CN105473120A - Cleansing sheet - Google Patents
Cleansing sheet Download PDFInfo
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- CN105473120A CN105473120A CN201480042903.4A CN201480042903A CN105473120A CN 105473120 A CN105473120 A CN 105473120A CN 201480042903 A CN201480042903 A CN 201480042903A CN 105473120 A CN105473120 A CN 105473120A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0208—Tissues; Wipes; Patches
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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Abstract
Provided is a cleansing sheet in which a cleansing emulsion composition has excellent storage stability despite having a relatively low viscosity, and whereby markedly superior cleansing power can be demonstrated. The cleansing sheet pertaining to the present invention is provided with a sheet substrate and a cleansing emulsion composition, impregnated in the sheet substrate. The cleansing emulsion composition contains a nonionic surfactant, an alkyl acrylate/methacrylate copolymer, and an ointment, the nonionic surfactant being at least one species selected from the group consisting of polyoxyethylene glyceryl diisostearate, polyoxyethylene glyceryl monoisostearate, and polyoxyethylene hydrogenated castor oil, and the viscosity of the cleansing emulsion composition being 1000 mPa*s or less at 25 DEG C.
Description
Technical field
The present invention relates to the Compond fibre table for removing lipstick being impregnated with makeup removing emulsification composition in plate substrate.
Background technology
In order to remove ornaments and formal dress etc., the makeup removing cosmetic preparation employing makeup removing compositions is well-known.In recent years, in order to simply and remove ornaments and formal dress rapidly, the use making makeup removing compositions impregnated in the Compond fibre table for removing lipstick in plate substrate increases.In addition, as above-mentioned makeup removing compositions, there are the fluid composition of not emulsion and emulsification composition etc.
Above-mentioned makeup removing sheet cosmetic preparation is such as disclosed in following patent documentation 1 ~ 5.
Patent Document 1 discloses a kind of O/W emulsion composition that makes impregnated in sheet cosmetic removing material in non-woven fabrics following.Above-mentioned O/W emulsion composition contains: (A) comprises the aqueous phase (this water soluble compound (a) has expoxy propane addition molal quantity and is the polyoxypropylene structure of more than 3 and do not have alkyl and/or the polyoxyethylene structure that carbon number is more than 4) of the water soluble compound (a) of 1 quality % ~ 25 quality %; (B) boiling point comprised under the 1013.25hPa of more than 50 quality % is the oil phase of the oil preparation (b) of 160 DEG C ~ 300 DEG C; (C) there is the AQUO-THICKENING AGENT 0.01 quality % ~ 1 quality % of hydrophobic portion.In above-mentioned O/W emulsion composition, (A) aqueous phase is 97:3 ~ 40:60 with the mass ratio ((A): (B)) of (B) oil phase.
A kind ofly make lo-tionized makeup material impregnated in cosmetic removing material in plate substrate following Patent Document 2 discloses, this lo-tionized makeup material is 200mPas ~ 4000mPas the viscosity of 25 DEG C and is 100mPas ~ 2000mPas the viscosity of 50 DEG C.In addition, in patent documentation 2, as above-mentioned emulsion cosmetic preparation, describe a kind of lo-tionized makeup material comprising oil preparation 10 % by weight ~ 80 % by weight, water 10 % by weight ~ 80 % by weight and surfactant 0.5 % by weight ~ 10 % by weight.
In the embodiment of patent documentation 2, describe a kind of lo-tionized makeup material, its ratio of viscosities is higher, and the viscosity of 25 DEG C is 1100mPas ~ 1500mPas.In addition, describe a kind of lo-tionized makeup material in the comparative example of patent documentation 2, lower, 25 DEG C the viscosity of its ratio of viscosities is 150mPas.But, in patent documentation 2, describe following content: if the viscosity of 25 DEG C is 150mPas, then liquid stability and dipstick bad stability.
Patent Document 3 discloses a kind of sheet cosmetic removing cosmetic preparation following, it makes the viscosity of 25 DEG C be that the emulsion compositions of below 200mPas impregnated in plate substrate.Above-mentioned emulsion compositions comprises (A) phospholipid 0.1 quality % ~ 3 quality %, (B) liquid oil content 0.1 quality % ~ 15 quality %, (C) polyhydric alcohol 1 quality % ~ 25 quality % and (D) water 40 quality % ~ 85 quality %.
In the embodiment of patent documentation 3, describe the lower emulsion compositions of ratio of viscosities, but the stability of this emulsion compositions is not recorded especially.
Patent Document 4 discloses a kind of O/W emulsion composition that makes impregnated in sheet cosmetic removing material in non-woven fabrics following.Above-mentioned O/W emulsion composition comprises AQUO-THICKENING AGENT 0.01 quality % ~ 0.5 quality %, boiling point is 160 DEG C ~ 300 DEG C oil preparation 5 quality % ~ 30 quality % and water.
A kind ofly liquid makeup removing agent compositions is made to impregnated in Compond fibre table for removing lipstick in plate substrate following Patent Document 5 discloses.The above-mentioned liquid state makeup removing agent compositions viscosity comprised as (A) 25 DEG C of oil components is the oil preparation of 1000mPas ~ 50000mPas and the viscosity of (B) 25 DEG C is the oil preparation of below 20mPas.(A) composition in whole oil components is more than 30 quality % with the total content of (B) composition.(A) composition is 1 ~ 5 with the mass ratio ((B)/(A)) of (B) composition.In addition, in patent documentation 5, describe (C) non-ionic surface active agent that above-mentioned liquid state makeup removing agent compositions can comprise 3 quality % ~ 30 quality %.
Prior art document
Patent documentation
Patent documentation 1: Japanese Unexamined Patent Publication 2005-239561 publication
Patent documentation 2: Japanese Unexamined Patent Publication 2001-302450 publication
Patent documentation 3: Japanese Unexamined Patent Publication 2003-183126 publication
Patent documentation 4: Japanese Unexamined Patent Publication 2005-145872 publication
Patent documentation 5: Japanese Unexamined Patent Publication 2006-306780 publication
Summary of the invention
The problem that invention will solve
In order to improve makeup removing effect, in most cases mixture oil preparation in above-mentioned Compond fibre table for removing lipstick.But in order to stably mixture oil preparation and when making above-mentioned cleansing composition be emulsified state, although mixture oil preparation, makeup removing power reduces sometimes.
In addition, if make makeup removing compositions be emulsified state, then the viscosity of makeup removing compositions raises, and exists and is difficult to make makeup removing compositions to impregnated in problem in sheet above base material equably.On the other hand, if reduce the viscosity of makeup removing compositions, then the storage stability of makeup removing compositions significantly reduces sometimes.
As described in patent documentation 1 ~ 5, the known various makeup removing compositionss that impregnated in plate substrate in the past.But existing makeup removing compositions cannot meet following over-all properties: for realizing the low viscosity of uniform dipping, high storage stability and high makeup removing power.
The object of the present invention is to provide a kind of Compond fibre table for removing lipstick, in this Compond fibre table for removing lipstick, although makeup removing emulsification composition is lower the ratio of viscosities of 25 DEG C, but the excellent storage stability of makeup removing emulsification composition, and the ratio of viscosities of makeup removing emulsification composition is lower, therefore, it is possible to make makeup removing emulsification composition impregnated in equably in plate substrate, especially excellent makeup removing power thus can be given play to.
For solving the scheme of problem
Compond fibre table for removing lipstick of the present invention possesses plate substrate and impregnated in the makeup removing emulsification composition in sheet above base material, above-mentioned makeup removing emulsification composition contains nonionic surfactant, acrylic arid methacrylic acid alkyl ester copolymer and oil preparation, above-mentioned nonionic surfactant is be selected from least one in the group that is made up of two isostearic acid polyoxyethylene glycerides, single isostearic acid polyoxyethylene glyceride and polyoxyethylene hydrogenated Oleum Ricini, and above-mentioned makeup removing emulsification composition is below 1000mPas the viscosity of 25 DEG C.
Above-mentioned oil preparation is preferably at least one in hydrocarbon ils and silicone oil.Above-mentioned nonionic surfactant is preferably two isostearic acid polyoxyethylene glycerides.
In above-mentioned makeup removing emulsification composition 100 quality %, preferably, content as the above-mentioned nonionic surfactant of at least one be selected from the group that is made up of two isostearic acid polyoxyethylene glycerides, single isostearic acid polyoxyethylene glyceride and polyoxyethylene hydrogenated Oleum Ricini is more than 0.1 quality %, below 5 quality %, the content of aforesaid propylene acids methacrylic acid alkyl ester copolymer is more than 0.01 quality %, below 0.2 quality %, and the content of above-mentioned oil preparation is more than 1 quality %, below 25 quality %.
Above-mentioned makeup removing emulsification composition is preferably also containing polyhydric alcohol.
The effect of invention
Compond fibre table for removing lipstick of the present invention possesses plate substrate and impregnated in the makeup removing emulsification composition in this plate substrate, and then above-mentioned makeup removing emulsification composition contains nonionic surfactant, acrylic arid methacrylic acid alkyl ester copolymer and oil preparation, above-mentioned nonionic surfactant is for being selected from by two isostearic acid polyoxyethylene glycerides, at least one in the group of single isostearic acid polyoxyethylene glyceride and polyoxyethylene hydrogenated Oleum Ricini composition, above-mentioned makeup removing emulsification composition is below 1000mPas the viscosity of 25 DEG C, therefore, although above-mentioned makeup removing emulsification composition is lower the ratio of viscosities of 25 DEG C, but the storage stability of above-mentioned makeup removing emulsification composition can be improved.In addition, because the ratio of viscosities of above-mentioned makeup removing emulsification composition is lower, above-mentioned makeup removing emulsification composition can be made to impregnated in sheet above base material equably, thus, Compond fibre table for removing lipstick of the present invention can give play to especially excellent makeup removing power.
Detailed description of the invention
Below, the present invention is described in detail.
Compond fibre table for removing lipstick of the present invention possesses plate substrate and impregnated in the makeup removing emulsification composition in this plate substrate.In Compond fibre table for removing lipstick of the present invention, the compositions that impregnated in sheet above base material is emulsification composition.
Compond fibre table for removing lipstick of the present invention contains (A) nonionic surfactant, (B) acrylic arid methacrylic acid alkyl ester copolymer and (C) oil preparation.In Compond fibre table for removing lipstick of the present invention, (A) nonionic surfactant is be selected from least one in the group that is made up of two isostearic acid polyoxyethylene glycerides, single isostearic acid polyoxyethylene glyceride and polyoxyethylene hydrogenated Oleum Ricini.In Compond fibre table for removing lipstick of the present invention, above-mentioned makeup removing emulsification composition is below 1000mPas the viscosity of 25 DEG C.Above-mentioned makeup removing emulsification composition is lower the ratio of viscosities of 25 DEG C.
In the present invention, have employed above-mentioned formation, impregnated in the above-mentioned makeup removing emulsification composition in sheet above base material the viscosity of 25 DEG C is below 1000mPas, thus can make above-mentioned makeup removing emulsification composition easily and impregnated in equably in sheet above base material.Such as, if compositions the viscosity of 25 DEG C more than 1000mPas, then in Compond fibre table for removing lipstick, the pickup of above-mentioned makeup removing compositions easily changes because of the part of sheet above base material.On the other hand, by making above-mentioned makeup removing emulsification composition be below 1000mPas the viscosity of 25 DEG C, in Compond fibre table for removing lipstick, the pickup of above-mentioned makeup removing emulsification composition can be made even in sheet above base material entirety.
In addition, in the present invention, above-mentioned makeup removing emulsification composition has above-mentioned specific composition, thus, although above-mentioned makeup removing emulsification composition is lower the ratio of viscosities of 25 DEG C, can improve the storage stability of above-mentioned makeup removing emulsification composition.Particularly for comprising the composition of (C) oil preparation, (A) nonionic surfactant is be selected from least one in the group that is made up of two isostearic acid polyoxyethylene glycerides, single isostearic acid polyoxyethylene glyceride and polyoxyethylene hydrogenated Oleum Ricini, and this can go far towards the raising of storage stability.
In addition, in the present invention, above-mentioned makeup removing emulsification composition has above-mentioned specific composition, thus can improve makeup removing power.In addition, above-mentioned makeup removing emulsification composition be impregnated in sheet above base material equably to go far towards effectively to improve makeup removing power.
Above-mentioned makeup removing emulsification composition is below 1000mPas the viscosity of 25 DEG C.Above-mentioned makeup removing emulsification composition is preferably below 800mPas the viscosity of 25 DEG C.If above-mentioned viscosity is below the above-mentioned upper limit, then above-mentioned makeup removing compositions can more uniformly impregnated in sheet above base material.The lower limit of above-mentioned viscosity is not particularly limited.Above-mentioned makeup removing emulsification composition is preferably more than 150mPas the viscosity of 25 DEG C, is more preferably more than 200mPas.If above-mentioned viscosity is more than above-mentioned lower limit, then storage stability improves further.
Above-mentioned viscosity measures as follows: utilize viscometer, uses No.2 rotor to measure with rotary speed 30rpm, the rotational time condition of 1 minute at 25 DEG C.As above-mentioned viscometer, the TV-22 type viscometer etc. that Dong Ji industry society manufactures can be used.
Compond fibre table for removing lipstick of the present invention is preferably the Compond fibre table for removing lipstick used as cosmetic preparation, quasi drug or pharmaceuticals.Above-mentioned makeup removing emulsification composition preferably comprises (D) polyhydric alcohol.Above-mentioned makeup removing emulsification composition preferably comprises (E) ethanol.Above-mentioned makeup removing emulsification composition comprises water usually.
Below, spendable each composition and plate substrate in Compond fibre table for removing lipstick of the present invention and above-mentioned makeup removing emulsification composition are described in detail.
((A) nonionic surfactant)
Above-mentioned makeup removing emulsification composition comprises (A) nonionic surfactant, and thus, storage stability becomes quite high, and then makeup removing power also improves effectively.As nonionic surfactant, polyoxyethylene fatty acid, polyoxyethylene alkyl ether, Polyoxyethylene Sorbitan acid esters, polyoxyethylene glycerol fatty acid esters, fatty acid monoglyceride, polyglyceryl fatty acid ester, polyoxyethylene fatty acid amide, sorbitan aliphatic ester, polyoxyethylene sorbitol Cera Flava, polyoxyethylene hydrogenated Oleum Ricini, polyoxyethylene castor oil, Wool wax alcohols,ethoxylated, polyoxyethylene lanolin alcohol, polyoxyethylene sorbitol lanoline and Dimethyl Lauryl Amine oxide etc. can be enumerated.
Among these, in the present invention, as nonionic surfactant, use at least one in polyoxyethylene glycerol fatty acid esters and polyoxyethylene hydrogenated Oleum Ricini.
As the concrete example of above-mentioned polyoxyethylene glycerol fatty acid esters, polyoxyethylene (caprylic/capric) glyceride, polyoxyethylene coconut fatty acid oil glyceride, single oleic acid polyoxyethylene glyceride, single myristic acid polyoxyethylene glyceride, monostearate polyoxyethylene glyceride, single isostearic acid polyoxyethylene glyceride, two isostearic acid polyoxyethylene glycerides and three isostearic acid polyoxyethylene glycerides etc. can be enumerated.
Among these, in the present invention, when using polyoxyethylene glycerol fatty acid esters, employ at least one in single isostearic acid polyoxyethylene glyceride and two isostearic acid polyoxyethylene glycerides.
Therefore, in the present invention, (A) nonionic surfactant is be selected from least one in the group that is made up of two isostearic acid polyoxyethylene glycerides, single isostearic acid polyoxyethylene glyceride and polyoxyethylene hydrogenated Oleum Ricini.(A) nonionic surfactant can only use a kind, also can share two or more.
For above-mentioned makeup removing emulsification composition, as (A) nonionic surfactant, two isostearic acid polyoxyethylene glycerides can be comprised, also can comprise single isostearic acid polyoxyethylene glyceride, can also polyoxyethylene hydrogenated Oleum Ricini be comprised.
From the aspect improving storage stability further, (A) nonionic surfactant is preferably at least one in two isostearic acid polyoxyethylene glycerides and polyoxyethylene hydrogenated Oleum Ricini, is particularly preferably two isostearic acid polyoxyethylene glycerides.
From the aspect improving makeup removing power further, (A) nonionic surfactant is preferably at least one in two isostearic acid polyoxyethylene glycerides and single isostearic acid polyoxyethylene glyceride, is preferably two isostearic acid polyoxyethylene glycerides.
The addition molal quantity of the oxirane in above-mentioned polyoxyethylene glycerol fatty acid esters is not particularly limited, is preferably more than 2, is more preferably more than 4, be preferably less than 100, be more preferably less than 90.If the addition molal quantity of the oxirane in above-mentioned polyoxyethylene glycerol fatty acid esters is that below more than above-mentioned lower limit and the above-mentioned upper limit, then the storage stability of above-mentioned makeup removing emulsification composition becomes better.
As above-mentioned polyoxyethylene glycerol fatty acid esters, commercially available product can be used.5), " RGL-8MISE " (ethyleneoxide addition molal quantity: 8), " RGL-10MISE " (ethyleneoxide addition molal quantity: 10) and " RGL-20MISE " (ethyleneoxide addition molal quantity: 20) as the commercially available product of single isostearic acid polyoxyethylene glyceride, " blaunonRGL-5MISE " (the ethyleneoxide addition molal quantity: of the commercially available product manufactured as Qing Mu oil prodution industry society can be enumerated; 8), " EMALEXGWIS-120 " (ethyleneoxide addition molal quantity: 20) and " EMALEXGWIS-160 " (ethyleneoxide addition molal quantity: 60) etc. and " GWIS-108 " of the commercially available product to manufacture as NIHONEMULSION society (ethyleneoxide addition molal quantity:.10), " EMALEXGWIS-220 " (ethyleneoxide addition molal quantity: 20), " EMALEXGWIS-230 " (ethyleneoxide addition molal quantity: 30)) and " EMALEXGWIS-260 " (ethyleneoxide addition molal quantity: 60) etc. as the commercially available product of two isostearic acid polyoxyethylene glycerides, " GWIS-210 " (the ethyleneoxide addition molal quantity: of the commercially available product manufactured as NIHONEMULSION society can be enumerated.
As above-mentioned polyoxyethylene hydrogenated Oleum Ricini, commercially available product can be used.20), " HC-40 " (ethyleneoxide addition molal quantity: 40) and " HC-100 " (ethyleneoxide addition molal quantity: 100) etc. as the commercially available product of polyoxyethylene hydrogenated Oleum Ricini, such as, " HC-20 " (the ethyleneoxide addition molal quantity: of the commercially available product manufactured as NIHONEMULSION society can be enumerated.
The addition molal quantity of the oxirane in above-mentioned two isostearic acid polyoxyethylene glycerides and single isostearic acid polyoxyethylene glyceride is not particularly limited, is preferably more than 10, be more preferably more than 20, be preferably less than 80, be more preferably less than 60.If the addition molal quantity of the oxirane in above-mentioned two isostearic acid polyoxyethylene glycerides and single isostearic acid polyoxyethylene glyceride is that below more than above-mentioned lower limit and the above-mentioned upper limit, then the storage stability of above-mentioned makeup removing emulsification composition becomes better.
The addition molal quantity of the oxirane in above-mentioned polyoxyethylene hydrogenated Oleum Ricini is not particularly limited, is preferably more than 20, is more preferably more than 30, be preferably less than 100.If the addition molal quantity of the oxirane in above-mentioned polyoxyethylene hydrogenated Oleum Ricini is that below more than above-mentioned lower limit and the above-mentioned upper limit, then the storage stability of above-mentioned makeup removing emulsification composition becomes better.
(A) HLB value of nonionic surfactant is preferably more than 7, is more preferably more than 8, is preferably less than 16, is more preferably less than 15.If HLB value is more than above-mentioned lower limit, then storage stability becomes better.If HLB value is below the above-mentioned upper limit, then power of removing ornaments and formal dress improves further.
In above-mentioned makeup removing emulsification composition 100 quality %, content (total content of two isostearic acid polyoxyethylene glycerides, single isostearic acid polyoxyethylene glyceride and polyoxyethylene hydrogenated Oleum Ricini) as (A) nonionic surfactant of at least one be selected from the group that is made up of two isostearic acid polyoxyethylene glycerides, single isostearic acid polyoxyethylene glyceride and polyoxyethylene hydrogenated Oleum Ricini is preferably more than 0.1 quality %, is more preferably more than 0.3 quality %, is preferably below 5 quality %, is more preferably below 3 quality %.If (A) content of nonionic surfactant is more than above-mentioned lower limit, then power of removing ornaments and formal dress improves further.If (A) content of nonionic surfactant is below the above-mentioned upper limit, then storage stability becomes better, and then easily moderately reduces the viscosity of above-mentioned makeup removing emulsification composition.
In above-mentioned makeup removing emulsification composition 100 quality %, the content of two isostearic acid polyoxyethylene glycerides is preferably more than 0.1 quality %, is more preferably more than 0.3 quality %, is preferably below 5 quality %, is more preferably below 3 quality %.If the content of two isostearic acid polyoxyethylene glycerides is more than above-mentioned lower limit, then power of removing ornaments and formal dress improves further.If the content of two isostearic acid polyoxyethylene glycerides is below the above-mentioned upper limit, then storage stability becomes better, and then easily moderately reduces the viscosity of above-mentioned makeup removing emulsification composition.
((B) acrylic arid methacrylic acid alkyl ester copolymer)
By making above-mentioned makeup removing emulsification composition comprise (B) acrylic arid methacrylic acid alkyl ester copolymer, even if the viscosity of above-mentioned makeup removing emulsification composition is low, also can improve storage stability, and the makeup removing power of above-mentioned Compond fibre table for removing lipstick can be improved.That is, by using (B) acrylic arid methacrylic acid alkyl ester copolymer, high storage stability and high makeup removing power can be taken into account.(B) acrylic arid methacrylic acid alkyl ester copolymer can only use a kind, also can share two or more.
As (B) acrylic arid methacrylic acid alkyl ester copolymer, commercially available product can be used.As the commercially available product of (B) acrylic arid methacrylic acid alkyl ester copolymer, " PEMULENTR-1 ", " PEMULENTR-2 ", " Carbopol1342 ", " Carbopol1382 " and " ETD2020 " etc. of the commercially available product manufactured as LUBRIZOL society can be enumerated.
In above-mentioned makeup removing emulsification composition 100 quality %, (B) content of acrylic arid methacrylic acid alkyl ester copolymer is preferably more than 0.01 quality %, is more preferably more than 0.015 quality %, is preferably below 0.2 quality %, is more preferably below 0.15 quality %.If (B) content of acrylic arid methacrylic acid alkyl ester copolymer is more than above-mentioned lower limit, then storage stability and makeup removing power improve further.If (B) content of acrylic arid methacrylic acid alkyl ester copolymer is below the above-mentioned upper limit, then power of removing ornaments and formal dress becomes better.
((C) oil preparation)
By making above-mentioned makeup removing emulsification composition comprise (C) oil preparation, then can effectively improve makeup removing power.In addition, in the present invention, in order to stably mixture oil preparation, makeup removing compositions is emulsification composition.(C) oil preparation is different from (A) nonionic surfactant, different from (B) acrylic arid methacrylic acid alkyl ester copolymer, also different from (D) polyhydric alcohol.
As (C) oil preparation, hydrocarbon ils, silicone oil, oils and fats, higher fatty acids, fatty acid ester and higher alcohol etc. can be enumerated.(C) oil preparation can only use a kind, also can share two or more.
As above-mentioned hydrocarbon ils, such as, can enumerate light isoparaffins, light liquid isoparaffin, synthesis squalane, vegetalitas squalane, squalane, ceresine, paraffin, liquid paraffin, liquid isoparaffin, microwax, polyethylene powders, Tissuemat E and vaseline etc.Above-mentioned hydrocarbon ils can only use a kind, also can share two or more.
From the aspect effectively improving makeup removing power, above-mentioned hydrocarbon ils is preferably selected from least one in the group be made up of light isoparaffins, light liquid isoparaffin, liquid paraffin and liquid isoparaffin.
Above-mentioned silicone oil can be ordinary silicon ketone (straightsilicone), also can be modified silicone, can also be cyclic silicone.As above-mentioned common silicone, such as, can enumerate octamethyltrisiloxane, tetradecamethylhexasiloxane, methyl polysiloxane, high polymeric MAO polysiloxanes, methyl phenyl silicone and methylhydrogenpolysi,oxane etc.As above-mentioned modified silicone, such as, can enumerate alcohol modified silicone, alkyl-modified silicone, amino modified silicone, polyether modified silicone and epoxide modified silicone etc.As above-mentioned cyclic silicone, such as, can enumerate octamethylpolysiloxane, octamethylcy-clotetrasiloxane, decamethylcyclopentaandoxane and ten diformazan basic ring six siloxanes etc.Above-mentioned silicone oil can only use a kind, also can share two or more.
From the aspect effectively improving makeup removing power, above-mentioned silicone oil is preferably cyclic silicone.
As above-mentioned oils and fats, such as, can enumerate Oleum Helianthi, Oleum Gossypii semen, soybean oil, olive oil, Oleum Cocois, Oleum Ricini, Jojoba oil, Flos Camelliae Japonicae caul-fat and ermine wet goods.Above-mentioned oils and fats can only use a kind, also can share two or more.
As above-mentioned higher fatty acids, such as, can enumerate lauric acid, myristic acid, Palmic acid, stearic acid, oleic acid, behenic acid, 9-undecylenic acid, lanoceric acid and isostearic acid etc.Above-mentioned higher fatty acids can only use a kind, also can share two or more.
As above-mentioned fatty acid ester, such as ethyl oleate can be enumerated, isopropyl myristate, isopropyl palmitate, myristyl myristate, cetyl palmitate, oleic acid oleic alcohol ester, myristic acid octyldodecyl, octyldodecyl oleate, isostearic acid ethyl ester, IPIS, 2 ethyl hexanoic acid cetyl ester, 2 ethyl hexanoic acid cetearyl alcohol ester, sad isocetyl ester, sad different stearyl ester, IPIS, isostearic acid isocetyl ester, isostearic acid octyldodecyl, dimethyl-octa acid octyldodecyl, two oleic acid glycol esters, two sad propylene glycol esters, didecyl acid propylene glycol ester, two (caprylic/capric) propylene glycol ester, isostearic acid propylene glycol ester, two capric acid DOPCP, three 2 ethyl hexanoic acid glyceride, three different tripalmitins and four 2 ethyl hexanoic acid pentaerythritol esters etc.Above-mentioned fatty acid ester can only use a kind, also can share two or more.
As above-mentioned higher alcohol, such as, can enumerate lauryl alcohol, myristyl alcohol, hexadecanol, stearyl alcohol, oleyl alcohol, lanolin alcohol, tadenan, cetearyl alcohol, octyl decanol and decyl tetradecyl alcohol etc.Above-mentioned higher alcohol can only use a kind, also can share two or more.
From suppressing the stimulation of skin, improving the aspect of makeup removing power further, (C) oil preparation is preferably at least one in hydrocarbon ils and silicone oil, is preferably hydrocarbon ils and silicone oil.Therefore, above-mentioned makeup removing emulsification composition is preferably containing hydrocarbon ils and silicone oil.
In above-mentioned makeup removing emulsification composition 100 quality %, the content of (C) oil preparation is preferably more than 1 quality %, is more preferably more than 3 quality %, is preferably below 25 quality %, is more preferably below 20 quality %.If (C) content of oil preparation is more than above-mentioned lower limit, then power of removing ornaments and formal dress improves further.If (C) content of oil preparation is below the above-mentioned upper limit, then storage stability becomes better.
In above-mentioned makeup removing emulsification composition 100 quality %, the total content of hydrocarbon ils and silicone oil is preferably more than 1 quality %, is more preferably more than 3 quality %, is preferably below 25 quality %, is more preferably below 20 quality %.In above-mentioned makeup removing emulsification composition 100 quality %, the content of hydrocarbon ils is preferably more than 0.5 quality %, is more preferably more than 1.5 quality %, is preferably below 20 quality %, is more preferably below 15 quality %.In above-mentioned makeup removing emulsification composition 100 quality %, the content of silicone oil is preferably more than 0.5 quality %, is more preferably more than 1.5 quality %, is preferably below 20 quality %, is more preferably below 15 quality %.If the content of the total content of hydrocarbon ils and silicone oil, the content of hydrocarbon ils and silicone oil is respectively more than above-mentioned lower limit, then power of removing ornaments and formal dress improves further.If the content of the total content of hydrocarbon ils and silicone oil, the content of hydrocarbon ils and silicone oil is respectively below the above-mentioned upper limit, then storage stability becomes better.
((D) polyhydric alcohol)
By making above-mentioned makeup removing emulsification composition comprise (D) polyhydric alcohol, then can obtain the effect relaxing skin irritation.
As (D) polyhydric alcohol, such as can enumerate ethylene glycol, diethylene glycol, Polyethylene Glycol, propylene glycol, dipropylene glycol, polypropylene glycol, glycerol, diglycerol, polyglycereol, 1,3-butanediol, isoprene, Sorbitol, maltose alcohol, mannitol, glucol, 1,2-butanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-heptandiol, 1,2-ethohexadiol, 1,2-nonanediol and 1,2-decanediol etc.(D) polyhydric alcohol can only use a kind, also can use two or more.
In above-mentioned makeup removing emulsification composition 100 quality %, (D) content of polyhydric alcohol is preferably more than 0 quality % (also comprise and not using), is more preferably more than 0.5 quality %, is preferably below 25 quality %, is more preferably below 20 quality %.If (D) content of polyhydric alcohol is more than above-mentioned lower limit, then skin irritation is relaxed further.If (D) content of polyhydric alcohol is below the above-mentioned upper limit, then the salubrious sense after makeup removing becomes better.
((E) ethanol)
Above-mentioned makeup removing emulsification composition preferably comprises (E) ethanol.By making above-mentioned makeup removing emulsification composition comprise (E) ethanol, antiseptic effect improves effectively.
From the aspect improving antiseptic effect further, how better the content of (E) ethanol is.On the other hand, from suppressing skin irritant aspect further, the content of (E) ethanol is better less.Particularly, for Compond fibre table for removing lipstick, skin irritation becomes large problem sometimes in use.
In above-mentioned makeup removing emulsification composition 100 quality %, the content of (E) ethanol is preferably more than 0 quality % (also comprise and not using), is more preferably more than 2 quality %, is preferably below 10 quality %, is more preferably below 8 quality %.If (E) content of ethanol is more than above-mentioned lower limit, then antiseptic effect becomes better.If (E) content of ethanol is below the above-mentioned upper limit, then skin irritation is suppressed further.
(water)
The remaining part of above-mentioned makeup removing emulsification composition employs water.Water is preferably normally used water in cosmetic preparation.Water is not particularly limited, pure water, tap water and ion exchange water etc. can be enumerated.Water is preferably pure water.
(other composition)
In the scope not hindering effect of the present invention, above-mentioned makeup removing emulsification composition can comprise other compositions such as amphoteric surfactant, cationic surface active agent, anionic surfactant, antiseptic, freshener, antioxidant, metal-chelator, vitamins, animals and plants extract, pearling agent and coloring agent.These other compositions can only use a kind, also can use two or more.
As above-mentioned amphoteric surfactant, amino acid type amphoteric surface active agent and betaine type amphoteric surfac-tant etc. can be enumerated.As above-mentioned amino acid type amphoteric surface active agent, glycine type amphoterics and aminopropan acid type amphoteric surfactant etc. can be enumerated.As above-mentioned betaine type amphoteric surfac-tant, oxyneurine type amphoteric surfactant and sulfobetaine type amphoteric surfactant etc. can be enumerated.
As above-mentioned cationic surface active agent, alkylamine salt and fatty acid amide amine etc. can be enumerated.As abovementioned alkyl amine salt, lauryl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride and VARISOFT TA100 etc. can be enumerated.As above-mentioned fatty acid amide amine, myristic acid dimethyl aminoethyl amide and stearic acid diethyl amino propyl amide etc. can be enumerated.
As above-mentioned anionic surfactant, alkyl sulfate salt, polyoxyethylene alkyl ether sulfate salt, alpha-alkene sulfonate, N-acyl methyl taurine salt, sulfosuccinic dialkylaminobenzoic acid salt, the polyxyethylated salt of 2-Sulfosuccinic acid, alkylphosphonate, polyoxyethylene alkyl ether phosphate ester salt, N-acyl sarcosinates, N-acyl-N-methyl-Beta-alanine salt, N-acyl glutamate, N-acylglycine salt and alkyl ether glycol acetate etc. can be enumerated.
As foregoing preservatives, p-Hydroxybenzoate (methyl parahydroxybenzoate), phenyl phenol, sodium benzoate, potassium sorbate and polyaminopropyl biguanide etc. can be enumerated.
(plate substrate)
About the material of sheet above base material, be just not particularly limited as long as above-mentioned makeup removing emulsification composition can be flooded.Can suitably use the plate substrate being typically used as cosmetics.
As sheet above base material, can enumerate by weaving cotton cloth of forming of natural fiber, synthetic fibers or half-natural fiber or non-woven fabrics etc.From making the immersion and better aspect of use sense, sheet above base material is preferably non-woven fabrics.
As above-mentioned natural fiber, cotton, paper pulp, silk, cellulose, fiber crops, cotton linter and kapok etc. can be enumerated.As above-mentioned synthetic fibers, nylon, polyester fiber, polyacrylic fibre, polypropylene fibre, polyethylene fiber peacekeeping pet fiber etc. can be enumerated.As above-mentioned half-natural fiber, artificial silk and acetate etc. can be enumerated.Above-mentioned fiber can only use a kind, also can use two or more.
Embossing processing can be carried out in the surface of sheet above base material.In addition, in sheet above base material, film base material is comprised.
The method that above-mentioned makeup removing emulsification composition be impregnated in sheet above base material is not particularly limited, known method can be adopted.
About the amount of the above-mentioned makeup removing emulsification composition that impregnated in sheet above base material, relative to plate substrate 1 mass parts, be preferably more than 1 mass parts, be more preferably more than 3 mass parts, be preferably below 7 mass parts, be more preferably below 6 mass parts.If the pickup of above-mentioned makeup removing emulsification composition is more than above-mentioned lower limit, then power of removing ornaments and formal dress improves further.If the pickup of above-mentioned makeup removing emulsification composition is below the above-mentioned upper limit, then above-mentioned makeup removing emulsification composition impregnated in sheet above base material better, can maintain impregnation state better.
Embodiment
Below, embodiment is enumerated and comparative example is specifically described the present invention.The present invention is not only defined in following embodiment.
Following compositions is employed in embodiment and comparative example.
((A) nonionic surfactant)
(NIHONEMULSION society manufactures " EMALEXGWIS-220 ", ethyleneoxide addition molal quantity to two isostearic acid polyoxyethylene glycerides: 20)
(NIHONEMULSION society manufactures " EMALEXGWIS-230 ", ethyleneoxide addition molal quantity to two isostearic acid polyoxyethylene glycerides: 30)
(NIHONEMULSION society manufactures " EMALEXGWIS-260 ", ethyleneoxide addition molal quantity to two isostearic acid polyoxyethylene glycerides: 60)
(NIHONEMULSION society manufactures " EMALEXGWIS-120 ", ethyleneoxide addition molal quantity to single isostearic acid polyoxyethylene glyceride: 20)
(NIHONEMULSION society manufactures " EMALEXGWIS-160 ", ethyleneoxide addition molal quantity to single isostearic acid polyoxyethylene glyceride: 60)
(NIHONEMULSION society manufactures " HC-40 ", ethyleneoxide addition molal quantity to polyoxyethylene hydrogenated Oleum Ricini: 40)
(NIHONEMULSION society manufactures " HC-100 ", ethyleneoxide addition molal quantity to polyoxyethylene hydrogenated Oleum Ricini: 100)
((A) ' other nonionic surfactant)
(NIHONEMULSION society manufactures " EMALEXGWIS-320 ", ethyleneoxide addition molal quantity to three isostearic acid polyoxyethylene glyceryl: 20)
(NIHONEMULSION society manufactures " EMALEXGWIS-108 ", ethyleneoxide addition molal quantity to isostearic acid polyoxyethylene glycol ester: 8)
((B) acrylic arid methacrylic acid alkyl ester copolymer)
Acrylic arid methacrylic acid alkyl ester copolymer (LUBRIZOL society manufactures " PEMULENTR-2 ")
(with (B) ' similar other composition of acrylic arid methacrylic acid alkyl ester copolymer)
CVP Carbopol ETD2050 (LUBRIZOL society manufactures " Carbopol981 ")
(C) oil preparation
Hydrocarbon ils:
Liquid isoparaffin (You society manufactures " ParleamEX ")
Silicone oil:
Decamethylcyclopentaandoxane (chemical industry society of SHIN-ETSU HANTOTAI manufactures " KF-955 ")
((D) polyhydric alcohol)
Concentrated glycerin (this pharmaceutical industries of slope society manufactures " cosmetic concentrated glycerin ")
((E) ethanol)
Ethanol (JapanAlcoholTrading society manufactures " 95 ° of synthols ")
(other composition)
Antiseptic:
Methyl parahydroxybenzoate (u'eno pharmacy society manufactures " メ ッ キ Application ス M ")
Phenyl phenol (Yokkaichi synthesis society manufactures " phenyl phenol-S ")
Nertralizer:
Potassium hydroxide
Water:
Pure water
(embodiment 1 ~ 12 and comparative example 1 ~ 5)
The following table 1 of mixture, the compounding ingredients (mixture unit is quality %) shown in 2, be prepared according to conventional methods, obtain makeup removing emulsification composition thus.
As plate substrate, prepare the non-woven fabrics of paper pulp/artificial silk (three Zhao Zhi industry societies manufacture " KP9340 ").Make sheet above base material flood above-mentioned makeup removing emulsification composition, obtain Compond fibre table for removing lipstick (sheet cosmetic preparation).It should be noted that, relative to plate substrate 1 mass parts, flood above-mentioned makeup removing emulsification composition 5 mass parts.
(test example 1: viscosimetric analysis)
The viscosity of the emulsification composition obtained measures as follows: utilize the TV-22 type viscometer that Dong Ji industry society manufactures, and uses No.2 rotor to measure with rotary speed 30rpm, the rotational time condition of 1 minute at 25 DEG C.
(test example 2: storage stability)
Obtained emulsification composition was preserved for 1 week in the thermostatic constant wet chamber of 25 DEG C and 40 DEG C.According to the state of emulsification composition after preserving, the storage stability according to following benchmark evaluation.
The metewand > of < storage stability
Zero (well): evenly
△ (insufficient): confirm slightly uneven state
× (bad): confirm clear and definite separation
(test example 3: the evaluation of makeup removing power)
Use the Compond fibre table for removing lipstick obtained to carry out the wiping removing of cosmetics by 20 women specialty judging panels made up, the makeup removing power based on following benchmark evaluation.
The metewand > of < makeup removing power
00 (fairly good): in 20, more than 16 answer makeup removing power are high
Zero (well): in 20,11 ~ 15 answer makeup removing power are high
△ (insufficient): in 20,6 ~ 10 answer makeup removing power are high
× (bad): in 20, less than 5 answer makeup removing power are high
(test example 4: the evaluation of stimulation)
When the makeup removing of test example 3, whether the stimulation stimulation that is whether strong and skin evaluating eye is strong.In addition, after the makeup removing of test example 3, whether the stimulation of evaluating skin is strong.
The metewand > that < stimulates
00 (fairly good): the stimulation that in 20, more than 16 are answered the stimulation of eye and the stimulation of skin and makeup removing rear skin when removing ornaments and formal dress is all not strong
Zero (well): the stimulation that in 20,11 ~ 15 are answered the stimulation of eye and the stimulation of skin and makeup removing rear skin when removing ornaments and formal dress is all not strong
△ (insufficient): the stimulation that in 20,6 ~ 10 are answered the stimulation of eye and the stimulation of skin and makeup removing rear skin when removing ornaments and formal dress is all not strong
× (bad): the stimulation that in 20, less than 5 are answered the stimulation of eye and the stimulation of skin and makeup removing rear skin when removing ornaments and formal dress is all not strong
Composition and result are shown in following table 1,2.
Claims (5)
1. a Compond fibre table for removing lipstick, it possesses plate substrate and impregnated in the makeup removing emulsification composition in described plate substrate,
Described makeup removing emulsification composition contains nonionic surfactant, acrylic arid methacrylic acid alkyl ester copolymer and oil preparation,
Described nonionic surfactant is be selected from least one in the group that is made up of two isostearic acid polyoxyethylene glycerides, single isostearic acid polyoxyethylene glyceride and polyoxyethylene hydrogenated Oleum Ricini,
Described makeup removing emulsification composition is below 1000mPas the viscosity of 25 DEG C.
2. Compond fibre table for removing lipstick as claimed in claim 1, wherein, described oil preparation is at least one in hydrocarbon ils and silicone oil.
3. Compond fibre table for removing lipstick as claimed in claim 1 or 2, wherein, described nonionic surfactant is two isostearic acid polyoxyethylene glycerides.
4. the Compond fibre table for removing lipstick according to any one of claims 1 to 3, wherein, in described makeup removing emulsification composition 100 quality %, as being selected from by two isostearic acid polyoxyethylene glycerides, the content of the described nonionic surfactant of at least one in the group of single isostearic acid polyoxyethylene glyceride and polyoxyethylene hydrogenated Oleum Ricini composition is more than 0.1 quality %, below 5 quality %, the content of described acrylic arid methacrylic acid alkyl ester copolymer is more than 0.01 quality %, below 0.2 quality %, the content of described oil preparation is more than 1 quality %, below 25 quality %.
5. the Compond fibre table for removing lipstick according to any one of Claims 1 to 4, wherein, described makeup removing emulsification composition is also containing polyhydric alcohol.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
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| JP2014-010601 | 2014-01-23 | ||
| JP2014010601 | 2014-01-23 | ||
| PCT/JP2014/075075 WO2015111249A1 (en) | 2014-01-23 | 2014-09-22 | Cleansing sheet |
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| CN201480042903.4A Active CN105473120B (en) | 2014-01-23 | 2014-09-22 | Compond fibre table for removing lipstick |
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| JP (1) | JP6125671B2 (en) |
| KR (1) | KR101786449B1 (en) |
| CN (1) | CN105473120B (en) |
| WO (1) | WO2015111249A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111939102A (en) * | 2019-05-16 | 2020-11-17 | 株式会社漫丹 | Emulsified makeup-removing cosmetic |
| CN116419745A (en) * | 2021-06-07 | 2023-07-11 | 花王株式会社 | Sheet-like cosmetic |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| KR102517441B1 (en) * | 2015-11-18 | 2023-03-31 | 주식회사 엘지생활건강 | Liquid detergent composition having excellent cleansing effect to be packed into foamer containers |
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| JP2006306780A (en) * | 2005-04-28 | 2006-11-09 | Kao Corp | Liquid cleansing agent composition |
| JP4901464B2 (en) * | 2006-12-28 | 2012-03-21 | 高級アルコール工業株式会社 | Diester and cleansing cosmetic containing the same |
| JP2011173862A (en) * | 2010-02-01 | 2011-09-08 | Lion Corp | Skin cleanser composition |
| JP5714833B2 (en) * | 2010-03-31 | 2015-05-07 | 株式会社ナリス化粧品 | Cleansing cream |
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2014
- 2014-09-22 KR KR1020167002524A patent/KR101786449B1/en active IP Right Grant
- 2014-09-22 JP JP2015558728A patent/JP6125671B2/en active Active
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| JPH0892032A (en) * | 1994-09-19 | 1996-04-09 | Shiseido Co Ltd | Skin detergent |
| JP2001002528A (en) * | 1999-06-16 | 2001-01-09 | Pola Chem Ind Inc | Cleansing sheet for wiping |
| JP2005343943A (en) * | 2004-06-01 | 2005-12-15 | Shiseido Co Ltd | Oil-in-water type detergent composition and sheet-like detergent |
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| CN116419745A (en) * | 2021-06-07 | 2023-07-11 | 花王株式会社 | Sheet-like cosmetic |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105473120B (en) | 2018-02-02 |
| KR20160027094A (en) | 2016-03-09 |
| WO2015111249A1 (en) | 2015-07-30 |
| JP6125671B2 (en) | 2017-05-10 |
| JPWO2015111249A1 (en) | 2017-03-23 |
| KR101786449B1 (en) | 2017-10-18 |
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