CN119110821A - 用于制备磺化聚亚芳基砜聚合物（sP）的方法 - Google Patents

用于制备磺化聚亚芳基砜聚合物（sP）的方法 Download PDF

Info

Publication number
CN119110821A
CN119110821A CN202380023910.9A CN202380023910A CN119110821A CN 119110821 A CN119110821 A CN 119110821A CN 202380023910 A CN202380023910 A CN 202380023910A CN 119110821 A CN119110821 A CN 119110821A
Authority
CN
China
Prior art keywords
component
sulfone
sulfonated polyarylene
group
polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202380023910.9A
Other languages
English (en)
Chinese (zh)
Inventor
M·韦伯
D·马尔科
B·施密德-汉斯伯格
C·亨舍尔
O·格朗瓦尔德
J·巴拉克
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of CN119110821A publication Critical patent/CN119110821A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/20—Polysulfones
    • C08G75/23—Polyethersulfones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
    • C08G65/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols
    • C08G65/40—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols from phenols (I) and other compounds (II), e.g. OH-Ar-OH + X-Ar-X, where X is halogen atom, i.e. leaving group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B01D61/422—Electrodialysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/66—Polymers having sulfur in the main chain, with or without nitrogen, oxygen or carbon only
    • B01D71/68—Polysulfones; Polyethersulfones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
    • C08G65/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols
    • C08G65/40—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols from phenols (I) and other compounds (II), e.g. OH-Ar-OH + X-Ar-X, where X is halogen atom, i.e. leaving group
    • C08G65/4012—Other compound (II) containing a ketone group, e.g. X-Ar-C(=O)-Ar-X for polyetherketones
    • C08G65/4056—(I) or (II) containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2256—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions other than those involving carbon-to-carbon bonds, e.g. obtained by polycondensation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B13/00—Diaphragms; Spacing elements
    • C25B13/04—Diaphragms; Spacing elements characterised by the material
    • C25B13/08—Diaphragms; Spacing elements characterised by the material based on organic materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1027—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1032—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2381/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen, or carbon only; Polysulfones; Derivatives of such polymers
    • C08J2381/06—Polysulfones; Polyethersulfones
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Electrochemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Sustainable Development (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Energy (AREA)
  • Metallurgy (AREA)
  • Water Supply & Treatment (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Urology & Nephrology (AREA)
  • Inorganic Chemistry (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Polyethers (AREA)
  • Fuel Cell (AREA)
CN202380023910.9A 2022-02-28 2023-02-23 用于制备磺化聚亚芳基砜聚合物（sP）的方法 Pending CN119110821A (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP22159251.2 2022-02-28
EP22159251 2022-02-28
EP22215613 2022-12-21
EP22215613.5 2022-12-21
PCT/EP2023/054578 WO2023161355A1 (en) 2022-02-28 2023-02-23 Process for the preparation of a sulfonated polyarylenesulfone polymer (sp)

Publications (1)

Publication Number Publication Date
CN119110821A true CN119110821A (zh) 2024-12-10

Family

ID=85382595

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202380023910.9A Pending CN119110821A (zh) 2022-02-28 2023-02-23 用于制备磺化聚亚芳基砜聚合物（sP）的方法

Country Status (6)

Country Link
US (1) US20250179250A1 (enExample)
EP (1) EP4486819A1 (enExample)
JP (1) JP2025517244A (enExample)
KR (1) KR20240154061A (enExample)
CN (1) CN119110821A (enExample)
WO (1) WO2023161355A1 (enExample)

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3330154A1 (de) 1983-08-20 1985-03-07 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von polyethern
EP0297363A3 (de) 1987-06-27 1989-09-13 BASF Aktiengesellschaft Hochtemperaturbeständige thermoplastische formmassen mit verbesserter Schmelzestabilität
JP4234422B2 (ja) * 2000-09-20 2009-03-04 バージニア テック インテレクチュアル プロパティーズ インコーポレーテッド イオン導電性スルホン化重合体材料
US7361729B2 (en) * 2000-09-20 2008-04-22 Virginia Tech Intellectual Properties, Inc. Ion-conducting sulfonated polymeric materials
DE60329518D1 (de) * 2002-10-08 2009-11-12 Toyo Boseki SULFONSuUREGRUPPENHALTIGE POLYARYLENETHER-VERBINDUNG, DIESE ENTHALTENDE ZUSAMMENSETZUNG UND VERFAHREN ZU DEREN HERSTELLUNG
WO2004086584A2 (en) * 2003-03-19 2004-10-07 Virginia Tech Intellectual Properties, Inc. Aromatic nitrile containing ion-conducting sulfonated polymeric material
KR100963409B1 (ko) * 2008-06-02 2010-06-14 광주과학기술원 술폰화된 폴리(아릴렌 에테르) 교대 공중합체와 고분자사슬 말단에 가교구조를 함유한 술폰화된 폴리(아릴렌에테르) 교대 공중합체 및 이를 이용한 고분자 전해질막
WO2014095973A1 (en) * 2012-12-18 2014-06-26 Solvay Specialty Polymers Usa, Llc Mobile electronic devices made of low-chlorine aromatic polysulfones
WO2017220363A1 (en) * 2016-06-20 2017-12-28 Basf Se Process for removing arsenic compounds from aqueous systems
CN106279693B (zh) * 2016-08-31 2018-08-21 浙江工业大学 一种侧链含苯并咪唑聚芳醚酮/砜及其制备方法与应用
KR101756343B1 (ko) * 2016-10-26 2017-07-11 한국과학기술연구원 연료전지의 전극 바인더용 신규한 폴리아릴렌에테르계 공중합체, 이를 포함하는 막전극접합체 및 그 제조방법
KR20200034760A (ko) * 2017-07-20 2020-03-31 바스프 에스이 설폰화 폴리아릴에테르설폰 및 이의 막
JP7460549B2 (ja) * 2018-05-18 2024-04-02 ソルベイ スペシャルティ ポリマーズ ユーエスエー， エルエルシー ポリアミドを含む相溶化ポリマー組成物
CN112673052A (zh) * 2018-09-11 2021-04-16 巴斯夫欧洲公司 聚亚芳基醚砜
KR102142566B1 (ko) * 2018-11-22 2020-08-07 건국대학교 글로컬산학협력단 부분 불소화된 설폰이미드를 포함하는 신규한 중합체, 이의 제조방법 및 이를 포함하는 양성자 교환막

Also Published As

Publication number Publication date
JP2025517244A (ja) 2025-06-04
WO2023161355A1 (en) 2023-08-31
US20250179250A1 (en) 2025-06-05
EP4486819A1 (en) 2025-01-08
KR20240154061A (ko) 2024-10-24

Similar Documents

Publication Publication Date Title
Harrison et al. Influence of the bisphenol structure on the direct synthesis of sulfonated poly (arylene ether) copolymers. I
EP1327278B1 (en) Ion-conducting sulfonated polymeric materials
KR100810922B1 (ko) 중합체 전해질 및 이의 제조방법
US8846854B2 (en) Sulfonated poly(arylenes), polymer compounds and methods of producing the same
US20120083541A1 (en) Aromatic polyether sulfone block copolymers
WO2017148850A1 (en) Method for the preparation of a membrane which comprises an organic polymer of intrinsic microporosity (pim) and a sulfonated polyarylenesulfone polymer
EP1611182B1 (en) Aromatic nitrile containing ion-conducting sulfonated polymeric material
CN102634008A (zh) 高分子电解质材料、高分子电解质成型体、膜电极复合体和固体高分子型燃料电池
KR100629667B1 (ko) 설폰화 방향족 중합체, 이러한 중합체를 함유하는 막,이의 제조방법 및 용도
EP2084210A1 (en) Sulfonated poly(arylene ether) containing crosslinkable moity at end group, method of manufacturing the same, and polymer electrolyte membrane using the sulfonated poly(arylene ether) and the method
JP2023503064A (ja) 求核置換によって高フッ素化芳香族基を有するポリマーから作製されるカチオン交換ポリマー及びアニオン交換ポリマー及び対応する（ブレンド）膜
US20050261442A1 (en) Materials for use as proton conducting membranes for fuel cells
WO2023161355A1 (en) Process for the preparation of a sulfonated polyarylenesulfone polymer (sp)
KR20170109295A (ko) 폴리에테르에테르케톤 기반의 양이온 교환막, 이의 제조방법 및 이를 포함하는 연료전지
CN110655648A (zh) 一种利用后磺化法制备的主链型磺化聚喹喔啉及其质子交换膜
EP4486822B1 (en) Process for the preparation of a membrane (m) containing a sulfonated polyarylenesulfone polymer (sp)
CN118900870A (zh) 具有至少双峰态分子量分布的磺化聚亚芳基砜聚合物(sP)
CN101580584B (zh) 嵌段磺化聚芳香(硫)醚的高效制备方法
WO2026074001A1 (en) Method for the preparation of a catalyst coated membrane (ccm)
CN115298866A (zh) 电解质膜和使用该电解质膜的氧化还原液流电池
JP4089821B2 (ja) プロトン伝導性樹脂組成物、プロトン伝導性膜および架橋物
Khomein et al. Sulfonated Aromatic Polymers and Copolymers for Membrane Engineering
KR20250162244A (ko) 양이온 교환 수지, 그 제조 방법, 양이온 교환막 및 전기 투석 장치
WO2025132101A1 (en) Use of a membrane (m) comprising a non-crosslinked sulfonated polyarylene ether sulfone polymer (sp) in an aqueous redox flow battery (arfb)
AU2022243650A1 (en) Polymer electrolyte membrane, block copolymer, polymer electrolyte material, polymer electrolyte molded body, electrolyte membrane with catalyst layer, membrane electrode composite, solid polymer fuel cell, and water electrolytic hydrogen generator

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
CB03 Change of inventor or designer information

Inventor after: M. Weber

Inventor after: D Marco

Inventor after: B. Schmid Hansberg

Inventor after: C. Hensher

Inventor after: O. Gronwald

Inventor after: JOSE BARAK

Inventor after: J. Strokie

Inventor before: M. Weber

Inventor before: D Marco

Inventor before: B. Schmid Hansberg

Inventor before: C. Hensher

Inventor before: O. Gronwald

Inventor before: JOSE BARAK

CB03 Change of inventor or designer information
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination