CN1297607C - 硅橡胶组合物 - Google Patents
硅橡胶组合物 Download PDFInfo
- Publication number
- CN1297607C CN1297607C CNB2004100896487A CN200410089648A CN1297607C CN 1297607 C CN1297607 C CN 1297607C CN B2004100896487 A CNB2004100896487 A CN B2004100896487A CN 200410089648 A CN200410089648 A CN 200410089648A CN 1297607 C CN1297607 C CN 1297607C
- Authority
- CN
- China
- Prior art keywords
- composition
- mass parts
- organohydrogensiloxanes
- poly
- mass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 72
- 229920002379 silicone rubber Polymers 0.000 title abstract description 39
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 56
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 26
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 12
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 10
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 7
- 150000001282 organosilanes Chemical class 0.000 claims abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- 229920001971 elastomer Polymers 0.000 claims description 15
- 239000005060 rubber Substances 0.000 claims description 15
- 238000006459 hydrosilylation reaction Methods 0.000 claims description 6
- 150000001336 alkenes Chemical class 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 3
- 239000000725 suspension Substances 0.000 claims 1
- 239000004945 silicone rubber Substances 0.000 abstract description 37
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 2
- 239000004848 polyfunctional curative Substances 0.000 abstract 1
- 238000001723 curing Methods 0.000 description 18
- 238000000034 method Methods 0.000 description 16
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 14
- 230000015556 catabolic process Effects 0.000 description 13
- 238000006731 degradation reaction Methods 0.000 description 13
- 239000004033 plastic Substances 0.000 description 13
- 229920003023 plastic Polymers 0.000 description 13
- -1 β-phenylpropyl Chemical group 0.000 description 11
- 150000002430 hydrocarbons Chemical group 0.000 description 9
- 238000006116 polymerization reaction Methods 0.000 description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 8
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 8
- 239000003054 catalyst Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 238000013329 compounding Methods 0.000 description 6
- 150000001451 organic peroxides Chemical class 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- 229920002554 vinyl polymer Polymers 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 125000003342 alkenyl group Chemical group 0.000 description 5
- 239000000945 filler Substances 0.000 description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 125000005375 organosiloxane group Chemical group 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- 230000003014 reinforcing effect Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000004073 vulcanization Methods 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000007900 aqueous suspension Substances 0.000 description 3
- 229920005601 base polymer Polymers 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 239000012763 reinforcing filler Substances 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 125000000725 trifluoropropyl group Chemical group [H]C([H])(*)C([H])([H])C(F)(F)F 0.000 description 3
- FFHGJCBXRQUCED-UHFFFAOYSA-N 1-methyl-2-(2-methylphenyl)peroxybenzene Chemical compound CC1=CC=CC=C1OOC1=CC=CC=C1C FFHGJCBXRQUCED-UHFFFAOYSA-N 0.000 description 2
- ZHJVTEQTDADLKP-UHFFFAOYSA-N 1-methyl-4-(4-methylphenyl)peroxybenzene Chemical compound C1=CC(C)=CC=C1OOC1=CC=C(C)C=C1 ZHJVTEQTDADLKP-UHFFFAOYSA-N 0.000 description 2
- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 description 2
- 239000004342 Benzoyl peroxide Substances 0.000 description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000000370 acceptor Substances 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- 125000004369 butenyl group Chemical group C(=CCC)* 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 2
- 125000004093 cyano group Chemical group *C#N 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 125000006038 hexenyl group Chemical group 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000006068 polycondensation reaction Methods 0.000 description 2
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 125000003944 tolyl group Chemical group 0.000 description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
- QEQBMZQFDDDTPN-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy benzenecarboperoxoate Chemical compound CC(C)(C)OOOC(=O)C1=CC=CC=C1 QEQBMZQFDDDTPN-UHFFFAOYSA-N 0.000 description 1
- KNCZPLRYWQLPQT-UHFFFAOYSA-N 1-tert-butyl-2-propan-2-ylbenzene Chemical compound CC(C)C1=CC=CC=C1C(C)(C)C KNCZPLRYWQLPQT-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 239000005046 Chlorosilane Substances 0.000 description 1
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical group C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000019241 carbon black Nutrition 0.000 description 1
- 239000006231 channel black Substances 0.000 description 1
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical compound Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 229910002026 crystalline silica Inorganic materials 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000006232 furnace black Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000012454 non-polar solvent Substances 0.000 description 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 1
- 150000003058 platinum compounds Chemical class 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003284 rhodium compounds Chemical class 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/006—Additives being defined by their surface area
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003381963A JP4395355B2 (ja) | 2003-11-12 | 2003-11-12 | シリコ−ンゴム組成物 |
| JP381963/03 | 2003-11-12 | ||
| JP381963/2003 | 2003-11-12 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1621447A CN1621447A (zh) | 2005-06-01 |
| CN1297607C true CN1297607C (zh) | 2007-01-31 |
Family
ID=34691155
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100896487A Expired - Fee Related CN1297607C (zh) | 2003-11-12 | 2004-10-29 | 硅橡胶组合物 |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP4395355B2 (enExample) |
| KR (1) | KR101099174B1 (enExample) |
| CN (1) | CN1297607C (enExample) |
| TW (1) | TW200517443A (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI412506B (zh) * | 2006-05-12 | 2013-10-21 | 電氣化學工業股份有限公司 | 陶瓷粉末及其用途 |
| KR101379392B1 (ko) * | 2012-07-06 | 2014-04-01 | 주식회사 이라이콤 | 디스플레이 작업용 실리콘 고무 밴드 조성물 및 그 제조방법 |
| CN107050650A (zh) * | 2017-05-18 | 2017-08-18 | 北京博然基业健康科技有限公司 | 一种新型磁疗器 |
| JP2022085603A (ja) * | 2020-11-27 | 2022-06-08 | 信越化学工業株式会社 | ミラブル型シリコーンゴム組成物及びシリコーンゴム硬化物 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH061878A (ja) * | 1992-06-22 | 1994-01-11 | Nippon Shirika Kogyo Kk | シリコーンゴム充填剤用含水珪酸 |
| US6339124B1 (en) * | 1999-06-10 | 2002-01-15 | Shin-Etsu Chemical Co., Ltd. | Silicone rubber compositions |
| JP2003221507A (ja) * | 2002-01-30 | 2003-08-08 | Shin Etsu Chem Co Ltd | 加熱硬化性シリコーンゴム組成物 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3611025B2 (ja) * | 1999-06-10 | 2005-01-19 | 信越化学工業株式会社 | シリコーンゴム組成物 |
-
2003
- 2003-11-12 JP JP2003381963A patent/JP4395355B2/ja not_active Expired - Fee Related
-
2004
- 2004-10-29 CN CNB2004100896487A patent/CN1297607C/zh not_active Expired - Fee Related
- 2004-11-11 TW TW093134508A patent/TW200517443A/zh not_active IP Right Cessation
- 2004-11-11 KR KR1020040091729A patent/KR101099174B1/ko not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH061878A (ja) * | 1992-06-22 | 1994-01-11 | Nippon Shirika Kogyo Kk | シリコーンゴム充填剤用含水珪酸 |
| US6339124B1 (en) * | 1999-06-10 | 2002-01-15 | Shin-Etsu Chemical Co., Ltd. | Silicone rubber compositions |
| JP2003221507A (ja) * | 2002-01-30 | 2003-08-08 | Shin Etsu Chem Co Ltd | 加熱硬化性シリコーンゴム組成物 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2005146029A (ja) | 2005-06-09 |
| TWI356838B (enExample) | 2012-01-21 |
| KR20050045904A (ko) | 2005-05-17 |
| CN1621447A (zh) | 2005-06-01 |
| TW200517443A (en) | 2005-06-01 |
| JP4395355B2 (ja) | 2010-01-06 |
| KR101099174B1 (ko) | 2011-12-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1446249A (zh) | 从尼龙树脂形成的热塑性硅氧烷弹性体 | |
| JP2004262972A (ja) | 熱伝導性シリコーン組成物 | |
| CN1571820A (zh) | 来自增容聚酯树脂的热塑性硅氧烷弹性体 | |
| US5424352A (en) | Heat-conductive silicone rubber composition | |
| JP4781276B2 (ja) | カオリン含有シリコーンゴム組成物の製造方法 | |
| CN103351628B (zh) | 一种高模量低温阻尼硅树脂组合物及其制备方法 | |
| US20110184112A1 (en) | Silicone rubber compositions | |
| JP5343912B2 (ja) | シリコーンゴム組成物及びその製造方法 | |
| JP2000248183A (ja) | シリコーンゴム組成物 | |
| CN1752146A (zh) | 以有机硅化合物为主要成分的可交联组合物 | |
| US20110172340A1 (en) | Silicone rubber compositions | |
| CN1297607C (zh) | 硅橡胶组合物 | |
| JPH04100861A (ja) | 硬化性シリコーンゴム組成物及び硬化物 | |
| JP4520159B2 (ja) | シリコーンゴム組成物 | |
| JP4704987B2 (ja) | 押出成型用シリコ−ンゴム組成物 | |
| JP3482834B2 (ja) | シリコーンゴムの製造方法 | |
| CN1506406A (zh) | 硅橡胶组合物 | |
| JP3919011B2 (ja) | 熱硬化性シリコーンゴム組成物 | |
| JPH09143370A (ja) | シリコーンゴム組成物 | |
| JP3611025B2 (ja) | シリコーンゴム組成物 | |
| JP2021038352A (ja) | ミラブル型シリコーンゴム組成物及びその硬化物 | |
| JP7564055B2 (ja) | フロロシリコーンゴム組成物及び硬化成型物 | |
| JP4548559B2 (ja) | オイルブリード性シリコーンゴムの成型方法及びオイルブリード性シリコーンゴム組成物 | |
| JP4528392B2 (ja) | シリコーンゴム組成物およびその製造方法 | |
| JP2008120969A (ja) | シリコーンゴム組成物及び定着部材 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20070131 Termination date: 20201029 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |