CN117701313B - 一种石油化工助剂及其制备方法 - Google Patents
一种石油化工助剂及其制备方法 Download PDFInfo
- Publication number
- CN117701313B CN117701313B CN202410163513.8A CN202410163513A CN117701313B CN 117701313 B CN117701313 B CN 117701313B CN 202410163513 A CN202410163513 A CN 202410163513A CN 117701313 B CN117701313 B CN 117701313B
- Authority
- CN
- China
- Prior art keywords
- petrochemical
- acrylamide
- diesel oil
- polymer emulsifier
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 36
- 239000000654 additive Substances 0.000 title claims abstract description 18
- 230000000996 additive effect Effects 0.000 title claims abstract description 18
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 33
- 239000002283 diesel fuel Substances 0.000 claims abstract description 31
- 229920000642 polymer Polymers 0.000 claims abstract description 29
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000002904 solvent Substances 0.000 claims abstract description 25
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 22
- 238000002485 combustion reaction Methods 0.000 claims abstract description 20
- 239000004593 Epoxy Substances 0.000 claims abstract description 14
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims abstract description 13
- DZSVIVLGBJKQAP-UHFFFAOYSA-N 1-(2-methyl-5-propan-2-ylcyclohex-2-en-1-yl)propan-1-one Chemical compound CCC(=O)C1CC(C(C)C)CC=C1C DZSVIVLGBJKQAP-UHFFFAOYSA-N 0.000 claims abstract description 12
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 12
- AVWKSSYTZYDQFG-UHFFFAOYSA-M dimethyl-octadecyl-prop-2-enylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC=C AVWKSSYTZYDQFG-UHFFFAOYSA-M 0.000 claims abstract description 12
- 239000000295 fuel oil Substances 0.000 claims abstract description 11
- 238000002156 mixing Methods 0.000 claims abstract description 11
- 239000012459 cleaning agent Substances 0.000 claims abstract description 10
- 239000000446 fuel Substances 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 238000010438 heat treatment Methods 0.000 claims description 17
- 238000003756 stirring Methods 0.000 claims description 17
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 16
- 238000001914 filtration Methods 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 11
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 10
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 10
- 230000001804 emulsifying effect Effects 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- -1 dodecyl dimethyl tertiary amine Chemical class 0.000 claims description 9
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- 239000000178 monomer Substances 0.000 claims description 7
- 238000005406 washing Methods 0.000 claims description 7
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 5
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 5
- 239000003999 initiator Substances 0.000 claims description 4
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims description 3
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 3
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 3
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 2
- 239000011261 inert gas Substances 0.000 claims description 2
- 239000000779 smoke Substances 0.000 abstract description 7
- 238000004945 emulsification Methods 0.000 abstract description 5
- 239000003921 oil Substances 0.000 abstract description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052799 carbon Inorganic materials 0.000 abstract description 3
- 230000003749 cleanliness Effects 0.000 abstract description 3
- 230000008021 deposition Effects 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 239000003502 gasoline Substances 0.000 abstract description 3
- 230000003647 oxidation Effects 0.000 abstract description 3
- 238000007254 oxidation reaction Methods 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 description 4
- 101150065749 Churc1 gene Proteins 0.000 description 4
- 102100038239 Protein Churchill Human genes 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 3
- 238000011160 research Methods 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000003723 Smelting Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
- C08F283/065—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals on to unsaturated polyethers, polyoxymethylenes or polyacetals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/02—Use of additives to fuels or fires for particular purposes for reducing smoke development
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/12—Inorganic compounds
- C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
- C10L1/125—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/223—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond having at least one amino group bound to an aromatic carbon atom
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/224—Amides; Imides carboxylic acid amides, imides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/232—Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
- C10L1/2493—Organic compounds containing sulfur, selenium and/or tellurium compounds of uncertain formula; reactions of organic compounds (hydrocarbons, acids, esters) with sulfur or sulfur containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
本发明提出了一种石油化工助剂及其制备方法,属于石油化工技术领域。包括聚合物乳化剂、助燃剂、燃油洁净剂和溶剂,所述聚合物乳化剂由烯丙基聚氧烷基环氧基醚、十八烷基二甲基烯丙基氯化铵、丙烯酰胺和2‑丙烯酰胺‑2‑甲基丙磺酸制备而成。本发明制备的石油化工助剂能够提高汽柴油的燃烧性性能,加入柴油中混合均匀能够制备乳化柴油,乳化效果好,不会发生柴油分层,燃料燃烧特性和排放特性优于普通柴油,特别是烟度排放下降明显,烟度排放可下降95%以上,不伤害发动机,不增加油耗,具有清洁性、抗氧化性和低腐蚀性,促进柴油充分燃烧,积碳减少,具有广阔的应用前景。
Description
技术领域
本发明涉及石油化工技术领域,具体涉及一种石油化工助剂及其制备方法。
背景技术
遍及国内的发电、冶炼、交通车辆等工业领域都以柴油作为能源,然而使用普通柴油的最大缺点就是燃烧不充分,大量的柴油能源没有燃烧充分便以黑烟的形式排放而流失,不仅对环境造成很大的污染,而且对自然资源是一大浪费。
为了解决这一问题,世界各国都在研究如何让柴油能燃烧充分,使其发挥更大的作用,而解决这一问题很好的途径就是给普通柴油中添加由各种化学成份组成的乳化助剂,再用水和柴油配制成乳化柴油。水和油由于互不相溶而形成界面,为了尽量缩小接触面积和降低体系能量,水与油混合时形成了分开的两层。为了使乳化柴油达到理想的乳化效果,需要一个合适的掺水乳化剂,此外还需要解决普通柴油、乳化助剂与水的配制比例以及配制乳化柴油的方法等问题,这些都是困扰目前乳化柴油发展研究的重大难题问题,也正是由于这些难题,使得乳化柴油的研究难以取得实质性的进展。
发明内容
本发明的目的在于提出一种石油化工助剂及其制备方法,能够提高汽柴油的燃烧性性能,加入柴油中混合均匀能够制备乳化柴油,乳化效果好,不会发生柴油分层,燃料燃烧特性和排放特性优于普通柴油,特别是烟度排放下降明显,烟度排放可下降95%以上,不伤害发动机,不增加油耗,具有清洁性、抗氧化性和低腐蚀性,促进柴油充分燃烧,积碳减少,具有广阔的应用前景。
本发明的技术方案是这样实现的:
本发明提供一种石油化工助剂,包括聚合物乳化剂、助燃剂、燃油洁净剂和溶剂,所述聚合物乳化剂由烯丙基聚氧烷基环氧基醚、十八烷基二甲基烯丙基氯化铵、丙烯酰胺和2-丙烯酰胺-2-甲基丙磺酸制备而成。
作为本发明的进一步改进,所述聚合物乳化剂、助燃剂、燃油洁净剂和溶剂的质量比为15-20:10-15:20-25:30-50。
作为本发明的进一步改进,所述助燃剂选自甲基苯骈三氮唑、十二烷基二甲基叔胺、十四烷基二甲基叔胺、十六烷基二甲基叔胺中的至少一种。
作为本发明的进一步改进,所述燃油洁净剂选自乙基四胺、二苯胺中的至少一种。
作为本发明的进一步改进,所述溶剂为水、N,N-二甲基甲酰胺和碳酸二甲酯的混合物,体积比为3-5:10:3-5。
作为本发明的进一步改进,所述烯丙基聚氧烷基环氧基醚、十八烷基二甲基烯丙基氯化铵、丙烯酰胺和2-丙烯酰胺-2-甲基丙磺酸的质量比为30-225:66-89:21-36:27-39。
作为本发明的进一步改进,所述烯丙基聚氧烷基环氧基醚的化学式为CH2=CHCH2O(PO)m(EO)nCH2(CHCH2)O,平均分子量为300-1500。
作为本发明的进一步改进,所述聚合物乳化剂的制备方法如下:
S1.将烯丙基聚氧烷基环氧基醚、十八烷基二甲基烯丙基氯化铵、丙烯酰胺和2-丙烯酰胺-2-甲基丙磺酸溶于水中,配制成单体总质量浓度为30-35wt%的水溶液;
S2.惰性气体保护下,向步骤S1中体系加入引发剂,加热搅拌反应,过滤,洗涤,干燥,粉碎,制得聚合物乳化剂。
作为本发明的进一步改进,所述加热搅拌反应的温度为50-70℃,时间为3-5h,所述引发剂选自过硫酸钾、过硫酸钠、过硫酸铵中的至少一种。
本发明进一步保护一种上述石油化工助剂的制备方法,包括以下步骤:向溶剂中加入聚合物乳化剂、助燃剂、燃油洁净剂,加热至50-70℃,搅拌混合0.5-1h,5000-7000r/min乳化10-15min,过滤,制得石油化工助剂。
本发明具有如下有益效果:本发明制备的石油化工助剂能够提高汽柴油的燃烧性性能,加入柴油中混合均匀能够制备乳化柴油,乳化效果好,不会发生柴油分层,燃料燃烧特性和排放特性优于普通柴油,特别是烟度排放下降明显,烟度排放可下降95%以上,不伤害发动机,不增加油耗,具有清洁性、抗氧化性和低腐蚀性,促进柴油充分燃烧,积碳减少,具有广阔的应用前景。
具体实施方式
下面将对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。
烯丙基聚氧烷基环氧基醚的化学式为CH2=CHCH2O(PO)m(EO)nCH2(CHCH2)O,平均分子量为300-1500,购于武汉市聚舜化工有限公司。
制备例1 聚合物乳化剂的制备
方法如下:
S1.将30重量份烯丙基聚氧烷基环氧基醚、66重量份十八烷基二甲基烯丙基氯化铵、21重量份丙烯酰胺和27重量份2-丙烯酰胺-2-甲基丙磺酸溶于水中,配制成单体总质量浓度为30wt%的水溶液;
S2.氮气保护下,向步骤S1中体系加入过硫酸铵,添加量为体系总质量的0.1wt%,加热至50℃,搅拌反应3h,过滤,洗涤,干燥,粉碎,制得聚合物乳化剂。
制备例2 聚合物乳化剂的制备
方法如下:
S1.将225重量份烯丙基聚氧烷基环氧基醚、89重量份十八烷基二甲基烯丙基氯化铵、36重量份丙烯酰胺、39重量份2-丙烯酰胺-2-甲基丙磺酸溶于水中,配制成单体总质量浓度为35wt%的水溶液;
S2.氮气保护下,向步骤S1中体系加入过硫酸钠,添加量为体系总质量的0.1wt%,加热至70℃,搅拌反应5h,过滤,洗涤,干燥,粉碎,制得聚合物乳化剂。
制备例3 聚合物乳化剂的制备
方法如下:
S1.将155重量份烯丙基聚氧烷基环氧基醚、72重量份十八烷基二甲基烯丙基氯化铵、30重量份丙烯酰胺和32重量份2-丙烯酰胺-2-甲基丙磺酸溶于水中,配制成单体总质量浓度为32wt%的水溶液;
S2.氮气保护下,向步骤S1中体系加入过硫酸钾,添加量为体系总质量的0.1wt%,加热至60℃,搅拌反应4h,过滤,洗涤,干燥,粉碎,制得聚合物乳化剂。
对比制备例1
与制备例3相比,不同之处在于,未添加烯丙基聚氧烷基环氧基醚。
具体如下:
S1.将72重量份十八烷基二甲基烯丙基氯化铵、30重量份丙烯酰胺和32重量份2-丙烯酰胺-2-甲基丙磺酸溶于水中,配制成单体总质量浓度为32wt%的水溶液;
S2.氮气保护下,向步骤S1中体系加入过硫酸钾,添加量为体系总质量的0.1wt%,加热至60℃,搅拌反应4h,过滤,洗涤,干燥,粉碎,制得聚合物乳化剂。
对比制备例2
与制备例3相比,不同之处在于,未添加十八烷基二甲基烯丙基氯化铵。
具体如下:
S1.将155重量份烯丙基聚氧烷基环氧基醚、30重量份丙烯酰胺和32重量份2-丙烯酰胺-2-甲基丙磺酸溶于水中,配制成单体总质量浓度为32wt%的水溶液;
S2.氮气保护下,向步骤S1中体系加入过硫酸钾,添加量为体系总质量的0.1wt%,加热至60℃,搅拌反应4h,过滤,洗涤,干燥,粉碎,制得聚合物乳化剂。
实施例1
本实施例提供一种石油化工助剂的制备方法,包括以下步骤:向30重量份溶剂中加入15重量份制备例1制得的聚合物乳化剂、10重量份十二烷基二甲基叔胺、20重量份乙基四胺,加热至50℃,搅拌混合0.5h,5000r/min乳化10min,过滤,制得石油化工助剂。
所述溶剂为水、N,N-二甲基甲酰胺和碳酸二甲酯的混合物,体积比为3:10:3。
实施例2
本实施例提供一种石油化工助剂的制备方法,包括以下步骤:向50重量份溶剂中加入20重量份制备例2制得的聚合物乳化剂、15重量份十四烷基二甲基叔胺、25重量份乙基四胺,加热至70℃,搅拌混合1h,7000r/min乳化15min,过滤,制得石油化工助剂。
所述溶剂为水、N,N-二甲基甲酰胺和碳酸二甲酯的混合物,体积比为5:10:5。
实施例3
本实施例提供一种石油化工助剂的制备方法,包括以下步骤:向40重量份溶剂中加入17重量份制备例3制得的聚合物乳化剂、12重量份甲基苯骈三氮唑、22重量份二苯胺,加热至60℃,搅拌混合1h,6000r/min乳化12min,过滤,制得石油化工助剂。
所述溶剂为水、N,N-二甲基甲酰胺和碳酸二甲酯的混合物,体积比为4:10:4。
实施例4
本实施例提供一种石油化工助剂的制备方法,包括以下步骤:向40重量份溶剂中加入17重量份制备例3制得的聚合物乳化剂、12重量份甲基苯骈三氮唑、22重量份二苯胺,加热至60℃,搅拌混合1h,6000r/min乳化12min,过滤,制得石油化工助剂。
所述溶剂为水、N,N-二甲基甲酰胺和碳酸二甲酯的混合物,体积比为1:10:1。
实施例5
本实施例提供一种石油化工助剂的制备方法,包括以下步骤:向40重量份溶剂中加入17重量份制备例3制得的聚合物乳化剂、12重量份甲基苯骈三氮唑、22重量份二苯胺,加热至60℃,搅拌混合1h,6000r/min乳化12min,过滤,制得石油化工助剂。
所述溶剂为水、N,N-二甲基甲酰胺和碳酸二甲酯的混合物,体积比为10:10:10。
对比例1
与实施例3相比,不同之处在于,聚合物乳化剂由对比制备例1制得。
具体如下:
本实施例提供一种石油化工助剂的制备方法,包括以下步骤:向40重量份溶剂中加入17重量份对比制备例1制得的聚合物乳化剂、12重量份甲基苯骈三氮唑、22重量份二苯胺,加热至60℃,搅拌混合1h,6000r/min乳化12min,过滤,制得石油化工助剂。
所述溶剂为水、N,N-二甲基甲酰胺和碳酸二甲酯的混合物,体积比为4:10:4。
对比例2
与实施例3相比,不同之处在于,聚合物乳化剂由对比制备例2制得。
具体如下:
本实施例提供一种石油化工助剂的制备方法,包括以下步骤:向40重量份溶剂中加入17重量份对比制备例2制得的聚合物乳化剂、12重量份甲基苯骈三氮唑、22重量份二苯胺,加热至60℃,搅拌混合1h,6000r/min乳化12min,过滤,制得石油化工助剂。
所述溶剂为水、N,N-二甲基甲酰胺和碳酸二甲酯的混合物,体积比为4:10:4。
对比例3
与实施例3相比,不同之处在于,未添加聚合物乳化剂。
具体如下:
本实施例提供一种石油化工助剂的制备方法,包括以下步骤:向40重量份溶剂中加入12重量份甲基苯骈三氮唑、22重量份二苯胺,加热至60℃,搅拌混合1h,6000r/min乳化12min,过滤,制得石油化工助剂。
所述溶剂为水、N,N-二甲基甲酰胺和碳酸二甲酯的混合物,体积比为4:10:4。
测试例1
将本发明实施例1-5和对比例1-3制得的石油化工助剂分别加入200号重油和250号重油中,添加量为0.15g/kg,测试CO排放量,评估其燃烧效率。结果见表1。
表1
由上表可知,添加本发明石油化工助剂后,能够明显提高重油的燃烧效率,CO排放量明显降低。
测试例2
向柴油中添加200ppm的本发明实施例1-5和对比例1-3制得的石油化工助剂,测试柴油十六烷值,结果见表2。
表2
组别 | 柴油十六烷值 |
实施例1 | 57 |
实施例2 | 58 |
实施例3 | 60 |
实施例4 | 55 |
实施例5 | 56 |
对比例1 | 53 |
对比例2 | 51 |
对比例3 | 48 |
未添加助剂 | 46 |
由上表可知,添加本发明石油化工助剂后,能够明显提高柴油的十六烷值。
以上所述仅为本发明的较佳实施例而已,并不用以限制本发明,凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。
Claims (5)
1.一种提高柴油燃烧性能的石油化工助剂,其特征在于,包括聚合物乳化剂、助燃剂、燃油洁净剂和溶剂,所述聚合物乳化剂、助燃剂、燃油洁净剂和溶剂的质量比为15-20:10-15:20-25:30-50;所述聚合物乳化剂由烯丙基聚氧烷基环氧基醚、十八烷基二甲基烯丙基氯化铵、丙烯酰胺和2-丙烯酰胺-2-甲基丙磺酸制备而成,所述烯丙基聚氧烷基环氧基醚、十八烷基二甲基烯丙基氯化铵、丙烯酰胺和2-丙烯酰胺-2-甲基丙磺酸的质量比为30-225:66-89:21-36:27-39;
所述助燃剂选自甲基苯骈三氮唑、十二烷基二甲基叔胺、十四烷基二甲基叔胺、十六烷基二甲基叔胺中的至少一种;
所述燃油洁净剂选自乙基四胺、二苯胺中的至少一种。
2.根据权利要求1所述石油化工助剂,其特征在于,所述溶剂为水、N,N-二甲基甲酰胺和碳酸二甲酯的混合物,体积比为3-5:10:3-5。
3.根据权利要求1所述石油化工助剂,其特征在于,所述聚合物乳化剂的制备方法如下:
S1.将烯丙基聚氧烷基环氧基醚、十八烷基二甲基烯丙基氯化铵、丙烯酰胺和2-丙烯酰胺-2-甲基丙磺酸溶于水中,配制成单体总质量浓度为30-35wt%的水溶液;
S2.惰性气体保护下,向步骤S1中体系加入引发剂,加热搅拌反应,过滤,洗涤,干燥,粉碎,制得聚合物乳化剂。
4.根据权利要求3所述石油化工助剂,其特征在于,所述加热搅拌反应的温度为50-70℃,时间为3-5h,所述引发剂选自过硫酸钾、过硫酸钠、过硫酸铵中的至少一种。
5.一种如权利要求1-4任何一项所述石油化工助剂的制备方法,其特征在于,包括以下步骤:向溶剂中加入聚合物乳化剂、助燃剂、燃油洁净剂,加热至50-70℃,搅拌混合0.5-1h,5000-7000r/min乳化10-15min,过滤,制得石油化工助剂。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202410163513.8A CN117701313B (zh) | 2024-02-05 | 2024-02-05 | 一种石油化工助剂及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202410163513.8A CN117701313B (zh) | 2024-02-05 | 2024-02-05 | 一种石油化工助剂及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN117701313A CN117701313A (zh) | 2024-03-15 |
CN117701313B true CN117701313B (zh) | 2024-04-05 |
Family
ID=90161096
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202410163513.8A Active CN117701313B (zh) | 2024-02-05 | 2024-02-05 | 一种石油化工助剂及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN117701313B (zh) |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101555424A (zh) * | 2009-05-14 | 2009-10-14 | 济南泉香实业有限公司 | 秸秆油/水/柴油的微乳燃料及其制备方法 |
CN104558401A (zh) * | 2013-10-14 | 2015-04-29 | 郭保祥 | 一种多功能离子缔合型乳液及其制备方法 |
CN104651002A (zh) * | 2013-11-19 | 2015-05-27 | 张晨 | 一种水煤浆分散稳定剂 |
CN106146730A (zh) * | 2015-03-25 | 2016-11-23 | 中国石油天然气股份有限公司 | 一种丙烯酰胺类聚合物增稠剂及其制备方法和压裂液 |
CN109181486A (zh) * | 2018-09-26 | 2019-01-11 | 雅图高新材料有限公司 | 一种低voc的环氧底漆及其制备方法 |
CN111320728A (zh) * | 2020-03-20 | 2020-06-23 | 陕西科技大学 | 一种两性单宁酸基煤沥青水浆分散剂及制备方法 |
CN111321605A (zh) * | 2020-03-13 | 2020-06-23 | 李圣舜 | 一种pvb合成革及其制备方法 |
CN114702990A (zh) * | 2022-05-11 | 2022-07-05 | 深圳市厚和科技有限公司 | 一种复合型清净增效燃油添加剂及其制备方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040020105A1 (en) * | 2002-07-23 | 2004-02-05 | The Lubrizol Corporation A Corporation Of The State Of Ohio | Emulsified water fuel blend containing an aqueous organic ammonium salt |
-
2024
- 2024-02-05 CN CN202410163513.8A patent/CN117701313B/zh active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101555424A (zh) * | 2009-05-14 | 2009-10-14 | 济南泉香实业有限公司 | 秸秆油/水/柴油的微乳燃料及其制备方法 |
CN104558401A (zh) * | 2013-10-14 | 2015-04-29 | 郭保祥 | 一种多功能离子缔合型乳液及其制备方法 |
CN104651002A (zh) * | 2013-11-19 | 2015-05-27 | 张晨 | 一种水煤浆分散稳定剂 |
CN106146730A (zh) * | 2015-03-25 | 2016-11-23 | 中国石油天然气股份有限公司 | 一种丙烯酰胺类聚合物增稠剂及其制备方法和压裂液 |
CN109181486A (zh) * | 2018-09-26 | 2019-01-11 | 雅图高新材料有限公司 | 一种低voc的环氧底漆及其制备方法 |
CN111321605A (zh) * | 2020-03-13 | 2020-06-23 | 李圣舜 | 一种pvb合成革及其制备方法 |
CN111320728A (zh) * | 2020-03-20 | 2020-06-23 | 陕西科技大学 | 一种两性单宁酸基煤沥青水浆分散剂及制备方法 |
CN114702990A (zh) * | 2022-05-11 | 2022-07-05 | 深圳市厚和科技有限公司 | 一种复合型清净增效燃油添加剂及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN117701313A (zh) | 2024-03-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2317399C (en) | An additive composition also used as a fuel composition comprising water soluble alcohols | |
CN101643677B (zh) | 一种燃油添加剂 | |
CN102517101B (zh) | 一种车用甲醇柴油燃料及其制备方法 | |
CN104212503B (zh) | 一种柴油添加剂 | |
CN117701313B (zh) | 一种石油化工助剂及其制备方法 | |
CN106811249A (zh) | 一种燃油环保添加剂及其制备方法 | |
CN104388129A (zh) | 一种汽油掺烧燃料及含有该掺烧燃料的汽油 | |
CN109628175A (zh) | 一种提高抗爆性与节能减排的燃油添加剂 | |
DK174108B1 (da) | Brændstof på basis af ethanol og anvendelse heraf som dieselbrændstof | |
CN104818057A (zh) | 一种汽车用醇基柴油复合树脂型乳化剂及其制备方法和应用其的助剂 | |
CN104593105B (zh) | 一种高清洁汽油添加剂及其制备方法 | |
CN110872534A (zh) | 一种增强节油片、制备方法及其应用方法 | |
CN115197756A (zh) | 一种醇基汽油燃料及其制备方法 | |
CN111607440A (zh) | 一种纳米材料柴油助燃剂及其制备方法 | |
CN101328424B (zh) | 一种生物质乳化柴油组合物 | |
CN113088347B (zh) | 一种点燃式车用改性甲醇燃料及其制备方法 | |
CN101497830A (zh) | 一种高效环保节能柴油添加剂 | |
CN110317647A (zh) | 一种乙醇汽油清净剂及其制备方法 | |
CN111978998A (zh) | 一种新型m100车用甲醇燃料 | |
CN114479981B (zh) | 一种低掺量的高效节煤剂及其制备方法 | |
CN117210254A (zh) | 一种甲醇改性剂 | |
KR940009045B1 (ko) | 연료의 개질제(改質劑) | |
CN108276306B (zh) | 一种胺基叠氮类十六烷值改进剂及其制备方法和应用 | |
CN111218310A (zh) | 一种重油掺水催化剂 | |
CN1539926A (zh) | 一种醇燃料配方 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |