JP4266904B2 - Emulsified cosmetics - Google Patents

Description

  The present invention relates to an emulsifier type cosmetic, and more particularly to an emulsifier type cosmetic suitable as a cleansing cream or massage cream.

  In the emulsifier type cosmetics, massage cosmetics and cleansing cosmetics exist as typical cosmetics containing an oil content of 50% by mass or more. These have similarities in terms of the properties of high internal phase oil-in-water emulsions, but massage cosmetics do not cause irritation due to excessive friction, but have effects such as increased blood flow due to massage with moderate stimulation. Whereas cleansing cosmetics have the effect of removing oil stains due to the solvent effect of the oil present in the inner phase, the effect is greatly different. Even in a configuration that supports these characteristics, massage cosmetics are high-grade to liquid oils and fats, such as oil, for the purpose of reducing the coefficient of friction on the skin and embodying moderate finger skin adhesion. In addition to solid fats such as alcohol, the oil phase itself takes a solid or semi-solid form, whereas cleansing cosmetics refrain from blending solid fats as much as possible to maximize the solvent effect. This is a principle, and in this sense, it can be said that the dosage form differs greatly in composition.

  On the other hand, along with the speeding up of the world, in the cosmetics field, the flow of simplification of makeup steps has become one of the tides of the last decades. Even in cleansing cosmetics and massage cosmetics, this trend has a great impact, and the development of multifunctional cosmetics that combine these functions is continuing. For example, massage pack cosmetics (see, for example, Patent Document 1), cleansing pack cosmetics (see, for example, Patent Document 2 and Patent Document 3), and oil-based cleaning materials having a massage function (for example, Patent Document) 4) is known. However, since the technique of Patent Document 4 is the provision of a massage function at the expense of the cleansing function, a cosmetic having a massage function and a cleansing function that can exist independently has not been developed yet. Is the current situation.

  On the other hand, it is a cosmetic which takes an oil-in-water emulsion form containing a fatty acid soap, and at least two kinds of cosmetics containing a mono-fatty acid ester of polyglycerol are not known at all, but a cosmetic containing a polyglycerol fatty acid ester As a material, application to foaming cosmetics (for example, see Patent Document 5 and Patent Document 6) and cleansing cosmetics (for example, see Patent Document 7) is known.

Japanese Patent Laid-Open No. 11-341292 JP 2002-187715 A Japanese Patent Laid-Open No. 7-173033 JP 2001-278742 A JP 2004-168714 A JP 2004-83498 A JP 2004-83438 A

  The present invention has been made under such circumstances, and an object of the present invention is to provide a cosmetic having a massage function and a cleansing function that can exist independently of each other.

In view of such a situation, the present inventors have sought for cosmetics having a massage function and a cleansing function that can exist independently, and as a result of intensive research efforts, an oil-in-water emulsification containing a fatty acid soap It has been found that cosmetics that take a form and contain at least two types of polyglycerin mono-fatty acid esters of lipophilicity and hydrophilicity have such characteristics, and have led to the completion of the invention. It was. That is, the present invention is as follows.
(1) fatty acid soap a cosmetic that takes an oil-in-water emulsion form comprising, at least a polymerization degree of 2 to degree of polymerization of the lipophilic polyglycerol mono-fatty acid ester and glycerin 3 of glycerin 7-12 hydrophilic A cosmetic for cleansing or massage , comprising two types of polyglycerin monofatty acid ester of polyglycerin monofatty acid ester. (2) as the lipophilic polyglycerol mono-fatty acid ester, a diglycerin mono fatty acid esters, as the hydrophilic polyglycerol mono-fatty acid esters, characterized in that it contains a decaglycerin fatty acid ester, as described in (1) Cosmetics.
(3) The cosmetic according to (2), comprising diglycerin monolaurate as the diglycerin monofatty acid ester and decaglycerin monooleate as the decaglycerin monofatty acid ester.
(4) The cosmetic according to any one of (1) to (3), wherein the fatty acid soap contains a hydroxy fatty acid soap.
(5) The cosmetic according to any one of (1) to (4), wherein the fatty acid soap contains a branched fatty acid soap.
(6) The cosmetic according to any one of (1) to (5), further comprising diglycerin tetraoleate.

  ADVANTAGE OF THE INVENTION According to this invention, the cosmetics which have the massage function and cleansing function which can exist independently can be provided.

(1) Polyglycerin monofatty acid ester which is an essential component of the cosmetic of the present invention The cosmetic of the present invention is a cosmetic taking an oil-in-water emulsion form containing a fatty acid soap, and is at least hydrophilic and lipophilic 2 It contains polyglycerol mono-fatty acid ester of seeds. Examples of the hydrophilic polyglycerin monofatty acid ester include those having a degree of polymerization of glycerin of 7 to 12 as the polyglycerin moiety constituting the hydrophilic polyglycerin monofatty acid ester. Moreover, as a fatty acid residue, as long as it is generally known, it can be used without any particular limitation, for example, a linear fatty acid residue having 10 to 30 carbon atoms, a fatty acid residue having a branched chain, A fatty acid residue having a cyclic structure, a fatty acid residue having an unsaturated bond and the like can be preferably exemplified. Specifically, for example, lauric acid residue, myristic acid residue, palmitic acid residue, stearic acid residue, behen Preferred examples include acid residues, isostearic acid residues, octyldodecanoic acid residues, oleic acid residues, linoleic acid residues, linolenic acid residues and the like. More preferable examples include a lauric acid residue, a stearic acid residue, an isostearic acid residue or an oleic acid residue. As such a hydrophilic polyglycerin monofatty acid ester, decaglycerin monofatty acid ester can be preferably exemplified, and among them, decaglycerin monooleate is particularly preferred. The degree of polymerization of glycerin in the polyglycerin moiety in the polyglycerin monofatty acid ester as a lipophilic surfactant is 2 to 3. Examples of the fatty acid moiety are preferably linear fatty acid residues having 10 to 30 carbon atoms, fatty acid residues having a branched chain, fatty acid residues having a cyclic structure, fatty acid residues having an unsaturated bond, and the like. Specifically, for example, lauric acid residue, myristic acid residue, palmitic acid residue, stearic acid residue, behenic acid residue, isostearic acid residue, octyldodecanoic acid residue, oleic acid residue, linoleic acid residue Preferred examples include groups and linolenic acid residues. More preferable examples include lauric acid residues, stearic acid residues, isostearic acid residues, and oleic acid residues, and lauric acid residues are particularly preferable. Particularly preferred is diglycerin monolaurate. In the cosmetic of the present invention, the polyglycerin monofatty acid ester is a hydrophilic surfactant and a lipophilic surfactant, but each can contain only one species, or two or more species. Can also be contained in combination. In the cosmetic of the present invention, the preferred content of the polyglycerin monofatty acid ester is preferably 1 to 10% by mass, more preferably 2 to 7% by mass with respect to the total amount of the cosmetic.

(2) Fatty acid soap which is an essential component of the cosmetic of the present invention The cosmetic of the present invention contains a fatty acid soap as an essential component and is in an oil-in-water emulsion form. Among the fatty acid soaps that can be contained in the cosmetics of the present invention, the alkali components that form soaps can be used without particular limitation as long as they are alkali components that are usually used in cosmetics, such as sodium and potassium. Preferred examples include alkali metals of the above, alkaline earth metals such as calcium and magnesium, organic amine salts such as ammonium, triethanolamine and triethylamine, and basic amino acids such as lysine and arginine. Particularly preferred is a form taking an alkali metal salt, and a form using sodium and potassium in combination is particularly preferred. The amount ratio in this case is preferably 99 to 90 potassium hydroxide with respect to 1 to 10 sodium hydroxide in terms of mass ratio in the form of hydroxide. In order to form such soaps, these alkalis may be reacted with fatty acids in the form of hydroxides. The alkali content is preferably 0.1 to 1.5% by mass, more preferably 0.2 to 1.3% by mass in terms of the total amount of hydroxide.

  Moreover, as a fatty acid part which comprises fatty acid soap, if it is normally used by cosmetics, it can be used without special limitation, for example, lauric acid, myristic acid, palmitic acid, stearic acid, Preferred examples include saturated linear fatty acids such as behenic acid, unsaturated linear fatty acids such as oleic acid, linoleic acid, and linolenic acid, branched fatty acids such as isostearic acid, and hydroxy fatty acids such as lithinolic acid and 12-hydroxystearic acid. The fatty acid which comprises this soap can also contain a seed | species alone, and can also be contained in combination of 2 or more types. The content of the fatty acid in the cosmetic of the present invention is preferably 1 to 5% by mass, more preferably 1.1 to 4% by mass, as the total amount of fatty acid. This is because the fatty acid soap acts as a hydrophilic emulsifier in the cosmetic of the present invention. If the amount is too small, the emulsification system may not be stable. If the amount is too large, the usability such as increase in viscosity over time may be impaired. This is to exist.

  In the case where a fatty acid is used in combination as a soap, the inclusion of a hydroxy fatty acid is preferable in terms of improving the emulsion stability. In order to achieve such an effect, it is preferable that the hydroxy fatty acid is contained in an amount of 1 to 5% by mass of the total amount of fatty acid and 0.05 to 0.5% by mass based on the total amount of the cosmetic.

  In the case of using a fatty acid in combination as a soap, the inclusion of a branched fatty acid is preferable in terms of improving high-temperature stability. In order to exhibit such an effect, it is preferable that the branched fatty acid is contained in an amount of 0.5 to 5% by mass based on the total amount of the fatty acid and 0.01 to 0.5% by mass based on the total amount of the cosmetic.

(3) Cosmetics of this invention The cosmetics of this invention contain the said essential component, and take an oil-in-water emulsion form, It is characterized by the above-mentioned. In addition, it has a feature that it contains 50% by mass or more of oil and contains little or no higher alcohol such as cetanol. From such characteristics, the cosmetic of the present invention can fully utilize the solvent effect of the oil, and thus can exhibit an excellent cleansing effect. In addition, a highly stable emulsion based on the combination of essential ingredients exhibits a frictional resistance that is moderate but not excessive enough to cause irritation when spread on the skin during use. It can also be used as a fee. In other words, by taking such a configuration, it can be said that a cosmetic having a massage function and a cleansing function that can exist independently can be realized.

In the cosmetics of this invention, the arbitrary component normally used by cosmetics other than the said essential component can be contained. Examples of such optional components include, for example, macadamia nut oil, avocado oil, corn oil, olive oil, rapeseed oil, sesame oil, castor oil, safflower oil, cottonseed oil, jojoba oil, and palm oil. Oils such as palm oil, liquid lanolin, hydrogenated coconut oil, hydrogenated oil, molasses, hydrogenated castor oil, beeswax, candelilla wax, carnauba wax, ibota wax, lanolin, reduced lanolin, hard lanolin, jojoba wax, waxes, liquid paraffin, squalane , Hydrocarbons such as pristane, ozokerite, paraffin, ceresin, petrolatum, microcrystalline wax, cetyl alcohol, stearyl alcohol, isostearyl alcohol, behenyl alcohol, octyldodecanol, myristyl alcohol, cetostearyl Higher alcohols such as alcohol, cetyl isooctanoate, isopropyl myristate, hexyl decyl isostearate, diisopropyl adipate, di-2-ethylhexyl sebacate, cetyl lactate, diisostearyl malate, ethylene glycol di-2-ethylhexanoate , Neopentyl glycol dicaprate, glycerin di-2-heptylundecanoate, glycerin tri-2-ethylhexanoate, trimethylolpropane tri-2-ethylhexanoate, trimethylolpropane triisostearate, tetra-2-ethylhexanoic acid Synthetic ester oils such as pentane erythritol, diglycerin tetraoleate, diglycerindiolate, diglycerin trioleate, diglycerin tetraisostearate, diglycerin triiso Tearate, diglycerin diisostearate, triglycerin pentaoleate, triglycerin tetraoleate, triglycerin trioleate, triglycerin diolate, triglycerin pentaisostearate, triglycerin tetraisostearate, triglycerin triisostearate, Polyglycerin fatty acid esters not classified as polyglycerin monofatty acid esters of essential components such as triglycerin diisostearate, chain polysiloxanes such as dimethylpolysiloxane, methylphenylpolysiloxane, diphenylpolysiloxane, octamethylcyclotetrasiloxane, Cyclic polysiloxanes such as decamethylcyclopentasiloxane and dodecamethylcyclohexanesiloxane, amino-modified polysiloxanes, polyether modified Oils such as silicone oils such as functional polysiloxane, alkyl-modified polysiloxane, modified polysiloxane such as fluorine-modified polysiloxane, anionic surfactants such as potassium lauryl sulfate, alkylethanol triethanolamine ether, stearyltrimethylammonium chloride, Cationic surfactants such as benzalkonium chloride and laurylamine oxide, imidazoline amphoteric surfactants (such as 2-cocoyl-2-imidazolinium hydroxide-1-carboxyethyloxy disodium salt), betaine surfactants Agents (alkylbetaines, amidebetaines, sulfobetaines, etc.), amphoteric surfactants such as acylmethyltaurine, sorbitan fatty acid esters (sorbitan monostearate, sorbitan sesquioleate, etc.), glycerin fatty acids Glyceryl monostearate, etc.), propylene glycol fatty acid esters (propylene glycol monostearate, etc.), hardened castor oil derivatives, glycerin alkyl ethers, POE sorbitan fatty acid esters (POE sorbitan monooleate, polyoxyethylene sorbitan monostearate, etc.) ), POE sorbite fatty acid esters (such as POE-sorbite monolaurate), POE glycerin fatty acid esters (such as POE-glycerin monoisostearate), POE fatty acid esters (such as polyethylene glycol monooleate, POE distearate), POE alkyl Ethers (POE2-octyldodecyl ether, etc.), POE alkylphenyl ethers (POE nonylphenyl ether, etc.), Pluronic types, P E / POP alkyl ethers (POE / POP2-decyltetradecyl ether, etc.), Tetronics, POE castor oil / hardened castor oil derivatives (POE castor oil, POE hardened castor oil, etc.), sucrose fatty acid ester, alkyl glucoside, etc. Nonionic surfactants, polyethylene glycol, glycerin, 1,3-butylene glycol, erythritol, sorbitol, xylitol, maltitol, propylene glycol, dipropylene glycol, diglycerin, isoprene glycol, 1,2-pentanediol, 2 Polyhydric alcohols such as 1,4-hexylene glycol, 1,2-hexanediol, 1,2-octanediol, moisturizing ingredients such as sodium pyrrolidonecarboxylate, lactic acid, sodium lactate, guar gum, quince seed, Laginan, galactan, gum arabic, pectin, mannan, starch, xanthan gum, curdlan, methylcellulose, hydroxyethylcellulose, carboxymethylcellulose, methylhydroxypropylcellulose, chondroitin sulfate, dermatan sulfate, glycogen, heparan sulfate, hyaluronic acid, sodium hyaluronate, tragacanth gum , Keratan sulfate, chondroitin, mucoitin sulfate, hydroxyethyl guar gum, carboxymethyl guar gum, dextran, keratosulfate, locust bean gum, succinoglucan, caronic acid, chitin, chitosan, carboxymethyl chitin, agar, polyvinyl alcohol, polyvinyl pyrrolidone, carboxy Vinyl polymer, sodium polyacrylate, polyethylene glycol Thickeners such as bentonite, surface may be treated, powders such as mica, talc, kaolin, synthetic mica, calcium carbonate, magnesium carbonate, anhydrous silicic acid (silica), aluminum oxide, barium sulfate, surface May be treated, bengara, yellow iron oxide, black iron oxide, cobalt oxide, ultramarine, bitumen, titanium oxide, zinc oxide inorganic pigments, surface may be treated, titanium mica, fish phosphorus foil Pearls such as bismuth oxychloride, lake 202, red 228, red 226, yellow 4, blue 404, yellow 5, red 505, red 230, red Organic dyes such as No. 223, Orange No. 201, Red No. 213, Yellow No. 204, Yellow No. 203, Blue No. 1, Green No. 201, Purple No. 201, Red No. 204, polyethylene powder Organic powders such as polymethyl methacrylate, nylon powder, organopolysiloxane elastomer, paraaminobenzoic acid UV absorber, anthranilic acid UV absorber, salicylic acid UV absorber, cinnamic acid UV absorber, benzophenone UV Absorbers, sugar-based UV absorbers, UV absorbers such as 2- (2′-hydroxy-5′-t-octylphenyl) benzotriazole, 4-methoxy-4′-t-butyldibenzoylmethane, ethanol, Lower alcohols such as isopropanol, vitamin A or its derivatives, vitamin B6 hydrochloride, vitamin B6 tripalmitate, vitamin B6 dioctanoate, vitamin B2 or its derivatives, vitamin B such as vitamin B12, vitamin B15 or its derivatives, α- Tocopherol, β-tocopherol, γ-tokov Preferred examples include vitamin E such as erol and vitamin E acetate, vitamin D, vitamin H, pantothenic acid, panthetin, pyrroloquinoline quinone and the like.

  Among these optional components, particularly preferred components are diglycerin tetraoleate, diglycerindiolate, diglycerin trioleate, diglycerin tetraisostearate, diglycerin triisostearate, diglycerin diisostearate, triglycerin. Essential components such as pentaoleate, triglycerin tetraoleate, triglycerin trioleate, triglycerindiolate, triglycerin pentaisostearate, triglycerin tetraisostearate, triglycerin triisostearate, triglycerin diisostearate Polyglycerin fatty acid esters that are not classified as polyglycerin monofatty acid esters, and among them, diglycerin tetraoleate is particularly preferable. These can contain only the seed | species, and can also be made to contain in combination of 2 or more type. A particularly preferred form is a form containing only the diglycerin tetraoleate. Moreover, as content, 20-45 mass% is preferable, and 25-40 mass% is more preferable. This is because an excellent solvent effect is exhibited in this range and the cleansing action is excellent.

  The cosmetic of the present invention can be produced by treating the above components according to a conventional method. The cosmetic thus obtained has excellent stability, and at the same time has a massage function and a cleansing function that can exist independently of each other. In order to utilize this, it is preferable that the cosmetic of the present invention is applied to a multifunctional cosmetic such as a cleansing massage or a massage cleansing. Of course, since the cosmetic of the present invention can have basic characteristics as a basic cosmetic by containing an active ingredient, utilization in such a preparation also belongs to the technical field of the present invention.

  Hereinafter, the present invention will be described in more detail with reference to examples, but it is needless to say that the present invention is not limited to such examples.

<Example 1>
Accordance with the formulations shown in below, a cosmetic of the present invention were prepared emulsified cosmetic. That is, components (a) and (b) were heated to 80 ° C., and (b) was gradually added to emulsify with stirring, followed by stirring and cooling to obtain a creamy cosmetic 1 in the form of an oil-in-water emulsifier.

<Test Example 1>
The cleansing effect of cosmetic 1 was examined. That is, using the eyeliner shown below, apply the eyeliner uniformly to the 1cm x 2cm part provided on the inner side of the forearm, and rub well with 0.1g of cosmetic 1 and cut. After wiping with cotton, it was rinsed with running water and dried, and then the color difference (ΔE) from the untreated site was measured. Comparative Example 1 in which diglycerin monolaurate and decaglycerin monooleate of cosmetic 1 were replaced with POE (20) oleate, and Comparative Example 2 in which fatty acid and alkali were replaced with POE (45) stearate were also prepared. The same was tested. The test results are shown in Table 2. From this, it can be seen that the cosmetic of the present invention is excellent in cleansing action. Moreover, it turns out that this outstanding cleansing effect is synergistically expressed by the combination of polyglycerol mono fatty acid ester and fatty acid soap.

(eyeliner)
Microcrystalline wax 20% by mass
Iron black 10% by mass
Cetanol 5% by mass
Stearic acid 3% by mass
Zinc stearate 3% by mass
Morpholine 2% by mass
1,3-butanediol 8% by mass
11% by mass of water
Polymethyl methacrylate emulsion 30% by mass

<Test Example 2>
About the cosmetics 1, the comparative example 1, and the comparative example 2 of the test example 1, the effect as a massage material was confirmed. The effect as a massage fee is that massage treatment is performed using these cosmetics by estheticians using five panelists, and the concentration of plasterone sulfate in saliva is measured by the sandwich antibody method before and after the treatment, The rate of increase by treatment was calculated and evaluated using it as an index. At the same time, the skin color difference before and after the treatment was measured. The results are shown in Table 3. From this, it can be seen that the cosmetic 1 according to the present invention embodies comfort and does not cause redness or the like, and provides an appropriate stimulus.

<Example 2>
Like the actual Example 1, in accordance with the following Table 4 were prepared cosmetic 2. When evaluated by the method of Test Example 1, the color difference (ΔE) is 0.49, the rate of increase in plasterone sulfate in the evaluation of Test Example 2 is 12.9%, and the color difference of the skin color at that time is 0.62. Met. It seems to have the same effect as cosmetic 1.

<Reference Example 1>
In the same manner as in Example 1, the cosmetic material of Reference Example 1 was prepared according to Table 5 below. When evaluated by the method of Test Example 1, the color difference (ΔE) is 0.72, the rate of increase in plasterone sulfate in the evaluation of Test Example 2 is 10.3%, and the color difference of the skin color at that time is 0.76. Met. It seems to have the same effect as cosmetic 1. However, it is judged that cosmetic 1 is superior as an effect. From this, Poriguriseri Nmo Roh fatty acid ester is found also it is preferable that a combination of two hydrophilic and lipophilic.

<Example 3>
In the same manner as in Example 1, cosmetic 3 was prepared according to Table 6 below. When evaluated by the method of Test Example 1, the color difference (ΔE) is 0.67, the rate of increase of plasterone sulfate in the evaluation of Test Example 2 is 9.4%, and the color difference of the skin color at that time is 0.92. Met. It seems to have the same effect as cosmetic 1. However, it is judged that cosmetic 1 is superior as an effect. This shows that it is preferable to contain a hydroxy fatty acid.

  The present invention can be applied to complex cosmetics such as cleansing massage materials.

Claims (6)

A cosmetic comprising an oil-in-water emulsion containing a fatty acid soap, wherein at least a lipophilic polyglycerin monofatty acid ester having a degree of polymerization of glycerin of 2 to 3 and a degree of polymerization of glycerin of 7 to 12 is a hydrophilic polyglycerin mono A cosmetic for cleansing or massage , comprising two polyglycerin monofatty acid esters of fatty acid esters. The lipophilic polyglycerol mono-fatty acid ester, a diglycerin mono fatty acid esters, as the hydrophilic polyglycerol mono-fatty acid esters, characterized in that it contains a decaglycerin fatty acid esters, cosmetic composition according to claim 1.   The cosmetic according to claim 2, comprising diglycerin monolaurate as the diglycerin monofatty acid ester, and decaglycerin monooleate as the decaglycerin monofatty acid ester.   The cosmetic according to any one of claims 1 to 3, wherein the fatty acid soap contains a hydroxy fatty acid soap.   The cosmetic according to any one of claims 1 to 4, wherein the fatty acid soap contains a branched fatty acid soap.   Furthermore, diglycerin tetraoleate is contained, Cosmetics in any one of Claims 1-5 characterized by the above-mentioned.