CN118304876A - 用于生产烯属不饱和羧酸或者羧酸酯的催化剂和生产方法 - Google Patents

用于生产烯属不饱和羧酸或者羧酸酯的催化剂和生产方法 Download PDF

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Publication number
CN118304876A
CN118304876A CN202410300905.4A CN202410300905A CN118304876A CN 118304876 A CN118304876 A CN 118304876A CN 202410300905 A CN202410300905 A CN 202410300905A CN 118304876 A CN118304876 A CN 118304876A
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China
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modified
metal
zirconium
silica
modifying
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Chinese (zh)
Inventor
亚当·卡伦
大卫·威廉·约翰逊
伊恩·安德鲁·约克
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Mitsubishi Chemical UK Ltd
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Mitsubishi Chemical UK Ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B01J23/04—Alkali metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/086—Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/313—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by introduction of doubly bound oxygen containing functional groups, e.g. carboxyl groups

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN202410300905.4A 2017-09-13 2018-09-13 用于生产烯属不饱和羧酸或者羧酸酯的催化剂和生产方法 Pending CN118304876A (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GBGB1714756.2A GB201714756D0 (en) 2017-09-13 2017-09-13 A catalyst and a process for the production of ethylenicallly unsaturated carboxylic acids or esters
GB1714756.2 2017-09-13
PCT/GB2018/052606 WO2019053438A1 (en) 2017-09-13 2018-09-13 PROCESS AND CATALYST FOR PRODUCTION OF CARBOXYLIC ACIDS OR ESTERS WITH ETHYLENE UNSATURATION
CN201880073462.2A CN111344059B (zh) 2017-09-13 2018-09-13 用于生产烯属不饱和羧酸或者羧酸酯的催化剂和生产方法

Related Parent Applications (1)

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CN201880073462.2A Division CN111344059B (zh) 2017-09-13 2018-09-13 用于生产烯属不饱和羧酸或者羧酸酯的催化剂和生产方法

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Publication Number Publication Date
CN118304876A true CN118304876A (zh) 2024-07-09

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CN201880073462.2A Active CN111344059B (zh) 2017-09-13 2018-09-13 用于生产烯属不饱和羧酸或者羧酸酯的催化剂和生产方法

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Country Link
US (1) US11602733B2 (enExample)
EP (1) EP3681628A1 (enExample)
JP (2) JP7384788B2 (enExample)
KR (1) KR102740946B1 (enExample)
CN (2) CN118304876A (enExample)
CA (1) CA3074006C (enExample)
GB (1) GB201714756D0 (enExample)
MX (1) MX2020002792A (enExample)
SG (1) SG11202001886QA (enExample)
WO (1) WO2019053438A1 (enExample)

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GB201714756D0 (en) 2017-09-13 2017-10-25 Lucite Int Uk Ltd A catalyst and a process for the production of ethylenicallly unsaturated carboxylic acids or esters
EP3939698A4 (en) * 2019-03-12 2022-06-08 Mitsubishi Chemical Corporation CATALYST, PROCESS FOR PREPARING A CATALYST AND PROCESS FOR PREPARING UNSATURATED CARBONIC ACIDS AND/OR UNSATURATED CARBONIC ESTERS
GB201903455D0 (en) * 2019-03-13 2019-04-24 Lucite Int Uk Ltd A process for the protection of a catalyst, a catalyst therefrom and a process for production of ethylenically unsaturated carboxlyic acids or esters
GB201910754D0 (en) * 2019-07-26 2019-09-11 Lucite Int Uk Ltd A catalyst and a process for the production of ethylenically unsaturated carboxylic acids or esters
CN112707814A (zh) * 2019-10-25 2021-04-27 中国石油化工股份有限公司 用醋酸甲酯制备丙烯酸甲酯的方法
US11806694B2 (en) 2020-03-12 2023-11-07 Mitsubishi Chemical UK Limited Catalyst and a process for the production of ethylenically unsaturated carboxylic acids or esters
US12064750B2 (en) * 2020-09-17 2024-08-20 Sk Innovation Co., Ltd. Cobalt-based single-atom dehydrogenation catalysts having high selectivity and regenerability and method for producing corresponding olefins from paraffins using the same
WO2022196717A1 (ja) * 2021-03-16 2022-09-22 積水化学工業株式会社 触媒、触媒の製造方法、ジエン化合物の製造方法、ポリマーの製造方法、ポリマー成形品の製造方法、触媒性能測定方法および長寿命化方法
CA3222204A1 (en) 2021-06-01 2022-12-08 Mitsubishi Chemical Corporation Catalyst, method for producing catalyst, and method for producing unsaturated carboxylic acid and/or unsaturated carboxylic acid ester
CN115814841A (zh) * 2021-10-31 2023-03-21 浙江新和成股份有限公司 功能化介孔材料催化剂及其制备方法和应用
CN117205909A (zh) * 2023-09-05 2023-12-12 中国科学院过程工程研究所 一种聚合物修饰的羟醛缩合催化剂的制备方法及应用
CN119793495B (zh) * 2023-10-09 2025-10-31 中国石油化工股份有限公司 醋酸甲酯与甲醛缩合制备丙烯酸甲酯用催化剂及其制备方法以及丙烯酸甲酯的制备方法
CN117563577B (zh) * 2023-11-16 2024-10-25 中国科学院过程工程研究所 一种二氧化硅载体表面羟基调控方法应用于合成甲基丙烯酸甲酯催化剂的制备
CN117654466B (zh) * 2024-02-01 2024-04-23 浙江新和成股份有限公司 催化剂及其制备方法、烯属不饱和酸或其酯的制备方法

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Publication number Publication date
JP2020533170A (ja) 2020-11-19
CA3074006A1 (en) 2019-03-21
GB201714756D0 (en) 2017-10-25
BR112020004960A2 (pt) 2020-09-15
KR102740946B1 (ko) 2024-12-11
KR20200053567A (ko) 2020-05-18
CN111344059B (zh) 2024-04-19
MX2020002792A (es) 2020-07-22
WO2019053438A1 (en) 2019-03-21
US11602733B2 (en) 2023-03-14
CA3074006C (en) 2024-06-11
JP7384788B2 (ja) 2023-11-21
SG11202001886QA (en) 2020-03-30
RU2020113238A3 (enExample) 2021-10-28
JP2023153789A (ja) 2023-10-18
RU2020113238A (ru) 2021-10-15
US20200269214A1 (en) 2020-08-27
EP3681628A1 (en) 2020-07-22
CN111344059A (zh) 2020-06-26
JP7851891B2 (ja) 2026-04-27

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