CN1210165A - Process of dual mercerized and dual singered cotton fabrics - Google Patents
Process of dual mercerized and dual singered cotton fabrics Download PDFInfo
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- CN1210165A CN1210165A CN 97106067 CN97106067A CN1210165A CN 1210165 A CN1210165 A CN 1210165A CN 97106067 CN97106067 CN 97106067 CN 97106067 A CN97106067 A CN 97106067A CN 1210165 A CN1210165 A CN 1210165A
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Abstract
A technology for making cotton knitwear includes sequentially such technological steps as singeing yarns, mercerizing yarns, dyeing yarns, knitting, singeing greige cloth, softening greige cloth, mercerizing greige cloth and shape fixation. The finished knitwear features improved lustre, softness and washing shrinkage.
Description
The present invention relates to a kind of preparation technology of cotton knitwear, belong to textile technology field.
In recent years, the performance of cotton products is familiar with by people, still, the low in glossiness of cotton products, flexibility is poor, and feel is bad, and the big grade of washing shrinkage has limited its development, and this just need adjust, improve performance, to satisfy various requirement.At present, yarn mercerising, yarn singeing, grey cloth mercerising, grey cloth are singed as the existing report of single technical matters, but only limit to research, test, single process operation stage, far can not adapt to large-scale production, especially fairly large production.
The object of the present invention is to provide the two preparation technologies that singe of mariages light of cotton knitwear a kind of maturation, that can adapt to large-scale production.
Purpose of the present invention can be realized by following scheme:
The two preparation technologies that singe of the mariages light of described cotton knitwear, comprise mercerising, the operation of singing, it is characterized in that its concrete processing step is followed successively by: yarn singeing, yarn mercerising, yarn dyeing, braiding, grey cloth are singed, grey cloth softness, grey cloth mercerising, typing, at last cotton knitwear.
The translational speed of yarn is 650~850m/min during yarn singeing, and optimum value is 800m/min, and the tension force of yarn is 1.5~2Kg/cm
2Yarn passes through burned flame fast, removes the filoplume of yam surface, reaches the effect of yarn any surface finish, and its cleanliness factor can reach more than 80%.
The yarn mercerising mainly is the glossiness that increases yarn, improves affinity and the intensity of yarn to dyestuff.Behind the yarn mercerising, its internal junction crystalline region changes, and crystal region reduces to 68~70% by original 82~87%, because the increase of noncrystalline domain, fiber is accelerated dye absorption rate, and dye-uptake improves.Mercerization adopts the method for handling with alkali lye.The technological parameter of yarn mercerising is controlled to be: alkali (NaOH) liquid concentration is that 27~30 ° of Be tension force are that 20~25 ℃ of mercerising times are 120~140s for the power temperature than raw yarn long 2%.
During yarn dyeing, selected suitable dyestuff and auxiliary agent, and adjusted technology, be specially: heating rate is 0.5-1 ℃/min; Reinforced branch adds for three times; Alkali number with hot water injection's yarns of 70~80 ℃; Used dyestuff is the KN type dye; With leveling agent o is retarding agents; Dyeing temperature is 90 ℃, and color fixing temperature is 80 ℃.
The translational speed of grey cloth was 60~70m/min when grey cloth was singed, and the tension force of grey cloth is 1.5~2Kg/cm
2This is to singe for the second time, and purpose is the filoplume that is created in blank cloth surface in the burning-off knitting process.
The grey cloth mercerising is in order further to improve the glossiness of grey cloth, the stability of controlling dimension, improve the cloth cover feel, make fabric face Paint Gloss, prevent the edge-rolling of single face fabric, the technological parameter of operation is that alkali (NaOH) liquid concentration is that 260~280g/l mercerising tension force is that 25~30Kg mercerising temperature is to be that 5~6min mercerising speed is 15~17m/min 20~25 ℃ of mercerising times.
In order to strengthen mercerization effect, accelerate mercerising speed, need to add mercerizing assistant in the alkali lye, we choose Tianjin and reach the mercerizing assistant FM-3A that an outstanding company produces from no phenol mercerizing assistant alkyl sulfide sodium commonly used, hydrocarbyl sulfonic sodium, pure ether compound, alkamine compound, organic acid compound, organic amidated compound, phosphate compounds.
After mercerising was handled, the acetum lixiviating of the alkali lye on yarn and/or the grey cloth finally reached pH value and is 6~7 more suitable.
For stability and the pleasant softness that further improves grey cloth, grey cloth also will be handled through soft and typing, and grey cloth is soft with 910
#Softener, bath raio are 1: 8, and treatment temperature is 100 ℃.
The typing of grey cloth is treated to:
Stentering forming: tentering 175cm
Cloth speed 15m/min
Temperature 130
Grey cloth preshrunk 10m/min abb finishing automatically is adjusted
In the present invention, singe, the mechanism of mercerising is as follows:
Singe:
Staple fibre has a large amount of gloss filoplumes on yarn in spinning process, directly influence the gloss of yarn, and the grease on the yarn, wax ester have a strong impact on the dyeing of yarn.The processing of singing of yarn, grey cloth has strengthened glossiness, has improved last chromatic effect.
Mercerising:
Mercerising is can improve fabric sheen from changing the manufacturing procedure of knitted fabric characteristic in essence one, improves the anti-intensity that rises, and strengthens dyeing uniformity and tinctorial yield, improves elasticity, guarantees size stability, can make the final washing shrinkage of knitted fabric reach 2~3%.
Mercerising is analyzed from following several respects the effect of fiber:
In order to understand this problem, we begin from swelling and backtwisting earlier, when cotton fiber is handled with concentrated alkali solution, the cotton fiber cross section that original not specification is similar to the broad bean shape becomes more and more round, and the cell disappearance, the variation of length and width can take place in cotton fiber simultaneously, is exactly swelling.Under swelling action, what fabric became is more abundant tight.And, in high concentration alkali solution, handle cellulose fibre, can cause the contraction of the wide and length of cellulose, amount of contraction is inversely proportional to the power that applies, this contraction is corresponding with the increase of cellulosic material volume, be swelling cause a kind of, swelling also can cause the variation of fiber cross section, when processing is to increase under the tension force to carry out, then fiber become round.Meanwhile, it is more glossy that fiber surface becomes, and by swelling, the distortion of fiber disappears, and this is that the result causes the backtwisting of fiber, the glossiness of fortifying fibre because the outer fibril layer of fiber more dwindles than internal layer.
Mercerising is processed the influence to cellulose fibre character:
(1) to the influence of gloss
The gloss of cellulosic material (yarn and fabric) is decided with the characteristic of fiber and yarn, the characteristic of fiber comprise cross section shapes and all once, spirality, surface roughness and transparency etc., the characteristic of yarn comprises the twist, compound with regular structure degree and fineness etc., mercerising is handled the gloss that causes cotton fiber to be increased, the characteristic of fabric and surface obtain changing, change more orienting reflex into by the diffuse reflection to light before the mercerising, increased catoptrical intensity, thereby made fabric demonstrate soyeux gloss.
(2) influence to dyeing
Mercerization causes fiber crystal region volume to reduce, degree of crystallinity about 70% before by mercerising reduces to 50~60%, the crystal region area increases, this processing, change the quality of fiber, particularly changed their accessibilities in aqueous medium, so the mercerising fiber has had bigger wettability power, the chemical reagent aqueous solution there is bigger reagency, higher accessibility is arranged with dye molecule.Mercerization has increased the absorption (dyestuff dye-uptake) and the dyeing rate of dyestuff, and has increased the vision tinctorial yield.
(3) mercerising is to the influence of brute force
Because the effect of concentrated base makes the fiber swelling, big intermolecular force is destroyed, hydrogen bond rupture, under straight laterally forceful action, the macromolecular arrangement trend of fiber is neat, the degree of orientation is improved, eliminated the uneven distortion of fiber surface, reduced weak link, the big molecule of some bendings is originally unfolded to be stretched, molecules align is neat, and is stressed even, via the fiber of expanded rearrangement, be close to mutually, embrace and power improves, eliminate or reduced the factor that fiber ruptures because of molecule slippage greatly, so its brute force increases.
(4) mercerising is to the influence of dimensional stability for fabric and washing shrinkage
In the mercerising process, owing to the swelling of cotton fiber in concentrated caustic solution broken and weakened active force between original fiber macromolecular chain, alleviate the internal stress that stores in the fiber by the fracture hydrogen bond, reset by stretching then, big molecular link is set up new molecular link on new position, fiber molecule tend to arrange and intermolecular active force than original swelling before molecular force big.Applying lixiviating under the brute force at last, a large amount of new hydrogen bonds have been formed between the fiber of orientations, like this, fiber is more natural, and new stable state is fixed, and at this moment fiber is in lower energy state, reach dimensionally stable, the also corresponding decline of washing shrinkage, mercerization simultaneously also makes COTTON FABRIC wrinkle resilience obtain moderate improvement, thereby has partly prevented because the tensile strength that the flatiron arrangement causes reduces.
Step of preparation process of the present invention is reasonable, and parameter stability can adapt to large-scale production.By the cotton knitwear of the present invention preparation, its performance has obtained improving greatly, is mainly reflected in glossiness, soft, aspect such as washing shrinkage is little.The key technical indexes is as follows after testing:
It is blunt to 3.2% vertical 2.7% to shrink
Barium value 165
Glossiness 80
The washable 4-5 of dyefastness
Sweat stain 4-5
Friction 4-5
With the cotton knitting ready-made clothes of making through PROCESS FOR TREATMENT of the present invention, the quality top grade has vast market prospect.
The invention will be further described below in conjunction with embodiment.Embodiment 1
The translational speed of yarn is 800m/min during the yarn singeing of cotton knitwear, and the tension force of yarn is 1.8Kg/cm
2The technological parameter of yarn mercerising is controlled to be: alkali (NaOH) liquid concentration is that 28 ° of Be tension force are that 23 ℃ of mercerising times are 125s for the power temperature than raw yarn long 2%.
During yarn dyeing, heating rate is 0.8 ℃/min; Reinforced branch adds for three times; Alkali number with hot water injection's yarns of 76 ℃; Used dyestuff is the KN type dye; With leveling agent o is retarding agents; Dyeing temperature is 90 ℃, and color fixing temperature is 80 ℃.
The translational speed of grey cloth was 65m/min when grey cloth was singed, and the tension force of grey cloth is 1.8Kg/cm
2
Grey cloth is through soft treatment, and grey cloth is soft with 910
#Softener, bath raio are 1: 8, and treatment temperature is 100 ℃.
The technological parameter of grey cloth mercerising operation is that alkali (NaOH) liquid concentration is that 270g/l mercerising tension force is that 26Kg mercerising temperature is to be that 5min mercerising speed is 16m/min 23 ℃ of mercerising times.In order to strengthen mercerization effect, accelerate mercerising speed, need to add mercerizing assistant in the alkali lye, we choose Tianjin and reach the mercerizing assistant FM-3A that an outstanding company produces.
After mercerising is handled, the acetum lixiviating of the alkali lye on yarn and/or the grey cloth, finally reaching pH value is 6.
The typing of grey cloth is treated to:
Stentering forming: tentering 175cm
Cloth speed 15m/mim
Temperature 130
Grey cloth preshrunk 10m/min abb finishing automatically is adjusted embodiment 2
The translational speed of yarn is 700m/min during the yarn singeing of cotton knitwear, and the tension force of yarn is 2Kg/cm
2The technological parameter of yarn mercerising is controlled to be: alkali (NaOH) liquid concentration is that 29 ° of Be tension force are that 25 ℃ of mercerising times are 125s for the power temperature than raw yarn long 2%.
During yarn dyeing, heating rate is 1 ℃/min; Reinforced branch adds for three times; Alkali number with hot water injection's yarns of 80 ℃; Used dyestuff is the KN type dye; With leveling agent o is retarding agents; Dyeing temperature is 90 ℃, and color fixing temperature is 80 ℃.
The translational speed of grey cloth was 60m/min when grey cloth was singed, and the tension force of grey cloth is 1.5Kg/cm
2
Grey cloth is through soft treatment, and grey cloth is soft with 910
#Softener, bath raio are 1: 8, and treatment temperature is 100 ℃.
The technological parameter of grey cloth mercerising operation is that alkali (NaOH) liquid concentration is that 280g/l mercerising tension force is that 29Kg mercerising temperature is to be that 5.5min mercerising speed is 16m/min 25 ℃ of mercerising times.
In order to strengthen mercerization effect, accelerate mercerising speed, need to add mercerizing assistant in the alkali lye, we choose Tianjin and reach the mercerizing assistant FM-3A that an outstanding company produces.
After mercerising is handled, the acetum lixiviating of the alkali lye on yarn and/or the grey cloth, finally reaching pH value is 7.
The typing of grey cloth is treated to:
Stentering forming: tentering 175cm
Cloth speed 15m/min
130 ℃ of temperature
Grey cloth preshrunk 10m/min abb finishing automatically is adjusted
Claims (9)
1, the two preparation technologies that singe of a kind of mariages light of cotton knitwear, comprise mercerising, the operation of singing, it is characterized in that its concrete processing step is followed successively by: yarn singeing, yarn mercerising, yarn dyeing, braiding, grey cloth are singed, grey cloth softness, grey cloth mercerising, typing, at last cotton knitwear.
2, preparation technology according to claim 1, the translational speed of yarn is 650~850m/min when it is characterized in that yarn singeing, the tension force of yarn is 1.5~2Kg/cm
2
3, preparation technology according to claim 1 is characterized in that the technological parameter of yarn mercerising is: concentration of lye is that 27~30 ° of Be tension force are that 20~25 ℃ of mercerising times are 120~1408 for the power temperature than raw yarn long 2%.
4, preparation technology according to claim 1, the translational speed that it is characterized in that grey cloth when grey cloth is singed is 60~70m/min, the tension force of grey cloth is 1.5~2Kg/cm
2
5, preparation technology according to claim 1, the technological parameter that it is characterized in that the grey cloth mercerising is that concentration of lye is that 260~280g/l mercerising tension force is that 25~30Kg mercerising temperature is to be that 5~6min mercerising speed is 15~17m/min 20~25 ℃ of mercerising times.
6,, it is characterized in that alkali lye is sodium hydrate aqueous solution according to claim 3 or 5 described preparation technologies.
7, preparation technology according to claim 1, the heating rate that it is characterized in that yarn dyeing is 0.5~1 ℃/min, used dyestuff is the KN type dye, is retarding agents with leveling agent o.
8, preparation technology according to claim 1 is characterized in that grey cloth is soft with 910
#Softener, bath raio are 1: 8, and treatment temperature is 100 ℃.
9, preparation technology according to claim 1 is characterized in that the grey cloth typing is treated to:
Stentering forming: tentering 175cm
Cloth speed 15m/min
130 ℃ of temperature
Grey cloth preshrunk 10m/min abb finishing automatically is adjusted
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CN 97106067 CN1210165A (en) | 1997-08-29 | 1997-08-29 | Process of dual mercerized and dual singered cotton fabrics |
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CN 97106067 CN1210165A (en) | 1997-08-29 | 1997-08-29 | Process of dual mercerized and dual singered cotton fabrics |
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1300409C (en) * | 2005-08-26 | 2007-02-14 | 宁波雅戈尔针织染整有限公司 | Processing method for washable knitted face fabric |
CN1763300B (en) * | 2004-05-21 | 2010-05-05 | 世联株式会社 | Cotton fiber product having smooth surfaces and method of producing compound fiber product from cotton and regenerated cellulose fibre |
CN101899740A (en) * | 2010-07-21 | 2010-12-01 | 无锡市天然纺织实业有限公司 | Method for manufacturing cool cotton knitting fabric |
CN101403157B (en) * | 2008-10-20 | 2011-04-13 | 无锡市天然纺织实业有限公司 | Slurry-free shirt face fabric with cotton warp and production method thereof |
CN102011243A (en) * | 2010-11-03 | 2011-04-13 | 宁波人丰家纺有限公司 | Method for preparing double-mercerized yarn-dyed jacquard fabric |
CN101643988B (en) * | 2009-06-29 | 2011-08-31 | 江苏阳光股份有限公司 | Production method of invisible strip worsted woolen fabric |
CN102517772A (en) * | 2011-12-30 | 2012-06-27 | 无锡市纳溪迩服饰有限公司 | Processing method of two-sided colorful knitted fabric |
CN102560819A (en) * | 2012-01-20 | 2012-07-11 | 无锡诺赛净科技有限公司 | Production method of zero release woven fabric |
CN109208141A (en) * | 2018-09-03 | 2019-01-15 | 南通市新纪元宾馆用品有限公司 | A kind of production technology of pro-skin type high-count high-density fabric |
CN112030437A (en) * | 2020-09-10 | 2020-12-04 | 洪英豪 | Fabric production process |
-
1997
- 1997-08-29 CN CN 97106067 patent/CN1210165A/en active Pending
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1763300B (en) * | 2004-05-21 | 2010-05-05 | 世联株式会社 | Cotton fiber product having smooth surfaces and method of producing compound fiber product from cotton and regenerated cellulose fibre |
CN1300409C (en) * | 2005-08-26 | 2007-02-14 | 宁波雅戈尔针织染整有限公司 | Processing method for washable knitted face fabric |
CN101403157B (en) * | 2008-10-20 | 2011-04-13 | 无锡市天然纺织实业有限公司 | Slurry-free shirt face fabric with cotton warp and production method thereof |
CN101643988B (en) * | 2009-06-29 | 2011-08-31 | 江苏阳光股份有限公司 | Production method of invisible strip worsted woolen fabric |
CN101899740A (en) * | 2010-07-21 | 2010-12-01 | 无锡市天然纺织实业有限公司 | Method for manufacturing cool cotton knitting fabric |
CN102011243A (en) * | 2010-11-03 | 2011-04-13 | 宁波人丰家纺有限公司 | Method for preparing double-mercerized yarn-dyed jacquard fabric |
CN102517772A (en) * | 2011-12-30 | 2012-06-27 | 无锡市纳溪迩服饰有限公司 | Processing method of two-sided colorful knitted fabric |
CN102560819A (en) * | 2012-01-20 | 2012-07-11 | 无锡诺赛净科技有限公司 | Production method of zero release woven fabric |
CN109208141A (en) * | 2018-09-03 | 2019-01-15 | 南通市新纪元宾馆用品有限公司 | A kind of production technology of pro-skin type high-count high-density fabric |
CN112030437A (en) * | 2020-09-10 | 2020-12-04 | 洪英豪 | Fabric production process |
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