CN1265604A - 用于气态废物脱硫的方法 - Google Patents
用于气态废物脱硫的方法 Download PDFInfo
- Publication number
- CN1265604A CN1265604A CN98807855A CN98807855A CN1265604A CN 1265604 A CN1265604 A CN 1265604A CN 98807855 A CN98807855 A CN 98807855A CN 98807855 A CN98807855 A CN 98807855A CN 1265604 A CN1265604 A CN 1265604A
- Authority
- CN
- China
- Prior art keywords
- gas
- volume
- hydrogen sulfide
- sulphur
- sulfur
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000007789 gas Substances 0.000 title claims abstract description 118
- 238000000034 method Methods 0.000 title claims abstract description 71
- 230000003009 desulfurizing effect Effects 0.000 title description 4
- 238000010521 absorption reaction Methods 0.000 claims abstract description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000000243 solution Substances 0.000 claims abstract description 32
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 17
- 230000003647 oxidation Effects 0.000 claims abstract description 15
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims abstract description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 90
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 76
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 62
- 229910052717 sulfur Inorganic materials 0.000 claims description 50
- 239000011593 sulfur Substances 0.000 claims description 47
- 239000005864 Sulphur Substances 0.000 claims description 43
- 238000006243 chemical reaction Methods 0.000 claims description 25
- 238000005984 hydrogenation reaction Methods 0.000 claims description 21
- 239000007788 liquid Substances 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims description 2
- 239000012670 alkaline solution Substances 0.000 abstract description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 47
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 42
- 229910052739 hydrogen Inorganic materials 0.000 description 42
- 241000196324 Embryophyta Species 0.000 description 32
- 238000011084 recovery Methods 0.000 description 24
- 235000010269 sulphur dioxide Nutrition 0.000 description 21
- 229910002091 carbon monoxide Inorganic materials 0.000 description 16
- 239000001257 hydrogen Substances 0.000 description 14
- 238000009833 condensation Methods 0.000 description 13
- 230000005494 condensation Effects 0.000 description 13
- 238000002485 combustion reaction Methods 0.000 description 12
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 11
- 239000000203 mixture Substances 0.000 description 11
- 239000003054 catalyst Substances 0.000 description 10
- 229910052760 oxygen Inorganic materials 0.000 description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
- 239000001301 oxygen Substances 0.000 description 9
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 230000003197 catalytic effect Effects 0.000 description 7
- 238000006477 desulfuration reaction Methods 0.000 description 6
- 239000003546 flue gas Substances 0.000 description 6
- GVGLGOZIDCSQPN-PVHGPHFFSA-N Heroin Chemical compound O([C@H]1[C@H](C=C[C@H]23)OC(C)=O)C4=C5[C@@]12CCN(C)[C@@H]3CC5=CC=C4OC(C)=O GVGLGOZIDCSQPN-PVHGPHFFSA-N 0.000 description 5
- 238000000746 purification Methods 0.000 description 5
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 3
- 230000023556 desulfurization Effects 0.000 description 3
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 3
- 229940043276 diisopropanolamine Drugs 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 239000003863 metallic catalyst Substances 0.000 description 3
- 238000005987 sulfurization reaction Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- -1 alkyl chain alcohol amine Chemical class 0.000 description 2
- JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 229910052602 gypsum Inorganic materials 0.000 description 2
- 239000010440 gypsum Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 238000003672 processing method Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000013207 serial dilution Methods 0.000 description 1
- 229940079827 sodium hydrogen sulfite Drugs 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 239000004291 sulphur dioxide Substances 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/84—Biological processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL1006339A NL1006339C2 (nl) | 1997-06-17 | 1997-06-17 | Werkwijze voor het ontzwavelen van afgassen. |
| NL1006339 | 1997-06-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1265604A true CN1265604A (zh) | 2000-09-06 |
Family
ID=19765181
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN98807855A Pending CN1265604A (zh) | 1997-06-17 | 1998-06-15 | 用于气态废物脱硫的方法 |
Country Status (15)
| Country | Link |
|---|---|
| EP (1) | EP0989902A1 (de) |
| JP (1) | JP2002504858A (de) |
| KR (1) | KR20010013905A (de) |
| CN (1) | CN1265604A (de) |
| AR (1) | AR016072A1 (de) |
| AU (1) | AU737133B2 (de) |
| BR (1) | BR9810187A (de) |
| CA (1) | CA2295443A1 (de) |
| HU (1) | HUP0001892A3 (de) |
| NL (1) | NL1006339C2 (de) |
| NO (1) | NO996257L (de) |
| PL (1) | PL337501A1 (de) |
| SK (1) | SK182099A3 (de) |
| TW (1) | TW386895B (de) |
| WO (1) | WO1998057731A1 (de) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100425324C (zh) * | 2006-01-10 | 2008-10-15 | 武汉加华科技有限公司 | 减顶瓦斯常压脱硫工艺及装置 |
| CN100553746C (zh) * | 2004-03-03 | 2009-10-28 | 国际壳牌研究有限公司 | 从酸性气流中高效回收硫的方法 |
| CN106139812A (zh) * | 2015-04-20 | 2016-11-23 | 兰州信元新型材料有限责任公司 | 二硫化碳专用脱硫剂及其制备方法 |
| CN113209794A (zh) * | 2021-05-07 | 2021-08-06 | 南京飞锦环保科技有限公司 | 一种生物土壤除臭系统及防臭方法 |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL1011490C2 (nl) * | 1999-03-08 | 2000-09-12 | Paques Bio Syst Bv | Werkwijze voor het ontzwavelen van gassen. |
| KR20070011346A (ko) | 2004-03-03 | 2007-01-24 | 쉘 인터내셔날 리써취 마트샤피지 비.브이. | 산성 가스 스트림으로부터 황을 고효율로 회수하는 방법 |
| MXPA06011999A (es) * | 2004-04-22 | 2007-01-25 | Fluor Tech Corp | Configuraciones y metodos para planta claus para sulfuro de carbonilo (cos). |
| WO2010115871A1 (en) * | 2009-04-08 | 2010-10-14 | Shell Internationale Research Maatschappij B.V. | Method of treating an off-gas stream and an apparatus therefor |
| EP3034157A1 (de) | 2015-02-19 | 2016-06-22 | Paqell B.V. | Verfahren zur Behandlung eines Schwefelwasserstoffs und Mercaptanen mit Gas |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE7612503L (sv) * | 1975-11-11 | 1977-05-12 | Courtaulds Ltd | Behandling av gaser |
| DE3204907A1 (de) * | 1982-02-12 | 1983-08-25 | Dr. C. Otto & Co. Gmbh, 4630 Bochum | Verfahren zum entfernen von schwefelwasserstoff aus gasen, insbesondere kohlendestillationsgasen |
| DE3542345A1 (de) * | 1985-11-29 | 1987-06-04 | Imhausen Chemie Gmbh | Verfahren zum entfernen von schwefelwasserstoff aus abgas |
| NL8801009A (nl) * | 1988-04-19 | 1989-11-16 | Rijkslandbouwuniversiteit | Werkwijze voor de verwijdering van sulfide uit afvalwater. |
| NL9001369A (nl) * | 1990-06-15 | 1992-01-02 | Pacques Bv | Werkwijze voor de verwijdering van h2s uit biogas. |
| NL9002661A (nl) * | 1990-12-04 | 1992-07-01 | Pacques Bv | Werkwijze voor de verwijdering van h2s uit gas. |
| US5236677A (en) * | 1992-03-13 | 1993-08-17 | Grupo Cydsa S.A. De C.V. | Biological process for the elimination of sulphur compounds present in gas mixtures |
| NL9301000A (nl) * | 1993-06-10 | 1995-01-02 | Pacques Bv | Werkwijze voor de zuivering van sulfidehoudend afvalwater. |
-
1997
- 1997-06-17 NL NL1006339A patent/NL1006339C2/nl not_active IP Right Cessation
-
1998
- 1998-06-15 EP EP98931121A patent/EP0989902A1/de not_active Ceased
- 1998-06-15 AU AU81321/98A patent/AU737133B2/en not_active Ceased
- 1998-06-15 PL PL98337501A patent/PL337501A1/xx unknown
- 1998-06-15 CN CN98807855A patent/CN1265604A/zh active Pending
- 1998-06-15 TW TW087109447A patent/TW386895B/zh not_active IP Right Cessation
- 1998-06-15 KR KR1019997011927A patent/KR20010013905A/ko not_active Application Discontinuation
- 1998-06-15 SK SK1820-99A patent/SK182099A3/sk unknown
- 1998-06-15 CA CA002295443A patent/CA2295443A1/en not_active Abandoned
- 1998-06-15 JP JP50420299A patent/JP2002504858A/ja active Pending
- 1998-06-15 BR BR9810187-0A patent/BR9810187A/pt not_active IP Right Cessation
- 1998-06-15 WO PCT/NL1998/000342 patent/WO1998057731A1/en not_active Application Discontinuation
- 1998-06-15 HU HU0001892A patent/HUP0001892A3/hu unknown
- 1998-06-16 AR ARP980102855A patent/AR016072A1/es not_active Application Discontinuation
-
1999
- 1999-12-16 NO NO996257A patent/NO996257L/no not_active Application Discontinuation
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100553746C (zh) * | 2004-03-03 | 2009-10-28 | 国际壳牌研究有限公司 | 从酸性气流中高效回收硫的方法 |
| CN100425324C (zh) * | 2006-01-10 | 2008-10-15 | 武汉加华科技有限公司 | 减顶瓦斯常压脱硫工艺及装置 |
| CN106139812A (zh) * | 2015-04-20 | 2016-11-23 | 兰州信元新型材料有限责任公司 | 二硫化碳专用脱硫剂及其制备方法 |
| CN113209794A (zh) * | 2021-05-07 | 2021-08-06 | 南京飞锦环保科技有限公司 | 一种生物土壤除臭系统及防臭方法 |
| CN113209794B (zh) * | 2021-05-07 | 2022-05-17 | 南京飞锦环保科技有限公司 | 一种生物土壤除臭系统及防臭方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| SK182099A3 (en) | 2000-07-11 |
| NO996257L (no) | 2000-02-16 |
| TW386895B (en) | 2000-04-11 |
| NL1006339C2 (nl) | 1998-12-21 |
| NO996257D0 (no) | 1999-12-16 |
| CA2295443A1 (en) | 1998-12-23 |
| HUP0001892A3 (en) | 2002-02-28 |
| WO1998057731A1 (en) | 1998-12-23 |
| HUP0001892A2 (hu) | 2000-11-28 |
| AU8132198A (en) | 1999-01-04 |
| JP2002504858A (ja) | 2002-02-12 |
| BR9810187A (pt) | 2000-08-08 |
| AR016072A1 (es) | 2001-06-20 |
| PL337501A1 (en) | 2000-08-28 |
| AU737133B2 (en) | 2001-08-09 |
| KR20010013905A (ko) | 2001-02-26 |
| EP0989902A1 (de) | 2000-04-05 |
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