JP5465831B2 - Composition for removing horn plugs - Google Patents

Description

  The present invention relates to a composition suitable for cosmetics and a matrix for adhesives, and more particularly to a cosmetic for removing horn plugs and a matrix for adhesives.

  Since pores and horn plugs have a significant effect on whether the skin looks clean and have a high probability of physiologically affecting acne formation, treatment is a major theme in cosmetics. It has become. Against this background, technology for reducing pores using amino acid derivatives (see, for example, Patent Document 1 and Patent Document 2), technology for removing square plugs filled in pores with cosmetics (for example, patents) Reference 3 and Patent Document 4) have been developed, but there are certainly cases where these technologies are effective, but they may be invalid or may worsen due to conspicuous pores. Not a few. In other words, it can be said that development of a means for improving the conspicuousness of pores that can achieve an effect accurately has been desired.

  In addition, N-acylamino acid diesters such as N-lauroylglutamate di (phytosteryl octyldodecyl) are incorporated into cosmetics such as detergents as moisturizing surfactants (for example, Patent Document 5 and Patent Documents). 6) is also known, but the action of removing keratin plugs has already been disclosed, and 1% by mass of this is cleansed with 3% by mass of a nonionic surfactant having a branched fatty acid residue. A technique for removing oil from the square plug is also known (see, for example, Patent Document 7). In such cleansing oil, an excellent effect of removing keratin plugs has been confirmed. However, in such a dosage form, the degree of removal of keratin plugs did not reach that of a sheet-like kerato plug remover. .

  The ability to remove horn plugs in the cleansing action is equivalent to cleansing that removes oily dirt and removal of horn plugs, compared to the case of using a dedicated horn plug removal sheet. It can be said that it was desired to improve the stopper removing action.

  On the other hand, it is a cosmetic composition for removing horn plugs that has a contact time with pores of at least 1 minute and is washed away after use, 1) 1 to 4% by mass of water, and 2) N- An acylamino acid ester of 0.05 to 3% by mass and 3) 10 to 20% by mass of a hydrophilic nonionic surfactant having a branched alkyl group in the molecule are not known at all. It is also not known at all that a composition having such a structure has an effect of removing horn plugs comparable to a dedicated horn plug removal sheet even when used as a cosmetic.

JP 2005-281197 A JP 2005-179343 A JP 2005-145982 A JP 2004-161631 A JP 2002-104951 A JP 2004-292484 A JP 2007-192556 A

  The present invention has been made under such circumstances, and an object of the present invention is to provide a technique for improving the action of removing a plug in a cleansing material.

In view of such a situation, the present inventors have sought a means to improve the effect of removing the horn plugs so as to be comparable to the sheet-like horn plug removal charges in the cleansing charges that can be normally used as a cleansing charge. After extensive research efforts, the contact time with the pores is at least 1 minute or more, and it is a cosmetic composition for removing horn plugs that is used in a mode of washing away after use. 1) 1 to 4% by mass of water And 2) 0.1 to 1% by mass of an N-acylamino acid ester and 3) 12 to 15% by mass of a hydrophilic nonionic surfactant having a branched alkyl group in the molecule It has been found that it has various characteristics, and the invention has been completed. That is, the present invention is as follows.
<1> A cosmetic composition for removing horn plugs that has a contact time with pores of at least 1 minute and is washed away after use, 1) 1 to 4% by mass of water, and 2) N -Removal of square plugs, comprising 0.1 to 1% by mass of an ester of acylamino acid and 3) 12 to 15% by mass of a hydrophilic nonionic surfactant having a branched alkyl group in the molecule Cosmetic composition.
<2> Cosmetic composition for removing horn plugs according to <1>, characterized in that the aqueous phase is a dosage form solubilized in the oil phase and exhibits a fluid and transparent property at 25 ° C. object.
<3> Impregnated on a support, affixed to the nose for 5 minutes or more, peeled off from the nose, and then used in a mode of washing the affixed site, <1> or <2> The cosmetic composition as described.
<4> The cosmetic composition according to any one of <1> to <3>, further comprising a carbonic acid diester.
<5> The cosmetic composition according to any one of <1> to <3>, further comprising phenylmethicone.
<6> An adhesive for removing horn plugs, wherein the cosmetic composition according to any one of <1> to <5> is impregnated into a support.
<7> A cosmetic comprising the cosmetic composition according to any one of <1> to <5>, impregnated in a support, and scraped together with the support.

  ADVANTAGE OF THE INVENTION According to this invention, the technique which improves the square plug removal effect | action in a cleansing material can be provided.

<1> Water which is an essential component of the cosmetic composition of the present invention The cosmetic composition of the present invention contains 1 to 4% by mass of water as an essential component, more preferably 2 to 3% by mass. In the cosmetic composition of the present invention, fine micelles are formed together with a hydrophilic nonionic surfactant, solubilized in an oil phase, and has an action of improving wash-off characteristics. Therefore, the wash-off characteristics that wash away dirt and the oily component of the cosmetic composition with running water, and the solid fat component that fixes the square plugs are dissolved, and the action of promoting the removal from the pores of the square plugs is developed. There must be a sufficient amount of hydrophilic nonionic surfactant, specifically, an amount sufficient to make 10-20% by weight of hydrophilic nonionic surfactant into micelles, It is preferable that it is 1-10 mass% with respect to the total amount of a hydrophilic nonionic surfactant. That is, the hydrophilic nonionic surfactant is mixed with the oil phase component in a manner in which the hydrophobic group is directed outward in the oil phase, but a part of the hydrophilic group is inhibited by the three-dimensional structure of the surfactant, These are also oriented outward. If the content of the hydrophilic nonionic surfactant is too large due to this orientation, it is insolubilized and deposited. When a very small amount of water is added here, micelles are formed around the water, and the hydrophilic groups are neatly oriented in the micelles, so that the hydrophobicity outside the micelles is increased and the compatibility with the oil phase is increased. Thus, the increase in the solubilizing amount of the surfactant improves both the cleansing characteristics against oily soil and the wash-off characteristics.

<2> Ester of N-acylamino acid which is an essential component of the cosmetic composition of the present invention The cosmetic composition of the present invention is characterized by containing an ester of N-acylamino acid as an essential component. The acyl group constituting the ester of N-acylamino acid is preferably a fatty acid residue having 10 to 30 carbon atoms, specifically, 2-ethylhexanoic acid residue, lauric acid residue, myristic acid residue, palmitic acid. Preferred examples include acid residues, stearic acid residues, behenic acid residues, isopalmitic acid residues, isostearic acid residues, oleic acid residues, linoleic acid residues, linolenic acid residues and the like. Examples of the amino acid moiety include acidic amino acids such as glutamic acid and aspartic acid, neutral amino acids such as glutamine, asparagine and glycine, and basic amino acids such as lysine and arginine. Particularly, acidic amino acids are preferred, and glutamic acid is preferred. Especially preferred. The hydrocarbon group that forms an ester with the carboxyl group of such an amino acid is, for example, a branched alkyl group such as a lauryl group, a cetyl group, a stearyl group, or a behenyl group, a 2-ethylhexyl group, or an isostearyl group. Preferred examples include linear alkenyl groups such as alkyl groups, oleyl groups, linoleyl groups, and linolyl groups, and cyclic hydrocarbon groups such as cholesteryl groups and phytosteryl groups. Such an ester of N-acylamino acid can be obtained by treating an amino acid with an acid chloride in the presence of a base to form an N-acylamino acid, and condensing the corresponding alcohol in the presence of a base. As such N-acyl amino acid esters, if the amino acid is glutamic acid, specific examples of N-acyl (10-30 carbon atoms) dialkyl (1-30 carbon atoms) glutamic acid esters include: N-lauroyl-L-glutamate di (cholesteryl / behenyl / octyldodecyl), N-lauroyl-L-glutamate di (cholesteryl / octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl / behenyl / octyldodecyl), N -Lauroyl-L-glutamate di (phytosteryl / octyldodecyl) can be preferably exemplified, and N-lauroyl-L-glutamate di (cholesteryl / octyldodecyl) can be particularly suitably exemplified. N-acylated glutamic acid diesters can be synthesized in this way, but some are already commercially available as cosmetic raw materials, and such commercial products can be purchased and used. . Particularly preferred commercially available products are “El Deu PS203” (N-lauroyl-L-glutamate di (phytosteryl / octyldecyl)) and “El Deu CL-301” (N-lauroyl glutamate di (cholesteryl / Behenyl / octyldodecyl)), “Elduu CL-202” (N-lauroylglutamate di (cholesteryl / octyldodecyl)), “Elduu PS-304” (N-lauroylglutamate di (phytosteryl / behenyl / octyldodecyl)), etc. Among them, “El Dew PS203” is particularly preferable. Similarly, when the amino acid is glutamine, N-lauroylglutamine cholesteryl, N-lauroylglutamine phytosteryl and the like can be preferably exemplified. In the cosmetic composition of the present invention, the ester of N-acylamino acid dissolves the lipid component that penetrates deep into the skin of the pores and fixes the angular plugs to the pores, and the nonionic surfactant and It has the effect of enhancing the action of micelles made by water. In order to achieve such an effect, the total amount of the N-acylamino acid ester is preferably 0.05 to 3% by mass, and more preferably 0.1 to 1% by mass. If this is too much, the effect of the micelle may be impaired.

<3> Nonionic surfactant which is an essential component of the cosmetic composition of the present invention The cosmetic composition of the present invention has a hydrophilic nonionic surfactant having a branched alkyl group in the molecule as an essential component. It is characterized by containing 10 to 20% by mass, more preferably 12 to 15% by mass. Here, the term “hydrophilic” means that the HLB (hydrophilic / lipophilic balance) is at least 8 or more, and specifically, those having an addition mole number of 10 or more are preferable if they have a polyoxyethylene group. Further, the branched alkyl group may have an alkyl group or an acyl group. If it is an alkyl group, an isostearyl group, an octyldodecyl group, etc. can be illustrated suitably, and if it is an acyl group, a 2-ethylhexanoyl group, an isopalmitoyl group, an isostearoyl group etc. can be illustrated suitably. Preferable surfactants include, for example, polyoxyethylene (12) isostearate, polyoxyethylene (20) glyceryl monoisostearate, polyoxyethylene (20) glyceryl triisostearate and the like. As described above, this component forms micelles with water, assuring the wash-off property of the composition, works together with the ester of the N-acylamino acid, dissolves the lipid fixing the horn plug, It has the effect of extracting the square plug out of the pores. By such an action, the cosmetic composition of the present invention exhibits the same effect of removing the horn plug as that of the sheet-shaped horn plug remover while being a normal cleansing agent. If the amount of the hydrophilic nonionic surfactant having a branched alkyl group in the molecule is too large, the cleansing function may be impaired. If the amount is too small, the cleansing function, the wash-off function, and the plug removal function may be impaired. Exist.

<4> Cosmetic Composition of the Present Invention The cosmetic composition of the present invention is characterized by containing the essential components and having wash-off properties, a cleansing function, and a plug removal function. The wash-off function referred to in the present invention is a function of flushing away the cosmetic composition on the skin and the skin by simply scrubbing with warm water after the skin treatment with the cosmetic composition such as a cleansing operation. It means having. The property of the cosmetic composition of the present invention is a dosage form in which the aqueous phase is solubilized in the oil phase as described above, and is in the form of an oil that shows a transparent solution in the operating temperature range. The above-described function is manifested in such properties.

In the cosmetic composition of the present invention, in addition to such components, optional components usually used in cosmetics can be contained. Examples of such optional components, e.g., macadamia nut oil, Abou transient oil, corn oil, olive oil, rapeseed oil, sesame oil, castor oil, safflower oil, cottonseed oil, jojoba oil, coconut oil, palm oil, liquid lanolin, cured Oils such as coconut oil, hydrogenated oil, owl, hydrogenated castor oil, beeswax, candelilla wax, carnauba wax, ibotarou, lanolin, reduced lanolin, hard lanolin, jojoba wax, waxes , liquid paraffin, squalane, pristane, ozokerite, paraffin, ceresin , petrolatum, hydrocarbons such as microcrystalline wax, oleic acid, isostearic acid, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, higher fatty acids such as undecylenic acid, cetyl alcohol, stearyl alcohol, Isosuteari Alcohol, behenyl alcohol, octyldodecanol, myristyl alcohol, higher alcohols such as cetostearyl alcohol, cetyl isooctanoate, isopropyl myristate, isostearate hexyl decyl, diisopropyl adipate, sebacic di-2-ethylhexyl, cetyl lactate, malate Diisostearyl, di-2-ethylhexanoic acid ethylene glycol, dicaprate neopentyl glycol, di-2-heptylundecanoic acid glycerin, tri-2-ethylhexanoic acid glycerin, tri-2-ethylhexanoic acid trimethylolpropane, tri Diester carbonate such as trimethylolpropane isostearate, pentane erythritol tetra-2-ethylhexanoate, dicapryl carbonate, ethylene carbonate, propylene carbonate Synthetic ester oils and the like, dimethyl polysiloxane, methylphenyl polysiloxane, linear polysiloxanes such as diphenyl polysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, cyclic polysiloxanes such as dodeca methylcyclohexane siloxane, amino-modified polysiloxanes, polyether-modified polysiloxane, alkyl-modified polysiloxanes, modified polysiloxane emissions, fatty acid soaps, such as fluorine-modified polysiloxane (sodium laurate, sodium palmitate), potassium lauryl sulfate, anion and alkyl sulfate triethanolamine ether surfactants, stearyl trimethyl ammonium chloride, benzalkonium chloride, cationic surfactants such as lauryl amine oxide, imidazoline Amphoteric surfactants (such as 2-cocoyl-2-imidazolinium hydroxide-1-carboxyethyloxy disodium salt), betaine surfactants (such as alkyl betaines, amide betaines, sulfobetaines), acylmethyl taurines, etc. Amphoteric surfactants , sorbitan fatty acid esters (such as sorbitan monostearate, sorbitan sesquioleate), glycerin fatty acids (such as glyceryl monostearate), propylene glycol fatty acid esters (such as propylene glycol monostearate), cured castor Oil derivatives, glycerin alkyl ethers, POE sorbitan fatty acid esters (POE sorbitan monooleate, polyoxyethylene sorbitan monostearate, etc.), POE sorbite fatty acid esters (POE-sorbit mono) Ureates, etc.), POE glycerol fatty acid esters (POE-glycerol monostearate, etc.), POE fatty acid esters (polyethylene glycol monooleate, POE distearate, etc.), POE alkyl ethers (POE2-octyldodecyl ether, etc.), POE alkylphenyl Ethers (POE nonylphenyl ether, etc.), Pluronic types, POE / POP alkyl ethers (POE / POP2-tetradecyl ether, etc.), Tetronics, POE castor oil / hardened castor oil derivatives (POE castor oil, POE cured) castor oil, etc.), sucrose fatty acid esters, nonionic surface active agents that do not fall into essential components such as an alkyl glucoside, polyethylene glycol, glycerine, 1,3-butylene glycol, erythritol, Many types such as rubitol, xylitol, maltitol, propylene glycol, dipropylene glycol, diglycerin, isoprene glycol, 1,2-pentanediol, 2,4-hexanediol, 1,2-hexanediol, 1,2-octanediol valence alcohols, sodium pyrrolidone carboxylic acid, lactic acid, moisturizing ingredients, such as sodium lactate, may be surface treated, mica, talc, kaolin, synthetic mica, calcium carbonate, magnesium carbonate, silicic anhydride (silica), Powders such as aluminum oxide and barium sulfate , the surface may be treated, inorganic pigments such as bengara, yellow iron oxide, black iron oxide, cobalt oxide, ultramarine, bitumen, titanium oxide, zinc oxide , surface treatment It may also be used as a filter for titanium mica, fish phosphorus foil, bismuth oxychloride, etc. Lumpur agents, have been laked good Red No. 202 also red No. 228, Red No. 226, Yellow No. 4, Blue No. 404, Yellow No. 5, Red No. 505, 230 Red No., Red 223 No., orange 201 No., Red No. 213, Yellow No. 204, Yellow No. 203, Blue No. 1, Green No. 201, Purple No. 201, Red No. 204, and the like , polyethylene powder, polymethyl methacrylate, nylon powder, organopolysiloxane elastomer organic powders such like, para-aminobenzoic acid UV absorbers, anthranilic acid UV absorbers, salicylic acid ultraviolet absorbers, cinnamic acid UV absorbers, benzophenone UV absorbers, sugar-based ultraviolet absorber, 2- ( UV absorption such as 2'-hydroxy-5'-t-octylphenyl) benzotriazole, 4-methoxy-4'-t-butyldibenzoylmethane Adsorbents such as ethanol, lower alcohols such as isopropanol, vitamin A or its derivatives, vitamin B ₆ hydrochloride, vitamin B ₆ tripalmitate, vitamin B ₆ dioctanoate, vitamin B ₂ or derivatives thereof, vitamin B _12, vitamin B Vitamin B such as ₁₅ or derivatives thereof , α-tocopherol, β-tocopherol, γ-tocopherol, vitamin E such as vitamin E acetate, vitamin D, vitamin H, pantothenic acid, panthetin, pyrroloquinoline quinone etc., anti-microbial agents such as phenoxyethanol can be preferably exemplified. Particularly preferred among these are diester carbonates having a large solvent effect and excellent lipid dissolving action, among which dicapryl carbonate is particularly preferred and is preferably contained in an amount of 10 to 20% by mass based on the total amount of the cosmetic composition. Such components also have the effect of stabilizing the solubility of the nonionic surfactant in the oil phase. Further, in these particularly preferred it is a large effect of increasing the orientation of the N- acyl amino acid Jiesu ethers and branched alkyl nonionic surfactants from the bulk to the keratotic plug, methylphenyl polysiloxane (phenyl excellent keratotic plugs removal action Methicone) is particularly preferable, and it is preferably contained in an amount of 5 to 15% by mass based on the total amount of the cosmetic composition. Such a component works as a release agent from the pores of the square plugs, and also has an effect of easily removing the square plugs.

The cosmetic composition of the present invention can be produced by treating the essential components and optional components according to a conventional method. The cosmetic composition thus obtained can be directly filled in a bottle or the like and used as a cosmetic, or impregnated into a support such as a nonwoven fabric, lint cloth, gauze, cut cotton, etc. It can be pasted and used as a sticking agent. In the impregnation, it is preferred to impregnate the cosmetic composition of 1~3g respect to the support 50 cm ² having a basis weight of 100 g / m ^2. The impregnation can be carried out by packing a pre-impregnated product, or it can be used by impregnating the support with a cosmetic composition at the time of use. When used as a cosmetic or a sticking agent, it should be rubbed or pasted so that the square plug and the cosmetic composition are in contact with each other for at least 5 minutes, and then rinsed with warm water under the rubbing conditions and used in a state of washing away. preferable. Further, it is preferable that the support in the case of rubbing is processed with unevenness.

  Hereinafter, the present invention will be described in more detail with reference to examples.

According to the prescription of Table 1 shown below, the cosmetic composition 1 which is the cosmetic composition of the present invention was obtained. That is, while heating the prescription ingredients at 80 ° C., the mixture was stirred and solubilized, cooled by stirring, and a transparent oily cosmetic composition 1 was obtained. In the same manner, Comparative Example 1 in which “Erudu PS203” was replaced with POE (12) isostearic acid, POE (12) isostearic acid was replaced with POE (10) oleic acid, and POE (20) glyceryl isostearate was olein. Comparative Example 2 in which the acid POE (20) was replaced with glyceryl, Comparative Example 3 in which the water was replaced with dicapryl carbonate, and "El Dew PS203", and POE (12) isostearic acid into POE (10) oleic acid, and isostearic acid POE (20) Comparative Example 4 in which glyceryl was replaced with oleic acid POE (20) glyceryl and water was replaced with dicapryl carbonate was also produced in the same manner. Comparative Examples 1 and 2 exhibited a transparent oil form, and Comparative Examples 3 and 4 exhibited a slightly cloudy oil form.

<Evaluation 1>
For cosmetic composition 1 and Comparative Examples 1 to 4, the effect of removing the angular plugs when the cosmetic composition was used as a cosmetic (oil cleansing) was examined. The method is to spread the specimen on the half-face, rub it for 3 minutes, wash the face with facial cleanser using warm water, remove the square plugs with a commercially available square plug removal sheet, and per unit area fixed to the sheet. The number of square plugs was counted under a microscope. The remaining half face was washed with soap, and then the number of square plugs per unit area that had been removed from the square plugs and fixed to the sheet with a commercially available square plug removal sheet was counted under a microscope. The number of treated square plugs was divided by the number of untreated square plugs, and a value obtained by multiplying by 100 was used as the residual plug percentage, and the plug removal ability was evaluated by this amount. The results are shown in Table 2. From this, it can be seen that the cosmetic composition of the present invention is excellent in the action of removing horn plugs.

<Evaluation 2>
The face wash with the face wash of Evaluation 1 was changed to a mode of pouring with warm water for 1 minute under rubbing and evaluated in the same manner. The results are shown in Table 3. Use a surfactant that does not have a branched alkyl group as a surfactant, or if there is no water and it is cloudy, the cosmetic composition remains on the skin. You can see that it is hindering.

<Evaluation 3>
About the cosmetic composition 1 and Comparative Examples 1-4, the wash-off cleansing function at the time of using a cosmetic composition as cosmetics (oil cleansing) was investigated. Specifically, 0.1 g of lip color is applied to a 2 cm × 4 cm portion provided on the inner side of the forearm, and 0.1 ml of the sample is put on this, and after rubbing with a finger for 5 minutes, rubbing with warm running water for 2 minutes, towel The remaining wiping lip color was observed. The results are shown in Table 4. It can be seen that the cosmetic composition of the present invention has a cleansing function.

As in Example 1, according to the formulation in Table 5 shown below, and the cosmetic composition 2 was created made. In this method, the residual rate of horn plugs was 6% in the method of Evaluation 1, and the difference between the background and the site was not recognized even in the measurement of the wash-off cleansing function according to Evaluation 3, and the same effect as in Cosmetic Composition 1 was confirmed. .

As in Example 1, according to the formulations shown in Table 6 shown below, and the cosmetic composition 3 was created made. In this method, the residual rate of horn plugs was 12% in the method of Evaluation 1, and even in the measurement of the wash-off cleansing function according to Evaluation 3, there was almost no difference between the background and the site, which was slightly inferior to the cosmetic composition 1, but the same The effect was recognized. It turns out that the form containing a carbonic acid diester is especially preferable.

As in Example 1, according to the formulations shown in Table 7 shown below, and the cosmetic composition 4 was created made. In this method, the residual rate of horn plugs was 10% in the method of Evaluation 1, and even when measuring the wash-off cleansing function according to Evaluation 3, there was almost no difference between the background and the site, which was slightly inferior to the cosmetic composition 1, but the same The effect was recognized. It can be seen that the form containing phenylmethicone is particularly preferred.

As in Example 1, according to the formulation in Table 8 shown below, and the cosmetic composition 5 was created made. This is the method of evaluation 1 and the residual rate of horn plugs is 9%, and even in the measurement of the wash-off cleansing function according to evaluation 3, there is almost no difference between the background and the site, which is slightly inferior to the cosmetic composition 1, but the same The effect was recognized. It turns out that the upper limit of content of water is about 4 mass%.

The cosmetic compositions 1 to 5 are each applied to a nonwoven fabric sheet having a basis weight of 100 g / m ² and 7 cm × 7 cm . 5 g was impregnated to obtain sheet-type cleansings 1 to 5 . This was applied to the nose for 5 minutes, and then evaluated in the same manner as in Evaluation 2 in the form of washing off with warm water. The results are shown in Table 9. Results similar to those used as cosmetics were obtained.

The cosmetic compositions 1 to 5 are each applied to a nonwoven fabric sheet having a basis weight of 100 g / m ² and 7 cm × 7 cm . 5 g was impregnated to obtain sheet-type cleansings 1 to 5 . Evaluation was performed in the same manner as in Evaluation 2 in such a manner that the nose was rubbed for 1 minute and then washed off with warm water. The results are shown in Table 10. Results similar to those used as cosmetics were obtained.

  The present invention can be applied to cosmetic compositions and cosmetics.

Claims (7)

A cosmetic composition for removing horn plugs that has a contact time with pores of at least 1 minute or more and is washed away after use, 1) 1 to 4% by mass of water, and 2) N-acylamino acid A cosmetic composition for removing horn plugs, comprising 0.1 to 1% by mass of an ester and 3) 12 to 15% by mass of polyoxyethylene (20) glyceryl triisostearate . The cosmetic composition for removing horn plugs according to claim 1, characterized in that the aqueous phase is a dosage form solubilized in the oil phase and exhibits a fluid and transparent property at 25 ° C. The cosmetic composition according to claim 1 or 2, wherein the cosmetic composition is impregnated on a support, attached to the nose for 5 minutes or longer, peeled off from the nose, and then washed with water. object. The cosmetic composition according to claim 1, further comprising a carbonic acid diester. Furthermore, phenylmethicone is contained, The cosmetic composition in any one of Claims 1-3 characterized by the above-mentioned. A sticking agent for removing horn plugs, wherein a support is impregnated with the cosmetic composition according to any one of claims 1 to 5. A cosmetic comprising the cosmetic composition according to any one of claims 1 to 5 impregnated in a support and scraped together with the support.