CN1206556A - Smoking pesticide and smoking method - Google Patents
Smoking pesticide and smoking method Download PDFInfo
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- CN1206556A CN1206556A CN 97125773 CN97125773A CN1206556A CN 1206556 A CN1206556 A CN 1206556A CN 97125773 CN97125773 CN 97125773 CN 97125773 A CN97125773 A CN 97125773A CN 1206556 A CN1206556 A CN 1206556A
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Abstract
A smoking agent composition containing 2-15 wt.% one or more selected from a pyrethroid- based insecticide and a carbamate-based insecticide, 70-97 wt.% azodicarbonamide (a foaming agent) and 1-15 wt.% one or more selected from zinc oxide and zinc carbonate in a film bag, made of a synthetic resin and capable of forming a jetting hole in a part brought into contact with an ignition tool comprising a slowly combustible material. This smoking insecticide is prepared by sealing a smoking agent composition into the film bag. Bringing the smoking insecticide into contact with the ignition tool, thermally decomposing the foaming agent and making the smoking agent composition continuously jet smoke from the jetting hole.
Description
The invention relates to smoking insecticide and smoking method, is exactly about smoking insecticide that contains one or two kind of insecticide in organic foaming agent and pyrethroid insecticides and the carbamate insecticide and the improvement of using the smoking method of this insecticide in more detail.
For drive away and prevent managing a household in the insects such as living blattaria, bedbug, lice, flat lice, dirt mite class that dwell generally use fumigant.Fumigant is equivalent to short time high concentration spatial manipulation agent, requires to have the advantage that can handle broad space rapidly, also will fully pay attention to its effect conversely, to the safety of human body, to the safety of fire etc.The fumigant that existing market is sold has two types, and one of them contains inflammable substance and oxygen dissociant, and for example nitrate, chromate, perchlorate etc., are positioned at the diffusing material of waving of burning portion and fly away in the air with suitable speed burning from ignition location.Another kind is to contain insecticidal constituent and organic foaming agent, adds incremental agent (organic matter or inorganic matter) more as required, and modulation forms, and produces the power of gas when utilizing the organic foaming agent thermolysis, and it is diffusing that insecticidal constituent is waved.In addition, be that gas flow Celogen Azs how are representative so that stink is few as organic foaming agent.
In addition, also varied according to its smoked method of difference of fumigant constituent, from before match light a fire and add water heating method the quicklime, utilize the method for alkali metal sulphide air oxidation etc., now developed many kinds and entered practicability.The advantage of these methods is not use fire, in order to prevent to cause danger among the stock and be subjected to breakage, requires packing container firm and air-tightness good, therefore has to use double-layer plastic container or the so expensive packing of metal aluminium pot.In addition, also there is the problem in the use in the method that adds water in the quicklime, and promptly Dian Huo the water yield goes wrong then that fumigation can not begin.
Containing insecticide contacts with firing tools through the packed smoking insecticide that makes with the fumigant of decomposition temperature at the organic foaming agent below 250 ℃, make the organic foaming agent thermolysis, from contact portion ejection insecticidal constituent, be that author of the present invention at first develops [disclosing clear and 58-18301 number (Japanese patent laid-open publication gazette is put down into 1-57081 number) with reference to Japan Patent] as the smoking method of the smoking insecticide of feature.Japan Patent discloses clear and 63-267705, Japan Patent and disclose clear and 64-42401 number disclosed smoking insecticide and to use the smoking method of smoking insecticide be the improvement of and 58-18301 technology clear to the Japan Patent public affairs in addition, and smoking insecticide contains permethrin, antioxidant and organic foaming agent.When fumigant touched the firing tools that is made of slow-burning material, only in this contact portion, film of synthetic resin or fusing point were 90-120 ℃ film of synthetic resin perforate.Fumigant is to pack in the above film of synthetic resin bag.These smoking insecticides and smoking method provide system easy and high efficiency fumigation insecticidal constituent, but as optimal organic foaming agent, because used 4.4 '-just キ ミ PVC ス (benzene sulfonyl hydrazide), this blowing agent is very smelly, on usability, await to improve.
The present invention has used the extraordinary organic foaming agent Celogen Az of serviceability and security performance, the fumigant constituent that will be combined with blowing agent simultaneously is encapsulated in the film of synthetic resin bag and makes smoking insecticide, compared with former smoking method, fumigation safely and efficiently under thermal source low in calories, the present invention is to serve as the exploitation problem so that following smoking insecticide and smoking method to be provided.
For solving above problem, the inventor is through research repeatedly, is furnished with the azodicarbonamide foaming agent of specific adjuvant by use, and discovery can be finished the fumigation system of expection, finishes the present invention again after further study the most eventually.
That is to say that the invention of claim 1 is to be the smoking insecticide of feature with following content.The fumigant constituent contains one in 2-15 weight % pyrethroid insecticides and the carbamate insecticide or two kind, the Celogen Az that contains 70-97 weight %, contain in 1-15 weight % zinc oxide and the zinc carbonate one or both, when contacting the firing tools that constitutes by the deflagration material, the film of synthetic resin bag forms spray orifice in its contact portion, and the fumigant constituent is sealing in the above resin film bag.
The pyrethroid insecticides that the present invention uses lists phenothrin, permethrin, phenylate hydrocyanic ester, cypermethrin, allethrin, prallethrin, alkynes chaff, resmethrin, ether chrysanthemum ester etc., because insect is killed soon, safe to people and animals, expeling or the control of insects such as the blattaria that is fit to very much to live in the family, bedbug, lice, flat lice, dirt mite class.In addition, in chemical constitution, exist asymmetric carbon or two bond to close, when having optics metamer and how much metamers on this basis, in them each or arbitrarily mixture also be contained in the pyrethroid insecticides among the present invention, optimal compound is the big phenothrin of residual effect, permethrin, cyphenothrin, cypermethrin.
In addition, carbamate insecticide has メ ト キ サ ミ ゾ ソ etc.
One or both insecticides of selecting from pyrethroid and carbamates, be to cooperate in the fumigant constituent with 2-15 weight %, can not get desirable effect during less than 2 weight %, if surpass the ejection power that 15 weight % can influence blowing agent, effect is bad.
Among the present invention, except that pyrethroid insecticides, should be used to good with other type insecticide, miticide, the synergist, stabilizing agent, spices, binder etc. that are anti-epiphyte pharmaceutical, antibacterial agent and the bactericide of object or pyrethroid insecticides with fungi mushroom etc.Can list just compounds such as ワ ソ, Ha イ De ロ プ レ Application, ピ リ プ ロ キ シ Off ェ Application of the Folithion, dichlorvos, basudin, low toxicity sulphur phosphorus etc. of organophosphorus insecticides or シ ラ ヮ Le as insecticide.Miticide has phenyl salicytate, 3-sulphur-2 propine butyl carbamate etc., as anti-epiphyte pharmaceutical, antibacterial agent and bactericide 2-TGA benzothiazole, 2-(4-thiazole), benzimidazole, イ リ ホ リ Application, 3-methyl-4 isopropyl-phenol, O-phenylphenol etc. are arranged in addition, and be not limited only to these.
Characteristics of the present invention are, as blowing agent, cooperate specific adjuvant in the Celogen Az of total amount 70-97 weight %, promptly select one or two kind from zinc oxide and zinc carbonate, and total amount is 1-15 weight %.The intrinsic stink of blowing agent is low in the Celogen Az, gas flow is many, demonstrates good foam performance, still, because decomposition temperature up to 210 ℃, therefore needs the thermal source of continuous high temperature, in addition, is difficult to be applicable to the insecticidal constituent of easy decomposes under the high temperature.
Yet, the inventor and handy and safe and efficiently smoking method made up, in Celogen Az, cooperate one in the zinc oxide of specified quantitative and the zinc carbonate or two kind, this method descends the decomposition temperature of Celogen Az.On the other hand, other adjuvant can reduce the decomposition temperature of organic foaming agent in addition, and for example zinc stearate, methyl isooctenylamine acid zinc, calcium stearate, urea, melamine, guanidine etc. only depend on these adjuvants can not obtain high efficiency fumigation performance.In addition, the decomposition temperature that reduces organic foaming agent also has other means, and the method for mixing other low type blowing agent of some decomposition temperatures is arranged, and still, unhappy foul smell can occur like this, also has a lot of problems if family uses.
Used the Celogen Az of total amount 70-97 weight % among the present invention, if less than 70 weight % then blowing agent ejection strength deficiency, insecticidal constituent can not play one's part to the full, if surpass 97 weight %, other composition so, for example insecticide ingredient then can tail off, and can not get desirable insecticidal effect.In addition, select 1 or two kind use level from zinc oxide and zinc carbonate, its total amount is 1-15 weight %, preferably selects from the scope of 2-5 weight %.If less than 1 weight %, it is as the DeGrain of adjuvant, if surpass 15 weight % then the enhancing of ejection power, so not only the time of fumigation needs shortens, and the rate of loosing of waving of insecticidal constituent reduces, and causes seriously polluted and inadvisable because of the adjuvant precipitation behind the fumigation.The azodicarbonamide foaming agent that is combined with adjuvant is 140-205 ℃ of decomposition, even heat thermal source seldom also can fumigation, still, do not bringing in the limit of obstacle for the fumigation performance, to add other above-mentioned adjuvant again for well.
The characteristics of smoking insecticide of the present invention are to have proposed the fumigant constituent is enclosed in the film of synthetic resin bag.Fumigant in the past must be accommodated in the firm dual plastic containers or metal aluminium pot, and the present invention encloses in the easy film of synthetic resin bag.
The material of film of synthetic resin bag generally can be used polyethylene, polypropylene, nylon, polyester etc., through aerosol spraying efficient and long duration test research, it is the most desirable when thickness is the 20-50 μ m left and right sides, in addition, the composite article of polyethylene and other film of synthetic resin, it is effective especially that for example polyethylene laminated cellophane is compound, the polyethylene polypropylene is compound etc.
In addition, the slow right material system firing tools that uses among the present invention has smoked mosquito line spices, Buddhist altar line spices, carbon fire, leads lighted torch etc. by what ferrosilicon and metal oxide were made, and is best with bar-shaped line spices.
The invention of claim 2 be pyrethroid insecticides used select in phenothrin, cypermethrin, cyphenothrin and the cypermethrin one or two kind.
The invention of claim 3 is that the material of film of synthetic resin bag has been used desirable polyethylene laminated film.
The invention of claim 4 is the smoking methods about smoking insecticide, use is enclosed the smoking insecticide that the film of synthetic resin bag makes with the fumigant constituent, the fumigant constituent closes one in 2-15 weight % pyrethroid insecticides and the carbamate insecticide or two kind, contain 70-97 weight % Celogen Az, contain one in 1-15 weight % zinc oxide and the zinc carbonate or two kind.Firing tools igniting by slow-burning material constitutes contacts bag film after the fray-out of flame, form spray orifice on this bag film, uses Celogen Az (blowing agent) thermolysis simultaneously, and the fumigant constituent is from the continuous aerosol spraying of spray orifice.
The firing tools that slow-burning material constitutes not is to resemble the high temperature of quicklime with the water reaction to continue type, but the characteristic of comprehensive fumigant constituent and the material of bag film as long as contact fumigant constituent seals people's bag, can begin aerosol spraying continuously.
The invention of claim 5 is that pyrethroid insecticides has used one or both in phenothrin, permethrin, cyphenothrin and the cypermethrin.
The invention of claim 6 is that the firing tools that slow-burning material constitutes has used bar-shaped line spices.
Formation according to claim 1, as blowing agent, in Celogen Az, cooperate specific adjuvant, decomposition temperature is adjusted to 140-205 ℃ of use, enclose simultaneously in the synthetic resin bag of specific materials, providing can be safely, the smoking insecticide of fumigation efficiently.Compared with former smoking insecticide, as long as the few thermal source of contact low-temperature heat quantity, smoking insecticide just can continue fumigation.For the fumigant constituent of pyrethroid insecticides that contains easy thermolysis under the high temperature and carbamate insecticide, its sensitivity is high especially.One or the two kind of insecticide kind of selecting from pyrethroid insecticides and carbamate insecticide, the formulation and the consumption of fumigant constituent can carry out suitable selection according to application target and field of employment.For example formulation is that powdery is than graininess, granular good.In addition, only consumption is that the active ingredient of the treated side landing behind fumigation is 0.1mg-1.0g/m
2In addition, for the stop processing of the strong insect of worm agent of anti-pyrethroid alcohols, with the メ ト キ サ ジ ア ゾ Application of carbamate insecticide and the Folithion of organophosphorus insecticides etc. and with for well.
When implementing, making smoking insecticide in the fumigant constituent inclosure synthetic resin bag, smoking insecticide is put into the such simple container of dixie cup or plastic cup or pottery, use with the firing tools of bar-shaped line spices class slow-burning material as base material, aerosol spraying is very practical simply.
If adopt claim 2, from phenothrin, permethrin, cyphenothrin and cypermethrin, select one or both and use as pyrethroid insecticides, can provide residual effect more good smoking insecticide.
If adopt claim 3, use optimal polyethylene composite wood, for example use the material of polyethylene laminated cellophane laminated film as the film of synthetic resin bag, can provide residual effect more good smoking insecticide.
If adopt claim 4, from pyrethroid insecticides and carbamate insecticide, select one or both and contain Celogen Az and specific adjuvant, enclose in the lump in the film of synthetic resin bag, firing tools contacts the insecticide that makes, promptly form spray orifice at bag film, meanwhile organic foaming agent carries out thermolysis, constantly sprays the fumigant constituent from spray orifice, and a kind of useful smoking method is provided.
If according to claim 5, from phenothrin, permethrin, cyphenothrin and cypermethrin, select one or both and use as pyrethroid insecticides, a kind of efficient, practical and good smoking method can be provided.
According to claim 6, as the slow-burning material firing tools, can provide more practical smoking method with bar-shaped line spices,
[embodiment]
Further describe fumigation worm of the present invention agent and smoking method according to specific embodiment and test example below.
Embodiment 1
6.0 weight % permethrins, 90.0 weight % Celogen Azs and 4.0 weight % zinc oxide are mixed, obtain powdery fumigation constituent 20g, this powdery fumigation constituent is sealing in the compound bag film of polyethylene and glassine paper, makes smoking insecticide of the present invention.This smoking insecticide is put into dixie cup, place the airtight room central authorities of putting 6 straw mattresses.After the igniting, when the bar-shaped line spices one of knock down the flame contacted a part of bag film, in the contact site perforation, cigarette sprayed naturally from this hole, diffuses to whole room then.Investigate after 5 hours, observe a lot of blattaria corpse in doors, demonstrate very high insecticidal effect, and almost can't see the pollution that aerosol spraying causes.
Embodiment 2
In 5.0 weight % phenothrins and 3.0 weight %3-iodo-, 2 propine butyl carbamates, mix 83.9 weight % Celogen Azs and 8.0 weight % zinc carbonates, add 0.1 weight % spices again and obtain 20g fumigation constituent, this fumigation constituent is sealing in the polyethylene made membrane bag, makes smoking insecticide of the present invention.This smoking insecticide is put into earthen container, place the house central authorities of 10 straw mattresses, airtight the room.The firing tools that uses Buddhist altar line spices to do withdraws from from the room behind the beginning aerosol spraying, places diel, and within doors the variation of blattaria, mite and Mycophyta density is before and after treatment investigated, found that handling all parasitic density of back all obviously reduces.
The test example
According to the various fumigant constituents shown in embodiment 1 modulomenter 1,20g fumigant constituent is sealing into after the film of synthetic resin bag, use smoked mosquito line spices to carry out following fumigation test as firing tools.Result of the test is also listed in the table 1.
(1) foam performance: continuously the aerosol spraying situation according to order such as good with zero, △ estimates.In addition, foam performance be evaluated as * the evaluation of not carrying out following pilot project.
(2) insecticidal constituent wave diffusing rate: collect the cigarette of some ejections, analyze contained insecticidal constituent amount in the cigarette, obtain the diffusing rate of waving initial stage amount before the fumigation.Be positioned in the table 1 in addition _ numeral of a__b_ is the diffusing rate of waving of the insecticidal constituent shown in the insecticidal constituent item.
(3) desinsection is renderd a service: being equipped with 10 respectively pyrethroid susceptibility Groton bug and 10 cylinders to analogy chrysanthemic acid insensitivity Groton bug be placed in the room four jiaos, 48 hours dead worm rates of " Invest, Then Investigate " of fumigation.In addition, in the table 1 _ feel _ be the susceptibility blattaria, and _ resist _ be expression non-sensibility blattaria.
(4) serviceability: the foul smell during to fumigation and handle after pollution situation investigate, all good usefulness zero is represented, the wherein bad time standby * expression of a side or two sides, and increase this content when specific (special) requirements is arranged.
In addition, accommodate in the table 1 form Xiang Zhongyou _ polyethylene film _, _ polyethylene and glassine paper be compound _, _ polyethylene and polypropylene be compound _, _ aluminium film _ represent respectively fumigant constituent inclosure _ polythene film bag _, _ polyethylene and glass laminated film bag _, _ the aluminum bag _.
| Smoking insecticide | Performance test | |||||||
| The fumigant composition; Weight % (20%) | Take in form | Foam performance | Wave diffusing rate (%) | Desinsection is renderd a service (%) | Usability | |||
| Insecticidal constituent | Blowing agent and other composition | |||||||
| The present invention | ?1 ?2 ?3 ?4 ?5 ?6 ?7 ?8 ?9 | Permethrin a)6.0 permethrin a)5.0 ?メトキサシアソソ ???? b)4.0 phenothrin a)6.5 phenothrin a)6.5 phenothrin a)6.5 cyphenothrin a)4.0 EXTHIN a)*5.5 メ ト キ シ ア ソ is 3.0 cypermethrins a) a)3.5 Folithion b)3.5 ?メトキサシアソソ ???? a)7.0 | Celogen Az 84.5 zinc oxide 7.5 Celogen Azs 86.0 zinc oxide 3.5 Celogen Azs 92.0 zinc carbonates 11.0 Celogen Azs 92.0 zinc oxide 1.0 Celogen Azs 77.5 zinc oxide 15.0 Celogen Azs 90.0 zinc oxide 3.8 zinc carbonates 1.2 Celogen Azs 83.5 zinc oxide 5.0 glycerine boron purport lead plumbates 1.5 Celogen Azs 88.0 zinc oxide 3.0 Celogen Azs 86.5 zinc oxide 4.5 | Polyethylene film polyethylene film polyethylene film polyethylene film polyethylene film polyethylene and glassine paper composite polyethylene and polypropylene composite materials polyethylene and polypropylene composite materials polyethylene film | ○ ○ ○ ○ ○ ○ ○ ○ ○ | ?a；71 ?a；73 ?b；75 ?a；70 ?a；68 ?a；66 ?a；72 ?a；78 ?b’74 ?a；72 ?b；69 ?a；75 | Sense 100 anti-60 senses, 100 anti-100 senses, 100 senses, 95 senses, 100 senses, 100 senses, 100 anti-100 senses, 100 anti-100 senses 100 | ○ ○ ○ ○ ○ ○ ○ ○ ○ |
*: the S-EXTHIN: the optically active body of allethrin
| Smoking insecticide | Performance test | |||||||
| The fumigant composition; Weight % (20g) | Take in form | Foam performance | Wave diffusing rate (%) | Desinsection is renderd a service (%) | Usability | |||
| Contrast | Insecticidal constituent | Blowing agent and other composition | ||||||
| ?1 ?2 ?3 ?4 ?5 ?6 | Permethrin a)6.0 permethrin a)5.0 4.0 permethrins メ ト キ サ シ ア ソ ソ b) a)6.0 permethrin a)6.0 permethrin a)6.0 permethrin a)6.0 | Celogen Az 93.0 ォ キ シ ピ ス ゼ Application ス ホ ニ Le ヒ De ラ シ Off De 90.0 Celogen Azs 74.0 urea 13.0 zinc oxide 6.0 Celogen Azs 92.0 zinc oxide 0.7 Celogen Az 75.0 zinc oxide 18.0 Celogen Azs 84.5 zinc oxide 7.5 | Polyethylene film polyethylene film polyethylene film polyethylene film polyethylene film aluminium foil | × ○ × × ○ × | a;- a;78 b;66 a;- a;- a;59 a;- | Sense-sense 100 anti-100 sense-senses-sense 100 senses- | -* smelly--* dirty- | |
* the expression of "-" in table foam performance is bad and do not estimate.
As can be seen from the test results, if adopt smoking insecticide of the present invention and smoking method, not only easy but also fumigation performance, desinsection are renderd a service all very good, almost do not have foul smell during fumigation, almost do not pollute or pollute after handling considerably less, so its practical be worth very high.In addition, because the blattaria of tolerance pyrethroid is had sufficient insecticidal effect, thus except that pyrethroid insecticides, the insecticide of other type, for example carbamate insecticide cooperates ideal.
In contrast, as blowing agent, separately complete with Celogen Az (reference examples 1) or when using the azodicarbonamide foaming agent (reference examples 3) that adds the adjuvant (main body interpolation) beyond zinc oxide or the zinc carbonate in Celogen Az, its foam performance is low.In addition, also there is the problem of use aspects such as foam performance or pollution in (reference examples 4,5) of the use level of zinc oxide and zinc carbonate beyond the 1-15% scope.In addition, when cooperating low other blowing agent of the such decomposition temperature of hydroxyl two benzene sulfonyl hydrazides (reference examples 2), though the fumigation performance is good, foul smell is seriously very undesirable.In addition, as reference examples 6, the form of accommodating of fumigation constituent is not to use the film of synthetic resin bag, and this does not conform to the fumigation of the present invention system that is suitable for.
Invention according to claim 1 and even claim 3, being combined with zinc oxide or zinc carbonate in the Celogen Az or being combined with zinc oxide and the blowing agent of zinc carbonate one or both pesticides in pyrethroid insecticides and carbamate insecticides are enclosed in the film of synthetic resin bag, one our smoking insecticide can be provided thus, new smoking insecticide was compared with former smoking method, though under the few thermal source of heat also fumigation serially.
According to the invention of claim 4 and even claim 6, as long as the firing tools that deflagration is made touches safely and effectively aerosol spraying of aforesaid useful smoking insecticide, provide a kind of very practical smoking method.
Claims (6)
1. smoking insecticide, it is characterized in that, the fumigant composition contains 1 in the pyrethroid insecticides of 2-15 weight % and the carbamate insecticide or 2 kind, in the zinc oxide of the Celogen Az of 70-97 weight %, 1-15 weight % and the zinc carbonate 1 or 2 kind, said composition is encapsulated in when contacting the firing tools that is made of the deflagration material, forms in the film of synthetic resin bag of spray orifice in its contact portion.
2. according to the smoking insecticide of claim 1, wherein pyrethroid insecticides is to select a kind or 2 kinds from phenothrin, Cyano chrysanthemate, cyphenothrin and cypermethrin.
3. according to the smoking insecticide of claim 1 or 2, wherein the film of synthetic resin bag is made with the polyethylene laminated film.
4. the smoking method of smoking insecticide, it is characterized in that, the fumigant composition contains 1 in the zinc oxide of Celogen Az, 1-15 weight % of 1 in the pyrethroid insecticides of 2-15 weight % and the carbamate insecticide or 2 kind, 70-97 weight % and the zinc carbonate or 2 kind, to contact with the smoking insecticide that fumigant composition inclosure film of synthetic resin is made by the firing tools that the deflagration material constitutes, when bag film forms spray orifice, Celogen Az carries out thermolysis, constantly sprays the fumigant composition from spray orifice.
5. according to the smoking insecticide smoking method of claim 4, wherein pyrethroid insecticides is to select 1 or 2 kind from phenothrin, permethrin, cyphenothrin, cypermethrin.
6. according to the smoking insecticide smoking method of claim 4 or 5, wherein firing tools is bar-shaped line spices.
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP233210/1997 | 1997-07-24 | ||
| JP233210/97 | 1997-07-24 | ||
| JP23321097 | 1997-07-24 | ||
| JP296196/97 | 1997-10-14 | ||
| JP29619697A JP4452955B2 (en) | 1997-07-24 | 1997-10-14 | Smoke pesticide and method |
| JP296196/1997 | 1997-10-14 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1206556A true CN1206556A (en) | 1999-02-03 |
| CN1099831C CN1099831C (en) | 2003-01-29 |
Family
ID=26530910
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97125773A Expired - Fee Related CN1099831C (en) | 1997-07-24 | 1997-11-24 | Smoking pesticide and smoking method |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP4452955B2 (en) |
| CN (1) | CN1099831C (en) |
| HK (1) | HK1017585A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110612983A (en) * | 2019-10-29 | 2019-12-27 | 江苏扬农化工股份有限公司 | Insecticidal composition containing famoxadone and acetamiprid and application thereof |
| CN111296431A (en) * | 2019-11-04 | 2020-06-19 | 吉林省农业科学院 | Plant smoking agent for expelling insects and killing insects and use method thereof |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000351702A (en) * | 1999-06-08 | 2000-12-19 | Dainippon Jochugiku Co Ltd | Smoking insecticidal composition |
| JP4885371B2 (en) * | 2001-05-17 | 2012-02-29 | 大日本除蟲菊株式会社 | How to smoke smoke insecticides |
| JP2003089611A (en) * | 2001-07-11 | 2003-03-28 | Dainippon Jochugiku Co Ltd | Smoking insecticide and method for preventing the same from aggregation |
| JP4920377B2 (en) * | 2006-11-17 | 2012-04-18 | ライオン株式会社 | Smoke composition |
| CN102972433A (en) * | 2011-09-07 | 2013-03-20 | 中国人民解放军疾病预防控制所 | New health and epidemic prevention insecticidal fumigant |
| CN112088888A (en) * | 2019-06-18 | 2020-12-18 | 江苏功成生物科技有限公司 | Sanitary insecticidal composition containing oxadixic ketone and application thereof |
| CN110583672A (en) * | 2019-10-29 | 2019-12-20 | 江苏扬农化工股份有限公司 | Sanitary insecticidal composition containing oxadixic ketone and pyrethroid |
| CN110637822B (en) * | 2019-10-29 | 2021-07-27 | 江苏扬农化工股份有限公司 | Binary sanitary insecticidal composition containing oxadixyl and application thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63267705A (en) * | 1987-04-24 | 1988-11-04 | Dainippon Jiyochiyuugiku Kk | Smoking insecticide and method for smoking said insecticide |
| JP3548935B2 (en) * | 1995-01-10 | 2004-08-04 | 株式会社南方除虫粉製造所 | Smoke composition |
| JP3548934B2 (en) * | 1995-01-10 | 2004-08-04 | 株式会社南方除虫粉製造所 | Smoke composition |
-
1997
- 1997-10-14 JP JP29619697A patent/JP4452955B2/en not_active Expired - Lifetime
- 1997-11-24 CN CN97125773A patent/CN1099831C/en not_active Expired - Fee Related
-
1999
- 1999-07-05 HK HK99102824A patent/HK1017585A1/en not_active IP Right Cessation
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110612983A (en) * | 2019-10-29 | 2019-12-27 | 江苏扬农化工股份有限公司 | Insecticidal composition containing famoxadone and acetamiprid and application thereof |
| CN110612983B (en) * | 2019-10-29 | 2021-03-09 | 江苏扬农化工股份有限公司 | Insecticidal composition containing famoxadone and acetamiprid and application thereof |
| CN111296431A (en) * | 2019-11-04 | 2020-06-19 | 吉林省农业科学院 | Plant smoking agent for expelling insects and killing insects and use method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH1192312A (en) | 1999-04-06 |
| JP4452955B2 (en) | 2010-04-21 |
| CN1099831C (en) | 2003-01-29 |
| HK1017585A1 (en) | 1999-11-26 |
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