CN1234624C - Fragrance deodorizing filtering and cleaning block and making method thereof - Google Patents

Abstract

The present invention relates to a fragrant deodorization filtering and cleaning block comprising the components of 10 wt% to 30 wt% of solid alcohol with polyethyleneglycol as an effective component having the molecular weight of 3000 to 6000, 12 wt% to 24 wt% of fatty alcohol-polyoxyethylene ether, 8 wt% to 15 wt % of lauric monoethanol enamine, 8 wt % to 15 wt% of sodium dodecylbenzene sulfonate, 25 wt% to 35 wt% of alkyl sodium sulfate, 2 wt% to 5 wt% of carboxymethyl cellulose (CMC), 1.5 wt% to 2.5 wt% of dibrom hydantoin and 2.5 wt% to 3.5 wt% of natural vegetal spice with zanthoxylum nitidum or locust bark aldehyde as an effective component. In the preparation method, the solid alcohol, the fatty alcohol-polyoxyethylene ether, the monoethanol enamine, the sodium dodecylbenzene sulfonate and the alkyl sodium sulfate are mixed in a reaction vessel at the temperature of 80 DEG C to 110 DEG C under the condition of continuous stir, and are cooled to 60 DEG C to 80 DEG C. At this time, the dibrom hydantoin and the vegetal spice are added, and the fragrant deodorization filtering and cleaning block is formed at room temperature. The fragrant deodorization filtering and cleaning block has the advantages for effectively removing odour and urine scale in toilets, and having no toxic side effects or environmental pollution.

Description

A kind of fragrance deodorizing filtering and cleaning block and manufacture method thereof

Technical field:

The present invention relates to a kind of filtering and cleaning block and manufacture method thereof of removing lavatory stink and urine dirt, refer to a kind of deodorizing filtering and cleaning block and manufacture method thereof that has aromatising flavour especially.

Background technology:

At present, widely used toilet deodorization articles for use can be divided into two kinds: a kind of is traditional sanitary product, adopts and is mixed with globular reodorant by mothball, santochlor, synthetic perfume.The employed mothball of this reodorant, santochlor belong to sublimability, easy volatile material, its smell of naphthalene in the mothball and santochlor all has hormesis to eyes, the nasal membrane of human body, influence HUMAN HEALTH, and polluted air, and the assorted phosphorus that contains in the santochlor has severe contamination to environment.Another kind of is to adopt tripoly phosphate sodium STPP or tertiary sodium phosphate and spices to be mixed into bulk, as reodorant, utilizes the spices deodorizing, utilizes tripoly phosphate sodium STPP or tertiary sodium phosphate scale removal.But, because this class reodorant has used phosphorated tripoly phosphate sodium STPP or tertiary sodium phosphate, though can be to toilet deodorization, its pollution to environment, destruction are seriously.

Summary of the invention:

The purpose of this invention is to provide a kind of pleasant aroma, have no side effect, non-environmental-pollution, can effectively soften and get rid of the fragrance deodorizing filtering and cleaning block of the urine dirt that accumulates in the pipeline of lavatory and the manufacture method of this filtering and cleaning block.

The objective of the invention is to be achieved through the following technical solutions:

1, fragrance deodorizing filtering and cleaning block of the present invention, its compositions in weight percentage is constructed as follows:

(1) effective constituent is polyoxyethylene glycol, and polyoxyethylene glycol

Molecular weight is the solid alcohol 10-30% of 3000-6000;

(2) fatty alcohol-polyoxyethylene ether: 12-24%;

(3) laurostearic acid monoethanolamine enamine: 8-15%;

(4) Sodium dodecylbenzene sulfonate: 8-15%;

(5) sodium alkyl sulfate: 25-35%;

(6) carboxymethyl cellulose (CMC) caking agent: 2-5%;

(7) C5H6Br2N2O2: 1.5-2.5%;

(8) effective ingredient is the natural plant pefume of Shinyleaf Pricklyash Root or Chinese scholartree skin aldehyde: 2.5-3.5%.

2, the manufacture method of fragrance deodorizing filtering and cleaning block of the present invention, according to above-mentioned weight percent, earlier with the above-mentioned each component amount of getting, its manufacturing process is as follows:

(1) taking polyethylene glycol places pool glass reaction pot, is heated to 80-110 ℃, and constantly stirs;

(2) under aforesaid agitation condition, treat that polyoxyethylene glycol all is dissolved into pulpous state after, in reactor, add fatty alcohol-polyoxyethylene ether, temperature is controlled at 80-110 ℃, and constantly stirs, allow compound react;

(3) be 80-110 ℃ in aforesaid temperature, fully under the agitation condition, in reactor, add laurostearic acid monoethanolamine enamine again, allow compound further react again 45-90 minute;

(4) under abundant agitation condition, in above-mentioned compound, add Sodium dodecylbenzene sulfonate and sodium alkyl sulfate, allow compound continue reaction 30-45 minute, stir and lower the temperature;

(5) when above-mentioned mixture temperature is reduced to 60-80 ℃, continue to stir, and add carboxymethyl cellulose (CMC) caking agent, stirred 20-40 minute, filter, get filtrate;

(6) when the stirring of aforesaid filtrate is cooled to 60-40 ℃,, continue to stir to wherein adding C5H6Br2N2O2 and natural plant pefume;

(7) with above-mentioned compound after stirring 15-20 minute, import mould, under normal temperature condition, cool off, make that it solidifies, moulding, get product.

Advantage of the present invention is: (1) utilizes the Shinyleaf Pricklyash Root of natural plant pefume or Chinese scholartree skin aldehyde to the price reduction effect of ammonia, can effectively remove typical foul smell-ammonia gas in the lavatory; And its pleasant aroma has no side effect to human body.(2) owing to adopt solid alcohol, adopt aliphatic alcohol polyethenoxy, laurostearic acid monoethanolamine enamine, Sodium dodecylbenzene sulfonate, sodium alkyl sulfate detergent as scale remover, so it have no side effect non-environmental-pollution as flocculation agent; (3) with above-mentioned detergent as scale remover, when entering the soil line road after their dissolvings, the ammonium ion in the urine dirt that can neutralize, the assorted dirt that accumulates for a long time in the softening pipeline, after water slug, can play the effect of good removing pipeline incrustation, thus the mediation, cleanser conduit.

Embodiment:

Embodiment 1:

By weight percentage, take off row component 100 grams, wherein:

(1) effective constituent is polyoxyethylene glycol, and poly-second

The molecular weight of glycol is 3000 solid alcohol: 20 grams;

(2) fat-fat polyoxyethylenated alcohol: 18 grams;

(3) laurostearic acid monoethanolamine enamine: 12 grams;

(4) Sodium dodecylbenzene sulfonate: 10 grams;

(5) trialkyl sodium sulfate: 30 grams;

(6) carboxymethyl cellulose (CMC) caking agent: 4 grams;

(7) C5H6Br2N2O2: 2.5 grams;

(8) effective ingredient is the natural plant pefume of Shinyleaf Pricklyash Root: 3.5 grams.

Press following technological operation:

(1) above-mentioned 20 gram solid alcohol is placed 500 milliliters of glass beakers, be heated to 110 ℃, and constantly stir;

(2) under agitation condition, treat that solid alcohol all is dissolved into pulpous state after, in beaker, add fatty alcohol-polyoxyethylene ether 18 grams, constantly stir, temperature is controlled at 85 ℃, allow compound react;

(3) be 85 ℃ in aforesaid temperature, fully under the agitation condition, in beaker, add laurostearic acid monoethanolamine enamine 12 grams again, allow compound reaction 85 minutes;

(4) under abundant agitation condition, in above-mentioned compound, add Sodium dodecylbenzene sulfonate 10 grams and trialkyl sodium sulfate 30 grams, allow compound continue to react 45 minutes, stir cooling;

(5) when above-mentioned mixture temperature is reduced to 80 ℃, continue to stir, and add carboxymethyl cellulose (CMC) caking agent 4 grams, stirred 40 minutes, filter, get filtrate;

(6) stirring of above-mentioned filtrate is cooled to 60 ℃,, continues to stir to wherein adding natural plant pefume 3.5 grams that C5H6Br2N2O2 2.5 grams and effective ingredient are Shinyleaf Pricklyash Root;

(7) with above-mentioned compound after stirring 20 minutes, it is imported piece shape mould, under normal temperature condition, cool off, make that it solidifies, moulding, promptly get blocky fragrance deodorizing filtering and cleaning block finished product of the present invention.

Embodiment 2:

Take off row component 100 grams by weight percentage:

(1) effective constituent is polyoxyethylene glycol, and poly-second

Glycol molecular weight is 4500 solid alcohol: 28 grams;

(2) fatty alcohol-polyoxyethylene ether: 14 grams;

(3) laurostearic acid monoethanolamine enamine: 14 grams;

(4) Sodium dodecylbenzene sulfonate: 12 grams;

(5) five sodium alkyl sulfates: 25 grams;

(6) carboxymethyl cellulose (CMC) caking agent: 3 grams;

(7) C5H6Br2N2O2: 1.5 grams;

(8) effective ingredient is the natural plant pefume of Chinese scholartree skin aldehyde: 2.5 grams.

Press following technological operation:

(1) above-mentioned 28 gram solid alcohol is placed 500 milliliters of glass beakers, be heated to 100 ℃, and constantly stir;

(2) under agitation condition, treat that solid alcohol all is dissolved into pulpous state after, in beaker, add fatty alcohol-polyoxyethylene ether 14 grams, constantly stir, temperature is controlled at 90 ℃, allow compound react;

(3) be 90 ℃ in aforesaid temperature, fully under the agitation condition, in beaker, add laurostearic acid monoethanolamine enamine 14 grams again, allow compound reaction 60 minutes;

(4) under abundant agitation condition, in above-mentioned compound, add Sodium dodecylbenzene sulfonate 12 grams and five sodium alkyl sulfates, 25 grams, allow compound continue to react 35 minutes, stir cooling;

(5) when above-mentioned mixture temperature is reduced to 70 ℃, continue to stir, and add carboxymethyl cellulose (CMC) caking agent 3 grams, stirred 30 minutes, filter, get filtrate;

(6) stirring of above-mentioned filtrate is cooled to 50 ℃,, continues to stir to wherein adding natural plant pefume 2.5 grams that C5H6Br2N2O2 1.5 grams and effective ingredient are Chinese scholartree skin aldehyde;

(7) with above-mentioned compound after stirring 18 minutes, it is imported spherical mould, under normal temperature condition, cool off, make that it solidifies, moulding, promptly get globular fragrance deodorizing filtering and cleaning block finished product of the present invention.

Embodiment 3:

Take off row component 100 grams by weight percentage:

(1) effective constituent is polyoxyethylene glycol, and poly-second

Glycol molecular weight is 6000 solid alcohol: 10 grams;

(2) fatty alcohol-polyoxyethylene ether: 24 grams;

(3) laurostearic acid monoethanolamine enamine: 9 grams;

(4) Sodium dodecylbenzene sulfonate: 15 grams;

(5) six sodium alkyl sulfates: 35 grams;

(6) carboxymethyl cellulose (CMC) caking agent: 2 grams;

(7) C5H6Br2N2O2: 2 grams;

(8) effective ingredient is the natural plant pefume of Shinyleaf Pricklyash Root: 3 grams.

Press following technological operation:

(1) above-mentioned 10 gram solid alcohol is placed 500 milliliters of glass beakers, be heated to 85 ℃, and constantly stir;

(2) under agitation condition, treat that solid alcohol all is dissolved into pulpous state after, in beaker, add fatty alcohol-polyoxyethylene ether 24 grams, constantly stir, temperature is controlled at 80 ℃, allow compound react;

(3) be 80 ℃ in aforesaid temperature, fully under the agitation condition, in beaker, add laurostearic acid monoethanolamine enamine 9 grams again, allow compound reaction 45 minutes;

(4) under abundant agitation condition, in above-mentioned compound, add Sodium dodecylbenzene sulfonate 15 grams and six sodium alkyl sulfates, 35 grams, allow compound continue to react 30 minutes, stir cooling;

(5) when above-mentioned mixture temperature is reduced to 60 ℃, continue to stir, and add carboxymethyl cellulose (CMC) caking agent 2 grams, stirred 20 minutes, filter, get filtrate;

(6) stirring of above-mentioned filtrate is cooled to 40 ℃,, continues to stir to wherein adding natural plant pefume 3 grams that C5H6Br2N2O2 2 grams and effective ingredient are Shinyleaf Pricklyash Root;

(7) above-mentioned compound is stirred 15 minutes after, it is imported spherical mould, under normal temperature condition, cool off, make that it solidifies, moulding, promptly get globular fragrance deodorizing filtering and cleaning block finished product of the present invention.

The filtering and cleaning block that above-mentioned three embodiment are made is used for toilet deodorization, scale removal, not only has pleasant aromatising flavour, and has good descale effect, can effectively stop the lavatory fouling.

Claims (2)

1, a kind of fragrance deodorizing filtering and cleaning block, it is characterized in that: its compositions in weight percentage is constructed as follows:

(1) effective constituent is polyoxyethylene glycol, and polyoxyethylene glycol

Molecular weight is the solid alcohol 10-30% of 3000-6000;

(2) fatty alcohol-polyoxyethylene ether: 12-24%;

(3) laurostearic acid monoethanolamine enamine: 8-15%:

(4) Sodium dodecylbenzene sulfonate: 8-15%;

(5) sodium alkyl sulfate: 25-35%;

(6) carboxymethyl cellulose (CMC) binding agent: 2-5%;

(7) C5H6Br2N2O2: 1.5-2.5%;

(8) effective constituent is the natural plant pefume of Shinyleaf Pricklyash Root or Chinese scholartree skin aldehyde: 2.5-3.5%.

2, the manufacture method of the described fragrance deodorizing filtering and cleaning block of claim 1 according to the weight percent of its component, earlier with each component amount of getting, is characterized in that manufacturing process is as follows:

(1) taking polyethylene glycol places pool glass reaction pot, is heated to 80-110 ℃, and constantly stirs;

(2) under aforesaid agitation condition, treat that polyoxyethylene glycol all is dissolved into pulpous state after, in reactor, add fatty alcohol-polyoxyethylene ether, temperature is controlled at 80-110 ℃, and constantly stirs, allow compound react;

(3) be 80-110 ℃ in aforesaid temperature, fully under the agitation condition, in reactor, add laurostearic acid monoethanolamine enamine again, allow compound further react again 45-90 minute;

(4) under abundant agitation condition, in above-mentioned compound, add Sodium dodecylbenzene sulfonate and sodium alkyl sulfate, allow compound continue reaction 30-45 minute, stir and lower the temperature;

(5) when above-mentioned mixture temperature is reduced to 60-80 ℃, continue to stir, and add carboxymethyl cellulose (CMC) binding agent, stirred 20-40 minute, filter, get filtrate;

(6) when the stirring of aforesaid filtrate is cooled to 60-40 ℃,, continue to stir to wherein adding C5H6Br2N2O2 and natural plant pefume;

(7) with above-mentioned compound after stirring 15-20 minute, import mould, under normal temperature condition, cool off, make that it solidifies, moulding, get product.