CN1235481C - Water soluble composite potassium monopersulfate powder disinfectant - Google Patents
Water soluble composite potassium monopersulfate powder disinfectant Download PDFInfo
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- CN1235481C CN1235481C CN 200310110649 CN200310110649A CN1235481C CN 1235481 C CN1235481 C CN 1235481C CN 200310110649 CN200310110649 CN 200310110649 CN 200310110649 A CN200310110649 A CN 200310110649A CN 1235481 C CN1235481 C CN 1235481C
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- water soluble
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- 239000000645 desinfectant Substances 0.000 title claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 13
- 239000000843 powder Substances 0.000 title claims abstract description 8
- 239000002131 composite material Substances 0.000 title abstract description 5
- 239000012425 OXONE® Substances 0.000 title abstract 2
- HJKYXKSLRZKNSI-UHFFFAOYSA-I pentapotassium;hydrogen sulfate;oxido sulfate;sulfuric acid Chemical compound [K+].[K+].[K+].[K+].[K+].OS([O-])(=O)=O.[O-]S([O-])(=O)=O.OS(=O)(=O)O[O-].OS(=O)(=O)O[O-] HJKYXKSLRZKNSI-UHFFFAOYSA-I 0.000 title 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 16
- -1 hydrogen potassium monopersulfate Chemical class 0.000 claims abstract description 8
- 239000011780 sodium chloride Substances 0.000 claims abstract description 8
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims abstract description 7
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 7
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims abstract description 7
- 235000011090 malic acid Nutrition 0.000 claims abstract description 7
- 239000001630 malic acid Substances 0.000 claims abstract description 7
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 7
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 claims abstract description 6
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims abstract description 4
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 239000000470 constituent Substances 0.000 claims description 4
- HDMGAZBPFLDBCX-UHFFFAOYSA-M potassium;sulfooxy sulfate Chemical compound [K+].OS(=O)(=O)OOS([O-])(=O)=O HDMGAZBPFLDBCX-UHFFFAOYSA-M 0.000 claims description 4
- 235000005979 Citrus limon Nutrition 0.000 claims 2
- 244000131522 Citrus pyriformis Species 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 2
- 241000894006 Bacteria Species 0.000 abstract description 21
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract description 15
- 230000000694 effects Effects 0.000 abstract description 10
- 230000002147 killing effect Effects 0.000 abstract description 8
- 238000000034 method Methods 0.000 abstract description 7
- 239000000126 substance Substances 0.000 abstract description 6
- 241000700605 Viruses Species 0.000 abstract description 5
- 235000015165 citric acid Nutrition 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 238000002360 preparation method Methods 0.000 abstract description 4
- 230000008569 process Effects 0.000 abstract description 3
- 230000009471 action Effects 0.000 abstract description 2
- 230000000249 desinfective effect Effects 0.000 abstract description 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 206010007269 Carcinogenicity Diseases 0.000 abstract 1
- 206010022998 Irritability Diseases 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 230000007670 carcinogenicity Effects 0.000 abstract 1
- 231100000260 carcinogenicity Toxicity 0.000 abstract 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- JRKICGRDRMAZLK-UHFFFAOYSA-N peroxydisulfuric acid Chemical compound OS(=O)(=O)OOS(O)(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 abstract 1
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 abstract 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 abstract 1
- 239000002689 soil Substances 0.000 description 12
- 241000361919 Metaphire sieboldi Species 0.000 description 11
- 238000002474 experimental method Methods 0.000 description 11
- 238000004659 sterilization and disinfection Methods 0.000 description 11
- 241001465754 Metazoa Species 0.000 description 10
- 230000001954 sterilising effect Effects 0.000 description 10
- 241000283973 Oryctolagus cuniculus Species 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 235000013305 food Nutrition 0.000 description 5
- 244000144977 poultry Species 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 241000233866 Fungi Species 0.000 description 4
- 241000726221 Gemma Species 0.000 description 4
- 241000700159 Rattus Species 0.000 description 4
- 230000037396 body weight Effects 0.000 description 4
- 201000010099 disease Diseases 0.000 description 4
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 210000001508 eye Anatomy 0.000 description 4
- 150000007524 organic acids Chemical class 0.000 description 4
- 244000063299 Bacillus subtilis Species 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 231100000225 lethality Toxicity 0.000 description 3
- 244000000010 microbial pathogen Species 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 235000014469 Bacillus subtilis Nutrition 0.000 description 2
- 241000588724 Escherichia coli Species 0.000 description 2
- 208000010201 Exanthema Diseases 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 150000001412 amines Chemical group 0.000 description 2
- 238000010171 animal model Methods 0.000 description 2
- 238000009360 aquaculture Methods 0.000 description 2
- 244000144974 aquaculture Species 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000002498 deadly effect Effects 0.000 description 2
- 201000005884 exanthem Diseases 0.000 description 2
- 210000000744 eyelid Anatomy 0.000 description 2
- 230000036039 immunity Effects 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 206010037844 rash Diseases 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- RTKIYNMVFMVABJ-UHFFFAOYSA-L thimerosal Chemical compound [Na+].CC[Hg]SC1=CC=CC=C1C([O-])=O RTKIYNMVFMVABJ-UHFFFAOYSA-L 0.000 description 2
- 229940033663 thimerosal Drugs 0.000 description 2
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 241000710189 Aphthovirus Species 0.000 description 1
- 241000222122 Candida albicans Species 0.000 description 1
- 241000711573 Coronaviridae Species 0.000 description 1
- 208000028399 Critical Illness Diseases 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 208000005577 Gastroenteritis Diseases 0.000 description 1
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 1
- 241000709721 Hepatovirus A Species 0.000 description 1
- 231100000111 LD50 Toxicity 0.000 description 1
- 241000204031 Mycoplasma Species 0.000 description 1
- 206010058667 Oral toxicity Diseases 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 241000725643 Respiratory syncytial virus Species 0.000 description 1
- 241000270295 Serpentes Species 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 210000005252 bulbus oculi Anatomy 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 241001233061 earthworms Species 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000002008 hemorrhagic effect Effects 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000000338 in vitro Methods 0.000 description 1
- 229910001410 inorganic ion Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 150000002497 iodine compounds Chemical class 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 230000000622 irritating effect Effects 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000003340 mental effect Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 210000000214 mouth Anatomy 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
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- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a water soluble composite hydrogen potassium monopersulfate powder disinfectant, which solves the problems that many of the domestic chemical products, such as organochlorine preparation and composite prescription disinfectant, have the disadvantages of limited actions, corrosiveness and irritability, and furthermore, aldehyde has carcinogenicity in domestic chemical products. The present invention is prepared from sodium chloride, peroxydisulfuric acid hydrogen potassium, sulfamic acid, malic acid, citric acid, sodium hexametaphosphate, sodium dodecanesulphonate and sodium silicate, according to weight and percentage by scientific technology. The present invention has the advantages of special prescription, simple process flow, low manufacture cost, conspicuous effects on bacterium disinfecting and virus killing, stable and safe product, and environment protection. The present invention has wide purpose and broad market foreground.
Description
Technical field:
The present invention relates to stud bird poultry and use disinfectant, particularly a kind of Water Soluble Compound potassium hydrogen persulfate powder disinfectant.
Technical background:
At present, development along with the modern intensive aquaculture, highly dense, enclosed raising condition makes the fowl poultry more and more seriously be subjected to the threat of pathogenic microorganisms, although drop into a large amount of funds on vaccine and medicine, still can't avoid the appearance of disease, the appearance of these diseases not only endangers the health of animal, also threaten human health, and, have a strong impact on the economic construction of country.
Sterilization is to eliminate pathogenic microorganism in the environment, cuts off the route of transmission, eliminates the attack of pathogenic microorganism to the fowl poultry, stops the propagation of eqpidemic disease.Sterilization is animal health management system centre point and guarantee in the modern breeding production, and it is the overall process through aquaculture, is to realize bio-safety, and the key link of high-quality and safety animal food is provided.Sterilization is that the useful of immunity and medical treatment defective replenished, and has only immunity, medical treatment and sterilization three acting in conjunction, could guarantee that the fowl poultry avoids the evil of being critically ill, and realizes production safety.And the present widely used disinfectant of China mainly is some simple chemicals, organochlorine preparation and compound prescription disinfectant, simple chemicals disinfective action is limited, be subjected to organic matter, temperature, water quality and the influence of environment pH value, and have corrosivity mostly, excitant, wherein aldehydes also has carcinogenic possibility.Organochlorine preparation excitant is very big, and the producer and user are brought great inconvenience.Compound prescription disinfectant commonly used at present comprises quaternary amine one glutaraldehyde compound, quaternary amine one chelated iodine compound etc., though these products have kill bacteria and viral effect simultaneously, but still there is safety problem in glutaraldehyde wherein, and when low temperature, there is not effect, chelated iodine is degraded easily under with serious pollution plant and hot environment, loses efficacy.Therefore in current animal epidemic complexity, today of pollution-free food is called by society, and the sterilization in early stage of livestock and poultry breeding industry is important key link and means.
Summary of the invention:
The object of the present invention is to provide a kind of safety, efficient, long-acting, low-residual, low corrosion and sterilization spectrum are wide, and environmental protection is stable, widely applicable, has the Water Soluble Compound potassium hydrogen persulfate powder disinfectant of active indication.
The objective of the invention is to realize by following approach: the composition of composition is by weight percentage:
Sodium chloride 0.5-8% potassium hydrogen persulfate 20-65%
Sulfamic acid 2-10% malic acid 0-30%
Citric acid 0-30% calgon 0-30%
Dodecyl sodium sulfate 5-20% sodium silicate 2-10%
Constituent is by weight percentage:
Sodium chloride 5 potassium hydrogen persulfates 35
Sulfamic acid 10 malic acid 15
Citric acid 5 calgons 18.8
Dodecyl sodium sulfate 10 sodium silicate 1.2
It is as follows that the present invention has characteristics: 1, broad-spectrum high efficacy, can kill various bacteriums and fungi at 1: 1000, and can safely kill aftosa poison by force at 1: 400, can kill transmissible gastroenteritis germ at 1: 450, to the diluted concentration of porcine reproductive respiratory syndrome be: 700.2, safety, little to operator's excitant and corrosivity, 1% solution of the present invention has no stimulation to eyes and the skin of rabbit, and oral toxicity is extremely low, and 5g/kg dosage does not still have deadly ability to big white mouse.3, stable, product powder 24 months (25 degree are following) has only 2.3% to lose original activity, and 1% solution has only 10% to lose original activity after 7 days in 350ppm hard water.4, meet environment protection requirement, all constituents all can be decomposed or become harmless by biological degradation.5, be widely used, cheap, lower by 1/3 than external like product price, simultaneously, can be used for environment, air, the sterilization of water body and animal.
Embodiment:
Constituent of the present invention is by weight percentage: sodium chloride 5, potassium hydrogen persulfate 35, sulfamic acid 10, malic acid 15, citric acid 5, calgon 18.8, dodecyl sodium sulfate 10, sodium silicate 1.2.The aqueous ph value of combination is 1-5.5, and the effect of composite organic acid systematic collaboration significantly improves disinfecting power, solves agglomeration problems, has strengthened the stability of prescription.Organic acid in the prescription is malic acid and citric acid, and the environment of the pH value of composite organic acid system and formation produces the collaborative effect of killing pathogene.Surfactant is a dodecyl sodium sulfate, strengthens membrane permeability, produces the concurrent disinfection bactericidal action.Anti-caking agent silicate base slaine is a sodium silicate, prevents caking, improves formulation stability.Because, contain stable per-compound among the present invention, sodium chloride, active chlorine bond, surfactant, organic acid and activated indicators class infect the virus of humans and animals to all, bacterium and gemma thereof, mycoplasma, egg capsule all has powerful killing action in fungi and the ball, particularly to aphthovirus, PCV-II, coronavirus, the spore exanthema virus, adenovirus, Respiratory Syncytial Virus(RSV), hepatitis A virus, oral cavity spore exanthema virus, epizootic hemorrhagic venereal disease poison has significant killing action.
Embodiment:
(1) the present invention is to the killing effect of part bacterium and fungi.
A, method
(a) adopt invention to be configured to 1%, 0.5% by the operation instruction apportion, 0.01% 3 kind of solution in different concentration.
(b) experimental bacteria is that staphylococcus aureus (ATCC6538), Escherichia coli (8089), Candida albicans (ATCC10231), bacillus subtilis black variety gemma (ATCC9373), black mould (ATCC16404) are cultivated according to the different cultural methods of various microorganisms
B, in and experimental result
(a) experimental bacteria bacillus subtilis black variety gemma, concentration are 1%, and neutralizer is 0.5% sodium thiosulfate, establish 6 groups, and experimental result shows 1,4,6 group and cannot not be long bacterium, and 2,3,5 long bacterium amounts are similar, show that degree of neutralization and concentration are suitable.
| Numbering | The group agent | Average bacterium algae number |
| (1) | (disinfectant+bacterium liquid)+neutralizer | 0 |
| (2) | Neutralizer+bacterium liquid | 5.8×10 8 |
| (3) | (disinfectant+neutralizer)+bacterium liquid | 5.2×10 8 |
| (4) | Disinfectant+bacterium liquid | 0 |
| (5) | Normal bacterium contrast | 6.8×10 8 |
| (6) | Do not inoculate the medium contrast of bacterium | 0 |
Annotate: several 25 degree of experimental temperature, added behind the bacterium liquid effect 10 minutes, in the neutralizer and 10 minutes, the result is 5 empirical average values.
C, quantitative sterilization experiment
Under 25 degree conditions, go the 0.5mI bacteria suspension to add in the 4.5mI thimerosal mixing effect to the scheduled time, go 0.5mI bacterium liquid to mix the in vitro mixed rhythm of adding 4.5mI neutralizer, in and 10min, make count plate, calculate 1: 1000 diluent concentration of killing rate and can effectively kill various bacteriums and fungi.
Table two
| Experimental bacteria | Thimerosal concentration | Control group bacterium number | The killing rate of effect different time (min) | ||
| (cfu/mI) | 2 | 5 | 10 | ||
| Golden yellow grape nodule number | 1％ | 4.8×10 8 | 100 | 100 | 100 |
| 0.5％ | 4.8×10 8 | 100 | 100 | 100 | |
| 0.01％ | 4.8×10 8 | 99.98 | 100 | 100 | |
| Escherichia coli | 1％ | 5.2×10 8 | 100 | 100 | 100 |
| 0.5％ | 5.2×10 8 | 100 | 100 | 100 | |
| 0.01％ | 5.2×10 8 | 100 | 100 | 100 | |
| Bacillus subtilis black variety gemma | 1％ | 5.4×10 8 | 100 | 100 | 100 |
| 0.5％ | 5.4×10 8 | 100 | 100 | 100 | |
| 0.01％ | 5.4×10 8 | 99.03 | 99.06 | 99.9 | |
| White is read coccobacillus | 1％ | 4.5×10 8 | 100 | 100 | 100 |
| 0.5％ | 4.5×10 8 | 100 | 100 | 100 | |
| 0.01％ | 4.5×10 8 | 100 | 100 | 100 | |
| Black-koji mould | 1％ | 4.8×10 8 | 100 | 100 | 100 |
| 0.5％ | 4.8×10 8 | 100 | 100 | 100 | |
| 0.01％ | 4.8×10 8 | 100 | 100 | 100 | |
(2) irritant experiment of the present invention
1, buy from market, 3 healthy White Rabbits that body weight is about 3.48 to 3.85 kilograms are tested preceding 3 days adaptation laboratory environments, and whole experimental session White Rabbit is freely drunk water and ingested.
2, experimental procedure:
(1) the present invention is diluted to 1% concentration.
(2) the rabbit left eyelid is drawn back, put into 0.1 milliliter of test fluid to the rabbit eyeball, upper and lower eyelid closed 1.2 seconds, decontroled then, not have the right eye of processing to be used as tester.
(3) tested thing and done excitant situation eye examination after 2 hours splashing into.
(4) experimental result splashes into 1% solution to the rabbit eyes, does not have irritative response.
See Table
(3) toxicity test of the present invention
(1) tried thing: the present invention
(2) experiential function: 25 healthy rats, body weight are the 450-680 gram.
Test first three day adaptation laboratory environment, whole experimental session, animal freely drinks water and ingests.
(3) experimental procedure:
A is divided into five groups with laboratory animal, every group of laboratory animal numbering, the mental status before the record experiment.
B establishes the dosage group of 1,2 and 5 gram/kg body weight, blank group and positive controls.
C will be tried thing and be assigned to oral administration medicine supplying to rat, from offeing medicine 1, the 2 day every 30min observed and recorded in back once, observed and recorded seven days
(4) experimental result:
In 60 hours, rats death does not all appear in 3 dosage groups being tried thing, and the result shows that the solution of the present invention of oral 5 gram/kilogram dosage does not have deadly ability to rat.
(4) environmental protection experiment of the present invention
Important component of the present invention is mineral salt, as potassium hydrogen persulfate, and sodium chloride.These salt can resolve into the inorganic ions that does not have harm, K in water
+, Na
+, SO
4 2-Cr etc., the another one important component is the straight chained alkyl sodium sulfonate.The straight chained alkyl sodium sulfonate is to be widely used in the daily washing agent, and under the test of OECD, its thing degraded is greater than 90%.
Earthworm is very active in the soil ecosystem, very important life, and its vital movement can not only be improved soil structure, is of value to the aeration status and the draining of soil, and water retaining function, and energy decomposition and inversion soil organic substance are increase soil fertility.Earthworm still is many animals such as snake class, the food source of horse class and muroid, and in food chain, it is an important bridge of transmitting pollutant between terrestrial organism and the soil organisms.
For the influence of experiment the present invention, carried out experiment to earthworm to soil ecology in the environment.
1, materials and methods
A, selection body weight are the earthworm of 300-500, and earthworm is placed moistening last 3 hour of filter paper, make food eliminating in its enteron aisle, flushing then, and filter paper blots, and uses for testing.
B, the chemicals experiment guide preparation of employing State Bueau of Environmental Protection.
C, tried thing: the present invention establishes 0,0.5,6 dosage groups of 1.0,1.5,2.0,2.5 soil.
D, experiment method: with certain density solution and earth mixture.Regulating soil moisture content is 60% of maximum water-holding capacity, after the balance 48 hours, transfer in the specimen bottle of rinsing well, add 10 earthworms of under artificial condition, raising 24 hours, tie the sample bottleneck with gauze or plastic film, in temperature is 20 ± 2 degree, and humidity is that continuous illumination is cultivated under 80% the condition.When testing 14 days, the soil in the specimen bottle is poured on the glass container, checked of the reaction of the preceding afterbody of earthworm, place specimen bottle to continue to cultivate again in soil and earthworm then, finish until experiment to mechanical stimulus.The death toll of record earthworm is a coordinate to weigh the present invention and earthworm lethality, draws dose-effect curve, each processed group establish 2 parallel.
2, experimental result
Through 20 degree down, handled in 14 days, 6 dosage groups 0,0.5,1.0,1.5,2.0 of the present invention, 2.5g/kg has 0,0,1,3,6 and 8 earthworm death respectively, and lethality is respectively 0,10%, 30%, 60% and 80%.Experimental data sees Table:
| Metering group (g/kg) | Death toll after 14 days (bar) | Lethality % after 14 days |
| 0 | 0 | 0 |
| 0.5 | 0 | 0 |
| 1.0 | 1 | 10％ |
| 1.5 | 3 | 30％ |
| 2.0 | 6 | 60％ |
| 2.5 | 8 | 80％ |
3, conclusion, the present invention is 1.85g/kg to the median lethal concentration of earthworm, and is nontoxic to soil and environment, compliance with environmental protection requirements.
The present invention's uniqueness of filling a prescription, technological process is simple, low cost of manufacture, product safety is stable, meets environment protection requirement, broad-spectrum high efficacy, the sterilization effect of killing the virus is remarkable.Product has activated indicators, can judge its validity from sense organ, and is the same with sterilization under the low temperature environment effective at organic matter, of many uses, has vast market prospect.
Claims (2)
1, a kind of Water Soluble Compound potassium hydrogen persulfate powder disinfectant is characterized in that the composition of forming is by weight percentage:
Sodium chloride 0.5-8% potassium hydrogen persulfate 20-65%
Sulfamic acid 2-10% malic acid 0-30%
Lemon rubber acid 0-30% calgon 0-30%
Dodecyl sodium sulfate 5-20% sodium silicate 2-10%.
2, Water Soluble Compound potassium hydrogen persulfate powder disinfectant according to claim 1 is characterized in that constituent is by weight percentage:
Sodium chloride 5 potassium hydrogen persulfates 35
Sulfamic acid 10 malic acid 15
Lemon rubber acid 5 calgons 18.8
Dodecyl sodium sulfate 10 sodium silicate 1.2.
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| CN102265904A (en) * | 2011-06-03 | 2011-12-07 | 宋海鹏 | Compound potassium hydrogen persulfate disinfectant and manufacturing process thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102265904A (en) * | 2011-06-03 | 2011-12-07 | 宋海鹏 | Compound potassium hydrogen persulfate disinfectant and manufacturing process thereof |
| CN102265904B (en) * | 2011-06-03 | 2015-01-07 | 宋海鹏 | Compound potassium hydrogen persulfate disinfectant and manufacturing process thereof |
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| CN1545883A (en) | 2004-11-17 |
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