CN1214049C - 制备乙烯/烯烃共聚物的方法 - Google Patents
制备乙烯/烯烃共聚物的方法 Download PDFInfo
- Publication number
- CN1214049C CN1214049C CN99816849.1A CN99816849A CN1214049C CN 1214049 C CN1214049 C CN 1214049C CN 99816849 A CN99816849 A CN 99816849A CN 1214049 C CN1214049 C CN 1214049C
- Authority
- CN
- China
- Prior art keywords
- properties
- ether
- correcting agent
- methyl
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/14—Monomers containing five or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13798199P | 1999-06-07 | 1999-06-07 | |
| US60/137,981 | 1999-06-07 | ||
| US09/387,363 US6417298B1 (en) | 1999-06-07 | 1999-08-31 | Process for producing ethylene/olefin interpolymers |
| US09/387,363 | 1999-08-31 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1367798A CN1367798A (zh) | 2002-09-04 |
| CN1214049C true CN1214049C (zh) | 2005-08-10 |
Family
ID=26835759
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN99816849.1A Expired - Lifetime CN1214049C (zh) | 1999-06-07 | 1999-10-14 | 制备乙烯/烯烃共聚物的方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6417298B1 (https=) |
| EP (1) | EP1192196B1 (https=) |
| JP (1) | JP2003501527A (https=) |
| CN (1) | CN1214049C (https=) |
| BR (1) | BR9917352B1 (https=) |
| CA (1) | CA2375738A1 (https=) |
| DE (1) | DE69926150T2 (https=) |
| MX (1) | MXPA01012597A (https=) |
| WO (1) | WO2000075204A1 (https=) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2377259A1 (en) * | 1999-06-25 | 2001-01-04 | Randal Ray Ford | Process for the polymerization of olefins; polyolefins, and films and articles produced therefrom |
| RU2330862C2 (ru) * | 2001-09-14 | 2008-08-10 | ИНЕОС ЮЭсЭй ЭлЭлСи | Латентные металлоценовые каталитические системы для полимеризации олефинов |
| US6998449B2 (en) * | 2001-09-14 | 2006-02-14 | Bp Corporation North America | Latent metallocene catalyst systems for olefin polymerization |
| EP1348719B2 (en) † | 2002-03-25 | 2010-11-17 | Mitsui Chemicals, Inc. | Process for producing polyolefin |
| US6630547B1 (en) * | 2002-06-11 | 2003-10-07 | Equistar Chemicals, Lp | Use of silanes to control molecular weight in olefin polymerizations |
| JP5095909B2 (ja) * | 2003-06-24 | 2012-12-12 | ローム・アンド・ハース・エレクトロニック・マテリアルズ,エル.エル.シー. | 触媒組成物および析出方法 |
| US7053158B2 (en) * | 2003-09-22 | 2006-05-30 | Agency For Science, Technology And Research | Carborane trianion based catalyst |
| US6828395B1 (en) | 2003-10-15 | 2004-12-07 | Univation Technologies, Llc | Polymerization process and control of polymer composition properties |
| US7238756B2 (en) * | 2003-10-15 | 2007-07-03 | Univation Technologies, Llc | Polymerization process and control of polymer composition properties |
| RU2331653C2 (ru) * | 2003-10-15 | 2008-08-20 | Юнивейшн Технолоджиз, Ллс | Способ полимеризации и регулирование характеристик полимерной композиции |
| US7834092B2 (en) | 2003-12-12 | 2010-11-16 | E. I. Du Pont De Nemours And Company | Article comprising poly(hydroxyalkanoic acid) |
| US7754830B2 (en) | 2004-05-20 | 2010-07-13 | Univation Technologies, Llc | Polymerization reaction monitoring with determination of induced condensing agent concentration for preventing discontinuity events |
| AU2005245921B2 (en) * | 2004-05-20 | 2007-11-15 | Univation Technologies, Llc | Gas olefin polymerization process |
| US7683140B2 (en) * | 2004-05-20 | 2010-03-23 | Univation Technologies, Llc | Method for determining temperature value indicative of resin stickiness from data generated by polymerization reaction monitoring |
| CN101511877B (zh) * | 2006-09-07 | 2012-09-05 | 尤尼威蒂恩技术有限责任公司 | 由聚合反应监测产生的数据确定指示树脂粘附的温度值的方法 |
| ES2405556T3 (es) * | 2006-09-07 | 2013-05-31 | Univation Technologies, Llc | Métodos para determinación en línea del grado de pegajosidad de una resina utilizando un modelo para depresión de la temperatura de iniciación de la fusión |
| CN102007182B (zh) * | 2008-04-16 | 2013-03-27 | 纳幕尔杜邦公司 | 由乙烯丙烯酸烷基酯韧化的聚(羟基链烷酸)组合物 |
| US7960486B2 (en) * | 2008-08-08 | 2011-06-14 | Sumitomo Chemical Company, Limited | Process for producing olefin polymer |
| JP5688236B2 (ja) * | 2010-05-25 | 2015-03-25 | 出光興産株式会社 | 触媒組成物及び当該触媒組成物を用いるオレフィン系重合体の製造方法 |
| CN102432640B (zh) * | 2011-10-09 | 2014-01-08 | 复旦大学 | 含碳硼烷脒结构的半夹心铱、铑化合物及其制备方法和应用 |
| EP2855150B1 (en) * | 2012-06-05 | 2016-09-14 | Dow Global Technologies LLC | Films containing functional ethylene-based polymer compositions |
| WO2013186025A1 (en) * | 2012-06-14 | 2013-12-19 | Saudi Basic Industries Corporation | Gas phase polymerisation of ethylene |
| US10662262B2 (en) * | 2016-12-02 | 2020-05-26 | Exxonmobil Chemical Patents, Inc. | Olefin polymerization catalyst systems and methods for making the same |
| WO2018098796A1 (en) * | 2016-12-02 | 2018-06-07 | Dow Global Technologies Llc | Process to form a composition containing functionalized and un-functionalized ethylene-based polymers |
| JP2022158974A (ja) * | 2021-03-31 | 2022-10-17 | 三井化学株式会社 | オレフィン重合体の製造方法 |
| JP2022159145A (ja) * | 2021-03-31 | 2022-10-17 | 三井化学株式会社 | オレフィン重合体の製造方法 |
Family Cites Families (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4076698A (en) | 1956-03-01 | 1978-02-28 | E. I. Du Pont De Nemours And Company | Hydrocarbon interpolymer compositions |
| BE559727A (https=) | 1956-08-02 | |||
| US4003712A (en) | 1970-07-29 | 1977-01-18 | Union Carbide Corporation | Fluidized bed reactor |
| NO136797C (no) | 1970-09-25 | 1977-11-09 | Union Carbide Corp | Fremgangsm}te for polymerisering av etylen med modifisert katalysator |
| US4012573A (en) | 1970-10-09 | 1977-03-15 | Basf Aktiengesellschaft | Method of removing heat from polymerization reactions of monomers in the gas phase |
| US3709853A (en) | 1971-04-29 | 1973-01-09 | Union Carbide Corp | Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts |
| US4011382A (en) | 1975-03-10 | 1977-03-08 | Union Carbide Corporation | Preparation of low and medium density ethylene polymer in fluid bed reactor |
| US4302566A (en) | 1978-03-31 | 1981-11-24 | Union Carbide Corporation | Preparation of ethylene copolymers in fluid bed reactor |
| US4543399A (en) | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
| US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
| US4564647A (en) | 1983-11-14 | 1986-01-14 | Idemitsu Kosan Company Limited | Process for the production of polyethylene compositions |
| US4752597A (en) | 1985-12-12 | 1988-06-21 | Exxon Chemical Patents Inc. | New polymerization catalyst |
| FR2618786B1 (fr) | 1987-07-31 | 1989-12-01 | Bp Chimie Sa | Procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise |
| US5227440A (en) | 1989-09-13 | 1993-07-13 | Exxon Chemical Patents Inc. | Mono-Cp heteroatom containing Group IVB transition metal complexes with MAO: supported catalysts for olefin polymerization |
| US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| FR2656314B1 (fr) * | 1989-12-22 | 1992-04-17 | Bp Chemicals Snc | Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines. |
| US5466766A (en) | 1991-05-09 | 1995-11-14 | Phillips Petroleum Company | Metallocenes and processes therefor and therewith |
| EP0515132B2 (en) | 1991-05-20 | 2003-08-27 | Mitsui Chemicals, Inc. | Olefin polymerization catalyst and olefin polymerization |
| DE69224600T2 (de) | 1991-11-12 | 1998-08-27 | Nippon Oil Co Ltd | Katalysatorbestandteile für Olefinpolymerisation |
| US5352749A (en) | 1992-03-19 | 1994-10-04 | Exxon Chemical Patents, Inc. | Process for polymerizing monomers in fluidized beds |
| EP0564211A3 (en) | 1992-04-03 | 1993-10-20 | BP Chemicals Limited | Process for the preparation of a ziegler-natta catalyst |
| EP0578838A1 (en) | 1992-04-29 | 1994-01-19 | Hoechst Aktiengesellschaft | Olefin polymerization catalyst, process for its preparation, and its use |
| US5350723A (en) | 1992-05-15 | 1994-09-27 | The Dow Chemical Company | Process for preparation of monocyclopentadienyl metal complex compounds and method of use |
| JP3202349B2 (ja) | 1992-09-22 | 2001-08-27 | 三菱化学株式会社 | 触媒組成物およびそれを用いるオレフィンの重合法 |
| US5332706A (en) | 1992-12-28 | 1994-07-26 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
| ZA943399B (en) | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
| EP0630910A1 (en) | 1993-06-28 | 1994-12-28 | Union Carbide Chemicals & Plastics Technology Corporation | Use of Lewis Bases for activity reduction in metallocene catalyzed olefin polymerization reactions |
| FR2707651B1 (fr) | 1993-07-13 | 1995-08-25 | Bp Chemicals Snc | Procédé pour augmenter l'activité d'un catalyseur de type Ziegler-Natta. |
| WO1996000245A1 (en) | 1994-06-24 | 1996-01-04 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
| US5468702A (en) | 1994-07-07 | 1995-11-21 | Exxon Chemical Patents Inc. | Method for making a catalyst system |
| JP3517471B2 (ja) | 1994-12-28 | 2004-04-12 | 三井化学株式会社 | 環状オレフィン共重合体の製造方法 |
| US6114477A (en) * | 1996-02-09 | 2000-09-05 | Exxon Chemical Patents Inc. | Polymerization process |
| CZ170897A3 (en) | 1996-06-06 | 1997-12-17 | Union Carbide Chem Plastic | Control of static charge in the course of polymerization process during which metallocene catalyst is used |
| JP2000044613A (ja) * | 1998-07-31 | 2000-02-15 | Ube Ind Ltd | オレフィンの気相重合方法 |
| JP2000281707A (ja) * | 1999-03-30 | 2000-10-10 | Sumitomo Chem Co Ltd | オレフィン重合用触媒、およびオレフィン重合体の製造方法 |
| US6417299B1 (en) * | 1999-06-07 | 2002-07-09 | Eastman Chemical Company | Process for producing ethylene/olefin interpolymers |
-
1999
- 1999-08-31 US US09/387,363 patent/US6417298B1/en not_active Expired - Lifetime
- 1999-10-14 CA CA002375738A patent/CA2375738A1/en not_active Abandoned
- 1999-10-14 EP EP99952018A patent/EP1192196B1/en not_active Expired - Lifetime
- 1999-10-14 JP JP2001502484A patent/JP2003501527A/ja active Pending
- 1999-10-14 DE DE69926150T patent/DE69926150T2/de not_active Expired - Lifetime
- 1999-10-14 CN CN99816849.1A patent/CN1214049C/zh not_active Expired - Lifetime
- 1999-10-14 MX MXPA01012597A patent/MXPA01012597A/es unknown
- 1999-10-14 BR BRPI9917352-2A patent/BR9917352B1/pt not_active IP Right Cessation
- 1999-10-14 WO PCT/US1999/024234 patent/WO2000075204A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| WO2000075204A1 (en) | 2000-12-14 |
| JP2003501527A (ja) | 2003-01-14 |
| MXPA01012597A (es) | 2002-04-10 |
| BR9917352B1 (pt) | 2010-05-18 |
| EP1192196B1 (en) | 2005-07-13 |
| DE69926150T2 (de) | 2005-12-22 |
| CA2375738A1 (en) | 2000-12-14 |
| EP1192196A1 (en) | 2002-04-03 |
| CN1367798A (zh) | 2002-09-04 |
| BR9917352A (pt) | 2002-02-26 |
| US6417298B1 (en) | 2002-07-09 |
| DE69926150D1 (de) | 2005-08-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: WESTLAKE LONGVIEW CORPORATION Free format text: FORMER OWNER: YISIMAN CHEMICAL COMPANY Effective date: 20070511 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20070511 Address after: American Texas Patentee after: Westlake Longview Corp. Address before: Tennessee Patentee before: Eastman Chem Co. |
|
| CX01 | Expiry of patent term |
Granted publication date: 20050810 |
|
| CX01 | Expiry of patent term |