CN1227255C - 用于烯烃聚合反应的甲硅烷氧基取代的助催化剂活化剂 - Google Patents

用于烯烃聚合反应的甲硅烷氧基取代的助催化剂活化剂 Download PDF

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Publication number
CN1227255C
CN1227255C CNB018114792A CN01811479A CN1227255C CN 1227255 C CN1227255 C CN 1227255C CN B018114792 A CNB018114792 A CN B018114792A CN 01811479 A CN01811479 A CN 01811479A CN 1227255 C CN1227255 C CN 1227255C
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CN
China
Prior art keywords
tri
silyloxy
isopropyl
perfluorophenyl
borate
Prior art date
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Expired - Fee Related
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CNB018114792A
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English (en)
Chinese (zh)
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CN1437607A (zh
Inventor
G·罗德里格斯
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ExxonMobil Chemical Patents Inc
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Exxon Chemical Patents Inc
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Priority claimed from US09/602,289 external-priority patent/US6346636B1/en
Priority claimed from US09/599,909 external-priority patent/US6541410B1/en
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Publication of CN1437607A publication Critical patent/CN1437607A/zh
Application granted granted Critical
Publication of CN1227255C publication Critical patent/CN1227255C/zh
Anticipated expiration legal-status Critical
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/643—Component covered by group C08F4/64 with a metal or compound covered by group C08F4/44 other than an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerisation Methods In General (AREA)
CNB018114792A 2000-06-23 2001-06-18 用于烯烃聚合反应的甲硅烷氧基取代的助催化剂活化剂 Expired - Fee Related CN1227255C (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US09/602,289 US6346636B1 (en) 2000-06-23 2000-06-23 Siloxy substituted cocatalyst activators for olefin polymerization
US09/602,289 2000-06-23
US09/599,909 2000-06-23
US09/599,909 US6541410B1 (en) 2000-06-23 2000-06-23 Siloxy substituted cocatalyst activators for olefin polymerization

Publications (2)

Publication Number Publication Date
CN1437607A CN1437607A (zh) 2003-08-20
CN1227255C true CN1227255C (zh) 2005-11-16

Family

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Family Applications (2)

Application Number Title Priority Date Filing Date
CNB018114792A Expired - Fee Related CN1227255C (zh) 2000-06-23 2001-06-18 用于烯烃聚合反应的甲硅烷氧基取代的助催化剂活化剂
CNB018114784A Expired - Fee Related CN1178960C (zh) 2000-06-23 2001-06-19 用于烯烃聚合反应的甲硅烷氧基取代的助催化剂活化剂

Family Applications After (1)

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CNB018114784A Expired - Fee Related CN1178960C (zh) 2000-06-23 2001-06-19 用于烯烃聚合反应的甲硅烷氧基取代的助催化剂活化剂

Country Status (8)

Country Link
EP (2) EP1296991B1 (enExample)
JP (2) JP2004501926A (enExample)
KR (2) KR20030019447A (enExample)
CN (2) CN1227255C (enExample)
BR (2) BR0111515A (enExample)
CA (2) CA2412606A1 (enExample)
MX (2) MXPA02012672A (enExample)
WO (2) WO2002000666A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8066965B2 (en) 2002-09-27 2011-11-29 Co2 Solution Inc. Process for recycling carbon dioxide emissions from power plants into carbonated species
US8329460B2 (en) 2001-07-13 2012-12-11 CO2 Solutions, Inc. Carbonic anhydrase bioreactor and process

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003128720A (ja) 2001-10-19 2003-05-08 Sunallomer Ltd オレフィン重合用固体助触媒成分、オレフィン重合用触媒およびイオン含有化合物
WO2009057600A1 (ja) 2007-11-01 2009-05-07 Adeka Corporation 塩化合物、カチオン重合開始剤およびカチオン重合性組成物
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
JP5688236B2 (ja) 2010-05-25 2015-03-25 出光興産株式会社 触媒組成物及び当該触媒組成物を用いるオレフィン系重合体の製造方法
US9234060B2 (en) 2011-11-08 2016-01-12 Univation Technologies, Llc Methods of preparing a catalyst system
JP6492018B2 (ja) * 2014-02-13 2019-03-27 三井化学株式会社 エチレン／α−オレフィン共重合体の製造方法
WO2020198196A1 (en) 2019-03-28 2020-10-01 Dow Global Technologies Llc Anionic group iii complexes as weakly coordinating anions for olefin polymerization catalyst activators

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
FR2679564A1 (fr) 1991-07-23 1993-01-29 Inst Nat Sante Rech Med Nouveaux acylmercaptoalcanoldipeptides, leur preparation et les compositions qui les contiennent.
US5296433A (en) 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US5635573A (en) 1992-12-01 1997-06-03 Exxon Chemical Patents Inc. Method for preparing alpha-olefin/cycloolefin copolymers
US5502017A (en) * 1994-03-10 1996-03-26 Northwestern University Metallocene catalyst containing bulky organic group
US5447895A (en) 1994-03-10 1995-09-05 Northwestern University Sterically shielded diboron-containing metallocene olefin polymerization catalysts
EP0698825A1 (en) 1994-07-29 1996-02-28 AT&T Corp. An energy sensitive resist material and a process for device fabrication using the resist material
ATE233790T1 (de) * 1995-03-10 2003-03-15 Dow Global Technologies Inc Geträgerter katalysatorbestandteil, trägerkatalysator, herstellungsverfahren, polymerisationsverfahren, komplexverbindungen und ihre herstellung
WO1997019959A1 (en) * 1995-11-27 1997-06-05 The Dow Chemical Company Supported catalyst containing tethered cation forming activator
US5856256A (en) 1996-02-20 1999-01-05 Northwestern University Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations
US5763556A (en) 1996-05-21 1998-06-09 Exxon Chemical Patents Inc. Copolymers of ethylene and geminally disubstituted olefins
US5895771A (en) 1997-06-05 1999-04-20 Akzo Nobel Nv Fluorinated alkoxy and/or aryloxy aluminates as cocatalysts for metallocene-catalyzed olefin polymerizations
WO1999030822A1 (en) 1997-12-16 1999-06-24 Exxon Research And Engineering Company Group 11 transition metal amine catalysts for olefin polymerization
TR200002404T2 (tr) 1998-02-20 2001-01-22 The Dow Chemical Company Genişletilmiş anyonlar ihtiva eden katalizör etkinleştiriciler
DE19808253A1 (de) 1998-02-27 1999-09-02 Aventis Res & Tech Gmbh & Co Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8329460B2 (en) 2001-07-13 2012-12-11 CO2 Solutions, Inc. Carbonic anhydrase bioreactor and process
US8329459B2 (en) 2001-07-13 2012-12-11 Co2 Solutions Inc. Carbonic anhydrase system and process for CO2 containing gas effluent treatment
US8329458B2 (en) 2001-07-13 2012-12-11 Co2 Solutions Inc. Carbonic anhydrase bioreactor and process for CO2 containing gas effluent treatment
US8066965B2 (en) 2002-09-27 2011-11-29 Co2 Solution Inc. Process for recycling carbon dioxide emissions from power plants into carbonated species
US8277769B2 (en) 2002-09-27 2012-10-02 Co2 Solutions Inc. Process for treating carbon dioxide containing gas
US8435479B2 (en) 2002-09-27 2013-05-07 Co2 Solutions Inc. Process for treating carbon dioxide containing gas

Also Published As

Publication number Publication date
WO2002000666A1 (en) 2002-01-03
MXPA02012673A (es) 2003-10-14
MXPA02012672A (es) 2004-04-21
WO2002000738A1 (en) 2002-01-03
BR0111487A (pt) 2003-03-25
JP2004501989A (ja) 2004-01-22
EP1297027A1 (en) 2003-04-02
EP1296991B1 (en) 2013-05-15
EP1296991A1 (en) 2003-04-02
CA2412606A1 (en) 2002-01-03
CA2412608A1 (en) 2002-01-03
KR20030011363A (ko) 2003-02-07
CN1178960C (zh) 2004-12-08
CN1437618A (zh) 2003-08-20
BR0111515A (pt) 2003-05-06
KR20030019447A (ko) 2003-03-06
CN1437607A (zh) 2003-08-20
JP2004501926A (ja) 2004-01-22

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