CN1242617A - 阀门调节的铅－酸蓄电池 - Google Patents

阀门调节的铅－酸蓄电池 Download PDF

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CN1242617A
CN1242617A CN98116129A CN98116129A CN1242617A CN 1242617 A CN1242617 A CN 1242617A CN 98116129 A CN98116129 A CN 98116129A CN 98116129 A CN98116129 A CN 98116129A CN 1242617 A CN1242617 A CN 1242617A
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oil
battery
regulated lead
acid battery
valve regulated
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CN1152448C (zh
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小齐雅斋
鎌田彰
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GS Yuasa International Ltd
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Japan Storage Battery Co Ltd
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Priority to DE69803561T priority Critical patent/DE69803561T2/de
Priority to US09/118,001 priority patent/US6177212B1/en
Priority to EP98113416A priority patent/EP0973215B1/en
Application filed by Japan Storage Battery Co Ltd filed Critical Japan Storage Battery Co Ltd
Priority to CNB981161294A priority patent/CN1152448C/zh
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/06—Lead-acid accumulators
    • H01M10/12—Construction or manufacture
    • H01M10/121—Valve regulated lead acid batteries [VRLA]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/06—Lead-acid accumulators
    • H01M10/12—Construction or manufacture
    • H01M10/128—Processes for forming or storing electrodes in the battery container
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/14—Electrodes for lead-acid accumulators
    • H01M4/16—Processes of manufacture
    • H01M4/20—Processes of manufacture of pasted electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/627—Expanders for lead-acid accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/06—Lead-acid accumulators
    • H01M10/12—Construction or manufacture
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/027—Negative electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

本发明提供通过所谓电池容器化成法生产阀门调节铅—酸蓄电池,该法包括由未化成正极和负极板栅制备电池,将预定的稀硫酸注入所述电池中,然后向所述电池施加电流,致使板栅群就地化成。阀门调节铅—酸蓄电池具有向其中掺入油的负极活性物质。掺入油的量按重量计优选为0.05—1%。所述油可以是石蜡油、环烷油、烯烃油、芳烃油或硅基油。

Description

阀门调节的铅-酸蓄电池
本发明涉及阀门调节铅-酸蓄电池生产方法的改进。
为了适应近期发展的多样化系统，光学通讯网方面与此相应的基础设施改进进步迅速。尽管光学通讯纤维系统能传送大量数据，但它要求在接点上把光信号转换成电信号。用于此目的光电转换器，在没有防备电源故障的备用电源下是不能操作的。这些转化器大部分用在室外。因此，作为备用电源的这种阀门调节铅-酸蓄电池要暴露在非常恶劣的温度环境下。尤其是，在夏季的高温环境下，由于在浮置充电过程中电解质发生分解而使蓄电池易于“干涸”或“漏热”，因而显示出已损坏的电池特性。
在浮置充电过程中发生的上述干涸是一种分解作用引起电解质损失水含量，结果降低了电池的放电容量的现象。上述漏热是充电电流升高伴随温度升高的一种现象，这种现象能引起电池产生不正常的热量，最终导致电池干涸，使电池不能使用。这些现象，尤其是漏热，容易发生在电池于不低于60℃那样高的温度下使用持续一段时间的时候。当电池在不低于70℃那样高的温度下使用时，这些现象即使在短期内使用也会发出。因此，人们一直希望研制出一种能在这样的条件下使用的电池。
不太容易产生这些现象的阀门调节铅-酸蓄电池是一种即使用于高温下也不太会显示浮置充电电流升高的电池。这样的电池是用常规技术所不能获得的。
伴随温度升高充电电流升高，是一种在正极上由于电解质分解产生的氧量增加和在伴随闭路反应速率提高的负极上吸氧反应速率提高的协同作用。当伴随反应热和充电电流升高使焦耳热产生速率大于由电池散失热的速率时，电池温度升高会超过环境温度。电池温度的升高能引起充电电流的进一步升高，而充电电流的进一步升高又能引起电池温度更进一步的升高。这样，出现了恶性循环，最终导致漏热。
本发明的目的在于提供阀门调节铅-酸蓄电池，这种电池即使在高温下使用，也几乎不出现漏热现象。
本发明通过所谓的电池容器化成法提供该法生产的阀门调节铅-酸蓄电池，该法包括的步骤有：由未化成的正极和负极板栅制备电池；把预定的稀硫酸注入所述电池中；然后向所述电池施加电流，致使板栅群在电池箱内化成，其中使用向其中掺入油的负极活性物质。根据本发明，可以提供具有稳定电池性能的阀门调节铅-酸蓄电池，它即使在高温下也不显示浮置充电电流的升高。
根据本发明，可以提供具有稳定电池性能的阀门调节铅-酸蓄电池，它即使在高温下也不显示浮置充电电流的升高。
对本发明的详细说明描述如下。
本发明的阀门调节铅-酸蓄电池涉及用所谓电池容器化成法生产的阀门调节铅-酸蓄电池，该法具有步骤：用未化成的正极和负极板栅制备电池；把预定的稀硫酸注入所述电池中；然后向所述电池施加电流，致使板栅群在电池容器内化成，其中使用了往其中加有油的负极活性物质。油的加入是在负极浆料合浆过程中进行的。加入的油量优选0.05-1wt％。有关使用的油的种类，可使用动物油和植物油。然而，石腊油、环烷油、烯烃油、芳烃油以及硅基油都可择优使用。从市场上买到的油包含往其中掺有的各种添加剂。可以使用以适当量掺入普通润滑剂和缓蚀剂的油类。
实施例
本发明将在下列实施例中进一步予以描述。
在用Pb-Ca-Sn合金制成的正极和负极板栅中，分别填涂适于铅蓄电池用的正极和负极浆料，然后熟化和干燥，得到未化成的正极和负极板栅。所用负极浆料按下列方法制备。对正极和负极板栅用的合金无特殊限制，但是，Pb-Ca-Sn合金、Pb-Ca合金、Pb-Sn合金、Pb合金(无Sb)等为负极板栅优选使用的材料。对于正极板栅，用于负极板栅的上述合金可优选使用，而且，可使上述合金少量含有Sb如Pb-Sb、Pb-Sb-Sn合金。
往球磨的氧化铅中加入适量的硫酸钡、木素磺酸和炭黑。对混合物进行干混。接着，把预定量的水和1.4比重的稀硫酸按次序加到混合物中。然后混合该混合物。加入的硫酸钡、木素磺酸和炭黑的量可分别为0.1-2％、0.05-1％和0.05-2％。之后，往浆料中加入数量为0-1.5％的油。然后混合该混合物以便制备出如表1所列出的七种浆料。
           表  1
  负极板栅   油的添加量(％)
    A       0
    B       0.05
    C       0.1
    D       0.2
    E       0.5
    F       1
    G       1.5
再把这些正极和负极板栅组装成电池。把预定量的稀硫酸注入电池中。使这些板栅于电池箱内化成，获得如表2所列出的1-7号固定式阀门调节铅-酸蓄电池。同时，为了比较，使如上所用的相同未化成的正极和负极板栅在比重为1.05的硫酸中按槽化成法进行化成，水洗，然后干燥，得到化成板栅。再把这些化成板栅组装成电池。将预定的稀硫酸注入电池中。这些电池经初充电后制备出表2所列出的8-14号电池。

Claims (4)

1.通过所谓电池容器化成法生产的阀门调节铅-酸蓄电池，所述化成法包括的步骤有：由未化成正极和负极板栅制备电池，将预定的稀硫酸注入所述电池中，然后向所述电池施加电流，使得板栅群在电池箱内化成；
所述阀门调节铅-酸蓄电池含有向其中掺入油的负极活性物质。
2.按权利要求1所述阀门调节铅-酸蓄电池，其中所述油量按重量计在0.05-1％的范围内。
3.按权利要求1所述阀门调节铅-酸蓄电池，其中所述油至少是石腊油、环烷油、烯烃油、芳烃油和硅基油中的一种。
4.按权利要求2所述阀门调节铅-酸蓄电池，其中所述油至少是石腊油、环烷油、烯烃油、芳烃油和硅基油中的一种。
CNB981161294A 1998-07-17 1998-07-18 阀门调节的铅-酸蓄电池 Expired - Fee Related CN1152448C (zh)

Priority Applications (4)

Application Number Priority Date Filing Date Title
DE69803561T DE69803561T2 (de) 1998-07-17 1998-07-17 Ventilgeregelter Bleiakkumulator
US09/118,001 US6177212B1 (en) 1998-07-17 1998-07-17 Valve-regulated lead-acid battery
EP98113416A EP0973215B1 (en) 1998-07-17 1998-07-17 Valve-regulated lead-acid battery
CNB981161294A CN1152448C (zh) 1998-07-17 1998-07-18 阀门调节的铅-酸蓄电池

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/118,001 US6177212B1 (en) 1998-07-17 1998-07-17 Valve-regulated lead-acid battery
EP98113416A EP0973215B1 (en) 1998-07-17 1998-07-17 Valve-regulated lead-acid battery
CNB981161294A CN1152448C (zh) 1998-07-17 1998-07-18 阀门调节的铅-酸蓄电池

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CN1242617A true CN1242617A (zh) 2000-01-26
CN1152448C CN1152448C (zh) 2004-06-02

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EP (1) EP0973215B1 (zh)
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114243126A (zh) * 2015-02-26 2022-03-25 达拉米克有限责任公司 蒸汽压力屏障的提供方法、相关的铅酸蓄电池和车辆

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100362679C (zh) * 2006-01-10 2008-01-16 赵恒祥 稀硫酸浸渍生产蓄电池极板的方法
DE102022209933A1 (de) 2022-09-21 2024-03-21 Robert Bosch Gesellschaft mit beschränkter Haftung Stoffgemisch, Verwendung eines Stoffgemisches, Verfahren für die Herstellung eines Funktionskörpers für einen elektrochemischen Energiewandler sowie elektrochemischer Energiewandler

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA696098B (en) 1968-12-26 1971-04-28 Eltra Corp Expander for battery plates
US4252877A (en) * 1977-12-29 1981-02-24 Johnson, Matthey & Co., Limited Battery electrode
US4383011A (en) 1980-12-29 1983-05-10 The Gates Rubber Company Multicell recombining lead-acid battery
US4888259A (en) * 1988-12-05 1989-12-19 Honeywell Inc. Electrode composition and method of making
US5403462A (en) * 1993-06-24 1995-04-04 Yissum Research Development Company Of The Hebrew Univeristy Of Jerusalem Electrochemical electrodes and methods for the preparation thereof
ES2087023B1 (es) 1994-04-06 1997-03-16 Tudor Acumulador Bateria de acumuladores electricos.
US5656393A (en) * 1994-10-21 1997-08-12 W. R. Grace & Co.-Conn. Flexible electrode, product and process of forming same
US5558960A (en) 1995-05-03 1996-09-24 Exide Corporation Seasonal use lead acid electrical storage battery

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114243126A (zh) * 2015-02-26 2022-03-25 达拉米克有限责任公司 蒸汽压力屏障的提供方法、相关的铅酸蓄电池和车辆

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EP0973215B1 (en) 2002-01-23
US6177212B1 (en) 2001-01-23
DE69803561T2 (de) 2002-08-29
DE69803561D1 (de) 2002-03-14
EP0973215A1 (en) 2000-01-19
CN1152448C (zh) 2004-06-02

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