CN105473120B - Compond fibre table for removing lipstick - Google Patents
Compond fibre table for removing lipstick Download PDFInfo
- Publication number
- CN105473120B CN105473120B CN201480042903.4A CN201480042903A CN105473120B CN 105473120 B CN105473120 B CN 105473120B CN 201480042903 A CN201480042903 A CN 201480042903A CN 105473120 B CN105473120 B CN 105473120B
- Authority
- CN
- China
- Prior art keywords
- mentioned
- makeup removing
- mass
- emulsification composition
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0208—Tissues; Wipes; Patches
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
Abstract
The present invention provides a kind of Compond fibre table for removing lipstick, although the Compond fibre table for removing lipstick ratio of viscosities is relatively low, the excellent storage stability of makeup removing emulsification composition, and especially excellent makeup removing power can have been given play to.The Compond fibre table for removing lipstick of the present invention possesses plate substrate and the makeup removing emulsification composition being impregnated in above-mentioned plate substrate, above-mentioned makeup removing emulsification composition contains nonionic surface active agent, acrylic arid methacrylic acid alkyl ester copolymer and finish, above-mentioned nonionic surface active agent is at least one kind of in the group being made up of two isostearic acid polyoxyethylene glycerides, single isostearic acid polyoxyethylene glyceride and Crodaret, and above-mentioned makeup removing is below 1000mPas in 25 DEG C of viscosity with emulsification composition.
Description
Technical field
The present invention relates to the Compond fibre table for removing lipstick that makeup removing emulsification composition is impregnated with plate substrate.
Background technology
In order to remove ornaments and formal dress etc., it with cosmetic preparation is well-known to have used makeup removing of the makeup removing with composition.In recent years, it is
Simply and quickly removed ornaments and formal dress, make the use increase for the Compond fibre table for removing lipstick that makeup removing is impregnated in composition in plate substrate.In addition, make
For above-mentioned makeup removing composition, the not fluid composition of emulsion and emulsification composition etc. be present.
Above-mentioned makeup removing is with piece cosmetic preparation e.g., as disclosed in following patent documents 1~5.
Make O/W emulsion composition be impregnated in the sheet in non-woven fabrics to unload Patent Document 1 discloses a kind of following
Adornment material.Above-mentioned O/W emulsion composition contains：(A) water soluble compound (a) comprising the mass % of 1 mass %~25
(water soluble compound (a) has the polyoxypropylene structure that expoxy propane addition molal quantity is more than 3 and without carbon original aqueous phase
Alkyl and/or the polyoxyethylene structure that subnumber is more than 4)；(B) boiling point under the 1013.25hPa comprising more than 50 mass % is
The oil phase of 160 DEG C~300 DEG C of finish (b)；(C) has the mass % of mass % of AQUO-THICKENING AGENT 0.01~1 of hydrophobic portion.
In above-mentioned O/W emulsion composition, (A) aqueous phase and the mass ratio ((A) of (B) oil phase:(B) it is) 97:3~40:60.
Emulsion cosmetic preparation is set to be impregnated in the cosmetic removing material in plate substrate Patent Document 2 discloses a kind of following, the breast
Liquefaction makeup material 25 DEG C of viscosity be 200mPas~4000mPas and 50 DEG C of viscosity be 100mPas~
2000mPa·s.In addition, in patent document 2, as above-mentioned emulsion cosmetic preparation, describe it is a kind of comprising the weight % of finish 10~
The weight % of the weight % and weight % of surfactant 0.5 of 80 weight %, the weight % of water 10~80~10 emulsion cosmetic preparation.
A kind of emulsion cosmetic preparation is recorded in the embodiment of patent document 2, its ratio of viscosities is higher, and 25 DEG C of viscosity is
1100mPas~1500mPas.In addition, a kind of emulsion cosmetic preparation, its viscosity are recorded in the comparative example of patent document 2
It is 150mPas than relatively low, 25 DEG C viscosity.But the description below is recorded in patent document 2：If 25 DEG C of viscosity is
150mPas, then liquid stability and dipstick bad stability.
Following Patent Document 3 discloses a kind of sheet cosmetic removing cosmetic preparation, it is to make 25 DEG C of viscosity be 200mPas
Following emulsion compositions are impregnated in what is formed in plate substrate.Above-mentioned emulsion composition includes mass %~3 of (A) phospholipid 0.1
The mass % of the mass % of quality %, the mass % of (B) liquid oil 0.1~15, the mass % of (C) polyalcohol 1~25 and the matter of (D) water 40
Measure the mass % of %~85.
The relatively low emulsion compositions of ratio of viscosities have been recorded in the embodiment of patent document 3, but for the Emulsion combination
The stability of thing is not recorded especially.
O/W emulsion composition is set to be impregnated in the piece formed in non-woven fabrics Patent Document 4 discloses a kind of following
Shape cosmetic removing material.Above-mentioned O/W emulsion composition includes the mass % of the mass % of AQUO-THICKENING AGENT 0.01~0.5, boiling point is
The mass % of 160 DEG C~300 DEG C of the mass % of finish 5~30 and water.
Liquid makeup removing agent composition is set to be impregnated in the makeup removing formed in plate substrate Patent Document 5 discloses a kind of following
Piece.The viscosity that above-mentioned liquid makeup removing agent composition includes 25 DEG C of (A) as oil components be 1000mPas~
50000mPas finish and 25 DEG C of (B) viscosity are below 20mPas finish.(A) composition in whole oil components
Total content with (B) composition is more than 30 mass %.(A) mass ratio ((B)/(A)) of composition and (B) composition is 1~5.In addition,
Above-mentioned liquid makeup removing agent composition has been recorded in patent document 5 can include the mass % of 3 mass %~30 (C) nonionic table
Face activating agent.
Prior art literature
Patent document
Patent document 1：Japanese Unexamined Patent Publication 2005-239561 publications
Patent document 2：Japanese Unexamined Patent Publication 2001-302450 publications
Patent document 3：Japanese Unexamined Patent Publication 2003-183126 publications
Patent document 4：Japanese Unexamined Patent Publication 2005-145872 publications
Patent document 5：Japanese Unexamined Patent Publication 2006-306780 publications
The content of the invention
The invention problem to be solved
In order to improve makeup removing effect, the mixture finish in above-mentioned Compond fibre table for removing lipstick in most cases.But for stably mixture
Finish and when to make above-mentioned cleansing composition be emulsified state, although mixture finish, makeup removing power reduce sometimes.
If in addition, making makeup removing with composition be emulsified state, the viscosity rise of makeup removing composition, exist and be difficult to make to unload
The problem of adornment is uniformly impregnated with above-mentioned plate substrate with composition.On the other hand, if reducing the viscosity of makeup removing composition,
Makeup removing is significantly reduced sometimes with the storage stability of composition.
As described in patent document 1~5, the in the past known various makeup removings combination being impregnated in plate substrate
Thing.But existing makeup removing composition can not meet following over-all properties：For realizing the low viscosity uniformly impregnated, Gao Bao
Deposit stability and high makeup removing power.
It is an object of the invention to provide a kind of Compond fibre table for removing lipstick, in the Compond fibre table for removing lipstick, although makeup removing emulsification composition is at 25 DEG C
Ratio of viscosities it is relatively low, but the excellent storage stability of makeup removing emulsification composition, and the viscosity of makeup removing emulsification composition
Than relatively low, therefore makeup removing can be made to be uniformly impregnated with emulsification composition in plate substrate, it is thus possible to give play to especially excellent
Makeup removing power.
For solving the scheme of problem
The Compond fibre table for removing lipstick of the present invention possesses plate substrate and the makeup removing emulsification composition being impregnated in above-mentioned plate substrate, above-mentioned to unload
Adornment emulsification composition contains nonionic surface active agent, acrylic arid methacrylic acid alkyl ester copolymer and finish, on
It is selected from by two isostearic acid polyoxyethylene glycerides, single isostearic acid polyoxyethylene glyceride to state nonionic surface active agent
At least one kind of in the group formed with Crodaret, above-mentioned makeup removing is with viscosity of the emulsification composition at 25 DEG C
Below 1000mPas.
Above-mentioned finish is preferably at least one kind of in hydrocarbon ils and silicone oil.Above-mentioned nonionic surface active agent is preferably two different
Stearic acid polyoxyethylene glyceride.
In above-mentioned makeup removing with the mass % of emulsification composition 100, it is preferred that as selected from by two isostearic acid polyoxy second
It is at least one kind of upper in the group of alkene glyceride, single isostearic acid polyoxyethylene glyceride and Crodaret composition
The content for stating nonionic surface active agent is more than 0.1 mass %, below 5 mass %, aforesaid propylene acids methacrylic acid
The content of alkyl ester copolymer is more than 0.01 mass %, below 0.2 mass %, the content of above-mentioned finish is more than 1 mass %,
Below 25 mass %.
Above-mentioned makeup removing emulsification composition preferably also contains polyalcohol.
The effect of invention
The Compond fibre table for removing lipstick of the present invention possesses plate substrate and the makeup removing emulsification composition being impregnated in the plate substrate, and then above-mentioned
Makeup removing emulsification composition contains nonionic surface active agent, acrylic arid methacrylic acid alkyl ester copolymer and finish,
Above-mentioned nonionic surface active agent is selected from by two isostearic acid polyoxyethylene glycerides, single isostearic acid polyoxyethylene glycerol
At least one kind of in the group of ester and Crodaret composition, above-mentioned makeup removing is with viscosity of the emulsification composition at 25 DEG C
Below 1000mPas, therefore, although above-mentioned makeup removing emulsification composition is relatively low in 25 DEG C of ratio of viscosities, it can improve
State the storage stability of makeup removing emulsification composition., can be with further, since the ratio of viscosities of above-mentioned makeup removing emulsification composition is relatively low
Above-mentioned makeup removing is set to be uniformly impregnated with emulsification composition in above-mentioned plate substrate, thus, Compond fibre table for removing lipstick of the invention can have been given play to
Especially excellent makeup removing power.
Embodiment
Below, the present invention is described in detail.
The Compond fibre table for removing lipstick of the present invention possesses plate substrate and the makeup removing emulsification composition being impregnated in the plate substrate.The present invention's
In Compond fibre table for removing lipstick, the composition being impregnated in above-mentioned plate substrate is emulsification composition.
The Compond fibre table for removing lipstick of the present invention contains (A) nonionic surface active agent, (B) acrylic arid methacrylic acid Arrcostab is total to
Polymers and (C) finish.In the Compond fibre table for removing lipstick of the present invention, (A) nonionic surface active agent is selected from by two isostearic acid polyoxies
It is at least one kind of in the group of Ethylene Glycol ester, single isostearic acid polyoxyethylene glyceride and Crodaret composition.This
In the Compond fibre table for removing lipstick of invention, above-mentioned makeup removing is below 1000mPas in 25 DEG C of viscosity with emulsification composition.Above-mentioned makeup removing breast
It is relatively low in 25 DEG C of ratio of viscosities to change composition.
In the present invention, above-mentioned composition is employed, is impregnated in the above-mentioned makeup removing emulsification composition in above-mentioned plate substrate 25
DEG C viscosity be below 1000mPas, it is thus possible to above-mentioned makeup removing is easily and evenly impregnated in emulsification composition above-mentioned
In plate substrate.If for example, composition in 25 DEG C of viscosity more than 1000mPas, the above-mentioned makeup removing composition in Compond fibre table for removing lipstick
Pickup easily changed because of the part of above-mentioned plate substrate.On the other hand, by making above-mentioned makeup removing emulsification composition
It is below 1000mPas in 25 DEG C of viscosity, in Compond fibre table for removing lipstick, can emulsifies integrally above-mentioned makeup removing in above-mentioned plate substrate
The pickup of composition is uniform.
In addition, in the present invention, above-mentioned makeup removing emulsification composition has above-mentioned specific composition, thus, although above-mentioned unload
Adornment emulsification composition is relatively low in 25 DEG C of ratio of viscosities, but the preservation that can improve above-mentioned makeup removing emulsification composition is stable
Property.For the composition comprising (C) finish, (A) nonionic surface active agent is selected from being gathered by two isostearic acids
It is at least one kind of in the group of oxygen Ethylene Glycol ester, single isostearic acid polyoxyethylene glyceride and Crodaret composition,
This can go far towards the raising of storage stability.
In addition, in the present invention, above-mentioned makeup removing emulsification composition has above-mentioned specific composition, it is thus possible to improves makeup removing
Power.In addition, above-mentioned makeup removing is set to be uniformly impregnated with going far towards to effectively improve makeup removing in above-mentioned plate substrate with emulsification composition
Power.
Above-mentioned makeup removing is below 1000mPas in 25 DEG C of viscosity with emulsification composition.Above-mentioned makeup removing emulsification composition
It is preferably below 800mPas in 25 DEG C of viscosity.If above-mentioned viscosity is below the above-mentioned upper limit, above-mentioned makeup removing composition can
More uniformly it is impregnated in above-mentioned plate substrate.The lower limit of above-mentioned viscosity is not particularly limited.Above-mentioned makeup removing emulsification composition
It is preferably more than 150mPas, more preferably more than 200mPas in 25 DEG C of viscosity.If above-mentioned viscosity be above-mentioned lower limit with
On, then storage stability further improves.
Above-mentioned viscosity determines as follows：Using viscosimeter, when using No.2 rotors with rotary speed 30rpm, rotation for 25 DEG C
Between the condition of 1 minute be measured.As above-mentioned viscosimeter, TV-22 type viscosimeters of Dong Ji industries society manufacture etc. can be used.
The Compond fibre table for removing lipstick of the present invention is preferably the Compond fibre table for removing lipstick used as cosmetic preparation, quasi drug or pharmaceuticals.Above-mentioned makeup removing is used
Emulsification composition preferably comprises (D) polyalcohol.Above-mentioned makeup removing preferably comprises (E) ethanol with emulsification composition.Above-mentioned makeup removing breast
Change composition and generally comprise water.
Below, to workable each composition and chip base in Compond fibre table for removing lipstick of the invention and above-mentioned makeup removing emulsification composition
Material is described in detail.
((A) nonionic surface active agent)
Above-mentioned makeup removing includes (A) nonionic surface active agent with emulsification composition, and thus, storage stability becomes suitable
Height, and then power of removing ornaments and formal dress also effectively improves.As nonionic surface active agent, polyoxyethylene fatty acid, polyoxy can be enumerated
It is vinyl alkyl ether, Polyoxyethylene Sorbitan acid esters, polyglyceryl fatty acid ester, mono-fatty acid glyceride, poly- sweet
Oil and fat acid esters, polyoxyethylene fatty acid acid amides, sorbitan aliphatic ester, polyoxyethylene sorbitol beeswax, polyoxyethylene
Rilanit special, Emulsifier EL-60, Wool wax alcohols,ethoxylated, polyoxyethylene lanolin alcohol, polyoxyethylene sorbitol sheep
Hair fat and Dimethyl Lauryl Amine oxide etc..
Among these, in the present invention, as nonionic surface active agent, using polyglyceryl fatty acid ester and gather
It is at least one kind of in oxygen ethylene hydrogenation castor oil.
As the concrete example of above-mentioned polyglyceryl fatty acid ester, polyoxyethylene (caprylic/capric) glycerine can be enumerated
Ester, polyoxyethylene coconut fatty acid oil glyceride, single oleic acid polyoxyethylene glyceride, single myristic acid polyoxyethylene glyceride,
Monostearate polyoxyethylene glyceride, single isostearic acid polyoxyethylene glyceride, two isostearic acid polyoxyethylene glycerides and three
Isostearic acid polyoxyethylene glyceride etc..
Among these, in the present invention, in the case of using polyglyceryl fatty acid ester, single isostearic acid has been used to gather
It is at least one kind of in oxygen Ethylene Glycol ester and two isostearic acid polyoxyethylene glycerides.
Therefore, the present invention in, (A) nonionic surface active agent be selected from by two isostearic acid polyoxyethylene glycerides,
It is at least one kind of in the group of single isostearic acid polyoxyethylene glyceride and Crodaret composition.(A) nonionic table
Face activating agent can be used only a kind, can also share two or more.
For above-mentioned makeup removing emulsification composition, as (A) nonionic surface active agent, it is different hard that two can be included
Resin acid polyoxyethylene glyceride, single isostearic acid polyoxyethylene glyceride can also be included, can also be included polyethylene glycol hydrogenated
Castor oil.
From further improving storage stability aspect, (A) nonionic surface active agent is preferably two different tristearin
It is at least one kind of in sour polyoxyethylene glyceride and Crodaret, particularly preferably two isostearic acid polyoxyethylene
Glyceride.
Makeup removing power aspect is improved from further, (A) nonionic surface active agent is preferably that two isostearic acids gather
At least one kind of in oxygen Ethylene Glycol ester and single isostearic acid polyoxyethylene glyceride, preferably two isostearic acid polyoxyethylene are sweet
Grease.
Addition molal quantity to the oxirane in above-mentioned polyglyceryl fatty acid ester is not particularly limited, and is preferably
More than 2, more than 4, preferably less than 100, more preferably less than 90 are more preferably.If in above-mentioned polyglyceryl fatty acid ester
Oxirane addition molal quantity for more than above-mentioned lower limit and below the above-mentioned upper limit, then the guarantor of above-mentioned makeup removing emulsification composition
Depositing stability becomes more preferable.
As above-mentioned polyglyceryl fatty acid ester, commercially available product can be used.It is sweet as single isostearic acid polyoxyethylene
The commercially available product of grease, " blaunon the RGL-5MISE " (epoxies of the commercially available product as the manufacture of Qing Mu oil prodution industries society can be enumerated
Ethane addition molal quantity：5), " RGL-8MISE " (ethyleneoxide addition molal quantity：8), " RGL-10MISE " (ethyleneoxide addition
Molal quantity：And " RGL-20MISE " (ethyleneoxide addition molal quantity 10)：20)；And as the manufacture of NIHON EMULSION societies
Commercially available product " GWIS-108 " (ethyleneoxide addition molal quantity：8), " EMALEX GWIS-120 " (ethyleneoxide additions mole
Number：And " EMALEX GWIS-160 " (ethyleneoxide addition molal quantitys 20)：60) etc..It is sweet as two isostearic acid polyoxyethylene
The commercially available product of grease, (oxirane adds " GWIS-210 " of commercially available product that can enumerate as the manufacture of NIHON EMULSION societies
Into molal quantity：10), " EMALEX GWIS-220 " (ethyleneoxide addition molal quantitys：20), " EMALEX GWIS-230 " (epoxies
Ethane addition molal quantity：) and " EMALEX GWIS-260 " (ethyleneoxide addition molal quantitys 30)：60) etc..
As above-mentioned Crodaret, commercially available product can be used.City as Crodaret
Product are sold, such as " HC-20 " (ethyleneoxide addition mole of the commercially available product as the manufacture of NIHON EMULSION societies can be enumerated
Number：20), " HC-40 " (ethyleneoxide addition molal quantity：And " HC-100 " (ethyleneoxide addition molal quantity 40)：100) etc..
To the oxirane in above-mentioned two isostearic acids polyoxyethylene glyceride and single isostearic acid polyoxyethylene glyceride
Addition molal quantity be not particularly limited, preferably more than 10, more preferably more than 20, be preferably less than 80, more preferably 60
Below.If above-mentioned two isostearic acids polyoxyethylene glyceride and the oxirane in single isostearic acid polyoxyethylene glyceride plus
It is that then the storage stability of above-mentioned makeup removing emulsification composition becomes more more than above-mentioned lower limit and below the above-mentioned upper limit into molal quantity
It is good.
Addition molal quantity to the oxirane in above-mentioned Crodaret is not particularly limited, and preferably 20
Above, more preferably more than 30, preferably less than 100.If the addition of the oxirane in above-mentioned Crodaret
Molal quantity is that then the storage stability of above-mentioned makeup removing emulsification composition becomes more more than above-mentioned lower limit and below the above-mentioned upper limit
It is good.
(A) HLB value of nonionic surface active agent is preferably more than 7, is more preferably more than 8, preferably less than 16, more
Preferably less than 15.If HLB value is more than above-mentioned lower limit, storage stability becomes more preferable.If HLB value be the above-mentioned upper limit with
Under, then power of removing ornaments and formal dress further improves.
In above-mentioned makeup removing with the mass % of emulsification composition 100, as selected from by two isostearic acid polyoxyethylene glycerides,
At least one kind of (A) nonionic in the group of single isostearic acid polyoxyethylene glyceride and Crodaret composition
Content (two isostearic acid polyoxyethylene glycerides, single isostearic acid polyoxyethylene glyceride and the polyoxyethylene of surfactant
The total content of rilanit special) be preferably more than 0.1 mass %, more preferably more than 0.3 mass %, preferably 5 mass % with
Under, more preferably below 3 mass %.If the content of (A) nonionic surface active agent is more than above-mentioned lower limit, makeup removing power is entered
One step improves.If the content of (A) nonionic surface active agent is below the above-mentioned upper limit, storage stability becomes more preferable, enters
And easily moderately reduce the viscosity of above-mentioned makeup removing emulsification composition.
In above-mentioned makeup removing with the mass % of emulsification composition 100, the content of two isostearic acid polyoxyethylene glycerides is preferred
For more than 0.1 mass %, more preferably more than 0.3 mass %, preferably below 5 mass %, more preferably below 3 mass %.
If the content of two isostearic acid polyoxyethylene glycerides is more than above-mentioned lower limit, makeup removing power further improves.If two different tristearin
The content of sour polyoxyethylene glyceride is that then storage stability becomes more preferable, and then easily moderately reduces below the above-mentioned upper limit
The viscosity of above-mentioned makeup removing emulsification composition.
((B) acrylic arid methacrylic acid alkyl ester copolymer)
By making above-mentioned makeup removing emulsification composition include (B) acrylic arid methacrylic acid alkyl ester copolymer, even if
The viscosity of above-mentioned makeup removing emulsification composition is low, can also improve storage stability, and can improve unloading for above-mentioned Compond fibre table for removing lipstick
Adornment power.That is, by using (B) acrylic arid methacrylic acid alkyl ester copolymer, high storage stability and height can be taken into account and unloaded
Adornment power.(B) acrylic arid methacrylic acid alkyl ester copolymer can be used only a kind, can also share two or more.
As (B) acrylic arid methacrylic acid alkyl ester copolymer, commercially available product can be used.As (B) acrylic acid
The commercially available product of methacrylate copolymer, " the PEMULEN of the commercially available product as the manufacture of LUBRIZOL societies can be enumerated
TR-1 ", " PEMULEN TR-2 ", " Carbopol 1342 ", " Carbopol 1382 " and " ETD2020 " etc..
In above-mentioned makeup removing with the mass % of emulsification composition 100, (B) acrylic arid methacrylic acid alkyl ester copolymer
Content is preferably more than 0.01 mass %, is more preferably more than 0.015 mass %, preferably below 0.2 mass %, more preferably
Below 0.15 mass %.If the content of (B) acrylic arid methacrylic acid alkyl ester copolymer is more than above-mentioned lower limit, preserve
Stability and makeup removing power further improve.The content of (if B) acrylic arid methacrylic acid alkyl ester copolymer is the above-mentioned upper limit
Hereinafter, then makeup removing power becomes more preferable.
((C) finish)
By making above-mentioned makeup removing emulsification composition include (C) finish, then makeup removing power can be effectively improved.In addition, this
In invention, in order to which stably mixture finish, makeup removing are emulsification composition with composition.(C) finish is lived with (A) non-ionic surface
Property agent it is different, it is different from (B) acrylic arid methacrylic acid alkyl ester copolymer, it is also different from (D) polyalcohol.
As (C) finish, hydrocarbon ils, silicone oil, grease, higher fatty acids, fatty acid ester and higher alcohol etc. can be enumerated.(C)
Finish can be used only a kind, can also share two or more.
As above-mentioned hydrocarbon ils, such as light isoparaffins, light liquid isoparaffin, synthesis saualane, plant can be enumerated
Physical property saualane, saualane, ceresine, paraffin, atoleine, liquid isoparaffin, microwax, polyethylene powders, Tissuemat E
With vaseline etc..Above-mentioned hydrocarbon ils can be used only a kind, can also share two or more.
From effectively improving makeup removing power aspect, above-mentioned hydrocarbon ils is preferably selected from by light isoparaffins, lightweight liquid
It is at least one kind of in the group of body isoparaffin, atoleine and liquid isoparaffin composition.
Above-mentioned silicone oil can be ordinary silicon ketone (straight silicone), or modified silicone, can also be ring
Shape silicone.As above-mentioned common silicone, such as octamethyltrisiloxane, tetradecamethylhexasiloxane, methyl polysilicon can be enumerated
Oxygen alkane, high polymeric MAO polysiloxanes, methyl phenyl silicone and methylhydrogenpolysi,oxane etc..As above-mentioned modified silicone,
Such as alcohol modified silicone, alkyl-modified silicone, amino modified silicone, polyether modified silicone and epoxide modified silicone can be enumerated
Deng.As above-mentioned cyclic silicone, such as octamethylpolysiloxane, octamethylcy-clotetrasiloxane, the silicon of decamethyl ring five can be enumerated
Oxygen alkane and the siloxanes of ten diformazan basic ring six etc..Above-mentioned silicone oil can be used only a kind, can also share two or more.
From effectively improving makeup removing power aspect, above-mentioned silicone oil is preferably cyclic silicone.
As above-mentioned grease, for example, can enumerate sunflower oil, cottonseed oil, soybean oil, olive oil, coconut oil, castor oil,
Jojoba oil, camellia caul-fat and ermine oil etc..Above-mentioned grease can be used only a kind, can also share two or more.
As above-mentioned higher fatty acids, such as laurate, myristic acid, palmitic acid, stearic acid, oleic acid, two can be enumerated
Dodecylic acid, undecenoic acid, lanoceric acid and isostearic acid etc..Above-mentioned higher fatty acids can be used only a kind, can also close
Use two or more.
As above-mentioned fatty acid ester, such as ethyl oleate, isopropyl myristate, isopropyl palmitate, meat can be enumerated
Myristic acid myristin, cetyl palmitate, oleic acid oleic alcohol ester, myristic acid octyldodecyl, oleic acid octyl group ten
Dialkyl ester, isostearic acid ethyl ester, isopropyl isostearate, 2 ethyl hexanoic acid cetyl ester, 2 ethyl hexanoic acid cetearyl alcohol
Ester, sad isohexadecane base ester, the different stearyl ester of octanoic acid, isopropyl isostearate, isostearic acid isohexadecane base ester, isostearic acid
Octyldodecyl, dimethyl-octa acid octyldodecyl, two oleic acid glycol esters, two sad propylene glycol esters, two capric acid
Propylene glycol ester, two (caprylic/capric) propylene glycol esters, isostearic acid propylene glycol ester, two capric acid DOPCPs, three 2 ethyl hexanoic acids
Glyceride, three different tripalmitins and four 2 ethyl hexanoic acid pentaerythritol esters etc..Above-mentioned fatty acid ester can be used only a kind,
Two or more can also be shared.
As above-mentioned higher alcohol, such as laruyl alcohol, myristyl alcohol, hexadecanol, stearyl alcohol, oleyl alcohol, lanolin can be enumerated
Alcohol, tadenan, cetostearyl alcohol, octyl decanol and decyl tetradecyl alcohol etc..Above-mentioned higher alcohol can be used only a kind, also may be used
To share two or more.
From the stimulation for suppressing skin, further raising makeup removing power aspect, (C) finish is preferably in hydrocarbon ils and silicone oil
At least one kind of, preferably both hydrocarbon ils and silicone oil.Therefore, above-mentioned makeup removing preferably comprises hydrocarbon ils and silicone oil with emulsification composition.
In above-mentioned makeup removing with the mass % of emulsification composition 100, the content of (C) finish is preferably more than 1 mass %, is more excellent
Elect as more than 3 mass %, preferably below 25 mass %, be more preferably below 20 mass %.The content of (if C) finish is above-mentioned
More than lower limit, then power of removing ornaments and formal dress further improves.If the content of (C) finish is below the above-mentioned upper limit, storage stability becomes more
It is good.
In above-mentioned makeup removing with the mass % of emulsification composition 100, the total content of hydrocarbon ils and silicone oil be preferably 1 mass % with
Upper, more preferably more than 3 mass %, preferably below 25 mass %, are more preferably below 20 mass %.In above-mentioned makeup removing breast
Change in the mass % of composition 100, the content of hydrocarbon ils is preferably more than 0.5 mass %, is more preferably more than 1.5 mass %, preferably
For below 20 mass %, more preferably below 15 mass %.In above-mentioned makeup removing with the mass % of emulsification composition 100, silicone oil
Content is preferably more than 0.5 mass %, is more preferably more than 1.5 mass %, preferably below 20 mass %, is more preferably 15 matter
Measure below %.If the content of the total content of hydrocarbon ils and silicone oil, hydrocarbon ils and the content of silicone oil are respectively more than above-mentioned lower limit,
Makeup removing power further improves.If the content of the total content of hydrocarbon ils and silicone oil, hydrocarbon ils and the content of silicone oil be respectively the above-mentioned upper limit with
Under, then storage stability becomes more preferable.
((D) polyalcohol)
By making above-mentioned makeup removing emulsification composition include (D) polyalcohol, then it can obtain relaxing the effect of skin irritation.
As (D) polyalcohol, such as ethylene glycol, diethylene glycol, polyethylene glycol, propane diols, DPG, poly- can be enumerated
Propane diols, glycerine, diglycerol, polyglycereol, 1,3 butylene glycol, isoprene, D-sorbite, maltitol, mannitol, 1,2-
Butanediol, 1,2- pentanediol, 1,2- hexylene glycols, 1,2- heptandiols, 1,2- ethohexadiols, 1,2- nonanediols and 1,2- decanediol etc..
(D) polyalcohol can be used only a kind, can also use two or more.
In above-mentioned makeup removing with the mass % of emulsification composition 100, the content of (D) polyalcohol be preferably more than 0 mass % (
Including be not used), more preferably more than 0.5 mass %, preferably below 25 mass %, more preferably below 20 mass %.If
(D) content of polyalcohol is that more than above-mentioned lower limit then skin irritation is further relaxed.The content of (if D) polyalcohol is
Below the above-mentioned upper limit, then the salubrious sense after removing ornaments and formal dress becomes more preferable.
((E) ethanol)
Above-mentioned makeup removing preferably comprises (E) ethanol with emulsification composition.By making above-mentioned makeup removing emulsification composition include (E)
Ethanol, antiseptic effect effectively improve.
From further improving antiseptic effect aspect, how preferable the content of (E) ethanol is.On the other hand, from further
Suppress to set out in terms of skin irritatin, the content of (E) ethanol is preferable less.Particularly, for Compond fibre table for removing lipstick, skin irritatin makes
Use turns into big problem sometimes.
In above-mentioned makeup removing with the mass % of emulsification composition 100, the content of (E) ethanol is preferably more than 0 mass % (also to wrap
Include unused), more preferably more than 2 mass %, preferably below 10 mass %, more preferably below 8 mass %.(if E) second
The content of alcohol is that more than above-mentioned lower limit then antiseptic effect becomes more preferable.The content of (if E) ethanol is below the above-mentioned upper limit, skin
Skin, which stimulates, further to be suppressed.
(water)
Above-mentioned makeup removing has used water with the remaining part of emulsification composition.Water is preferably water usually used in cosmetic preparation.To water
It is not particularly limited, pure water, running water and ion exchange water etc. can be enumerated.Water is preferably pure water.
(other compositions)
In the range of the effect of the present invention is not hindered, above-mentioned makeup removing emulsification composition can include amophoteric surface active
Agent, cationic surface active agent, anionic surfactant, preservative, freshener, antioxidant, metal-chelator, dimension
Other compositions such as raw plain class, animals and plants extract, pearling agent and colouring agent.These other compositions can be used only a kind, can also
Use two or more.
As above-mentioned amphoteric surfactant, amino acid type amphoteric surfactant and betaine type amphoteric table can be enumerated
Face activating agent etc..As above-mentioned amino acid type amphoteric surfactant, glycine type amphoterics and ammonia can be enumerated
Base propionic acid type amphoteric surfactant etc..As above-mentioned betaine type amphoteric surfac-tant, amion acetic acid beet can be enumerated
Alkaline amphoteric surfactant and sulfobetaine type amphoteric surfactant etc..
As above-mentioned cationic surface active agent, alkylamine salt and fatty acid amide amine etc. can be enumerated.As above-mentioned
Alkylamine salt, lauryl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride and VARISOFT TA100 can be enumerated
Deng.As above-mentioned fatty acid amide amine, myristic acid dimethyl aminoethyl acid amides and stearic acid diethylamino can be enumerated
Propyl amides etc..
As above-mentioned anionic surfactant, can enumerate alkyl sulfate salt, polyoxyethylene alkyl ether sulfate salt,
Alpha-alkene sulfonate, N- acyl methyl taurine salts, sulfosuccinic dialkylaminobenzoic acid salt, the polyxyethylated salt of sulfosuccinic acid, list
Alkyl phosphate salt, polyoxyethylene alkyl ether phosphate salt, N- acyl sarcosinates, N- acyl-N-methyls-Beta-alanine salt,
N- acyl glutamates, N- acylglycines salt and alkyl ether glycol acetate etc..
As foregoing preservatives, p-hydroxybenzoate (methyl p-hydroxybenzoate), phenoxetol, benzene can be enumerated
Sodium formate, potassium sorbate and polyaminopropyl biguanide etc..
(plate substrate)
On the material of above-mentioned plate substrate, just it is not particularly limited with emulsification composition as long as above-mentioned makeup removing can be impregnated.
Can be suitably using the plate substrate for being typically used as cosmetics.
As above-mentioned plate substrate, can enumerate by weaving cotton cloth of forming of natural fiber, synthetic fibers or half-natural fiber or nothing
Spin cloth etc..From making immersion and use feeling preferably aspect, above-mentioned plate substrate is preferably non-woven fabrics.
As above-mentioned natural fiber, cotton, paper pulp, silk, cellulose, fiber crops, cotton linter and kapok etc. can be enumerated.As above-mentioned
Synthetic fibers, nylon, polyester fiber, polyacrylic fibre, polypropylene fibre, the poly- terephthaldehyde of polyethylene fiber peacekeeping can be enumerated
Sour glycol ester fiber etc..As above-mentioned half-natural fiber, artificial silk and acetate etc. can be enumerated.Above-mentioned fiber can only make
With a kind, two or more can also be used.
The surface of above-mentioned plate substrate can carry out Embossing processing.In addition, film base material is included in above-mentioned plate substrate.
The method for making above-mentioned makeup removing be impregnated in emulsification composition in above-mentioned plate substrate is not particularly limited, can be used
Known method.
On the amount for the above-mentioned makeup removing emulsification composition being impregnated in above-mentioned plate substrate, relative to the mass parts of plate substrate 1,
Preferably more than 1 mass parts, more preferably more than 3 mass parts, preferably below 7 mass parts, more preferably below 6 mass parts.
If the pickup of above-mentioned makeup removing emulsification composition is more than above-mentioned lower limit, makeup removing power further improves.If above-mentioned makeup removing is used
The pickup of emulsification composition is that then above-mentioned makeup removing is preferably impregnated in above-mentioned plate substrate with emulsification composition below the above-mentioned upper limit
In, it can preferably maintain impregnation state.
Embodiment
Below, enumerate embodiment and the present invention is specifically described comparative example.The present invention is not limited to following reality
Apply example.
Following compositions have been used in embodiment and comparative example.
((A) nonionic surface active agent)
(NIHON EMULSION societies manufacture " EMALEX GWIS-220 ", epoxy second to two isostearic acid polyoxyethylene glycerides
Alkane addition molal quantity：20)
(NIHON EMULSION societies manufacture " EMALEX GWIS-230 ", epoxy second to two isostearic acid polyoxyethylene glycerides
Alkane addition molal quantity：30)
(NIHON EMULSION societies manufacture " EMALEX GWIS-260 ", epoxy second to two isostearic acid polyoxyethylene glycerides
Alkane addition molal quantity：60)
(NIHON EMULSION societies manufacture " EMALEX GWIS-120 ", epoxy second to single isostearic acid polyoxyethylene glyceride
Alkane addition molal quantity：20)
(NIHON EMULSION societies manufacture " EMALEX GWIS-160 ", epoxy second to single isostearic acid polyoxyethylene glyceride
Alkane addition molal quantity：60)
Crodaret (NIHON EMULSION societies manufacture " HC-40 ", ethyleneoxide addition molal quantity：40)
Crodaret (NIHON EMULSION societies manufacture " HC-100 ", ethyleneoxide addition molal quantity：
100)
((A) ' other nonionic surface active agent)
(NIHON EMULSION societies manufacture " EMALEX GWIS-320 ", epoxy second to three isostearic acid polyoxyethylene glyceryls
Alkane addition molal quantity：20)
(NIHON EMULSION societies manufacture " EMALEX GWIS-108 ", epoxy second to isostearic acid polyoxyethylene glycol ester
Alkane addition molal quantity：8)
((B) acrylic arid methacrylic acid alkyl ester copolymer)
Acrylic arid methacrylic acid alkyl ester copolymer (manufacture of LUBRIZOL societies " PEMULEN TR-2 ")
(with (B) ' the similar other compositions of acrylic arid methacrylic acid alkyl ester copolymer)
Carboxyl vinyl polymer (manufacture of LUBRIZOL societies " Carbopol 981 ")
(C) finish
Hydrocarbon ils：
Liquid isoparaffin (manufacture of You societies " Parleam EX ")
Silicone oil：
Decamethylcyclopentaandoxane (chemical industry society of SHIN-ETSU HANTOTAI manufactures " KF-955 ")
((D) polyalcohol)
Concentrated glycerin (this pharmaceutical industries of slope society manufactures " cosmetic concentrated glycerin ")
((E) ethanol)
Ethanol (Japan Alcohol Trading societies manufacture " 95 ° of synthols ")
(other compositions)
Preservative：
Methyl p-hydroxybenzoate (manufacture of u'eno pharmacy society " メ ッ キ Application ス M ")
Phenoxetol (Yokkaichi synthesis society's manufacture " phenoxetol-S ")
Nertralizer：
Potassium hydroxide
Water：
Pure water
(embodiment 1~12 and comparative example 1~5)
Mixture table 1 below, the compounding ingredients (mixture unit is quality %) shown in 2, are prepared according to conventional methods, by
This obtains makeup removing emulsification composition.
As plate substrate, the non-woven fabrics of paper pulp/artificial silk (three clear paper industry society manufactures " KP9340 ") is prepared.Make sheet above
Base material impregnates above-mentioned makeup removing emulsification composition, obtains Compond fibre table for removing lipstick (piece cosmetic preparation).It should be noted that relative to plate substrate 1
Mass parts, impregnate the above-mentioned mass parts of makeup removing emulsification composition 5.
(test example 1：Viscosimetric analysis)
The viscosity of resulting emulsification composition determines as follows：The TV-22 type viscosimeters manufactured using Dong Ji industries society,
25 DEG C are measured using No.2 rotors with rotary speed 30rpm, the rotational time condition of 1 minute.
(test example 2：Storage stability)
Resulting emulsification composition was preserved into for 1 week in 25 DEG C and 40 DEG C of thermostatic constant wet chamber.After preservation
Emulsification composition state, the storage stability according to following benchmark evaluations.
<The metewand of storage stability>
Zero (good)：Uniformly
△ (insufficient)：Confirm slightly uneven state
× (bad)：Confirm clear and definite separation
(test example 3：The evaluation for power of removing ornaments and formal dress)
The wiping that cosmetics are carried out by the Compond fibre table for removing lipstick obtained by 20 women professional judging panel's uses having made up removes, and is based on
Following benchmark evaluations makeup removing power.
<The metewand for power of removing ornaments and formal dress>
00 (fairly good)：Makeup removing power height is answered in 20 for more than 16
Zero (good)：Makeup removing power height is answered in 20 for 11~15
△ (insufficient)：Makeup removing power height is answered in 20 for 6~10
× (bad)：Makeup removing power height is answered in 20 for less than 5
(test example 4：The evaluation of stimulation)
In the makeup removing of test example 3, that evaluates eye stimulates whether strong and skin stimulation is strong.In addition,
After the makeup removing of test example 3, whether the stimulation for evaluating skin is strong.
<The metewand of stimulation>
00 (fairly good)：In 20 more than 16 answer makeup removing when the stimulation of eye and the stimulation of skin and makeup removing after
The stimulation of skin is not strong
Zero (good)：In 20 11~15 answer makeup removing when the stimulation of eye and the stimulation of skin and makeup removing after skin
Stimulation it is not strong
△ (insufficient)：In 20 6~10 answer makeup removing when the stimulation of eye and the stimulation of skin and makeup removing after skin
Stimulation it is not strong
× (bad)：Skin after less than 5 stimulations of eye when answering makeup removing and the stimulation of skin and makeup removing in 20
Stimulate not strong
Composition and result are shown in table 1 below, 2.
Claims (4)
1. a kind of Compond fibre table for removing lipstick, it possesses plate substrate and the makeup removing emulsification composition being impregnated in the plate substrate,
The makeup removing emulsification composition contains nonionic surface active agent, acrylic arid methacrylic acid alkyl ester copolymer
And finish,
The nonionic surface active agent is two isostearic acid polyoxyethylene glycerides,
The makeup removing is below 1000mPas in 25 DEG C of viscosity with emulsification composition,
It is the nonionic of two isostearic acid polyoxyethylene glycerides in the makeup removing with the mass % of emulsification composition 100
The content of type surfactant is more than 0.1 mass %, below 5 mass %, and the acrylic arid methacrylic acid Arrcostab is total to
The content of polymers is more than 0.01 mass %, below 0.2 mass %, and the content of the finish is more than 1 mass %, 25 mass %
Below.
2. Compond fibre table for removing lipstick as claimed in claim 1, wherein, the finish is at least one kind of in hydrocarbon ils and silicone oil.
3. Compond fibre table for removing lipstick as claimed in claim 1 or 2, wherein, the makeup removing emulsification composition also contains polyalcohol.
4. Compond fibre table for removing lipstick as claimed in claim 1 or 2, wherein, the makeup removing emulsification composition also contains ethanol.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2014-010601 | 2014-01-23 | ||
| JP2014010601 | 2014-01-23 | ||
| PCT/JP2014/075075 WO2015111249A1 (en) | 2014-01-23 | 2014-09-22 | Cleansing sheet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105473120A CN105473120A (en) | 2016-04-06 |
| CN105473120B true CN105473120B (en) | 2018-02-02 |
Family
ID=53681072
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480042903.4A Active CN105473120B (en) | 2014-01-23 | 2014-09-22 | Compond fibre table for removing lipstick |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP6125671B2 (en) |
| KR (1) | KR101786449B1 (en) |
| CN (1) | CN105473120B (en) |
| WO (1) | WO2015111249A1 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102517441B1 (en) * | 2015-11-18 | 2023-03-31 | 주식회사 엘지생활건강 | Liquid detergent composition having excellent cleansing effect to be packed into foamer containers |
| JP7359568B2 (en) * | 2019-05-16 | 2023-10-11 | 株式会社マンダム | Emulsified cleansing cosmetics |
| CN116419745A (en) * | 2021-06-07 | 2023-07-11 | 花王株式会社 | Sheet-like cosmetic |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001002528A (en) * | 1999-06-16 | 2001-01-09 | Pola Chem Ind Inc | Cleansing sheet for wiping |
| JP2005343943A (en) * | 2004-06-01 | 2005-12-15 | Shiseido Co Ltd | Oil-in-water type detergent composition and sheet-like detergent |
| JP2013116868A (en) * | 2011-12-02 | 2013-06-13 | Kao Corp | Sheet-like cosmetic |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0892032A (en) * | 1994-09-19 | 1996-04-09 | Shiseido Co Ltd | Skin detergent |
| JP2001302450A (en) * | 2000-04-21 | 2001-10-31 | Kao Corp | Cleansing material |
| JP4054939B2 (en) * | 2000-05-08 | 2008-03-05 | ライオン株式会社 | Face cleansing sheet for removing makeup or sebum |
| JP2002255787A (en) * | 2001-02-27 | 2002-09-11 | Shiseido Co Ltd | Skin detergent |
| JP2003183126A (en) * | 2001-12-20 | 2003-07-03 | Kose Corp | Sheet-type cleansing cosmetic |
| JP3935421B2 (en) * | 2002-11-28 | 2007-06-20 | 日本メナード化粧品株式会社 | Cleansing composition |
| JP3789455B2 (en) * | 2004-02-24 | 2006-06-21 | 花王株式会社 | Sheet cleansing material |
| JP4001858B2 (en) | 2003-11-14 | 2007-10-31 | 花王株式会社 | Sheet cleansing material |
| JP2005239586A (en) * | 2004-02-25 | 2005-09-08 | Pola Chem Ind Inc | Cleansing cosmetic |
| JP2005239587A (en) * | 2004-02-25 | 2005-09-08 | Pola Chem Ind Inc | Liquid cleansing cosmetic |
| JP2006306780A (en) | 2005-04-28 | 2006-11-09 | Kao Corp | Liquid cleansing agent composition |
| JP4901464B2 (en) * | 2006-12-28 | 2012-03-21 | 高級アルコール工業株式会社 | Diester and cleansing cosmetic containing the same |
| JP2011173862A (en) * | 2010-02-01 | 2011-09-08 | Lion Corp | Skin cleanser composition |
| JP5714833B2 (en) * | 2010-03-31 | 2015-05-07 | 株式会社ナリス化粧品 | Cleansing cream |
| JP6054287B2 (en) * | 2011-03-03 | 2016-12-27 | ライオン株式会社 | Hair cleaner composition and skin cleaner composition |
| JP5593406B2 (en) * | 2012-02-07 | 2014-09-24 | 株式会社 資生堂 | Oil-in-water emulsified skin cleanser |
| JP6006152B2 (en) * | 2012-08-24 | 2016-10-12 | 株式会社ナリス化粧品 | Cleansing cosmetics |
-
2014
- 2014-09-22 KR KR1020167002524A patent/KR101786449B1/en active IP Right Grant
- 2014-09-22 WO PCT/JP2014/075075 patent/WO2015111249A1/en active Application Filing
- 2014-09-22 CN CN201480042903.4A patent/CN105473120B/en active Active
- 2014-09-22 JP JP2015558728A patent/JP6125671B2/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001002528A (en) * | 1999-06-16 | 2001-01-09 | Pola Chem Ind Inc | Cleansing sheet for wiping |
| JP2005343943A (en) * | 2004-06-01 | 2005-12-15 | Shiseido Co Ltd | Oil-in-water type detergent composition and sheet-like detergent |
| JP2013116868A (en) * | 2011-12-02 | 2013-06-13 | Kao Corp | Sheet-like cosmetic |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20160027094A (en) | 2016-03-09 |
| WO2015111249A1 (en) | 2015-07-30 |
| JPWO2015111249A1 (en) | 2017-03-23 |
| KR101786449B1 (en) | 2017-10-18 |
| JP6125671B2 (en) | 2017-05-10 |
| CN105473120A (en) | 2016-04-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101959509B (en) | Alcohol antimicrobial skin sanitizing compositions including cationic compatible thickeners | |
| TWI458496B (en) | Transparent multi-layered liquid cosmetic | |
| US8298557B2 (en) | Cleansing cosmetic composition | |
| JP5495757B2 (en) | Aqueous cleansing cosmetics | |
| BRPI0906082B1 (en) | MOISTURIZING HAND SANITIZER, MOISTURIZING WRINKLE AND METHOD OF PRODUCING A MOISTURIZING HAND SANITIZER | |
| KR20110119774A (en) | Oily hair cosmetic | |
| CN101370474A (en) | Stable oil-in-water and water/oil/water multiple emulsions and hair treating compositions comprising them | |
| WO2008057245A2 (en) | Water-based skin care composition with polyalkylsilsesquioxane powder emulsion and method for making the same | |
| KR20160103139A (en) | Cleansing cosmetic and sheet product | |
| CN105473120B (en) | Compond fibre table for removing lipstick | |
| CN102573763A (en) | O/W type cosmetic composition with improved dosage form stability | |
| JP6773594B2 (en) | Skin cosmetics | |
| JP2018165260A (en) | Skin Cosmetic | |
| JP6618404B2 (en) | Emulsified moisturizing cosmetic and method for using the same | |
| JP2011032175A (en) | Composition for prepack, pack method and cosmetic set for pack | |
| JPWO2020059167A1 (en) | Composition for skin cosmetics | |
| US20130280310A1 (en) | Sheet-like cosmetic | |
| AU2019263111A1 (en) | Cleansing compositions | |
| KR102170742B1 (en) | Skin cosmetics | |
| KR102065321B1 (en) | Oil-in-water emulsion composition containing recrystallized particle and cosmetic composition comprising the same | |
| KR101834196B1 (en) | Hair cosmetic composition gel form | |
| JP2021080209A (en) | Sheet cosmetic | |
| JP7460289B2 (en) | Water-in-oil emulsion cosmetics | |
| JP7359568B2 (en) | Emulsified cleansing cosmetics | |
| WO2000056277A1 (en) | Cosmetic towelettes |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |