CN1226181C - 产氢固体组合物、产氢方法、氢气发生器以及燃料电池 - Google Patents
产氢固体组合物、产氢方法、氢气发生器以及燃料电池 Download PDFInfo
- Publication number
- CN1226181C CN1226181C CNB031601839A CN03160183A CN1226181C CN 1226181 C CN1226181 C CN 1226181C CN B031601839 A CNB031601839 A CN B031601839A CN 03160183 A CN03160183 A CN 03160183A CN 1226181 C CN1226181 C CN 1226181C
- Authority
- CN
- China
- Prior art keywords
- hydrogen
- composition
- alkaline
- alkali metal
- strontium nitrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000001257 hydrogen Substances 0.000 title claims abstract description 66
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 66
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 46
- DHEQXMRUPNDRPG-UHFFFAOYSA-N strontium nitrate Chemical compound [Sr+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O DHEQXMRUPNDRPG-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 239000008247 solid mixture Substances 0.000 title abstract description 3
- 239000000203 mixture Substances 0.000 claims abstract description 61
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 23
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 22
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 21
- 150000001342 alkaline earth metals Chemical class 0.000 claims abstract description 21
- 238000002485 combustion reaction Methods 0.000 claims abstract description 12
- 239000007787 solid Substances 0.000 claims description 37
- 239000000446 fuel Substances 0.000 claims description 23
- 239000002131 composite material Substances 0.000 claims description 20
- 150000002431 hydrogen Chemical class 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 15
- 239000011777 magnesium Substances 0.000 claims description 8
- 239000012528 membrane Substances 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 5
- 230000001698 pyrogenic effect Effects 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 239000012448 Lithium borohydride Substances 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 238000000354 decomposition reaction Methods 0.000 claims description 2
- 239000012279 sodium borohydride Substances 0.000 claims description 2
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 abstract description 3
- 230000000977 initiatory effect Effects 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 8
- 238000004455 differential thermal analysis Methods 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- JOSWYUNQBRPBDN-UHFFFAOYSA-P ammonium dichromate Chemical compound [NH4+].[NH4+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O JOSWYUNQBRPBDN-UHFFFAOYSA-P 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- -1 polytetrafluoroethylene Polymers 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910013553 LiNO Inorganic materials 0.000 description 1
- 229910018487 Ni—Cr Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052987 metal hydride Inorganic materials 0.000 description 1
- 150000004681 metal hydrides Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/065—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents from a hydride
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B47/00—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase
- C06B47/02—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase the components comprising a binary propellant
- C06B47/10—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase the components comprising a binary propellant a component containing free boron, an organic borane or a binary compound of boron, except with oxygen
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06D—MEANS FOR GENERATING SMOKE OR MIST; GAS-ATTACK COMPOSITIONS; GENERATION OF GAS FOR BLASTING OR PROPULSION (CHEMICAL PART)
- C06D5/00—Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets
- C06D5/06—Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets by reaction of two or more solids
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/065—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants by dissolution of metals or alloys; by dehydriding metallic substances
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Fuel Cell (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
Description
NaBH4/Sr(NO3)2质量比 | 理论氢气产率(%) | 实验氢气产率(%) | |
实施例1 | 65/35 | 6.93 | 4.55 |
实施例2 | 60/40 | 6.39 | 5.90 |
实施例3 | 55/45 | 5.86 | 5.75 |
实施例4 | 50/50 | 5.33 | - |
实施例5 | 40/60 | 4.2 | - |
实施例6 | 30/70 | 3.0 | - |
实施例7 | 20/80 | 0.47 | - |
NaBH4/Sr(NO3)2质量比 | 燃烧温度(°K) | 氢气产率(%) | |
实施例8 | 70/30 | 265 | 11.20 |
实施例9 | 60/40 | 743 | 10.20 |
实施例10 | 50/50 | 1251 | 9.26 |
实施例11 | 40/60 | 1491 | 7.40 |
实施例12 | 30/70 | 1680 | 5.53 |
实施例13 | 20/80 | 2048 | 3.58 |
实施例14 | 10/90 | 2392 | 0.02 |
Mg(BH4)2/Sr(NO3)2质量比 | 燃烧温度(°K) | 氢气产率(%) | |
实施例15 | 80/20 | 571 | 11.95 |
实施例16 | 70/30 | 1079 | 10.45 |
实施例17 | 60/40 | 1789 | 8.93 |
实施例18 | 50/50 | 1947 | 7.16 |
实施例19 | 40/60 | 2049 | 5.51 |
实施例20 | 30/70 | 2145 | 4.04 |
实施例21 | 20/80 | 2673 | 1.74 |
实施例22 | 10/90 | 2477 | 0.01 |
Claims (11)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0212313A FR2845376B1 (fr) | 2002-10-04 | 2002-10-04 | Compositions solides generatrices d'hydrogene par combustion comprenant un borohydrure alcalin ou alcalino-terreux et du nitrate de strontium sr (no3)2 |
FR0212313 | 2002-10-04 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1496953A CN1496953A (zh) | 2004-05-19 |
CN1226181C true CN1226181C (zh) | 2005-11-09 |
Family
ID=31985439
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB031601839A Expired - Fee Related CN1226181C (zh) | 2002-10-04 | 2003-09-29 | 产氢固体组合物、产氢方法、氢气发生器以及燃料电池 |
Country Status (5)
Country | Link |
---|---|
US (1) | US20040065395A1 (zh) |
EP (1) | EP1405823A3 (zh) |
JP (1) | JP4361773B2 (zh) |
CN (1) | CN1226181C (zh) |
FR (1) | FR2845376B1 (zh) |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2857358B1 (fr) * | 2003-07-10 | 2005-10-14 | Snpe Materiaux Energetiques | Composition solides generatrices d'hydrogene par combustion comprenant un borohydrure de magnesium et un oxydant de la famille des dinitramines |
JP2007522916A (ja) * | 2003-12-05 | 2007-08-16 | エンサイン−ビツクフオード・エアロスペース・アンド・デフエンス・カンパニー | ガス発生構造とガス発生法及び発生ガスを用いる動力源 |
US20050158609A1 (en) * | 2004-01-16 | 2005-07-21 | Gennadi Finkelshtain | Hydride-based fuel cell designed for the elimination of hydrogen formed therein |
US20050260481A1 (en) * | 2004-05-20 | 2005-11-24 | Gennadi Finkelshtain | Disposable fuel cell with and without cartridge and method of making and using the fuel cell and cartridge |
US20060057435A1 (en) * | 2004-09-15 | 2006-03-16 | Medis Technologies Ltd | Method and apparatus for preventing fuel decomposition in a direct liquid fuel cell |
US20060210470A1 (en) * | 2005-03-18 | 2006-09-21 | Purdue Research Foundation | System and method for generating hydrogen |
CN100339339C (zh) * | 2005-03-31 | 2007-09-26 | 张根发 | 一种产气药剂的模塑制品及其制备方法 |
WO2006134419A2 (en) * | 2005-06-15 | 2006-12-21 | More Energy Ltd. | Hydride-based fuel cell for the elimination of hydrogen therein |
US7381390B2 (en) * | 2005-12-19 | 2008-06-03 | General Electric Company | Method for manufacturing magnesium borohydride |
US20080035252A1 (en) * | 2006-02-27 | 2008-02-14 | Mallery Carl F | Solid hydrogen fuel elements and methods of making the same |
US20070297964A1 (en) * | 2006-06-21 | 2007-12-27 | Grigorii Lev Soloveichik | Compositions comprising magnesium borohydride and magnesium hydridoborohydride and method for manufacturing the same |
US7906092B2 (en) * | 2006-06-21 | 2011-03-15 | General Electric Company | Methods for preparing compositions which comprise magnesium borohydride, and related materials |
FR2906805B1 (fr) * | 2006-10-09 | 2009-01-23 | Snpe Materiaux Energetiques Sa | Procede de pyrotechnique de mise a disposition, a la demande d'hydrogene non pressurise et dispositif associe |
FR2918661B1 (fr) * | 2007-07-13 | 2012-02-03 | Snpe Materiaux Energetiques | Composes solides generateurs d'hydrogene et procede de generation d'hydrogene |
JP5265158B2 (ja) * | 2007-09-05 | 2013-08-14 | キネテイツク・リミテツド | 水素発生器及び燃料スティック |
US20090078345A1 (en) * | 2007-09-25 | 2009-03-26 | Ensign-Bickford Aerospace & Defense Company | Heat generating structures |
GB2465531B (en) | 2007-10-16 | 2010-12-15 | Qinetiq Ltd | Improvements in hydrogen generators |
FR2999167B1 (fr) | 2012-12-12 | 2014-12-26 | Herakles | Procede pyrotechnique de mise a disposition d'hydrogene de tres grande purete et dispositif associe |
FR2999168B1 (fr) | 2012-12-12 | 2014-12-26 | Herakles | Procede pyrotechnique de mise a disposition d'hydrogene de tres grande purete et dispositif associe |
FR3003092B1 (fr) * | 2013-03-05 | 2015-04-03 | Herakles | Procede et dispositif d'alimentation d'une pile a combustible |
FR3002977B1 (fr) * | 2013-03-05 | 2015-04-03 | Herakles | Procede de fonctionnement d'une machine thermique ditherme a cycle ouvert avec les gaz de combustion d'au moins un chargement pyrotechnique solide |
FR3008969B1 (fr) * | 2013-07-23 | 2016-12-23 | Herakles | Procede de generation d'hydrogene par combustion auto-entretenue ou par decomposition d'un produit solide et dispositif |
FR3027459B1 (fr) | 2014-10-21 | 2019-06-21 | Snecma | Procede de production d'electricite par une pile a combustible ; dispositif associe |
CN107149167A (zh) * | 2017-04-28 | 2017-09-12 | 南京理工大学 | 卷烟用中低温含能热源及其制备方法 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3126305A (en) * | 1964-03-24 | Ignition compositions comprising boron containing salts | ||
BE636879A (zh) * | 1957-10-22 | |||
US3066009A (en) * | 1959-01-15 | 1962-11-27 | Olin Mathieson | Preparation of decaboranyl sodium |
US3734863A (en) * | 1971-06-11 | 1973-05-22 | Us Navy | Hydrogen generating compositions |
US3977990A (en) * | 1974-10-30 | 1976-08-31 | The United States Of America As Represented By The Secretary Of The Navy | Controlled generation of cool hydrogen from solid mixtures |
US3948699A (en) * | 1974-11-08 | 1976-04-06 | The United States Of America As Represented By The Secretary Of The Army | Hydrogen gas generators for use in chemical lasers |
US4061512A (en) * | 1976-03-22 | 1977-12-06 | The United States Of America As Represented By The Secretary Of The Army | Solid propellants for generating hydrogen |
US4302259A (en) * | 1979-10-31 | 1981-11-24 | The United States Of America As Represented By The Secretary Of The Army | MgH2 and Sr(NO3)2 pyrotechnic composition |
US4468263A (en) * | 1982-12-20 | 1984-08-28 | The United States Of America As Represented By The Secretary Of The Army | Solid propellant hydrogen generator |
US4673528A (en) * | 1985-09-30 | 1987-06-16 | The United States Of America As Represented By The Secretary Of The Army | Solid H2 /D2 gas generators |
US5608182A (en) * | 1996-04-22 | 1997-03-04 | The United States Of America As Represented By The Secretary Of The Army | Fuel gas generator for airbreathing propulsion systems |
US6165295A (en) * | 1999-11-23 | 2000-12-26 | Wagaman; Kerry L. | Gas-generating liquid compositions (PERSOL 1) |
GB0021386D0 (en) * | 2000-09-01 | 2000-10-18 | Secr Defence | Hydrogen source |
-
2002
- 2002-10-04 FR FR0212313A patent/FR2845376B1/fr not_active Expired - Lifetime
-
2003
- 2003-09-11 US US10/659,306 patent/US20040065395A1/en not_active Abandoned
- 2003-09-11 EP EP03292233A patent/EP1405823A3/fr not_active Withdrawn
- 2003-09-29 CN CNB031601839A patent/CN1226181C/zh not_active Expired - Fee Related
- 2003-10-06 JP JP2003347143A patent/JP4361773B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US20040065395A1 (en) | 2004-04-08 |
FR2845376A1 (fr) | 2004-04-09 |
EP1405823A2 (fr) | 2004-04-07 |
CN1496953A (zh) | 2004-05-19 |
JP4361773B2 (ja) | 2009-11-11 |
EP1405823A3 (fr) | 2010-10-06 |
FR2845376B1 (fr) | 2006-03-24 |
JP2004123532A (ja) | 2004-04-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1226181C (zh) | 产氢固体组合物、产氢方法、氢气发生器以及燃料电池 | |
CN1496952A (zh) | 包含氢硼化物和基于高氯酸盐的氧化性盐的产生氢气的固体组合物 | |
US20030051785A1 (en) | Solid compositions generating hydrogen by combustion, comprising an alkali metal borohydride and an ammonium salt | |
US2928891A (en) | Double skeleton catalyst electrode | |
US7641889B1 (en) | Hydrogen generator | |
CN1871728A (zh) | 电极、其制造方法、金属-空气燃料电池和金属氢化物电池 | |
CN113394410B (zh) | 一种锚定NiPd/Ni的氮掺杂碳纳米片复合材料及其制备方法和应用 | |
CN111250076A (zh) | 一种纳米铋催化剂及其制备方法和应用 | |
CN113054210A (zh) | 一种氧还原铁–氮化四铁@单原子铁和氮共掺杂无定形碳-炭黑复合催化剂及其制备和应用 | |
CN111690944A (zh) | 一种高效的有机电化学合成氨反应体系及其应用 | |
CN101885476A (zh) | 一种氮化钴化合物及其制备方法,以及一种甲醇燃料电池催化剂及其制备方法 | |
CN111573621B (zh) | 一种水解制氢的方法 | |
CN108766772A (zh) | 一种碳包覆磷酸钛钠及其制备和应用 | |
CN1529373A (zh) | 锌空气电池空气扩散电极的造孔方法及其造孔剂 | |
CN1723580A (zh) | 含水电极粘合剂和电极及包括其的燃料电池 | |
CN114944480B (zh) | 一种蜂窝状多孔锡碳复合材料的制备方法 | |
CN114420927B (zh) | 一种负极材料及其制备方法和负极片 | |
EP1496035B1 (fr) | Compositions solides génératrices d'hydrogène par combustion comprenant un borohydrure de magnésium et un oxydant de la famille des dinitramines | |
CN114380281B (zh) | 一种磷酸铁锂材料及其制备方法 | |
Wei et al. | Cathodes with MnO 2 catalysts for metal fuel battery | |
CN113562694B (zh) | 基于镁基复合材料的水解制氢方法 | |
CN102270777A (zh) | 锌空气燃料电池的氧化锌的还原方法 | |
CN1627551A (zh) | 高能碱性一次电池正极材料及其正极的制备方法 | |
CN1496590A (zh) | 发电装置 | |
CN1072845C (zh) | 镍——金属氢化物蓄电池氢化物负极的制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
ASS | Succession or assignment of patent right |
Owner name: SNPE MATERIAUX ENERGETIQUES Free format text: FORMER OWNER: SNPC Effective date: 20040917 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20040917 Address after: Paris France Applicant after: SNPE giant material Co. Address before: Paris France Applicant before: SNPE |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: SME CORPORATION Free format text: FORMER OWNER: SNPE Effective date: 20130701 Owner name: HERAKLES Free format text: FORMER OWNER: SME CORPORATION Effective date: 20130701 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20130701 Address after: France Le Aya Jan Patentee after: Hai Ruikelizi Address before: Paris France Patentee before: SME Effective date of registration: 20130701 Address after: Paris France Patentee after: SME Address before: Paris France Patentee before: SNPE giant material Co. |
|
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20051109 Termination date: 20170929 |
|
CF01 | Termination of patent right due to non-payment of annual fee |