JPWO2020059167A1 - Composition for skin cosmetics - Google Patents
Composition for skin cosmetics Download PDFInfo
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- JPWO2020059167A1 JPWO2020059167A1 JP2020547908A JP2020547908A JPWO2020059167A1 JP WO2020059167 A1 JPWO2020059167 A1 JP WO2020059167A1 JP 2020547908 A JP2020547908 A JP 2020547908A JP 2020547908 A JP2020547908 A JP 2020547908A JP WO2020059167 A1 JPWO2020059167 A1 JP WO2020059167A1
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- skin
- composition
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- LVGKNOAMLMIIKO-QXMHVHEDSA-N ethyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC LVGKNOAMLMIIKO-QXMHVHEDSA-N 0.000 description 1
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- 239000010642 eucalyptus oil Substances 0.000 description 1
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- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 description 1
- FHKSXSQHXQEMOK-UHFFFAOYSA-N hexane-1,2-diol Chemical compound CCCCC(O)CO FHKSXSQHXQEMOK-UHFFFAOYSA-N 0.000 description 1
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- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
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- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
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- WCVRQHFDJLLWFE-UHFFFAOYSA-N pentane-1,2-diol Chemical compound CCCC(O)CO WCVRQHFDJLLWFE-UHFFFAOYSA-N 0.000 description 1
- 235000019477 peppermint oil Nutrition 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
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- 239000000049 pigment Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920003216 poly(methylphenylsiloxane) Polymers 0.000 description 1
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- 229920001223 polyethylene glycol Polymers 0.000 description 1
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- 239000008213 purified water Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000008165 rice bran oil Substances 0.000 description 1
- 239000010667 rosehip oil Substances 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
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- 239000003352 sequestering agent Substances 0.000 description 1
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- 229940057910 shea butter Drugs 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
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- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 125000005063 tetradecenyl group Chemical group C(=CCCCCCCCCCCCC)* 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0212—Face masks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/732—Starch; Amylose; Amylopectin; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
使用後の肌に、乾燥した感触が抑制されつつサラサラ感を付与することができる皮膚化粧料用組成物を提供する。成分（Ａ）：タルク及び／又はシリカ、成分（Ｂ）：オクテニルコハク酸デンプンアルミニウム、成分（Ｃ）：エタノール、並びに成分（Ｄ）：水を含有し、前記成分（Ａ）の含有割合が０．５〜１５．０質量％、前記成分（Ｂ）の含有割合が０．５〜１５．０質量％、前記成分（Ｃ）の含有割合が２０．０〜７０．０質量％、前記成分（Ｄ）の含有割合が１０．０〜７５．０質量％である、皮膚化粧料用組成物。Provided is a composition for skin cosmetics capable of imparting a smooth feeling to the skin after use while suppressing a dry feel. The component (A): talc and / or silica, the component (B): aluminum starch octenyl succinate, the component (C): ethanol, and the component (D): water are contained, and the content ratio of the component (A) is 0. 5 to 15.0% by mass, the content ratio of the component (B) is 0.5 to 15.0% by mass, the content ratio of the component (C) is 20.0 to 70.0% by mass, and the component (D). ) Is a composition for skin cosmetics having a content of 10.0 to 75.0% by mass.
Description
本発明は、皮膚化粧料用組成物に関する。 The present invention relates to a composition for skin cosmetics.
シート化粧料は、シート基材に化粧料組成物を含浸させて形成される。シート化粧料としては、汗、皮脂汚れや古い角質などの汚れを拭き取って肌を清潔に保つことを主目的とするフェイス用やボディ用のシート化粧料、メイク落としを主目的とするクレンジングシートなどのシート化粧料が知られている。 The sheet cosmetic is formed by impregnating the sheet base material with the cosmetic composition. Sheet cosmetics include face and body sheet cosmetics whose main purpose is to wipe off dirt such as sweat, sebum stains and old keratin to keep the skin clean, and cleansing sheets whose main purpose is to remove makeup. Sheet cosmetics are known.
従来、シート基材に含浸する化粧料組成物に粉体を配合し、使用後の肌に、肌を擦る際に肌の摩擦が低い感触（サラサラ感）を付与する技術が知られている。例えば、引用文献１及び２などには、粉体の配合による白残りを改善し、肌にサラサラ感を付与するシート化粧料が記載されている。 Conventionally, there has been known a technique of blending a powder into a cosmetic composition impregnated in a sheet base material to give the skin after use a feeling of low friction (smoothness) when the skin is rubbed. For example, Cited Documents 1 and 2 and the like describe sheet cosmetics that improve white residue by blending powder and give a smooth feeling to the skin.
しかしながら、従来のシート化粧料では、使用後においてサラサラ感を付与すると同時に、肌が乾燥したような感触となるという問題があった。多価アルコールなどの保湿剤をシート化粧料に配合することで乾燥した感触（乾燥感）を抑えることが可能であるが、粉体によるサラサラ感が損なわれてしまう。このため、乾燥した感触がなくサラサラ感を付与できるシート化粧料を得ることは困難であった。 However, the conventional sheet cosmetics have a problem that the skin feels dry at the same time as giving a smooth feeling after use. By blending a moisturizer such as polyhydric alcohol into the sheet cosmetics, it is possible to suppress the dry feeling (dry feeling), but the smooth feeling due to the powder is impaired. For this reason, it has been difficult to obtain a sheet cosmetic that does not have a dry feel and can give a smooth feeling.
従って、本発明の目的は、使用後の肌に、乾燥した感触が抑制されつつサラサラ感を付与することができる皮膚化粧料用組成物を提供することにある。 Therefore, an object of the present invention is to provide a composition for skin cosmetics capable of imparting a smooth feeling to the skin after use while suppressing a dry feel.
本発明者らは、上記目的を達成するため鋭意検討した結果、成分（Ａ）：タルク及び／又はシリカ、成分（Ｂ）：オクテニルコハク酸デンプンアルミニウム、成分（Ｃ）：エタノール、並びに成分（Ｄ）：水を含有し、成分（Ａ）の含有割合が０．５〜１５．０質量％、成分（Ｂ）の含有割合が０．５〜１５．０質量％、成分（Ｃ）の含有割合が２０．０〜７０．０質量％、成分（Ｄ）の含有割合が１０．０〜７５．０質量％である皮膚化粧料用組成物を用いることにより、使用後の肌に、乾燥した感触が抑制されつつサラサラ感を付与することができることを見出した。本発明はこれらの知見に基づいて完成させたものである。 As a result of diligent studies to achieve the above object, the present inventors have found that component (A): talc and / or silica, component (B): starch aluminum octenyl succinate, component (C): ethanol, and component (D). : Contains water, the content of the component (A) is 0.5 to 15.0% by mass, the content of the component (B) is 0.5 to 15.0% by mass, and the content of the component (C) is 0.5 to 15.0% by mass. By using a composition for skin cosmetics having a content of 20.0 to 70.0% by mass and a content of the component (D) of 10.0 to 75.0% by mass, the skin after use has a dry feel. It was found that it is possible to give a smooth feeling while being suppressed. The present invention has been completed based on these findings.
すなわち、本発明は、下記成分（Ａ）、下記成分（Ｂ）、下記成分（Ｃ）、及び下記成分（Ｄ）を含有し、上記成分（Ａ）の含有割合が０．５〜１５．０質量％、上記成分（Ｂ）の含有割合が０．５〜１５．０質量％、上記成分（Ｃ）の含有割合が２０．０〜７０．０質量％、上記成分（Ｄ）の含有割合が１０．０〜７５．０質量％である、皮膚化粧料用組成物を提供する。
成分（Ａ）：タルク及び／又はシリカ
成分（Ｂ）：オクテニルコハク酸デンプンアルミニウム
成分（Ｃ）：エタノール
成分（Ｄ）：水That is, the present invention contains the following component (A), the following component (B), the following component (C), and the following component (D), and the content ratio of the above component (A) is 0.5 to 15.0. The content ratio of the component (B) is 0.5 to 15.0% by mass, the content ratio of the component (C) is 20.0 to 70.0% by mass, and the content ratio of the component (D) is 0.5 to 15.0% by mass. A composition for skin cosmetics, which is 10.0 to 75.0% by mass, is provided.
Component (A): Talc and / or silica Component (B): Starch aluminum octenyl succinate Component (C): Ethanol Component (D): Water
上記皮膚化粧料用組成物は、炭化水素油、エステル油、シリコーン油、油脂、及び炭素数１２〜２２の脂肪族アルコールからなる群より選択される１以上の油性成分の含有割合が１．０質量％以下であることが好ましい。 The composition for skin cosmetics contains 1.0 or more oily components selected from the group consisting of hydrocarbon oils, ester oils, silicone oils, fats and oils, and aliphatic alcohols having 12 to 22 carbon atoms. It is preferably mass% or less.
また、本発明は、シート基材と、上記シート基材に含浸された上記皮膚化粧料用組成物とを含むシート化粧料を提供する。 The present invention also provides a sheet cosmetic containing the sheet base material and the skin cosmetic composition impregnated in the sheet base material.
本発明の皮膚化粧料用組成物によれば、サラサラ感を付与する。それでいて、使用後の肌に皮膜が形成されたような感触（皮膜感）を付与することができ、これにより乾燥した感触（乾燥感）を抑制することができ、肌にしっとりした感触を付与することができる。また、使用後の肌の白浮きを抑制することができる。 According to the composition for skin cosmetics of the present invention, a smooth feeling is imparted. Nevertheless, it is possible to give the skin a feeling of forming a film (film feeling) after use, thereby suppressing a dry feeling (dry feeling) and giving the skin a moist feeling. be able to. In addition, it is possible to suppress whitening of the skin after use.
［皮膚化粧料用組成物］
本発明の皮膚化粧料用組成物は、タルク及び／又はシリカ、オクテニルコハク酸デンプンアルミニウム、エタノール、並びに水を少なくとも含む。なお、本明細書において、タルク及び／又はシリカを「成分（Ａ）」、オクテニルコハク酸デンプンアルミニウムを「成分（Ｂ）」、エタノールを「成分（Ｃ）」、水を「成分（Ｄ）」とそれぞれ称する場合がある。[Composition for skin cosmetics]
The composition for skin cosmetics of the present invention contains at least talc and / or silica, aluminum starch octenyl succinate, ethanol, and water. In the present specification, talc and / or silica is referred to as "component (A)", starch aluminum octenyl succinate is referred to as "component (B)", ethanol is referred to as "component (C)", and water is referred to as "component (D)". They may be referred to as each.
すなわち、本発明の皮膚化粧料用組成物は、成分（Ａ）、成分（Ｂ）、成分（Ｃ）、及び成分（Ｄ）を少なくとも含む。本発明の皮膚化粧料用組成物は、上記成分（Ａ）〜（Ｄ）以外の成分を含んでいてもよい。また、本発明の皮膚化粧料用組成物に含まれる各成分、例えば、成分（Ａ）、成分（Ｂ）、成分（Ｃ）、成分（Ｄ）、及び他の成分などの各成分は、それぞれ、一種のみを用いてもよいし、二種以上を用いてもよい。 That is, the composition for skin cosmetics of the present invention contains at least the component (A), the component (B), the component (C), and the component (D). The composition for skin cosmetics of the present invention may contain components other than the above components (A) to (D). In addition, each component contained in the composition for skin cosmetics of the present invention, for example, each component such as component (A), component (B), component (C), component (D), and other components, respectively. , Only one kind may be used, or two or more kinds may be used.
［成分（Ａ）］
成分（Ａ）は、タルク及び／又はシリカである。すなわち、成分（Ａ）は、タルク及びシリカの一方又は両方である。成分（Ａ）を用いることにより、粒子が肌上（特に皮丘）に広がり摩擦を低減するためと考えられるが、皮膚化粧料用組成物使用後の肌にサラサラ感を付与することができる。成分（Ａ）は、一種のみを用いてもよいし、二種以上を用いてもよい。[Ingredient (A)]
Ingredient (A) is talc and / or silica. That is, the component (A) is one or both of talc and silica. It is considered that the use of the component (A) causes the particles to spread on the skin (particularly the skin hills) to reduce friction, but it is possible to impart a smooth feeling to the skin after using the composition for skin cosmetics. As the component (A), only one kind may be used, or two or more kinds may be used.
上記タルクとしては、特に限定されず、化粧料用組成物に一般的に用いられているタルクを使用することができる。 The talc is not particularly limited, and talc generally used in cosmetic compositions can be used.
上記タルクの吸油量は、特に限定されないが、１８〜５０ｍｌ／１００ｇが好ましい。また、上記タルクの平均粒径Ｄ５０は、特に限定されないが、０．５〜２５．０μｍが好ましい。 The oil absorption of the talc is not particularly limited, but is preferably 18 to 50 ml / 100 g. The average particle size D50 of the talc is not particularly limited, but is preferably 0.5 to 25.0 μm.
上記シリカとしては、特に限定されず、化粧料用組成物に一般的に用いられているシリカ（無水ケイ酸）を使用することができる。上記シリカは、疎水化処理されていない無水ケイ酸（親水性のシリカ）であってもよいし、疎水化無水ケイ酸であってもよい。また、上記シリカは、アミノ酸、エステル、又はレシチンなどで表面処理されたシリカであってもよい。上記シリカは、肌への摩擦抵抗の低減に優れる観点から、球状シリカが好ましく、真球状シリカがさらに好ましい。 The silica is not particularly limited, and silica (silicic anhydride) generally used in cosmetic compositions can be used. The silica may be silicic anhydride (hydrophilic silica) that has not been hydrophobized, or may be hydrophobicized silicon dioxide. Further, the silica may be silica surface-treated with amino acids, esters, lecithin or the like. The silica is preferably spherical silica, and more preferably true spherical silica, from the viewpoint of excellent reduction of frictional resistance to the skin.
上記シリカの吸油量は、特に限定されないが、２０〜３００ｍｌ／１００ｇが好ましく、より好ましくは２０〜１２０ｍｌ／１００ｇである。また、上記シリカの平均粒径Ｄ５０は、特に限定されないが、１〜１５μｍが好ましい。 The oil absorption amount of the silica is not particularly limited, but is preferably 20 to 300 ml / 100 g, and more preferably 20 to 120 ml / 100 g. The average particle size D50 of the silica is not particularly limited, but is preferably 1 to 15 μm.
なお、本明細書において、成分（Ａ）の吸油量はＪＩＳ Ｋ５１０１に記載の測定方法に準拠して測定される値である。また、本明細書において、成分（Ａ）の平均粒径Ｄ５０はレーザー回折法により測定される値である。 In this specification, the oil absorption amount of the component (A) is a value measured according to the measuring method described in JIS K5101. Further, in the present specification, the average particle size D50 of the component (A) is a value measured by a laser diffraction method.
成分（Ａ）は市販品を用いることもできる。タルクの市販品としては、商品名「タルクＭＳ」（日本タルク株式会社製）などが挙げられる。シリカの市販品としては、例えば、商品名「ＳＩＬＩＣＡ ＰＥＡＲＬ Ｐ−４Ｍ」、商品名「ＳＩＬＩＣＡ ＰＥＡＲＬ ２０ＣＧ」、商品名「ＨＣＳ １６０Ｍ５」、商品名「ＳＩＬＩＣＡ ＭＩＣＲＯ ＢＥＡＤ ＢＡ−１」（以上、日揮触媒化成株式会社製）などが挙げられる。 A commercially available product can also be used as the component (A). Examples of commercially available talc products include the trade name "talc MS" (manufactured by Japan Talc Co., Ltd.). Examples of commercially available silica products include the product name "SILICA PEARL P-4M", the product name "SILICA PEARL 20CG", the product name "HCS 160M5", and the product name "SILICA MICRO BEAD BA-1" (above, JGC Catalysts and Chemicals). (Made by Co., Ltd.) and so on.
本発明の皮膚化粧料用組成物中の成分（Ａ）の含有割合は、本発明の皮膚化粧料用組成物１００質量％に対して、０．５〜１５．０質量％であり、好ましくは０．７〜１４．０質量％、より好ましくは２．０〜１３．０質量％である。上記含有割合が０．５質量％以上であることにより、肌への摩擦抵抗を低減して、使用後の肌にサラサラ感を付与することができる。上記含有量が１５．０質量％以下であることにより、白浮きを抑制することができる。上記成分（Ａ）の含有割合は、本発明の皮膚化粧料用組成物中の全ての成分（Ａ）の含有割合の合計である。 The content ratio of the component (A) in the composition for skin cosmetics of the present invention is 0.5 to 15.0% by mass, preferably 0.5 to 15.0% by mass, based on 100% by mass of the composition for skin cosmetics of the present invention. It is 0.7 to 14.0% by mass, more preferably 2.0 to 13.0% by mass. When the content ratio is 0.5% by mass or more, the frictional resistance to the skin can be reduced and the skin after use can be given a smooth feeling. When the content is 15.0% by mass or less, whitening can be suppressed. The content ratio of the above component (A) is the total content ratio of all the components (A) in the composition for skin cosmetics of the present invention.
［成分（Ｂ）］
成分（Ｂ）は、オクテニルコハク酸デンプンアルミニウムである。上記オクテニルコハク酸デンプンアルミニウムは、オクテニルコハク酸デンプンＡｌ又はオクテニルコハク酸トウモロコシデンプンアルミニウムと表記される場合がある。成分（Ｂ）を用いることにより、使用後の肌において、成分（Ａ）によるサラサラ感を維持しつつ、皮膜感を付与し、これにより乾燥感を抑制することができる。成分（Ｂ）は、一種のみを用いてもよいし、二種以上を用いてもよい。[Component (B)]
Ingredient (B) is starch aluminum octenyl succinate. The octenyl succinate starch aluminum may be referred to as octenyl succinate starch Al or octenyl succinate corn starch aluminum. By using the component (B), it is possible to impart a film feeling to the skin after use while maintaining the smooth feeling due to the component (A), thereby suppressing the dry feeling. As the component (B), only one kind may be used, or two or more kinds may be used.
本発明の皮膚化粧料用組成物において、成分（Ｂ）は粉体として配合される。オクテニルコハク酸デンプンアルミニウムは、親水化・ゲル化（所謂、α化や糊化）させるように比較的高温に加温することで、オクテニルコハク酸デンプンアルミニウムに由来する増粘剤として、粉体状ではなくなった状態で使用されることがある。しかしながら、本発明の皮膚化粧料用組成物では、成分（Ｂ）は例えば５０℃以下の比較的低温で配合されることで、粉体の状態で含まれる。粉体として成分（Ｂ）を配合することで、使用後の肌において、皮膜感を保持しつつ乾燥感を抑制するという効果を発揮することができる。 In the composition for skin cosmetics of the present invention, the component (B) is blended as a powder. Starch aluminum octenyl succinate is no longer in powder form as a thickener derived from aluminum starch octenyl succinate by heating to a relatively high temperature so as to hydrophilize and gel (so-called pregelatinization and gelatinization). It may be used in a state of being. However, in the composition for skin cosmetics of the present invention, the component (B) is contained in a powder state by being blended at a relatively low temperature of, for example, 50 ° C. or lower. By blending the component (B) as a powder, it is possible to exert the effect of suppressing the dry feeling while maintaining the film feeling on the skin after use.
成分（Ｂ）は市販品を用いることもできる。成分（Ｂ）の市販品としては、例えば、商品名「ＤＲＹ−ＦＬＯ ＰＵＲＥ」（Ａｋｚｏ Ｎｏｂｅｌ Ｃｈｅｍｉｃａｌｓ社製）、商品名「オクティエ」（日澱化学株式会社製）などが挙げられる。 A commercially available product can also be used as the component (B). Examples of commercially available products of the component (B) include the trade name "DRY-FLO PURE" (manufactured by Akzo Nobel Chemicals) and the trade name "Octier" (manufactured by Nissho Chemical Co., Ltd.).
本発明の皮膚化粧料用組成物中の成分（Ｂ）の含有割合は、本発明の皮膚化粧料用組成物１００質量％に対して、０．５〜１５．０質量％であり、好ましくは１．０〜１４．０質量％、より好ましくは２．０〜１３．０質量％である。上記含有割合が０．５質量％以上であることにより、肌に均一に塗布することが可能となり、成分（Ａ）によるサラサラ感を維持しつつ、皮膜感を付与し、これにより乾燥感を抑制することができる。上記含有量が１５．０質量％以下であることにより、白浮きを抑制することができる。上記成分（Ｂ）の含有割合は、本発明の皮膚化粧料用組成物中の全ての成分（Ｂ）の含有割合の合計である。 The content ratio of the component (B) in the composition for skin cosmetics of the present invention is 0.5 to 15.0% by mass, preferably 0.5 to 15.0% by mass, based on 100% by mass of the composition for skin cosmetics of the present invention. It is 1.0 to 14.0% by mass, more preferably 2.0 to 13.0% by mass. When the content ratio is 0.5% by mass or more, it can be applied uniformly to the skin, and while maintaining the smooth feeling due to the component (A), it gives a film feeling and thereby suppresses the dry feeling. can do. When the content is 15.0% by mass or less, whitening can be suppressed. The content ratio of the above component (B) is the total content ratio of all the components (B) in the composition for skin cosmetics of the present invention.
［成分（Ｃ）］
成分（Ｃ）はエタノールである。成分（Ｃ）を用いることにより、皮膚化粧料用組成物中において疎水性である成分（Ｂ）を分散させることができる。また、速乾性やさっぱりとした使用感を付与できる。[Component (C)]
The component (C) is ethanol. By using the component (C), the hydrophobic component (B) can be dispersed in the composition for skin cosmetics. In addition, quick-drying and a refreshing feeling can be imparted.
本発明の皮膚化粧料用組成物中の成分（Ｃ）の含有割合は、本発明の皮膚化粧料用組成物１００質量％に対して、２０．０〜７０．０質量％であり、好ましくは２２．０〜６５．０質量％、より好ましくは２５．０〜６０．０質量％である。上記含有割合が２０．０質量％未満であると、成分（Ａ）が皮膚化粧料用組成物中で均一分散できなくなる。上記含有量が７０．０質量％を超えると、乾燥感が生じやすくなる。 The content ratio of the component (C) in the composition for skin cosmetics of the present invention is 20.0 to 70.0% by mass, preferably 20.0 to 70.0% by mass, based on 100% by mass of the composition for skin cosmetics of the present invention. It is 22.0 to 65.0% by mass, more preferably 25.0 to 60.0% by mass. If the content ratio is less than 20.0% by mass, the component (A) cannot be uniformly dispersed in the composition for skin cosmetics. When the content exceeds 70.0% by mass, a feeling of dryness is likely to occur.
［成分（Ｄ）：水］
成分（Ｄ）は水であり、特に限定されないが、精製水が好ましい。本発明の皮膚化粧料用組成物中の成分（Ｄ）の含有割合は、本発明の皮膚化粧料用組成物１００質量％に対して、１０．０〜７５．０質量％であり、好ましくは３０．０〜７０．０質量％である。[Component (D): Water]
The component (D) is water, and although it is not particularly limited, purified water is preferable. The content ratio of the component (D) in the composition for skin cosmetics of the present invention is 10.0 to 75.0% by mass, preferably 10.0 to 75.0% by mass, based on 100% by mass of the composition for skin cosmetics of the present invention. It is 30.0 to 70.0% by mass.
［その他の成分］
本発明の皮膚化粧料用組成物は、上記成分（Ａ）〜（Ｄ）以外の成分（その他の成分）を含んでいてもよい。上記その他の成分しては、特に限定されず、例えば、化粧品や医薬部外品に通常用いられる成分等が挙げられる。具体的には、例えば、成分（Ｃ）以外の低級アルコール；ノニオン性界面活性剤、アニオン性界面活性剤、カチオン性界面活性剤、両性界面活性剤等の界面活性剤；多価アルコール；グリチルリチン酸及びその塩等の抗炎症剤；メントール等の清涼剤；リン酸及びその塩類、クエン酸及びその塩類、乳酸及びその塩類、水酸化ナトリウム、トリエタノールアミン等のｐＨ調整剤；香料；紫外線吸収剤；酸化防止剤；防腐剤；金属イオン封鎖剤；成分（Ａ）以外の粉体；色素；顔料；ビタミン類；アミノ酸類；収斂剤；美白剤；動植物抽出物；中和剤；殺菌剤；制汗剤；消臭剤；酸；アルカリなどが挙げられる。[Other ingredients]
The composition for skin cosmetics of the present invention may contain components (other components) other than the above components (A) to (D). The other ingredients are not particularly limited, and examples thereof include ingredients usually used in cosmetics and quasi-drugs. Specifically, for example, lower alcohols other than the component (C); surfactants such as nonionic surfactants, anionic surfactants, cationic surfactants, and amphoteric surfactants; polyhydric alcohols; glycyrrhizinic acid. And anti-inflammatory agents such as salts; refreshing agents such as menthol; pH adjusters such as phosphoric acid and its salts, citric acid and its salts, lactic acid and its salts, sodium hydroxide, triethanolamine and the like; fragrances; ultraviolet absorbers Antioxidants; Preservatives; Metal ion sequestering agents; Powders other than component (A); Dyes; Pigments; Vitamins; Amino acids; Astringents; Whitening agents; Animal and plant extracts; Neutralizing agents; Bactericides; Antiseptic Sweat agents; deodorants; acids; alkalis and the like.
本発明の皮膚化粧料用組成物は、炭化水素油、エステル油、シリコーン油、油脂、及び炭素数１２〜２２の脂肪族アルコールからなる群より選択される１以上の油性成分を含まないか、又は上記油性成分の含有割合が１．０質量％以下であることが好ましく、より好ましくは０．７質量％以下、さらに好ましくは０．５質量％以下である。上記油性成分の含有割合が１．０質量％以下であると、油性成分に由来するぬるつきを抑制することができる。 The composition for skin cosmetics of the present invention does not contain one or more oily components selected from the group consisting of hydrocarbon oils, ester oils, silicone oils, fats and oils, and fatty alcohols having 12 to 22 carbon atoms. Alternatively, the content ratio of the oily component is preferably 1.0% by mass or less, more preferably 0.7% by mass or less, still more preferably 0.5% by mass or less. When the content ratio of the oily component is 1.0% by mass or less, the sliminess derived from the oily component can be suppressed.
上記炭化水素油としては、例えば、α−オレフィンオリゴマー、ワセリン、イソパラフィン、軽質イソパラフィン、軽質流動イソパラフィン、スクワラン、合成スクワラン、植物性スクワラン、流動イソパラフィン、流動パラフィン等、水添ポリイソブテン、水添（テトラデセニル／メチルペンタデセン）、イソドデカンなどが挙げられる。 Examples of the hydrocarbon oil include α-olefin oligomer, petrolatum, isoparaffin, light isoparaffin, light liquid isoparaffin, squalane, synthetic squalane, vegetable squalane, liquid isoparaffin, liquid paraffin, hydrogenated polyisobutene, hydrogenated (tetradecenyl /). Methylpentadecene), isododecane and the like.
上記エステル油としては、例えば、オレイン酸エチル、ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ミリスチン酸ミリスチル、パルミチン酸セチル、パルミチン酸２−エチルヘキシル、ミリスチン酸オクチルドデシル、イソステアリン酸イソプロピル、イソステアリン酸プロピレングリコール、２−エチルヘキサン酸セチル、トリ２−エチルヘキサン酸グリセリル、トリ（カプリル酸／カプリン酸）グリセリル、イソノナン酸イソノニル、アジピン酸ジイソプロピル、テトラオクタン酸ペンタエリスリチル、テトライソステアリン酸ペンタエリトリット、リンゴ酸ジイソステアリル、トリエチルヘキサン酸エリスリチル、ヒドロキシステアリン酸２−エチルヘキシル、ヘキサ（ヒドロキシステアリン酸／ステアリン酸／ロジン酸）ジペンタエリスリチル、テトラ（ヒドロキシステアリン酸／イソステアリン酸）ジペンタエリスリチル、ヘキサヒドロキシステアリン酸ジペンタエリスリチル、（エチルヘキサン酸／ステアリン酸／アジピン酸）グリセリル、トリ（カプリル酸／カプリン酸／ミリスチン酸／ステアリン酸）グリセリル、ヘキサ（ベヘン酸／安息香酸／エチルヘキサン酸）ジペンタエリスリチル、安息香酸アルキル（Ｃ１２−１５）などが挙げられる。 Examples of the ester oil include ethyl oleate, isopropyl myristate, isopropyl palmitate, myristyl myristate, cetyl palmitate, 2-ethylhexyl palmitate, octyldodecyl myristate, isopropyl isostearate, propylene glycol isostearate, 2-. Cetyl ethylhexanate, glyceryl tri2-ethylhexanoate, glyceryl tri (caprylic acid / capric acid), isononyl isononanoate, diisopropyl adipate, pentaerythrityl tetraoctanoate, pentaerythrit tetraisostearate, diisostearyl malate , Erythrityl triethylhexarate, 2-ethylhexyl hydroxystearate, hexa (hydroxystearic acid / stearic acid / logonic acid) dipentaerythrityl, tetra (hydroxystearic acid / isostearic acid) dipentaerythrityl, dipentaerythrityl hexahydroxystearate, (ethylhexanoic acid / stearic acid) Examples thereof include acid / adipic acid) glyceryl, tri (caprylic acid / capric acid / myristic acid / stearic acid) glyceryl, hexa (bechenic acid / benzoic acid / ethylhexanoic acid) dipentaerythrityl, alkyl benzoate (C12-15) and the like.
上記シリコーン油としては、特に限定されないが、例えば、メチルポリシロキサン、高重合メチルポリシロキサン等のジメチルシリコーン油；メチルフェニルポリシロキサン等のメチルフェニルシリコーン油；メチルシクロポリシロキサン、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサシロキサン等の環状シリコーン油；アミノプロピルメチルシロキサン・ジメチルシロキサン共重合体、アミノエチルアミノプロピルシロキサン・ジメチルシロキサン共重合体、アミノエチルアミノプロピルメチルシロキサン・ジメチルシロキサン共重合体等のアミノ変性シリコーン、カルボキシ変性シリコーン、脂肪酸変性シリコーン、アルコール変性シリコーン、脂肪族アルコール変性シリコーン、エポキシ変性シリコーン、フッ素変性シリコーン、アルキル変性シリコーン等の変性シリコーン；メチルハイドロジェンポリシロキサン、ジメチコノールなどが挙げられる。 The silicone oil is not particularly limited, but for example, dimethyl silicone oil such as methylpolysiloxane and highly polymerized methylpolysiloxane; methylphenylsilicone oil such as methylphenylpolysiloxane; methylcyclopolysiloxane, octamethylcyclotetrasiloxane, and the like. Cyclic silicone oils such as decamethylcyclopentasiloxane and dodecamethylcyclohexasiloxane; aminopropylmethylsiloxane / dimethylsiloxane copolymer, aminoethylaminopropylsiloxane / dimethylsiloxane copolymer, aminoethylaminopropylmethylsiloxane / dimethylsiloxane Amino-modified silicones such as polymers, carboxy-modified silicones, fatty acid-modified silicones, alcohol-modified silicones, aliphatic alcohol-modified silicones, epoxy-modified silicones, fluorine-modified silicones, alkyl-modified silicones and other modified silicones; methylhydrogenpolysiloxane, dimethiconol, etc. Can be mentioned.
上記油脂としては、マカデミアンナッツ油、ユーカリ油、ヤシ油、アボガド油、サフラワー油、オリーブ油、パーム油、パーム核油、ククイナッツ油、シア脂（シアバター）、カカオバター、アーモンド油、ヒマワリ油、ローズヒップ油、オリーブスクワラン、カメリアオイル、キウイフルーツシード油、ツバキ油、杏仁油、ゴマ油、大豆油、ホホバ油、ヒマシ油、ヘーゼルナッツ油、メドウフォーム油、ハッカ油、アルガンオイル、カロットオイル、ラベンダー油、シュガースクワラン、ダマスクバラ花ロウ、センチフォリアバラ花ロウ、ソケイ花ワックス、椿油、綿実油、コーン油、菜種油、米ぬか油、カポック油、乳脂、ラード、魚油、鯨油、これらの水素添加物（例えば、水素添加ヒマシ油、水素添加ホホバ油、水素添加パーム油、水素添加アボカド油、水素添加大豆油等）などが挙げられる。 The above fats and oils include macadamian nut oil, eucalyptus oil, palm oil, avocado oil, safflower oil, olive oil, palm oil, palm kernel oil, kukui nut oil, shea butter, cacao butter, almond oil, sunflower oil. , Rosehip oil, olive squalane, camellia oil, kiwi fruit seed oil, camellia oil, apricot oil, sesame oil, soybean oil, jojoba oil, castor oil, hazelnut oil, meadowfoam oil, peppermint oil, argan oil, carrot oil, lavender Oil, sugar squalane, damask rose flower wax, centifolia rose flower wax, sokei flower wax, camellia oil, cottonseed oil, corn oil, rapeseed oil, rice bran oil, capoc oil, milk fat, lard, fish oil, whale oil, their hydrogen additives (eg , Hydrogenated castor oil, hydrogenated jojoba oil, hydrogenated palm oil, hydrogenated avocado oil, hydrogenated soybean oil, etc.).
上記炭素数１２〜２２の脂肪族アルコールとしては、例えば、セチルアルコール、ステアリルアルコール、イソステアリルアルコール、ミリスチルアルコール、２−オクチルドデカノール、オレイルアルコール等が挙げられる。 Examples of the fatty alcohol having 12 to 22 carbon atoms include cetyl alcohol, stearyl alcohol, isostearyl alcohol, myristyl alcohol, 2-octyldodecanol, and oleyl alcohol.
本発明の皮膚化粧料用組成物は、保湿感を付与するなどの観点で、多価アルコールを含んでいてもよい。上記多価アルコールは、一種のみを使用してもよいし、二種以上を使用してもよい。 The composition for skin cosmetics of the present invention may contain a polyhydric alcohol from the viewpoint of imparting a moisturizing feeling. As the polyhydric alcohol, only one kind may be used, or two or more kinds may be used.
上記多価アルコールとしては、特に限定されないが、例えば、エチレングリコール、ジエチレングリコール、トリエチレングリコール、プロピレングリコール、１，３−プロパンジオール、ジプロピレングリコール、イソプレングリコール、１，３−ブチレングリコール、１，２−ブタンジオール、１，２−ペンタンジオール、１，２−ヘキサンジオール、１，２−オクタンジオール、１，２−デカンジオール、ポリエチレングリコール、グリセリン、ジグリセリン、ポリグリセリン、ソルビトール、マルチトール、トレハロースなどが挙げられる。 The polyhydric alcohol is not particularly limited, but for example, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, 1,3-propanediol, dipropylene glycol, isoprene glycol, 1,3-butylene glycol, 1,2. -Butanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol, 1,2-decanediol, polyethylene glycol, glycerin, diglycerin, polyglycerin, sorbitol, martitol, trehalose, etc. Can be mentioned.
上記多価アルコールの含有割合は、本発明の皮膚化粧料用組成物１００質量％に対して、保湿感を付与する観点から、０．５〜２．０質量％が好ましい。ただし、サラサラ感を付与する効果を特に優れたものとする観点からは、本発明の皮膚化粧料用組成物は、多価アルコールを含まないか、又は多価アルコールの含有割合が１．０質量％以下であることが好ましい。 The content ratio of the polyhydric alcohol is preferably 0.5 to 2.0% by mass from the viewpoint of imparting a moisturizing feeling to 100% by mass of the composition for skin cosmetics of the present invention. However, from the viewpoint of making the effect of imparting a smooth feeling particularly excellent, the composition for skin cosmetics of the present invention does not contain polyhydric alcohol, or the content ratio of polyhydric alcohol is 1.0 mass by mass. % Or less is preferable.
本発明の皮膚化粧料用組成物は、特に限定されず、公知乃至慣用の方法により製造することができる。例えば、上記各成分を混合し、ディスパーミキサー、パドルミキサー等の公知の撹拌装置を用いて撹拌する方法などで、各成分を均一化する方法が挙げられる。 The composition for skin cosmetics of the present invention is not particularly limited, and can be produced by a known or conventional method. For example, a method of mixing each of the above components and stirring using a known stirring device such as a disper mixer or a paddle mixer to homogenize each component can be mentioned.
本発明の皮膚化粧料用組成物は、水［成分（Ｄ）］中にタルク及び／又はシリカ［成分（Ａ）］を配合することにより、使用後の肌にサラサラ感を与える。また、オクテニルコハク酸デンプンアルミニウム［成分（Ｂ）］を特定の割合で併用することにより、皮膜感を付与し、乾燥感を抑制することができる。これにより、使用後の肌の、サラサラ感と、乾燥感の抑制によるしっとり感とが両立することができる。この効果のメカニズムは以下のように推測される。成分（Ａ）は皮膚上の凹凸部の凸部（皮丘）に広がり摩擦を低減するためと考えられるが、皮膚化粧料用組成物使用後の肌にサラサラ感を付与することができる。しかしながら、成分（Ａ）は、皮膚上の凹凸の凹部（皮溝）に入りにくい。このため、成分（Ａ）のみでは、使用後の肌に皮膜感を付与することはできない。一方、粉体の成分（Ｂ）は疎水性が高いため肌への親和性が高いこと、また形状などの表面性能に基づき、皮膚上の凹凸の凹部（皮溝）に入りやすい。これにより、成分（Ａ）と成分（Ｂ）を併用することによって、粉体が肌全体を覆うことが可能となり、優れた皮膜感を付与することができる。また、使用後の肌において白浮きも抑制される。なお、エタノール［成分（Ｃ）］を特定の割合で配合することにより、疎水性が高く粉体として通常水媒体に配合されることがない成分（Ｂ）が成分（Ｄ）中で分散することが可能となる。また、速乾性を付与することができる。 The composition for skin cosmetics of the present invention gives a smooth feeling to the skin after use by blending talc and / or silica [component (A)] in water [component (D)]. Further, by using the starch aluminum octenyl succinate [component (B)] in combination at a specific ratio, a film feeling can be imparted and a dry feeling can be suppressed. As a result, it is possible to achieve both a smooth feeling of the skin after use and a moist feeling by suppressing the feeling of dryness. The mechanism of this effect is speculated as follows. It is considered that the component (A) spreads on the convex portion (skin hill) of the uneven portion on the skin to reduce friction, but it is possible to impart a smooth feeling to the skin after using the composition for skin cosmetics. However, the component (A) does not easily enter the uneven recesses (skin grooves) on the skin. Therefore, the component (A) alone cannot give a film feeling to the skin after use. On the other hand, the powder component (B) has a high affinity for the skin because it is highly hydrophobic, and it easily enters the uneven recesses (skin grooves) on the skin based on the surface performance such as the shape. As a result, by using the component (A) and the component (B) in combination, the powder can cover the entire skin, and an excellent film feeling can be imparted. In addition, whitening is suppressed on the skin after use. By blending ethanol [component (C)] in a specific ratio, the component (B), which is highly hydrophobic and is not normally blended in an aqueous medium as a powder, is dispersed in the component (D). Is possible. In addition, quick-drying property can be imparted.
本発明の皮膚化粧料用組成物は、皮膚（肌）に塗布するために用いられる化粧料用組成物である。本発明の皮膚化粧料用組成物を塗布する部位としては、特に限定されず、例えば、顔面（例えば、額、目元、目じり、頬、口元など）や、腕、肘、手の甲、指先、足、膝、かかと、首、脇、背中などが挙げられる。 The composition for skin cosmetics of the present invention is a composition for cosmetics used for application to the skin (skin). The site to which the composition for skin cosmetics of the present invention is applied is not particularly limited, and for example, the face (for example, forehead, eyes, eyes, cheeks, mouth, etc.), arms, elbows, back of hands, fingertips, feet, etc. Knees, heels, neck, sides, back, etc.
［シート化粧料］
本発明の皮膚化粧料用組成物をシート基材に含浸することによりシート化粧料が得られる。すなわち、上記シート化粧料は、シート基材と、上記シート基材に含浸された本発明の皮膚化粧料用組成物とを含む。なお、本明細書では、上記シート化粧料を「本発明のシート化粧料」と称する場合がある。本発明のシート化粧料は、シート基材及び本発明の皮膚化粧料用組成物以外の構成成分を含んでいてもよい。[Sheet cosmetics]
A sheet cosmetic can be obtained by impregnating the sheet base material with the composition for skin cosmetics of the present invention. That is, the sheet cosmetic contains the sheet base material and the composition for skin cosmetics of the present invention impregnated in the sheet base material. In addition, in this specification, the said sheet cosmetics may be referred to as "the sheet cosmetics of this invention". The sheet cosmetics of the present invention may contain components other than the sheet base material and the composition for skin cosmetics of the present invention.
上記シート基材は、本発明の皮膚化粧料用組成物が含浸可能なシート状の支持体である。上記シート基材としては、織布、不織布が好ましい。上記シート基材は、積層体（即ち、積層シート）であってもよく、例えば、織布の積層体、不織布の積層体、織布と不織布の積層体などであってもよい。上記シート基材は、使用感、加工のしやすさ等の観点から、不織布を含むシート基材であることが好ましく、より好ましくは不織布である。 The sheet base material is a sheet-like support that can be impregnated with the composition for skin cosmetics of the present invention. As the sheet base material, a woven fabric or a non-woven fabric is preferable. The sheet base material may be a laminated body (that is, a laminated sheet), and may be, for example, a laminated body of a woven fabric, a laminated body of a non-woven fabric, a laminated body of a woven fabric and a non-woven fabric, or the like. From the viewpoint of usability, ease of processing, and the like, the sheet base material is preferably a sheet base material containing a non-woven fabric, and more preferably a non-woven fabric.
上記不織布としては、スパンボンド不織布、スパンレース不織布、サーマルボンド不織布、ニードルパンチ不織布、スティッチボンド不織布などが挙げられる。 Examples of the non-woven fabric include spunbond non-woven fabric, spunlace non-woven fabric, thermal bond non-woven fabric, needle punch non-woven fabric, stitch bond non-woven fabric and the like.
上記織布や不織布を構成する繊維としては、特に限定されず、例えば、天然繊維、合成繊維、半天然繊維などが挙げられる。上記天然繊維としては、綿、パルプ、シルク、セルロース、麻、リンター、カボックなどが挙げられる。上記合成繊維としては、ナイロン繊維、ポリエステル繊維（例えば、ポリエチレンテレフタレート繊維、ポリブチレンテレフタレート繊維等）、アクリル繊維、ポリオレフィン繊維（例えば、ポリプロピレン繊維、ポリエチレン繊維等）などが挙げられる。上記半天然繊維としては、レーヨン、アセテートなどが挙げられる。上記繊維は、一種のみを用いてもよいし、二種以上を用いてもよい。また、二種以上の上記繊維からなる混紡繊維を用いてもよい。 The fibers constituting the woven fabric or the non-woven fabric are not particularly limited, and examples thereof include natural fibers, synthetic fibers, and semi-natural fibers. Examples of the natural fiber include cotton, pulp, silk, cellulose, hemp, linter, and cabock. Examples of the synthetic fiber include nylon fiber, polyester fiber (for example, polyethylene terephthalate fiber, polybutylene terephthalate fiber, etc.), acrylic fiber, polyolefin fiber (for example, polypropylene fiber, polyethylene fiber, etc.) and the like. Examples of the semi-natural fiber include rayon and acetate. As the fiber, only one kind may be used, or two or more kinds may be used. Further, a blended fiber composed of two or more kinds of the above fibers may be used.
上記シート基材は、エンボス加工処理が施されていてもよい。上記エンボス加工処理としては、特に限定されず、例えば、裏面を押し上げて浮かす（したがって裏面は凹む）方式や、表面に特殊なインクを付着することで凸部を形成する（裏面は凹まない）方式などが挙げられる。 The sheet base material may be embossed. The embossing process is not particularly limited, and for example, a method of pushing up the back surface to float (therefore the back surface is dented) or a method of forming a convex portion by adhering a special ink to the front surface (the back surface is not dented). And so on.
上記シート基材の目付は、特に限定されないが、２０〜１００ｇ／ｍ2が好ましく、より好ましくは３０〜８０ｇ／ｍ2である。目付が上記範囲内であると、肌を拭く際に、シート基材が丸まらず使用感に優れる。また、シート化粧料の単位面積あたりの皮膚化粧料用組成物の含浸量が多くなる。これにより、シリカ等の粉体の肌への付着量が多くなるため、使用後の肌の皮膜感及び乾燥感のなさがより向上する。さらに、肌の広範囲に使用する場合にも十分な効果が得られ、特にボディ用のシート化粧料等として用いる場合の使用性がより一層向上するため好ましい。The basis weight of the sheet base material is not particularly limited , but is preferably 20 to 100 g / m 2, and more preferably 30 to 80 g / m 2 . When the basis weight is within the above range, the sheet base material does not curl when wiping the skin, and the feeling of use is excellent. In addition, the impregnation amount of the skin cosmetic composition per unit area of the sheet cosmetic is increased. As a result, the amount of powder such as silica adhering to the skin increases, so that the feeling of film and dryness of the skin after use is further improved. Further, a sufficient effect can be obtained even when it is used over a wide range of skin, and it is particularly preferable because its usability is further improved when it is used as a sheet cosmetic for a body or the like.
上記シート基材は、織布や不織布等の種類に応じて、公知乃至慣用の製造方法により製造することができる。また、上記シート基材は市販品を用いることもできる。上記シート基材の市販品としては、特に限定されないが、例えば、商品名「ＲＨ」、商品名「ＰＬＤＦ−４０Ｄ」、商品名「ＡＳ−４０」（以上、ダイワボウポリテック株式会社製）、商品名「ＴＣＦ４０４ＷＪ」（フタムラ化学株式会社製）、商品名「コットエース Ａ０６０Ｓ／Ａ１８」、商品名「コットエース Ｃ０３０Ｓ／Ａ１８」（以上、ユニチカ株式会社製）、商品名「クラフレックスＪＰ２４４５Ｂ０１９」、商品名「クラフレックスＪＰ０５０９Ｂ０５６」、商品名「クラフレックスＪＰ４２５０Ｈ０２３」（以上、株式会社クラレ製）、商品名「ベンリーゼＪＰ２５４」、商品名「ベンリーゼＲＥ７５Ｋ」（以上、旭化成株式会社製）、商品名「サンモアＳＰ８７４０」、商品名「サンモアＳＰ８７４８」（以上、三昭紙業株式会社製）、商品名「Ｍ１−３０−２ＰＥ」（伊野紙株式会社製）などが挙げられる。 The sheet base material can be produced by a known or conventional manufacturing method depending on the type of woven fabric, non-woven fabric, or the like. Further, as the sheet base material, a commercially available product can also be used. The commercially available product of the sheet base material is not particularly limited, but for example, the product name "RH", the product name "PLDF-40D", the product name "AS-40" (all manufactured by Daiwa Bow Polytech Co., Ltd.), and the product name. "TCF404WJ" (manufactured by Futamura Chemical Co., Ltd.), product name "Cott Ace A060S / A18", product name "Cott Ace C030S / A18" (manufactured by Unitika Co., Ltd.), product name "Claflex JP2445B019", product name " Clarflex JP0509B056 ", product name" Craflex JP4250H023 "(above, manufactured by Kuraray Co., Ltd.), product name" Benrise JP254 ", product name" Benrise RE75K "(above, manufactured by Asahi Kasei Co., Ltd.), product name" Sunmore SP8740 ", Examples thereof include the product name "Sunmore SP8748" (manufactured by Sansho Paper Industry Co., Ltd.) and the product name "M1-30-2PE" (manufactured by Ino Paper Co., Ltd.).
本発明のシート化粧料における、上記シート基材に対する含浸された本発明の皮膚化粧料用組成物の質量割合は、特に限定されないが、上記シート基材１００質量部に対して、１００〜１０００質量部であることが好ましく、より好ましくは１５０〜７００質量部である。 The mass ratio of the impregnated skin cosmetic composition of the present invention to the sheet substrate in the sheet cosmetic of the present invention is not particularly limited, but is 100 to 1000 mass with respect to 100 parts by mass of the sheet substrate. It is preferably parts, more preferably 150 to 700 parts by mass.
本発明のシート化粧料の形状はシート状である。これにより、皮膚（肌）を拭く使用形態での使用性に優れ、携帯性にも優れる。シートの平面形状は、特に限定されないが、例えば、四角形（例えば、正方形、長方形等）、三角形等の多角形；円形、楕円形、半円形；三日月形；樽形；鼓形；キャラクターの形状などが挙げられる。中でも、生産性、使用性や梱包性の観点からは四角形が好ましい。本発明のシート化粧料には、切れ込み部、くり抜き部、凹凸部などの成型が施されていてもよい。本発明のシート化粧料のシートの片面の表面積は、特に限定されないが、使用性、携帯性、包装性などの観点から、１００〜３０００ｃｍ2が好ましく、より好ましくは１５０〜１０００ｃｍ2である。The shape of the sheet cosmetic of the present invention is sheet-like. As a result, it is excellent in usability in a usage form for wiping the skin (skin) and also excellent in portability. The planar shape of the sheet is not particularly limited, but for example, a quadrangle (for example, a square, a rectangle, etc.), a polygon such as a triangle; a circle, an ellipse, a semicircle; a crescent shape; a barrel shape; a drum shape; a character shape, etc. Can be mentioned. Above all, a quadrangle is preferable from the viewpoint of productivity, usability and packing property. The sheet cosmetic of the present invention may be molded with a notch, a hollow, an uneven portion, or the like. One side of the surface area of the sheet of the sheet cosmetic of the present invention is not particularly limited, usability, portability, from the viewpoint of packaging properties, preferably 100～3000Cm 2, more preferably 150~1000cm 2.
本発明のシート化粧料は、乾燥防止、外出時の携帯性、使用時の取り扱い性等の観点から、包装容器に収納されることが好ましい。本発明のシート化粧料は１枚ごとに個別包装されてもよいし、生産コスト、生産効率等の観点から、複数枚の本発明のシート化粧料が同一包装容器内に収納されてもよい。１つの包装容器に収納される本発明のシート化粧料の枚数は、特に限定されないが、２〜５０枚（／１包装容器）が好ましい。本発明のシート化粧料は、二つ折り、三つ折り、四つ折り等に折り畳んで包装容器に収納されていることが好ましい。 The sheet cosmetic of the present invention is preferably stored in a packaging container from the viewpoints of preventing drying, portability when going out, handleability when using, and the like. The sheet cosmetics of the present invention may be individually packaged individually, or a plurality of sheet cosmetics of the present invention may be stored in the same packaging container from the viewpoint of production cost, production efficiency and the like. The number of sheet cosmetics of the present invention stored in one packaging container is not particularly limited, but is preferably 2 to 50 sheets (1/1 packaging container). The sheet cosmetic of the present invention is preferably folded in half, folded in three, folded in four, or the like and stored in a packaging container.
上記包装容器としては、例えば、袋体（包装袋）、箱状容器などが挙げられる。上記包装容器は、本発明の皮膚化粧料用組成物の揮発を抑制できるものが好ましい。上記包装容器の材質としては、特に限定されないが、例えば、ポリエチレンテレフタレート（ＰＥＴ）、ポリエチレン（ＰＥ）、ポリプロピレン（ＰＰ）等の樹脂；アルミニウム等の金属等が挙げられる。上記包装容器としては、軽量であり優れた揮発防止効果を有する観点から、表面に金属層が積層又は蒸着された樹脂製の包装容器（特に、包装袋）が好ましく、より好ましくは表面にアルミニウム蒸着された樹脂製の包装袋である。 Examples of the packaging container include a bag body (packaging bag) and a box-shaped container. The packaging container is preferably one capable of suppressing volatilization of the composition for skin cosmetics of the present invention. The material of the packaging container is not particularly limited, and examples thereof include resins such as polyethylene terephthalate (PET), polyethylene (PE), and polypropylene (PP); and metals such as aluminum. As the packaging container, a resin packaging container (particularly, a packaging bag) in which a metal layer is laminated or vapor-deposited on the surface is preferable, and aluminum vapor deposition is more preferable on the surface, from the viewpoint of being lightweight and having an excellent anti-volatile effect. It is a packaging bag made of resin.
本発明のシート化粧料は、上記シート基材に本発明の皮膚化粧料用組成物を含浸させることにより製造することができる。シート基材に本発明の皮膚化粧料用組成物を含浸させる方法は、特に限定されず、例えば、折りたたまれた状態のシート基材に本発明の皮膚化粧料用組成物を注入し含浸させる方法、シート基材に本発明の皮膚化粧料用組成物をスプレーする方法、印刷法を用いてシート基材に本発明の皮膚化粧料用組成物を含浸させる方法、本発明の皮膚化粧料用組成物中にシート基材を浸す方法などが挙げられる。 The sheet cosmetic of the present invention can be produced by impregnating the sheet base material with the composition for skin cosmetic of the present invention. The method of impregnating the sheet base material with the composition for skin cosmetics of the present invention is not particularly limited, and for example, a method of injecting the composition for skin cosmetics of the present invention into a folded sheet base material and impregnating the sheet base material. , A method of spraying the composition for skin cosmetics of the present invention on a sheet base material, a method of impregnating a sheet base material with the composition for skin cosmetics of the present invention using a printing method, a composition for skin cosmetics of the present invention. Examples include a method of immersing the sheet base material in an object.
本発明のシート化粧料は、皮膚（肌）を拭くために用いられる。本発明のシート化粧料により拭き取る部位としては、特に限定されず、例えば、顔面（例えば、額、目元、目じり、頬、口元等）や、腕、肘、手の甲、指先、足、膝、かかと、首、脇、背中などが挙げられる。本発明のシート化粧料としては、例えば、シート洗顔料（洗顔シート）、ボディ用拭き取りシート、ウェットティッシュ、使い捨ておしぼり、お尻拭きシート、メイク落としシート（クレンジングシート）などが挙げられる。中でも、本発明のシート化粧料は、使用後の肌に、乾燥した感触が抑制されつつ皮膜が形成されたような感触を付与することができるため、ボディ拭き取り用に特に好ましく用いられる。なお、本発明のシート化粧料は、例えば、化粧品、医薬部外品、医薬品、雑貨のいずれであってもよい。 The sheet cosmetic of the present invention is used for wiping the skin (skin). The part to be wiped off by the sheet cosmetic of the present invention is not particularly limited, and for example, the face (for example, forehead, eyes, eyes, cheeks, mouth, etc.), arms, elbows, back of hands, fingertips, feet, knees, heels, etc. Neck, armpits, back, etc. Examples of the sheet cosmetics of the present invention include sheet facial cleansers (face wash sheets), body wipe sheets, wet tissues, disposable hand towels, buttocks wipe sheets, makeup remover sheets (cleansing sheets), and the like. Among them, the sheet cosmetic of the present invention is particularly preferably used for wiping the body because it can give the skin after use a feeling of forming a film while suppressing a dry feeling. The sheet cosmetics of the present invention may be, for example, cosmetics, quasi-drugs, pharmaceuticals, or miscellaneous goods.
本発明のシート化粧料の使用方法は、特に限定されないが、肌上の汚れ、古い角質や皮脂等を拭き取る方法が挙げられる。本発明のシート化粧料は、肌上を拭いて使用するだけで、汚れ等が拭きとられるだけでなく、使用後の肌に、乾燥した感触が抑制されつつ皮膜が形成されたような感触を付与することができるため、肌上を拭いて使用する拭き取り用シート化粧料とすることが好ましい。 The method of using the sheet cosmetic of the present invention is not particularly limited, and examples thereof include a method of wiping off dirt on the skin, old keratin, sebum and the like. The sheet cosmetic of the present invention not only wipes off dirt and the like by simply wiping the skin, but also gives the skin a feeling of forming a film while suppressing a dry feeling. Since it can be applied, it is preferable to use a wiping sheet cosmetic that is used by wiping the skin.
以下に、実施例に基づいて本発明をより詳細に説明するが、本発明はこれらの実施例にのみ限定されるものではない。なお、表に記載の配合量は、各成分の配合量（すなわち、各原料中の有効成分の配合量。所謂純分）であり、特記しない限り「質量％」で表す。 Hereinafter, the present invention will be described in more detail based on Examples, but the present invention is not limited to these Examples. The blending amount shown in the table is the blending amount of each component (that is, the blending amount of the active ingredient in each raw material, so-called pure content), and is represented by "mass%" unless otherwise specified.
実施例１〜８、比較例１〜５
表に記した各成分（成分（Ａ）〜（Ｄ））を用い、実施例及び比較例の各皮膚化粧料用組成物を常法により調製した。さらに、上記皮膚化粧料用組成物を、目付４０ｇ／ｍ2のスパンレース不織布に、不織布１００質量部に対して化粧料組成物を２９０質量部の割合で含浸させ、実施例及び比較例の各シート化粧料（シートサイズ：１４ｃｍ×２０ｃｍ、長方形）を作製した。Examples 1-8, Comparative Examples 1-5
Using each component (components (A) to (D)) shown in the table, each skin cosmetic composition of Examples and Comparative Examples was prepared by a conventional method. Further, the skin cosmetic composition was impregnated into a spunlace non-woven fabric having a texture of 40 g / m 2 at a ratio of 290 parts by mass with respect to 100 parts by mass of the non-woven fabric, and each of Examples and Comparative Examples. A sheet non-woven fabric (sheet size: 14 cm × 20 cm, rectangular) was prepared.
（評価）
実施例及び比較例で得られた各シート化粧料について以下の通り評価した。評価結果は表に記載した。但し、比較例５は成分（Ｂ）が均一分散しなかったため他の評価を行わなかった。(Evaluation)
Each sheet cosmetic obtained in Examples and Comparative Examples was evaluated as follows. The evaluation results are shown in the table. However, in Comparative Example 5, the component (B) was not uniformly dispersed, so no other evaluation was performed.
（１）サラサラ感
実施例及び比較例で得られた各シート化粧料１枚で、片方の前腕の内側を２０ｃｍ幅で３往復するように拭き取り、１０分後の拭き取り部分について、サラサラ感（粉が肌上に存在することによって、掌との摩擦が小さくなったような感触）を評価した。上記評価は、２５℃、湿度５０％ＲＨの恒温恒湿の条件下で実施した。下記評価基準で判定し、結果を表に記載した。
［サラサラ感の判定基準］
◎（優れる）：サラサラ感を非常に感じる。
○（良好）：サラサラ感をわずかに感じる。
×（不良）：サラサラ感を感じない。(1) Smooth feeling With one sheet of cosmetics obtained in each of the examples and comparative examples, wipe the inside of one forearm with a width of 20 cm so as to make three reciprocations, and after 10 minutes, the wiped part has a smooth feeling (powder). (It feels like the friction with the palm is reduced due to the presence of the powder on the skin) was evaluated. The above evaluation was carried out under constant temperature and humidity conditions of 25 ° C. and 50% humidity RH. Judgment was made according to the following evaluation criteria, and the results are shown in the table.
[Criteria for smooth feeling]
◎ (excellent): I feel very smooth.
○ (Good): I feel a slight feeling of smoothness.
× (bad): I don't feel smooth.
（２）皮膜感
上記サラサラ感の評価と同時に、皮膜感を評価した。下記評価基準で判定し、結果を表に記載した。
［皮膜感の判定基準］
◎（優れる）：皮膜感を非常に感じる。
○（良好）：皮膜感をわずかに感じる。
×（不良）：皮膜感を感じない。(2) Film feeling The film feeling was evaluated at the same time as the evaluation of the smooth feeling. Judgment was made according to the following evaluation criteria, and the results are shown in the table.
[Criteria for film feeling]
◎ (excellent): I feel a film feeling very much.
○ (Good): A slight film feeling is felt.
× (defective): No film feeling is felt.
（３）白浮き
実施例及び比較例で得られた各シート化粧料１枚で、片方の前腕の内側を２０ｃｍ幅で３往復するように拭き取り、１０分後の拭き取り部分について、目視で白浮きを評価した。上記評価は、２５℃、湿度５０％ＲＨの恒温恒湿の条件下で実施した。下記評価基準で判定し、結果を表に記載した。
［白浮きの判定基準］
◎（優れる）：塗布部分に白浮きがない。
○（良好）：塗布部分の一部に白浮きがあるが使用可能。
×（不良）：塗布部分の全体に白浮きが生じる。(3) Whitening With one sheet of cosmetics obtained in Examples and Comparative Examples, wipe the inside of one forearm with a width of 20 cm so that it makes three reciprocations, and visually whiten the wiped part after 10 minutes. Was evaluated. The above evaluation was carried out under constant temperature and humidity conditions of 25 ° C. and 50% humidity RH. Judgment was made according to the following evaluation criteria, and the results are shown in the table.
[Criteria for whitening]
◎ (excellent): There is no whitening on the coated part.
○ (Good): Can be used although there is whitening on a part of the coated part.
X (defective): Whitening occurs on the entire coated portion.
（４）分散性
実施例及び比較例において皮膚化粧料用組成物を作製する際、水とエタノールを混合した溶液に成分（Ａ）及び成分（Ｂ）を投入し、１０分間撹拌したときの粉体の分散性について目視で評価した。下記評価基準で判定し、結果を表に記載した。
［分散性の判定基準］
○（良好）：均一分散する。
×（不良）：均一分散しない。(4) Dispersibility When preparing the composition for skin cosmetics in Examples and Comparative Examples, the powder when the component (A) and the component (B) were added to a solution in which water and ethanol were mixed and stirred for 10 minutes. The dispersibility of the body was visually evaluated. Judgment was made according to the following evaluation criteria, and the results are shown in the table.
[Criteria for dispersibility]
○ (Good): Uniformly dispersed.
× (defective): Not uniformly dispersed.
本発明の皮膚化粧料用組成物を用いたシート化粧料（実施例）は、サラサラ感を有し、且つ皮膜感が得られ乾燥感が抑制された。また、白浮きも抑制されていた。これに対し、成分（Ａ）の含有割合が少ない場合（比較例１）、サラサラ感が得られなかった。成分（Ａ）の含有割合が多い場合（比較例２）、塗布部分全体に白浮きが発生した。成分（Ｂ）の含有割合が少ない場合（比較例３）、皮膜感が得られず乾燥感を抑制することができなかった。成分（Ｂ）の含有割合が多い場合（比較例４）、塗布部分全体に白浮きが発生した。成分（Ｃ）の含有割合が少ない場合（比較例５）、粉体が均一分散しなかった。 The sheet cosmetic (Example) using the composition for skin cosmetics of the present invention had a smooth feeling, a film feeling was obtained, and a dry feeling was suppressed. In addition, whitening was also suppressed. On the other hand, when the content ratio of the component (A) was small (Comparative Example 1), a smooth feeling was not obtained. When the content ratio of the component (A) was large (Comparative Example 2), whitening occurred in the entire coated portion. When the content ratio of the component (B) was small (Comparative Example 3), a film feeling could not be obtained and a dry feeling could not be suppressed. When the content ratio of the component (B) was large (Comparative Example 4), whitening occurred in the entire coated portion. When the content ratio of the component (C) was small (Comparative Example 5), the powder was not uniformly dispersed.
さらに、以下に、本発明の皮膚化粧料用組成物の処方例を示す。 Further, a formulation example of the composition for skin cosmetics of the present invention is shown below.
（処方例１）ボディシート
＜皮膚化粧料用組成物＞
タルク ５．０質量％
オクテニルコハク酸デンプンアルミニウム １０．０質量％
エタノール ３０．０質量％
ＰＰＧ−６デシルテトラデセス−２０ ０．４質量％
水 ５３．２５質量％
メントール ０．７質量％
香料 ０．５質量％
クエン酸 ０．０５質量％
クエン酸Ｎａ ０．１質量％
合計 １００．０質量％
（＊）不織布１００質量部に対して上記皮膚化粧料用組成物を２９０質量部の質量割合で含浸。(Prescription Example 1) Body Sheet <Composition for Skin Cosmetics>
Talc 5.0% by mass
Starch aluminum octenyl succinate 10.0% by mass
Ethanol 30.0% by mass
PPG-6 decyltetradeceth-20 0.4% by mass
Water 53.25% by mass
Menthol 0.7% by mass
Fragrance 0.5% by mass
Citric acid 0.05% by mass
Na citrate 0.1% by mass
Total 100.0% by mass
(*) The composition for skin cosmetics is impregnated in a mass ratio of 290 parts by mass with respect to 100 parts by mass of the non-woven fabric.
（処方例２）デオドラントウォーター
タルク ２．０質量％
オクテニルコハク酸デンプンアルミニウム ２．０質量％
エタノール ５０．０質量％
ＰＰＧ−６デシルテトラデセス−２０ ０．４質量％
水 ４５．１質量％
メントール ０．３質量％
香料 ０．２質量％
合計 １００．０質量％(Prescription example 2) Deodorant water talc 2.0% by mass
Starch aluminum octenyl succinate 2.0% by mass
Ethanol 50.0% by mass
PPG-6 decyltetradeceth-20 0.4% by mass
Water 45.1% by mass
Menthol 0.3% by mass
Fragrance 0.2% by mass
Total 100.0% by mass
Claims (3)
成分（Ａ）：タルク及び／又はシリカ
成分（Ｂ）：オクテニルコハク酸デンプンアルミニウム
成分（Ｃ）：エタノール
成分（Ｄ）：水It contains the following component (A), the following component (B), the following component (C), and the following component (D), and the content ratio of the component (A) is 0.5 to 15.0% by mass. The content ratio of B) is 0.5 to 15.0% by mass, the content ratio of the component (C) is 20.0 to 70.0% by mass, and the content ratio of the component (D) is 10.0 to 75. A composition for skin cosmetics, which is 0% by mass.
Component (A): Talc and / or silica Component (B): Starch aluminum octenyl succinate Component (C): Ethanol Component (D): Water
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
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| JP2018176765 | 2018-09-21 | ||
| JP2018176765 | 2018-09-21 | ||
| PCT/JP2019/004909 WO2020059167A1 (en) | 2018-09-21 | 2019-02-12 | Composition for skin cosmetics |
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| JPWO2020059167A1 true JPWO2020059167A1 (en) | 2021-04-08 |
| JP7139438B2 JP7139438B2 (en) | 2022-09-20 |
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| JP2020547908A Active JP7139438B2 (en) | 2018-09-21 | 2019-02-12 | Skin cosmetic composition |
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| KR (1) | KR20210011986A (en) |
| CN (1) | CN112312878A (en) |
| WO (1) | WO2020059167A1 (en) |
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|---|---|---|---|---|
| KR20220144583A (en) | 2021-04-20 | 2022-10-27 | 주식회사 가나씨앤피 | Cosmetic composition Comprising Butyl Palmitate Compound as Ester Based Oil and Fatty Component, and Uses Thereof |
| CN116059149B (en) * | 2023-04-06 | 2023-08-01 | 广东一芙化妆品有限公司 | Antibacterial sun-proof powder solid block composition with decorative component and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10158138A (en) * | 1996-12-02 | 1998-06-16 | Kanebo Ltd | Aerosol composition |
| JP2002338428A (en) * | 2001-05-14 | 2002-11-27 | Kose Corp | Water-in-oil type cosmetic |
| JP2005239633A (en) * | 2004-02-26 | 2005-09-08 | T Hasegawa Co Ltd | Cosmetic composition |
| JP2016000703A (en) * | 2014-06-11 | 2016-01-07 | 株式会社マンダム | Liquid body odor suppressing agent |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3167300B2 (en) | 1998-04-17 | 2001-05-21 | 花王株式会社 | Sheet cosmetics |
| JP2002201109A (en) | 2000-12-28 | 2002-07-16 | Lion Corp | Sheetlike cosmetic |
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2019
- 2019-02-12 WO PCT/JP2019/004909 patent/WO2020059167A1/en active Application Filing
- 2019-02-12 CN CN201980041688.9A patent/CN112312878A/en active Pending
- 2019-02-12 KR KR1020207036636A patent/KR20210011986A/en unknown
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10158138A (en) * | 1996-12-02 | 1998-06-16 | Kanebo Ltd | Aerosol composition |
| JP2002338428A (en) * | 2001-05-14 | 2002-11-27 | Kose Corp | Water-in-oil type cosmetic |
| JP2005239633A (en) * | 2004-02-26 | 2005-09-08 | T Hasegawa Co Ltd | Cosmetic composition |
| JP2016000703A (en) * | 2014-06-11 | 2016-01-07 | 株式会社マンダム | Liquid body odor suppressing agent |
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| JP7139438B2 (en) | 2022-09-20 |
| KR20210011986A (en) | 2021-02-02 |
| CN112312878A (en) | 2021-02-02 |
| WO2020059167A1 (en) | 2020-03-26 |
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