch variation after the use.
(d) water-soluble polyol
Water-soluble polyol is the water soluble compound that an intramolecularly contains plural hydroxyl, typically uses the material as wetting agent such as material of making up.Can enumerate for example propylene glycol, dipropylene glycol, isobutyl glycol, 1,3 butylene glycol, glycerol, two glycerol, Polyethylene Glycol, Sorbitol, maltose alcohol etc. particularly.Wherein preferred alcohol is dipropylene glycol, isobutyl glycol, 1,3 butylene glycol, glycerol, two glycerol and Polyethylene Glycol, and more preferably molecular weight is 600～4000 polytetramethylene glycol.
Water-soluble polyol of the present inventionly wipe away in the agent compositions full dose clearly, be preferably 3～18 weight % with 1～20 weight %, more preferably the ratio of 5～15 weight % contains.During less than 1 weight %, sense of touch after the use or bad stability; During greater than 20 weight %, the dispersibility variation during dilution.
(e) plant extract
The plant extract that contains in the agent compositions of wiping away clearly of the present invention is plant extract at least a that is selected from following (i)～(iv).
(i) from the extract of the leaf of the tea (C.sinensis L.) of Theaceae Camellia
This is that a kind of usefulness is selected from the extract of at least a solvent of water and lower alcohol (ethanol, isopropyl alcohol, propylene glycol, 1,3 butylene glycol etc.) from the leaf extraction of the tea (C.sinensis L.) of Theaceae Camellia.At this moment, tea roughly is divided into two kinds usually, and a kind of is the var.sinensis that is used as so-called green tea, and another kind is var.assamica (Mast.) Kitam. as so-called black tea.Among the present invention, can use this any of two kinds.When extracting extract, preferably carry out drying, fermentation (fermentation in the Folium Camelliae sinensis), steaming, stir-fry etc. usually and handle as its pre-treatment by these Folium Camelliae sinensis.For example, handle the azymic tea of tea leaf, can enumerate green tea, yellow tea etc., the tea of still parches such as tea that be in particular YULU, simmer tea, matcha, kind tea, bake and parch tea etc. steams and jade green tea, Chinese green tea as direct heating.As the fermented tea of making by fermentation (utilizing the oxygen of Folium Camelliae sinensis to carry out the oxidation reaction of Folium Camelliae sinensis composition), can enumerate postfermented tea, black tea, Ramulus et Folium Mussaendae Pubescentis etc., as its intermediary semi-fermented tea, can enumerate oolong tea etc.
The (ii) extract of the plant (Houttuynia Thunb) that belongs to from Herba Houttuyniae section Herba Houttuyniae
This is that a kind of usefulness is selected from least a solvent of water and lower alcohol (ethanol, isopropyl alcohol, propylene glycol, 1,3 butylene glycol etc.) from the aerial parts of the plant (Houttuynia Thunb) of Herba Houttuyniae section Herba Houttuyniae genus or the extract of Herb plant extract.Be preferably the extract of aerial parts (pharmacognosy be called " ten medicines ") extraction in the florescence of the plant (Houttuynia Thunb) that belongs to from Herba Houttuyniae section Herba Houttuyniae.
(iii) from the extract of the plant (Artemisia L.) of Compositae artemisia
This is that a kind of usefulness is selected from least a solvent of water and lower alcohol (ethanol, isopropyl alcohol, propylene glycol, 1,3 butylene glycol etc.) from the leaf of the plant (Artemisia L.) of Compositae artemisia or the extract of Herb plant extract.The extract that extracts from Artemisia absinihium L (A.absinthium L.), Herba Artemisiae Scopariae (A.capillaries Thunb.), Herba Artemisiae Japonicae (A.japonica Thunb.), Artemisia princeps Pamp. (A.princeps Pamp.), Hai Ai (A.maritima L.), Herba Artemisiae mongolicae (A.mongoria Fisch.), mountain Artemisia (A.montamaPamp.) for example.Be preferably the extract that extracts from the leaf of Herba Artemisiae Japonicae (A.japonica Thunb.), Artemisia princeps Pamp. (A.princeps Pamp.), Hai Ai (A.maritima L.), Herba Artemisiae mongolicae (A.mongoria Fisch.) or mountain Artemisia (A.montama Pamp.).
The (iv) extract of the plant (Phellodendron Rupr.) that belongs to from the Rutaceae Cortex Phellodendri
This is that a kind of usefulness is selected from the extract of at least a solvent of water and lower alcohol (ethanol, isopropyl alcohol, propylene glycol, 1,3 butylene glycol etc.) from the bark extraction of the plant (Phellodendron Rupr.) of Rutaceae Cortex Phellodendri genus.Be preferably the extract that the bark (pharmacognosy is called " Cortex Phellodendri " or " Cortex Phellodendri ") from the perithelium of removing Cortex Phellodendri (P.amurense Rupr.) extracts.
The plant extract of these (i)～(iv) is because further improved moist feeling after using, prevented the effect of chapped skin and given the effect of skin elasticity, so contain these extracts of the present invention wiping away clearly in the agent compositions according to necessity.Wipe away clearly in the agent compositions of the present invention, the ratio that is preferably with 0.00005～1 weight % contains the said extracted thing as dried residue, and more preferably the ratio with 0.0001～0.5 weight % contains.During less than 0.00005 weight %, be difficult to bring into play the effect of interpolation; During greater than 1 weight %, the poor stability of compositions sometimes, and also also unfavorable aspect cost.In the present invention, so-called " dried residue " typically refers at 105 ℃ of following dryings or drying under reduced pressure curing extract and removes residue---solute when desolvating.In addition, when the extraction solvent is nonvolatile solvent, utilize the value of quantitative solvent amounts such as gas chromatogram, high performance liquid chromatography to calculate the solute amount, as the dried residue amount.
(f) additive
As additive, can use any of the additive that being used in the material of making up usually, in the scope of the performance of not damaging compositions of the present invention, additive is contained in compositions.For example can enumerate following such additive: lower alcohols such as ethanol, isopropyl alcohol; Hydrocarbon system oil such as liquid paraffin, liquid isoparaffin, isotriacontane, vaseline, hard paraffin; Natural oil lipids such as Adeps Bovis seu Bubali, leaf fat, fish oil; Synthetic glycerine three acid esters such as three-2-ethyl acid glyceride; Ester oils such as isopropyl myristate, isopropyl palmitate, cetyl palmitate, ethyl oleate, Cetiol, myristic acid octyl group dodecane ester; Wax such as Cera Flava, Brazil wax class; Silicone derivatives such as straight chain and cyclic dimethyl polysiloxane, polyether-modified dimethyl polysiloxane; Oiliness bases such as ceramide, cholesterol, protein derivatives, lanoline, lanolin derivative, lecithin; Polyoxyethylene alkyl ether, cithrol, polyoxypropylene alkyl ether, polypropylene glycol fatty acid ester, Sorbitol fatty acid ester, polyoxyethylene solidify non-ionic surface active agents such as Oleum Ricini, polyglyceryl fatty acid ester, fatty acid monoglyceride, alkyl polyglucoside, polyoxyethylene-polyoxypropylene block polymer, alkanolamide; Anion surfactants such as soap, alkyl sulfate salt, alkyl ether sulphate salts, alpha-olefin sulfonate, acyl group N-methyltaurine, acyl glutamate, acylglycine salt, acyl sarcosinates, acyl group isethionic acid, alkyl ether carboxy acid salt, amide ether sulfuric acid, alkyl phosphate salt; Amphoteric surfactantes such as alkyl dimethyl glycine betanin, amido propyl dimethylaminoethyl acid betanin, amidoamino acid salt, alkyl imino diacetin; Semi-polarity such as alkyl amine oxide, polyxyethylated amine oxide surfactant; Cationic surfactant such as alkyl trimethyl ammonium chloride, dialkyl dimethyl ammonium chloride; The hydrochlorate of alkylamine or amide and acetate; The powder of inorganic matters such as Talcum, Kaolin, sericite, Muscovitum, Vermiculitum, magnesium carbonate, calcium carbonate, kieselguhr, magnesium silicate, calcium silicates, aluminium silicate, barium silicate, strontium silicate, barium sulfate, wolframic acid slaine, Silicon stone, zeolite, hydroxyapatite, boron nitride, pottery; Organic dusts such as crystalline cellulose, polyethylene powders, poly-tetrafluoroethylene powder; Inorganic pigments such as titanium oxide, zinc oxide, red iron oxide (colcother), loess, carbon black, cobalt violet, chromium oxide, ultramarine; Pearl pigment such as titanium oxide lining Muscovitum, guanin, painted titanium oxide lining Muscovitum; Metallic powdery pigment such as aluminium powder, copper powder; Organic pigments such as redness No. 201, orange No. 204, No. 205, yellow, No. 404, blueness; Two zirconium compounds such as No. 3, redness, No. 106, redness, No. 227, redness, No. 4, yellow, No. 6, yellow, No. 1, cyan; Natural pigment such as chlorophyll, beta-carotene; The water soluble polymers such as copolymer of alginic acid, carbopol preparation, hydroxy methocel, hydroxypropyl methylcellulose, hydroxyethyl-cellulose, xanthan gum, hyaluronic acid, 2-(methyl) acryloyl group ethoxy phosphocholine and (methyl) acrylic acid propylene ester; Inorganic or organic salts such as magnesium sulfate, sodium chloride, sodium citrate, pyrrolidone sodium carboxylate; PH such as acid and alkali adjusts agent; Antibacterial; Chelating agen; Antioxidant; UV absorbent; Anti-inflammatory agent; The natural extract of animals and plants origin; Spice etc.
When containing above-mentioned additive, in the scope of the degree of not damaging stability, can contain above-mentioned additive in the compositions.
(g) solvent
As solvent, make water (Purified Water etc.) usually.The residual amount of the total content (weight %) of above-mentioned (a)～(f) is a solvent.
Of the present inventionly wipe away the agent compositions clearly because contain specific composition with the ratio of regulation, thus have after sufficient detergency, the use skin be not clamminess sense, maintenance sufficient elasticity and wettability, prevent chapped skin.And, be difficult to when wiping away again recontaminate, ageing stability also excellent, can long preservation.Said composition is because design in the mode that is diluted to about 5～100 multiples, is preferably about 10～80 times of uses, so cost value is also arranged.Therefore, suitablely especially wipe away agent clearly as the dirt that is used for wiping away clearly buttocks or pudendum etc.
Embodiment
Then, utilize embodiment to illustrate in greater detail the present invention.Wipe away the agent compositions clearly about what make in the present invention, utilize the method for (1)～(5) of following record, estimate its performance.
(1) detergency and preventing property of recontaminate
Wipe away agent compositions to 30 times clearly with Purified Water dilution, use (wealth) to wash chemical association system " wet type artificial contamination's cloth " (JIS-C9606 specification), utilize Terg-0-tometer, wash three times with commensurability water 40 ℃ of washings 10 minutes down.Then, dehydration, air-dry, " the color measurement device " that utilizes Japanese electric color industry (strain) to make carries out the mensuration of whiteness.The whiteness of the calico that uses when measuring the above-mentioned pollution cloth of modulation in advance before cleaning (not have pollute calico) and clean the whiteness of preceding pollution cloth utilizes following formula to calculate clean rate, according to following benchmark evaluation detergency.Then, when the above-mentioned pollution cloth of cleaning, clean the test of this pollution cloth and calico together, utilize above-mentioned formula to calculate the recontaminate rate of calico, according to following preventing property of benchmark evaluation recontaminate.
Clean rate (%)=(C-B)/(A-B) * 100
Recontaminate rate (%)=(A-D)/A * 100
The whiteness of calico: A
The whiteness of the pollution cloth before cleaning: B
The whiteness of the pollution cloth after cleaning: C
With the whiteness of polluting the clean calico of cloth: D
Detergency:
Zero: detergency good (rate of cleaning is more than 25%)
*: detergency bad (rate of cleaning is less than 25%)
Preventing property of recontaminate:
Zero: preventing property of recontaminate good (preventing property of recontaminate is below 5%)
*: preventing property of recontaminate bad (preventing property of recontaminate is greater than 5%)
(2) sense of being clamminess of the skin after the use
With 13 women (32～45 years old) and 7 male (33～44 years old) as panel.Use wash basin, wipe away agent compositions 35mL clearly with the about 1L dilution of about 40 ℃ warm water (about 30 times), be impregnated into the dry non-woven fabrics of 135mm * 190mm in this liquid after, gently twist.This wipes away the non-woven fabrics wiping buttocks and the pudendum of agent compositions clearly with impregnation, then, about the sense of being clamminess of skin after the wiping, marks in following mode.
2 minutes: do not feel after the use that skin has the situation of the sense of being clamminess
1 minute: feel after the use that skin has the situation of the sense of being clamminess slightly
0 minute: feel the situation that skin is clamminess and feels blue after the use
Ask the meansigma methods of 20 user, the sense of being clamminess after using with following benchmark evaluation.
Zero: the sense of not being clamminess, good (meansigma methods is more than 1.5)
*: the sense of being clamminess, bad (meansigma methods is less than 1.5 points) are arranged
(3) elasticity and the wettability of the skin after the use
With 13 women (32～45 years old) and 7 male (33～44 years old) as panel.The same with above-mentioned (2), be impregnated with the non-woven fabrics wiping whole body of wiping away the agent compositions clearly with containing, about the wettability of the skin after 15 minutes, mark in following mode.
2 minutes: feel the flexible and wettability of skin, be the situation of healthy skin
1 minute: feel that skin is dry slightly, do not have a wettability or do not have elastic situation a little a little
0 minute: feel xerosis cutis, do not have wettability or do not have elastic situation
Ask the meansigma methods of 20 user, the elasticity and the wettability of the skin after using with following benchmark evaluation.
Zero: flexible and wettability, good (meansigma methods is more than 1.5)
*: there are not elasticity and wettability, bad (meansigma methods is less than 1.5 points)
(4) prevent the effect of chapped skin
The male 3 (33～37 years old) that the women 7 (32～40 years old) of sensitive skin will be arranged and sensitive skin arranged is as panel.The same with above-mentioned (2), be impregnated with the non-woven fabrics of wiping away the agent compositions clearly with containing, dab the upper arm medial part for several times to wipe away the mode of getting dirt, wiped away in one day by this way and get twice, used for two weeks continuously after, about the state of skin, mark in following mode.
2 minutes: feel the situation that skin is not a bit chapped
1 minute: feel the situation that skin is chapped slightly
0 minute: feel the situation that skin is obviously chapped
Ask 10 meansigma methods, prevent the effect of chapped skin with following benchmark evaluation.
Zero: respond well (meansigma methods is more than 1.5) that prevents chapped skin
*: the effect bad (meansigma methods is less than 1.5 points) that prevents chapped skin
(5) ageing stability
Be sealed in the transparent glass container and under the condition of 5 ℃, 25 ℃ and 40 ℃, preserved 3 months respectively wiping away the agent compositions clearly, observe its outward appearance, estimate with three levels described below.
Zero: (even under any temperature, outward appearance does not change yet) has good stability
△: stability bad a little (under any temperature, produce a little residue or produce precipitation or produce that a little is painted)
*: stability bad (under any temperature, producing a little residue or precipitation or separation or painted obvious)
(embodiment 1～7)
With the ratio shown in the table 1 modulate respectively contain each composition wipe away the agent compositions clearly, utilize said method evaluation.About the details of each composition of table 1, shown in another table 2.The result is as shown in table 4.In table 4, " cleaning rate " reaches the interior numerical value of parantheses of the item of " recontaminate rate " and represents the rate of cleaning and recontaminate rate respectively.The numerical value that " sense of being clamminess of the skin after the use ", " elasticity after the use and wettability " reach in the parantheses of item of " preventing the chapped skin effect " is represented the mark tested respectively.
Table 1
Composition Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6 Embodiment 7
(a) Amino modified silicone emulsion (annotating 1) (amino modified silicone: weight %) 0.3 (0.06) 0.5 (0.1) 1 (0.21) 2 (0.42) 0.5 (0.1) 0.3 (0.06) 0.3 (0.06)
(b) Myristic acid (annotating 2) 0.2 - - - - - -
Oleic acid (annotating 3) - 0.15 0.15 0.15 0.15 0.3 0.15
48% potassium hydroxide aqueous solution 0.18 0.15 0.15 0.15 0.15 0.28 0.15
(c) Polyoxyethylene (20mol) mono laurate sorbitol ester (annotating 4) 0.2 0.3 - - 0.3 0.3 0.2
The single oleic acid sorbitol ester of polyoxyethylene (20mol) (annotating 5) - - 0.2 0.5 - - 0.3
(d) Glycerol 5 5 5 2 5 3 2
Dipropylene glycol 2 2 2 2 5 3 2
Macrogol 1540 2 2 2 2 2 3 2
(e) Tea extract 1 (annotating 6) (dry scaled value: weight %) 1 (0.012) - 0.1 (0.0012) 0.5 (0.006) - - 10 (0.12)
Tea extract 2 (annotating 7) (dry scaled value: weight %) - 1 (0.011) - - - - -
Herba Houttuyniae extract (annotating 8) (dry scaled value: weight %) - - - 0.2 (0.003) - 10 (0.15) -
Biennial wormwood extract (annotating 9) (dry scaled value: weight %) - 0.5 (0.0055) - 0.1 (0.0011) - - 10 (0.11)
Cortex Phellodendri extract (annotating 10) (dry scaled value: weight %) - - 2 (0.02) - - - -
(a)’ Methyl polysiloxane emulsion (annotating 11) (methyl polysiloxane: weight %) - - - - - - -
Additive Methyl betaine 0.2 0.2 0.2 0.2 0.2 0.2 0.2
Spice (annotating 12) 0.1 0.1 0.1 0.1 0.1 0.1 0.1
Purified Water Residue Residue Residue Residue Residue Residue Residue
Meter 100 100 100 100 100 100 100
Unit is weight %
Table 2
Annotate number Trade name Manufacturing company's name In detail
(annotating 1) XS65-B6413 GE Toshiba silicone (strain) Contain aminoethyl ammonia third methylsiloxane---the emulsion of dimethylsiloxane copolymer 21 weight %
(annotating 2) NAA-142 Japan's oils and fats (strain) [fatty acid composition] tetradecanoic acid 99 weight %, other fatty acid 1%
(annotating 3) EXTRA OS-85 Japan's oils and fats (strain) [fatty acid composition] cis-Δ 9-octadecenic acid 87%, cis-Δ 9, cis-12-octadecane dienoic acid 4%, hexadecanoic acid 3%, octadecanoid acid 4%, behenic acid, other fatty acid 1%, (cis-Δ 9-unsaturated fatty acid 91%)
(annotating 4) Nonionic LT-221 Japan's oils and fats (strain)
(annotating 5) NOFABLE ESO-8520 Japan's oils and fats (strain)
(annotating 6) Tea extract Fragrant Rong Xingye (strain) [extraction solvent] 30% ethanol water
(annotating 7) Black tea extracting solution S Fragrant Rong Xingye (strain) [extraction solvent] 30% ethanol water
(annotating 8) The Herba Houttuyniae extracting solution Fragrant Rong Xingye (strain) [extraction solvent] 50%1,3-butanediol aqueous solution
(annotating 9) Radix Artemisia ordosicae liquid ICHIMARU PHARCOS CO.，LTD. [extraction solvent] 24% ethanol 20%1,3-butanediol aqueous solution
(annotating 10) Cortex Phellodendri liquid E ICHIMARU PHARCOS CO.，LTD. [extraction solvent] 50% ethanol water
(annotating 11) XS65-B2907 GE Toshiba silicone (strain) The emulsion that contains high polymerization methyl polysiloxane 34.8 weight %
(annotating 12) Fragrance F3-2373 Fragrant Rong Xingye (strain)
(comparative example 1～5)
Wipe away the agent compositions clearly with what the ratio shown in the table 3 modulation contained each composition, utilize said method evaluation.The result is as shown in table 4.
Table 3
Composition Comparative example 1 Comparative example 2 Comparative example 3 Comparative example 4 Comparative example 5
(a) Amino modified silicone emulsion (annotating 1) (amino modified silicone: weight %) - - 0.5 (0.1) 0.5 (0.1) 0.5 (0.1)
(b) Myristic acid (annotating 2) - - - - -
Oleic acid (annotating 3) 0.15 0.15 - 0.15 0.15
48% potassium hydroxide aqueous solution 0.15 0.15 - 0.15 0.15
(c) Polyoxyethylene (20mol) mono laurate sorbitol ester (annotating 4) 0.3 0.3 0.3 0.02 0.3
The single oleic acid sorbitol ester of polyoxyethylene (20mol) (annotating 5) - - - - -
(d) Glycerol 5 5 5 5 -
Dipropylene glycol 2 2 2 2 -
Macrogol 1540 2 2 2 2 -
(e) Tea extract 1 (annotating 6) (dry scaled value: weight %) - - - - -
Tea extract 2 (annotating 7) (dry scaled value: weight %) 1 (0.011) 1 (0.011) 1 (0.011) 1 (0.011) 1 (0.011)
Herba Houttuyniae extract (annotating 8) (dry scaled value: weight %) - - - - -
Biennial wormwood extract (annotating 9) (dry scaled value: weight %) 0.5 (0.0055) 0.5 (0.0055) 0.5 (0.0055) 0.5 (0.0055) 0.5 (0.0055)
Cortex Phellodendri extract (annotating 10) (dry scaled value: weight %) - - - - -
(a)’ Methyl polysiloxane emulsion (annotating 11) (methyl polysiloxane: weight %) - 0.5 (0.174) - - -
Additive Methyl betaine 0.2 0.2 0.2 0.2 0.2
Spice (annotating 12) 0.1 0.1 0.1 0.1 0.1
Purified Water Residue Residue Residue Residue Residue
Meter 100 100 100 100 100
Unit is weight %
Table 4
Assessment item Embodiment Comparative example
1 2 3 4 5 6 7 1 2 3 4 5
Clean rate (%) ○ (30) ○ (35) ○ (37) ○ (33) ○ (34) ○ (35) ○ (40) ○ (36) × (23) × (20) × (16) ○ (37)
Recontaminate rate (%) ○ (0) ○ (0) ○ (0) ○ (0) ○ (0) ○ (0) ○ (0) × (10) ○ (3) ○ (0) ○ (0) ○ (0)
The sense of being clamminess of the skin after the use ○ (1.7) ○ (1.8) ○ (1.9) ○ (1.9) ○ (1.8) ○ (1.8) ○ (1.8) × (1.1) ○ (1.6) ○ (1.5) ○ (1.8) ○ (1.9)
Elasticity after the use and moist feeling ○ (1.6) ○ (1.8) ○ (1.8) ○ (1.8) ○ (1.6) ○ (1.9) ○ (1.8) ○ (1.6) ○ (1.6) ○ (1.7) ○ (1.5) × (11)
Prevent the effect of chapped skin ○ (1.6) ○ (1.8) ○ (1.9) ○ (1.8) ○ (1.7) ○ (1.9) ○ (1.8) ○ (1.5) ○ (1.7) × (1.3) ○ (1.7) ○ (1.5)
Ageing stability ○ ○ ○ ○ ○ ○ ○ ○ × ○ △ ×
By the result shown in the table 4 as can be known: embodiment 1～7 of the present invention wipe away clearly the agent compositions any all have after sufficient detergency, the use skin be not clamminess sense, when keeping sufficient elasticity and wettability, can prevent chapped skin.But also as can be known: when using said composition, the ageing stability that is difficult to recontaminate, compositions self is also excellent.
On the other hand, the agent compositions of wiping away clearly of comparative example 1～5 does not obtain sufficient performance.At length as can be known: the compositions of comparative example 1 is clamminess sense and prevents the recontaminate weak effect so produce after using because do not contain (a) composition.In comparative example 2,, contain the silicone derivative (a) different with (a) of the present invention composition because replace (a) composition ', so the rate of cleaning is low and ageing stability is poor.In comparative example 3, because do not contain (b) composition, so the detergency difference time, prevent that the effect of chapped skin is also insufficient.In comparative example 4, because (c) content of composition is few, so the detergency difference time, ageing stability is also insufficient.In comparative example 5, because do not cooperate (d) composition, so the skin after using does not have elasticity and wettability, ageing stability is poor.Like this, use ratio with regulation to contain (a) and (b), (c) and (d) when composition of the present invention wiped away the agent compositions clearly, can obtain excellent cleaning effect and usability.
Utilizability on the industry
As mentioned above, of the present invention wipe away clearly the agent composition and have sufficient detergency, use after skin be not clamminess sense, maintenance sufficient elasticity and wettability, prevent chapped skin. And, be difficult to when wiping away again pollute again, ageing stability also excellent, can long preservation. Said composition is diluted to about 5～100 times of uses usually, so also have cost value. Therefore, suitable wipes away clearly as being used for skin, wipe away clearly agent especially for the dirt of wiping away clearly buttocks or private parts etc.

Claims (2)

1. wipe away the agent compositions clearly for one kind, it is characterized in that: contain
(a) amino modified silicone 0.01～1 weight % that represents with formula (I),
Figure C038114210002C1
In the formula (I), R 1Independent respectively expression methyl or phenyl, and a plurality of R 1At least one be methyl; R 2Independent respectively expression methyl, hydroxyl or R 3Z; R 3The alkylidene of independent respectively expression carbon number 3～6; Z represents usefulness-N (R 4) 2Or-NR 4(CH 2) aN (R 4) 2The amino of expression, herein, R 4The alkyl of independent respectively expression hydrogen atom or carbon number 1～4, and a is 2～6 integer; M and n independently are respectively 0～20000 integer, and m+n=30～20000;
(b) fatty acid soaps 0.05～2 weight % that represents with formula (II),
R 5COOM (II)
In the formula (II), R 5COO represents that carbon number is the fatty acid residue of 8～24 straight or branched; And M represents alkali metal atom;
(c) sorbitan polyoxyethylene ester type non-ionic surface active agent 0.05～2 weight %; And
(d) water-soluble polyol 1～20 weight %.
2. the agent compositions of wiping away clearly as claimed in claim 1 is characterized in that:
At least a extract in the extract of the plant that also contain the extract that is selected from the plant that (e) belong to from the extract of the leaf of the tea of Theaceae Camellia, from Herba Houttuyniae section Herba Houttuyniae, belongs to from the extract of the plant of Compositae artemisia and from the Rutaceae Cortex Phellodendri, its content is counted 0.00005～1 weight % with dried residue.
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KR101482595B1 (en) * 2007-03-30 2015-01-14 유니챰 가부시키가이샤 Cleaning composition for cleaning wet sheet and cleaning wet sheet containing the same
US8124061B2 (en) * 2007-11-02 2012-02-28 Kimberly-Clark Worldwide, Inc. Cleansing compositions including modified sorbitan siloxanes and use thereof
US7820149B2 (en) 2007-11-02 2010-10-26 Kimberly-Clark Worldwide, Inc. Modified sorbitan siloxane compositions and use thereof
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6438018A (en) * 1987-07-31 1989-02-08 Pigeon Corp Skin cleanly wiping agent of milky lotion state
JPS6479108A (en) * 1987-09-18 1989-03-24 Shiseido Co Ltd Cleanly washing and wiping agent composition
JPH11199467A (en) * 1998-01-06 1999-07-27 Nonogawa Shoji Kk Skin preparation for external use
JP2000226324A (en) * 1998-11-30 2000-08-15 Kansai Koso Kk Liquid agent composition for cleaning/wiping and for cosmetic water

Family Cites Families (5)

* Cited by examiner, † Cited by third party
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JP3415197B2 (en) * 1993-06-30 2003-06-09 三省製薬株式会社 External preparation for skin
JPH07118132A (en) * 1993-10-18 1995-05-09 Shiseido Co Ltd Ultraviolet-absorbing skin cosmetic
JPH07274977A (en) * 1994-04-14 1995-10-24 Shikoku Sogo Kenkyusho:Kk Extraction of useful plant essence, plant essence obtained by the extraction and skin-improving product containing the same essence as the active component
JP4635359B2 (en) * 2001-03-26 2011-02-23 日油株式会社 Cleaning composition
JP4792648B2 (en) * 2001-03-26 2011-10-12 日油株式会社 Hot cleansing fee

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6438018A (en) * 1987-07-31 1989-02-08 Pigeon Corp Skin cleanly wiping agent of milky lotion state
JPS6479108A (en) * 1987-09-18 1989-03-24 Shiseido Co Ltd Cleanly washing and wiping agent composition
JPH11199467A (en) * 1998-01-06 1999-07-27 Nonogawa Shoji Kk Skin preparation for external use
JP2000226324A (en) * 1998-11-30 2000-08-15 Kansai Koso Kk Liquid agent composition for cleaning/wiping and for cosmetic water

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