CN1227239A - Ink/media combination - Google Patents
Ink/media combination Download PDFInfo
- Publication number
- CN1227239A CN1227239A CN98111670.1A CN98111670A CN1227239A CN 1227239 A CN1227239 A CN 1227239A CN 98111670 A CN98111670 A CN 98111670A CN 1227239 A CN1227239 A CN 1227239A
- Authority
- CN
- China
- Prior art keywords
- ink
- media combination
- printing
- fabric
- printing ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- -1 alginic acid salt Chemical class 0.000 claims abstract description 27
- 235000010443 alginic acid Nutrition 0.000 claims abstract description 21
- 229920000615 alginic acid Polymers 0.000 claims abstract description 21
- 150000003839 salts Chemical class 0.000 claims abstract description 17
- 229910052751 metal Inorganic materials 0.000 claims abstract description 9
- 239000002184 metal Substances 0.000 claims abstract description 9
- 238000007639 printing Methods 0.000 claims description 83
- 239000000975 dye Substances 0.000 claims description 44
- 239000004744 fabric Substances 0.000 claims description 34
- 239000000049 pigment Substances 0.000 claims description 33
- 239000000463 material Substances 0.000 claims description 28
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 claims description 18
- 229940072056 alginate Drugs 0.000 claims description 18
- 239000000126 substance Substances 0.000 claims description 16
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 239000008135 aqueous vehicle Substances 0.000 claims description 12
- 239000006185 dispersion Substances 0.000 claims description 8
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical group [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 6
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- 150000002500 ions Chemical class 0.000 claims description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims description 4
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 claims description 4
- DHEQXMRUPNDRPG-UHFFFAOYSA-N strontium nitrate Chemical compound [Sr+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O DHEQXMRUPNDRPG-UHFFFAOYSA-N 0.000 claims description 4
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 claims description 4
- VNDYJBBGRKZCSX-UHFFFAOYSA-L zinc bromide Chemical compound Br[Zn]Br VNDYJBBGRKZCSX-UHFFFAOYSA-L 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- 239000001110 calcium chloride Substances 0.000 claims description 3
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 3
- 229910052744 lithium Inorganic materials 0.000 claims description 3
- BAVYZALUXZFZLV-UHFFFAOYSA-N mono-methylamine Natural products NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 210000002268 wool Anatomy 0.000 claims description 3
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 claims description 2
- OURWKHLDAVYMGO-UHFFFAOYSA-N 7-thiophen-2-ylpyrazolo[1,5-a]pyrimidine-3-carboxylic acid Chemical compound C=1C=NC2=C(C(=O)O)C=NN2C=1C1=CC=CS1 OURWKHLDAVYMGO-UHFFFAOYSA-N 0.000 claims description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 claims description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 claims description 2
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims description 2
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 2
- ITHZDDVSAWDQPZ-UHFFFAOYSA-L barium acetate Chemical compound [Ba+2].CC([O-])=O.CC([O-])=O ITHZDDVSAWDQPZ-UHFFFAOYSA-L 0.000 claims description 2
- NKQIMNKPSDEDMO-UHFFFAOYSA-L barium bromide Chemical compound [Br-].[Br-].[Ba+2] NKQIMNKPSDEDMO-UHFFFAOYSA-L 0.000 claims description 2
- 229910001620 barium bromide Inorganic materials 0.000 claims description 2
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 claims description 2
- 229910001626 barium chloride Inorganic materials 0.000 claims description 2
- 229940045511 barium chloride Drugs 0.000 claims description 2
- 229910001622 calcium bromide Inorganic materials 0.000 claims description 2
- WGEFECGEFUFIQW-UHFFFAOYSA-L calcium dibromide Chemical compound [Ca+2].[Br-].[Br-] WGEFECGEFUFIQW-UHFFFAOYSA-L 0.000 claims description 2
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 claims description 2
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 claims description 2
- 239000011654 magnesium acetate Substances 0.000 claims description 2
- 235000011285 magnesium acetate Nutrition 0.000 claims description 2
- 229940069446 magnesium acetate Drugs 0.000 claims description 2
- OTCKOJUMXQWKQG-UHFFFAOYSA-L magnesium bromide Chemical compound [Mg+2].[Br-].[Br-] OTCKOJUMXQWKQG-UHFFFAOYSA-L 0.000 claims description 2
- 229910001623 magnesium bromide Inorganic materials 0.000 claims description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 2
- RCIVOBGSMSSVTR-UHFFFAOYSA-L stannous sulfate Chemical compound [SnH2+2].[O-]S([O-])(=O)=O RCIVOBGSMSSVTR-UHFFFAOYSA-L 0.000 claims description 2
- YJPVTCSBVRMESK-UHFFFAOYSA-L strontium bromide Chemical compound [Br-].[Br-].[Sr+2] YJPVTCSBVRMESK-UHFFFAOYSA-L 0.000 claims description 2
- 229910001625 strontium bromide Inorganic materials 0.000 claims description 2
- 229940074155 strontium bromide Drugs 0.000 claims description 2
- 229910001631 strontium chloride Inorganic materials 0.000 claims description 2
- AHBGXTDRMVNFER-UHFFFAOYSA-L strontium dichloride Chemical compound [Cl-].[Cl-].[Sr+2] AHBGXTDRMVNFER-UHFFFAOYSA-L 0.000 claims description 2
- FAKFSJNVVCGEEI-UHFFFAOYSA-J tin(4+);disulfate Chemical compound [Sn+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O FAKFSJNVVCGEEI-UHFFFAOYSA-J 0.000 claims description 2
- 229910000375 tin(II) sulfate Inorganic materials 0.000 claims description 2
- 239000004246 zinc acetate Substances 0.000 claims description 2
- 229940102001 zinc bromide Drugs 0.000 claims description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims 2
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims 2
- 229910000906 Bronze Inorganic materials 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 239000010974 bronze Substances 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 claims 1
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 claims 1
- 239000011592 zinc chloride Substances 0.000 claims 1
- 235000005074 zinc chloride Nutrition 0.000 claims 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims 1
- 229910000165 zinc phosphate Inorganic materials 0.000 claims 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims 1
- 229960001763 zinc sulfate Drugs 0.000 claims 1
- 229910000368 zinc sulfate Inorganic materials 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 17
- 239000003086 colorant Substances 0.000 abstract description 8
- 239000004753 textile Substances 0.000 abstract description 8
- 239000000783 alginic acid Substances 0.000 abstract description 3
- 229960001126 alginic acid Drugs 0.000 abstract description 3
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 83
- 238000000034 method Methods 0.000 description 36
- 230000000740 bleeding effect Effects 0.000 description 30
- 239000007788 liquid Substances 0.000 description 30
- 238000007641 inkjet printing Methods 0.000 description 16
- 239000000203 mixture Substances 0.000 description 14
- 239000000835 fiber Substances 0.000 description 11
- 239000011159 matrix material Substances 0.000 description 8
- 239000002131 composite material Substances 0.000 description 7
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 125000000129 anionic group Chemical group 0.000 description 6
- 229920001778 nylon Polymers 0.000 description 6
- 239000004677 Nylon Substances 0.000 description 5
- 239000013543 active substance Substances 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 239000000728 ammonium alginate Substances 0.000 description 5
- 235000010407 ammonium alginate Nutrition 0.000 description 5
- KPGABFJTMYCRHJ-YZOKENDUSA-N ammonium alginate Chemical compound [NH4+].[NH4+].O1[C@@H](C([O-])=O)[C@@H](OC)[C@H](O)[C@H](O)[C@@H]1O[C@@H]1[C@@H](C([O-])=O)O[C@@H](O)[C@@H](O)[C@H]1O KPGABFJTMYCRHJ-YZOKENDUSA-N 0.000 description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 241000512259 Ascophyllum nodosum Species 0.000 description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 125000003368 amide group Chemical group 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 229920005604 random copolymer Polymers 0.000 description 4
- 238000009987 spinning Methods 0.000 description 4
- 239000003981 vehicle Substances 0.000 description 4
- PLXMOAALOJOTIY-FPTXNFDTSA-N Aesculin Natural products OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@H](O)[C@H]1Oc2cc3C=CC(=O)Oc3cc2O PLXMOAALOJOTIY-FPTXNFDTSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 159000000003 magnesium salts Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 230000000176 photostabilization Effects 0.000 description 3
- 239000001103 potassium chloride Substances 0.000 description 3
- 235000011164 potassium chloride Nutrition 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- AEMOLEFTQBMNLQ-BZINKQHNSA-N D-Guluronic Acid Chemical compound OC1O[C@H](C(O)=O)[C@H](O)[C@@H](O)[C@H]1O AEMOLEFTQBMNLQ-BZINKQHNSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 241001491708 Macrocystis Species 0.000 description 2
- 229920002292 Nylon 6 Polymers 0.000 description 2
- 229920002302 Nylon 6,6 Polymers 0.000 description 2
- 241000209094 Oryza Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 150000004781 alginic acids Chemical class 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000003139 biocide Substances 0.000 description 2
- 239000007767 bonding agent Substances 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- 150000007942 carboxylates Chemical group 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 2
- 230000002939 deleterious effect Effects 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000011859 microparticle Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000003021 water soluble solvent Substances 0.000 description 2
- XGJHPGPVESLKKD-UHFFFAOYSA-N 2-ethylbutane-1,4-diamine Chemical compound CCC(CN)CCN XGJHPGPVESLKKD-UHFFFAOYSA-N 0.000 description 1
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
- JZUHIOJYCPIVLQ-UHFFFAOYSA-N 2-methylpentane-1,5-diamine Chemical compound NCC(C)CCCN JZUHIOJYCPIVLQ-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 1
- 229920002284 Cellulose triacetate Polymers 0.000 description 1
- 241000024244 Chelis Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 241000243681 Eisenia bicyclis Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 108010022355 Fibroins Proteins 0.000 description 1
- IAJILQKETJEXLJ-SQOUGZDYSA-N L-guluronic acid Chemical group O=C[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O IAJILQKETJEXLJ-SQOUGZDYSA-N 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 101100496858 Mus musculus Colec12 gene Proteins 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- 229920003189 Nylon 4,6 Polymers 0.000 description 1
- 229920000305 Nylon 6,10 Polymers 0.000 description 1
- 239000004687 Nylon copolymer Substances 0.000 description 1
- 241000199919 Phaeophyceae Species 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229920004935 Trevira® Polymers 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- SMWDFEZZVXVKRB-UHFFFAOYSA-N anhydrous quinoline Natural products N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- AOJOEFVRHOZDFN-UHFFFAOYSA-N benzyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC1=CC=CC=C1 AOJOEFVRHOZDFN-UHFFFAOYSA-N 0.000 description 1
- AEMOLEFTQBMNLQ-UHFFFAOYSA-N beta-D-galactopyranuronic acid Natural products OC1OC(C(O)=O)C(O)C(O)C1O AEMOLEFTQBMNLQ-UHFFFAOYSA-N 0.000 description 1
- 238000005537 brownian motion Methods 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 235000019994 cava Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 229960003280 cupric chloride Drugs 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- AEMOLEFTQBMNLQ-YBSDWZGDSA-N d-mannuronic acid Chemical compound O[C@@H]1O[C@@H](C(O)=O)[C@H](O)[C@@H](O)[C@H]1O AEMOLEFTQBMNLQ-YBSDWZGDSA-N 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- GLUUGHFHXGJENI-UHFFFAOYSA-N diethylenediamine Natural products C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 239000000989 food dye Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000013028 medium composition Substances 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000000983 mordant dye Substances 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 150000002828 nitro derivatives Chemical class 0.000 description 1
- 150000002832 nitroso derivatives Chemical class 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 150000004897 thiazines Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229920000428 triblock copolymer Polymers 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 230000004304 visual acuity Effects 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/67341—Salts or hydroxides of elements different from the alkaline or alkaline-earth metals or with anions containing those elements
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
- D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
- D06P1/67358—Halides or oxyhalides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/30—Ink jet printing
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Coloring (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Ink Jet (AREA)
Abstract
An ink/media combination in which the ink comprises an aqueous medium, a colorant and an alginic acid salt selected from the group consisting of monovalent ion salts and organic amine salts and in which the media, preferably a textile, is treated with a specified water soluble salt of a metal having a valence of at least 2 produce printed chromatic image with improved bleed characteristics and sharper edges.
Description
The present invention relates to a kind of printing ink that in ink jet printing, uses and media combination, particularly produce the ink/media combination of colored and sharp-edged image.
The method that many production printed elements are arranged wherein imposes on printed liquid on the matrix to form image.Well known in the art, term " printed liquid " refers to be different from the tinting material in liquid medium of solid and dry colorant, comprises coating, toning agent, printing ink etc.Liquid medium can be organic solvent (" solvent base ") or water (" water base ").Tinting material can be dyestuff or pigment.General other component that exists in printed liquid depends on employed special printing technology.
Use the typical method of printed liquid to comprise photoengraving, the impression printing, the xeroprinting technology of use liquid toner, and ink jet printing, or the like.In these methods, can produce the polychrome printing product owing on matrix, once scan introducing three or four primaries printing ink, it is more and more universal that ink jet printing becomes, and uses especially for so-called " publication table (desk-stop publishing) ".Every kind of primary colors of printing process for other generally needs at least by printing press once.
Although be applicable to that the technical scope of producing printed element is wide, when wishing to obtain the polychrome element, produced a common problem, wherein a kind of printed liquid of color is placed on the printed liquid of other color of adjoining.Show at the interface of two kinds of printed liquid and mix or " bleeding " this problem, therefore the blur boundary between two kinds of printed liquid is unclear.Bleeding can form at the interface not to be wished the color that obtains and causes that in image resolving power, color separation, edge acuity and colour purity reduce simultaneously.The color of two kinds of liquid that adjoin (as black and yellow) contrast is big more, and the visible bleeding is serious more.(as when blueness and yellow are mixed the generation green) bleeding also is significant especially when two kinds of printing ink mix the generation secondary color.
Bleeding is the specific question in the ink jet printing, prints three or four primaries because employed low viscous relatively printing ink helps to spread with the ink jet printing function in (or near simultaneously) mode simultaneously.
People have recommended to prevent the several method of the printed liquid bleeding of adjoining.The most significant method is alternately to apply at interval two kinds of printed liquid, so that the mixing of two kinds of printed liquid does not take place and mixes up.But this method is not a method of dealing with problems, and the image resolution rate variance that produces.
The most normally used a kind of other method comprises up to first kind of printed liquid complete drying and just postpones to apply second kind of printed liquid.The shortcoming of this method is because not only its efficient is low but also do not have a special effect.For example, be that exsiccant also bleeding may take place even people observe first kind of printed liquid, it is believed that this is because the tinting material of first kind of printed liquid " dissolving again " is caused in the liquid medium of second kind of printed liquid.Therefore, even first kind of printed liquid is exsiccant, the component of first kind of printed liquid is easy more to be dissolved in the liquid medium, more bleeding may take place.This method significant disadvantage in ink jet printing is used is because it produces uncertain border at printed matter.
U.S. Pat 5091005 instructions add the generation that methane amide can reduce bleeding in some cases in printing ink.The method that also has another kind of control bleeding is to improve the seepage velocity that printed liquid enters matrix, but it has the shortcoming of himself.At first, it is confined in those printings of using special printed liquid/matrix binding substances application substantially.For example, need high absorption base control bleeding.The second, make it on the matrix not by the dissolving of the liquid medium of second printed liquid unless first printed liquid is attached to, otherwise bleeding still can occur.The 3rd, the known method that increases infiltration has the shortcoming that reduces the version quality.
U.S. Pat 5116409 discloses the combination of aforesaid method, discloses working concentration and has surpassed the zwitterionics or the non-ionic amphiphilic thing of corresponding micelle-forming concentration separately.It is generally acknowledged that the micellar that contains dye molecule forms can prevent in the various printing ink that dye molecule mixes.
The method of a kind of ink jet printing of U.S. Pat 5181045 instruction, wherein a kind of printing ink contain to become under certain PH condition and are difficult to dissolved dyestuff and another kind of printing ink and have and give the contained dyestuff of first printing ink insoluble pH value.But this method is subjected to limit as the intrinsic of the specific groups of the dyestuff of tinting material.In addition, this ink formulations is owing to need the PH buffer reagent also to be restricted, and for example, it has further limited the purposes of this method.
EP 0586079A1 discloses the method that is used to prevent the color bleeding between two kinds of different colours ink composites, and wherein first kind of printing ink is anionic and comprises a kind of tinting material that this tinting material contains one or more carboxyls and/or carboxylate groups; Contain precipitation agent with second kind of printing ink, this precipitation agent be used for first printing ink in tinting material carry out ionization and be cross-linked to form solid precipitation, to prevent bleeding between two kinds of ink composites.The polyvalent metal salt that uses as precipitation agent is also disclosed.Though this method provides effective bleeding control for two kinds of printing ink, when imposing on printed medium with two or more printing ink, this is a difficult problem in production polychrome printing product.In addition, this method do not allow in first printing ink and to select tinting material to be restricted flexibly owing to it, first kind of printing ink must have can with one or more carboxyls of precipitation agent ionization bonded and/or the carboxylate groups in second kind of printing ink.
Dyestuff is because the solubility of dyestuff in water as normally used tinting material in ink jet printing.In addition, dyestuff provides great-hearted colour on printing paper.But what lose sense is that many dyestuffs have bad photostabilization, water tolerance and anti-keeping property on paper.Therefore, the dye coloring agent is defective for the printing sample of filing preservation.
Usually have good photostabilization, water-proof pigment colorant and can be used as the alternative of dyestuff.But many pigment can not reach the tinctorial strength (i.e. " colourity ") same with dyestuff on printing paper.
A kind of method of improving face material colourity is to use a kind of vehicle (vehicle), this vehicle fixedly tinting material and do not allow pigment to diffuse into printed medium, for example fabric and paper on the paper surface.But this vehicle often can not penetrate medium and not be suitable for rapid drying or bleeding control.
Therefore, need a kind of improved method that is used to print the multicolor image that does not produce aforementioned bleeding problem.In addition, need such improving one's methods especially, this method goes up at medium (as fabric, common paper or the like) can obtain suitable color colourity with the dye coloring agent, provides simultaneously with pigment colorant to reach excellent water tolerance and photostabilization.Need especially a kind of like this ink/textile combination, it can reproduce and have sharp edge and a kind of color nonbleeding color picture information to another kind of color.
The invention provides a kind of jetted ink/media combination, it comprises:
(a) printing ink, it comprises:
(1) aqueous vehicle;
(2) tinting material; With
(3) 0.01-10% is selected from the alginate of monovalent ion salt and organic amine salt; With
(b) with valence state be the medium of the water-soluble salt processing formed of the metal of divalence at least.
This medium is fabric preferably.Monovalent ion in the monovalent ion salt of alginic acid is selected from sodium, potassium, lithium and ammonium.In alginate, also there are trace amount calcium and magnesium salts and do not have deleterious effects.
At least the metal of divalence is preferably selected from calcium, magnesium, aluminium, strontium, barium, zinc, Ya Xi, tin and copper.
Tinting material can be pigment or dyestuff.Ink/textile combination in press particularly has general purposes in the ink jet printing of using heat or bubble jet printer, piezoelectric type printing press, continuous flow printing press, air-brush (air brush) printing press or valve stream (valvejet) printing press is used.
The invention provides a kind of jetted ink/media combination, preferred jetted ink/textile combination can provide the printed image that has improved line marginal sharpness or reduce bleeding at the imaging region of medium.The main component of binding substances is the alginate in the printing ink and has the water-soluble salt of divalent metal (hereinafter "+divalent metal-salt ") at least in medium.Medium
Medium can be can quilt+divalent metal-salt handle or any material of coating since general+divalent metal-salt is coated on the medium its absorbed by medium or coated on medium be coating.The medium that is fit to comprises fabric, paper, transparent medium such as polyethylene terephthalate film etc.Medium is preferably fabric.The fabric that is fit to is selected from Mierocrystalline cellulose, fibroin (original text fibrion) hydroxy polymer, polymeric amide, polyester, proteinoid fiber polypropylene, polyacrylonitrile, cellulose triacetate and its mixture.Fabric preferably contains hydroxyl, amido, amido or carboxyl.
The example that contains the hydroxyl fabric includes, but are not limited to the fiber of cellulose, as short rayon fiber and cotton fibre.The fiber that contains amido or amido that is fit to comprises wool, synthesizing polyamides and silk.Tynex includes, but are not limited to from fiber nylon 6,6, nylon 6,12, nylon 6,10 and the nylon 4,6 of diamines-diacid polymkeric substance spinning.Fiber by the polymkeric substance of cyclic lactames or omega-amino-carboxylic acid spinning: nylon 6, nylon 7, Ni Long11, nylon 12; Fiber by the copolyamide spinning of particularly nylon 6,6 or nylon 6 is also included within this dyeing process.The copolyamide that relates to previously comprises at least about the nylon polymer (being nylon Unit 6,6) of 85% poly-(1,6-ethylidene hexanediamide) or at least about 85% poly-(ε-hexanamide) (being nylon Unit 6).The nylon copolymer that is fit to comprises at least about 85% nylon Unit 6,6, remaining be poly-(1,6-methylene radical isophthaloyl amine unit (being m-phthalic acid and 1, the polyamide products of 6-hexanediamine).The other multipolymer that uses in enforcement of the present invention comprises those with different diamine components.The diamines that is fit to includes, but are not limited to 1,6-hexanediamine, 2 methyl pentamethylenediamine, 2-ethyl-1,4-butanediamine, m-xylenedimaine and 1,4-two-aminomethyl hexanaphthene.
The example that contains the carboxyl fabric comprises, but be not limited to those based on polybutylene terephthalate, poly terephthalic acid (1,4-cyclohexylidene dimethylene) ester, the trevira of polyethylene terephthalate particularly, this fiber can be modified, for example, with printability preferably is purpose, and they can be by itself and other component (as other dicarboxylic acid and other glycol) copolycondensation modification.
The mixture of these fabrics also is that the present invention considers.The finished state that usually is used for implementing fabric of the present invention includes, but are not limited to fiber, yarn, nonwoven fabric and clothes, and as the furnishings of carpet and upholstery fabric.Be used for media processes+the divalent metal-salt
The salt that is fit to comprises calcium chloride, Calcium Bromide, calcium formiate, nitrocalcite, strontium chloride, strontium bromide, strontium nitrate, barium acetate, barium bromide, bariumchloride, barium propionate, cupric chloride, cupric nitrate, magnesium acetate, magnesium bromide, magnesium chloride, magnesium nitrate, sal epsom, zinc acetate, zinc bromide, stannous sulfate, tin sulphate, aluminum chloride, Tai-Ace S 150, aluminum nitrate etc.
Can be with ordinary skill coating+divalent metal-salt well known to those skilled in the art.The preferred padding method that uses.In the method, in the aqueous solution with medium such as fabric immersion+divalent metal-salt, from medium, remove excessive water with squeeze roll.When small-scale, medium is immersed salts solution and the excessive solution of drip-dry.Another kind method, general+divalent metal-salt is coated on the medium.Tackiness agent, compositions such as coating supporting agents can be used for forming coating composition.
The amount of employed salt is the 0.5-50% of medium-weight, preferably between 5-20%.Ink composite
Printing ink comprises aqueous vehicle, tinting material and alginate.When beginning contact+divalent metal-salt (with pending matrix), alginic acid combines with printing ink, thereby reduces bleeding.Printing ink also can contain various other additive well known in the art.Aqueous vehicle
Aqueous vehicle is the mixture of water or at least a water-miscible organic solvent and water.The needs of special applications are depended in the selection of suitable mixture, for example, and desirable surface tension and viscosity, selected tinting material, the time of drying of printing ink and matrix type to be printed.The representative instance of selectable water-miscible organic solvent is disclosed in U.S. Pat 5085698.Aqueous vehicle is preferably the mixture of polyvalent alcohol such as glycol ether and water.
If make the mixture of water and water-soluble solvent, water and remaining 70-5% that aqueous vehicle generally contains 30-about 95% are water-soluble solvents.Composition preferably contains the water that accounts for the about 60-95% of aqueous vehicle gross weight.
When selecting pigment dyestuff, the aqueous vehicle amount accounts for about 70-99.8% of total ink in the printing ink, is preferably 80-99.8%; When selecting inorganic ink, the aqueous vehicle amount accounts for about 25-99.8% of total ink in the printing ink, is preferably 70-99.8%.When selecting dyestuff, be 70-99.8%.Tinting material
Tinting material can be dyestuff and pigment.Especially preferably use pigment.Dyestuff
The term of Shi Yonging " dyestuff " refers to certain the soluble tinting material that a bit becomes in printing process in the present invention.This term comprises two kinds of dyestuffs: be soluble in aqueous vehicle and the aqueous vehicle under the normal recipe condition in be insoluble.Dyestuff refers to known dispersed dye in nearest classification.
The dyestuff of Shi Yonging comprises anionic dyestuff in the present invention, zwitterionic dyestuff and non-ionic dye.These dyestuffs are known in the art.Anionic dyestuff produces painted negatively charged ion in aqueous solution.General anionic dyestuff contains as the carboxylic acid or the sulfonic acid group of ion part and comprises all matching stains.
The kind of the most frequently used anionic dyestuff is a matching stain among the present invention, substantive dyestuff, food dye, mordant dye, and reactive dyestuffs.Anionic dyestuff is a nitroso compound, nitro-compound, azo-compound, third constellations compound, triaryl methane compounds, xanthenes compound, quinoline compound, thiazolium compounds, bifurcation piperazine compound, oxazines compound, thiazine compounds, amino ketone compound, anthraquinone compounds, indigoid compound and phthalocyanine compound.
The color of employed dyestuff and amount mainly change with the function of selecting in ink composite, and these selections depend primarily on people and wish color with the printed matter of this printing ink acquisition, the purity of dyestuff and intensity.The concentration of dyestuff is low can not to reach enough bright-colored good.High density may cause printing head performance to reduce or not satisfied dead color.The amount of dyestuff accounts for the 0.01-20% weight of total weight, preferred 0.05-8% weight, more preferably 1-5% weight.Pigment
The term of Shi Yonging " pigment " refers to keep the tinting material of crystalline or graininess in printing process in the present invention.Can select organic or inorganic pigment separately or with combining form.The functional group that pigment dyestuff contains (for example, acid, alkali, epoxy group(ing) and carboxyl) can react with the medium composition of selecting the superior in special applications.
Enough little of to allow printing ink unrestricted flow by ink-jet printing apparatus of pigment particle particularly typically has a diameter from the nozzle of 10-50 micron.Particle size is also influential to dispersing of pigments stability, and dispersion stabilization is very crucial in whole printing ink lifetime.The pedesis meeting of micro particles helps prevent the particulate sedimentation.People also wish to use micro particles to connect maximum colour intensity.The scope of used particle size is about 0.005-15 micron.The pigment particle size is preferably the 0.005-5 micron, more preferably the 0.01-0.3 micron.
Can use selected pigment with dry or wet form.Generally pigment is made water-bearing media and obtained product pigment with the water wet cake.In cake form, pigment is assembled unlike dried forms.Therefore, depolymerization the pigment of water wet-cake form does not need in the method for preparing printing ink with dried pigment.The dried pigment of spendable typical commercialization and the advantage of filter cake pigment are disclosed in U.S. Pat 5085698.
The trickle particulate of metal or metal oxide also can be used to implement the present invention.For example, metal or metal oxide are suitable for the preparation of magnetic jetted ink.Also can select trickle particulate oxide thing, as silicon-dioxide, aluminum oxide, titanium dioxide or the like.In addition, can select the metal particle of fine powder such as copper, iron, steel, aluminium and alloy to be used for special purpose.
When selecting pigment dyestuff, printing ink can contain the pigment up to about 30% weight, but is used for the hottest ink jet printing purposes, and pigment generally is in the scope of 0.1-15% weight (preferred 0.1-8% weight).If the selection mineral dye is compared with the similar printing ink that uses pigment dyestuff, printing ink tends to contain the pigment of higher weight per-cent, under certain conditions can be up to about 75%, and this is because mineral dye is compared with pigment dyestuff and generally had higher proportion.
Generally the pigment (dispersed dye) that uses as tinting material needs dispersion agent and tensio-active agent to help to keep insoluble tinting material in the water ballast toner.Polymeric dispersant is the dispersion agent, particularly topology convergence dispersion agent of the most normal selection.Polymkeric substance
In preferred embodiments, printing ink contains polymkeric substance.Polymkeric substance can be used as the dispersion agent of insoluble tinting material (being pigment or dispersed dye) or as tackiness agent.Polymkeric substance is structural polymer such as AB or BAB segmented copolymer (for example referring to U.S. Pat 5085698) preferably, ABC triblock copolymer (for example referring to european patent application 0556649A1), or branched polymer or graftomer (for example referring to U.S. Pat 5231131).
Though random copolymers can be used as dispersion agent and uses, they are effective not as structure copolymer aspect the stable pigments dispersiveness, are not preferred therefore.The random copolymer that uses has narrow may command molecule weight range, and this scope preferably has 1.3 polymolecularity, and preferred 1.2.These polymkeric substance in fact are not have the higher molecular weight material of stopping up a nozzle easily.Number-average molecular weight must be less than 10000 dalton, and is preferably less than 6000 dalton, more preferably excellent in 3000 dalton.Random copolymers contains hydrophobic and hydrophilic monomeric units.The random dispersion multipolymer of commodity stops up a nozzle easily.But by use group transfer polymerization technology, or other provides low dispersed method can obtain the molecular weight that needs.The example that is used for the hydrophobic monomer of random copolymers is a methyl methacrylate, n-BMA, methacrylic acid (2-ethylhexyl) ester, benzyl methacrylate, methacrylic acid (2-styroyl) ester and corresponding acrylate.The example of hydrophilic monomer is a methacrylic acid, vinylformic acid, [methyl] vinylformic acid dimethylamino ethyl ester and its salt.
The polymeric bonding agent additive particularly has crosslinkable part, is also included within this ink formulations as the polymeric bonding agent additive of acid, hydroxyl, amine etc.They can be various types of, as the emulsion of linearity, comprise the core shell and by the stable emulsion of structural polymer, water-sol or the like.Alginate
These alginate are univalent ion salt or organic amine salt.Univalent ion salt is selected from sodium, potassium, lithium and ammonium.The trace calcium salt and the magnesium salts that can exist in the alginate do not have deleterious effect.The organic amine that uses comprises methylamine, dimethylamine, Trimethylamine 99, ethamine, diethylamine and triethylamine.
Alginate are made by the natural product ammonium alginate.Ammonium alginate is prepared by brown seaweed by the extracting method of complexity.Several brown algas are arranged.Macrocystis pyrifere is the primary commercial source of ammonium alginate.Other kind is Ascophyllum nodosum, and kelp belongs to digitata, and kelp belongs to hyperborea, and kelp belongs to cava, Eisenia bicyclis.The ammonium alginate polymkeric substance is made with 60: 40 ratio by D-mannuronic acid and L-Guluronic acid residue.It is believed that this polymkeric substance contains three kinds of segments: polymannuronic acid segment, poly-Guluronic acid segment and alternate cells segment.The ratio of these parts of the ammonium alginate that is obtained by Macrocystis pyrifere is 40: 20: 40.It is believed that poly-Guluronic acid segment links to each other with divalence that is connected polymer chain or trivalent ion.The alginate of preferably making mainly are sodium salts, but also can contain a spot of sylvite, calcium salt and magnesium salts.Other component
According to special purposes, can use various additives to improve the character of ink composite.In polymeric dispersant, can use anion surfactant, nonionogenic tenside, or amphoterics.Inventory as the non-polymeric tensio-active agent of some polymeric surfactants is listed in 1990 McCutcheon'sFunctional Materials, North American Edition, Manufacturing Confection Publishing Co., Glen Roek, the 110-129 page or leaf among the NJ.The selection of special tensio-active agent greatly depends on the kind of specialty inks composition and fabric to be printed.Those skilled in the art can select the suitable tensio-active agent that uses at the specialty inks composition that is used for special matrix.In aqueous ink, the amount of the tensio-active agent of existence is the 0.01-5% of total weight, is preferably 0.2-2%.
Can comprise the solubility promoter that penetrates and suppress to stop up character that improves ink composite, in fact preferably use solubility promoter.This solubility promoter is known in this area.The representative solubility promoter of preferential use has been described in U.S. Pat 5272201.Can use biocides to suppress microorganism growth.The example of this biocides is Dowicides
(Dow Chemical, Midland, MI), Nuosept
(Huls America, Inc., Piscataway, NJ), Omidines
(Olin Corp., Cheshire, CT), Nopcocides
(Henkel Corp., Ambler, PA), Troysans
(Troy Chemical Corp., Newark, NJ) and Sodium Benzoate.Can comprise that also sequestrant such as EDTA eliminate the harmful effect of beavy metal impurity.Also can add other known additive such as wetting agent, viscosity modifier and other vinylformic acid or non-acrylate copolymer are to improve the various character of desirable ink composite.Ink property
The surface tension of printing ink and viscosity pole earth effect jet velocity, the gap length of ink droplet, the size of ink droplet and discharge stability.In the time of 20 ℃, be applicable to surface tension that the pigmented ink-jet printing ink of ink jet printing system has be about 20 dynes per centimeter-70 dynes per centimeter and, 30 dynes per centimeter-70 dynes per centimeter more preferably.In the time of 20 ℃, the viscosity of allowing is not more than 20cP and is preferably 1.0cP-10.0cP.The physical properties that printing ink has is suitable for injection conditions widely, be driving voltage and the pulse width that is used for hot ink-jet printing apparatus, be used for instant drippage (drop-on-demand) device or the driving frequency of continuous apparatus press member and the size and the shape of nozzle.Printing ink has fabulous long storage stability and does not stop up in ink-jet printing apparatus.Fixing printing ink rapidly and reliably on the medium of suitably handling.The printing ink image of printing has bright and bright-coloured tone.In addition, printing ink does not corrode the parts of the ink-jet printing apparatus that contacts with it, and essentially no smell and nontoxic.Purposes
With ordinary method printing ink is used for textiles, these ordinary methods are heat or bubble jet printer, piezoelectric type printing press, continuous flow printing press, air-brush (air brush) printing press or valve stream (valve jet) printing press.With printing ink on the textiles printing after, the textiles after the air-dry printing.
Embodiment
In the following embodiments, unless otherwise noted, umber and percentage are represented with weight.
Embodiment 1
Prepare two kinds of printing ink.Printing ink A comprise 1% sun blue 199 (Organic Dyestuffs Corp., EastProvidence, RI), 20% TriMethylolPropane(TMP) and the 0.25 sodiun alginate aqueous solution.Printing ink C is the comparative ink that has same combination except that alginate.Fabric is 90 gram/rice
2Shusu, represent with S.This fabric soaks with 5% calcium chloride solution and is dry.Fabric after the processing is represented with ' ST '.
With printing ink pack into the recycling HP 51626A print cartridge.(Hewlett-Packard Co., Palo Alto CA) is printed on monochromatic block on the fabric to use HP Desk Jet 550C printer.Measure the color chrominance C of each sample
*With luminance brightness L
*Use C
*And L
*Calculate color saturation s
*Maximum absorbance is measured Kubelka Munk k/s.Calculate colour intensity with the k/s of sample divided by the k/s of doped oil China ink/textile combination not, the definition of ' in a large number ' bleeding is that absorption along fiber blotting rope is above 1 millimeter of printing zone.' nothing ' bleeding refers to use 10 times of magnifying glasses not observe bleeding.' moderate ' bleeding is the intermediate degree of absorption between ' in a large number ' and ' nothing ' of the blotting rope of printing ink.The result represents in following table 1.
Table 1
| Sample # | Printing ink | Fabric | Bleeding | C * | ??s * | ?k/s | Colour intensity |
| ????1 | ????A | ????ST | Do not have | 45.4 | ?0.72 | ?2.80 | ?147％ |
| 2 (contrasts) | ????A | ????S | Moderate | 37.8 | ?0.55 | ?1.91 | ?101％ |
| 3 (contrasts) | ????C | ????ST | Moderate | 42.2 | ?0.66 | ?2.41 | ?127％ |
| 4 (contrasts) | ????C | ????S | In a large number | 37.0 | ?0.54 | ?1.90 | ?100％ |
Data show: alginate and the salt in the fabric in the printing ink that sample 1 comprises are in full force and effect, and it shows by alginate and salt binding thing and has substantially improved colour intensity.
The comparative example
Repeat embodiment 1, different is to use 5% sodium chloride solution or Klorvess Liquid to replace 5% calcium chloride solution to handle silk fabrics.The result represents in following table 2.
Table 2
| Sample # | Fabric treating | Weight increases (%) | Printing ink | ?C * | ?????s * | ????k/s | Colour intensity |
| ????1 | Do not have | ?0.0 | ?A | ?38.0 | ????0.56 | ????2.08 | ?100％ |
| ????2 | ?NaCl | ?12.2 | ?A | ?38.3 | ????0.57 | ????2.33 | ?112％ |
| ????3 | ?NaCl | ?12.5 | ?A | ?37.7 | ????0.56 | ????2.37 | ?114％ |
| ????4 | Do not have | ?0.0 | ?C | ?36.4 | ????0.54 | ????2.10 | ?100％ |
| ????5 | ?KCl | ?10.6 | ?C | ?37.4 | ????0.56 | ????2.18 | ?104％ |
| ????6 | ?KCl | ?10.7 | ?C | ?37.7 | ????0.56 | ????2.20 | ?105％ |
This embodiment shows: when using monovalent salt to handle in fabric or the printing ink no alginate, colour intensity is not influenced.
Embodiment 2
Repeat embodiment 1, use 107 gram/rice
2Spinning slim wool fabric (being expressed as ' OWO ') replaces silk.Fabric after the processing is expressed as ' OWTO '.The result represents in following table 3.
Table 3
| Sample # | Printing ink | Fabric | ????C * | ????s * | ????k/s | Colour intensity |
| ????1 | ????A | ?OWTO | ????39.3 | ????0.65 | ????3.61 | ????138％ |
| 2 (contrasts) | ????A | ?OWO | ????38.0 | ????0.61 | ????3.20 | ????122％ |
| 3 (contrasts) | ????C | ?OWTO | ????38.4 | ????0.64 | ????3.44 | ????131％ |
| 4 (contrasts) | ????C | ?OWO | ????35.5 | ????0.56 | ????2.62 | ????100％ |
The same with embodiment 1, this embodiment shows: it is essential obtaining high shade of color and colour intensity alginate and salt.
Embodiment 3
With silk sheet S (with use among the embodiment 1 identical) in the calcium chloride solution of different concns, soak.The weightening finish of each sheet is measured in dry back.Equally use printing ink A printing silk cloth sheet with embodiment 1.Equally measure bleeding and colour intensity with embodiment 1.The result represents in following table 4.
Table 4
*Sample is moist
| Sample # | ??CaCl 2???(％) | Weight increases (%) | Bleeding | ????C * | ???s * | ????k/s | Colour intensity |
| 1 (contrast) | Do not have | ????0.0 | In a large number | ???35.3 | ???0.51 | ????1.83 | ???100％ |
| ????2 | ????0.1 | ????0.75 | Moderate | ???40.5 | ???0.61 | ????2.78 | ???151％ |
| ????3 | ????0.5 | ????1.35 | Slightly | ???41.5 | ???0.62 | ????2.70 | ???147％ |
| ????4 | ????1.0 | ????2.86 | Slightly | ???43.0 | ???0.66 | ????3.00 | ???164％ |
| ????5 | ????5.0 | ????14.04 | Do not have | ???44.8 | ???0.70 | ????3.50 | ???191％ |
| ????6 | ????10.0 | ????28.27 | Do not have | ???43.9 | ???0.67 | ????3.17 | ???173％ |
| ????7 | ????20.0 | ????* | ????* | ?????* | ????* | ?????* | ????* |
Data show: be used to handle fabric to reduce the calcium chloride of bleeding and increase dye yield, the scope of its usage quantity is very wide.
Embodiment 4
With silk sheet S (with use among the embodiment 1 identical) in 5% various salts solutions, soak.The weightening finish of each sheet is measured in dry back.Equally use printing ink A printing silk cloth sheet with embodiment 1.Equally measure bleeding and colour intensity with embodiment 1.The result represents in following table 5.
Table 5
Data show: can use any divalent salts or trivalent salt to obtain having the printed images that increases colour intensity and reduce bleeding in the present invention.
| Sample # | Fabric treating (5% solution) | Weight increases (%) | Bleeding | ?C * | ??s * | ?k/s | Colour intensity |
| 1 (contrast) | Do not have | ?0.0 | In a large number | 39.4 | ?0.59 | ?2.29 | ?100％ |
| ????2 | ?MgCl 2 | ?9.6 | Do not have | 40.4 | ?0.63 | ?2.80 | ?122％ |
| ????3 | ?SrCl 2 | ?9.6 | Do not have | 44.9 | ?0.70 | ?3.80 | ?166％ |
| ????4 | ?BaCl 2 | ?12.3 | Do not have | 44.6 | ?0.70 | ?4.00 | ?175％ |
| ????5 | ?AINO 4 | ?9.2 | Do not have | 40.5 | ?0.62 | ?3.19 | ?139％ |
| ????6 | ?CaCl 2 | ?8.4 | Do not have | 44.4 | ?0.71 | ?3.89 | ?170％ |
Claims (10)
1. jetted ink/media combination, it comprises:
(a) printing ink, it comprises:
(1) aqueous vehicle;
(2) tinting material; With
(3) 0.01-10% is selected from the alginate of monovalent ion salt and organic amine salt; With
(b) with valence state be the medium of the water-soluble salt processing formed of the metal of divalence at least.
2. the ink/media combination of claim 1, its medium is a fabric.
3. the ink/media combination of claim 2, wherein alginate comprise monovalent ion salt, monovalent ion wherein is selected from sodium, potassium, lithium and ammonium.
4. the ink/media combination of claim 2, wherein alginate are organic amine salts, wherein organic peace is selected from methylamine, dimethylamine, Trimethylamine 99, ethamine, diethylamine and triethylamine.
5. the ink/media combination of claim 2, wherein water-soluble salt is selected from calcium chloride, Calcium Bromide, calcium formiate, nitrocalcite, strontium chloride, strontium bromide, strontium nitrate, barium acetate, barium bromide, bariumchloride, barium propionate, chlorine seven bronze medals, cupric nitrate, magnesium acetate, magnesium bromide, magnesium chloride, magnesium nitrate, sal epsom, zinc acetate, zinc bromide, zinc chloride, zinc nitrate, zinc phosphate, zinc sulfate, stannous sulfate, tin sulphate, aluminum chloride, Tai-Ace S 150 and aluminum nitrate.
6. the ink/media combination of claim 2, wherein printing ink also contains polymkeric substance.
7. the ink/media combination of claim 6, wherein polymkeric substance is a dispersion agent, and wherein tinting material is a pigment.
8. the ink/media combination of claim 6, wherein polymkeric substance is a structural polymer.
9. the ink/media combination of claim 2, wherein tinting material comprises dyestuff.
10. the ink/media combination of claim 2, wherein fabric is selected from silk fabric and wool fabric.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US54697A | 1997-12-30 | 1997-12-30 | |
| US09/000546 | 1997-12-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1227239A true CN1227239A (en) | 1999-09-01 |
Family
ID=21691978
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN98111670.1A Pending CN1227239A (en) | 1997-12-30 | 1998-12-30 | Ink/media combination |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP0928841A3 (en) |
| JP (1) | JPH11269785A (en) |
| CN (1) | CN1227239A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102775844A (en) * | 2011-05-10 | 2012-11-14 | 精工爱普生株式会社 | Ink jet recording method, recorded material and ink jet |
| CN104246062A (en) * | 2012-03-19 | 2014-12-24 | 尼纳纸业公司 | Kits and methods of treating a substrate prior to formation of an image thereon |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1309923B1 (en) | 1999-09-03 | 2002-02-05 | Ferrania Spa | RECEPTOR SHEET FOR INK JET PRINT INCLUDING GELATINE AND A METAL SALT. |
| DE102004041536A1 (en) * | 2004-08-27 | 2006-03-02 | Merck Patent Gmbh | Use of random copolymers |
| EP2411229B1 (en) * | 2009-03-24 | 2014-08-27 | E. I. du Pont de Nemours and Company | Pigmented inkjet ink comprising a bleed control agent |
| KR20210130729A (en) * | 2019-02-25 | 2021-11-01 | 닛뽄 가야쿠 가부시키가이샤 | Dispersion composition for ink and ink composition |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4222740A (en) * | 1979-03-05 | 1980-09-16 | Armstrong Cork Company | Coloration method for textiles |
| JPS6081379A (en) * | 1983-10-07 | 1985-05-09 | 東レ株式会社 | Dyeing method |
| US5108504A (en) * | 1991-07-29 | 1992-04-28 | Hewlett-Packard Company | High chroma color dye-set for use in ink-jet inks employing polysaccharide-containing vehicles |
| US5429860A (en) * | 1994-02-28 | 1995-07-04 | E. I. Du Pont De Nemours And Company | Reactive media-ink system for ink jet printing |
| JPH0952463A (en) * | 1995-08-10 | 1997-02-25 | Riso Kagaku Corp | Fixing method of printing water base ink and water base ink |
-
1998
- 1998-12-21 EP EP98124200A patent/EP0928841A3/en not_active Withdrawn
- 1998-12-28 JP JP10374746A patent/JPH11269785A/en active Pending
- 1998-12-30 CN CN98111670.1A patent/CN1227239A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102775844A (en) * | 2011-05-10 | 2012-11-14 | 精工爱普生株式会社 | Ink jet recording method, recorded material and ink jet |
| CN104246062A (en) * | 2012-03-19 | 2014-12-24 | 尼纳纸业公司 | Kits and methods of treating a substrate prior to formation of an image thereon |
| TWI593567B (en) * | 2012-03-19 | 2017-08-01 | 里拿紙業有限公司 | Kits and methods of treating a substrate prior to formation of an image thereon |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0928841A2 (en) | 1999-07-14 |
| JPH11269785A (en) | 1999-10-05 |
| EP0928841A3 (en) | 2001-02-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1114007C (en) | Ink jet printing of textiles | |
| JP5337351B2 (en) | Inkjet printing method and inkjet printed matter | |
| US8466213B2 (en) | White ink composition for ink jet textile printing and ink jet textile printing process | |
| US5396275A (en) | Method of ink jet printing on cloth | |
| JP5191227B2 (en) | Ink composition for inkjet printing and inkjet printing method | |
| DE69834599T2 (en) | Inkjet ink surfactant system for printing on hydrophobic surfaces | |
| WO2009084600A1 (en) | Treatment solution for ink jet textile printing, ink jet textile printing method, and product printed by ink jet textile printing | |
| JP2006152454A (en) | Pretreating liquid for inkjet printing and inkjet printing method using the same | |
| CN1205280C (en) | Ink/textile combination having improved durability | |
| JPH09137112A (en) | Water-base phase change ink composition and method for printing therewith | |
| CN1844275A (en) | Digital-printing ink-jet ink made of nano pigment and its making process | |
| JP2011105915A (en) | Ink composition for inkjet textile printing, method of inkjet textile printing, and inkjet textile printed material | |
| KR20040079309A (en) | The printing ink applying to various textile materials, the process for preparing it and the printing method using it | |
| JP2019524916A (en) | Aqueous inkjet ink containing non-water soluble additive | |
| CN1227239A (en) | Ink/media combination | |
| DE69918867T2 (en) | MACROPOROUS MATERIAL FOR INK RAY PRINTING PROCESS | |
| JP2014108417A (en) | Water-soluble surfactant composition, ink and paper coating agent | |
| JP3824181B2 (en) | Erasable colorant composition | |
| JPH0123507B2 (en) | ||
| JPH08319442A (en) | Ink jet composition and ink jet recording method | |
| JPH02112489A (en) | Production of cloth of ink jet | |
| JP3972391B2 (en) | Dye dispersion composition, ink-jet ink composition and dyeing method | |
| JPH0284593A (en) | Production of cloth for ink jet | |
| JPS6321990A (en) | Ink jet discharge style method | |
| WO2019087826A1 (en) | Ink composition and production method for ink composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |